Fill Conditions and Planned Fill/Soil Disposal & Groundwater ...

Fill Conditions and Planned Fill/Soil Disposal & Groundwater Management Waupaca Foundry – Plant 4 – Historical Landfill 805 Ogden Street Marinette, Wisconsin 54143

Submitted to: Wisconsin Department of Natural Resources 2984 Shawano Avenue Green Bay, WI 54313-6727

Submitted by: GEI Consultants, Inc. 3159 Voyager Drive Green Bay, WI 54311 920.455.8200

August 12, 2019 Project 1902287

Kyle C. Sandmire Project Manager

Roger A. Miller, P.G., C.P.G. Senior Hydrogeologist

Consulting

Engineers and

Scientists

Fill Conditions and Planned Fill/Soil Disposal & Groundwater Management Waupaca Foundry – Plant 4 – Historical Landfill 805 Ogden Street Marinette, Wisconsin 54143 August 12, 2019

GEI Consultants, Inc. i

Table of Contents 1. Background 1

1.1 Ogden Street Networking Project – Background and Understanding 1 1.2 Site Description 2 1.3 Existing Site Conditions 2 1.4 Subsurface Conditions 2

2. Historical Landfill Information 5 2.1 Waupaca Foundry Historical Site Information 5

2.1.1 Historical Landfill Documentation Information 5 2.1.2 WDNR Landfill Documentation Information 5

3. ATC – Environmental Testing 6 3.1 2015 – Geotechnical Subsurface Assessment 6 3.2 2018 – Groundwater Testing 8 3.3 2019 – Groundwater Testing 9

4. Construction Activities Summary 13 4.1 Transmission Line Construction 13 4.2 Substation Construction 13

5. Soil and Groundwater Management Strategy 15 5.1 Soil Management 15 5.2 Groundwater Management 17 5.3 Construction Considerations 17

Figures Figure 1 – ATC Structure Location Map – Waupaca Foundry Figure 2 – Sampling Location Map – Waupaca Foundry Figure 3 – Ogden Street Substation Foundation Plan

Tables Table 1 – Fill Sampling Analytical Test Results Summary Table 2 – Groundwater Sampling Analytical Test Results Summary Table 3 – PFAS Groundwater Sampling Analytical Test Results Summary

Appendices Appendix A – Historical Site Assessment Documentation Appendix B – WDNR SHWIMS Database Information Appendix C – AECOM 2015 Subsurface Assessment Documentation Appendix D – GEI 2018-2019 Subsurface Assessment Documentation


GEI Consultants, Inc. ii

Appendix E – Development at Historic Fill Site Exemption Application and Supporting Documentation KCS:cah K:\American Transmission Co\ATC Projects\1902287_ATC-Ogden Street Networking\In_Progress\Reports\Waupaca Foundry - Sampling Summary\ATC-WaupacaFoundry-DNRReport-20190812_SIGNED.docx


GEI Consultants, Inc. 1

1. Background

1.1 Ogden Street Networking Project – Background and Understanding

American Transmission Company (ATC) has developed a project to partially rebuild the existing U-73 and N-14 electric transmission lines and upgrade an existing substation in Marinette, Wisconsin. The scope of the project includes overhead electric transmission line structure installations to support a new transmission line crossing of the Menominee River and upgrades to an existing Wisconsin Public Service (WPS) substation on an island in the river owned by Waupaca Foundry, Inc. (Waupaca Foundry). Upgrades to the electrical transmission lines will include installation of two steel transmission line structures (145387 and 145388) to the north of the existing Ogden Street Substation. The attached Figure 1 – ATC Structure Location Map – Waupaca Foundry depicts the proposed transmission line structure locations on the west side of the Waupaca Foundry and in an area identified as an inactive, unclassified landfill (aka, an “historic fill site”) with facility name “Waupaca Foundry Inc PLT4”. Construction for the two overhead transmission line structures 145388 and 145387 is scheduled to start on September 9, 2019.

As part of the overall electric utility upgrade project, WPS will be expanding the existing Ogden Street Substation to the northwest and southwest of its current configuration to allow for installation of new yard lights, lightning masts, trenway, substation equipment, and associated foundation installations. The installation of new foundations will be required for the structures associated with the new 69 kV transmission line N-14, the rework of existing 69 kV transmission line U-73, the new 69 kV bus sectionalizing circuit breaker and disconnect switch structures and new 69 kV bus potential transformers. Construction activities related to the substation expansion and reconfiguration is scheduled to start on September 9, 2019. ATC and WPS have developed a preliminary fill/soil and groundwater management plan describing the approach for properly managing fill/soil and groundwater generated during the foundation excavations at these two transmission line structure locations and during planned excavations at the Ogden Street Substation, based on fill sampling completed by AECOM in 2015 and groundwater sampling completed by GEI Consultants, Inc. (GEI) in 2018-2019. Sampling locations are depicted on the attached Figure 2 – Sampling Location Map – Waupaca Foundry. Solid waste fill (saturated and unsaturated) and underlying saturated soil will be hauled to an appropriately licensed disposal facility; and groundwater will be containerized and trucked to a licensed treatment and disposal facility.

Per recent communications with the Wisconsin Department of Natural Resources (WDNR), ATC and WPS, the WDNR has requested that the project proceed under an exemption to develop at a historic fill site. Accordingly, this submittal includes WDNR Form 440-226 (rev 05/16) (Development at Historic Fill Site or Licensed Landfill Exemption Application) and provides supporting information required for the application (Appendix E).



A summary of the identified materials to be managed during construction activities and associated environmental testing results are described in the sections below. Engineering controls for the proposed transmission line structure foundation installations and related construction are incorporated into the proposed soil and groundwater management plan for this project presented in Section 4.

1.2 Site Description

The property located at 805 Ogden Street in Marinette, Wisconsin, is currently owned and operated by Waupaca Foundry and is developed as a ductile iron metal casting facility (Plant 4) for manufacturing various types of parts for the light vehicle, material handling, power transmission, agriculture, hydraulics, and commercial vehicle market sectors.

1.3 Existing Site Conditions

The existing Ogden Street Substation is located in the southwestern portion of the Waupaca Foundry property in Marinette, Wisconsin. The current substation footprint is approximately 0.75 acres in size and is connected to the existing U-73 transmission line entering the substation from the southwest.

The proposed substation expansion will be completed to allow for the installation of new substation equipment to network the Ogden Street Substation to the existing U-73 transmission line to the southwest and to network the new portion of the N-14 transmission line from the northwest. The existing Ogden Street Substation is being expanded approximately 20 feet northwest and 20 feet southwest.

The proposed transmission line structures are located on grass-landscaped or sand/gravel ground surfaces on the west side of the Waupaca Foundry facility, which is currently used as a metal storage yard. The proposed transmission line structures are depicted on the attached Figure 1.

1.4 Subsurface Conditions

Subsurface soil assessments were completed at the proposed transmission line structure locations (142076, 145387, and 145388) during completion of geotechnical borings in 2015.

General observations of the conditions of the fill and native soil conditions encountered at each structure location are summarized in the attached boring logs in Appendix C, and are generally described as follows:



Subsurface groundwater assessments were completed at selected proposed transmission line structure locations (145387 and 145388) by GEI in 2018 and 2019. GEI installed monitoring wells and piezometers in general accordance with Chapter NR 141, Wisconsin Administrative Code. One groundwater monitoring well and one nested piezometer (S-MW and S-PZ), were

Sample ID ATC Proposed Structure # Soil Profile Descriptions [below ground surface (bgs)]

6-Ogden SS1 STR 145388 (~50’ SE)

0’-5’ – Sandy silt with bricks and roots (fill) 5’-7.5’ – Sandy topsoil with cinders and wood (fill)

7.5’-10’ – Silt with sand, plastic, rock, and paper (fill) 10’-15’ – Clayey silt with sand and gravel, plastic, and wood

(fill) 15’-17’ – Sand with wood (fill)

17’-25.5’ – Sand with gravel (SP) 25.5’-30’ – Sandy silt (ML)

30’-35’ – Sand (SM) 35’-36’ – Clay (CL)

36’-38’ – Silt with clay (ML) 38’-40’ – Clay (CL)

8-1 STR 145388 (~35’ W)

0’-5’ – Silty sand with gravel (fill) 5’-11’ – Silty sand with gravel, clay, wood, and cinders (fill)

11’-12.5’ – Sand with gravel (fill) 12.5’-15’ – Clayey silt with wood, glass, gravel, and plastic (fill)

15’-17.5’ – Organic clayey sand with roots (fill) 17.5’-27.5’ – Sand with gravel (SP)

27.5-29’ – Silty sand (SM)

7-Ogden SS2 STR 142076 (~40’ NE)

0’-2.5’ – Silty sand with roots (fill) 2.5’-7.5’ – Sandy topsoil (fill)

7.5’-10’ – Sand with organic silt (fill) 10’-15’ – Organic sand with gravel (fill)

15’-25’ – sand with gravel (SP) 25’-35’ – Silt with sand (ML)

35’-38.5’ – Clayey silt (CL-ML) 38.5’-40’ – Sandy clay (CL)

7-River Xing 2 7-River Xing 2A STR 145387 (~40’ E)

Boring 7-River Xing 2: 0’-2.5’ – Silt with topsoil (fill) 2.5’-5’ – Sand with silt (fill)

5’-10’ – Silty sand with organics and wood (fill) 10’-15’ – Organic silt with sand (OL)

15’-20’ – Sand with silt, organics, and roots (SP-SM) 20’-21.5’ – Sand with silt (SP-SM)

Boring 7-River Xing 2A: 21.5’-25’ – Sand (SP)

25’-38.5’ – Clayey silt (CL-ML) 38.5’-43.5’ – Clay (CL)

43.5’-44.2’ – Gravel with clay (GP-GC)



installed to the northwest of the Ogden Street Substation at proposed structure 145388. Another groundwater monitoring well and nested piezometer (N-MW and N-PZ) were installed to the north of the Ogden Street Substation and along the south side of the Menominee River at proposed structure 145387. Groundwater level measurements were taken from each groundwater monitoring well and piezometer during each sampling event. A summary of measured groundwater depths were generally measured from the ground surface are generally as follows:

Photographs of the well and piezometer locations are included in Appendix E.

ATC Proposed Structure # Sample ID Depth to Groundwater (from ground surface)

STR 145387 S-MW Ranged from 6.63’ to 7.59’ STR 145387 S-PZ Ranged from 6.57’ to 7.91’ STR 145388 N-MW Ranged from 2.35’ to 3.75’ STR 145388 N-PZ Ranged from 3.11’ to 3.92’



2. Historical Landfill Information

2.1 Waupaca Foundry Historical Site Information

A 1938 aerial photograph of the site appears to show the central portion of the current island (west of present-day Ogden Street) as being used for coal storage along the north side of the island and agricultural land in the central and southern portion of the island. The western portion of the island appears to be a part of the Menominee River with areas filled to form boat channels and docking areas. A copy of the 1938 aerial photograph is included in Appendix E. The City of Marinette reportedly owned and operated a landfill on the island, including the western portion (years of operation unknown but ceased by 1970). Waupaca Foundry purchased the Property from the City of Marinette in 1970.

2.1.1 Historical Landfill Documentation Information

Waupaca Foundry has provided ATC with historical site assessment records including the “WFI Plant 4 Subsurface Site Conditions.pdf” which provide Waupaca Foundry’s current understanding of where wastes can be found at the site. Subsurface site assessments were completed in the 1990s to support the expansion of the Waupaca Foundry facility and the installation of a City of Marinette water main through the western portion of the Property in 1999 and indicate that fill materials including municipal refuse, wood waste, and construction debris were encountered during construction in the western portion of the facility.

Waupaca Foundry received a grant of exemption from the WDNR to expand the plant to the west on the historic landfill site in 1994 and as summarized in the attached “WDNR Grant of Exemption to Expand Waupaca Foundry, 1994.pdf”. Findings of Fact provided by the WDNR in this grant exemption identify the historical landfill as the “Old City of Marinette landfill (temporary license #378).”

Historical site assessment records are induced in Appendix A.

2.1.2 WDNR Landfill Documentation Information

Review of currently available WDNR Solid and Hazardous Waste Information System (SHWIMS) information for the Waupaca Foundry site indicates that the site was formerly a municipal landfill operated by the City of Marinette. SHWIMS database information currently identifies the site as a “Landfill Unclassified – Inactive.”

Available SHWIMS database records are induced in Appendix B.



3. ATC – Environmental Testing

3.1 2015 – Geotechnical Subsurface Assessment

To support the ATC construction project, AECOM collected fill samples from four geotechnical boring locations on the west side of the Waupaca Foundry property in 2015. Fill samples were logged, observed, and screened in the field utilizing a photoionization detector (PID), to qualitatively assess for the presence of volatile organic compounds (VOC) in the recovered samples. In addition, samples were collected from each of the borings for subsequent laboratory analysis. AECOM collected samples of fill at each boring location for waste characterization testing including the following:

Field screening of the soils collected from Boring B-6 Ogden SS1 produced measurements that exceeded 1 PID unit (2.2 PID units) at the sampling interval. Additionally, petroleum odors were noted in fill from 10 feet to 17 feet bgs. However, AECOM did not note any corresponding visual evidence of impact or detectable PID readings from the depth interval exhibiting petroleum odors.

Boring logs completed by AECOM at the Waupaca Foundry property in are included in Appendix C, 2015 – AECOM Subsurface Assessment Documentation.

Analytical Testing Results

The fill samples were analyzed for the following: VOCs, Polycyclic aromatic hydrocarbons (PAHs), and Resource Conservation and Recovery Act (RCRA) metals. The fill sample analytical testing results are summarized on Table 1.

Volatile Organic Compounds

The following is a summary of the VOCs detected in the fill samples collected from proposed structure locations:

Sample ID ATC Proposed Structure #

Sample Depth (bgs) Sample Comments

6-Ogden SS1 STR 145388 (~50’ SE) 2.5’-4’

Bricks, cinders, wood, plastic, paper, and petroleum odors noted in variable sands, topsoil,

silt, and clay (fill within the top 17 feet).

8-1 STR 145388 (~35’ W) 7.5’-9’ Wood, cinders, glass, gravel and plastic in

variable sand, silt, gravel, and clay (fill within the top 17.5 feet), no odor.

7-Ogden SS2 STR 142076 (~40’ NE) 2.5’-4’ Variable sand and gravel fill within the top 15 feet, no odor.

7-River Xing 2 STR 145387 (~40’ E) 2.5’-4’ Sand and silt fill within the top 10 feet, no odor



Polycyclic Aromatic Hydrocarbons

PAHs were detected in the fill samples tested from the four geotechnical boring locations. Chrysene was detected at a concentration (151 µg/kg) above the established NR 720 groundwater pathway RCL (144 µg/kg) at boring location 8/1 (near proposed structure location 145388). Other detected PAHs were at concentrations below the lowest NR 720 standards.

Resource Conservation and Recovery Act Metals

The following is a summary of the RCRA metals detected above background threshold values (BTVs) established by the Wisconsin Department of Natural Resources (WDNR) in fill samples collected from geotechnical borings completed in 2015:

Arsenic, chromium, and lead were detected at concentrations (37.2, 56.7, and 593 milligrams per kilogram [mg/kg]) above their established BTVs of 8, 44, and 52 mg/kg, respectively, near proposed structure 145388. Arsenic also was detected above the NR 720 industrial direct contact RCL (3 mg/kg) near proposed structure 145388. Lead, selenium, and silver were detected above their respective NR 720

Sample ID VOCs Detected NR 720 Exceedances Sample Comments

6-Ogden SS1 (near STR 145388)

Benzene, ethylbenzene, and

toluene.

Benzene > GW Pathway

Standard

Bricks, cinders, wood, plastic, paper, and petroleum odors noted in variable sands, topsoil, silt, and clay (fill within

the top 17 feet).

8-1 (near STR 145388)

Ethylbenzene, naphthalene, and

toluene. None

Wood, cinders, glass, gravel and plastic in variable sand, silt, gravel, and clay (fill within the top 17.5 feet), no odor.

7-Ogden SS2 Toluene None Variable sand and gravel fill within the top 15 feet, no odor.

7-River Xing 2 (near STR 145387) None None Sand and silt fill within the top 10 feet,

no odor

Sample ID

Metals Detected

(above BTVs, if established)

Sample Comments

6-Ogden SS1 (near STR 145388)

Arsenic and Chromium

Bricks, cinders, wood, plastic, paper, and petroleum odors noted in variable sands, topsoil, silt, and clay (fill within the top

17 feet). 8-1 (near STR

145388) Lead Wood, cinders, glass, gravel and plastic in variable sand, silt, gravel, and clay (fill within the top 17.5 feet), no odor.

7-Ogden SS2 None Variable sand and gravel fill within the top 15 feet, no odor. 7-River Xing 2

(near STR 145387)

None Sand and silt fill within the top 10 feet, no odor



groundwater pathway RCLs near proposed structure 145388. Note that the WDNR generally does not interpret metals concentrations that exceed an RCL but which are below established BTVs as representing contamination.

Concentrations of VOCs, PAHs, arsenic, and lead in the fill samples above applicable standards correlate with the variable non-soil fill observed at boring locations 6-Ogden SS1 (near STR 145388) and boring 8-1 (near STR 145388) in the west-central portion of the Waupaca Foundry site.

3.2 2018 – Groundwater Testing

To support the ATC construction project, GEI and a subcontract drilling company mobilized to proposed structure locations 145388 and 145387 in the City of Marinette, Wisconsin, on February 5 through 7, 2018, and installed water table observation wells and piezometers in general accordance with Chapter NR 141, Wisconsin Administrative Code. One observation well and one nested piezometer (S-MW and S-PZ), were installed to the northwest of the Ogden Street Substation at proposed structure 145388. Another observation well and nested piezometer (N-MW and N-PZ), were installed to the north of the Ogden Street Substation and along the south side of the Menominee River at proposed structure 145387.

Monitoring wells were constructed with 2-inch diameter, schedule 40 PVC with 10-slot well screens. Observation well S-MW screen was installed from 8 feet bgs to 13 feet bgs. Piezometer S-PZ screen from was installed from 22.2 feet bgs to 24.2 feet bgs. Observation well N-MW screen was installed from 4.5 feet bgs to 9.5 feet bgs. Piezometer N-PZ screen was installed from 16.5 feet bgs to 19 feet bgs. The observation well construction diagrams area included in Appendix D.

GEI developed the wells and piezometers on February 5, 2018, and collected unfiltered groundwater samples for analytical testing. Groundwater samples (unfiltered) were collected using low-flow purging and sampling with disposable tubing and a peristaltic pump on February 7, 2018, and were submitted to Pace Analytical Services, LLC for analytical testing. Unfiltered groundwater samples were collected for metals analyses to estimate anticipated concentrations of total metals that may be generated during dewatering activities. Analytical test results from unfiltered groundwater samples may assist with designing appropriate filtration and treatment for construction dewatering at the transmission line and substation structure locations.

Well construction forms completed by Coleman Engineering for the groundwater monitoring wells and piezometers installed at the Waupaca Foundry property in are included in Appendix D, 2018-2019 – GEI Subsurface Assessment Documentation.

Analytical Testing Results

The unfiltered groundwater samples were analyzed for selected metals (arsenic, barium, cadmium, chromium, lead, and mercury) and VOCs. Groundwater testing analytical results for VOCs were compared to preventative action limits (PALs) and enforcement standards (ESs) established in the NR 140, Wisconsin Administrative Code, Groundwater Quality Standards. The groundwater sample analytical testing results are summarized on Table 2.




The following is a summary of the VOC results for groundwater samples collected from observation wells and piezometers installed at the proposed structure locations in February 2018:

Metals

Arsenic, lead, mercury, cadmium, and chromium were detected in the unfiltered groundwater samples. Groundwater samples were noted as being slightly turbid in the field which would contribute to the reported total metals concentrations. Refer to the analytical results for field-filtered samples collected on July 10, 2019, in the section below for comparison to dissolved metals concentrations.

3.3 2019 – Groundwater Testing

GEI mobilized to the Waupaca Foundry site to collect additional groundwater samples from the wells and piezometers previously installed at proposed structure locations 145388 (S-MW and S-PZ) and 1245387 (N-MW and N-PZ) to determine potential acceptance and disposal of groundwater generated during construction into the City of Marinette or City of Menominee wastewater treatment facilities. Discussions with representatives from the City of Marinette and City of Menominee wastewater treatment facilities confirmed that testing for Per- and polyfluoroalkyl substances (PFAS) would be required for groundwater to determine the potential for acceptance of groundwater at their facility. Both facilities requested that groundwater sampled be analyzed for the Michigan 24 analyte PFAS list.

GEI mobilized to the site on July 2, 2019, and low-flow purged the two monitoring wells (S-MW and N-MW) to facilitate the collection of unfiltered groundwater samples. Unfiltered groundwater samples collected from the two monitoring wells on July 2, 2019, were submitted to Pace Analytical Services, LLC for analytical testing. Unfiltered groundwater samples for metals analyses were collected to estimate concentrations of total metals that may be generated during dewatering activities. Analytical test results from unfiltered groundwater samples may assist with designing appropriate filtration and treatment for construction dewatering at the transmission line and substation structure locations.

Groundwater samples collected for PFAS analysis were collected in general accordance with the Michigan Department of Environmental Quality (MDEQ) – General PFAS Sampling Guidance (Revised 10/16/2018).

