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Version: 13
Primax Electronics LTD.
Green Product Chemical Substances Specification PAGE: 1 OF 32
Green Product Chemical Substances Specification –v13 Document No.: QW-5Q002 Level of Secret ■Common□confidential
Green Product Chemical Substances Specification
Approver Reviewer Issuer Department
By Honda Lee Jay Yung IT&PDTC
Date 09/04/2013 09/04/2013
Version: 13
Primax Electronics LTD.
Green Product Chemical Substances Specification PAGE: 2 OF 32
Green Product Chemical Substances Specification –v13 Document No.: QW-5Q002 Level of Secret ■Common□confidential
Version Date Change Content Issuer Approver
1.0 8/29/2003 Original Issue Hongdar Kuo LY Wang
2.0 12/15 / 2003 Title, Scope, Spec and requirement Hongdar Kuo Honda Lee
2.1 12/30 / 2003 Spec update Hongdar Kuo Honda Lee
2.2 1/15 / 2004 Revise testing method, spec and wording
Hongdar Kuo Honda Lee
3.0 9/29/2004 Revise testing method and update spec. Add heat resistance requirements for lead-free component
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5 Requirement
5.1 Any materials, parts, assemblies, accessories, auxiliary materials and packaging materials
provided to Primax must not contain environment-related substances defined by the Primax
Green Products Chemical Substances Specification (except for substances that are used for
survey). Natural impurities are acceptable but they must be in line with the related regulations.
5.2 When part approved, Primax’s suppliers must send parts/materials to an authorized laboratory
(see Appendix 3) and follow up disassembling rule 6.2.1 to test and complete the “GP Portal”.
(Test report deadline is one year). Test report requirements follow up item 8.
5.3 If parts/materials provided or added to a product in processing process by Primax suppliers
contained environment-related substances listed in Appendix 1, suppliers must report and
complete the “GP Portal” by homogenous materials. In order to comply with EU related
environmental rules (ex. REACH directive…..), Primax’s suppliers must survey all substances
(100% composition) which contained in parts and fill out the “GP Portal”. Reference example:
capacitor (see the following picture) is disassembled at least 7 homogenous materials and fill
out the “GP Portal”.
Terminal Plating
5.4 When fill out the “GP Portal”, supplier must follow up homogenous material principle to
declare coating material which is used on pin of electronic component(such as
Sn-3.0Ag-0.5Cu,matte Sn….) or surface treatment of metal alloy.(such as Ni,Cr3+, Cr6+…)
5.5 Primax will use XRF to carry out incoming inspection for Br and Cr (Cr3+ + Cr6+) contained in
homogenous material of a product. Primax’s suppliers must fill Br, Cr3+ and Cr6+ content
clearly in the “GP Portal”.
5.6 If suppliers don’t follow 5.3 to fill out the “GP Portal”, suppliers must send the samples to test
by Primax approved laboratory. Furthermore, suppliers must provide MSDS/materials content
list of parts again and identify what kinds of environment-related substances.
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Green Product Chemical Substances Specification –v13 Document No.: QW-5Q002 Level of Secret ■Common□confidential
5.7 Halogen threshold of Appendix 1 is applicable to Halogen-Free part.
5.8 Halogen-Free part must meet requirements of Safety, EMC, Reliability, electrical, mechanical
and related criteria.
5.9 Lithium battery must provide MSDS and test report of UN manual of tests and criteria, part III,
subsection 38.3. Non-lithium battery must provide MSDS.
5.10 If parts/materials provided or added to a product in processing process by Primax suppliers
contained conflict minerals, such as tin, tantalum, gold, tungsten or their derivatives. Suppliers
must upload the “Declaration of DRC Conflict-free” and complete the smelter information in
GP Portal.
6 Specifications
6.1 Environment-related substances that are controlled by Primax, for detailed specifications, see
Appendix 1.
6.2 Highly hazardous banned substances:
According to EU RoHS, six chemical substances: lead, cadmium, mercury, hexavalent
Chromium, PBB, and PBDE are considered as highly hazardous banned substances by Primax.
Suppliers must report to Primax if they used the environment-related substances in their
parts/materials and provide testing report if they used highly hazardous banned substances as
well.
6.2.1 The same type of parts may contain several kinds of materials. Therefore, when parts are
testing, they must be disassembled and testing separately. Disassembling rule is suggested
as follows:
a. Outer or exposed parts of a product should be disassembled as separate materials.
