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Genel Kimya - Afyonkarahisar Üniversitesi Mühendislik Kimyası Ders Notları

Jun 02, 2018

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  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

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    Hmjfltnzhm [ npn Ltdnfgnd Mtahnd Hmjfltnd K mvrmf rfld

    Knmhmjfltnzhm DdFljmtno

    hmjfltndhahlftl

    smenp klngknr

    Pmrmhljfltnzhm DdPazntno

    jlgnnjzlghmjfltndhahlftlsmenptnr

    Olrrahmjfltnzhm

    Iyd Pazntno

    \yj. mgmffoafdsnyafu

    Hndraympymimg

    pmrmglg srmghmjfltndhahlftlsmenptnr

    Mftnolrrahmjfltnzhm DdPazntno

    dmrd pmrmglgvl mftnpmrmglg

    hmjfltndhahlftlsmenptnr

    Olrrnhmjfltnzhm

    Iyd

    Pazntno

    Hndraympymimg

    mftnpmrmglghmjfltndhahlftlsmenptnr

    notglhlhn lgldtrafgmrm smenp hmkklglrnf jstlrknnhmjfltnd mgmfm karu ldnghl zlggnnfl pmrmhmjfltnzhm

    klfnr.Iufuf zkk zlggnd knmhmjfltnzhmkr. ^mfn itflgldtrafgmr notglhn hmkklglrnf jstlrknn hmjfltnd mgmftmrmofkmf ntnghlsn zlggnnfl knmhmjfltnzhm klfnr.Pmrmhmjfltnzhm smklcl kmrkmf inr hmjfltnd mgmfuyjugmfk zmhmf jrglf inr zlggndtnr.

    Inrkl Daimgt, Fndlg, Klhnr jnin hltmgglrnf kmrkmf inrhmjfltnd mgmf uyjugmfhmk emgkl dlfkngnnfklf hmjfltndzlggnd jstlrhlsn zlggnn vmrkr dn, iufm kmolrrahmjfltnzhm klfnr.

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    rfld

    f mz inr notglhlhn lgldtrafm smenp

    Mtahgmr, hagldgglr

    ymkm nyafgmr, pmrmhmjfltndtnr.

    Mzat mtahu, PMYMHMJFL[D[Y

    =s 9s 9p

    F =s99s99p3

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Saru 11

    Mmkmdnglrklf emfjnsn pmrmhmjfltndtnr1

    Fm (==)

    Cm (90)

    D+ (=>)

    A9- (5)

    rfld 2 Pmrmhmjfltnzhm

    Plrnyaknd [miga

    Plrnyaknd tmiga flklfflhgnknr 1

    Plrnyaknd tmiga inrdnhymc nnf ad omykmgmrmtr.

    Elr tlst vlmrmtrhmkm duggmfgr.

    Lglhlftglr emdd

    fkminr ad ingjnyn nnfklimrfkrr.

    gd Klflhlglr

    kzlfsnzkn !!!

    Lglhlftglrnfarjmfnzmsyafu yadtu.

    Ingjnyn iughmd jt.

    Dnhymcgmr mfgmhyarku.

    Plrnyaknd [migakmdn Mnglglr

    Dagafgmr mnglglr emgnfkldnjrupgmrkr.

    Mnglglr inr dagafkmagminglcln jnin inrdmdagafkm km agmingnr.

    Mnglglr fuhmrmkmf znymklnsnhglrl smenptnr.

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Plrnyaknd [miga

    g ingnhslg plrnyaknd tmiga Yus dnhymc Khntrn Hlfklgllv

    tmrmo

    fkmf =5?> y

    g

    fkm artmym dafughutur.

    Hlfklgllv, ilfzlr zlggndglr tmymf lglhlftglrn mrdmmrdmym knzknnfkl, mtah dtglsnfl kmymfmf inr tmiga lgkllthntnr.

    A zmhmfgmr ingnfhlylf imz lglhlftglrnf (sdmfknyuh,jmgyuh vl jlrhmfyuh (ldmsngndaf) jnin) vmrgf, emttmzlggndglrnfn tmehnf lklinghntn.

    Gatemr Hlylr nsnhgn mrmtrhmc km, =55? ygfkm, Hlfklgllv'klfimhsz agmrmd, mtah dtglglrnfl jrl inr plrnyaknd tmiga aguturhuvl "vmgmfs" dmvrmhf artmym mtht.

    Lglhlftglrnf Snhjlglrn

    ad mz smykm lglhlftnf ingnfknn zmhmfgmrkm, lglhlftglr, Pgmta'fuf

    Lsdn ^ufmfggmrf duggmfk taprmd-emvm-su vl mtl slhiagglrnfklf

    ympt uymrgmhmgmrgm snhjlglfnyarku. Kmem safrm ylfn lglhlftglr

    dlolkngkndl, th lglhlftglrnf lfnfkl safufkm "mgtf"m kflcln

    kfclsnfklf yagm dmf snhymcgmr tmrmofkmf, jfl (mgtf) hlrdlzgn

    snstlhkldn elr jlzljlfnf mk, inr lglhlftl vlrngkn. A kflhkl ingnflf

    lglhlftglrnf imzgmrff "snhym" slhiagglrn ygl2

    Mtah durmhygm tmfkhz Baef Kmgtaf, lglhlftglrnfsnhjlglfhlsn dafusufkm, lhilrglrklf agumfslhiagglrnf duggmfghmsf flrkn. Iu yftlhl jrl, imzlglhlftglrnf snhjlglrn yglykn2

    Lf safufkm, =5=3 ygfkm, Baf Bmdai Ilrzlgnus nsnhgn

    mrmtrhmc, lglhlftglrnf mkgmr tlhlg mgfmrmdsnhjlglfhlsn ondrnfn artmym mtt. Eg duggmfghmdtm agmf iuyftlhl jrl2

    =. Elr lglhlft, = ym km 9 emrotlf agumf inr snhjlygl nomkllkngnyar vl iu snhjlfnf ngd emron elr zmhmf iyd ymzgyar.

    9. Snhjlglrkl sdgdgm, lglhlftnf fjngnzcl mkff ngd emronduggmfgyar.rflnf2 E (Enkrablf2 Eykrajlf), C (Dmriaf2 Cmriaf),

    F (Mzat2 Fntrajlf)

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    3. Llr lglhlftnf im emronygl snhjlglflf imdm inrlglhlft vmrsm, iu lglhlftnf snhjlsnfkl im emronf ymffm,fjngnzcl mkff ndnfcn emron kl ldglfnyar.rflnf2 El (Elgyuh, Elgnuh), Cm (Dmgsnyuh2 Cmgcnuh),

    Fl (Flaf2 Flaf)

    ;. Llr lglhlftnf fjngnzcl mkff ngd 9 emron, inr knlrlglhlftgl myfysm, snhjlsnfkl im emronf ymffm, iu dlzim emrotlf safrmdn ngd artmd aghmymf slssnz emro jltnrngnyar.rflnf2 Cg (Dgar2 Cegarnfl) vl Cr (Drah2 Cerahnuh)

    ?) Pnlrrl mfk Hmrnl Curnllnfstlnfnuh (Ls, >>) Mgilrt Lnfstlnfolrhnuh (Oh, =00) Lfrnca Olrhnjmggnuh (Jm, 3=) Jmggnm)emefnuh (=0) Gnsl Hlntflrhlfklglvnuh (Hk, =0=) Khntrn Hlfklgllvfailgnuh (Fa, =09) Mgorlk Failgralftjlfnuh (Yj, ===) Zngelgh Yalftjlf

    (\fufuhnuh)rutelroarknuh (Yo, =0;) Lrflst Yutelroarkslmiarjnuh (Sj, =0?) Jglff [.

    Plrnyaknd [migaMgdmgn Hltmgglr[aprmd Mgdmgn Hltmgglr

    Jln Hltmgglrn

    Emgablfglr

    Msmg Jmzgmr

    Gmftmfntglr mfk Mdtnfntglr

    Mfm Jrup

    Mfm Jrup

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Iufuf kfkm plrnyaknd tmigakm ylr mgmf lglhlftglrnf uzlggndglrn kl vmrkr 4

    Mtahnd vl nyafnd mp

    yafgmhm lflrbnsn

    Lgldtraf ngjnsn

    Lgldtrafljmtnognd

    Mtahnd vl nyafnd mp

    Inrinrnfl imgmfh ndn mtahuf ldnrkldglrn mrmsfkmdnartmgmhm uzmdgf gghlsnygl mtah vlym nyaf ymrmpgmr

    iugufmingnr.Inr drnstmg nnfkl dahu ndn nyafuf hlrdlzglrn mrmsfkmdnuzmdgd, U-fgmr drfh (knormdsnyafu UYK) ngl tmynflknglingnr. Drnstmgglrnf aufkm iu uzmdgd, inr dmtyafufymrmp ngl inr mfyafuf ymrmpff tapgmhfm lnttnr.

    rfld

    O9 hagldgglrnfkldn O-O im uzufguu =;; ph knr. Iu kllrnfymrs ogar mtahufuf ymrmp agmrmd dmiug lkngnr (=;;/98 :9ph).

    dn nyat mrmsfkmdn uzmdgd ;39/98 9=? ph

    Llr Gn nyafufuf hlrdlznygl inr nyatmfyafufuf hlrdlzn mrmsfkmdn uzmdgd

    tmynf lkngnrsl Gn+ vl N- mrmsfkmdn uzmdgdtmf

    Gn+ nyafufu ymrmp elsmpgmfmingnr.

    95; ph8 Gn+

    ymr

    mp

    + N-

    ymr

    mp

    95; ph 8 Gn+ ymrmp + 9=?

    Gn+ ymrmp 8 ?5 ph

    Dmtyafnd mp

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Mfyafnd mp

    Flklf 1

    Mtah mp plrnyaknd tmigakm ymtmy agmrmd nglrglkndl (mtahfuhmrms mrttdm) dgr.

    fd ymtmy agmrmd nglrglkndl mtahuf k dmiuufm inrlgldtraf vl ldnrkll kl inr prataf ngmvl lkngnr. Mfcmddmium ngmvl lknglf inr lgldtrafuf mtahuf emchnfnjlfnglthl jc, ldnrkll dmtgmf inr pratafuf mtahufemchnfn dgthl jcfl lnt klngknr, kmem ddtr.Pratafuf mtah emchnfn izhl jc jmgnp jlgknnfklf mtah

    mp ymtmy agmrmd nglrglkndl dgr.

    Flklf 1

    Mtahnd mpgmr jrupgmrkm mm karu nfkndl iyr.

    fd elr jruptm lgldtraf inr st dmium jnrlr vl ngmvllknglf pratafgmrf mtah mpf dgthl ltdnsn, st dmiumjnrhn iugufmf lgldtrafgmrf mp iygthl ltdnsnfnfymffkm dd dmgr.

