- 1. Tomasz Liskiewicz* and Amal Al-Borno Charter Coating Service
(2000) Ltd., No. 6, 4604 13th Street NE, Calgary, AB, T2E 6P1,
Canada * [email protected] I N T E R C O R R 2 0 1 4 ,
F o r t a l e za / C E , B ra z i l , M ay 1 9 - 2 3 , 2 0 1 4
Functional surfaces for corrosion protection current challenges and
future trends
2. Functional surfaces for corrosion protection: What are
available classes of anti-corrosion coatings? What are current
technology trends? What might be future technology trends? How to
stay ahead of the game in anti-corrosion business? What I want to
achieve with this talk 2 Where are we now? Where are we going
to?Where are we coming from? [* Credits to Creative Commons images
used in the presentation given in the final slide] 3. Outline
Background Surface Engineering Coating selection Corrosion
resistant coatings Where are we coming from? Bit of history - from
painting caves to painting bridges Where are we now? Coating vs
surface modification Comparison of some coating technologies
Coating design fit for purpose Market & patent analysis Where
are we going? Industry challenges Technology trends Early ideas /
novel technologies Summary 3 4. What is Surface Engineering?
Engineers perspective makes possible the design and manufacture of
engineering components with combination of bulk and surface
properties unobtainable in a single monolithic material Bell, 1985
Surface engineering 4 Manipulation of properties Tailored
performance Surface functionalization 5. 5 Surface
functionalization Design Improvements Longer service life Ability
to tolerate greater loads Ease and low cost of maintenance Improved
response in kinetic systems Lower energy consumption Resistance to
corrosion Possibility of designing to close tolerances
Environmental gains and conservation of resources Use of lower-cost
base materials 6. 6 Surface engineering technology Image cortesy:
Linkping University 7. 7 Role of corrosion resistant coating
Exposure time Freeenergychange,Go,k-calmole 0 -81 FeOOH line
Uncoated steel Coated steel Lifetime of coating After: Paint and
Coatings Applications and Corrosion Resistance, Philip A,
Schweitzer, Taylor & Francis, CRC Press, 2006 8. 8
Anti-corrosion coating: idealized scenario 9. 9 Anti-corrosion
coating: real-life scenario substrate coating substrate coating
substrate coating Barrier coating insulates substrate from the
corrosive atmosphere Barrier integrity broken: moisture and
corrosive species pass through Corrosion and barrier coating
undercutting atmosphere, mechanical damage 10. Where are we coming
from ? 11. 11 Coatings for decoration & identification 15000 BC
Roman Era First known cave painting from natural iron oxides
(France & Spain) Egypt: first synthetic pigment Egyptian Blue;
Vehicles used: egg white, gelatins, beeswax Asia: fired pigments
and organic pigments; similar vehicles as in Egypt American
Indians: variety of organic materials used for pigments charcoal,
graphite, lignite, calcined deer bones; vehicle salmon eggs Romans:
same essential materials as Egypt with more artificial colors 12.
12 First protective coatings 6000 BC Middle Ages Chinese lacquer
First protective coating developed in Egypt pitches and balsams to
coat boats Varnish developed in Egypt from Gum Arabic Lacquer also
used in Japan and Korea Romans use pitch and wax on ship bottoms
Sap used to waterproof drinking vessels in Japan Considerable use
of paint to protect wood in Middle Ages 13. 13 Emergence of paint
& varnish industry 18th Century 20th Century Watin first
described the paint and varnish industry (1773) First varnish
factory in England (1790) First reference to use of zinc as a
protective coating (1840) First prepared paint on the market (1867)
First protective coating system: red lead-graphite linseed oil
paint (1800- 1900) New era in the coating industry with increased
emphasis on science and chemistry (early 20th century) 14. 14
Historical trends Occurrence over time - books paint phrase search
Source: Google Ngram Viewer Shows how the phrase has occurred in a
corpus of books Years 1800 2000 15. 15 Historical trends Occurrence
over time - books coating phrase search Source: Google Ngram Viewer
Shows how the phrase has occurred in a corpus of books Years 1800
2000 16. 16 Historical trends Occurrence over time - books coating
& corrosion phrase search Source: Google Ngram Viewer Shows how
the phrases have occurred in a corpus of books Years 1800 2000 17.