GEI returned to the site on July 10, 2019, and low-flow purged the two monitoring wells (S-MW and N-MW) and the two piezometers (S-PZ and N-PZ) to facilitate the collection of filtered groundwater

Sample ID VOCs Detected NR 140 Exceedances

S-PZ (STR 145388) None None S-MW (STR 145388) Multiple compounds detected Benzene > Preventative Action Limit N-PZ (STR 145387) None None

N-MW (STR 145387) None None



samples for metals analysis. Filtered groundwater samples collected on July 10, 2019, were submitted to Pace Analytical Services, LLC for analytical testing.

Analytical Testing Results – July 2, 2019 (unfiltered)

The unfiltered groundwater samples were collected from S-MW (STR 145388) and N-MW using low-flow purging and sampling with disposable tubing and a peristaltic pump and analyzed for testing parameters prescribed by the Marinette Wastewater Treatment Facility pollutant limitation (Code of Ordinances 7.02113) and the City of Menominee Wastewater Treatment Facility discharge standards [Code of Ordinances Sub-Part A Chapter 28 Article III §28-89 (13)], summarized below:

*Both wastewater treatment facilities confirmed that testing for PFAS in groundwater would be required to determine the potential for acceptance of groundwater at their facility.

Groundwater testing analytical results were compared to the applicable PALs and ESs outlined in the WDNR NR 140 Groundwater Quality Standards as well as the prescribed Marinette Wastewater Treatment Facility pollutant limitation standards (Code of Ordinances 7.02113) and the City of Menominee Wastewater Treatment Facility discharge standards [Code of Ordinances Sub-Part A Chapter 28 Article III §28-89 (13)].

PFAS analytical test results were compared to the MDEQ R 299.44 Non-residential criteria and groundwater to surface water interface criteria as well as to the proposed WDNR PALs and ESs for Perfluorooctanoic acid (PFOA) and Perfluorooctanesulfonic acid (PFOS).The groundwater sample analytical testing results are summarized Tables 2 and 3.


The following is a summary of the VOC results for groundwater samples collected from observation wells installed at the proposed structure locations on July 2, 2019:

Bromomethane and chloromethane were detected in the groundwater samples collected from the two observation wells at concentrations exceeding NR 140 PALs for these VOCs. Bromomethane and

Wastewater Treatment Facility Required Testing Parameters

City of Marinette*

Arsenic, biochemical oxygen demand (BOD), cadmium, chromium, copper, cyanide, lead, mercury, nickel, phenols,

selenium, silver, total-suspended solids (TSS), zinc, phosphorus, oil/grease and PFAS (Michigan 24 analyte list).

City of Menominee* Beryllium, BOD, cadmium, chromium, copper, cyanide, lead, mercury, nickel, TSS, zinc, oil/grease and PFAS (Michigan 24

analyte list).

Sample ID VOCs Detected NR 140 Exceedances

S-MW (STR 145388) Multiple compounds detected Bromomethane and Chloromethane > PAL

N-MW (STR 145387) Bromomethane and Chloromethane detections

Bromomethane and Chloromethane > PAL



chloromethane are trihalomethanes (THMs) which form as disinfection byproducts for treated drinking water and therefore may not represent groundwater contaminants at this site.

Piezometers S-PZ (STR 145388) and N-PZ (STR 145387) were not sampled for VOCs during this investigation.

Metals

Arsenic and lead were detected in the unfiltered groundwater samples. Groundwater samples were noted as being slightly turbid in the field which would contribute to the reported total metals concentrations. Refer to the analytical results for field-filtered samples collected on July 10, 2019, in the section below for comparison to dissolved metals concentrations.

Per- and Polyfluoroalkyl Substances (PFAS)

PFAS compounds were detected in the groundwater samples collected from monitoring wells S-MW (at STR 145388) and N-MW (at STR 145387), including a duplicate sample from N-MW.

PFOA was detected at a concentration of (110 nanograms per liter [ng/L]) in the groundwater sample collected from S-MW (at STR 145388). PFOA was detected at concentrations of (1,100 ng/L and 1,000 ng/L) in the groundwater samples collected from N-MW (at STR 145387). These detected concentrations are above the proposed WDNR ES (20 ng/L) for PFOA and are above the established MDEQ non-residential criteria (70 ng/L).

PFOS was detected at a concentration of (200 ng/L) in the groundwater sample collected from S-MW (at STR 145388). PFOS was detected at concentrations of (20 ng/L and 21 ng/L) in the groundwater samples collected from N-MW (at STR 145387). These detected concentrations attain or exceed the proposed WDNR ES (20 ng/L) for PFOA and are above the established MDEQ non-residential criteria (70 ng/L) in S-MW and below this criteria in N-MW.

Perfluorohexanesulfonic acid (PFHxS) was detected in the HDPE tubing equipment blank at a concentration of 0.3 (ng)/L. As indicated in the analytical test report, PFHxS was also detected in the laboratory’s method blank. Accordingly, the trace detection of PFHxS in the tubing blank is not considered to represent potential cross-contamination with the groundwater samples which also contained detectable concentrations of this compound, but at concentrations an order of magnitude higher than the tubing blank.

Indicator Parameters:

Detected concentrations of groundwater indicator parameters including oil/grease, biochemical oxygen demand (BOD) and TSS in groundwater samples collected from STR 145388 (S-MW) and STR 143387 (N-MW) were below their respective wastewater treatment plant discharge limits for the City of Marinette wastewater treatment plant and the City of Menominee wastewater treatment plant.

Other Substances:



Detected concentrations of phenols, phosphorus, and cyanide in groundwater samples collected from STR 145388 (S-MW) and STR 143387 (N-MW) were below their respective wastewater treatment plant discharge limits for the City of Marinette wastewater treatment plant and the City of Menominee wastewater treatment plant, and below any applicable NR 140 standards.

Analytical Testing Results – July 10, 2019 (filtered):

Filtered groundwater samples were collected from the wells and piezometers previously installed at proposed structure locations 145388 (S-MW and S-PZ) and 1245387 (N-MW-N-PZ) to determine the dissolved concentrations of metals in the groundwater.

Filtered groundwater testing analytical results were compared to PALs and ESs for metals established in NR 140 Groundwater Quality Standards. The filtered groundwater sample analytical testing results are summarized on Table 2.

Metals:

Dissolved arsenic was detected at concentrations above NR 140 ES (10 µg/L) at proposed structure location 145388 in filtered groundwater samples collected from S-MW and S-PZ at concentrations of 16.0µg/L and 16.1µg/L, respectively. Dissolved arsenic was detected at concentrations above ESs (10 µg/L) at proposed structure location 145387 in filtered groundwater samples collected from N-MW and N-PZ at concentrations of 14.6 µg/L and 19.9 µg/L, respectively.

Dissolved lead was detected at a concentration of 1.1 µg/L in the filtered groundwater sample collected from S-MW (at STR 145388). This concentration is below the NR 140 PAL for lead (1.5 µg/L).

Dissolved nickel was detected at concentrations of 0.73 µg/L and 0.49 µg/L, respectively in the filtered groundwater samples collected from S-PZ (at STR 145388) and N-MW (at STR 145387). Both detected concentrations are below the NR 140 PAL for nickel (20 µg/L).

Dissolved zinc was detected at a concentration of 6.4 µg/L in the filtered groundwater sample collected from S-PZ (at STR 145388). This detected concentration is below the NR 140 PAL for zinc (2,500 µg/L).

These groundwater samples were collected using low-flow sampling techniques and passed through a disposable 45-micron filter at each well/piezometer and before placing the sample into the preserved bottles provided by the analytical laboratory.



4. Construction Activities Summary

4.1 Transmission Line Construction

MJ Electric will be installing transmission line foundations and structures for the Ogden Street Networking project on behalf of ATC. The MJ Electric foundation crew will install permanent solid steel casing at each transmission line structure location by vibratory methods down to the target foundation excavation base depth. Once the permanent casing has been vibrated down to the appropriate depth, MJ Electric will use an auger to drill out the fill and soil within the permanent steel casing.

Transmission line structure 145388 will be installed with a drilled pier foundation approximately 9.5 feet in diameter and 30 feet deep. Transmission line structure 145387 will be installed with a drilled pier foundation approximately 12 feet in diameter and 65 feet deep. Both excavations will be grouted with concrete to install the drilled pier foundations.

4.2 Substation Construction

WPS will be expanding the existing Ogden Street Substation to the northwest and southwest of its current configuration to allow for installation of new yard lights, lightning masts, trenway, substation equipment, and associated foundation installations. The installation of new foundations will be required for the structures associated with the new 69 kV transmission line N-14, the rework of existing 69 kV transmission line U-73, the new 69 kV bus sectionalizing circuit breaker and disconnect switch structures and new 69 kV bus potential transformers. WPS will be installing seven drilled pier foundations (3 feet in diameter by 21 feet deep) to support the installations of new switch stands and bus supports. Four drilled pier foundations (7 feet in diameter by 41 feet deep) will be installed to support two new H-frame riser structures to network the U-73 and N-14 transmission lines into the reconfigured Ogden Street Substation. WPS will install two 4-foot diameter by 21 feet deep drilled pier foundations to support the installation of two 45-foot lightning masts. Completion of all of the planned drilled pier foundations described above, will generate approximately 910 cyd of soil and 24,000 gallons of groundwater. Seven spread footer foundations will be installed to support 3-phase 69kV low switch stands, low bus supports and a voltage transformer support structures. The excavations associated with these seven spread footer foundation excavations will be approximately 10 feet by 5 feet and approximately 6 feet deep. Three spread footer foundations will be installed to support 3-phase 69kV modified high bus support structures. The excavations associated with these three spread footer foundation excavations will be approximately 7 feet by 7 feet and approximately 6 feet deep. Excavation slopes down to the base of each of the spread footer foundation excavations will be 1:1 slope. Completion of the planned spread foundations described above will generate approximately 324 cyd of soil. Three poured concrete slabs (6 feet by 6 feet by 1.5 feet deep) will be installed to support the installation of new circuit breakers. Completion of the three planned concrete slabs will generate approximately 6 cyd of unsaturated soil.



The existing control house will be expanded 15 feet to the southeast from the existing southern wall of the control house. The foundation of the control house expansion will consist of a poured concrete slab on top of a 6-mil vapor barrier directly beneath the footprint of the new foundation area. Cable and trenway will be installed for interconnection of new and existing station service equipment to the control house. The cable and trenway (19 inches wide by 30 inches deep) will extend from the south side of the control house approximately 155 feet to the west-northwest. The trenway will be capped with concrete covers with openings between the covers to allow for cable sections to be inspected. The cable trench will therefore be open to the atmosphere through the openings between the concrete covers. Installation of the trenway will generate approximately 23 cyd of unsaturated soil. The existing site perimeter fence will be expanded approximately 20 feet to the northwest and southwest in order to accommodate the new and relocated equipment. With the expansion of the yard and the addition of equipment, the ground grid, lightning protection and station lighting designs will be updated. The ground grid will be expanded to cover the new areas of the station to the west and south. New lightning protection will be added to shield the new equipment in the expanded areas as well as the existing equipment. New station lighting will be added to the yard to provide lighting in the expansion area for the new equipment as well as replacing existing lighting in the north and east areas of the substation. Completion of the planned subsurface excavations within the expanded Ogden Street Substation described above will generate approximately 1,263 cyd of fill/soil. The attached Figure 3 – Ogden Street Substation Foundation Plan depicts the proposed trenway location, foundation locations and the planned grading for the substation expansion.



5. Soil and Groundwater Management Strategy

5.1 Soil Management

Transmission line structure 145388 will be installed with a drilled pier foundation approximately 9.5 feet in diameter and 30 feet deep. Approximately 90 cyd of soil and fill material will be excavated for this structure installation (estimated 49 cyd of fill and 38 cyd of soil). The sandy, silty fill is expected to contain approximately 50% non-soil material (bricks, wood, cinders, glass, plastic, roots, and paper), based on review of the boring logs for 8/1 and 6/Ogden SS1 advanced near this planned structure location.

Transmission line structure 145387 will be installed with a drilled pier foundation approximately 12 feet in diameter and 65 feet deep. Approximately 300 cyd of soil and fill material will be excavated for this structure installation (estimated 46.5 cyd of fill and 253.5 cyd of soil). Based on available data, the fill at this location is anticipated to consist of sand and silt with only a small percentage of non-soil material (wood), based on review of the boring log for 7/River XING 2 .

Completion of the planned subsurface excavations within the expanded Ogden Street Substation described above will generate approximately 1,263 cyd of soil. Proportions of fill and native soil encountered at each proposed substation foundation location and proposed excavation area will vary by location. It is anticipated that fill/soil excavated within the top 5 feet will be unsaturated material.

Unsaturated Fill/Soil Management

Based on the subsurface fill conditions and associated analytical testing results for fill samples, fill/fill soil excavated above the apparent water table (i.e., from the unsaturated zone) during the installation of foundations at structure locations 145388 and 145387 or during substation foundation installations and associated excavations is planned to be disposed as solid waste at a licensed landfill. Results of the 2015 subsurface assessment were used to create a waste profile with Waste Management (Profile No. 124545WI) to dispose of exploration-derived fill/fill soil generated at that time. This Waste Management waste profile (Profile No. 124545WI) has been renewed in 2019 to allow for unsaturated fill/fill soil to be disposed of at a licensed facility (e.g., Waste Management, Menominee Landfill, Menominee, Michigan). WPS also obtained Profile No. 131806WI, which was approved by Waste Management in July 2019.

Saturated Fill/Soil Management

Saturated fill/soils generated during transmission line foundation installations, substation excavations will be managed based on chemical analysis, volume, construction methods and logistics, and acceptance criteria for a licensed disposal facility in one or a combination of the following ways:

• Saturated fill/soils may be excavated and placed in a dewatering pad to allow for pore water to be collected and containerized for offsite disposal. The dewatering pad is planned to utilize



a 30-foot by 16-foot steel box with 10-foot walls (comprised of 6 feet of steel and 4 feet of plexiglass). The box is constructed with slotted-steel plates on a 16-inch-high underlying steel water containment chamber. Dewatered fill/soil would then be placed in lined roll-off boxes and mixed with granular bentonite or other amendment to further solidify the fill/soil for disposal, as needed. Representative samples of the amended material may be collected for further waste characterization testing, as required by the licensed treatment/disposal facility. Composite samples would be collected from roll-off boxes exhibiting similar characteristics (fill material or native soil) and be sampled at a frequency of one composite sample (minimum 4 subsamples) for every 100 cyd of similar material. Results of additional analytical testing would be used to determine whether the material can be disposed at a licensed Subtitle D facility (e.g., Waste Management, Ridgeview Landfill, Whitelaw, Wisconsin). If disposal at a licensed Subtitle C facility (e.g., U.S. Ecology, Wayne County Landfill, Belleville, Michigan) is selected, waste characterization sampling and testing would be based on requirements of the facility.

• Saturated fill/soils may be excavated and placed in lined roll-off boxes and mixed with granular bentonite or other amendment to further solidify the fill/soil for disposal. Representative samples of the amended material may be collected for further waste characterization testing, as required by the licensed treatment/disposal facility. Composite samples would be collected from roll-off boxes exhibiting similar characteristics (fill material or native soil) and be sampled at a frequency of one composite sample (minimum 4 subsamples) for every 100 cyd of material. Results of additional analytical testing would be used to determine whether the material can be disposed at a licensed Subtitle D facility (e.g., Waste Management, Ridgeview Landfill, Whitelaw, Wisconsin). If disposal at a licensed Subtitle C facility (e.g., U.S. Ecology, Wayne County Landfill, Belleville, Michigan) is selected, waste characterization sampling and testing would be based on requirements of the facility.

• Saturated fill/soils may be excavated and placed in lined roll-off boxes for disposal. Samples of the excavated materials may be collected for further waste characterization testing, as required by the licensed treatment/disposal facility. Results of additional analytical testing may be necessary to obtain approval for the material to be disposed at a licensed facility (e.g., Subtitle C facility, U.S. Ecology, Wayne County Landfill, Belleville, Michigan).

Construction Documentation

Fill exhibiting characteristics that differ significantly from the analyzed fill samples will be segregated for further analysis, as appropriate. Such fill, if encountered, will be temporarily stored in lined roll-off boxes or placed on and covered with plastic sheeting in stockpile(s) pending further testing and waste classification, as appropriate.

A qualified environmental technician/scientist/engineer or competent environmental monitor will observe and document conditions of excavated material during construction.



5.2 Groundwater Management

Based on groundwater sample analytical test results, the construction team plans to use best-management practices (BMPs) to limit the volume of water generated during subsurface construction activities at these proposed structure locations.

Based on design information, approximately 18,000 gallons of groundwater will be generated during the foundation installation at proposed transmission line structure 145388 and 61,000 gallons of groundwater will be generated during the foundation installation at proposed transmission line structure 145387.

Construction dewatering for installation of substation structure foundations will generate approximately 24,000 gallons of groundwater from drilled pier foundations. The remainder of the substation excavations for spread footer foundation installations, trenway installation, expansion of the slab-on-grade control house and additions to the grounding grid are not likely to generate significant volumes of groundwater.

Groundwater generated by construction dewatering and pore water collected from saturated fill/soil will be managed based on chemical analysis, volume, construction methods and logistics and acceptance criteria for a licensed treatment and disposal facility in one or a combination of the following ways:

• Water may be containerized in frac tanks or open-top weir tanks to allow suspended solids to settle or be field-filtered. After pre-treatment in the field, groundwater will be pumped into tanker trucks for treatment/disposal at a licensed facility (e.g., OSI Environmental, Kaukauna, Wisconsin).

• Water may be containerized in frac tanks or open-top weir tanks to allow suspended solids to settle or be field-filtered. After pre-treatment in the field, groundwater will be treated with polymer and pumped into tanker trucks for treatment/disposal at a licensed facility (e.g., Elite Environmental Corporation, Milwaukee, Wisconsin).

• Water may be containerized in lined roll-off boxes and amended with bentonite to allow for solidified material to be disposed of at a licensed Subtitle D landfill (e.g., Waste Management, Ridgeview Landfill, Whitelaw, Wisconsin) or a licensed Subtitle C facility (e.g., U.S. Ecology, Wayne County Landfill, Belleville, Michigan), pending waste characterization testing, as needed.

5.3 Construction Considerations

ATC will generate approximately 96 cyd of fill and approximately 292 cyd of native soil during the installation of the transmission line structure 145387 and 145388 foundations. Substation construction at the Ogden Street Substation will generate approximately 1,263 cyd of fill/soil. Unsaturated and saturated material excavated/removed for construction will be disposed at an appropriate licensed facility as described in Section 4.1.

ATC will generate approximately 79,000 gallons of groundwater during dewatering of the foundation installations for transmission line structures 145388 and 145387, and an additional 24,000 gallons of groundwater will be generated by WPS during substation excavation dewatering associated with the



installation of drilled pier foundations. Groundwater will be containerized and handled as described in Section 4.2.

Design plans and construction methods will be reviewed to determine if methods can be modified to reduce the amount of fill/soil and groundwater generated. Accordingly, the above quantity estimates may be conservative.

Construction of foundations at transmission line structures 145387 and 145388 and construction of foundations within the substation will cause a temporary disturbance to the existing subsurface/historic fill. However, soil and groundwater displaced/generated during construction of the concrete drilled-pier foundations (transmission structures) or substation drilled piers, spread-footer foundations, trenway and other shallow foundation installations completed at the Ogden Street Substation will either be containerized and disposed of at licensed landfills (saturated and unsaturated material) or licensed treatment and disposal facility (liquids).

The transmission structure and control house expansion foundations will be constructed of concrete and the poured concrete slab for the control house expansion will be installed with a 6-mil vapor barrier. The concrete foundations for the transmission and substation structures and the vapor barrier beneath the control house will protect against infiltration or migration of substances detected in the fill at concentrations above background or applicable soil and/or groundwater standards. Concrete foundations and the vapor barrier placed beneath the control house expansion will also protect against soil vapor migration (e.g., potential methane migration).

The trenway will be constructed above the observed/apparent water table and will be capped with concrete panels installed with openings between the panels to allow for cable sections to be inspected. Accordingly, the cable trench will be open to the atmosphere which will help protect against potential soil vapor accumulation.

Substances detected in fill/soil and/or groundwater (e.g., arsenic, lead, and PFAS) and other conditions of the fill/soil may pose a hazard to workers during planned construction. We recommend that contractors review analytical data and other potential hazards for their construction activities and prepare project-specific health and safety plan(s) for their workers. Due to the presence of municipal fill and organic matter in the subsurface, construction crews should also preform monitoring for methane gas.

Construction equipment coming into contact with fill, soil, or wastewater should be decontaminated by pressure washing and/or rinsing with potable water on a decontamination pad, as feasible. Decontamination water should be obtained from a local source of municipal drinking water (e.g., City of Marinette Water Utility).



Figures

Figure 1 – ATC Structure Location Map – Waupaca Foundry

Figure 2 –Sampling Location Map - Waupaca Foundry

Figure 3 - Ogden Street Substation Foundation Plan

145387

145388

142075(LeftPole)

142075(RightPole)

142076(LeftPole)

142076(RightPole)

3159 Voyager DriveGreen Bay, WI 54311www.geiconsultants.com

Project Number: 1902287

Drawn: KCS 7/24/2019

Approved: 7/24/2019KCS

Figure Number: 1

Scale: AS SHOWN

±Sources: GEI Consultants, AECOM, ATC

Disclaimer: Care was taken in thecreation of this map. GEI Constultants nor any of its contractors or suppliers

can be held responsible for any damages due to errors or omissions in this product.

There are no warranties, expressed or implied. However, notification of any

errors will be appreciated.