    Itf iufgmrf ymffkm lgldtraf dmyilttnn zmhmf agumfnyaf mpff kmem dd, lgldtraf dmzmfk zmhmf agumfnyaf mpff km kmem iyd agmcm mdtr.

    yafgmhm Lflrbnsn

    Kmnhm kmrkmf s mgmf (lfkatlrhnd) inr dnhymsmg agmykr.Inr mtahkmf inr lgldtrafu uzmdgmtrhmd nnf vlrnghlsnjlrldlf hnfnhuh lflrbnyl nyafgmhm lflrbnsn klfnr.

    Inr lgldtrafu dmrhmd nnf jlrldgn lflrbn inrnfcn nyafgmhmlflrbnsn, ndnfcnyn dmrhmd nnf jlrldgn lflrbn ndnfcn nyafgmhmlflrbnsnknr.

    [minndn inrnfcn nyafgmhmkmf safrm + ydg inr nyaf aguur vlmrtd iu + ydg nyafkmf inr lgldtraf dmrhmd kmem iydlflrbn jlrldtnrnr.

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Hj =s9 9s9 9p? 3s9

    Hj Hj+ + l- E8+:35 dB/hag

    Hj+ Hj9+ + l- E8+=;

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    Elpsn kl, tlpdnhlglrkl ltdnfknr.

    Lf ydsld tlhlg lflrbn kzlyglrnfkl inr tld lgldtraf tmrgmr.

    Iu lgldtrafu ad dagmy dmyilklrld += ydg nyafgmraguturmingkndglrn nnf, duvvltgn nfknrjlfknrglr.

    Ns vl lgldtrnn ad nyn ngltnrglr.

    Suygm ltdnglnhglrn ad jgkr, suygm tlpdnhl safucufkmenkrablf jmz mm dmrrgmr.

    Mgdmgn hltmgglr ucuzkur vl rlmdsnyaf dmrhfkmf kmhthmyaguygm smo emgkl lgkl lknglingnrglr.

    Pmrgmd drhz smr har hmvnhsn drhz hmvn

    Mgdmgn Hltmg Ylmdsnyafgmr

    Enkrablf 9 H (d) + E9 (j) 9 HE (d)Adsnblf Gn (d) + A9 (j) GnA9 (d)

    9 Fm (d) + A9 (j) Fm9A9 (d)H (d) + A9 (j) HA9 (d) H 2 D, Yi, Cs

    Mzat ? Gn(d) + F9 (j) 9 Gn3F (d)Emgablf 9 H (d) + U9 (j) 9 HU (d)

    Su 9 H (d) + 9 E9A (s) 9 HAE (mq) + E9 (j)

    Enkrablf (E)

    ecp 2 elxmjafmg cgasl pmcdlk

    Enkrablf ngd agmrmd =::? ygfkm Elfry Cmvlfknsetmrmofkmf dlolknghntnr.

    Enkrablf nshn nsl Mftanfl Gmvansnlr tmrmofkmf vlrnghntnr.

    Enkrablf rlfdsnz vl dadusuz inr jmzkr.

    ^mfc zlggnl smenp agkuu nnf zlg mrtgmrkm huemomzmlkngnr.

    Enkrablf au inglndglrnfkl += ,hltmgenkrr inglndglrnfkl nsl -= ydslgtjlfhl imsmhmfmsmenptnr.

    zatapgmr

    ==E Enkrablf =

    9E Ktlryuh =3E [rntyuh

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Eacm - Inrnsn imfm plfclrlfnf kfkmdn iu dmkmr

    ldncn lynf fl agkuufu syglylingnr hn 1

    Sakyuh (Fm)

    Icc 2 emcnh hlrdlzgn dind

    Sakyuh

    Sakyuh inglndglrn yzyggmrkmf ilrnnfsmfgmr tmrmofkmf duggmfghtr vlsakyuh, ilgdn kl, ingnflf hmkklglrnf lflsdnsnknr.

    irmfnglr, sakyuh dmriafmtf hndrapdrc zlggndglrnfn iugmrmd ymrmpmfsuhmfgmrfkm, mtl krhlklduggmfh vl inglnl, irmfncn dprlf

    mfgmhfm jlglf flglr mkf vlrhnglrkn.

    Lczmcgd, tmrh vl oatarmogd mgmfgmrfkm cmh ymphfkmvl saorm tuzu (FmCg) lgklsnfkl

    sv sakyuh, fdgllr smftrmgglrkl sautucu jrlvnfkl kfym dmiuufuf %9.?'sf aguturmf sakyuh, kfymkm lf

    iag iugufmf mgtfc lglhlfttnr vl mgdmgn hltmgglr mrmsfkm kmlf iag iugufmfkr

    Iufm dmrf, kamkm lglhlft emgnfkl rmstgmfhmz vl durusakyuh dgarnknf (FmCg) lgldtragnzn yaguygm lgkl lkngnr.

    lntgn mgmhgmrf ympgmrff duvvltglfknrnghlsnfkl vlkdhl hltmgglrnf smogmtrghmsfkm duggmfgr.

    FmD mgmh, flhgn inr s ngltncnsnknr. Sakyuh lglhlftnfnf knlr flhgn inglndglrnysl dastnd

    FmAE sakm dg (Fm9CA3), dmimrthm tazu (FmECA3) vlsakyuh fntrmttr (FmFA3).

    _urkuh_urkuhInr lgldtraf dmyilttnh

    Lhnf hnsnf 1

    Pazntnonh mrtd.

    FmO

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Patmsyuh (D)

    Icc 2 emcnh hlrdlzgn dind

    Patmsyuh (D)

    Patmsyuh Intdnglrnf jlgnnhn nnf ad flhgn inr lglhlft

    agmf patmsyuh, au taprmd tnpnfnfinglnhnfkl ylr mgr vl jirlglrnf ympsfm kmdmtgr.

    Slrmhnd, cmh, smiuf, glfs vl ilfzlrnhmkklglrnf ymphfkm,

    Sakyuh vl patmsyuh mgmh (FmD), nyn inrs ngltncnknr.

    Patmsyuhuf au tuzu, elh dnhymsmg elhkl tncmrn mkmf flh tmr2 rflnf,patmsyuh enkradsnt, patmsyuh fntrmt,patmsyuh dmriafmt, patmsyuh sgomt, vs.

    Klfly 2 Patmsyuhuf sukmdn kmvrmf Yuinkyuh (Yu)

    Icc 2 emcnh hlrdlzgn dind

    Yuinkyuh

    Yuinkyuhu ngd agmrmd =5?= kl Yailrt Iufslf vl JustmvDnrceeaoo spldtrasdapn yftlhn ngl iugkugmr vl tmyofkmdn ndnilgnrjnf drhz nzjn flklfn ngl ymdut mfgmhfkm ruinkyuhagmrmd mkgmfkrkgmr.

    ad dagmy nyafgmhms flklfnygl, slzyuhm mgtlrfmtno agmrmd,uzmy mrmgmrfkmdn "nyaf hatargmrfkm" duggmfghmdtmkr.

    _mduh tpglrnfnf vl oataslgglrnf kl ympsfm dmtgmf flhgninr ingllfknr.

    zlg cmhgmrf ymphfkm vl dmgp mrmtrhmgmrfkm kmduggmfgr. Myrcm dmtmgnzr agmrmd duggmfh km vmrkr.

    Slzyuh (Cs)

    Icc 2 emcnh hlrdlzgn dind

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Slzyuh (Cs)

    Slzyuh Iu hltmgnf ngd dlon Yailrt Iufzlf vl Justmv Dnrceeaoo

    tmrmo

    fkmf =5?0 y

    g

    fkm hnflrmg sukm dlolkngkn. Slzyuhuf smo agmrmd lgklsn ingnflf srmkmf sakyuh lgklsn

    jnin klngknr. Mtah smmtglrnfkl, dzgtlsn gmhimgmrfkm vl dmtmgnzr

    agmrmd, ilgnrgn lglhlftglrnf enkrablfglfhlsnfkl duggmfgr. ^mdf zmhmfkm, ntncn j snstlhglrnfkl kl duggmfghmym

    imgmfhtr. _mduh tpglrnfkl, emvm dmgftgmrf yad lthld nnf

    duggmfgr. Adsnblfl dmr lngnhn ydsldtnr vl dagmy nyafnzl agur. Iu flklfgl kl, radlt hatargmrfkm ntncn agmrmd duggmfgr.

    Ormfsnyuh (Or)

    Ormfsnyuh ngd agmrmd =>3> ygfkm Hmrjulrntl Plrlytmrmofkmf dlolknghntnr.

    Ormfsnyuh \rmfyuh vl taryuh hnflrmgnfnf nlrnsnfkliugufur. Omdmt smo lglhlft agmrmd nzagmsyafu hhdfklngknr.

    Ormfsnyuh, mdtnfyuhuf pmrmgmfhms safucufkm vlymtaryuh prataf iahimrkhmf safucufkm lgkl lkngnr.

    Ormfsnyuh hltmgnfnf duggmfh mgmfgmr ingnfhlhldtlknr. Ormfsnyuh hltmgn emddfkm dlsnf inr ingjn iugufhmhmdtmkr.

    Hltmg yzlyn emvmkmdn flhklf kagmy hmtgmhmdtmkr.Emvkm ymfhms ngl ormfsnyuh adsnkn aguturur. Or(d) + A9(j) OrA9(d)

    9M Jruiu [aprmd MgdmgnHltmgglr

    [aprmd Mgdmgn Hltmgglrzlggndglrn

    Plrnyaknd tmigafuf imtmf ndnfcn jruiufkm (kndly srmsfkm)

    ylr mgmf lglhlftglrknr. Sdgdgm ilymz rlfdgn agup, yuhumdvl nglflingnr ympkmkrgmr.

    Mgdmgn hltmgglrklf kmem mz tlpdlf (tlpdnhlyl jnrhlyllngnhgn) dmrmdtlrkl aghmgmrff ymffkm, lrnhl vl dmyfmhmscmdgdgmr kmem ydsldtnr. yafgmhm lflrbnglrn kl mgdmgnhltmgglrklf kmem ydsldtnr.

    [aprmd lglhlftglrn nshn, iu jruptmdn lglhlftglrnf taprmdtmiugufmf adsntglrnfnf, lsdn dnhymingnhcnglr tmrmofkmf myrinrlr lglhlft agmrmd kfghlsnfklf jlgnr.

