FIRST RESULTS OF PROJECT EMPORE-LIFE15 “DEVELOPMENT OF AN EFFICIENT AND SUSTAINABLE METHODOLOGY FOR EMERGING POLLUTANTS REMOVAL IN WWTPS” (EMPORE-LIFE15 ENV/ES/000598) Autores/Authors: M.A., Bernal-Romero del Hombre Bueno; R., González; A. Sánchez; J.M., Santos; F., Martínez; H., García; S., Oyonarte; F., Bosch; M., Company; J., Andreu; L. Mendes-Predolin; D. Prats Presentador/Presenter: Mª Ángeles Bernal Romero del Hombre Bueno (universidad de Alicante) ma.bernal @ua.es ISBN 978-84-09-04625-6
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FIRST RESULTS OF PROJECT EMPORE-LIFE15 “DEVELOPMENT OF AN EFFICIENT AND SUSTAINABLE METHODOLOGY FOR EMERGING POLLUTANTS REMOVAL IN WWTPS” (EMPORE-LIFE15 ENV/ES/000598)
Autores/Authors: M.A., Bernal-Romero del Hombre Bueno; R., González; A. Sánchez; J.M., Santos; F., Martínez; H., García; S., Oyonarte; F., Bosch; M., Company; J., Andreu; L. Mendes-Predolin; D. Prats
Presentador/Presenter: Mª Ángeles Bernal Romero del Hombre Bueno (universidad de Alicante) [email protected]
EMPORE LIFE-EMPORE aims to demonstrate an innovative, cost-efficient and highly
replicable technology for the removal of emerging contaminants from EuropeanWWTPs. Duration: 36 months, from september-2016 to august-2019. Total budget: 1.783.824 € (co-financed by European Commission).
Specific goals To demonstrate that the combination of technologies is able to remove priority
substances and emerging contaminants (ECs), reaching: concentrations below the Directive 2013/39/UE threshold of chlorpyrifos, trifluralin, DEHP and 4-t-octylphenol, concentrations in a 99% of their original concentration of :
ECs included in the 1st watch list of DIRECTIVE 2013/39/UE: diclofenac, 17-a-ethinylestradiol and 17-b-estradiol, Other pharmaceutical pollutants: carbamazepine, ibuprofen, fluoxetine, chloramphenicol and estrone.
To design, construct and set-up a mobile DEMO plant able to reduce the listed ECs. To evaluate the occurrence of ECs in Europe. To assess the environmental and socio-economic impact of the project. To study the transferability of the project results to other European places with a
Benidorm is a popular tourist destination in Spain, whose population fluctuates considerably especially during Christmas, Easter and summer seasons. High presence of elderly population. Discharge of pharmaceutical products in wastewater.
B1: Characterization of water samples GOAL: To quantify the pre-selected pollutants present at the inlet/output of BWWTP. To study the seasonal variability of the concentration of ECs in the wastewater
received by BWWTP.
METHODOLOGY Annual analytical campaign of the influent and effluent of BWWTP (54
samples from the influent and effluent) from Nov. 2016 to Dec. 2017. Analytical techniques: GC-MS/MS and HPCL-MS/MS
B2& B3.Design, implementation and set up Design: Hydraulic capacity: ∼ 5-5.5 m3·h-1 of secondary effluent from BWWTP Mobile/versatile format of the DEMO plant.
Monitoring: weekly samples A) Concentration of each contaminant (indicators 1.3-01 to 1.3-20)
B) Canadian Water Quality Index (CWQI) considering the concentrations of ECsas variables and a modification named WQIEC that penalizes according to thenature of the ECs (indicator 1.3-21).
Benchmarks: Maximum Allowable Concentration (MAC) Directive 2013/39/EUfor priority substances; b) ECs: 2 x LOQ
N variables Water Quality ECs Classification
20 CWQI 28.3 PoorWQIEC 27.9 Poor
N variables Water Quality ECs Classification
20 CWQI 42.4 PoorWQIEC 39.7 Poor
SECONDARY EFFLUENT(54 samples)
INLET BWWTP(54 samples)
www.life-empore.org
C1. Monitoring of the impact of ECs removal
CWQI = 100−𝐅𝐅𝟏𝟏𝟐𝟐+𝐅𝐅𝟐𝟐
𝟐𝟐+𝐅𝐅𝟑𝟑𝟐𝟐
𝟏𝟏.𝟕𝟕𝟑𝟑𝟐𝟐(scale 0-100, 100 ideal)
Presence of priority substances and ECsin the secondary effluent.
Solution: EMPORE methodology
Seasonal variability
RESULTS B1: INFLUENT and SECONDARY EFFLUENT of BWWTPWeekly values of ECs concentration from Nov. 2016 to Dec. 2017 provided by LTL.
EMPORE (ref. LIFE15 ENV/ES/000598) is co-financied by LIFE+2015 Call. The LIFE Programme is the EU’s funding instrument for the environment and climate action.