Fluorinated Waste and Firefighting Activities Biodegradation Of Halogenated Foams From Petrochemical Refinery Soil Dr. Renato Nallin Montagnolli Postdoctoral research supervised by Prof. Ederio Dino Bidoia São Paulo State University Rio Claro – SP – Brazil
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Fluorinated Waste and Firefighting ActivitiesBiodegradation Of Halogenated Foams From Petrochemical Refinery Soil
Dr. Renato Nallin MontagnolliPostdoctoral research supervised
by Prof. Ederio Dino Bidoia
São Paulo State UniversityRio Claro – SP – Brazil
Petroleum
Coal
Hidroeletrical
Gas
Nuclear
Berkeley
Firefighting foam
AqueousFilmFormingFoam
Aqueous Film
Oxygen
Foam Blanket
Foam Blanket
Perfluorinated compounds (PFCs)
PFBSaAm
PFPeSaAmA
PFHxS
PFOSPFBA
PFHpA
PFNA
FtTAoS
FtSaAm
FtB
FtS
PFDS
PFOSaAm
PFUdA
PFHpS
PFBSaAmAPFBSaAm
PFPeSaAmA
PFHxSPFDS
PFHpS
PFHxS
PFOSPFBA
PFHpA
PFNA
FtTAoSFtB
FtS
PFBSaAm
PFPeSaAmA
PFHxS
PFHpS
PFOS
PFBA
PFHpA
PFNA
FtB
FtS
PFBSaAmA
PFBSaAm
PFHpS
PFBSaAm
PFPeSaAmA
PFHpS
Elet
roflu
orat
ion
Fluortelomeration
PFCs
PFASprecursoras
FtTAoSFTOH
PFOA e PFOS
ex.: PFHxS, PFBAPFCAsPFSAs
FtSsFtBs
Deg
rada
tion
Formulation
PersistenceBioacumulation
Ecotoxicity
Human HealthLow weight in
newborns (FEI et al., 2007)
Menopause ahead oftime (KNOX et al.,
2011)
Low fertility atdetected in young
men semen(JOENSEN et al.,
2009)
Tireoidal diseases athuman population in the US (MELZER et
al., 2010).
Lowered attention(HOFFMAN et al.,
2010)
Compromisedimmunoresponseafter vaccination
(GRANDJEAN et al., 2012).
Renal insuficiencynearby a PFAS
factory (BARRY et al., 2013).
Ecotoxicity
Hepatotoxicity (FUENTES et al., 2007, JOHANSSON et al., 2009)
Imunotoxicity (PEDEN -ADAMS et al., 2008 e THIBODEAUX et al., 2003, HUANG et al., 2010)
Neurotoxicity (HAGENAARS et al., 2008, ANKLEY et al., 2005).
Bioacumulation
General wildlife (BAO et al., 2009; HOUDE et al., 2011; LOOS et al., 2010). Swedish minks (PERSSON et al., 2013) Fish (OAKES et al., 2010) Canadian sea turtles (SOLLA et al.,
2012).
LawsA Norma ABNT NBR 12615, em vigor desde 25/03/92, supera os requisitos da norma Petrobrás N- 1886 (1983) e torna tais substancias aprovadas para a comercialização, sem a preocupação com contaminações ambientais subsequentes
BTEX AFFF
Petroleumindustrycontext
Micro-organisms
The objective of this research was to detect the effects of the
individual components of full AFFF formulations and
characterize shifts in aromaticsdegradation while measuring