17 Historical trends Occurrence over time - books thermal spray
phrase search Source: Google Ngram Viewer Shows how the phrase has
occurred in a corpus of books Years 1800 2000 18. 18 Historical
trends Occurrence over time - books Physical vapor deposition &
physical vapour deposition phrases search Source: Google Ngram
Viewer Shows how the phrases have occurred in a corpus of books
Years 1800 2000 19. Where are we now ? 20. 20 Coating vs surface
modification substrate surface modification coating 21. 21 Classes
of anti-corrosion coatings ORGANIC INORGANIC CONVERSION METALLIC
Coal tars Phenolics Vinyls Acrylics Epoxy Alkyds Urethanes
Silicates Ceramics Glass Anodizing Phosphating Chromate Molybdate
Galvanizing Vacuum vapor deposition Electroplating Diffusion 22.
Coating thickness (m) Substratetemperature(C) 1,000 0 200 400 600
800 0.1 100101 1,000 10,000 Physical Vapour Deposition (PVD)
Thermal Spray Welding Roll Cladding Chemical Vapour Deposition
(CVD) Electroplating 0-1-10 100,000 Thermo- chemical Diffusion Ion
Implant. Anodising / PEO Cold spray 22 Design criteria: process
temperature 23. 23 Design criteria: coating thickness Chemical
Vapor Deposition Physical Vapor Deposition Thermal Spray Organic
Coating 24. Particle velocity on impact, m/s Particletemperature,oC
1000 2000 3000 200 400 600 800 1000 Flame & arc spray Plasma
spray HVOF spray Cold spray Increased adhesion & cohesion /
Reduced porosity 24 Design criteria for thermal spray 25. 25 Design
criteria What conditions am I designing for? Environment Chemical
vs mechanical damage Geometrical limitations? Other factors? Short
series vs mass production Geographical technology limitations
Tailored surface functionality coating specification Feasible
solution 26. 26 Methodology for coating selection 2 Component
specification 1 Application and design study 3 Functional corrosion
requirements 4 Functional coating requirements 5 Non-functional
requirements 6 Economic and procurement requirements 7 Coating
process characteristics 8 Coating material characteristics 9
Specific coating material and process characteristics SOLUTION What
is needed? What is possible?
After:CoatingsTribology,KennethHolmbergandAllanMatthews,Elsevier,2009.
27. 27 Current trends Search popularity over time - web Phrase:
corrosion (worldwide search popularity) Source: Google Trends
Searches done relative to the total number of searches done on
Google over time Years 2004 - 2014 corrosion (worldwide) 28. 28
Current trends corrosion (Brazil) Search popularity over time - web
Phrase: corrosion (search popularity limited to Brazil) Source:
Google Trends Searches done relative to the total number of
searches done on Google over time Years 2004 - 2014 29. 29 Current
trends Search popularity over time - web Phrase: corrosion (search
popularity limited to Brazil) Source: Google Trends Searches done
relative to the total number of searches done on Google over time
Years 2004 - 2014 30. 30 Current trends smart coating (worldwide)
not enough data Search popularity over time - web Phrase: smart
coating (worldwide search popularity) Source: Google Trends
Searches done relative to the total number of searches done on
Google over time Years 2004 - 2014 31. 31 Current trends nano
coating (worldwide) Search popularity over time - web Phrase: nano
coating (worldwide search popularity) Source: Google Trends
Searches done relative to the total number of searches done on
Google over time Years 2004 - 2014 32. 32 Current trends zinc
coating (worldwide) Search popularity over time - web Phrase: zinc
coating (worldwide search popularity) Source: Google Trends
Searches done relative to the total number of searches done on
Google over time Years 2004 - 2014 33. 33 Current trends Search
popularity over time - web Phrase: zinc coating (worldwide search
popularity) Source: Google Trends Searches done relative to the
total number of searches done on Google over time Years 2004 - 2014
34. 34 Current trends functional coating (worldwide) Search
popularity over time - web Phrase: functional coating (worldwide
search popularity) Source: Google Trends Searches done relative to
the total number of searches done on Google over time Years 2004 -
2014 35. 35 Patents 0 500 1000 1500 2000 2500 1900 1910 1920 1930
1940 1950 1960 1970 1980 1990 2000 2010 Granted patents over time
(worldwide) Phrase: corrosion (in the patent title) Source:
Espacenet European Patent Office 36. Sustainedplasmadensity/10ncm-3
ILangmuir TMaiman,1sTLaser Teslaarcgeneration Crookesplasmaphysics
JJThomson BBerghaus,plasmaSEapplications V.Petrov,Arcdischarge
DMattox,IonPlating Penning-Trap/SimpleMagnetron