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LegendStructure

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Drilled Pier0 100 20050

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G E I Consultants

3159 Voyager Drive Green Bay, WI 54311 www .geiconsultants.com

Legend

9 GEl 2018 Groundwater Monitoring Wells

SB AECOM 2015 Soil Borings

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0 50 100 200 --.:::::::===----• Feet

OGDEN ST

FIGURE 1: SAMPLING

LOCATION MAP -WAUPACA FOUND

Approved : KCS 7/26/2019

Scale: As Shown

Project Number: 1902287

Figure Number: 2

81/4" 81/4"

142-0204 142-0217 1 1/4" X 42" BOLT 3" PROJECTION

"' 7" r 1" X 36" ANC. BOLT 3" PROJECTION

~ ~~~-------------------------------==----------------------------0 20' -0" 17' -8" ® 46' -4" -......... @ 25' -0" @ 0 14' -0" 12'-0" 22' -0" 58' -0" ® 16 PC. 10' LONG #4 REBAR SPACED 4" TO 6" "'

12 PC. 10' LONG #4 REBAR SPACED 4" TO 6"

2' PC 36" DIA SONATUBE

30" DIASONA 2' MIN. LG.

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/ ~ YARD ....._ ....._ ,__ 12' -0" 12' -0" 15' -0" 134-2754 /

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0 0

COLUMN FTG. A ENLARGED

COL. FTG. "B", SS-100-9 2-R

COLUMN FTG. B ENLARGED

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O.C.B. FOUND., SS-102-8 2-REQ'D. ELEV.@ TOP OF CONC. = 591.0

CONTROL HOUSE FOUND., SS-105-3 1-REQ'D. ELEV.@ TOP OF CONC. = 591.0

CABLE TERM. FOUND. C-22355 2-REQ'D. ELEV. @ TOP OF CONC. = 592.0

TRANS. FOUND .. SS-103-4 1-REQ'D. ELEV.@ TOP OF CONC. = 591.0

COL. FTG. "K'' SEE DETAIL 1-REQ'D. ELEV.@ TOP OF CONC. = 591.5

CABLE TERM. FOUND. C-22888 2-REQ'D. ELEV.@ TOP OF CONC. = 592.0

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CABLE TERM. FOUND. C-3191 - Q'D. ELEV.@ TOP OF CONC. = 592.0

THRU EE SEE DWGS, OGS-03-002-01 THR OGS-03-004-03

ALL TO CONC. = 590.5' (NAVD 88) UNLESS NOTED OTHERWISE. SEE PLAN VIEW THIS DWG AND CONSTRUCTION NOTE 3.

12' -0"

·I ~z'-O"MANI /~ ~ GATE

\ .A DRAWING ISSUED FOR CONSTRUCTION BY ATC

1

1

This ATC issued drawing is presently in the construction stage.

t- This ATC issued drawing is presently in the construction stage. ' '\, \,.. ! ~ • • ~I i J. Contact ATC Project Manager JIM PERICOLOSI \ "\...._ 25'-0" GATE

1 ~ ~ \:::::) -.;- / · at (906) 779-7904 on all construction related manners. \

'-0" '' ' For technical issues, proposed revisions to this drawing, \\

12• _0.. and to return "Field Mark-ups", contact the ATC Lead Engineer

)-, "") TOBIN LARSEN at (920) 338-6549 )

CONSTRUCTION NOTE:

1. EXERCISE CAUTION WHEN EXCAVATING NEAR EXISTING FOUNDATIONS FOR NEW FOUNDATION INTALLATIONS. EXISTING FOOTINGS SHALL NOT BE UNDERMINED AND TEMPORARY SHORING OR BRACING TO BE INSTALLED AS DEEMED NECESSARY.

/ Contact ATC Project Manager JIM PERICOLOSI .... 'r"Y .... 'r"Y "Y"'

\... . . . . . . . . . -;:::::.

I at (906) 779-7904 on all construction related manners.

Field Mark-ups Performed By: I EXISTING YARD Date: LIGHT REMOVED Contact Number: I

I I I I I

I

3' -0"

For technical issues, proposed revisions to this drawing, and to return "Field Mark-ups", contact the ATC Lead Engineer

TOBIN LARSEN at (920) 338-6549 Field Mark-ups Performed By: Date: Contact Number:

•

ISSUED FOR

CONSTRUCTION BYWPS

I NOTE: I

3'-0" OF COMPACTED FILL IS REQ'D. UNDER II ALL FLOATING SLAB FOUNDATIONS ,/

NEW YARD LIGHT---,. 3' -0~

9~ I U- -------------------------------------------------------------------------------------------"'-~----~

NEW YARD LIGHT 215' -0" I

2. PER WPS TOPOGRAPHY SURVEY DATED B/11/17, NO EXISTING UNDERGROUND UTILITIES WERE MARKED WITHIN AREA OF NEW CONTROL HOUSE FOUNDATION EXPANSION. FIELD TO VERI~ PRIOR TO EXCAVATION WORK AND AS DIRECTED BY WPS.

3. ALL NEW TOP OF CONCRETE \TOC) ELEVATIONS DEFINED WITHIN THIS FOUNDATION PLAN, WHERE NEW FOUNDAT ONS WILL BE INSTALLED TO ACCOMMODATE EXISTING RIGID BUS HEIGHTS, ARE BASED ON RECENT WPS TOPOGRAPHIC SURVEY INFORMATION DATED 8/11/17. FIELD-VERI~ THE REFERENCED TOC ELEVATIONS FOR NEW FOUNDATION INSTALLATIONS BY USING ADJACENT EXISTING FOUNDATION TOG'S IDENTIFIED AS REFRENCE BENCHMARKS (REF. BM PRIOR TO NEW CONCRETE POURS.

ANCHOR BOLT NOTE:

(SUPPLIED BY WPS CREW) (FDR 122-VCB & 123-VCB)

REV CLOUD LEGEND

C) = REVISION CLOUD FOR ATC W.O. #600637

1995 CON ST.

o4 REEl'S

Z! REEl'S

/\A -CUT ALL EXISTING ANCHOR BOLTS FLUSH WITH TOP OF CONCRETE

C :> =REVISION CLOUDS FOR WPS PROJ. #019001435

-DRILL FOR (4) 5/8" X 6" A. BOLTS WITH 2" PROJECTION

SUPERSEDES DD-22342

REVISIONS

W.O. # 600637 l-_li~TC ENG# T JL

ATC CONST # F4226

OGDEN STREET NETWORKING PROJECT

WPS PROJ. # 0190014135

OGDEN ST. COMMON FACILITIES ADDITIONS

DATE: 02/01118 DESIGNED BY: JZ REVIEWED BY: AJC ENGINEER: JRC

A ATC W.O.# 600637 ATC ENG 1/0#

ATC CONST 1/0 #


WPS CAP 1/0 # 0190014135 WPS OM 1/0# WPS REM 1/0#


DATE: 06/14/19 DESIGNED BY: JZ REVIEWED BY: JWS

B ATC W.O.# 600637 ATC ENG 1/0#

ATC CONST 1/0 #


WPS CAP 1/0 # 0190014135 WPS OM 1/0# WPS REM 1/0#


DATE: 07/03/19 DESIGNED BY: JZ REVIEWED BY: JWS

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ENGINEERING STAMP

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Analytical Summary Tables

Table 1 – Fill Sampling Analytical Testing Results

Table 2 – Groundwater Sampling Analytical Testing Results

Table 3 – PFAS Groundwater Sampling Analytical Testing Results

Table 1 - Fill Sampling Analytical Test Results Summary

Sample

Location

Sample Date

Project Number: 1902287 CAS # BTV Non-Industrial DC Industrial DC GWSample Depth

(ft)2.5-4 2.5-4 7.5-9 2.5-4

Indicator Parameters (µg/kg)3

PID NE NE NE NE 2.2 0.0 0.0 0.0

METALS (detected analytes)3,4

(mg/kg)

Arsenic 7440382 8 0.677 3 0.584 37.2* 7.1 5.8 <3.5

Barium 7440393 634 15,300 100,000 164.8 10.1 20.2 38.7 5.6

Cadmium 7440439 1 71.1 985 0.752 <1.2 0.14J 0.32J 0.15J

Chromium5 16065831 44 100,000/0.301 100,000/6.36 360,000* 593* 10 8.4 4.9

Lead 7439921 52 400 800 27 18.6 18.3 56.7* 4.5

Mercury Varies NE 3.13 3.13 0.208 0.005J 0.02 0.04 0.006J

Selenium 7782-49-2 NE 391 5,840 0.52 8J <1.2 <0.84 <0.84

Silver 7440-22-4 NE 391 5,840 0.8491 4.5J 0.8J 0.42J 0.59J

PAHs (detected analytes)3

(µg/kg)

Acenaphthene 83329 NE 3,590,000 45,200,000 NE <9 <13.9 43.1 <9.2

Acenaphthylene 208968 NE NE NE NE <8.1 <12.4 35.9 <8.2

Anthracene 120127 NE 17,900,000 100,000,000 196,949 <9.4 19.5J 91.9 <9.5

Benzo(a)anthracene 56553 NE 1,140 20,800 NE 7.5J 43.8 130 <6.4

Benzo(a)pyrene 50328 NE 115 2,110 470 7.5J 43.2 140 <6.6

Benzo(b)fluoranthene 205992 NE 1,150 21,100 478 9.3J 44.4 116 <9.2

Benzo(g,h,i)perylene 191242 NE NE NE NE <6.9 47.6 76.8 <7

Benzo(k)fluoranthene 207089 NE 11,500 211,000 NE <10 34.2 127 <10.2

Chrysene 218019 NE 115,000 21,110,000 144 9.3J 50.9 151 8.9J

Dibenzo(a,h)anthracene 53703 NE 115 2,110 NE <6.6 <10.2 29.4 <6.7

Fluoranthene 206440 NE 2,390,000 30,100,000 88,877.8 14J 71.2 288 <9.2

Fluorene 86737 NE 2,390,000 30,100,000 14,829.9 <9 <13.9 67.4 <9.2

Indeno(1,2,3-cd)pyrene 193395 NE 1,150 21,100 NE <6.9 24.2J 70.1 <7

1-Methylnaphthalene 90-12-0 NE 17,600 72,700 NE 14.4J 147 68 <9.2

2-Methylnaphthalene 91576 NE 239,000 3,010,000 NE 21.5 205 102 <9.2

Naphthalene 91203 NE 5,520 24,100 658.2 24.8 160 268 <9.2

Phenanthrene 85018 NE NE NE NE 15.1 110 210 <9.2

Pyrene 129000 NE 1,790,000 22,600,000 54,545.5 11.6 62.6 239 <9.2

VOCs (detected analytes)3

(µg/kg)

Benzene 71-43-2 NE 1,600 7,070 5.1 67.1 <25.0 <25.0 <33.8

Ethylbenzene 100414 NE 7,470 37,000 1,570.0 40.9J <25.0 29.1J <33.8

Naphthalene 91-20-3 NE 5,520 24,100 658.2 <40.0 <40.0 98J <54.1

Toluene 108883 NE 818,000 818,000 1,107.2 94.2 50.7J 45.4 <33.8

PCBs (detected analytes) 3 (µg/kg) - None Tested

Notes

(mg/kg) = milligrams per kilogram; (µg/kg) = micrograms per kilogram; -- = not analyzed;

< = not detected above method detection limit; DC = Direct Contact; GW = Groundwater

J = concentration between detection limit and reporting limit; NE = Not Established;

PAHs = Polycyclic Aromatic Hydrocarbons; VOCs = Volatile Organic Compounds;

4 Metal concentrations above an RCL, but not noted as such on this table, are considered to be representative of background conditions in Wisconsin soils. Any exceedance

Exceeds the NR 720 Non-Industrial Direct Contact RCL: 100 Exceeds the NR 720 Industrial Direct Contact RCL: 100 Exceeds the NR 720 Groundwater Pathway RCL: 100 Exceeds the BTV: 100*

7/RiverXing2

(STR 145387)

11/4/15

1 NR 720 RCL = Chapter NR 720, Wisconsin Administrative Code, Residual Contaminant Level;

2RCLs & BTVs, PAHs, and VOCs are based on USEPA methodology; presented in WDNR Guidance, Soil RCL Determinations using USEPA Regional Screening Level Web Calculator (RR-890) and summarized in the WDNR's R&R Program RCL Spreadsheet (December 2018).

3Only detected analytes are listed; refer to the laboratory analytical report for a full list of assessed analytes

5RCLs for chromium reported as Chromium III/Chromium VI; based on property history, it is anticipated that chromium detected on the Property is Chromium III, and as such, sample result was not considered an exceedance of the RCL.

ATC - Ogden Street Networking Project6 Ogden SS1

(North of Ogden St SS)

7 Ogden SS2

(STR 142076)8/1 (STR 145388)

Waupaca Foundry Property - Fill Sampling Results Wisconsin Regulatory Standards1,2 11/3/15 11/3/15 11/2/15

Table 2 - Groundwater Sampling Analytical Test Results Summary

Sample Location

Sample Date

Filtration

Project Number: 1902287 CAS # NR 140 PAL1 NR 140 ES2 Discharge Limits Surcharge Limits Discharge LimitsGroundwater

Elevation (ft)

Indicator Parameters (µg/L - except for pH)

Oil and Grease NE NE 100,000 NE 100,000 - - - - - - <710 - - - - - - - - <710 - -

BOD NE NE None 275,000 200,000 - - - - - - 5,300 - - - - - - - - 6,100 - -

pH (Standard units) NE NE 6.0-9.0 NE NE 7.2 7.2

Total Suspended Solids NE NE None 355,000 250,000 - - - - - - 27,100 - - - - - - - - 32,600 - -

METALS (detected analytes) 3 ( µg /L)

Arsenic 7440-38-2 1 10 100 NE NE 627 16.1 27.9 21.0 16.0 20.3J 19.9 12.8J 10.1 14.6

Barium 7440-39-3 400 2,000 NE NE NE 332 - - 285 - - - - 270 - - 292 - - - -

Beryllium 7440417 0.4 4 NE NE 5 - - <0.18 - - <0.18 <0.18 - - <0.18 - - <0.18 <0.18

Cadmium 7440-43-9 0.5 5 140 NE 2,000 <1.3 <0.15 1.6J <0.15 <0.15 <1.3 <0.15 <1.3 <0.15 <0.15

Chromium5 16065-83-1/18540-29-9 10 100 2,410 NE 4,000 16 <1.0 20.4 2.0J <1.0 2.9J <1.0 20.4 <1.0 <1.0

Copper 7440508 130 1,300 1,400 NE 3,000 - - <1.1 - - 2.8J <1.1 - - <1.1 - - <1.1 <1.1

Lead 7439-92-1 1.5 15 2,020 NE 1,000 23.3 <0.24 798 67.8 1.1 12.9J <0.24 35.6 0.52J <0.24

Mercury 7439-97-6 0.2 2 10 NE 1 <0.13 <0.084 0.46 <0.084 <0.084 <0.13 <0.084 0.15J <0.084 <0.084

Nickel 7440020 20 100 1,350 NE 3,000 - - 0.73J - - 1.6 <0.40 - - <0.40 - - 0.76J 0.49J

Selenium 7782492 10 50 120 NE NE - - <0.32 - - 0.39J <0.32 - - <0.32 - - <0.32 <0.32

Silver 7440224 10 50 500 NE NE - - <0.10 - - <0.10 <0.10 - - <0.10 - - <0.10 <0.10

Zinc 7440666 2,500 5,000 2,250 NE 3,000 - - 6.4J - - 132 <4.6 - - <4.6 - - <4.6 <4.6

VOCs (detected analytes) 3 (µg/L)

Benzene 71-43-2 0.5 5 150 NE NE <0.50 - - 1.4 0.28J - - <0.50 - - <0.50 <0.25 - -

Bromomethane 74-83-9 1 10 NE NE NE <2.4 - - <2.4 1.3J - - <2.4 - - <2.4 1.2J - -

n-Butylbenzene 104-51-8 NE NE NE NE NE <0.50 - - 1.3 <0.71 - - <0.50 - - <0.50 <0.71 - -

Chlorobenzene 108-90-7 NE NE NE NE NE <0.50 - - 18.9 1.3J - - <0.50 - - <0.50 <0.71 - -

Chloromethane 74-87-3 3 30 NE NE NE <0.50 - - <0.50 6.4J - - <0.50 - - <0.50 7.8 - -

1,3-Dichlorobenzene 541-73-1 120 600 NE NE NE <0.50 - - 1.7 <0.63 - - <0.50 - - <0.50 <0.71 - -

Dichlorodifluoromethane 75-71-8 200 1,000 NE NE NE <0.22 - - 0.29J <0.50 - - <0.22 - - <0.22 <0.50 - -

Isopropylbenzene (Cumene) 98-82-8 NE NE NE NE NE <0.23 - - 5.0 <0.39 - - <0.14 - - <0.14 <0.39 - -

Styrene 100-42-5 10 100 NE NE NE <0.50 - - 5.8 <0.47 - - <0.50 - - <0.50 <0.47 - -

Toluene 108-88-3 160 800 150 NE NE <0.50 - - 4.7 <0.17 - - <0.50 - - <0.50 <0.17 - -

1,2,4-Trimethylbenzene 95-63-6 96 480 NE NE NE <0.50 - - 9.2 0.91J - - <0.50 - - <0.50 <0.84 - -

m&p-Xylene 1330-20-7 400 2,000 150 NE NE <1.0 - - 1.8J <0.47 - - <1.0 - - <1.0 <0.47 - -

Other Substances (µg/L)

Phenols 108952 400 2,000 25,000 NE NE - - - - - - <9.6 - - - - - - - - <9.6 - -

Phosphorus 7723140 NE NE None 8,000 NE - - - - - - 1900 - - - - - - - - 130J - -

Cyanide 57125 40 200 190 NE 1,000 - - - - - - 19J - - - - - - - - 26J - -

Notes

(µg/L) = micrograms per liter; -- = not analyzed;

< = not detected above method detection limit;

J = concentration between detection limit and reporting limit; NE = Not Established;

VOCs = Volatile Organic Compounds;

1 NR 140 PAL = Chapter NR 140, Wisconsin Administrative Code, Preventive Action Limit;

2 NR 140 ES = Chapter NR 140, Wisconsin Administrative Code, Enforcement Standard;

Exceeds NR 140 ES standards 100

Exceeds NR 140 PAL standards 100

Exceeds the City of Marinette Waste-Water Discharge Limits 150 Any exceedance

Exceeds the City of Menominee Waste-Water Discharge Limits 150

Groundwater samples were submitted for analyses based on established City of Marinette Waste-Water Discharge Limits (Code of Ordinances 7.02113 A) and VOCs.

Groundwater samples were sampled using low-flow techniques and were not field filtered.

Unfiltered groundwater samples submitted for metals analyses were not compared to NR 140 standards.

Not Filtered

S-MW

3Only detected analytes are listed; refer to the laboratory analytical report for a full list of assessed analytes

ATC - Ogden Street Networking Project

Waupaca Foundry - Groundwater Sampling Results

7.91 7.59

Wisconsin Regulatory Standards1,2 City of Marinette Waste-

Water Discharge Limits

City of Marinette Waste-

Water Surcharge Limits

City of Menominee Waste-

Water Discharge Limits

S-PZ S-MW

2/7/18

6.92

N-MW

7/10/19

Filtered

2.94

N-MW

7/2/19

2.35

Not Filtered

3.58

N-PZ N-MW

6.85

S-MW N-PZ

7/10/19

Filtered

3.11

Not Filtered

2/7/18 2/7/187/10/19

Filtered Not Filtered

S-PZ

7/10/19

Filtered

6.91 3.77

7/2/192/7/18

Not Filtered Not Filtered

Table 3 - PFAS Groundwater Sampling Analytical Test Results Summary

Sample

LocationTubing Blank S-MW (STR 145388) N-MW (STR 145387)

N-MW Duplicate (STR

145387)

Sample Date 7/2/19 7/2/19 7/2/19 7/2/19

Project Number: 1902287 CAS # NR 140 PAL1,4 NR 140 ES2,4 Non-Residential

Criteria3,4

Groundwater Surface Water

Interface Criteria3,4

Groundwater

Elevation (ft)NA 9.3 9.6 9.6

PFAS Compounds ( ng/L)

Perfluorobutanoic acid (PFBA) 375-22-4 NE NE NE NE <0.33 49 52 51

Perfluoropentanoic acid (PFPeA) 2706-90-3 NE NE NE NE <0.46 120 150 140

Perfluorohexanoic acid (PFHxA) 307-24-4 NE NE NE NE <0.54 110 140 150

Perfluoroheptanoic acid (PFHpA) 375-85-9 NE NE NE NE <0.23 32 100 98

Perfluorooctanoic acid (PFOA) 335-67-1 2 20 70 12,000 <0.79 110 1100 1000

Perfluorononanoic acid (PFNA) 375-95-1 NE NE NE NE <0.25 1.4J 6.8 6.6

Perfluorodecanoic acid (PFDA) 335-76-2 NE NE NE NE <0.29 0.98J 0.93 0.82J

Perfluoroundecanoic acid (PFUnA) 2058-94-8 NE NE NE NE <1.0 <1.0 <1.0 <0.99

Perfluorododecanoic acid (PFDoA) 307-55-1 NE NE NE NE <0.51 <0.50 <0.50 <0.49

Perfluorotridecanoic acid (PFTriA) 72629-94-8 NE NE NE NE <1.2 <1.2 <1.2 <1.2

Perfluorotetradecanoic acid (PFTeA) 376-06-7 NE NE NE NE <0.27 <0.27 <2.6 <0.26

Perfluorobutanesulfonic acid (PFBS) 375-73-5 NE NE NE NE <0.19 0.83J 1.9 1.9

Perfluoropentanesulfonic acid (PFPeS) 2706-91-4 NE NE NE NE <0.28 <0.27 1.2J 1.2J

Perfluorohexanesulfonic acid (PFHxS) 355-46-4 NE NE NE NE 0.30J* 3.3* 9.9* 9.7*

Perfluoroheptanesulfonic Acid (PFHpS) 375-92-8 NE NE NE NE <0.18 1.8 1.7J 1.8

Perfluorooctanesulfonic acid (PFOS) 1763-23-1 2 20 70 12 <0.50 200 20 21

Perfluorononanesulfonic acid (PFNS) 474511-07-4 NE NE NE NE <0.15 <0.15 <0.15 <0.14

Perfluorodecanesulfonic acid (PFDS) 335-77-3 NE NE NE NE <0.30 <0.29 <0.29 <0.29

Perfluorooctanesulfonamide (FOSA) 754-91-6 NE NE NE NE <0.33 1.5J <0.32 <0.31

N-methylperfluorooctanesulfonamidoacetic acid (NMeFOSAA) NE NE NE NE <2.9 <2.8 <2.8 <2.8

N-ethylperfluorooctanesulfonamidoacetic acid (NEtFOSAA) NE NE NE NE <1.8 32 <1.7 <1.7

4:2 FTS NE NE NE NE <4.9 <4.8 <4.8 <4.7

6:2 FTS NE NE NE NE <1.9 <1.8 12J 12J

8:2 FTS NE NE NE NE <1.9 <1.8 <1.8 <1.8

Notes

(ng/L) = micrograms per kilogram; -- = not analyzed; PFASs = Per- and Polyfluoroalkyl Substances;

< = not detected above method detection limit;

J = concentration between detection limit and reporting limit; NE = Not Established; NA= Not Applicable

1 Proposed NR 140 PAL = Chapter NR 140, Wisconsin Administrative Code, Preventive Action Limit;

2 Proposed NR 140 ES = Chapter NR 140, Wisconsin Administrative Code, Enforcement Standard;

³ Nonresidential Criteria = R 299.44, Department of Environment, Great lakes and Energy, Nonresidential Drinking Water Criteria (June 2018)

Exceeds the proposed NR 140 ES standards 100

Exceeds the proposed NR 140 PAL standards 100 Any exceedance

*Perfluorohexanesulfonic acid (PFHxS) was also detected in the laboratory's method blank.