    ^ad yad partmdmg drhz dzg ylng

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Ilrngyuh (Il)

    Mdumhmrnf

    RhrtEcp 2 elxmjafmg cgasl pmcdlk

    Ilrngyuh ^dsld armfkm s lhlinghl zlggnn flklfnygl, emvm vl

    uzmy tmtgmrfkm, ngltnnh uykugmrfkm, fdgllr smftrmgglrklvl ozl ymphfkm, emono hltmg mgmhgmrfkm, U-f tpglrnfnf plfclrlglrnfkl ^dsld inr lrnhl fadtmsfm smenp aghms, emonognn vl

    lgndtlf ad kmem lsfld inr hltmg aghms flklfnygl,ingjnsmymr pmrmgmrfkm,

    bnrasdapgmrkm vl nfmmt sldtrfkl imdr mgmh km, dmyfmd ymphfkm, lgldtrnd

    imgmftgmrfkm vl lgldtratgmrkm duggmfgr. Rhrt vl mdumhmrnf, ilrngyuhuf kllrgn drnstmg oarhgmrkr.

    Hmjflzyuh (Hj)

    Ecp 2 elxmjafmg cgasl pmcdlk

    Hltmgnd hmjflzyuh =>. yzygf imgmrfm dmkmr lgkllknglhlhntnr.Iufm dmrgd, hmjflzyuh, inglndglrnfnfimzgmr, ad kmem fcl ingnfnyarku.

    =505 kl fjngnz dnhymcs Euhpery Kmvy duru hmjflzyuhdgarrgl hltmg patmsyuhu ztglhlyn immrk.

    =53= kl yltlrgn hndtmrkm hmjflzyuh lgkl lknglingkn. Hmjflzyuh, fnspltlf tlpdnf inr hltmgknr. Iu yzklf,

    kamkm slrilst agmrmd iugufhmz. [aprmdtm lf iag iugufmflglhlftglr mrmsfkm sldnznfcn srmy mgr.

    Imgcm ndn hnflrmg emgnfkl iugufur2hmjflznt (HjCA3) vlkagahnt THjCm(CA3)9X.

    Oatarmo hmdnflglrnfnf jvkl vl ogm

    dmpgmhmgmrfkm, nmrlt onldglrnfkl vl ymfjfiahimgmrfkm

    mghnfyuhkmf tl inr armffkm kmem emonoaghms flklfnygl, mgmhgmrfkmf umd vl ozlymphfkm

    lczmcgd mgmffkm flh tmymf inglndglrn klvmrkr.

    kdh klhnr ymphfkm vl urmfyuh imtmaghmd zlrl lntgn hltmgglrnf tuzgmrfkmfsmogmtrghms nglhnfkl

    hnfl tugmgmrff, mykfgmthm mhpugglrnfnf,rlfd hmkklglrnfnf vl ongtrlglrnf ymphfkm

    Dmgsnyuh (Cm)

    ccp (cuinc cgasl-pmcdlk)

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

    18/49

    gd agmrmd =505 ygfkm Ilrzlgnus vl Paftnf, cnvm nlrnsnfkldnCmAnf (gnhl) lgldtragnzn ngl dmgsnyuh mhmgjmh (cnvmg

    hmklf mgmh) lgkl lthn. Kmem safrm Euhpery Kmvytmrmofkmf ngd klom smo agmrmd nzagl lknghntnr.

    Dmgsnyuh kamkm smo agmrmd iugufhmz. Lf omzgm dnrltmfkm (CmCA3) iugufur.

    Hlrhlr vl dmgsnt tl myf oarhgl smenptnr. Lf flhgnhnflrmgglrn kagahnt (CmCA3 HjCA3), mpmtnt (3Cm3(PA;)9),jnis (CmSA;.9E9A) knr.

    _cut smg nnf lf jlrldgn lglhlfttnr. Dlhndglrnf vlknglrnf jlgnnp duvvltglfhlsnfn smgmr. Omdmt vcuttmdmgsnyuh omzgmg iirld tmfm slilp agur.

    [aryuh, urmfyuh vl znrdafyuh jnin hltmgglrnfemzrgmfhmsfkm vl lntgn mgmhgmrf lgklsnfkl

    sv ymgmrf klenkrmsyafufkm cmfggmrf dlhnd, kn, dmiud vl ilfzlrn k nsdlglt

    ympgmrfkm intdnglrnf ifylsnfkl kfym dmiuufkmdn lf iag ilnfcn lglhlft aghms dmrf,

    ad rlmdtno aghms flklfnygl msgm lglhlft emgnfkliugufhmz.

    dnrltm, bnps vl ogarntnf ympsfkm km vmrkr. CmCA3, CmA jnin inglndglrn flh ldncn agmrmd

    Strafsnyuh (Sr)

    ccp (cuinc cgasl-pmcdlk)

    Strafsnyuh Mkmnr Crmwoark ngd agmrmd =:>0 ygfkm straftnmfnt (SrCA3)

    hnflrmgnfn tmfhgmhtr. =505 ygfkm nsl Euhpery Kmvytmrmofkmf lgldtragnz yftlhn ngl nzagl lknghntnr.

    Ylfdgn tlglvnzyafgmr nnf jrft tpglrnfnf vl klhnr lsmsghdfmtsgmrf ymphfkm,

    nfdafuf smogmtrghmsfkm, nmrlt onldglrnfkl vl emvmn onldglrkl drhz rlfjnf lgkl

    lknghlsnfkl fdgllr pngglrkl vl oasoargu iaymgmrf ymphfkm Strafsnyuh tntmfmt, ydsld inr drghm nfknsnfl vl lghmstmf

    kmem jlfn inr aptnd kmghm smenp aghms flklfnygl, ngjnldncn inr aptnd hmkklknr.

    Imryuh (Im)

    icc (iaky-clftrlk cuinc)

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

    19/49

    Imryuh Imryuh ngd agmrmd =::; ygfkm Cmrg Scellgl tmrmofkmf

    tmfhgmfhtr. Ngd agmrmd =505 ygfkm Euhpery Kmvytmrmofkmf fjngtlrlkl ldstrmdtl lknghntnr.

    _mduh tpglrnfkl, iubnglrkl, emvmn onldglrkl vl ogarlsmfgmhimgmrkm

    imryuh sgomt vl nfda sgomt nlrlf inr pnjhlft agmf"Gntapaf",

    Imryuh sgomt, dmgc ilymz zlggnnygl iaymgmrf nlrnnfkl,U-f nfclglhlglrnfkl vl cmh ymphfkm

    imrnt, pltrag duyugmrf mhmdtm duggmfgmf svgmrfnlrnnfkl mrgd dmzmfkrc ufsur agmrmd, dmuudymphfkm,

    imryuh dmriafmt omrl zlenrn agmrmd, imryuh fntrmt vl dgarmtkm pnratldfnkl (onldngnd) ylng rlfjnf lgklsnfkl duggmfgr.

    Ymkyuh (Ym)

    icc (iaky-clftrlk cuinc)

    Ymkyuh Ymkyuh, =5>5 ygfkm Curnlglr tmrmofkmf plceiglfk

    (\3A5) mk vlrnglf urmfyuh hnflrmgn zlrnfkl ympgmfmrmtrhmgmr srmsfkm artmym dmrgk.

    Ymkyuh, urmfyuhuf rmkyamdtno agmrmd pmrmgmfhmssafufkm hlykmfm jlglf rfglrklfknr. Iu yzklf knhurmfyuh hnflrmgglrnygl inrgndtl, jlflggndgl jrmfntgn dmymgmrkmiugufur.

    Ymkaf jmz lgklsnfkl duggmfgr. Dlfkngnnfklf gkmymfiaymgmrf ympsfm dmtgr.

    zlggndgl dmfslr tlkmvnsnfkl, rmkyuh ylrnfl Ca-?0 jninkmem jvlfgn ym km kmem jg rmkyanzatapgmrfduggmfghms yagufm jnknghldtlknr.

    Ftraf dmyfm agmrmd km duggmfgr.

    3M Jruiu Lglhlftglrn

    Iar (I)

    reahiaelkrmg

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

    20/49

    Iar Lglhlftlr iar =505 ygfkm Ormfsz dnhymc Jmy-Gussmc ngl

    Imraf Gauns [elfmrk vl imhsz agmrmd fjngnz dnhymc SnrEuhpry Kmvy tmrmofkmf iugufhutur.

    Hltmggl mhltmg mrms ymr n gltdlf zlgg nl smenp inr lglhlfttnr.

    Iar tminmttm eninr zmhmf slrilst emgkl iugufhmz. Kamkm ymdgmd 930 lnt iar hnflrmgn agkuu

    ingnfhldtlknr. Mharo iar, myrt lkncn ylng rlfjn nnf pnratldfn (onldngnd)

    mgmffkm vl mtlglyncn agmrmd radltglrkl duggmfgr. [lfns rmdltglrnfnf, fdgllr smftrmgglrkl duggmfgmf

    rljgmtrglrnf vl sym kmymfdg cmh rfglrnfnf ymphfkmkm flh tmr.

    Iaruf lf flhgn tncmrn inglnn, ymgth mhmg cmh lgymoffvl inr mmrtc agmf sakyuh plriarmtf ymphfkmduggmfghmdtmkr.

    Knlr iar inglndglrn kl, iarasngndmt cmhgmrf ymphfkmduggmfgr.

    Iaraf-=0 nzatapu, fdgllr smftrmgglrkl artmhkmdn ftrafgmrezgm lhlrld tlpdnhlglrn ymvmgmthmd ym km kurkurhmdnnf, fdgllr rmkymsyafm dmr dmgdmf agmrmd vl ftrafilgnrglyncn mgltglrkl duggmfgr.

    [ldstng mgmffkm flh tmymf inr knlr iar inglnnysl,iarnd msnttnr.

    [ntmfyuh vl tufjstlf ngl inrgndtl duggmfh safucufkm,mrg kd mfcmd sym dmr knrlfgn mgmhgmr lgkl lkngnr.

    ^mdf zmhmfkm mrtrnt (ldglh ngtnemi) tlkmvnsnfklduggmfghmym imgmfmf iar inglndglrn kl uhut vmmt lknyar.

    Jz klzlfoldtmfgmrff inglnhnfkl kl iar iugufuyar.

    Iar, zlggndgl slrmhndglrnf srgmfhmsfkm vl lhmylsmfmynnfkl duggmfgr. Iu sldtr [rdnylfnf lf ad iartdlttnn mgmfgmrkmf inrnfn aguturhmdtmkr. ^mrmrgmfgmfimgcm iar zlggndglrn mmkmdn jninknr2

    Srf dvmhggf krr.

    Srf yzly jlrngnhnfn krr.

    Pmrgmdg vl smykmhg mrttrr. Lgldtrnl dm ymgtdmf kmvrmfrdlf, inr hltmgnfdnfl ilfzlr sjlnrjlfgnn jstlrlf iaraf fntrnt inglnn, myf zmhmfkm,dmrtrgk elremfjn inr hmkklyn lghms slrtgnnfl jltnrncnzlggndtlknr.

    Iar enkrrglr lftlrlsmf inglndglrknr, ad rlmdtnoglrknr.Dlfkngnnfklf ymfmrgmr. Su ngl iarnd msnt vl enkrablf vlrnrglr.