E.g.: If ink is used on an outer part, the ink and the outer part should be testing separately.
b. Small-scale parts smaller than 4 cubic millimeter (mm3) need not to be disassembled. The
part is more than 4 mm3 must follow up next 3 steps:
1.The parts with pin need to be disassembled pin and body. (such as: DIP, QFP…)
2.The parts without pin need to be disassembled electrode and body. (such as:
Resistance…)
3.BGA series need to be disassembled solder ball and body.
c. A part with different materials should be disassembled as separate materials.
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E.g.: Connectors should be disassembled as housing (plastic) and contact (metal) and be
testing separately.
d. A part with different colors materials (such as ink, plastic and cables) should be testing
separately.
E.g.: If a part has three colors for the same kind of wire: red, blue, and white. Wires of
different colors should be testing separately.
e. Parts made from different formulas or made by different vendors should be testing
separately.
E.g.: Different ABS materials should be testing separately.
f. Notice that materials added in manufacturing process, such as lubricants, must be testing.
6.2.2 Lead:
6.2.2.1 Applicable to all items apart from the exceptions listed in 6.2.2.4
6.2.2.2 Specifications: ・Plastic, rubber, paint, ink, printing, resin and packaging materials: lead concentration < 90 ppm ・Metal: lead concentration < 1000 ppm (*for lead concentration of steel, aluminum, copper, refer to 6.2.2.4 Exceptions) ・Glass materials, ceramic parts: lead concentration < 1000 ppm, but exceptions defined in RoHS are acceptable ・Electronic parts: lead concentration< 1000 ppm ・Solder: lead concentration < 1000 ppm ・Others: lead concentration < 1000 ppm ・Cable: cable wrappings, cable jacket, etc.: lead concentration < 90ppm; the metal part of a cable: lead concentration < 1000 ppm.
6.2.2.3 Testing Method: IEC 62321
6.2.2.4 Exceptions: · Alloys: a. steel: lead concentration < 3500 ppm b. aluminum alloy: lead concentration < 4000 ppm c. copper alloy: lead concentration < 40000 ppm · Lead contained in a high-melting point solder (lead based alloys containing 85% by weight or more lead) · Lead contained in solder used for a server or a storage device. · Electrical and electronic components containing lead in a glass or ceramic other than dielectric ceramic in capacitors. (e.g. piezoelectric devices, or in a glass or ceramic matrix compound) The above glass materials include adhesives, resistor elements, glass frit, conductive pastes(silver or cooper ones), and sealing materials. · Lead in glass of cathode-ray tubes.
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· Lead in glass of fluorescent tubes not exceeding 0.2 % by weight. · Optical glass, filter glass.
· Solder to complete a viable electrical connection between semiconductor die and carrier within integrated circuit Flip Chip packages.
6.2.3 Cadmium:
6.2.3.1 Applicable to all items apart from the exceptions listed in 6.2.3.4
6.2.3.2 Specifications:
・Metal coating: cadmium and cadmium compounds are banned.
・Others : cadmium concentration < 50 ppm
6.2.3.3 Testing Method: IEC 62321/EN 1122 (only for plastics)
6.2.3.4 Exceptions:
· The plating of electrical contacts is required highly reliability, which has no
substitute materials.
· Filter glass
6.2.4 Mercury:
6.2.4.1 Applicable to all items apart from the exceptions listed in 6.2.4.4
6.2.4.2 Specifications:
‧All applications: mercury concentration < 5 ppm
6.2.4.3 Testing Method: IEC 62321
6.2.4.4 Exceptions:
‧Mercury in cold cathode fluorescent lamps and external electrode fluorescent lamps
(CCFL and EEFL) for special purposes (per lamp):
a. Short length (≦500 mm): mercury concentration < 3.5 mg
b. Medium length ( >500 mm and ≦1500 mm): mercury concentration < 5 mg
c. Long length ( >1500 mm): mercury concentration < 13 mg
‧Mercury in other low pressure discharge lamps (per lamp) < 15 mg
6.2.5 Hexavalent Chromium:
6.2.5.1 Applicable to all items, no exception.
6.2.5.2 Specifications:
・Metal coating, printing, paint and ink: hexavalent chromium and hexavalent
chromium compounds are banned.