ATC - Ogden Street Networking Project Proposed Wisconsin Regulatory

Standards1,2 Michigan Regulatory Standards³

Waupaca Foundry - Groundwater Sampling Results - PFAS



Appendix A

Historical Site Assessment Documentation

George E. Meyer SecretarY

August 22, 1994

Mr. Jeffery Loeffler Waupaca Foundry, Inc. Tower Road P.O. Box 249 Waupaca, WI 54981

Subject:

Dear Mr. Loeffler:

State of Wisconsin\ qEPARTMENT OF NATURAL RESOURCES

Lake Michigan District Headquarters IUS N. Military Avenue

P.O. Box 10448 Green Bay, WI 54307-0448

TELEPHONE I (414)491-5867 TELEFAX I (414)491-5913

F"ale Ref:Waupaca Foundry

Grant of Exemption to Construct a Second Foundry Plant Expansion (Plant No.4) on the Closed City of Marinette Landfill (Temporary ID# 378)

Tbe Departm,ent has completed its rev'ew of your exemption request to construct a second expansion to your Marinette Plant No. 4 on a. closed landfill. A similar request was made by Waupaca. Foundcy in. 1991. Based on our review ·of information you .submitted for this expansion th.e Department here within conditionally approves your exemption request. The expansion consists of :a melt department. addition~ a warehouse addition, and installation of sand stora.ge. tank :foundations. Construction of the expansion may contin.ue provided the conditions :in the enclosed grant of exemption are fulftlled .

Project History

On June 10 1994 STS Consultants Ltd. on be.half ·of Waupaca Foundry submitted a report ·entitled 11Request for an NR 504.07 Exemption for the P.roposed Waupaca Foundry, Inc., Plant No . . 4 Expansi,on Located in Marinette. Wisconsin ·· .. P.rior to this submittal the Department had conditionally issued ,grants. of exemption to Waupaca Foundry to construct a new office building and expansion of Plant No. 4 on the ·Closed City of Marinette landfill. Tl1e Department issued grants of exemption for these oonstnu::tion activities on March l5, 1991 and June u. 1'991 respectiv·ely. No ~excavation ·of solid waste was done for the new office co.nstruction. For the first Pianl No. 4 expansion all solid waste encountered which included municipal refuse, wood waste and construction debris was excavat·ed and disposed at. a proped y licensed solid waste facility. The closed City of Marinette landfill was used for municipal soUd waste disposal prior to 1970. Even eadier, me are.a was used :for disposal of wood waste from at least one saw mill

2.

operation. The existing foundry, Plant #4 was build in 1973. During this original construction, rubbish and fill materials were removed within the building area and backfilled with poorly graded sand material.

At present the site is fairly level with approximately three feet of vertical change throughout the site. To date, STS has performed four subsurface explorations to collect information on the fill and soil conditions at the site. For this proposed expansion, STS performed 14 additional borings during May of 1994. According to the most recent investigation results the fill and natural soils found in the proposed expansion area are similar to previous findings. Borings indicate gravel and sand fill at the surface. Below this material saw mill waste and refuse mixed with sand was encountered in 10 of the borings. Fill depth ranged between 8 and 13.5 feet below the existing surface. This is fairly consistent with previous fill depths. During the explorations groundwater was observed between 6 and 10 feet below ground surface.

Waupaca Foundry is proposing to construct several expansions to Plant No. 4 on the west and southwest sides of the existing facility. The expansions will occur in two phases. The melt department expansion is scheduled for construction this summer, while the warehouse addition and sand silo foundations is scheduled for 1995. Drawings of the warehouse and sand silo expansion have not yet been developed. It is estimatect that the warehouse expansion will cover approximately 13~500 square feet.

The melt department expansion will be approximately 18,000 square feet and consist of a single story, pre-fabricated metal building extension around the perimeter of the existing structure. To support this structure, a shallow foundation system is proposed for all areas. In able to support the proposed building by shallow foundation system, the existing fill materials will be removed in the melt department, warehouse and sand silo areas. The excavations will extend to the natural grayish-brown natural fine to course sands. All excavated solid waste will be disposed at an appropriate landfill. Wood waste and refuse will be separated from any reusable sand fill. Approximately 15,600 cubic yards of material will be excavated and disposed at a solid waste disposal facility. The sand will be reused as general backfill. The excavation will be backfilled with well graded material containing less than 15% passing the No. 200 sieve. Densification of the loose fill sand and loose natural sand subsoils. will be done by a process called "vibrofloatation". The vibrofloatation technique was used for the first plant expansion in 1991. Densification will extend to a depth of approximately 30 feet.

The Department believes that the use of the vibrofloatation process will not adversely impact the surrounding groundwater. The foundry is proposing the installation of a stormdrain collection system similar to the one installed for the previous expansion. This system includes asphalt pavement and green areas around the foundry expansions to help inhibit infiltration.

In addition, because all solid waste is being removed from the expansion area and based on the evaluation of potential landfill gas generation and/or migration by STS, the Department feels that a gas venting or vapor barrier is not necessary at this time. As proposed any utility trenches entering the proposed structures (dug in areas containing wood waste or refuse) will have a minimum 3-foot long clay plug as they enter the additions and also near the property lines to prevent the migration of gas through the trench bedding.

3.

The Department is conditionally granting an exemption to Waupaca Foundry to build on a closed landfill. In summary tile conditions are as follows: 1) all solid waste excavated shall be disposed of at a properly licensed landfill, 2) any sand fill proposed for reuse shall be tested to assure it is below the 10 ppm level, 3) a construction documentation report shall be submitted within 90 days of oompletlo.n of construction e¥ents, 4) the Department shall be notified prior to excavation/compaction activities in ·order to conduct an .inspection.

If you have any questions regarding this grant of exemption please call me at (414)492-5867.

Attachment

cc: Cindy Cook- SW/3 Len Polczinski - LMH Bruce Urben - LMH Stan Nogalski - Marinette Paul Blindauer - STS Consultants, Ltd., Green Bay

t

I

/.

BEFORE THE STATE OF WISCON~IN

DEPARTMENT OF NATURAL RESOURCES

CONDffiONAL GRANT OF EXEMPTION FOR WAUPACA FOUNDRY, INC.

TO CONSTRUCT AN SECOND EXPANSION TO PLANT NO. 4

The Department finds that:

ON A CLOSED LANDFILL IN MARINETTE, WI

FINDINGS OF FACT

1. On June 10, 1994 STS Consultants, Ltd. on behalf of Waupaca Foundry, Inc., submitted an exemption request for Department review for construction of a second expansion to Plant No. 4 on an closed landfill. The plan review fee of $500.00 was also submitted on June 10, 1994.

2. The construction will be located on the Old City of Marinette landfill (temporary license # 378), SE 1/4, SE/4, Section 5, T 30 N, R 24 E, Town of Peshtigo, Marinette County, Wisconsin.

3. The information submitted in conjunction with the request includes the following:

a. A June 10, 1994 report submitted to the Department by STS Consultants, Ltd. on behalf of Waupaca Foundry, Inc. entitled, "Request for an NR 504.07 Exemption for the Proposed Waupaca Foundry, Inc. Plant No. 4 Expansion Located in Marinette, Wisconsin'', including plan sheets.

b. A May 26, 1994 report submitted to the Department by STS Consultants, on behalf of Waupaca Foundry, Inc. entitled, "Subs~rface Exploration for the Waupaca Foundry Plant No.4 Melt Department and Stockroom Addition Projects in Marinette, Wisconsin".

c. A April 29, 1991 report submitted to the Department by STS Consultants, Ltd. on behalf of Waupaca Foundry, Inc. entitled, "Revised Request for an NR 504.07 Exemption for the Proposed Waupaca Foundry, Inc. Plant No. 4 Expansion Located in Marinette, Wisconsin".

4. Additional documents considered in connection with this exemption include:

a. An exemption granted by the Department to Waupaca Foundry, Inc. to construct an new office building on the closed City of Marinette landfill (temporary license # 378), dated March 15, 1991.

-

f.

2. J

,I

b. An exemption granted by the Department to Waupaca Foundry, Inc. to construct an expansion to Plant No. 4 on the closed City of Marinette landfill (temporary license # 378), date June 11, 1991.

c. Information available in WDNR files.

5. On July 13, 1994 the Department gave verbal approval to initiate construction activities for the proposed expansion project.

CONCLUSIONS OF LAW

The Department has the authority under 144.44, Stats and NR 506.08, Wis. Adm. Code, to appfovc an exemption request with special conditions if the conditions are needed to ensure compliance. with NR 500-520, Wis. Adm. Code. ·

The conditions of approval set forth below are needed to ensure compliance with NR 500-520, Wis. Adm. Code.

CONDITIONAL GRANT OF EXEMPTION

The Department has authority under s. l44.44. Stats. and NR 506.08, Wis. Adm. Code to grant an ,exemption for Waupaca Foundry Inc. to build a second expansion to Plant No. 4. on the closed City of Marinette landfill (temporary license #378) in Marinette, Wisconsin subject to compliance with NR :SD0-520, Wis. Adm. Codet and the following conditions:

1. Any solid waste excavated during construction shall be disposed at a licensed engineered landfill.

2. The sand fill which is to be excavated from the site and then reused as backfill shall be characterized to assure it does not contain any organics. The sand shall be measured with a photo-ionization detecto.r (PID) using a 10. 2 .lamp or similar instrument, once every 2000 feet with a minimum of two measurements being made. If the sand gives a PID reading o,f greater than 10 parts per million, the sand may not be used as bac.ktlll at the site and must be disposed at an licensed engineered landfill.

3. A oonstniction documentation report verifying and documenting all aspects of the approved report and the above conditions shall be prepared following completion of construction and submitted to, the Department within 90 days of this completion. Written Department approval of this report shall be obtained · before the expansion may be used. The report shall contain the following at a minimum:

a. A plan sheet (or sheets) documenting the location of all pertinent items.

b. A comprehensive narrative explaining how construction of the project was accomplished.

3. I

c. A series of 35 mm slides or color prints documenting all major aspects of the site construction.

d.. A appendix containing all raw data and analysis performed including clay testing results for the plugs in the utility lines and the PID readings performed on the excavated sand.

e. A letter under the seal of a registered professional engineer certifying that all required features .have been constructed in substantial compliance with the approved plans. Any deviations from the approved pJan sball be noted.

4. The Department · shall be notified at least one week in advance of the excavation/compaction activities that take place along the west and southwest sides of the existing building in order that an inspection may be performed. A construction inspection fee shall be submitted according to the fee schedule contained in NR 520, Wis. Adm. Code to the Lake Michigan office at the time the construction documentation report is submitted.

5. If conditions at the closed landfill are found to be different than described in the submitted report, Waupaca Foundry shall notify the Department before continuation of construction.

The Department retains the jurisdiction either to require the submittal of additional information or to modify this grant of exemption at any time if, in the Department's opinion, conditions warrant further modifications.

NOTICE OF APPEAL RIGHTS

If you believe that you have a right to challenge this decision, you should know that Wisconsin statutes and administrative rules establish time periods within which requests to review Department decisions must be filed ..

For judicial review of a decision pursuant to sections 227.52 and 227.53, Stats., you have 30 days after the decision is mailed, or otherwise served by the Department. Such a petition for judicial review shall name the Department of Natural Resources as the respondent.

This notice is provided pursuant to section 227.48(2), Stats.

Dated: fJ~-:?!), $£' DEPARTMENT OF NATURAL RESOURCES

Forilie~

Joc:fr! Brand Industrial Waste Specialist Lake Michigan District

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WAUPACA FOU~mRY INC. ~AER"L

MEMO from Jeff Loeffler TO: DATE:

SUBJECT:

M. Arvey, Jeff Zeratsky August 20, 1999

City Sampling for Water Main

The City of Marinette ground water and soil analysis for the borings which were done as part of the water main project did not show any concentrations greater than state standards. Please see attached STS memo.

Let me know if you have any questions. X-1966

-

MEMORANDUM

DATE: August 17, 1999

TO: Mr. Jeff Loeffler Waupaca Foundry, Inc.

FROM: Ms. Paula Leier-Engy.\har~s40.g Mr. Roger Miller Q~N iV'e, STS ConsuJtants, Ltd.

RE: Review of Analytical Test Results Related to the City of Marinette Water Main Installation on the Waupaca Foundry Plant 4 Property in Mari.nette, Wisconsin- STS Project No. 17559XA

Based on our discussions and tabulated analytical test results you sent us, we understand that

HNTB collected six soil samples from two soil borings and two groundwater samples from two

monitoring wells for laboratory analysis. You requested that STS review these results and

provide you with our opinion regarding how these results compare with existing standards (in

Wisconsin Administrative Code and WDNR Guidance). As we discussed, based on our review ·

of the lab results presented by HNTB, metals and polycyclic aromatic hydrocarbons (P AHs) soil

concentrations were found not to exceed applicable residual contaminant levels (RCLs) (barium,

mercury, PARs) or typical background conditions (arsenic). No volatile organic compounds

(VOCs) were detected in the six soil samples analyzed. Accordingly, in our opinion, residual

soil concentrations do not pose an unacceptable threat to human health or the environment. This

memo provides a summary of our evaluation of the testing data along with the development of

site-specific RCLs (SSRCLs) as allowed under s. NR 720.19, Wisconsin Administrative Code.

Polynuclear Aromatic Hydrocarbons <PAID Residual Contaminant Levels CRCLs)

Eighteen PAHs were detected in the soi l sample collected from 3-5 feet in Boring SB006 at

concentrations ranging from 25 micrograms per kilogram (l!glkg) (acenaphthene) to 640 ).1g/kg

1 17S59XA(M459AOO I.DOC)

benzo(a)pyrene (BaP). The historical use of the property (former landfill) suggests that the

presence of these compounds is not unusual. Burning at landfills was a common practice in the

past.

When compared to suggested generic RCLs in the WDNR's Soil Cleanup Levels for Polycyclic

Aromatic Hydrocarbons (P AHs)-Jnterim Guidance (WDNR Publication RR-5 19-97 dated April

1997), benzo(a)anthracene, benzo(b)fluoranthene, dibenz(a,h)anthracene, and indeno(1,2,3-

cd)pyrene exceed their respective soil ingestion suggested generic non-industrial RCLs. BaP

(640 ~1g/kg) exceeds its soil ingestion suggested generic industrial RCL (390 ~glkg). SSRCLs

which are protective for non-industrialland use could be calculated for the five P AHs that exceed

their soil ingestion suggested generic RCLs. However, the highest SaP concentration exceeds

the non-industrial or industrial SSRCL which could be calculated using exposure assumptions

approved by the WDNR. Accordingly, an alternative approach to develop SSRCLs was used.

Instead of calculating SSRCLs for individual P AHs, the BaP-equivalent concentration for the

PAH mixture was calculated for comparison to the non-industrial SaP-equivalent RCL from the

WDNR's PAR Guidance.

To avoid a cleanup action which may be undertaken where the cumulative risk for the P AH

mixture may not warrant it, the SaP-equivalent concentration approach is often used at sites

where I or 2 P AHs exceed suggested generic direct contact RCLs or SSRCLs. The BaP

equivalent concentration approach involves conversion of the measured PAH concentrations to

an equivalent concentration of BaP based on the toxic potency of each PAH relative to BaP. As

shown of the attached table, each P AH concentration is multiplied by its relative potency factor

which, when the adjusted P AH concentrations are added together, yields a concentration for the

total PAH mixture as an equivalent concentration ofBaP. A RCL based onBaP-equivalent

concentration is then developed using the risk-based algorithm for carcinogenic compounds

(Appendix B ofWDNR's PAH Guidance), the cancer slope factor for BaP, and the cumulative

excess cancer risk of I x 10'5 as specified ins. NR 720.11(3), Wisconsin Administrative Code.

As presented on the attached calculation, the total BaP-equivalent soil concentration (0.89

mg/kg) does not exceed the BaP-equivalent non-industrial RCL of0.9 mglkg. The method for

2 17SS9XA(M4S9AOO t.DOC}

calculating the SaP-equivalent non-industrial RCL is presented in Appendix D of the WDNR's

P AH Guidance.

MetalsRCLs

Direct contact SSRCLs were calculated for two metals (barium, mercury) which were detected

but which do not have generic RCLs in s.NR 720.11 (2). As allowed is s.NR 720.19(5) I,

Wisconsin Administrative Code, the hazard quotient was adjusted to one (1) for the non

industrial SSRCL calculations. In addition, because the surface soils are frozen for

approximately four months out of the year, the exposure frequency was reduced from 350 to 250

days per year. Although SSRCL calculations for industrial sites are also included for

comparison, we selected the SSRCLs for non-industrial sites as the direct contact SSRCLs for

barium and mercury.

Although barium has a reference concentration published in the EPA's Health Effects

Assessment Summary Tables (HEAST), this metal is not reported to be of concern for inhalation

of vapors. Accordingly, the volatilization factor portion of the soil inhalation algorithm was not

used for calculating the barium soil inhalation SSRCL. Because mercury is reported to be of

concern for inhalation of vapors, the volatilization portion of the. soil inhalation algorithm was

used to calculate the mercury soil inhalation SSRCL. For the mercury soil ingestion SSRCL

calculation, we used the bealth criteria for methyl-mercury because mercury is typically

transformed into its organic form in soils.

As summarized on the attached table (Soil Laboratory Testing Results for Metals), the direct

contact SSRCLs are several orders of magnitude greater than the highest residual metal

concentrations. Therefore, barium and mercury concentrations do not exceed a hazard quotient

of one for non-carcinogens in accordance with s.NR 720.19(5)1, Wisconsin Administrative

Code.

3 17559XA(M459A00l.DOC)

Arsenic was detected in four out of the six soil samples analyzed at concentrations ranging from

1.4 to 3.9 mg/kg. While three out of the four arsenic detections exceed the generic industrial

direct contact RCL in NR 720 (1.6 mglkg), it is our opinion that arsenic concentrations are

representative of background conditions. Arsenic concentrations detected at depth in SB005

(18-20 feet) and SB006 (23-25 feet) are similar to arsenic concentrations detected at shallower

depths (3-5 feet) in these borings. ln accordance with s.NR 720.1 1 (5), Wisconsin Administrative

Code, if the background concentration for a substance in soil is higher than its RCL, the

background concentration may be used as the RCL for that substan.ce.

No SSRCL was calculated for silver because this metal was only reported in one soil boring at

the deepest sample interval (presumably in native soil [SB006, 23-25 feet]) at a low

concentration (0.1 mglkg) slightly above its detection limit.

Groundwater Results

Groundwater samples were collected from MW-1 and MW-2 for metals, biological oxygen

demand (BOD), oil and grease, phenolics, and total suspended solids (fSS) analysis. Arsenic,

cadmium, chromium, cyanide, lead, mereury, selenium, and silver were not detected. Barium

was detected in both wells below its NR 140 preventive action limit. Other parameters tested do

not have public health groundwater quality standards in NR 140. HNTB also compared test

results to Marinette and Menominee pretreatment standards. The TSS sample from Monitoring

Well MW-1 (23,000 mgll) reportedly exceeds the Marinette and Menominee pretreatment

standards of350 and 250 mgll , respectively. No other pretreatment standard exceedances were

noted in the test results.