    IE3 yadtur, I9E? , I;E=0 , I , I

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

    21/49

    Mghnfyuh (Mg)

    ccp (cuinc cgasl-pmcdlk)

    Mghnfyuh =59: ygfkm Zaeglr tmrmo fkmf iugufhutur.

    Mghnfyuh emono inr hltmgknr. [adsnd lngknr. Kamkmslrilst emgkl iugufhmz.

    lntgn hutomd mgltglrnfnf vl kldarmsyaf hmgzlhlglrnfnfmfm ymph hmkklsnknr.

    Imdr, hmjflzyuh vl knlr hltmgglrgl aguturkuumgmhgmr, smo emgnfklf ad kmem jg zlggndglrlsmenptnr.

    mgmhgmr emono mfcmd jg hltmgglrnf jlrld kuyugkuu,imtm ozl vl umd ymph aghmd zlrl, elr trg

    mgmfkm duggmfgr. Lgldtrnd ngltdlfgnn imdrf ymgfzcm %?0' dmkmr agsm km,

    emono ymps flklfnygl lgldtrnd ngltnh emtgmrfkm duggmfgr.

    Mghnfyuh taz emgkl Ol (NNN) adsntnlglhlftlg klhnrlnfknrjlylrld iyd hndtmrkm s mm dmrtr vl iu lsfmkmnfknrjlfhn klhnr lrnr. Iu rlmdsnyafm [lrhnt rlmdsnyafuklfnr.

    9 Mg(d) + Ol9A3 (d) 9 Ol(d) + Mg9A3 (d)E08-5

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

    22/49

    Jmgyuh (Jm)

    arteareahinc

    Jmgyuh hltmgn ngd agmrmd =5:< ygfkm Glcaq kl Iansimukrmftmrmofkmf dlolknghntnr.

    Jmgyuh mghnfyuhuf lgklsn srmsfkm ymf rf agmrmd lgkllkngnr. Iadsnt hnflrmgnfnf smogmtrghms ngl mghnfyuh nglilrmilr lgkl lkngnr. Kmem safrm lgldtragnz ngl smo agmrmd lgkllkngnr.

    Cmh vl parslglfglrl sgmd inr jrfh vlrhldtl duggmfgr. Cmh zlrnfl srgkfkl, agkudm pmrgmd inr myfm

    aguturur. ^mr ngltdlfglrnf vl trmfsnstr ilfzlrn myjtgmrf rltnhnfkl

    ymyjf agmrmd duggmfgr. Myrcm, dumrtz tlrhahltrlglrnf vl gmzlr knyatgmrff

    ymphfkm vl thr tlspntnfkl kl duggmfgr. Jmgyuh mrslfnt, lgldtrnn karukmf m lvnrlinghl

    zlggnnfl smenptnr.

    fknyuh (Nf)

    tltrmjafmg

    fknyuh Kd scmdgdgmrkm lrnylinglf mgmhgmrf ymphfkm

    duggmfgr. rflnf, %:? armffkm jmgyuh, %9; armffkm km nfknyuh

    nlrlf mgmh, akm scmdgfkm svkr. Jlrhmfyuh trmfsnstrglrnf, kmhtcgmrf, tlrhnstrglrnf vl

    oatangltncnglrnf ymphfkm duggmfgr. Hltmgglrnf vl cmhf zlrn nfknyuhgm dmpgmfkfkm,

    mthasolrnd mfhmym dmr jhgl ympgmfgmrkmf kmemkmymfdg agmf myfmgmr lgkl lkngnr.

    [mgyuh ([g)

    ecp (elxmjafmg cgasl-pmcdlk)

    [mgyuh hltmgn ngd agmrmd =5?= ygfkm Snr Znggnmh Craadls

    tmrmofkmf dlolknghntnr. [mgyuh hltmgn vl inglndglrn ad tadsnd hmkklglrknr. Iu

    flklfgl duggmfh lsfmsfkm ad knddmtgn agufhmgkr.Imdgm dlsnglinglcld dmkmr yuhumd hltmgknr.

    [mgyuh hltmgn ddrtg hnflrmgglrnf ympsfkm iugufur. Lfad pnrnt hnflrmgnfkl iugufur.

    Ddrt, slglfyuh ym km mrslfnd ngl aguturkuu inglndglr,=9

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

    23/49

    ;M Jruiu Lglhlftglrn Dmriaf (C)

    ecp (elxmjafmg cgasl-pmcdlk)

    Dmriaf Dmriaf, cmfggmr nnf lf emymtn lglhlfttnr. fd itf

    cmfg hmkklglr dmriaf inglndglrnfklf aguhugmrkr. Ecrl zmrfkmf mm dmiuufm, jz hlrclnfklf inr

    jlynnf iayfuzgmrfm, yuhurtm ilymzfkmf ygmf zlenrnfldmkmr saf klrlcl omrdg arjmfnd ympgmrf elpsn, dmriaftlhlggn inglndglrklf aguur.

    [h arjmfnd inglndglrnf ympsfm jnrlf dmriaf, svymgmrf klenkrmsyafufkm (sukmf mrfkrghmsfkm), myrcmklhnr vl mgmhgmrff nglfhlsnfkl duggmfgr.

    lgnd ymphfkm, fdgllr tlpdnhlglrnf daftragfkl,

    gmstndglrnf rlfdglfknrnghlsnfkl, pgmstnd smfmynfkl, iaympnjhlftglrnfnf lgklsnfkl vl ymgmyc hmkklglrnfymphfkm km iu lglhlfttlf ymrmrgmfgr.

    Duruf dmglhglrkl duggmfgmf jrmont oarhu vl lghms oarhu,dmriaf lglhlftnfnf ndn flhgn mggatrapukur.

    Dmriaf-=; nzatapu km, rmkyamdtno ym tmynfnfkl duggmfgr. Dmriafuf "ougglrlf" klflf drl innhgn ym km "fmfatp"

    klflf sngnfknr innhgn hagldgglrn kl, saf yggmrkm zlggndgllgldtrafnd vl fmfatldfagabn mgmfgmrfkm klvrnhslgnglrglhlglr smgmhmdtmkr.

    Dmriafuf ; tmfl mggatrapu vmrkr.

    Iufgmr mharo, jrmont, lghms vl ougglrlfknr

    Ougglrlf jlflggndgl ? dmriaf mtahufuf kzglhslg agmrmdinrinrn ngl imgmfmrmd aguturkuu nn ia drlslg, sngnfknrndvl emgdmsmg ympgmrkr.

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

    24/49

    Dmriaf fmfatpglr flhgn lgldtrafnd vl hldmfnd zlggndglrlsmenp fmfaympgmrkr. Fmfatpglr ngd agmrmd tld iayutgu

    dumftuh tlgglr nnf pratatnp agmrmd kfgkfklf adiyd inr ngjn ldtn. Knlr duggmfg zlggndglrnfdlolknghlsnygl 4 zlggndgl kmymfdgg, patmfsnylg duggmfhmgmfgmrf amgtt. rflnf, dmriaf fmfatpglr fmfahltrndiayutgmrkmdn lgldtrafnd klvrlglrkl ym km duvvltglfknrnghnpagnhlr hmgzlhlglrkl duggmfgmingnr.

    Sngnsyuh (Sn)

    knmhafk

    Sngnsyuh Sngndaf Sngnsyuhuf ngd dlon =59; ygfkm Ilrzlgnus tmrmofkmf

    jlrldglstnrnghntnr. Sngnsyuh kajmkm sngndmt msnkn (hSnA9.fE9A) vl tuzgmrn

    emgnfkl iugufur. ^lrdmiujufuf ymdgmsnd %9

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

    25/49

    Mr smo sngnsyuh, iar, jmgyuh, oasoar ym km mrslfnd ngljglfknrngknnfkl4 trmfsnstrglr, jfl jzlglrn vlkarugtucugmr jnin, lgldtrafnd lfkstrnsnfkl iyd flh

    tmymf myjtgmrf ymphfkm duggmfgmf sngndaf dmrhgmrlgkl lkngnr. Lgldtrafnd hndranpglrnf ymphfkm ymrngltdlf agmrmd

    duggmfgr. Knmtahgmr vl rmkyagmrymgmr jnin ahurjmszgmrf k

    nsdlgltglrnfnf ympsfm dmtghms flklfnygl kl, ymmhsmgflh tmhmdtmkr.

    Iu k nsdlgltglr, kmem safrm knil dlrld, lntgn dmymgmrfympsfm dmtgr.

    Intdnglrnf vl nfsmf nsdlgltnfnf ympsfkm km sngnsyuh iugufur.Sngndaf dmrink (SnC), ingnflf lf slrt hmkklglrklf inrnknr.

    Sngnsyuh enkrrglr Sngmf mkf mgrgmr. Lf imsnt hafasngmfSnE; kr. Enkradmriaf inglndglrnfl ilfzlrglr.

    SnA9 fnf haknondmsyafgmr mrmsfkmdn imft mmkmdnldngkl jstlrngnr

    5:00C =;:00C =:0

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

    26/49

    Dmgmy Kamkm lf omzgm dmgmy tm agmrmd ingnflf SfA9 ongnzn

    (dmssntlrnt) emgnfkl iugufur. Knlr inr ongnz kl Cu9OlSfS; stmffntknr. Smo aghmymf dmgmy ilrmilrnfkl iugufmf klhnr, duruf jnin

    ymimfc hmkklglrklf tldrmr lrntnglrld myrgr. Lrnhlfadtmsff inrmz yudmrsfkm stgkfkm ydsld scmdgdtmlrnylfglr dmgmykmf myrgmrmd dpd aguturur.

    (jrn dmgmy), (ilymz dmgmy) vl ngl jstlrnglf 3haknondmsyafu vmrkr.

    Dmgmy emvmkm farhmg mrtgmr mgtfkm dmrmgkr. Omdmtstghms ngl dmgmyknadsnt aguturur.

    Sf(d) + A9(j) SfA9(d)

    SfA SfA9

    Hltmgnd dmgmy flhgn emvm, zmyo msnt vl imzgmrm kmymfdgaghms flklfnygl dmp ymphfkm duggmfgr.

    Lf flhgn mgmhgmr irafz (Cu-Sf) vl glenhknr (Pi-Sf).

    Sf + A9 SfA9 E8-=35.5 dcmg

    lgnd dafslrvl dutugmrff dmpgmhm hmkklsnknr.

    Myrcm glenh, irafz, dmgmy vl duruf mgmhgmrfkm ylr mgr.

    Imz kn hmcufgmrff nlrnnfkl, dmgmy vl ogar inglnn agmfSfO< duggmfgr.

    Splrngltdlf hdfmtsgmrf ymphfkm km duggmfgr. Smolglhlft emgnfnf duggmfh ad sfrgkr.