BWindow,UnbalancedMS WSproul,ClosedFieldMS Lasersteeredarc 1800
1900 1920 1940 1960 1980 2000 2020
PVDworldwidepatentssubmittedperyear 150 100 50 200 250 n=15 n=10
n=5 n=20 n=25 TriodeIonPlating/Mag.sputtering HIPIMSTechnology
JThornton,RotatingMScathode 36 Evolution of plasma based technology
37. 37 Anti-corrosion coatings not limited to one class of coatings
Number of sector specific (traditional) technologies Incremental
improvements across all classes of coatings Coating choice often a
result of historical or geographical factors Potential coating
solutions to be identified through coating design / selection
methodology Coating selection informed by what is needed but also
by what is possible Various trends analyses can be used to
characterize current state of technology Summary where are we now
38. ) Where are we going ? 39. Industry challenges 39 Where are we
going? Technology trends Emerging technologies 40. Where are we
going ? Industry challenges 41. Industry aiming for ZERO defects
& ZERO failures 41 Major challenge zero BUT 85% of coatings
fail in the first 3 years of service 42. 42 Industry specific
challenges 43. Early failure detection Performance prediction New
chemistry coatings with higher Tg Retain adhesion Resist cathodic
disbondment 43 Oil & gas sector challenges Changing environment
Increasing depths (onshore and offshore) High temperature (enhanced
oil recovery, SAGD) Pipelines to carry viscous media (oil sands)
High abrasion Requirements 44. Specific challenge: DLC for internal
bores Drawback of PVD technology: line-of-sight deposition PECVD
equipment handles situation better but struggles with large
length:diameter situations Proprietary technology developed around
2005 to address tubular components W.J. Boardman, A.W. Tudhope,
R.D. Mercado, Method and system for coating internal surfaces of
prefabricated process piping in the field, United States Patent
7300684. 44 45. Specific challenge: DLC for internal bores D. Lusk,
M. Gore, W. Boardman, T. Casserly, K. Boinapally, M. Oppus, D.
Upadhyaya, A. Tudhope, M. Gupta, Y. Cao, S. Lapp, Thick DLC films
deposited by PECVD on the internal surface of cylindrical
substrates, Diamond and Related Materials, 17 (2008), pp.
1613-1621. W. Boardman, K. Boinapally, T. Casserly, M. Gupta, C.
Dornfest, D. Upadhyaya, Y. Cao, M. Oppus, Corrosion and Mechanical
Properties of Diamond-like Carbon Films Deposited Inside Carbon
Steel Pipes, NACE Corrosion, 2008, Paper 08032, pp. 1-11. M. Gore,
W. Boardman, Emergence of Diamond-like Carbon Technology: One Step
Closer to OCTG Corrosion Prevention, SPE International Conference
on Oilfield Corrosion, 2010, Paper 131120, pp.1-9. Plasma generated
within the pipe itself coating deposited on the internal wall of
the pipe multilayer Si-DLC coating up to 50 microns thick was
generated internal bores and enclosures up to 3 meters and aspect
ratio of 1:40 (length:diameter) BUT technology implementation
proved to be challenging 45 46. Where are we going ? Technology
trends 47. 47 "When I was a student at MIT, we all shared one
computer and it took up a whole building. The computer in your cell
phone today is a million times cheaper and a thousand times more
powerful. What now fits in your pocket 25 years from now will fit
into a blood cell and will again be millions of times more cost
effective." -- Ray Kurzweil Accelerating intelligence The
Singularity Is Near, book, 2005 Singularity University, CA, USA
Transcendent Man, movie, 2007 Transcendence, movie, 2014 48. 48
Exponential growth
Source:SingularityisNear,http://www.singularity.com/charts/page17.html
49. 49 Nanotechnology
Source:SingularityisNear,http://www.singularity.com/charts/page17.html
50. 50 Internet of things It was only 70 years after the invention
of the aeroplane that 100 million people travelled by air It took
50 years after the invention of the telephone for 100 million
people to use this form of communication The 100-million user mark
was achieved by PCs after 14 years The Internet made 100 million
users after just 7 years The cycles of adoption of Internet related
technologies are even shorter: Facebook acquired 100 million users
in 2 years 51. 51 TRIZ TRIZ: Theory of Inventive Problems Solving
Teoriya Resheniya Izobreatatelskikh Zadach TRIZ message: Innovation
Can Be Codified There are universal principles of invention that
are the basis for creative innovations that advance technology If
these principles are identified and codified, they can be taught to
people to make the process of invention more predictable 52. 52
TRIZ Genrich Altshuller Using the knowledge and experience of
former inventors 2m patents studied by Altshullers team 5m (?)