4 l7SS9XA(M4S9AOO l.DOC)

-

Attachments:

Benzo(a)pyrene-equivalent Residual Contaminant Level (RCL) Calculation

Soil Laboratory Testing Results for Metals

Site-Specific Residual Contaminant Level (SSRCL) Calculation Input Parameters

Barium Soil Ingestion Calculation

Barium Soil Inhalation Pathway Calculation

Methyl Mercury Soil Ingestion Pathway Calculation

Mercury (as vapor) Soil Inhalation Pathway Calculation

5 17559XA(M459AOO!.DOC)

Benzo(a)pyrenHquivalent Residual Contaminant Level (RCL) Calculation Waupa<2 Foundry

Marinette, Wisconsin

Compound Highest Relative BaP..,,Conc. Soil Potency Carcinogenic All Detected

Cone. Factor PAHs PAHs (mg/kg) (mJ!I]<g) (m•lko)

PAH Acenophthene O.D2S 0.001 0.000025 Aeenophthylene 0.099 0.001 0.000099 Anthracene 0.180 0.01 0.0018 Bcnzo(a)anthracene 0.480 0.1 0.048 0.048 Benzo(a)pyrene 0.640 I 0.64 0.64 Benzo(b)fluoranthcnc 0.540 0.1 0.054 0.054 Benzo(k)Ouoranthcne 0.270 0.01 0.0027 0.0027 Benzo(ghi)perylene 0.450 0.01 0.0045 Chyscne 0.430 0.001 0.00043 0.00043 Dibenzo(a,h)anthrncene 0.110 I 0.11 0.11 Fluoranthene 0.710 0.001 0.00071 Fluorene 0.064 0.001 0.000064 I ndeno{ 1 ,2,3-ed)pyrene 0.280 0.1 0.028 0.028 1-Methylnapbthalene 0.270 0.001 0.00027 2-Methylnapbthalene 0.420 0.001 0.00042 Naphthalene 0.350 0.001 0.00035 Phenanthrene 0.430 0.001 0.00043 l'yrene 0.520 0.001 0.00052

Subtotal PAris 6.268 Total SaP-equivalent 0.88313 0.8923

Bew.o(a)Pyrcne (BaP)-equivalent non-industrial soil ingestion RCL using Equation B

from the WDNRPAH Guidance Document and a combined target risk of I x 10"' is:

(1 x 10-5) x70x365

Ra= =09mgjkg ( 7Jx 10--6) X 350 X 114 .

Note:

Residual PAF! concenlnl.tions (as Total BaP-equivalen~ 0.892 mg./kg) do not exceed the BaP-cquivalent non-industrial RCL of0.9 mg./kg.

Calculated by: Roger A. Miller (814.199)

A .J~ o.(l 1 'i 'I Checked by: \¥ o :>'\:

I

Soil Laboratory Tuting Results for Mecals Waupaca Foundry

Marinette, Wisconsin

SB005 SB005 SB005 SB006 3.0'- 5.0' 18.0'- 20.0' 23.0'- 25.0' 3.0'- 5.0' 6/30/99 6/30/99 6130/99 6130199

Arsenic 3.9 1.8 <0.9 1.9 Barium 39 15 5.3 19 Cadmium 0.34 <0.088 <0.079 0.25 Chromium 8.4 7.5 3.7 5.9 Lead 22 1.8 1.2 14 Mercury 0.026 <0.0061 <0.0074 0.03 Selenium <1.3 <1.3 <1.2 <1.2 Silver <0.082 <0.084 <0.015 <O.Q7~ _

Notes: I) Concentrations given in milligrams per kilogram (mglkg). 2) Generic Residual Contaminant Levels (RCLs) a.rc from s.NR 720.11 {2),

Wisconsin Administtative Code (dated Februacy 1997). 3) ING. • Soil Ingestion

INH. = Soillnbalation

SB006 23.0' - 25.0'

6/30/99 1.4 II

<0.079 3.9 J.S

<0.0069 <1.2 0.1

SB006 33.0' - 35.0'

6/30/99 <0.91 8.5

0.094 4.4 2.4

<0.0079 <1.2

<0.076

Sice-Spcc:i.flc RCLs Generic RCLs Non-1ndustrinl Non-Industrial lnduscrinl

lNG. INH. lNG. lNG.

- - 0.039 1.6 7,670 521,000 - -

- - 8 510 - - 16,000 NA - - 50 500 II IS - -- - - -- -- -- --

Y;proiccu\J7$W..O\T4.$9'XAOOI:dt.

•

I

Site-Specific Residual Conta minant Level (SSRCL) Calculation Input Pa.rameters Waupacn Foundry MarlneUt, Wisconsin STS Project No. I 1S59XA

- SFo SFi RID Rlt: maih·dovr' Sooon:e (ma/1«-clavr' Source (mlih-clay] SOurce (IIIJ/m'J Sooorcc

Mttall Barhnn 7.01!-0Z I $.0E-04 2 Mereury. clcmenlal 3.0£.04 I MemorY (mclhvl) I.Oil-04 __ I_

---·-

NOTE; I) AbbrCYlaUou ror RCl.. chemical fa te pa.ramtters .ad lllr:•ltb c:rirula arc chnn~ on rhr: ulruhuloa Jhttts.

SOURCE&

K.. H' _Mg) Soun:c (unidas) SOurce

4.67&01 3

I) EPA (US. EnvironmentAl PrOltciMMs Agency). 1998. ln1cgr.u.ed Risk Information Sysrem (IRIS). Omce ofSoiMJ WaslC 1nd Emergency Rnponso, Washington. D.C. O...linc daoa._, avait>hlelluou&h TOXNET. Nllio<lal Libtlly of Mcdi<ine.ll<lhcsda. Matyland.

2) EPA (U.S. EnvironmentJI Proccclion A&enty). 1997t. Hcallh Effero AIX!Smcnt Summary Tables (II EAST). fY -1997 AMu.l Update. (and Update to Annwd} Office or Emers. and Remedial Response. Washinaron. D.C.

0. (cm1/!1_ Sow-ce

3.07E·OZ 3

3) I!PA (U.S. l!nviroomc-ntal rrorcerion A_gc:oey). 1996. Soil Screening Ouldonc;c: Tec.hnical81l(kground Ootumclil. Offi¢e or Solid Waslc.-and Bmcrgcncy Response, Washlnslcm, D.C.

Ow

Jcm'~- Source

6.l0E·06 3

t

Barium Soil Ingestion Pathway (RID)

Waupaca Foundry Marinette, Wisconsin

Algorithm for Ingestion of Noncarcinogenic Contaminants in Non-Ind ustrial (Residential) Soil

Parameter Value Source THQ- Target Hazard Quotient (unit less) I WDNR Default Value BWc- Average Body Weight for Child (kg) 15 WDNR Default Value AT- Averaging Time (years) 6 WDNR Default Value RfDo - Oral Reference Dose (mglkg-day) 7.0E-02 I EF - Exposure Frequency (day/year) 250 Frost-Free Days (Est.) EDc- Exposure Duration During Ages 1-6 (year) 6 WDNR Default Value IRe -Ingestion Rate of Soil Age 1-6 (mglday) 200 WDNR Default Value

Residual Contaminant Level (mg/kg) = THO x BWc x AT x 365 day/vear e l 7670 I 1/RfDo x I 0 .. kg/rug x EF xED x IRe

.

Algorithm for Ingestion of Noncarcinogenic Contaminants in Industrial Soil

Parameter Value THQ- Target Hazard Quotient (unitless) I BWa -Average Body Weight For Adult (kg) 70 AT - Averaging Time (years) 25 RfDo - Oral Reference Dose (mg/kg-day) ?.OE-02 EF - Exposure Frequency (day/year) 250 ED - Exposure Duration (year) 25 IRa- Ingestion Rate for Adult (me/day) 100

Residual Contaminant Level (mg/kg) = THO x BWa x AT x 365 day/vear

Calculated by: Roger Miller &14/99

Checked by: Jtf '</11 1~~ Note:

1/RfDo X l 0 .. kg/mg x EF X ED x IRa

See list of references for numbered source citations.

Source WDNR Default Value WDNR Default Value WDNR Default Value I WDNR Default Value WDNR Default Value WDNR Default Value

~ I 71500 I

Barium

Soil Inhalation Pathway (RfC)

Waupaca Foundry Marinctcc, Wiscon.sin

AlJerillua for l_n.b~l.aho~tofNoncxrrlMtffllc: C...t.•llunts r,.. l'ien-IDdustrW (Rrsidaubl) Stil

P•n.me-kt Volw Sourtr: ntQ • Tarscc Huan:l Quotict~t (urmlw) 1 WDNR Ocf•ull Val\110 AT- Avttqing Time (rtan) 30 WDNR Dcfalllt Value R.OC • Retttcncc Coo(entntioa (loJim') l .OE41 l EF • Uposure fre~ney (d11ylyclll) llO Fro,r-frM Days (Est.) EO • &cp»'ilrC Ou.ratlOft (year) 30 WDNR Ddaull Voluc

VF • Vo~liUza!iOil Factor (kalm ') NA C3kulation

leo- Concec~.nttoo o(Pric1c:slc:s.s Ibn 10 wt1 (ulllm'l 1.4 W'Cr\1\ DefauJI Value

Residual Ccm:amillao"'t Lnd tm&"c) - lH9;xATxJ6S~ -I mooo 1/lUCx ETA EDx ((Cpx 10•qtl'£))

A~ridw ror lahab..iiMI•f Neocs~ C.•taaiuDIJ •• ladiiiSutal SoU

p.,•attn Voluc Sou= rnQ. T.,.. """"'Qoai<ol C"'"""'l I W!)Sk Ddall v .... AT·A~Tim.c(ydi'S) ll ¥iD~"'R Ocbulc Vahu

M: ·Ra"""eCooc ....... (lap') l.OE-04 2

El' ·Ex ...... f"'!'""Y(,..y/ye><) 2$0 W'D"SR Odaoh: VafiJC EX>· Ex~ Duntioa (ycv) ll WDSR Dc!auh V•tu:r

[Rc: • Wlaluloo be CorteedOI\ for Adlllcl..abom (unitlm) l.l WDXR Oc£aull Val~c:

VY • VolatiliVL:ion Fxoor(m'nca) 1-!A Catcubtion Co . ConcentnUIOtl ofP.nidc$ lr:u 1han 10 ••luJ'.Im'1 ••• WDNR Dc(auJt V~tluc

llt:ddllal Coota:ninMt Level (ml¢rr:1) - n1Q x AT x )6j dam:·:ar - I IIlli!: x EF xED •IRe • ((Cpx 10• IQII~J))

4JSOOO

VQLriliutioo Fxtor ( .. ,A:J} - Q1C a ().14 .11 D.-,aT)1n x JO~m=/em2 -I NA

2•~ao,.

o.., (cn~:h«) - ((t.'"'DJf • 8. '"'o.Y.'l -I NA ~ ......... e.H'

ra ...... mr """' s. .... ()'C • ltn'ft'K MUD Coac:ta:lndoa aa NA

c ... ,., or s-ee (Jim'.,..Y(!<J'to') o,. .. AWV'«'I Di~ (em1J~) NA

T • Ex.posu" Intervals (sec) NA p., • Soil Dry Bulk Ocos.ity (Jicm 1) NA 9,. Air Filltd Porosity (c:m1/cm1) NA 0, · Air Di!f\I.Jion Coc:fficie:n1 (cm1Jioec:) NA H' .. Henry's Law CQCIJtant (W'Iit!e:s.s) NA o ... Volumetric Sot! Motsntrc Conlcftl (cm11c.:'1111) NA D .. • Wat.et Di.ffv.sioft Coefficient (crn1/Kc) NA

o ·ToW $oil Potasiry (cm'lcml) NA K, • Soil;Watcr Discn'btrtico Cod!"'.Om1 (l.lk".&) NA K, . Orpoic c..t>ac:w..,. P>mdoolq Codl'ld"" (lA&) NA t.. Soil-Orpoie Catlooo (&II) NA

Cobl>«d by: R.occ' >filln II-Cheeke411y: ~Q. <f/u!~ 1 riote: Sec list orn:rci"C':occs for num~tcd sot.~rce clratkiM.

-

I

I

I

I

Methyl Mercury Soil Ingestion Pathway (RID)

Waupaca Foundry Marinette, Wisconsin

Algorithm for Ingestion of Noncarcinogen ic Contaminants in Non-Industrial (Residential) Soil

Parameter Value Source THQ- Target Hazard Quotient (unitless) I WDNR Oefauh Value BWc- Average Body Weigbt for Child (kg) 15 WDNR Default Value AT- Averaging Time (years) 6 WDNR Default Value RfOo - Oral Reference Dose (mglkg-day) I.OE-04 I

EF- Exposure Frequency (day/year) 250 Frost-Free Days {Est.) EOc- Exposure Duration During Ages 1-6 (year) 6 WDNR Default Value IRe: -Ingestion Rate of Soil Age 1-6 (mglday) 200 WDNR Default Value

Residual Contaminant Level (mglkg) • THO x BWc: x AT x 365 daylvear =I 11 I 1/RfOo X 10-4 1\g/mg x EF X ED x IRe

.

Algorithm for Ingestion of Noncarcinogenic Contaminants in Industrial Soil

Pnrameter Value THQ- Target Hazard Quotient (unitless) 1 8Wa- Average Body Weight For Adult (kg) 70 AT- Averaging Time (years) 25 RJDo -Oral Reference Dose (mglkg-day) I.OE-04 EF- Exposure Frequency (day/year) 250 EO - Exposure Duration (year) 25 IRa- Ingestion Rate for Adult (mglday) 100

Residual Contaminant Level (mglkg) • THO x BWa x AT x 365 dav/vear

Calculated by: Roger MiUer 8/4/99

Checked by: j£.1- ~/ t t ~~~ Note:

1/RJDo x l0-4kglmg X EF x EO x IRa

Su list or references for numbered source citations.

Source WDNR Default Value WDNR Default Value WONR Default Value I WDNR Default Value WDNR Default Value WDNR Default Value

al 102 I

-

Mercury (as vapor) Soil Inhalation Pathway (RfC)

·"''"''""'I ~me {yean) Rcrc:tc:nee C'Mctntralion (mafm~

ExpoJure Fre:qaectC)' (dly/)'cu) • EXposure Duradoo (year)

VF ·Volatilization f actor (k&.lm,)

Waupaca Foundry Mannt:tte:, Wiscoosin

niOxATx)65d~Jvlycu .j IS

1/IUC a EF • ED x((IIVF)• (Cp• IO.I:&'I'&ll

A...,.;o& '""'()"an) Rci«CC<C Con«•m•loa (mp ')

IEF ·Exp<>••<f'«qo<OCJ (doylycv) Exposure Dluatioo (year)

• ln.hal:arioo. Rate- Comcdoo f« Ad~o~lt Ubotn {\!altius)

- Volatllizalioo Ft~etor (m'As)

n.cqxATx36Sdaylyeat .j 11

111\JC a Eh l!Ox Ill< x ((I/VF) • (Cp • 10• ka/,.1))

• QICx(l.l4xDAxl)tnxiO""abcm' •I J.Jl£+44

la P\XDA

.. c .. "'ors-..w-.' .... ~aim'l Appatt:~l l>i.B'ilsMry (c:nbscc) ~posute lntt't'VJk (sec)

-Soil Ory Sulk Detuity (at em')

AirFiUcd PorositY (cm,/c:mJ) DUTu.sioo Coefficient (cmJ/.ec)

Hecry's Law CoostAtlt (ul\itlcn) [a •• v ., l.,oco;d;o.lMoistu«C'oncenc (em,tcm')

- Wa:cr Oiffiuioo Coc!&dent (cm,/MC)

TOll! SoiJ Porosiry (cn:~'tcm')

((9, ""o,K • e. "'D.Y.'J ...x.•a.•e.K

• Soii:Wafr.' Disci~Mion Coc:Mcie~~1 (lA:a)

II<,·U'P"l<c.-Waf<1Pani ... ;.1 Cod!l<i<OI(UI<a)

- Orpol< c:.1Joo (Sri)

Col .. lal<d by: Rotu Mill" 11<199

Cbe<hdby: J&~ f/,,1,, Note: SH lbl otrcJr:rencu lor aumbtrtd aourcr chadoru.

-1 1.'1£.45

....

__ 07/28 / 1999 ~3: ~6 _F.U .:!!..4 35u 315

11270 Wtsl Parle Place One Parle Plaza, Suite 500 Milwaukee WI 53224

HNTB CORPORATION laJOOl

Telephone Number (414) 359-2300 Fax Telephone Number (4l4) 359-2315

1ob Number 30 I l.. 'i .-::..~-=-.!..-.---

Deliver to: Name: M \ 1(. e: A JE:fl..:-4,

Firm:

Fax No:

From: ~ , "-' S ·~ €"! cA

Total number of pages transmitted (including this cover sheet): ~

Comments:

M, \¥-. E: I .

lt-l..~ AiJ~l.'I.Ttc..At..... 'l-€::!:>uLI~ '<..:...; i:..e.~0t"S~tl A-.t..E"

SvMMAt..l~E"D 0~-> T,.H:: ArrA'-'"'0::"0 \4-f,t..E~. 5o,._ SAM. fL.£::.

VE-s•"-!~.4.TCD S"~Cool.. .AIJt> T\-\e \.J ~~ '5~,...~ 1..£. "Desl~t.lA~

M w-O"Z.. W£"9-~ ~ .......... e.<...~ z:,,.., r-.. u~'I>L'\ ?~tcPCL~.

-r~£" L..Ae,o~A-Ttlt-'\ ~ e.Po~T \<;, Too LE:..:JE,~'( To f=A~ 1

07128/1999 13:46 ~ti ~14 359 2J1S

SAMPLE ID $8005 DEPTH(ft) 3-5

DATE SAMPLED 6/30/99 PARAMETER ORO 7.3 GAO <3.3

BNTB CO.BfORATION

TABLE 1 ORO/GAO in Soil

Site Jnvestlgat!on Marinette River Crossing

! $8005 . SBOOS I 18-20 ! 23-25

SB006 3-5

$8006 ! 23-25

I 6/30/99 I 6/30/99 6/30/99 . 6/30/99 ! I

<5.0 I <4.3 ' 38 ' <4.3 ' I <3.4 <3.0 <3.0 <2.9 I

Note: Concentrations given In milligrams per kilogram (mglkg).

' .. , ..

laioo2

S8006 33-35

6/30/99

<4.0 <3.1

07/ 28 / 1999 1J:47 F.~ 414 359 2315 BNTB CORPORATION

TA6LE2 VOC$ in Soli

Site Investigation Marinette River Ctontng

urit=Jglkg

SA""'~'u )5 ~ iOOS 581 fOS 1·20 23-25·

DATE~~~; a 0199 ;J ~H

: : : <25 <25 <25 <25 <25 <25 <25 <2:5 <2~ <25 <25 <25 <25 <2.5 <25 <25 <25 <25 <25 <25 <2S

.Cor~ Tolr>CNot!dt <25 <25 45 <25 <2S <25 <25 <25 <25 .as <25 <25 <2.5 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 •2S <25 <25 <25 .as <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25

olso l <25 <25 <25 ...... <25 <25 <25

~·-· <25 <25 <25 .2·0ichloroprop0lne <25 <25 <2S ,I·OO:hlotocti\Me • <25 <25 <25 ,3-0ichlorop.rop<~~te <25 <25 <25

-· <25 <25 <25 <25 <25 .as

""·' <25 <25 <25 ·' <25 <25 <25

<25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <2S

; Clllori:._ <25 <25 <25 <2S <25 <25 <25 <25 <25 .as <25 <25 <25 <25 <25

):~:~: <25 <25 <25 <25 <25 <25 <25 <25 <2l>

""""'"' <25 <25 <25 ,2.~TriehJorob.I\111M &5 <25 <25 ,2.4--Tric.l'llotoben.tene <ZS <25 <25 , 1,1-TrichlatoOihDJHi <25 <25 <25 • 1 2 · T richlorocth 0110 45 <25 <25 .. , <25 <25 <IS

<25 <25 <25

• <25 <25 <25 ' .... <25 <25 <25 ~~yfl <25 <25 <25

<25 : : lx,lan•. • <25

!qJ 00~

58006 $8006 5800,

3·5 23-25 33-3!

<25 <25 : <25 <25 <25 <25 45 <2S <25 <25 <25 <2:5 <25 dS <25 <25 <25 .as <25 <25 <2S <25 <25 <25 <25 <25 <25 <2S <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 c2S'•. ·. .<25 .as <25 <25 <2S <25 <25 <25 <25 <25 <25 <25 <25 <25 .as <25 <25 <25 <25 <25 <25 <2S <25 .as <25 <25 <25 .as <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 . <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <2S <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <2S <25 <25 .as <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <2S <25 <2S <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <2$ <25 <25 <25 <25 <25 <25 <25 <2S <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25

: ~ ~

07 / 28 / 1999 13:~7 ~~1 414 359 2315 IJNTB CQJIPORATION

SAMPLE 10 OEPTH(tt)

OA TE SAMPLED PARAMETER

Acenaphlhene Acenaphthytene Anthracene Benzo(a)anthracene Senzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,l)perylene Benzo(k)fluoranthene Chrysene Oibenzo(k)Ouoranthene Fluoranthane Fluorene ldeno(1 ,2,3·cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pvrene

TABLE 3 PAHs In Soli

Site Investigation Marinette River Crossing

88005 88005 SB005 3·5 18-20 23·25

6/30/99 6/30/99 6/30/99

<17 <18 <16 <20 <20 <18 <19 <19 <17 27 <20 <18 26 <18 <16 26 <20 <18 21 <21 <19 28 <20 <18 25 <20 <18 21 <21 <19 40 <18 <16 <18 <18 <16 <21 <21 <19 <19 <20 <18 <17 <18 <16 <21 <22 <19 19 <17 <15 33 <20 <18

Note: Concentration's given In micrograms per kilogram (uglkg).