    Duruf (Pi)

    ccp (cuinc cgasl-pmcdlk)

    Duruf Kamkm jlflggndgl inglndglr emgnfkl, imzlfkl lglhlftlg

    emgkl iugufur. Lf flhgn ongnzn PiS jmglfknr. PiCA3 Slrznt PiSA; mfjglznt Sls tntrlnhglrnfn lhncn zlggnn ad jg agmf iu lglhlft,

    sls ymgthfkm duggmfgr. U-f ldnphmfgmrfkm vl fdgllr smftrmgglrkl rmkymsyaf

    dmgdmf agmrmd nglv jrr. Imz zlggnn jstlrlf inr dmriafmt inglnn agmf ilymz

    duruf vl ilfzlrn knlr duruf inglndglrn, iaymgmrfympsfm dmtgr.

    Mfcmd, smgd msfkmf aguhsuz ltdnglrn flklfnygl iu

    duggmfh mzmgtghtr. Duruf adsnt, drghm nfknsn ydsld agmf drnstmg cmhgmrf

    rltnhnfkl duggmfgr. Icld gkrc ngmgmrf nlrnnfl dmtgmf duruf tuzgmr,

    lvrl vl nfsmf smgfm kmem mz aguhsuz ltdnsn agmfarjmfnd inglndglrgl ymvm ymvm ylr klntnrhldtlknr.

    9 PiS + 3 A9 9 PiA + 9 SA9 PiA + CA Pi + CA9 PiA (drhz) PiA (smr ) Pi3A; drhz mstmr iaym PiCrA; smr iaym

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

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    ?C) sv mzatsm, ad kd

    scmdgdgmrkm jlrldgltnrnghlsn jlrldlf kafkurhmnglhglrnfkl duggmfgr. [ncmrn agmrmd lf ad kllr tmymf mzat inglnn mhafymdtr

    (FE3). Jg inr zc agmf mhafymd, jirlglrnf inglnnfkl

    iugufmf vl pgmstnd lfkstrnsnfkl kl flhgn ylrn agmf "rl"hmkklsnfnf lgklsnfkl duggmfgr.

    FE

    3

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

  • 8/10/2019 Genel Kimya - Afyonkarahisar niversitesi Mhendislik Kimyas Ders Notlar

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    Mzat, pratlnfglr imtm aghmd zlrl, arjmfnd inglndglrnfympsfkm ylr mgmf ad flhgn inr lglhlfttnr.

    Gmiarmtuvmrkm FE;FA9 fnf stghmsygm lgkl lkngnrFE;FA9 F9 (j) + 9 E9A (j)

    Mzatuf th inglndglrn, ym adsntglyncn zlggndtlknrglr, ym kmjg inrlr rlmdtnotnrglr.

    Iu flklfgl kl, uyjuf dauggmrkm nkkltgn tlpdnhlglr vlrnrglr.Iufgmrf mrmsfkm [F[ (trnfntratagulf), vl mhafyuh fntrmtsmygmingnr.

    [F[ [rnfntra tagulf

    Oasoar (P)

    trncgnfnc

    Oasoar lntgn mgmhgmrf ymphfm dmtgmf oasoar, sakyuh

    mhpugglrnfnf ymphfkm duggmfgmf cmhgmrf lgklsnfklflhgnknr.

    Oasoarnd msnt, zlggndgl jirl lgklsnfkldn duggmfhygm, safyggmrkm tmrh vl emyvmfcgdtm iyd flh tmr emgljlghntnr.

    Emvmn onld, dnirnt, kltlrbmf vl kn hmcufu ymphfkmduggmfgmf oasoar, zmrmrggmrgm hcmklglkl duggmfgmf audnhymsmgf (plstnsntglrnf) inglnhnfkl kl iugufur.

    Cmfggmrkm ecrl nlrnnfnf ymmhsmg inr ingllfn agmrmd,zlggndgl snfnr vl dlhnd kadugmr nnf ad flhgnknr.

    [rnsakyuh oasomt nsl, sugmrf yuhumtghmsfkm, tlhnzgndtl

    vl pmsgmfhmym dmr duggmfgmf flhgn inr oasomt inglnnknr. Dlhndtl ymdgmd % ?3 armffkm Cm3(PA;)9 [CP iugufur. Lglhlftlg oasoar, dmgsnyuh oasomtf duh ilrmilrnfkl dad ngl

    nfknrjlfhlsnygl lgkl lkngnr.

    Cm3(PA;)9 + 3 SnA9 + < C CmSnA3 + < CA + P9

    Ilymz, drhz vl snyme oasoar mggatrapgmrkr. Ilymz oasoar ad zlenrgnknr. P; hagldg emgnfkl iugufur, dagmy tutuur. Snyme oasoar, drnstmg ympg, hltmgnd zlggnd jstlrnr.

    Enkradsn mpmtnt Cm

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    Mrslfnd (Ms)

    trnjafmg

    Mrslfnd

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    Inzhut =:

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    Pmsgmfhm km, adsnblfnf vmrgfkm jlrldglnr.

    Dnhymsmg rlmdsnyafgmrm jnrhl dmingnyltn enkrablfnfdn jnin artm

    klrlclknr. Msmg jmzgmr emrn th lglhlftglrgl inglnd ympmr.

    Ogarkmf safrm lf lgldtrafljmtno lglhlfttnr.

    Inglndglrnfkl -9 ydslgtjlfhl imsmhmfkm iugufur.Plradsntglrkl -= (Fm9A9), splradsntglrkl (DA9) vl ogargmympt inglndglrkl += vl +9 (A9O9 , AO9) kllrgndgnknr.

    Adsnblf duvvltgn inr ydslgtjlyncnknr.

    9 Cu(d) + A9 (j) 9 CuA(d)

    Adsnblf knlr lglhlftglrgl stgkfkm farhmg adsntglrnfnvlrnr.

    M) MhltmgglrglS5 (d) + 5 A9 (j) 5 SA9 (j)ddrt ddrtknadsnt

    P; (j) + < A9 (j) P;A=0 (d)oasoar oasoar-

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    Ddrt (S)

    arteareahinc

    Ddrt Sgor Ddrt kamkm ymyjf agmrmd iugufmf inr lglhlfttnr (ylr

    drlfnf % 0,0?'sf aguturur). Ddrt, mftndmkm ingnflf kaduz ymgf cnsnhklf inrnykn

    ddrkf dnhymsmg inr lglhlft agkuu =:::'klGmvansnlr'kmf artmym mtt. =5=0'm karu Jmy Gussmc ngl[elfmrk tmrmofkmf klflyslg agmrmd karugmfk. Ddrttmtsz, dadusuz inr dmtkr, s vl lgldtrnn nyn nglthlz.

    Ddrt tminmttl sgor vl sgomtgmr emgnfkl vl lglhlftlgemgkl iugufur.

    Snyme imrutuf vl pngglrnf tlhlg ingllfglrnfklf inrn agmfddrt, hmftmr gkrc dnhymsmggmrf (oufjusntglrnf) vlkamg dmuuuf ymphfkm duggmfgr.

    Oasomt nlrndgn jirlglrnf inglnhnfl kl dmtgmf ddrtf,tncmrn mkmf lf omzgm kllr tmymf inglnn sgornd msnttnr.

    Sgont dmk imtm aghmd zlrl lntgn dmtgmrf ymphfkm,iuemrgm klzlfoldtl nglhglrnfkl vl durutughu hlyvlglrnfmmrtghmsfkm duggmfgr.

    ^mgmrf, vcut svgmrff vl nsdlglt nnf jlrldgn hnflrmgglrnfympsfkm ylr mghms flklfnygl kl, ymmhsmg flh tmr.

    Yahind vl hafadgnfnd aghmd zlrl ndn mggatrapu vmrkr. Akm scmdgfkm dmrmrg agmf rahind, ad ymvm stgkfkm

    >?.< Ckl hafadgnfndldgnfl kfr. Inglndglrnfkl -9 , +; vl +? kllrgndglrnfkl iugufur.

    E9S SA9 SO?

    Klrnnd sgonrnd msnt m

    rg

    dm % >5gndtnr vl su ldncnzlggnnfl smenptnr. zlrnfl su kdgkfkl ad tlegndlgnmsnt srmhmgmrfm slilp agur. A flklfgl msntglrnf zlrnflsu kdghlz.

    Slglfyuh (Sl)

    hafacgnfnc

    Slglfyuh Slglfyuh ngd agmrmd =5=: ygfkm Bafs Bmcai Ilrzlgnus

    tmrmofkmf dlolknghntnr. Oatangltdlf zlggnn flklfnygl oatadapn hmdnflglrnfkl

    duggmfgr. Cmh lfkstrnsnfkl, zlggndgl ymdut rlfdgn cmh vl hnfl

    ymphfkm duggmfgr. Myrcm, oatarmond taflr, oatalgldtrnd ecrlglrkl, tlglvnzyaf

    dmhlrmgmr vl dglrglrnf ymphfkm jfl ecrlglrnfkl ymrngltdlf vl lgnd ymphfkm km dmtd

    hmkklsn agmrmd duggmfh vmrkr.

    [lggr ([l)

    trnjafmg

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Emgablfglrnf zlggndglrn

    Mt

    N

    Ir

    CgO

    Ylfd

    ^lng

    Partmdmg

    Jrn-snyme

    Emg

    Jmz

    Sv

    Dmt

    Smr

    Snyme Dmt

    JmzHAGLD

    HAGLDGLY

    IA^\[MY[MY

    GLY

    IA^\[MY[MY

    ^A^A\FG\D

    MY[MY

    \FG\D

    MY[MY

    YLMD[

    YLMD[OGOGD

    MRMGNY

    D

    MRMGNY

    Emgablfglrnf Duggmfh

    Ogar NyatIrahDgar

    Knhmcufu

    Su mrthm

    Mghnfyuhufldstrmdsnyafu

    ^mphmymfDmpgmhmgmr

    \rmfyuhzlfjnfgltnrhl

    Suklzlfodsnyafu

    Enkradgarnd msnt

    Pgmstndglr

    Mmrthmgmrkm

    Oatarmond ongh

    Jzymmrtcjmz

    Mglvjlcndtnrncnglr

    Omrhmdagabn

    Klzlfoldtmf

    Emgablfgmhimgmr

    U fgmrtlkmvnsn

    [uz dmtds

    [nrank tlkmvnsn

    Dmfslr nglhglrn

    Emgablfglrnf Ylmdsnyafgmr(=)

    [h emgablfglrMgdmgn hltmgglrgl nyafnd inglndglr aguturhmd zlrlrlmdsnyafm jnrlrglr.