patents studied up to date Problems and solutions were repeated
across industries Patterns of technical evolution were repeated
across industries Innovations used scientific effects outside the
field where they were developed 53. 53 TRIZ trends - generic Number
of generic trends that systems tend to evolve along To determine
the evolutionary state of existing system To predict where the
system will evolve in the future Immobile system Joint Multiple
joints Completely elastic Liquid/ gas Field TRIZ for Engineers:
Enabling Inventive Problem Solving, Karen Gadd, Wiley, 2011 54. 54
TRIZ trend surface related Unique & straightforward repeatable
pattern Indication of the most likely successful future direction
Assessment and development of intellectual property TRIZ for
Engineers: Enabling Inventive Problem Solving, Karen Gadd, Wiley,
2011 55. PVD: technology for functional surfaces Full scale
industrial components and R&D samples Fully automated
Repeatable coating composition 55 56. Where are we going? Emerging
technologies Glimpse into the future 57. 57 Self-cleaning surfaces
Inspired by Lotus leaf surface Hierarchical structure
Super-hydrophobic effect Dirt picked up by water droplets
Replicated by nano-patterned surfaces Challenge: volumetric effect
Commercial self-cleaning glass 58. 58 Self-healing materials
Arteria Solutions: Start-up company at the Leeds University
Self-healing nano-coating Inside of pipes in oil extraction systems
Reduce corrosion and build-up of mineral scaling Inspired by nature
Many concepts including encapsulated healing agents and pressurised
vascular networks 59. 59 Programmable materials Prototype of a
selective vibration-damping material Piezoelectric discs which can
be simulated electronically to change their thickness Instant
adaptation to environment Can modify the propagation of mechanical
waves through the structures Vehicles, aircraft, microscopes,
microphones Idea from Empa and ETH Zurich Image courtesy: Empa 60.
60 Innovation happens every day
http://news.illinois.edu/news/14/0508plastic_ScottWhite_JeffryMoore_NancySottos.html,
accessed on May 19th 2014 61. 61 Innovation happens every day
http://http://www.nanowerk.com/nanotechnology-news/newsid=35422.php
, accessed on May 19th 2014 62. 62 Exciting journey from where we
were to where we are going We have a privilege of living in a
fantastic time of technological development Technological changes
become faster and more dramatic To stay ahead of the game need to
ask question How technology trends affect my work Looking for
inspiration in other sectors Anti-corrosion coatings not limited to
one class of coatings From passive coating to functional responsive
surface Summary 63. YOU NEVER CHANGE THINGS BY FIGHTING THE
EXISTING REALITY. TO CHANGE SOMETHING, BUILD A NEW MODEL THAT MAKES
THE EXISTING MODEL OBSOLETE. - BUCKMINSTER FULLER 64.
[email protected] @tomliskiewicz 65. IMAGE CREDITS
Slide 2: Image 1 - source: Wikimedia Commons
(http://commons.wikimedia.org/wiki/File:Bhimbetka_Cave_Paintings.jpg?uselang=en-gb),
creator: Ekabhishek; Image 2 - Courtesy of TWI Ltd, source:
flickr.com; Image 3 - source: Wikimedia Commons
(commons.wikimedia.org/wiki/File:Barnard's_Galaxy.jpg), creator:
European Southern Observatory (ESO) Slide 4: source:
http://commons.wikimedia.org/wiki/File:Exploring_new_continents_1200728.JPG,
creator: Wars Slide 5:
http://en.wikipedia.org/wiki/File:File-Water_droplet_at_DWR-coated_surface1.jpg,
creator: Brocken Inaglory Slide 10: source: Wikimedia Commons
(http://commons.wikimedia.org/wiki/File:Bhimbetka_Cave_Paintings.jpg?uselang=en-gb),
creator: Ekabhishek Slide 11: Image 1 source:
http://en.wikipedia.org/wiki/File:AltamiraBison.jpg, creator:
Rameessos; Image 2 source:
http://en.wikipedia.org/wiki/File:%C3%84gyptischer_Maler_um_1360_v._Chr._001.jpg,
creator: The Yorck Project: 10.000 Meisterwerke der Malerei.