~004

SB006 SB006 SB006 3·5 23·25 33·35

6/30/99 6/30/99 6/30/99

25 <15 <16 99 <17 <18

180 <16 <17 480 <17 <18 640 <15 <16 540 <17 <18 270 <18 <19 450 <17 <18 430". . <17 <18

' 110 <18 <19 710 <16 <17 64 <16 <17

280 <18 <19 270 <17 <16 420 <15 <16 350 <15 <15 430 <15 <15 520 <17 <18

07 / 28/ 1999 ll: 48 l'.il 4H 359 2315 HNTB CQRPORATION

' ::.: ·J': --·· ... .::. .. ~

SAMPLE IC OEPTH(ft)

DATE SAMPLED PARAMETER Arsenic Barium Cadmium Chromium lead Mercury Selenium Silver

Table 4 Metals In Soil


SB005 88005 88005 3-5 18-20 23-25

6/30/99 6/30/99 6/30/99

3.9 1.8 <0.9 39 15 5.3

0.34 <0.088 <0.079 8.4 7.5 3.7 22 1.8 1.2

0.026 <().0061 <0.0074 <1 .3 <1.3 <1.2

<0.082 <0.084 <0.075

Note: Concentrations given in miligrams per kllogram (mglkg).

88006 3-5

6/30/99

1.9 19

0.25 5.9 14

0.03' .

<1.2 <0.075

~oos

SB006 88006 23-25 33-35

6/30/99 6/30/99

1.4 <0.91 11 8.5

<0.079 0.094 3.9 . 4.4 1.5 2.4

<0.0069 <0.0079 <1.2 <1'.2 0.1 <0.076

· . ..

07/ 28/ 1999 13:~8 F.\1 ~14 359 2315 HN'l'B.J;ORPORA Tl ON

Table 5

Groundwater Characterization Results

SAMPLE LOCATION

DATE SAMPLEJ: PARAMETER Units

Arsenic ug/1 Barium Ug/1 BOO mg/1 Cadmium ug/1 Chromium ug/1 Cyanide mg/1 Lead ug/1 Mercury ug/1 Oil and Grease mg/1 Phenolics mg/1 Phosphorus rngl1 Selenium ugll Silver ug/1 Total Suspended Solids mg/1

Notes


MW-01 MW-02 WDNA 6/30/99 6130/99 PAL

<6.8 <6.8 5 150 220 400 6.9 15 <.50 <.50 0.5 <.53 <.53 10

<.0047 <.0047 40 <2.8 <2.8 1.5

<0.042 <0.042 0.2 0.1 0.1

0.006 <.0043 0.62 <.21 <8.7 <8.7 10 <0.6 <0.6 10 2300 94

a) TSS concentrations above this limit will be subject to a surcharge b) Based on typical pre-treatment requirements

Marinette

Preteatment

Standard

100 NL 300 140

2410 190 2020 10 100 25

. ·. ~ .. 14 .. 5 120 500 sso•

141006

Menomonee

Pretreatment Standard"

100 2000 4000 1000 1000

non-detect 100

250



Appendix B

WDNR SHWIMS Database Information

WONR SHWIMS on the Web Navl.gaflon: SOTW Home>> BaaloC Searcn :-:- Search Reeurta >:> l ocation Detail

WAUPACA FOUNDRY INC PL T 4 Facility Name

!Facility Name

I WAUPACA FOUNDRY INC PLT 4

IFacil ily Slatus IIFID

loPERAnNG 11<38041450

I Physical Address f ind oo Goook was 1805 OGDEN ST

!Mailing Address

1805 OGDEN ST

GenerallnformatEon

IiEPA ll

II WI0066457301

IIMunicil>alily

II MARINETTE

II city

II MARINETTE

II county

II MARINEITE

II SIC Code

11 3321

II state

II state

IIWDNR RegM>n

II NORTHEAST REGION

IINAICSCode

1133151

II ZiP

!Facility Owner Type II Public l and Survey System Oesc. II Latitude and Longitude

IPRNATE II NOT AVAILABLE II NOT AVAILABLE

Facil1ty Owner(s)

I THYSSEN KRUPP AG PO BOX249 WAUPACA. '1M 5498·1

I THYSSENKRUPP WAUPACA PLANT 4 PO BOX 249 WAUPACA. VVI 5498·1

I WAUPACA FOUNDRY INC 1955 BRUNNER OR WAUPACA. '1M 5498·1

~ ~c:.tial ~ silt:blhe~~dNIIkniResol.roes 101 S Websler&ted PO Boot 7921 Yaclisclr'l. ~"53107·7921 _ 608.266.2821 dnr.wi.gcw

WONR SHWIMS on the Web

070 Landfill unclassified SHWlMS on the Web· Waste Activity Details

I Activity Code and Name

I 070 Landfill unclassified

I Original II Original Approval Date .. Lteense Date

General Information

II II

Cl::~~ II

Activity Status

INACTIVE

Closure Ltr. Received Date

&iJ ~c:.tial ~ silt:blhe~~dNIIkniResol.roes 101 S Websler SRd PO Boot 7921 Macliscltl. 'W\sccnsiro 53107·7921 _ 808.266.2821

dnr.Wi.gcw

l icense Number

WA

Actual Closure Date

License Status

NIA

Status Changed Date

11/t612016



Appendix C

AECOM – 2015 Subsurface Assessment Documentation

GEI Consultants, Inc.

2015 - AECOM Fill Sampling

Laboratory Report

Geotechnical Boring Logs


Laboratory Report

#=CL#

November 24, 2015

LIMS USE: FR - LEOLIMS OBJECT ID: 40124373

40124373Project:Pace Project No.:

RE:

Leo B. Linnemanstons, P.G.AECOM, Inc. - Madison1350 Deming WaySuite 100Middleton, WI 53562

60344843 U73

Dear Leo Linnemanstons, P.G.:Enclosed are the analytical results for sample(s) received by the laboratory on November 09, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Christopher [email protected] Manager

Enclosures

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9

Green Bay, WI 54302(920)469-2436

Page 1 of 44

#=CP#

CERTIFICATIONS

Pace Project No.:Project:

4012437360344843 U73

Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334Virginia VELAP ID: 460263

North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Virginia VELAP ID: 460263Virginia VELAP Certification ID: 460263Wisconsin Certification #: 405132750


without the written consent of Pace Analytical Services, Inc..


Green Bay, WI 54302(920)469-2436

Page 2 of 44

#=AR#

ANALYTICAL RESULTS


4012437360344843 U73

Sample: 6 OGDEN SS1 2.5-4.0 Lab ID: 40124373004 Collected: 11/03/15 10:00 Received: 11/09/15 14:05 Matrix: SolidResults reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualLODLOQ

Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP

Arsenic 37.2 mg/kg 11/20/15 14:13 7440-38-211/17/15 13:0118.7 5.9 10Barium 10.1 mg/kg 11/19/15 19:10 7440-39-311/17/15 13:010.47 0.11 1Cadmium <1.2 mg/kg 11/23/15 08:31 7440-43-9 D311/17/15 13:019.3 1.2 20Chromium 593 mg/kg 11/20/15 14:13 7440-47-311/17/15 13:014.7 1.8 10Lead 18.6 mg/kg 11/20/15 14:13 7439-92-111/17/15 13:019.3 4.0 10Selenium 8.0J mg/kg 11/20/15 14:13 7782-49-2 D311/17/15 13:0118.7 7.2 10Silver 4.5J mg/kg 11/20/15 14:13 7440-22-4 D311/17/15 13:019.3 2.6 10

Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury

Mercury 0.0052J mg/kg 11/18/15 11:43 7439-97-611/17/15 09:060.0095 0.0028 1

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM

Acenaphthene <9.0 ug/kg 11/17/15 11:12 83-32-911/16/15 09:5518.1 9.0 1Acenaphthylene <8.1 ug/kg 11/17/15 11:12 208-96-811/16/15 09:5518.1 8.1 1Anthracene <9.4 ug/kg 11/17/15 11:12 120-12-711/16/15 09:5518.1 9.4 1Benzo(a)anthracene 7.5J ug/kg 11/17/15 11:12 56-55-311/16/15 09:5518.1 6.3 1Benzo(a)pyrene 7.5J ug/kg 11/17/15 11:12 50-32-811/16/15 09:5518.1 6.5 1Benzo(b)fluoranthene 9.3J ug/kg 11/17/15 11:12 205-99-211/16/15 09:5518.1 9.0 1Benzo(g,h,i)perylene <6.9 ug/kg 11/17/15 11:12 191-24-211/16/15 09:5518.1 6.9 1Benzo(k)fluoranthene <10.0 ug/kg 11/17/15 11:12 207-08-911/16/15 09:5518.1 10.0 1Chrysene 9.3J ug/kg 11/17/15 11:12 218-01-911/16/15 09:5518.1 8.4 1Dibenz(a,h)anthracene <6.6 ug/kg 11/17/15 11:12 53-70-311/16/15 09:5518.1 6.6 1Fluoranthene 14.0J ug/kg 11/17/15 11:12 206-44-011/16/15 09:5518.1 9.0 1Fluorene <9.0 ug/kg 11/17/15 11:12 86-73-711/16/15 09:5518.1 9.0 1Indeno(1,2,3-cd)pyrene <6.9 ug/kg 11/17/15 11:12 193-39-511/16/15 09:5518.1 6.9 11-Methylnaphthalene 14.4J ug/kg 11/17/15 11:12 90-12-0 B11/16/15 09:5518.1 9.0 12-Methylnaphthalene 21.5 ug/kg 11/17/15 11:12 91-57-6 B11/16/15 09:5518.1 9.0 1Naphthalene 24.8 ug/kg 11/17/15 11:12 91-20-311/16/15 09:5518.1 9.0 1Phenanthrene 15.1J ug/kg 11/17/15 11:12 85-01-811/16/15 09:5518.1 9.0 1Pyrene 11.6J ug/kg 11/17/15 11:12 129-00-011/16/15 09:5518.1 9.0 1Surrogates2-Fluorobiphenyl (S) 62 % 11/17/15 11:12 321-60-811/16/15 09:5539-130 1Terphenyl-d14 (S) 61 % 11/17/15 11:12 1718-51-011/16/15 09:5537-130 1

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B8260 MSV Med Level Normal List

1,1,1,2-Tetrachloroethane <25.0 ug/kg 11/12/15 03:40 630-20-6 W11/11/15 13:5860.0 25.0 11,1,1-Trichloroethane <25.0 ug/kg 11/12/15 03:40 71-55-6 W11/11/15 13:5860.0 25.0 11,1,2,2-Tetrachloroethane <25.0 ug/kg 11/12/15 03:40 79-34-5 W11/11/15 13:5860.0 25.0 11,1,2-Trichloroethane <25.0 ug/kg 11/12/15 03:40 79-00-5 W11/11/15 13:5860.0 25.0 11,1-Dichloroethane <25.0 ug/kg 11/12/15 03:40 75-34-3 W11/11/15 13:5860.0 25.0 11,1-Dichloroethene <25.0 ug/kg 11/12/15 03:40 75-35-4 W11/11/15 13:5860.0 25.0 11,1-Dichloropropene <25.0 ug/kg 11/12/15 03:40 563-58-6 W11/11/15 13:5860.0 25.0 11,2,3-Trichlorobenzene <25.0 ug/kg 11/12/15 03:40 87-61-6 W11/11/15 13:5860.0 25.0 11,2,3-Trichloropropane <25.0 ug/kg 11/12/15 03:40 96-18-4 W11/11/15 13:5860.0 25.0 11,2,4-Trichlorobenzene <47.6 ug/kg 11/12/15 03:40 120-82-1 W11/11/15 13:58250 47.6 1


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ANALYTICAL RESULTS


4012437360344843 U73




1,2,4-Trimethylbenzene <25.0 ug/kg 11/12/15 03:40 95-63-6 W11/11/15 13:5860.0 25.0 11,2-Dibromo-3-chloropropane <91.2 ug/kg 11/12/15 03:40 96-12-8 W11/11/15 13:58250 91.2 11,2-Dibromoethane (EDB) <25.0 ug/kg 11/12/15 03:40 106-93-4 W11/11/15 13:5860.0 25.0 11,2-Dichlorobenzene <25.0 ug/kg 11/12/15 03:40 95-50-1 W11/11/15 13:5860.0 25.0 11,2-Dichloroethane <25.0 ug/kg 11/12/15 03:40 107-06-2 W11/11/15 13:5860.0 25.0 11,2-Dichloropropane <25.0 ug/kg 11/12/15 03:40 78-87-5 W11/11/15 13:5860.0 25.0 11,3,5-Trimethylbenzene <25.0 ug/kg 11/12/15 03:40 108-67-8 W11/11/15 13:5860.0 25.0 11,3-Dichlorobenzene <25.0 ug/kg 11/12/15 03:40 541-73-1 W11/11/15 13:5860.0 25.0 11,3-Dichloropropane <25.0 ug/kg 11/12/15 03:40 142-28-9 W11/11/15 13:5860.0 25.0 11,4-Dichlorobenzene <25.0 ug/kg 11/12/15 03:40 106-46-7 W11/11/15 13:5860.0 25.0 12,2-Dichloropropane <25.0 ug/kg 11/12/15 03:40 594-20-7 W11/11/15 13:5860.0 25.0 12-Chlorotoluene <25.0 ug/kg 11/12/15 03:40 95-49-8 W11/11/15 13:5860.0 25.0 14-Chlorotoluene <25.0 ug/kg 11/12/15 03:40 106-43-4 W11/11/15 13:5860.0 25.0 1Benzene 67.1 ug/kg 11/12/15 03:40 71-43-211/11/15 13:5865.1 27.1 1Bromobenzene <25.0 ug/kg 11/12/15 03:40 108-86-1 W11/11/15 13:5860.0 25.0 1Bromochloromethane <25.0 ug/kg 11/12/15 03:40 74-97-5 W11/11/15 13:5860.0 25.0 1Bromodichloromethane <25.0 ug/kg 11/12/15 03:40 75-27-4 W11/11/15 13:5860.0 25.0 1Bromoform <25.0 ug/kg 11/12/15 03:40 75-25-2 W11/11/15 13:5860.0 25.0 1Bromomethane <69.9 ug/kg 11/12/15 03:40 74-83-9 W11/11/15 13:58250 69.9 1Carbon tetrachloride <25.0 ug/kg 11/12/15 03:40 56-23-5 W11/11/15 13:5860.0 25.0 1Chlorobenzene <25.0 ug/kg 11/12/15 03:40 108-90-7 W11/11/15 13:5860.0 25.0 1Chloroethane <67.0 ug/kg 11/12/15 03:40 75-00-3 W11/11/15 13:58250 67.0 1Chloroform <46.4 ug/kg 11/12/15 03:40 67-66-3 W11/11/15 13:58250 46.4 1Chloromethane <25.0 ug/kg 11/12/15 03:40 74-87-3 W11/11/15 13:5860.0 25.0 1Dibromochloromethane <25.0 ug/kg 11/12/15 03:40 124-48-1 W11/11/15 13:5860.0 25.0 1Dibromomethane <25.0 ug/kg 11/12/15 03:40 74-95-3 W11/11/15 13:5860.0 25.0 1Dichlorodifluoromethane <25.0 ug/kg 11/12/15 03:40 75-71-8 W11/11/15 13:5860.0 25.0 1Diisopropyl ether <25.0 ug/kg 11/12/15 03:40 108-20-3 W11/11/15 13:5860.0 25.0 1Ethylbenzene 40.9J ug/kg 11/12/15 03:40 100-41-411/11/15 13:5865.1 27.1 1Hexachloro-1,3-butadiene <25.0 ug/kg 11/12/15 03:40 87-68-3 W11/11/15 13:5860.0 25.0 1Isopropylbenzene (Cumene) <25.0 ug/kg 11/12/15 03:40 98-82-8 W11/11/15 13:5860.0 25.0 1Methyl-tert-butyl ether <25.0 ug/kg 11/12/15 03:40 1634-04-4 W11/11/15 13:5860.0 25.0 1Methylene Chloride <25.0 ug/kg 11/12/15 03:40 75-09-2 W11/11/15 13:5860.0 25.0 1Naphthalene <40.0 ug/kg 11/12/15 03:40 91-20-3 W11/11/15 13:58250 40.0 1Styrene <25.0 ug/kg 11/12/15 03:40 100-42-5 W11/11/15 13:5860.0 25.0 1Tetrachloroethene <25.0 ug/kg 11/12/15 03:40 127-18-4 W11/11/15 13:5860.0 25.0 1Toluene 94.2 ug/kg 11/12/15 03:40 108-88-311/11/15 13:5865.1 27.1 1Trichloroethene <25.0 ug/kg 11/12/15 03:40 79-01-6 W11/11/15 13:5860.0 25.0 1Trichlorofluoromethane <25.0 ug/kg 11/12/15 03:40 75-69-4 W11/11/15 13:5860.0 25.0 1Vinyl chloride <25.0 ug/kg 11/12/15 03:40 75-01-4 W11/11/15 13:5860.0 25.0 1cis-1,2-Dichloroethene <25.0 ug/kg 11/12/15 03:40 156-59-2 W11/11/15 13:5860.0 25.0 1cis-1,3-Dichloropropene <25.0 ug/kg 11/12/15 03:40 10061-01-5 W11/11/15 13:5860.0 25.0 1m&p-Xylene <50.0 ug/kg 11/12/15 03:40 179601-23-1 W11/11/15 13:58120 50.0 1n-Butylbenzene <25.0 ug/kg 11/12/15 03:40 104-51-8 W11/11/15 13:5860.0 25.0 1n-Propylbenzene <25.0 ug/kg 11/12/15 03:40 103-65-1 W11/11/15 13:5860.0 25.0 1




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ANALYTICAL RESULTS


4012437360344843 U73




o-Xylene <25.0 ug/kg 11/12/15 03:40 95-47-6 W11/11/15 13:5860.0 25.0 1p-Isopropyltoluene <25.0 ug/kg 11/12/15 03:40 99-87-6 W11/11/15 13:5860.0 25.0 1sec-Butylbenzene <25.0 ug/kg 11/12/15 03:40 135-98-8 W11/11/15 13:5860.0 25.0 1tert-Butylbenzene <25.0 ug/kg 11/12/15 03:40 98-06-6 W11/11/15 13:5860.0 25.0 1trans-1,2-Dichloroethene <25.0 ug/kg 11/12/15 03:40 156-60-5 W11/11/15 13:5860.0 25.0 1trans-1,3-Dichloropropene <25.0 ug/kg 11/12/15 03:40 10061-02-6 W11/11/15 13:5860.0 25.0 1SurrogatesDibromofluoromethane (S) 118 % 11/12/15 03:40 1868-53-711/11/15 13:5849-157 1Toluene-d8 (S) 106 % 11/12/15 03:40 2037-26-511/11/15 13:5861-148 14-Bromofluorobenzene (S) 99 % 11/12/15 03:40 460-00-411/11/15 13:5853-134 1

Analytical Method: ASTM D2974-87Percent Moisture

Percent Moisture 7.9 % 11/10/15 16:440.10 0.10 1




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ANALYTICAL RESULTS


4012437360344843 U73




Arsenic 7.1 mg/kg 11/19/15 19:13 7440-38-211/17/15 13:013.2 1.0 1Barium 20.2 mg/kg 11/19/15 19:13 7440-39-311/17/15 13:010.79 0.19 1Cadmium 0.14J mg/kg 11/19/15 19:13 7440-43-911/17/15 13:010.79 0.10 1Chromium 10 mg/kg 11/19/15 19:13 7440-47-311/17/15 13:010.79 0.31 1Lead 18.3 mg/kg 11/19/15 19:13 7439-92-111/17/15 13:011.6 0.68 1Selenium <1.2 mg/kg 11/19/15 19:13 7782-49-211/17/15 13:013.2 1.2 1Silver 0.80J mg/kg 11/19/15 19:13 7440-22-411/17/15 13:011.6 0.44 1