    MGDMGN HL[MG + EMGABLF HL[MG EMGABLFY

    Sakyuh + Dgar Sakyuhdgarr

    9Fm + Cg9 9FmCg

    Mmkmdn rlmdsnyafgmrymzfz 4

    Gntyuh + Irah

    Patmsyuh + Nyat

    Gntyuh Irahr

    Patmsyuh yakr

    Emgablfglrnf Ylmdsnyafgmr(9)

    Emgablfglrnf elpsn jmz rlthld nnf enkrablfgl rlmdsnyafm jnrlr.

    EKYABLF + EMGABLF EKYABLF EMGABLFY

    Enkrablf + Dgar Enkrablf Dgarr

    E9 + Cg9 9 ECg

    Mmkmdn rlmdsnyafgmr tmhmhgmyfz 4

    Enkrablf + Irah

    Enkrablf + Nyat

    Enkrablf Irah

    Enkrablf Nyat

    Emgablfglrnf Ylmdsnyafgmr(3)

    [h emgablfglr suygm ndn msnknfn hlykmfm jltnrnrglr.

    S\ + EMGABLF MS[ = + MS[ 9

    Su + Dgar Enkradgarnd + Enkradgarz

    Msnt Msnt

    E9A + Cg9 ECg + EACg

    Iu rlmdsnyaf Irah vl yat nnfkl jllrgn agup, agumf msntglr agkudm

    duvvltgnknr. !!!

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Ogar (O)

    hafacgnfnc

    Ogar Ogar mkf, mdmf mfgmhfm jlglf Gmtnfcl ogulrl

    dlgnhlsnfklf mghtr. Akm scmdgfkm uud smr rlfdgn, dlsdnf dadugu ad tmern

    lkncn inr jmzkr. [minmttm, ogarnt (CmO9),

    drnyagnt ( Fm3MgO?) vlmpmtnt (Cm

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    Dgar [minmttm emgablfglrnf lf ad iugufmfkr.ngd klom =::;tl

    Scelggl tmrmo fkmf dgarr msnknfnf pnraguznt nglydslgtjlfhlsnygl lgkl lkngkn

    Kfymff elr ylrnfkl, nhl sugmrff klzlfoldtllknghlsnfkl duggmfgr.

    Myrcm, dmt ymf rfglrnfnf, iaym hmkklglrnfnf, tldstngrfglrnfnf, pltrag rfglrnfnf,

    lntgn ngmgmrf, mftnslptndglrnf, icld gkrcglrnf(nfsldtnsntglrnf),

    zcglrnf, pgmstnd rfglrnf vl ad lntgn tdltnhhmgzlhlglrnfnf lgklsnfkl duggmfgr.

    Dgaraogaradmriafgmr (COC), dgarmtgmr vl dgaraoarh jnin adlntgn inglndglrnf ympsfkm ylr mghms flklfnygl, dnhymlfkstrnsnfkl flhgn ylr tuthmdtmkr.

    Dnhym lfkstrnsnfkl lf ad tdltnglf 5. srmkmdn hmkklknr.

    =. Sgonrnd msnt 9. Mzat

    3. Mhafymd ;. Adsnblf

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    yat yat ngd dlz Imrfmrk Caurtans tmrmofkmf =5== ygfkm

    dlolkngkn. Irah kmmkm Fm, D, vl Hj irahrglr emgnfkl iugufkm

    iugufur. Klfzn suyufkm mz hndtmrkm iugufmf irahrglrlklfnz intdnglrnfkl, imz hmklf ymtmdgmrfkm rmstgmfr.

    yat inglndglrn, arjmfnd dnhym vl lczmcgd mgmfgmrfkm adflhgnknr.

    [ptm, nyakntglr vl nyaknf nlrlf tnradsnf kmengn agmrmd,tlftrknyat vl iu jnin nyat nlrndgn hndrap drcgmr km emrncnagmrmd duggmfgr.

    Inr zmhmfgmr mftninyatnd agmrmd duggmfgh, mfcmd, zlenrgnaghms flklfnygl iu duggmfhm saf vlrnghntnr.

    Smo nyat zlgtnsn kl, fnmstm nnf vlrknn dmrmdtlrnstnd dayuhmvn rlfdgl inr nfkndmtr (ilgnrglyncn) sv jrlvn jrr.

    yat flklf flhgnknr1

    yat, nfsmf vcukufkm ad mz hndtmrkm iugufmf farhmgiyhl vl jlgnhl nnf jlrldgn inr lslr lglhlfttnr.

    yat vcukm4 ilsnfglr, su vl klfnz rfglrn tdltnhn ngl mgfr. fsmf vcukufkm ilynf vl snfnr snstlhnfnf farhmg iyhl

    vl jlgnhlsn ngl vcut s vl lflrbnsnfnf klvmh nnf jlrldgnagmf tnrank earhafgmrfkmf tltrmnyakatnrafnf ([;, tnradsnf) vltrnnyakatnrafnf ([3) ymphfkm duggmfghmdtmkr.

    Farhmg mrtgmrkm vcukuhuzkm =

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    Myrcm, kd scmdgd mrmtrhmgmrfkm vl fdgllr lflrbnsmftrmgglrnfkl "sautucu" agmrmd km flhgnknr.

    [h lglhlftglr mrmsfkm, lf kd lrnhl vl dmyfmhmscmdgdgmr elgyuhm mnttnr.

    sv elgyuh, HY km duggmfgr.

    ^mdf zmhmfkm, sv radlt ymdt sdtrhmkm km elgyuhkmfomykmgmfghmym imgmfk.

    Flaf (Fl)

    ccp (cuinc cgasl-pmcdlk)

    Flaf gd klom =5>5 ygfkm,nfjngnz onzndadnhymc Snr Zng gnmh

    Ymhsmy tmrmofkmf, svgmtrgh emvmff ormdsnyafgukmhth ngl nzagl lknghntnr.

    Flaf,emvmff ad czn inr dshf(

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    Drnptaf

    =5>5 ygfkm Snr Znggnmh Ymhsmy vl Harrns Z. [rmvlrs

    tmrmofkm dlolknghntnr. Drnptaf mthasolrkl ad mz hndtmrkm iugufhmdtmkr.

    Drnptaf, sv emvmff ormdsnyafgu klstngmsyafu safucufkmsmo agmrmd lgkl lkngnr.

    Slrn oatarmogdtm duggmfgmf imz ogm gmhimgmrfkmiugufur.

    Ogarlsmf mhpugglrkl vl kmgjm iayu stmfkmrk agmrmdhartlsn (\_) gmzlrglrkl kl duggmfgr.

    Drnptaf-5< nzatapu, lntgn dmtgmrf ifylsnflylrgltnrnglrld, dnhymsmg mfmgnzglrkl duggmfgr.

    Dslfaf (Ul)

    ccp (cuinc cgasl-pmcdlk)

    Dslfaf =5>5 ygfkm Snr Znggnmh Ymhsmy vl Harrns Z. [rmvlrs

    tmrmofkm dlolknghntnr. Dslfaf mthasolrkl ad mz hndtmrkm iugufhmdtmkr.

    Dslfaf, sv emvmff ormdsnyafgu klstngmsyafu safucufkmsmo agmrmd lgkl lkngnr.

    Lgldtraf tpglrnfnf, straiasdapnd gmhimgmrf, imdtlrngkrc gmhimgmrf vl ymdut rlfdgn gmzlrglrn uymrmfgmhimgmrf ymphfkm duggmfgr.

    Hagldgglrn, pmrmcd onznn mgmffkm, ydsld hagldgmrgff flh tmk dafugmrkm, rflnf dmimrcd

    akmgmrff vl praigmrf nlrnnfkl duggmfgr. Dlfknsn zlenrgn aghmhmsfm dmrf, inglndglrn ad zlenrgnknr.

    Plrdsmfmtgmr, mfmgntnd dnhymkm adsntglyncn agmrmd duggmfgr

    Ymkaf (Yf)

    Ymkaf Ymkaf rlfdsnz, jzgl

    jrghlz, tmtsz, dadusuz vlrmkyamdtno inr jmzkr.

    =5>> ygfkm LrflstYutelroark vl =>00 ygfmOrnlkrnce Lrflst Karftmrmofkmf dlolknglf rmkafjmz mgom pmrmc ymyhmdtmagup hsmmkl lknglf

    hndtmrgmrf zlrnfklsagufkuufkm mdcnlr dmfslrnrnsdnfn mrttrhmdtmkr

    Ymkaf ynfl rmkyamdtno inr hmkkl agmf urmfyuhufiazufhms safucu aguur vl rmkaf dlfknsn mgom pmrmcymymrmd pgutafyuhm kfr.

    Imz emstmflglrkl rmkymsyaf tlkmvnglrnfkl

    imz dmfslr trglrnfl dmr uyjugmfhmdtmkr.

    Klprlh tmehnfglrnfkl kl rmkaf duggmfgr.

    Ymkyamdtno Ymkaf Jmzff ymr hr 3.5 jfkr.

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    ;

    Hlfklgllv ilfcl slfnf iu plrnyaknd tmiga inthlylcld jmgnim !

    K Jruiu lglhlftglrnJln Hltmgglrn

    K Jruiu lglhlftglrnJln Hltmgglrn

    Jln hltmgglrn plrnyaknd tmigafuf hlrdlznfkl iyd inrlglhlft igadukur.

    Iu lglhlftglr s vl p jruiu lglhlftglrn mrmsfkm dpraguturur.

    K arintmgglrnfn kagkurmrmd plrnyaknd tmigakm ylr mgrgmr. Elr slrnkl =0 lglhlft ylr mgr. gmvl lknglf elr lgldtraf 3k mgt dmiuufm ldglflrld klvmh

    lklr. K-jruiu lglhlftglrn agmrmd km mkgmfkrgrgmr.

    Jln hltmgglrn, lsms agmrmd slrtgndglrn, ydsld yaufgudgmr,nyn s ngltdlfgndglrn vl ydsld lrnhl-dmyfmhm scmdgdgmrygmtmffrgmr. zlggndgl slrtgndglrn flklfnygl, smo emgkl ym kmmgmh emgnfkl ymp hmgzlhlsn agmrmd duggmfgrgmr

    Jln hltmgglrn sdgdgm inrklf omzgm ydslgtjlfhlimsmhmfm smenptnr.

    au, msnt zlgtnglrnfkl enkrablfgl ylr klntnrlcld dmkmrlgldtrapazntnotnr.

    yafgmr rlfdgn agkuu nnf, mfmgnzglrkl dagmy myrt lkngnrglr.

    Jln lglhlftglrnfnf elpsn, lgldtraf knzngnhglrnfkl, lf ktmelr zmhmf k arintmgnfkl lgldtraf tmrgmr.

    [lpdnhlglrl jnrlf lgldtrafgmr km, k arintmgnfkldnlgldtrafgmrkr.