DVD-ROM, 2002. ISBN 3936122202. Distributed by DIRECTMEDIA
Publishing GmbH; Image 3 source:
http://en.wikipedia.org/wiki/File:Pompeii_family_feast_painting_Naples.jpg,
creator: unknown Slide 12: Image 1 source:
http://en.wikipedia.org/wiki/File:20080918094303!Red_lacquer_tray_with_gold_engraving,_Song_Dynasty.jpg,
creator: User:PericlesofAthens; Image 2 -
http://www.wikirestauro.it, creator: Gixie; Image 3 -
http://commons.wikimedia.org/wiki/File:St_Mary's_church_-
_medieval_south_door_-_geograph.org.uk_-_1384477.jpg, creator:
Evelyn Simak Slide 13: Image 1 source:
http://en.wikipedia.org/wiki/File:Bridgewater_foundary.gif,
creator: Illegible; Image 2 source:
http://en.wikipedia.org/wiki/File:4-2-2_GNR_1001.jpg, creator: Tony
Hisgett from Birmingham, UK; Image 3 source:
http://en.wikipedia.org/wiki/File:Sir_Ernest_Rutherfords_laboratory,_early_20th_century._(9660575343).jpg,
creator: Science Museum London / Science and Society Picture
Library Slide 19: Courtesy of TWI Ltd, source: flickr.com Slide 23:
source:
http://commons.wikimedia.org/wiki/File:BurjKhalifaHeight.svg,
creator: Derivative works of this file: BurjKhalifaHeight-de.svg
Slide 25: source:
http://en.wikipedia.org/wiki/File:Steel_ruler_closeup.jpg, creator:
Ejay Slide 38, 39, 40, 46, 56: source: Wikimedia Commons
(commons.wikimedia.org/wiki/File:Barnard's_Galaxy.jpg), creator:
European Southern Observatory (ESO) Slide 41: source:
http://commons.wikimedia.org/wiki/File:Corrosion-on-ships-bow.JPG,
creator: Self Slide 42: Image 1 source:
http://commons.wikimedia.org/wiki/File:2012_Mercedes-Benz_C63_AMG_Car_Review_-_Flickr_-_NRMA_New_Cars.jpg,
creator: NRMA Motoring and Services from Sydney, Australia; Image 2
source: http://en.wikipedia.org/wiki/File:West_Texas_Pumpjack.JPG,
creator: Eric Kounce TexasRaiser; Image 3 - source:
http://en.wikipedia.org/wiki/File:Delta_A330.jpg, creator: Gietje;
Image 4 source:
http://en.wikipedia.org/wiki/File:Hip_prosthesis.jpg, creator: Nuno
Nogueira; Image 5 - source:
http://en.wikipedia.org/wiki/File:Salem_Nuclear_Power_Plant.jpg,
creator: Peretzp, Image 6 - source:
http://commons.wikimedia.org/wiki/File:Drummoyne_Iron_Cove_Bridge.JPG,
creator: J Bar Slide 43: source:
http://en.wikipedia.org/wiki/File:West_Texas_Pumpjack.JPG, creator:
Eric Kounce TexasRaiser Slide 50: source:
https://www.flickr.com/photos/_rq/2959253251/, creator: JaredZammit
Slide 51: source:
http://fr.wikipedia.org/?title=Wikip%C3%A9dia:Oracle/semaine_34_2009#mediaviewer/Fichier:Rubiks_cube_by_keqs.jpg,
creator: Lars Karlsson (Keqs) Slide 57: Image 1 source:
http://commons.wikimedia.org/wiki/File:LotusEffekt1.jpg, creator:
Ralf Pfeifer; Image 2 source:
http://en.wikipedia.org/wiki/File:Lotus3.jpg, creator: William
Thielicke Slide 58: source:
http://en.wikipedia.org/wiki/File:Sweet_Chestnut_Forest.jpg,
creator: Yzmo Slide 63: source:
https://www.flickr.com/photos/bethscupham/6597798731/, creator:
Beth Scupham