Mercury 0.019 mg/kg 11/18/15 11:50 7439-97-611/17/15 09:060.015 0.0045 1


Acenaphthene <13.9 ug/kg 11/17/15 14:17 83-32-911/16/15 09:5527.7 13.9 1Acenaphthylene <12.4 ug/kg 11/17/15 14:17 208-96-811/16/15 09:5527.7 12.4 1Anthracene 19.5J ug/kg 11/17/15 14:17 120-12-711/16/15 09:5527.7 14.4 1Benzo(a)anthracene 43.8 ug/kg 11/17/15 14:17 56-55-311/16/15 09:5527.7 9.6 1Benzo(a)pyrene 43.2 ug/kg 11/17/15 14:17 50-32-811/16/15 09:5527.7 9.9 1Benzo(b)fluoranthene 44.4 ug/kg 11/17/15 14:17 205-99-211/16/15 09:5527.7 13.9 1Benzo(g,h,i)perylene 47.6 ug/kg 11/17/15 14:17 191-24-211/16/15 09:5527.7 10.6 1Benzo(k)fluoranthene 34.2 ug/kg 11/17/15 14:17 207-08-911/16/15 09:5527.7 15.3 1Chrysene 50.9 ug/kg 11/17/15 14:17 218-01-911/16/15 09:5527.7 12.8 1Dibenz(a,h)anthracene <10.2 ug/kg 11/17/15 14:17 53-70-311/16/15 09:5527.7 10.2 1Fluoranthene 71.2 ug/kg 11/17/15 14:17 206-44-011/16/15 09:5527.7 13.9 1Fluorene <13.9 ug/kg 11/17/15 14:17 86-73-711/16/15 09:5527.7 13.9 1Indeno(1,2,3-cd)pyrene 24.2J ug/kg 11/17/15 14:17 193-39-511/16/15 09:5527.7 10.5 11-Methylnaphthalene 147 ug/kg 11/17/15 14:17 90-12-011/16/15 09:5527.7 13.9 12-Methylnaphthalene 205 ug/kg 11/17/15 14:17 91-57-611/16/15 09:5527.7 13.9 1Naphthalene 160 ug/kg 11/17/15 14:17 91-20-311/16/15 09:5527.7 13.9 1Phenanthrene 110 ug/kg 11/17/15 14:17 85-01-811/16/15 09:5527.7 13.9 1Pyrene 62.6 ug/kg 11/17/15 14:17 129-00-011/16/15 09:5527.7 13.9 1Surrogates2-Fluorobiphenyl (S) 64 % 11/17/15 14:17 321-60-811/16/15 09:5539-130 1Terphenyl-d14 (S) 67 % 11/17/15 14:17 1718-51-011/16/15 09:5537-130 1






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1,2,4-Trimethylbenzene <25.0 ug/kg 11/12/15 04:02 95-63-6 W11/11/15 13:5860.0 25.0 11,2-Dibromo-3-chloropropane <91.2 ug/kg 11/12/15 04:02 96-12-8 W11/11/15 13:58250 91.2 11,2-Dibromoethane (EDB) <25.0 ug/kg 11/12/15 04:02 106-93-4 W11/11/15 13:5860.0 25.0 11,2-Dichlorobenzene <25.0 ug/kg 11/12/15 04:02 95-50-1 W11/11/15 13:5860.0 25.0 11,2-Dichloroethane <25.0 ug/kg 11/12/15 04:02 107-06-2 W11/11/15 13:5860.0 25.0 11,2-Dichloropropane <25.0 ug/kg 11/12/15 04:02 78-87-5 W11/11/15 13:5860.0 25.0 11,3,5-Trimethylbenzene <25.0 ug/kg 11/12/15 04:02 108-67-8 W11/11/15 13:5860.0 25.0 11,3-Dichlorobenzene <25.0 ug/kg 11/12/15 04:02 541-73-1 W11/11/15 13:5860.0 25.0 11,3-Dichloropropane <25.0 ug/kg 11/12/15 04:02 142-28-9 W11/11/15 13:5860.0 25.0 11,4-Dichlorobenzene <25.0 ug/kg 11/12/15 04:02 106-46-7 W11/11/15 13:5860.0 25.0 12,2-Dichloropropane <25.0 ug/kg 11/12/15 04:02 594-20-7 W11/11/15 13:5860.0 25.0 12-Chlorotoluene <25.0 ug/kg 11/12/15 04:02 95-49-8 W11/11/15 13:5860.0 25.0 14-Chlorotoluene <25.0 ug/kg 11/12/15 04:02 106-43-4 W11/11/15 13:5860.0 25.0 1Benzene <25.0 ug/kg 11/12/15 04:02 71-43-2 W11/11/15 13:5860.0 25.0 1Bromobenzene <25.0 ug/kg 11/12/15 04:02 108-86-1 W11/11/15 13:5860.0 25.0 1Bromochloromethane <25.0 ug/kg 11/12/15 04:02 74-97-5 W11/11/15 13:5860.0 25.0 1Bromodichloromethane <25.0 ug/kg 11/12/15 04:02 75-27-4 W11/11/15 13:5860.0 25.0 1Bromoform <25.0 ug/kg 11/12/15 04:02 75-25-2 W11/11/15 13:5860.0 25.0 1Bromomethane <69.9 ug/kg 11/12/15 04:02 74-83-9 W11/11/15 13:58250 69.9 1Carbon tetrachloride <25.0 ug/kg 11/12/15 04:02 56-23-5 W11/11/15 13:5860.0 25.0 1Chlorobenzene <25.0 ug/kg 11/12/15 04:02 108-90-7 W11/11/15 13:5860.0 25.0 1Chloroethane <67.0 ug/kg 11/12/15 04:02 75-00-3 W11/11/15 13:58250 67.0 1Chloroform <46.4 ug/kg 11/12/15 04:02 67-66-3 W11/11/15 13:58250 46.4 1Chloromethane <25.0 ug/kg 11/12/15 04:02 74-87-3 W11/11/15 13:5860.0 25.0 1Dibromochloromethane <25.0 ug/kg 11/12/15 04:02 124-48-1 W11/11/15 13:5860.0 25.0 1Dibromomethane <25.0 ug/kg 11/12/15 04:02 74-95-3 W11/11/15 13:5860.0 25.0 1Dichlorodifluoromethane <25.0 ug/kg 11/12/15 04:02 75-71-8 W11/11/15 13:5860.0 25.0 1Diisopropyl ether <25.0 ug/kg 11/12/15 04:02 108-20-3 W11/11/15 13:5860.0 25.0 1Ethylbenzene <25.0 ug/kg 11/12/15 04:02 100-41-4 W11/11/15 13:5860.0 25.0 1Hexachloro-1,3-butadiene <25.0 ug/kg 11/12/15 04:02 87-68-3 W11/11/15 13:5860.0 25.0 1Isopropylbenzene (Cumene) <25.0 ug/kg 11/12/15 04:02 98-82-8 W11/11/15 13:5860.0 25.0 1Methyl-tert-butyl ether <25.0 ug/kg 11/12/15 04:02 1634-04-4 W11/11/15 13:5860.0 25.0 1Methylene Chloride <25.0 ug/kg 11/12/15 04:02 75-09-2 W11/11/15 13:5860.0 25.0 1Naphthalene <40.0 ug/kg 11/12/15 04:02 91-20-3 W11/11/15 13:58250 40.0 1Styrene <25.0 ug/kg 11/12/15 04:02 100-42-5 W11/11/15 13:5860.0 25.0 1Tetrachloroethene <25.0 ug/kg 11/12/15 04:02 127-18-4 W11/11/15 13:5860.0 25.0 1Toluene 50.7J ug/kg 11/12/15 04:02 108-88-311/11/15 13:5899.9 41.6 1Trichloroethene <25.0 ug/kg 11/12/15 04:02 79-01-6 W11/11/15 13:5860.0 25.0 1Trichlorofluoromethane <25.0 ug/kg 11/12/15 04:02 75-69-4 W11/11/15 13:5860.0 25.0 1Vinyl chloride <25.0 ug/kg 11/12/15 04:02 75-01-4 W11/11/15 13:5860.0 25.0 1cis-1,2-Dichloroethene <25.0 ug/kg 11/12/15 04:02 156-59-2 W11/11/15 13:5860.0 25.0 1cis-1,3-Dichloropropene <25.0 ug/kg 11/12/15 04:02 10061-01-5 W11/11/15 13:5860.0 25.0 1m&p-Xylene <50.0 ug/kg 11/12/15 04:02 179601-23-1 W11/11/15 13:58120 50.0 1n-Butylbenzene <25.0 ug/kg 11/12/15 04:02 104-51-8 W11/11/15 13:5860.0 25.0 1n-Propylbenzene <25.0 ug/kg 11/12/15 04:02 103-65-1 W11/11/15 13:5860.0 25.0 1




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Sample: 8/1 7.5-9.0 Lab ID: 40124373006 Collected: 11/02/15 12:20 Received: 11/09/15 14:05 Matrix: SolidResults reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.



Arsenic 5.8 mg/kg 11/18/15 20:12 7440-38-211/18/15 08:322.2 0.69 1Barium 38.7 mg/kg 11/18/15 20:12 7440-39-3 M011/18/15 08:320.54 0.13 1Cadmium 0.32J mg/kg 11/18/15 20:12 7440-43-911/18/15 08:320.54 0.072 1Chromium 8.4 mg/kg 11/18/15 20:12 7440-47-311/18/15 08:320.54 0.21 1Lead 56.7 mg/kg 11/18/15 20:12 7439-92-111/18/15 08:321.1 0.47 1Selenium <0.84 mg/kg 11/18/15 20:12 7782-49-211/18/15 08:322.2 0.84 1Silver 0.42J mg/kg 11/18/15 20:12 7440-22-411/18/15 08:321.1 0.30 1


Mercury 0.035 mg/kg 11/18/15 11:52 7439-97-611/17/15 09:060.010 0.0030 1


Acenaphthene 43.1 ug/kg 11/18/15 15:53 83-32-911/13/15 09:1318.1 9.0 1Acenaphthylene 35.9 ug/kg 11/18/15 15:53 208-96-811/13/15 09:1318.1 8.1 1Anthracene 91.9 ug/kg 11/18/15 15:53 120-12-711/13/15 09:1318.1 9.4 1Benzo(a)anthracene 130 ug/kg 11/18/15 15:53 56-55-311/13/15 09:1318.1 6.3 1Benzo(a)pyrene 140 ug/kg 11/18/15 15:53 50-32-811/13/15 09:1318.1 6.5 1Benzo(b)fluoranthene 116 ug/kg 11/18/15 15:53 205-99-211/13/15 09:1318.1 9.0 1Benzo(g,h,i)perylene 76.8 ug/kg 11/18/15 15:53 191-24-211/13/15 09:1318.1 6.9 1Benzo(k)fluoranthene 127 ug/kg 11/18/15 15:53 207-08-911/13/15 09:1318.1 10.0 1Chrysene 151 ug/kg 11/18/15 15:53 218-01-911/13/15 09:1318.1 8.4 1Dibenz(a,h)anthracene 29.4 ug/kg 11/18/15 15:53 53-70-311/13/15 09:1318.1 6.6 1Fluoranthene 288 ug/kg 11/18/15 15:53 206-44-011/13/15 09:1318.1 9.0 1Fluorene 67.4 ug/kg 11/18/15 15:53 86-73-711/13/15 09:1318.1 9.0 1Indeno(1,2,3-cd)pyrene 70.1 ug/kg 11/18/15 15:53 193-39-511/13/15 09:1318.1 6.9 11-Methylnaphthalene 68.0 ug/kg 11/18/15 15:53 90-12-011/13/15 09:1318.1 9.0 12-Methylnaphthalene 102 ug/kg 11/18/15 15:53 91-57-611/13/15 09:1318.1 9.0 1Naphthalene 268 ug/kg 11/18/15 15:53 91-20-311/13/15 09:1318.1 9.0 1Phenanthrene 210 ug/kg 11/18/15 15:53 85-01-811/13/15 09:1318.1 9.0 1Pyrene 239 ug/kg 11/18/15 15:53 129-00-011/13/15 09:1318.1 9.0 1Surrogates2-Fluorobiphenyl (S) 61 % 11/18/15 15:53 321-60-811/13/15 09:1339-130 1Terphenyl-d14 (S) 58 % 11/18/15 15:53 1718-51-011/13/15 09:1337-130 1






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1,2,4-Trimethylbenzene <25.0 ug/kg 11/12/15 05:10 95-63-6 W11/11/15 13:5860.0 25.0 11,2-Dibromo-3-chloropropane <91.2 ug/kg 11/12/15 05:10 96-12-8 W11/11/15 13:58250 91.2 11,2-Dibromoethane (EDB) <25.0 ug/kg 11/12/15 05:10 106-93-4 W11/11/15 13:5860.0 25.0 11,2-Dichlorobenzene <25.0 ug/kg 11/12/15 05:10 95-50-1 W11/11/15 13:5860.0 25.0 11,2-Dichloroethane <25.0 ug/kg 11/12/15 05:10 107-06-2 W11/11/15 13:5860.0 25.0 11,2-Dichloropropane <25.0 ug/kg 11/12/15 05:10 78-87-5 W11/11/15 13:5860.0 25.0 11,3,5-Trimethylbenzene <25.0 ug/kg 11/12/15 05:10 108-67-8 W11/11/15 13:5860.0 25.0 11,3-Dichlorobenzene <25.0 ug/kg 11/12/15 05:10 541-73-1 W11/11/15 13:5860.0 25.0 11,3-Dichloropropane <25.0 ug/kg 11/12/15 05:10 142-28-9 W11/11/15 13:5860.0 25.0 11,4-Dichlorobenzene <25.0 ug/kg 11/12/15 05:10 106-46-7 W11/11/15 13:5860.0 25.0 12,2-Dichloropropane <25.0 ug/kg 11/12/15 05:10 594-20-7 W11/11/15 13:5860.0 25.0 12-Chlorotoluene <25.0 ug/kg 11/12/15 05:10 95-49-8 W11/11/15 13:5860.0 25.0 14-Chlorotoluene <25.0 ug/kg 11/12/15 05:10 106-43-4 W11/11/15 13:5860.0 25.0 1Benzene <25.0 ug/kg 11/12/15 05:10 71-43-2 W11/11/15 13:5860.0 25.0 1Bromobenzene <25.0 ug/kg 11/12/15 05:10 108-86-1 W11/11/15 13:5860.0 25.0 1Bromochloromethane <25.0 ug/kg 11/12/15 05:10 74-97-5 W11/11/15 13:5860.0 25.0 1Bromodichloromethane <25.0 ug/kg 11/12/15 05:10 75-27-4 W11/11/15 13:5860.0 25.0 1Bromoform <25.0 ug/kg 11/12/15 05:10 75-25-2 W11/11/15 13:5860.0 25.0 1Bromomethane <69.9 ug/kg 11/12/15 05:10 74-83-9 W11/11/15 13:58250 69.9 1Carbon tetrachloride <25.0 ug/kg 11/12/15 05:10 56-23-5 W11/11/15 13:5860.0 25.0 1Chlorobenzene <25.0 ug/kg 11/12/15 05:10 108-90-7 W11/11/15 13:5860.0 25.0 1Chloroethane <67.0 ug/kg 11/12/15 05:10 75-00-3 W11/11/15 13:58250 67.0 1Chloroform <46.4 ug/kg 11/12/15 05:10 67-66-3 W11/11/15 13:58250 46.4 1Chloromethane <25.0 ug/kg 11/12/15 05:10 74-87-3 W11/11/15 13:5860.0 25.0 1Dibromochloromethane <25.0 ug/kg 11/12/15 05:10 124-48-1 W11/11/15 13:5860.0 25.0 1Dibromomethane <25.0 ug/kg 11/12/15 05:10 74-95-3 W11/11/15 13:5860.0 25.0 1Dichlorodifluoromethane <25.0 ug/kg 11/12/15 05:10 75-71-8 W11/11/15 13:5860.0 25.0 1Diisopropyl ether <25.0 ug/kg 11/12/15 05:10 108-20-3 W11/11/15 13:5860.0 25.0 1Ethylbenzene 29.1J ug/kg 11/12/15 05:10 100-41-411/11/15 13:5865.1 27.1 1Hexachloro-1,3-butadiene <25.0 ug/kg 11/12/15 05:10 87-68-3 W11/11/15 13:5860.0 25.0 1Isopropylbenzene (Cumene) <25.0 ug/kg 11/12/15 05:10 98-82-8 W11/11/15 13:5860.0 25.0 1Methyl-tert-butyl ether <25.0 ug/kg 11/12/15 05:10 1634-04-4 W11/11/15 13:5860.0 25.0 1Methylene Chloride <25.0 ug/kg 11/12/15 05:10 75-09-2 W11/11/15 13:5860.0 25.0 1Naphthalene 98.0J ug/kg 11/12/15 05:10 91-20-311/11/15 13:58271 43.4 1Styrene <25.0 ug/kg 11/12/15 05:10 100-42-5 W11/11/15 13:5860.0 25.0 1Tetrachloroethene <25.0 ug/kg 11/12/15 05:10 127-18-4 W11/11/15 13:5860.0 25.0 1Toluene 45.4J ug/kg 11/12/15 05:10 108-88-311/11/15 13:5865.1 27.1 1Trichloroethene <25.0 ug/kg 11/12/15 05:10 79-01-6 W11/11/15 13:5860.0 25.0 1Trichlorofluoromethane <25.0 ug/kg 11/12/15 05:10 75-69-4 W11/11/15 13:5860.0 25.0 1Vinyl chloride <25.0 ug/kg 11/12/15 05:10 75-01-4 W11/11/15 13:5860.0 25.0 1cis-1,2-Dichloroethene <25.0 ug/kg 11/12/15 05:10 156-59-2 W11/11/15 13:5860.0 25.0 1cis-1,3-Dichloropropene <25.0 ug/kg 11/12/15 05:10 10061-01-5 W11/11/15 13:5860.0 25.0 1m&p-Xylene <50.0 ug/kg 11/12/15 05:10 179601-23-1 W11/11/15 13:58120 50.0 1n-Butylbenzene <25.0 ug/kg 11/12/15 05:10 104-51-8 W11/11/15 13:5860.0 25.0 1n-Propylbenzene <25.0 ug/kg 11/12/15 05:10 103-65-1 W11/11/15 13:5860.0 25.0 1




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Sample: 7/RIVER XING 2 2.5-4.0 Lab ID: 40124373007 Collected: 11/04/15 11:00 Received: 11/09/15 14:05 Matrix: SolidResults reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.



Arsenic <3.5 mg/kg 11/19/15 14:13 7440-38-2 D311/18/15 08:3210.9 3.5 5Barium 5.6 mg/kg 11/18/15 20:19 7440-39-311/18/15 08:320.55 0.13 1Cadmium 0.15J mg/kg 11/18/15 20:19 7440-43-911/18/15 08:320.55 0.072 1Chromium 4.9 mg/kg 11/18/15 20:19 7440-47-311/18/15 08:320.55 0.21 1Lead 4.5 mg/kg 11/18/15 20:19 7439-92-111/18/15 08:321.1 0.47 1Selenium <0.84 mg/kg 11/18/15 20:19 7782-49-211/18/15 08:322.2 0.84 1Silver 0.59J mg/kg 11/18/15 20:19 7440-22-411/18/15 08:321.1 0.30 1


Mercury 0.0060J mg/kg 11/18/15 11:54 7439-97-611/17/15 09:060.010 0.0030 1


Acenaphthene <9.2 ug/kg 11/18/15 10:44 83-32-911/17/15 09:4018.4 9.2 1Acenaphthylene <8.2 ug/kg 11/18/15 10:44 208-96-811/17/15 09:4018.4 8.2 1Anthracene <9.5 ug/kg 11/18/15 10:44 120-12-711/17/15 09:4018.4 9.5 1Benzo(a)anthracene <6.4 ug/kg 11/18/15 10:44 56-55-311/17/15 09:4018.4 6.4 1Benzo(a)pyrene <6.6 ug/kg 11/18/15 10:44 50-32-811/17/15 09:4018.4 6.6 1Benzo(b)fluoranthene <9.2 ug/kg 11/18/15 10:44 205-99-211/17/15 09:4018.4 9.2 1Benzo(g,h,i)perylene <7.0 ug/kg 11/18/15 10:44 191-24-211/17/15 09:4018.4 7.0 1Benzo(k)fluoranthene <10.2 ug/kg 11/18/15 10:44 207-08-911/17/15 09:4018.4 10.2 1Chrysene 8.9J ug/kg 11/18/15 10:44 218-01-911/17/15 09:4018.4 8.5 1Dibenz(a,h)anthracene <6.7 ug/kg 11/18/15 10:44 53-70-311/17/15 09:4018.4 6.7 1Fluoranthene <9.2 ug/kg 11/18/15 10:44 206-44-011/17/15 09:4018.4 9.2 1Fluorene <9.2 ug/kg 11/18/15 10:44 86-73-711/17/15 09:4018.4 9.2 1Indeno(1,2,3-cd)pyrene <7.0 ug/kg 11/18/15 10:44 193-39-511/17/15 09:4018.4 7.0 11-Methylnaphthalene <9.2 ug/kg 11/18/15 10:44 90-12-011/17/15 09:4018.4 9.2 12-Methylnaphthalene <9.2 ug/kg 11/18/15 10:44 91-57-611/17/15 09:4018.4 9.2 1Naphthalene <9.2 ug/kg 11/18/15 10:44 91-20-311/17/15 09:4018.4 9.2 1Phenanthrene <9.2 ug/kg 11/18/15 10:44 85-01-811/17/15 09:4018.4 9.2 1Pyrene <9.2 ug/kg 11/18/15 10:44 129-00-011/17/15 09:4018.4 9.2 1Surrogates2-Fluorobiphenyl (S) 61 % 11/18/15 10:44 321-60-811/17/15 09:4039-130 1Terphenyl-d14 (S) 74 % 11/18/15 10:44 1718-51-011/17/15 09:4037-130 1