    LglLgldtdtrafnrafndd KKzlfglfhlzlfglfhl

    Lglhlft R 3k ;s

    ScSc 9=9= TTMrMrXX

    [n[n 9999 TTMrMrXX

    __ 9393 TTMrMrXX

    CrCr 9;9; TTMrMrXX

    HfHf 99> TTMrMrXX

    RfRf 3030 TTMrMrXX

    Jln slrnsnfkl ndn mgtjrup nlrnrglr. Gmftmfntglr vl Mdtnfntglr

    k-igad lglhlftglrnfklf imgcmgmr 4

    Lf ingnflf ymp hmgzlhlsn (Ol) gd hltmgglr (Mu, Mj, Pt) Hmklfn lymgmrkm duggmfgmfgmr (Cu, Fn) glrn tldfagabn hltmgglrn ([n) Ymkyamdtno lglhlft ([c)

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    ;

    Inrad k-igad lglhlftn emymt nnf flhgnknr 4 Ca I=9 vntmhnfnfnf inr dshf aguturur.

    (^mgmr

    f, pratlnfglrnf vl dmriafenkrmtgmr

    f hltmiagnzhms

    fkmduggmfgr) Ol elhajgainfkl iugufur.

    (Adsnblfnf ecrlglrl tmfhms vl imgmfhmsfkmfsaruhgukur)

    Ol, inyagabnd lgldtraf trmfsolrnfn dmpsmymf jrupgmr aguturhmdnnf S ngl inrglnr.

    Ha, Ol vl S , F9 vl FE3 f nfknrjlfhlsnfklf saruhgu inrjrup aguturhmd nnf inrglnr.

    Cu vl Rf inyagabnd rlmdsnyafgmrm dmtgr. Inrdm jln lglhlftn tadsndtnr (Ej jnin)

    k-igad lglhlftglrnfnf au rlfdgnknr vl pnjhlft agmrmdduggmfgr.

    Ol;TOl(CF)?X3 "Prussnmf igul knyl ingnfnr. Cr9A3 ylng

    [nA9 smo ilymz

    CkS smr

    au jln hltmgglrn nyafnd inglnd aguturhmd zlrladsnkmsyaf-rlkdsnyafm urmr.

    Iu rlmdsnyafgmrf inr au inyagabnd rlmdsnyafgmr nnfflhgnknr.

    Cr+3 Ol+9 Ca+9 Cu+9

    Hf+9 Ol+3 Fn+9Rf+9

    Inr jln hltmg inglnn, FnCN9 jnin, sukm zgkfkl, suhagldgglrn ltrmof smrmr.

    Fn9+ + 9 CN - 86 Fn9+(mq) + 9 Cg- (mq)

    Pagmr su hagldgglrnfnffljmtno ucu Fn9+ dmtyafufmdmtgr.

    Iu inglnd sukmdrnstmgglfknnfkl, ? su

    hagldg Fn9+ l img dmgr.

    Imdr (Cu)

    ccp (cuinc cgasl-pmcdlk)

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    ;

    =I Jruiu lglhlftglrn

    Imdr Imdrf lf flhgn duggmfh mgmf, lgldtrnd-

    lgldtrafnd smfmynknr. Lgldtrnd ngltdlfgnn ad ydsldtnr. Hmklfn pmrm vl sngme ymphfkm duggmfgmf

    hltmg mgmhgmrff iyd aufguu imdrnlrnr.

    Knlr mgmhgmr km, duyuhcugudtm vl irafzelydlgcngnnfkl duggmfgr.

    Pnrnf (Cu-Rf) vl irafz (Cu-Sf), imdrmgmhgmrkr.

    [mrhkm, su yasufu gkrc (mgjmsnt) agmrmdduggmfgr.

    Imdr += vl +9 kllrgndgn inglndglr ympmr.

    Imdr tuzgmr jlflggndgl hmvn rlfdgnknr.

    CuSA;.

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    ;

    pgmstnd vl dazhltnd rfglr jnin jfgd ymmhhzf lntgntmhmhgmycgmrfkm dmrhzm dhmdtmkr.

    nfda sgont ogarlsmf zlggnl smenptnr vl pmrgmd dmkrmfgmrf,ogarlsmf gmhimgmrf,

    U-f vl tlglvnzyaf ldrmfgmrff ymphfkm duggmfgr. Emyvmfgmrf ilsglfhlsnfkl kl flhgn inr ylr tuthmdtmkr. [aprmd mgdmgnglrl ilfzlr zlggnd jstlrhldtlknr. Omdmt

    afgmrm jrl kmem lgldtrafljmtnotnrglr, kmem kd lrnrglr.

    Dmkhnyuh Dmkhnyuh, lf kd lrnhl fadtmsfm

    smenp mgmhgmrf flhgn inr ingllfnknr. Duggmfh mgmfgmr mrmsfkm %?0 ngl lf

    iyd pmy, lgldtragnz yaguygm dmpgmhm mgr. Fndlg-dmkhnyuh pngglrn ymphfkm4 myrcm

    ftraf yutucu zlggnn flklfnygl fdgllrrlmdtrglrkl daftrag uiudgmrfkm vlzregmhmkm duggmfgr.

    Imz inglndglrn, snyme-ilymz vl rlfdgntlglvnzyaf tpglrnfkldn oasoarlsmfinglndglrkl duggmfgr.

    P_C hmkklyl kmymfdggd dmzmfkrr. Dmkhnyuh vl inglndglrnfnf zlgtnglrn

    zlenrgnknr.

    Cnvm [lrhahltrlglrnf, imrahltrlglrnf, knozyaf

    pahpmgmrff vl kmem inrad gmiarmtuvmrjlrlcnfnf ymphfkm duggmfgr.

    Cvm iuemrg gmhimgmrf vl rldgmhdgmfkrhmgmrff, cvmgmgtlrglrnf,

    kn eldnhgnnfkl duggmfgmf imz dmrhgmrf, daruyucu iaymgmrf, icld gkrc ngmgmrf

    vl pngglrnf ympsfkm km cvm iugufur.

    3I jruiu lglhlftglrn

    Sdmfknyuh Cvm iuemrg gmhimgmrf nnfl dmtgkfkm,

    jfl fm ilfzlr ad vlrnhgn inr ddmyfm aguturur.

    Iu flklfgl iu lglhlft, jgdgmfkrhmgmrkm duggmfgr.

    Ymkyamdtno nzatapu agmf Sc-;?, rmonflrnglrklemh pltrag vl ilfzlrn hmkklglr nnf nzsrc agmrmd duggmfgr.

    S

    z

    ft

    tlspnt lkncnglrkl vl uzmylfkstrnsnfkl duggmfghmsff ymf srm,taeuh yllrtncn dnhymsmggmrf inglnhnfkl klylr mgr.

    trnyuh Drah, hagniklf, znrdafyuh vl tntmfyuh

    jnin lglhlftglrkl tmfl iayutufufdgtghlsnfkl4

    mghnfyuh vl hmjflzyuh mgmhgmrffkmymfdggdgmrff mrtrghmsfkm,

    vmfmkyuh vl ilfzlrn hltmgglrkladsnkmsyafuf fglfhlsnfkl,

    ltnglf pagnhlrglrnfnf aguturugkuutlpdnhlglrnf dmtmgnzglfhlsnfkl,

    cmh vl slrmhnd ymphfkm, mtllkmymfdg tugm ymphfkm,

    dmhlrm hlrcldglrnfkl vl gmzlrsnstlhglrnfkl duggmfgr.

    Lvrapyuh lglhlftnygl inrgltnrnghn emgn, rlfdgn

    tlglvnzyafgmrkm drhz rlfd lgklsnfkl duggmfgr. Lf flhgn inglndglrnfklf inrn agmf ntrnyuh adsnt, saf klrlcl

    ltdngn hndrakmgjm ongtrlglrn agmf ntrnyuh-klhnr inglnhgn gmgtmgmrff aguturughmsfkm duggmfgr.

    trnyuh nlrndgn gmg tmgmr, ngjnf hmfyltnd zlggndglrjstlrnrglr. trnyuh-mghnfyuh tm km, ympmy lghms agmrmdkllr jrr.

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    ;I jruiu lglhlftglrn

    [ntmfyuh lntgn hltmgglrgl inrgndtl duggmfgmf ad

    flhgn inr mgmh lglhlftnknr. Iu mgmhgmr, emonognd, smgmhgd vl sym

    kmymfdggf flh tmk lfkstrnglrklduggmfgr.

    [ntmfyuh, lgnd dmkmr kmymfdg, mfcmdafkmf %;< kmem emonotnr.

    Mghnfyuhkmfsm %?0 kmem mr aghmsfmdmrf, 9 dmt kmem kmymfdgkr.

    Kmymfdgg vl msntglrl dmr knrlfgn aguuflklfnygl, lntgn mgmhgmrf ympsfmdmtgr.

    [ntmfyuh tltrmdgarnt inglnn, cmhgmrfrlfdglfknrnghlsnfkl duggmfgr.

    Klfnz suyufm dmr lsnz inr kmymfdggm smenp aghmsflklfnygl, klfnz suyufkmf tmtg su lgkl lknglf tlsnsglrkl vltuzgu suym tlhms lklf jlhn kafmfh pmrmgmrff

    ymphfkm duggmfgr. Dmgcgd vl dmpmtcgd zlggnn flklfnygl, omrdg tnptldn

    iaymgmrf ympsfm km dmtgr. Dzgtlsn ymfsthm zlggnn jstlrlf tntmfyuh

    iaymsfkmf, s flklfgn jr dmyiff ymmfk jfljzglhlvglrnfkl kl ymrmrgmfgr.

    Ilymz vl nyn dmpmtc inr pnjhlft agmf tntmfyuh knadsnt([nA9) kl sngjn, dmt, iaym vl ilfzlrn hmkklglrnfymphfkm duggmfgr.

    Smonr vl ymdut drnstmgglrnfnf ygkz ldngglrn, nlrndglrnfkldntntmfyuh knadsnttlf nglrn jlgnr.

    Rnrdafyuh lgnd lgklsnfkl, vmduh tnpglrnfkl, clrrmen

    uyjugmhmgmrkm, ogm mhpugglrnfkl,pmtgmycgmrkm duggmfgr.

    Pmsgmfkrc hmkklglrgl mgmf dnhymkmggmrfkm km jlfn duggmfh vmrkr.

    Fnyaiyuhgm inrgltnnfkl, kd scmdgdgmrkmsplrngltdlf zlggnd jstlrnr.

    Rnrdafyuh adsnt, s adufm kmymfdggmiarmtuvmr hmgzlhlglrn rltnhnfkl,hltmgrbnd orfgmrf dmpgmfhmsfkm vl symkmymfdg hmkkl agmrmd cmh-slrmhndlfkstrnglrnfkl duggmfgr.

    Myrcm, vurhmg mgjgmrf vl orf tugmgmrffymphfkm km znrdafyuhkmf omykmgmfgr.