・Plastic, rubber and packaging materials: hexavalent chromium concentration < 100
ppm
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a. LevelⅡRestricted Substances. Threshold < 1000 ppm (Except for ceramics and glass) b. Ceramics and glass: Level Ⅲ Managed Substances. For survey purpose (Example: electronic component)
a. Level Ⅱ Restricted Substances. Threshold < 50 ppm (Except for semiconductors and metal alloys) b. Level Ⅱ Restricted Substances. Restricted in metal alloys. Threshold < 1000 ppm c. Semiconductors: Level Ⅲ Managed Substances. For survey purpose
Beryllium 7440-41-7
Beryllium oxide 1304-56-9
Beryllium-Aluminum alloy 12770-50-2
Beryllium copper —
Beryllium hydroxide 13327-32-7
Beryllium phosphate 13598-15-7
Beryllium and Beryllium Compounds
Beryllium sulfate tetrahydrate 7787-56-6
a. Level Ⅱ Restricted Substances. Threshold < 1000 ppm (Except for electronic components) b. Electronic components: Level Ⅲ
Managed Substances. For survey purpose
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Category Substance CAS# Threshold
Beryl ore 1302-52-9
Beryllium Carbonate 66104-24-3
Beryllium Nitrate 13597-99-4
Beryllium Chloride 7787-47-5
Beryllium Fluoride 7787-49-7
Beryllium Sulfate 13510-49-1
Beryllium Copper —
Other Beryllium compounds —
Bismuth 7440-69-9
Bismuth trioxide 1304-76-3
Bismuth nitrate 10361-44-1
Bismuth and Bismuth Compounds
Other bismuth compounds —
Level Ⅲ Managed Substances. For survey purpose
Cadmium 7440-43-9
Cadmium oxide 1306-19-0
Cadmium sulfide 1306-23-6
Cadmium chloride 10108-64-2
Cadmium sulfate 10124-36-4
Cadmium Carbonate 513-78-0
Cadmium fluoroborate 14486-19-2
Cadmium nitrate 10325-94-7
Cadmium nitrate tetrahydrate 10022-68-1
Cadmium stearate 2223-93-0
Cadmium chromate 14312-00-6
Cadmium and Cadmium Compounds
Other cadmium compounds —
Level I Banned Substances. Threshold < 50 ppm; Metal coating is not intentionally added.
Chromium (Ⅲ) oxide 1308-38-9
Neochromium 64093-79-4 Chromium and its Compounds(excluding hexavalent chromium) Other chromium compounds —
Level Ⅲ Managed Substances. For survey purpose
Sodium dichromate 10588-01-9
Chromium(VI) oxide 1333-82-0
Calcium chromate 13765-19-0
Lead(II) chromate 7758-97-6
Potassium dichromate 7778-50-9
Potassium chromate 7789-00-6
Chromium (Cr6+) 18540-29-9
Chromic acetate 1066-30-4
Chromium (VI) and its Compounds2 18540-29-9
Lithium chromate 14307-35-8
Sodium chromate 7775-11-3
Hexavalent Chromium Compounds
Potassium chlorochromate 16037-50-6
a. Level I Banned Substances. Plastic, rubber and packaging materials. Threshold < 100 ppm; Metal coating, printing, ink and paint are not intentionally added. b. Other application. Threshold < 1000 ppm
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a. Level I Banned Substances. Banned in plastic, rubber, dyes, pigments, paints, polymer colorants , stabilizers, and packaging materials. Threshold < 90 ppm b. Other application, e.g. electronic parts. Threshold < 1000 ppm c. Solder: Threshold < 1000 ppm d. Steel: Threshold < 3500 ppm e. aluminum alloy: Threshold < 4000 ppm f. copper alloy: Threshold < 40000 ppm
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Category Substance CAS# Threshold
Lead (IV) chloride 13463-30-4
Lead (II) iodide 10101-63-0
Lead (II) cyanide 592-05-2
Lead fluoroborate 13814-96-5
Lead fluosilicate 25808-74-6
Lead nitrate 10099-74-8
Lead perchlorate 13637-76-8
Lead thiocyanate 592-87-0
Lead (II) acetate,trihydrate 6080-56-4
Lead (II) acetate 301-04-2
Lead (IV) acetate 546-67-8
Lead oleate 1120-46-3
Lead stearate 7428-48-0
Lead (II) metaborate 10214-39-8
Lead metasilicate 11120-22-2
Lead metasilicate 10099-76-0
Lead antimonite 13510-89-9
Lead arsenate (1:1) 7784-40-9
Lead (II) arsenite 10031-13-7
Lead chromate; chrome yellow 1344-37-2
Lead molybdate 10190-55-3
Calcium plumbate 12013-69-3
Tetramethyl lead 75-74-1
Tetraethyl lead 78-00-2
Lead Naphthenate 61790-14-5
Lead Methanesulfonate 17570-76-2
Lead Styphnate 15245-44-0
Other lead compounds —
Mercury 7439-97-6
Mercury(II) chloride 7487-94-7
Mercury(II) oxide 21908-53-2
Mercuric chloride 33631-63-9
Mercuric sulfide 1344-48-5
Mercury alloys; amalgam —
Mercury (I) oxide 15829-53-5
Mercury (I) chloride 10112-91-1
Mercury (II) nitrate 10045-94-0
Mercury (I) sulfate 7783-35-9
