ORGANIC CHEMISTRY Fundamental Concepts of Organic Chemistry Dr. Anju Srivastava Dept. of Chemistry Hindu College Delhi (12.04.2007) CONTENTS Introduction Ionic and Covalent Bonds Orbital Picture of Covalent Bonding Valence Bond Theory and Molecular Orbital Theory Hybridization: Covalent Bonding of Carbon Hybrid Orbitals Hybridization in Molecules Having Heteroatoms Parameters Affected By Hybridization Polar Covalent Bonds Polarity of Bonds Delocalised Chemical Bonding Resonance Types of Molecules That Have Delocalised Bonds Applications of Inductive Effect and resonance Effect Resonance Energy Aromaticity Hyperconjugation Intermolecular Forces Dipole - Dipole Interaction Van Der Waals Interactions Hydrogen Bonding Stereochemistry Organic Reactions Nucleophiles and Electrophiles Relative Strengths of Nucleophiles and Electrophiles Homolysis and Heterolysis of Covalents Bonds Types of Organic Reactions Energetics of Reaction Thermodynamics of Reaction Kinetics of Reaction
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ORGANIC CHEMISTRY
Fundamental Concepts of Organic Chemistry
Dr. Anju Srivastava Dept. of Chemistry
Hindu College Delhi
(12.04.2007) CONTENTS Introduction Ionic and Covalent Bonds
Orbital Picture of Covalent Bonding Valence Bond Theory and Molecular Orbital Theory Hybridization: Covalent Bonding of Carbon Hybrid Orbitals Hybridization in Molecules Having Heteroatoms
Parameters Affected By Hybridization Polar Covalent Bonds Polarity of Bonds Delocalised Chemical Bonding Resonance Types of Molecules That Have Delocalised Bonds Applications of Inductive Effect and resonance Effect Resonance Energy Aromaticity Hyperconjugation Intermolecular Forces Dipole - Dipole Interaction Van Der Waals Interactions Hydrogen Bonding Stereochemistry Organic Reactions Nucleophiles and Electrophiles Relative Strengths of Nucleophiles and Electrophiles Homolysis and Heterolysis of Covalents Bonds Types of Organic Reactions Energetics of Reaction Thermodynamics of Reaction Kinetics of Reaction
Reaction Profiles Reactive Intermediates Carbanions Carbocations Radicals Carbenes Nitrenes Arynes Formal Charge Investigating Reaction Mechanism by Various Techniques
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