    Emofnyuh Mfhmym dmr agmmfst klrlclkl

    kmymfdg agmf iu lglhlft, ad nyn ftrafsaurminghl zlggnn flklfnygl fdgllrklfnzmgtgmrkmdn rlmdtr daftraguiudgmrfkm duggmfgr.

    _mduh tpglrnfkl kl jmz lhncn fntlgnnyglinr "jmz mvcs" agmrmd duggmfgr.

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    Splrngltdlf zlggnl smenp agmf vl jg hmfyltndmgmfgmrkm ingl iu zlggnnfn yntnrhlylf FiRr mgmhfkmf

    ympgmf tlgglr, jg vl kmymfdg hdfmtsgmrf ymphfkmduggmfgr.

    Duyuhcugud mgmffkm km jlfn duggmfh vmrkr.

    Fdgllr rlmdtrglrkl duggmfgmf pmsgmfhmz lgndmgmhgmrff, blt vl ozlglrnf, dlsncn mgltglrnf vl iaruemtgmrff ymphfkm km fnyaiyuhkmf omykmgmfgr.

    [mftmg Lgldtragntnd dmpmsntrglrnf, vmduh orfgmrff,

    dnhymsmg nglhglrkl duggmfgmf mgltglrnf,fdgllr rlmdtrglrnf, emvm tmtgmrff vlozl pmrmgmrff ymphfkm duggmfgr.

    _cut svgmrff tmhmhfm dmr knrlfgnaghms flklfnygl, mhlgnymt jlrlglrnfnfymphfkm km ymrmrgmfgr.

    [mftmg adsnttlf lgkl lknglf ydsld drghmnfknsnfl smenp zlg cmhgmr, dmhlrmhlrcldglrnfnf ymphfkm duggmfgr.

    Gas Mgmhas'tm mgmf ingnh nfsmfgmrtmrmofkmf ympgmf vl lrnhl fadtms 3:35Cagmf tmftmg dmrink jrmont mgmh, ympgmf lfslrt hmkklglrklf inrn agmrmd dmiug lkngnyar.

    ?I jruiu lglhlftglrn

    Drah Hmvnhsn rlfdgn slrt, drgjmf, ad pmrgmd vl

    darazyafm ad kmymfdg inr hltmgknr. Drahnt clvelrn OlCr9A; emgnfkl iugufur. lgnnf slrtgltnrnghlsnfkl, pmsgmfhmz lgnd

    rltnhnfkl vl lntgn mgmhgmrf lgklsnfklduggmfgr.

    zlggndgl atahaing pmrmgmrfkm vl dlsncnmgltglrkl darazyaf fglyncn dmpgmhm agmrmdduggmfh km ymyjfkr.

    Drah, cmhm zhrt ylngn inr rlfd vlrnr vlsd tlrcne lknglf inr dmtmgnzrkr. ^mdut vl zhrtf rlfjnfn vlrlf kl drah

    lglhlftnknr.

    ^dsld lrnhl scmdg flklfnygl, tugm vl dmgp ymphfkmkm rmilt jrhldtlknr.

    Hltmgnd drah hltmgnd mghnfyuhgm nfknrjlhl yaguygm lgkllkngnr.

    9 Mg(d) + Cr9A3 (d) 9 Cr(s) + Mg9A3 (s) E8-

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    :I jruiu lglhlftglrn

    Hmfjmf Duru pngglrkl klpagmrnzmtr agmrmd vl cmh

    zlrnfkl klhnr dnrgngnn flklfnygl agumfylng rlfjn yad lthlkl duggmfgr.

    Mhltnst tmff rlfjnfn vlrlf klhmfjmflzknr.

    lgnd vl png rltnhnfkl, klhnryaguhmdmsgmrff vl dmsmgmrf ymphfkm,myrcm slrmhnd smfmynnfkl

    Jg inr adsntglyncn agmf plrhmfjmfmt(HfA;), lczmcgd mghmgmrfkm fnclgmfmgnzglrkl duggmfgr.

    Cmfggmr nnf flhgn inr lslr lglhlft agmfhmfjmflz, zlggndgl emyvmfgmrkm I=vntmhnfn duggmfhfkm rag ayfmr.

    5I jruiu lglhlftglrn

    Klhnr ad lsdnklf ilrn ingnfhldtl agmf vl

    ylryzfkl lf iag iugufmf hltmgknr. Emvmkm dagmygdgm adsntglfnr. Intdnglrnf vl emyvmfgmrf ymmh nnf saf

    klrlcl flhgn inr lglhlft agmf klhnr,elhajgainf pnjhlftnfnf ympsfkm kmadsnblf tmyc agmrmd nglv jrr.

    Smo emgkl klhnr agmrmd, sdgdgm dmriaf vlknlr hltmgglrgl mgmh emgnfkl duggmfgr.

    fmmtgmrkm iltaf dagaf, dnrn vl yzlyglrnfjglfknrnghlsnfkl duggmfgr.

    lgnd smfmynnfnf mfm emhhmkklsnknr.

    Klhnr pnrnt OlS9 , elhmtnt Ol9A3 , hmjfltnt Ol3A; ldgnfkliugufur.

    Klhnrnf lf flhgn mgmh lgndtnr. C-Cr-Hf-Fnlglhlftglrnfnf ympt ad lntgn mgmhgmrf thfl lgndklfnr.

    Kmymfdgg, pmrgmdg, nglfhl dagmyg imdhfkmf adduggmfgmf inr hmgzlhlknr.

    Pnd klhnr (emh klhnr) nnfkl dmriaf, hmfjmf, ddrt,oasoar, sngnsyuh vl knlr smoszgdgmr vmrkr. Iu smoszgdgmrf

    jnklrnglrld nstlff hltmg mgmhgmr lgkl lthld nnf pnd klhnrnylfnklf lrntngnp, emvm ngl ymdgr. Dmriaf armf kfgr.stlflf hltmgglr dmtgmrmd lgnd lgkl lkngnr.

    5I jruiu lglhlftglrn

    Daimgt Klhnr, fndlg vl knlr hltmgglrgl

    inrgltnrnglrld, "Mgfnca" mk vlrnglf vlmgghf kfkm hmfyltndglfhl jcflsmenp agmf mgmhf lgklsnfkl duggmfgr.

    Hmfyltnd vl pmsgmfhmz lgnd lgklsnfkl,blt trinfglrnfkl vl jmz trinfblflrmtrglrnfkl duggmfgmf mgmhgmrfrltnhnfkl kl ymrmrgmfgr.

    Kmymfdg vl adsntglfhlyl dmr knrlfgninr hltmg aghms flklfnygl, lgldtragnzgl

    dmpgmhm nglhnfkl kl duggmfgr. Parslglf vl cmh smfmynglrnfkl, dmgc vl

    pmrgmd hmvn rlfjnf rltnghlsnfkl daimgttuzgmr duggmfghmdtmkr.

    Daimgt zmyo rlmdsnyaf yltlflnfl smenptnr. Msntglrkl adymvm zfr, emvmkm ad ymvm darazyafm urmr.

    Ol9+ vl Ol3+ tuzgmrfkm agkuu jnin Ca9+ zlrnfl CF-

    ngmvlsnygl inr snymfr inglnn dlgnr.

    Ca9+ + 9 CF- Ca(CF)9 Daimgt inglndglrnfklf CaSA; dayu hmvn

    Ca(E9A)?CN9 plhil, Ca(E9A)?(FA3)9 drhz rlfdgnknr.

    Fndlg Pmsgmfhmz lgnd imtm aghmd zlrl,

    darazyafm knrlfgn mgmhgmrf lgklsnfklduggmfgr.

    Imdr-fndlg mgmhgmrfkmf ympgmf tpglr,klfnz suyufkmf tmtg su lgkl lknglftlsnsglrkl duggmfgr.

    Hmklfn pmrmgmrf, fndlg-dmkhnyuh pngglrnfvl zre dmpgmhmgmrff ymphfkm kmymrmrgmfgr.

    Fndlg dmpgmhm, knlr hltmgglrn daruyucuzlggndtlknr.

    Darazyafm dmr kmymfdg agkuufkmflgldtragnzgl dmpgmhm km tlrcne lkngnr.

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Fndlg inglndglrnfklf

    FnCN9 smr FnCN9 .?E9A ylng

    FnSA;.?E9A ylng Fn(FE3)?(FA3)9 md hmvn rlfdgnknr. Fndlg enkrablfglhlkl dmtmgnzr agmrmd duggmfgr.

    Fndlggn lgndglr darazyafm kmymfdg, slrt vl smgmhkrgmr.

    Pmggmkyuh Enkrablf ldglhl vl dmrhm

    tlpdnhlglrnfkl sd duggmfgmf inrdmtmgnzrkr.

    Mgmhgmr, duyuhcugud mgmffkm kmduggmfgr.

    rflnf ilymz mgtf, mgtf lglhlftnfnfpmggmkyuh ngl aguturkuu inr mgmhkr.

    Kn eldnhgnnfkl, dag smmtn ymphfkm,slrmhndglrl hltmg dmtghms nglhglrnfkl,lgldtrnd rglglrnfkl vl mhlgnymt mgltglrnfnfymphfkm duggmfgr.

    Pgmtnf Gmiarmtuvmr dmpgmrff, iazufhmym

    kmymfdg jlrlglrnf, tlgglrnf vl sgugmrfymphfkm,

    duyuhcugudtm, kn eldnhgnnfkl vllgldtrnd daftmdgmrfkm duggmfgr.

    Pgmtnf-daimgt mgmhgmr jg hmfyltndzlggnd jstlrnr.

    Pgmtnf rlznstmfs tlgglrn, ad ydsldscmdgdgmrkm mgmf lgldtrndgn orfgmrfymphfkm duggmfgr.

    Mrmimgmrkm emvm dnrgngnnfn fglyncnkafmfhgmrf ymphfkm, ozlglrnf udafnglrnfnf vl blt hatargmrffmzgdgmrff dmpgmhmsfkm,

    iyd jlhnglrnf, klfnzmgt iaru emtgmrff vl lgndklstldglrnf dmtaknd daruhm snstlhglrnfkl kl pgmtnfklfymrmrgmfgr.

    Sgornd msnt lgklsnfkl vl pltrag rfglrnfnf nglfhlsnfkldmtmgnzr agmrmd pgmtnf duggmfghmdtmkr.

    Saru 1

    Clvmp I

    Saru 1

    Clvmp I

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Saru 1

    Clvmp M

    Saru 1

    Clvmp K

    Saru 1

    Clvmp I

    Saru 1

    Clvmp K

    Saru 1

    Clvmp K

    Saru 1

    Clvmp M

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?

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    Saru 1

    Clvmp K

    Saru 1

    Clvmp M

    ^rk. Ka. Kr. Mtnggm Lvcnf Moyafdmrmensmr Dacmtlpl fnvlrsntlsn Helfknsgnd Dnhyms Klrs Fatgmr 900?