Mercury and Mercury Compounds
Mercury (II) fulminate 628-86-4
a. Level I Banned Substances. Threshold < 5 ppm b. Mercury in cold cathode fluorescent lamps and external electrode fluorescent lamps (CCFL and EEFL) for special purposes (per lamp): b-1 Short length (≦500 mm): mercury concentration < 3.5 mg b-2 Medium length ( >500 mm and ≦1500 mm): mercury concentration < 5 mg b-3 Long length ( >1500 mm): mercury concentration < 13 mg
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Category Substance CAS# Threshold
Mercury (II) acetate 1600-27-7
Methylmercury salts 22967-92-6
Ethymercury salts —
Propylmercury salts —
Phenylmercury salts —
Methoxyethylmercury salts —
Dialkylmercury —
Diphenylmercury 587-85-9
Mercuriphenyl Nitrate 55-68-5
Other mercury compounds —
c. Mercury in other low pressure discharge lamps (per lamp) < 15 mg
Nickel(II) oxide 1313-99-1
Nickel(II) Carbonate 3333-67-3
Nickel(II) Sulfate 7786-81-4
Nickel 7440-02-0
Nickel carbonyl 13463-39-3
Nickelhydroxide 11113-74-9
Nickel(II)hydroxide 12054-48-7
Nickeldioxide 12035-36-8
Nickelsubsulphide 12035-72-2
Nickelsulphide 11113-75-0
Nickelsulphide 12137-12-1
Nickel acetate 373-02-4
Nickelocene 1271-28-9
Nickel and Nickel Compounds
Other Nickel compounds —
a. Level Ⅱ Restricted Substances. It is not intentionally added in the surfaces of products that are intended to come into direct and prolonged contact with the skin. b. Other application: Level Ⅲ Managed Substances. For survey purpose
Selenium 7782-49-2
Selenous Acid 7783-00-8
Hydrogen selenide 7783-07-5
Sodium selenide 1313-85-5
Selenium dioxide 7446-08-4
Sodium selenate 10112-94-4
Dimethyl selenide 593-79-3
Selenium oxide 12640-89-0
Selenium and Selenium Compounds
Other selenium compounds —
Level Ⅲ Managed Substances. For survey purpose
Magnesium Magnesium 7439-95-4 Level Ⅲ Managed Substances. For survey purpose
Copolymer of alkyl acrylate, methyl methacrylate and tributyltin methacrylate(alkyl; C=8)
67772-01-4
Tributyltin sulfamate 6517-25-5
Bis(tributyltin) maleate 14275-57-1 24291-38-3
Tributyltin chloride 1461-22-9 7342-38-3
Mixture of tributyl tin cyclopentanecarboxylate and its alaogs (Tributyl tin naphthenate)
85409-17-2
Mixture of tributyltin 1,2,3,4,4a,4b,5,6,10,10a-decahydro-7- isopropyl-1,4a-dimethyl-1-phenanthlenecarboxylate and its analogs (Tributyltin rosin salt)
26239-64-5
Tributyl tin & compounds 688-73-3
Tributyl tin bromide 1461-23-0
Tributyl Tins & Triphenyl Tins
Triphenyl tin bromide —
Level I Banned Substances. Not intentionally added
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Level I Banned Substances. Not intentionally added
Vinyl Chloride Polymer (PVC)
Poly vinyl chloride(PVC) 9002-86-2
a. Level Ⅱ Restricted Substance. Not intentionally added (except for cable and connectors) b. Level Ⅲ Managed Substances. Cable and connectors for survey purpose
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(14) [ Aliphatic/alicyclic brominated compounds ]
—
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(15) [ Aliphatic/alicyclic brominated compounds in combination with antimony compounds ]
—
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(16) [ Aromatic brominated compounds (excluding brominated diphenyl ether and biphenyls) ]
—
Brominated Flame Retardants
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(17) [ Aromatic brominated compounds (excluding brominated diphenyl ether and biphenyls) in combination with antimony compounds ]
—
a. Level Ⅱ Restricted Substance. Threshold < 900 ppm (except for cable/connectors, electronic component, fans, power supplier,
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Category Substance CAS# Threshold
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(22) [ Aliphatic/alicyclic chlorinated and brominated compounds ]
—
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(42) [ Brominated organic phosphorus compounds ]
3846-71-7 Level I Banned Substances. Not intentionally added
Acids generated from chromium trioxide and their oligomers. Group containing: Chromic acid, Dichromic acid, and oligomers of chromic acid and dichromic acid
Acids generated from chromium trioxide and their oligomers. Group containing: Chromic acid, Dichromic acid and oligomers of chromic acid and dichromic acid