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ANALYTICAL RESULTS


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1,2,4-Trimethylbenzene <33.8 ug/kg 11/12/15 04:25 95-63-6 W11/11/15 13:5881.1 33.8 11,2-Dibromo-3-chloropropane <123 ug/kg 11/12/15 04:25 96-12-8 W11/11/15 13:58338 123 11,2-Dibromoethane (EDB) <33.8 ug/kg 11/12/15 04:25 106-93-4 W11/11/15 13:5881.1 33.8 11,2-Dichlorobenzene <33.8 ug/kg 11/12/15 04:25 95-50-1 W11/11/15 13:5881.1 33.8 11,2-Dichloroethane <33.8 ug/kg 11/12/15 04:25 107-06-2 W11/11/15 13:5881.1 33.8 11,2-Dichloropropane <33.8 ug/kg 11/12/15 04:25 78-87-5 W11/11/15 13:5881.1 33.8 11,3,5-Trimethylbenzene <33.8 ug/kg 11/12/15 04:25 108-67-8 W11/11/15 13:5881.1 33.8 11,3-Dichlorobenzene <33.8 ug/kg 11/12/15 04:25 541-73-1 W11/11/15 13:5881.1 33.8 11,3-Dichloropropane <33.8 ug/kg 11/12/15 04:25 142-28-9 W11/11/15 13:5881.1 33.8 11,4-Dichlorobenzene <33.8 ug/kg 11/12/15 04:25 106-46-7 W11/11/15 13:5881.1 33.8 12,2-Dichloropropane <33.8 ug/kg 11/12/15 04:25 594-20-7 W11/11/15 13:5881.1 33.8 12-Chlorotoluene <33.8 ug/kg 11/12/15 04:25 95-49-8 W11/11/15 13:5881.1 33.8 14-Chlorotoluene <33.8 ug/kg 11/12/15 04:25 106-43-4 W11/11/15 13:5881.1 33.8 1Benzene <33.8 ug/kg 11/12/15 04:25 71-43-2 W11/11/15 13:5881.1 33.8 1Bromobenzene <33.8 ug/kg 11/12/15 04:25 108-86-1 W11/11/15 13:5881.1 33.8 1Bromochloromethane <33.8 ug/kg 11/12/15 04:25 74-97-5 W11/11/15 13:5881.1 33.8 1Bromodichloromethane <33.8 ug/kg 11/12/15 04:25 75-27-4 W11/11/15 13:5881.1 33.8 1Bromoform <33.8 ug/kg 11/12/15 04:25 75-25-2 W11/11/15 13:5881.1 33.8 1Bromomethane <94.5 ug/kg 11/12/15 04:25 74-83-9 W11/11/15 13:58338 94.5 1Carbon tetrachloride <33.8 ug/kg 11/12/15 04:25 56-23-5 W11/11/15 13:5881.1 33.8 1Chlorobenzene <33.8 ug/kg 11/12/15 04:25 108-90-7 W11/11/15 13:5881.1 33.8 1Chloroethane <90.6 ug/kg 11/12/15 04:25 75-00-3 W11/11/15 13:58338 90.6 1Chloroform <62.8 ug/kg 11/12/15 04:25 67-66-3 W11/11/15 13:58338 62.8 1Chloromethane <33.8 ug/kg 11/12/15 04:25 74-87-3 W11/11/15 13:5881.1 33.8 1Dibromochloromethane <33.8 ug/kg 11/12/15 04:25 124-48-1 W11/11/15 13:5881.1 33.8 1Dibromomethane <33.8 ug/kg 11/12/15 04:25 74-95-3 W11/11/15 13:5881.1 33.8 1Dichlorodifluoromethane <33.8 ug/kg 11/12/15 04:25 75-71-8 W11/11/15 13:5881.1 33.8 1Diisopropyl ether <33.8 ug/kg 11/12/15 04:25 108-20-3 W11/11/15 13:5881.1 33.8 1Ethylbenzene <33.8 ug/kg 11/12/15 04:25 100-41-4 W11/11/15 13:5881.1 33.8 1Hexachloro-1,3-butadiene <33.8 ug/kg 11/12/15 04:25 87-68-3 W11/11/15 13:5881.1 33.8 1Isopropylbenzene (Cumene) <33.8 ug/kg 11/12/15 04:25 98-82-8 W11/11/15 13:5881.1 33.8 1Methyl-tert-butyl ether <33.8 ug/kg 11/12/15 04:25 1634-04-4 W11/11/15 13:5881.1 33.8 1Methylene Chloride <33.8 ug/kg 11/12/15 04:25 75-09-2 W11/11/15 13:5881.1 33.8 1Naphthalene <54.1 ug/kg 11/12/15 04:25 91-20-3 W11/11/15 13:58338 54.1 1Styrene <33.8 ug/kg 11/12/15 04:25 100-42-5 W11/11/15 13:5881.1 33.8 1Tetrachloroethene <33.8 ug/kg 11/12/15 04:25 127-18-4 W11/11/15 13:5881.1 33.8 1Toluene <33.8 ug/kg 11/12/15 04:25 108-88-3 W11/11/15 13:5881.1 33.8 1Trichloroethene <33.8 ug/kg 11/12/15 04:25 79-01-6 W11/11/15 13:5881.1 33.8 1Trichlorofluoromethane <33.8 ug/kg 11/12/15 04:25 75-69-4 W11/11/15 13:5881.1 33.8 1Vinyl chloride <33.8 ug/kg 11/12/15 04:25 75-01-4 W11/11/15 13:5881.1 33.8 1cis-1,2-Dichloroethene <33.8 ug/kg 11/12/15 04:25 156-59-2 W11/11/15 13:5881.1 33.8 1cis-1,3-Dichloropropene <33.8 ug/kg 11/12/15 04:25 10061-01-5 W11/11/15 13:5881.1 33.8 1m&p-Xylene <67.6 ug/kg 11/12/15 04:25 179601-23-1 W11/11/15 13:58162 67.6 1n-Butylbenzene <33.8 ug/kg 11/12/15 04:25 104-51-8 W11/11/15 13:5881.1 33.8 1n-Propylbenzene <33.8 ug/kg 11/12/15 04:25 103-65-1 W11/11/15 13:5881.1 33.8 1




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#=AR#

ANALYTICAL RESULTS


4012437360344843 U73




o-Xylene <33.8 ug/kg 11/12/15 04:25 95-47-6 W11/11/15 13:5881.1 33.8 1p-Isopropyltoluene <33.8 ug/kg 11/12/15 04:25 99-87-6 W11/11/15 13:5881.1 33.8 1sec-Butylbenzene <33.8 ug/kg 11/12/15 04:25 135-98-8 W11/11/15 13:5881.1 33.8 1tert-Butylbenzene <33.8 ug/kg 11/12/15 04:25 98-06-6 W11/11/15 13:5881.1 33.8 1trans-1,2-Dichloroethene <33.8 ug/kg 11/12/15 04:25 156-60-5 W11/11/15 13:5881.1 33.8 1trans-1,3-Dichloropropene <33.8 ug/kg 11/12/15 04:25 10061-02-6 W11/11/15 13:5881.1 33.8 1SurrogatesDibromofluoromethane (S) 208 % 11/12/15 04:25 1868-53-7 S311/11/15 13:5849-157 1Toluene-d8 (S) 195 % 11/12/15 04:25 2037-26-5 S311/11/15 13:5861-148 14-Bromofluorobenzene (S) 178 % 11/12/15 04:25 460-00-4 S311/11/15 13:5853-134 1






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#=QC#

QUALITY CONTROL DATA


4012437360344843 U73

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

MERP/5366EPA 7471

EPA 74717471 Mercury

Associated Lab Samples: 40124373001, 40124373002, 40124373003, 40124373004, 40124373005, 40124373006, 40124373007

Parameter UnitsBlankResult

ReportingLimit Qualifiers

METHOD BLANK: 1258817Associated Lab Samples: 40124373001, 40124373002, 40124373003, 40124373004, 40124373005, 40124373006, 40124373007

Matrix: Solid

Analyzed

Mercury mg/kg <0.0029 0.0097 11/18/15 11:17

Parameter UnitsLCS

Result% RecLimits Qualifiers% RecConc.

1258818LABORATORY CONTROL SAMPLE:LCSSpike

Mercury mg/kg 0.15.17 87 85-115

Parameter UnitsMS

Result% RecLimits Qual% RecConc.

1258819MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpikeResult

40124373001

1258820

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Mercury mg/kg .17 91 85-11593 4 20.180.0054J 0.16 0.17




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4012437360344843 U73




MPRP/12925EPA 3050

EPA 60106010 MET

Associated Lab Samples: 40124373001, 40124373002, 40124373003, 40124373004, 40124373005



METHOD BLANK: 1260416Associated Lab Samples: 40124373001, 40124373002, 40124373003, 40124373004, 40124373005

Matrix: Solid

Analyzed

Arsenic mg/kg <0.64 2.0 11/19/15 18:46Barium mg/kg 0.15J 0.50 11/19/15 18:46Cadmium mg/kg <0.066 0.50 11/19/15 18:46Chromium mg/kg <0.19 0.50 11/19/15 18:46Lead mg/kg <0.43 1.0 11/19/15 18:46Selenium mg/kg <0.77 2.0 11/19/15 18:46Silver mg/kg <0.28 1.0 11/19/15 18:46

Parameter UnitsLCS


1260417LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD

% Rec RPDMaxRPD

LCSDResult

1260420

Arsenic mg/kg 48.850 98 80-1209949.4 1 20Barium mg/kg 50.850 102 80-12010250.8 0 20Cadmium mg/kg 49.750 99 80-12010150.3 1 20Chromium mg/kg 50.350 101 80-12010250.9 1 20Lead mg/kg 50.050 100 80-12010251.0 2 20Selenium mg/kg 49.750 99 80-12010050.1 1 20Silver mg/kg 24.525 98 80-12010024.9 1 20

Parameter UnitsMS



MSSpikeResult

40124373001

1260419

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Arsenic mg/kg 52.7 93 75-12592 2 2052.52.6 51.7 51.0Barium mg/kg 52.7 98 75-12597 2 2052.510.1 61.8 60.8Cadmium mg/kg 52.7 96 75-12598 1 2052.5<0.069 50.7 51.3Chromium mg/kg 52.7 90 75-12593 3 2052.59.8 57.1 58.5Lead mg/kg 52.7 97 75-12598 1 2052.50.89J 51.9 52.5Selenium mg/kg 52.7 92 75-12592 0 2052.50.93J 49.2 49.4Silver mg/kg 26.4 94 75-12596 1 2026.30.30J 25.1 25.4




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4012437360344843 U73




MPRP/12931EPA 3050

EPA 60106010 MET

Associated Lab Samples: 40124373006, 40124373007



METHOD BLANK: 1260901Associated Lab Samples: 40124373006, 40124373007

Matrix: Solid

Analyzed

Arsenic mg/kg <0.64 2.0 11/18/15 20:02Barium mg/kg <0.12 0.50 11/18/15 20:02Cadmium mg/kg <0.066 0.50 11/18/15 20:02Chromium mg/kg <0.19 0.50 11/18/15 20:02Lead mg/kg <0.43 1.0 11/18/15 20:02Selenium mg/kg <0.77 2.0 11/18/15 20:02Silver mg/kg <0.28 1.0 11/18/15 20:02

Parameter UnitsLCS



Arsenic mg/kg 50.050 100 80-120Barium mg/kg 50.950 102 80-120Cadmium mg/kg 51.450 103 80-120Chromium mg/kg 51.550 103 80-120Lead mg/kg 51.050 102 80-120Selenium mg/kg 49.450 99 80-120Silver mg/kg 24.425 98 80-120

Parameter UnitsMS



MSSpikeResult

40124373006

1260904

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Arsenic mg/kg 54.1 96 75-12596 1 2053.85.8 57.8 57.4Barium mg/kg M054.1 104 75-125138 17 2053.838.7 94.9 113Cadmium mg/kg 54.1 101 75-125100 2 2053.80.32J 54.8 53.9Chromium mg/kg 54.1 104 75-125101 3 2053.88.4 64.6 62.7Lead mg/kg 54.1 99 75-125116 8 2053.856.7 110 119Selenium mg/kg 54.1 93 75-12593 1 2053.8<0.84 50.4 50.0Silver mg/kg 27.1 96 75-12596 1 2026.90.42J 26.5 26.1




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4012437360344843 U73




MSV/31211EPA 5035/5030B

EPA 82608260 MSV Med Level Normal List





Matrix: Solid

Analyzed

1,1,1,2-Tetrachloroethane ug/kg <13.7 50.0 11/11/15 19:451,1,1-Trichloroethane ug/kg <14.4 50.0 11/11/15 19:451,1,2,2-Tetrachloroethane ug/kg <17.5 50.0 11/11/15 19:451,1,2-Trichloroethane ug/kg <20.2 50.0 11/11/15 19:451,1-Dichloroethane ug/kg <17.6 50.0 11/11/15 19:451,1-Dichloroethene ug/kg <17.6 50.0 11/11/15 19:451,1-Dichloropropene ug/kg <14.0 50.0 11/11/15 19:451,2,3-Trichlorobenzene ug/kg <17.0 50.0 11/11/15 19:451,2,3-Trichloropropane ug/kg <22.3 50.0 11/11/15 19:451,2,4-Trichlorobenzene ug/kg <47.6 250 11/11/15 19:451,2,4-Trimethylbenzene ug/kg <12.2 50.0 11/11/15 19:451,2-Dibromo-3-chloropropane ug/kg <91.2 250 11/11/15 19:451,2-Dibromoethane (EDB) ug/kg <14.7 50.0 11/11/15 19:451,2-Dichlorobenzene ug/kg <16.2 50.0 11/11/15 19:451,2-Dichloroethane ug/kg <15.0 50.0 11/11/15 19:451,2-Dichloropropane ug/kg <16.8 50.0 11/11/15 19:451,3,5-Trimethylbenzene ug/kg <14.5 50.0 11/11/15 19:451,3-Dichlorobenzene ug/kg <13.2 50.0 11/11/15 19:451,3-Dichloropropane ug/kg <12.0 50.0 11/11/15 19:451,4-Dichlorobenzene ug/kg <15.9 50.0 11/11/15 19:452,2-Dichloropropane ug/kg <12.6 50.0 11/11/15 19:452-Chlorotoluene ug/kg <15.8 50.0 11/11/15 19:454-Chlorotoluene ug/kg <13.0 50.0 11/11/15 19:45Benzene ug/kg <9.2 20.0 11/11/15 19:45Bromobenzene ug/kg <20.6 50.0 11/11/15 19:45Bromochloromethane ug/kg <21.4 50.0 11/11/15 19:45Bromodichloromethane ug/kg <9.8 50.0 11/11/15 19:45Bromoform ug/kg <19.8 50.0 11/11/15 19:45Bromomethane ug/kg <69.9 250 11/11/15 19:45Carbon tetrachloride ug/kg <12.1 50.0 11/11/15 19:45Chlorobenzene ug/kg <14.8 50.0 11/11/15 19:45Chloroethane ug/kg <67.0 250 11/11/15 19:45Chloroform ug/kg <46.4 250 11/11/15 19:45Chloromethane ug/kg <20.4 50.0 11/11/15 19:45cis-1,2-Dichloroethene ug/kg <16.6 50.0 11/11/15 19:45cis-1,3-Dichloropropene ug/kg <16.6 50.0 11/11/15 19:45Dibromochloromethane ug/kg <17.9 50.0 11/11/15 19:45Dibromomethane ug/kg <19.3 50.0 11/11/15 19:45Dichlorodifluoromethane ug/kg <12.3 50.0 11/11/15 19:45Diisopropyl ether ug/kg <17.7 50.0 11/11/15 19:45Ethylbenzene ug/kg <12.4 50.0 11/11/15 19:45




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4012437360344843 U73





Matrix: Solid

Analyzed

Hexachloro-1,3-butadiene ug/kg <24.5 50.0 11/11/15 19:45Isopropylbenzene (Cumene) ug/kg <12.6 50.0 11/11/15 19:45m&p-Xylene ug/kg <34.4 100 11/11/15 19:45Methyl-tert-butyl ether ug/kg <12.7 50.0 11/11/15 19:45Methylene Chloride ug/kg <16.2 50.0 11/11/15 19:45n-Butylbenzene ug/kg <10.5 50.0 11/11/15 19:45n-Propylbenzene ug/kg <11.6 50.0 11/11/15 19:45Naphthalene ug/kg <40.0 250 11/11/15 19:45o-Xylene ug/kg <14.0 50.0 11/11/15 19:45p-Isopropyltoluene ug/kg <12.0 50.0 11/11/15 19:45sec-Butylbenzene ug/kg <11.9 50.0 11/11/15 19:45Styrene ug/kg <9.0 50.0 11/11/15 19:45tert-Butylbenzene ug/kg <9.5 50.0 11/11/15 19:45Tetrachloroethene ug/kg <12.9 50.0 11/11/15 19:45Toluene ug/kg <11.2 50.0 11/11/15 19:45trans-1,2-Dichloroethene ug/kg <16.5 50.0 11/11/15 19:45trans-1,3-Dichloropropene ug/kg <14.4 50.0 11/11/15 19:45Trichloroethene ug/kg <23.6 50.0 11/11/15 19:45Trichlorofluoromethane ug/kg <24.7 50.0 11/11/15 19:45Vinyl chloride ug/kg <21.1 50.0 11/11/15 19:454-Bromofluorobenzene (S) % 105 53-134 11/11/15 19:45Dibromofluoromethane (S) % 115 49-157 11/11/15 19:45Toluene-d8 (S) % 107 61-148 11/11/15 19:45

Parameter UnitsLCS



1,1,1-Trichloroethane ug/kg 25902500 104 70-1301,1,2,2-Tetrachloroethane ug/kg 22402500 90 70-1301,1,2-Trichloroethane ug/kg 22802500 91 70-1301,1-Dichloroethane ug/kg 27102500 108 70-1301,1-Dichloroethene ug/kg 29002500 116 70-1321,2,4-Trichlorobenzene ug/kg 23502500 94 70-1301,2-Dibromo-3-chloropropane ug/kg 22302500 89 45-1501,2-Dibromoethane (EDB) ug/kg 23302500 93 70-1301,2-Dichlorobenzene ug/kg 25102500 101 70-1301,2-Dichloroethane ug/kg 30002500 120 70-1341,2-Dichloropropane ug/kg 26502500 106 70-1301,3-Dichlorobenzene ug/kg 25002500 100 70-1301,4-Dichlorobenzene ug/kg 25102500 100 70-130Benzene ug/kg 24602500 99 70-130Bromodichloromethane ug/kg 27102500 109 70-130Bromoform ug/kg 21102500 84 48-130Bromomethane ug/kg 31502500 126 70-169




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4012437360344843 U73


Parameter UnitsLCS



Carbon tetrachloride ug/kg 26602500 106 67-130Chlorobenzene ug/kg 25702500 103 70-130Chloroethane ug/kg 27402500 109 70-191Chloroform ug/kg 28702500 115 70-130Chloromethane ug/kg 25102500 100 52-132cis-1,2-Dichloroethene ug/kg 25102500 100 70-130cis-1,3-Dichloropropene ug/kg 24502500 98 70-130Dibromochloromethane ug/kg 23002500 92 65-130Dichlorodifluoromethane ug/kg 25402500 102 12-150Ethylbenzene ug/kg 24902500 100 70-130Isopropylbenzene (Cumene) ug/kg 24402500 97 70-130m&p-Xylene ug/kg 47705000 95 70-130Methyl-tert-butyl ether ug/kg 22302500 89 70-130Methylene Chloride ug/kg 29502500 118 70-131o-Xylene ug/kg 22902500 91 70-130Styrene ug/kg 24102500 96 70-130Tetrachloroethene ug/kg 24002500 96 70-130Toluene ug/kg 24502500 98 70-130trans-1,2-Dichloroethene ug/kg 27802500 111 69-130trans-1,3-Dichloropropene ug/kg 22702500 91 65-130Trichloroethene ug/kg 27502500 110 70-130Trichlorofluoromethane ug/kg 34002500 136 50-150Vinyl chloride ug/kg 28302500 113 67-1344-Bromofluorobenzene (S) % 100 53-134Dibromofluoromethane (S) % 115 49-157Toluene-d8 (S) % 101 61-148




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4012437360344843 U73




OEXT/28752EPA 3546

EPA 8270 by SIM8270/3546 MSSV PAH by SIM

Associated Lab Samples: 40124373006



METHOD BLANK: 1258257Associated Lab Samples: 40124373006

Matrix: Solid

Analyzed

1-Methylnaphthalene ug/kg <8.3 16.7 11/13/15 13:302-Methylnaphthalene ug/kg <8.3 16.7 11/13/15 13:30Acenaphthene ug/kg <8.3 16.7 11/13/15 13:30Acenaphthylene ug/kg <7.5 16.7 11/13/15 13:30Anthracene ug/kg <8.6 16.7 11/13/15 13:30Benzo(a)anthracene ug/kg <5.8 16.7 11/13/15 13:30Benzo(a)pyrene ug/kg <6.0 16.7 11/13/15 13:30Benzo(b)fluoranthene ug/kg <8.3 16.7 11/13/15 13:30Benzo(g,h,i)perylene ug/kg <6.3 16.7 11/13/15 13:30Benzo(k)fluoranthene ug/kg <9.2 16.7 11/13/15 13:30Chrysene ug/kg <7.7 16.7 11/13/15 13:30Dibenz(a,h)anthracene ug/kg <6.1 16.7 11/13/15 13:30Fluoranthene ug/kg <8.3 16.7 11/13/15 13:30Fluorene ug/kg <8.3 16.7 11/13/15 13:30Indeno(1,2,3-cd)pyrene ug/kg <6.3 16.7 11/13/15 13:30Naphthalene ug/kg <8.3 16.7 11/13/15 13:30Phenanthrene ug/kg <8.3 16.7 11/13/15 13:30Pyrene ug/kg <8.3 16.7 11/13/15 13:302-Fluorobiphenyl (S) % 77 39-130 11/13/15 13:30Terphenyl-d14 (S) % 90 37-130 11/13/15 13:30

Parameter UnitsLCS



1-Methylnaphthalene ug/kg 266333 80 53-1302-Methylnaphthalene ug/kg 273333 82 52-130Acenaphthene ug/kg 272333 82 54-130Acenaphthylene ug/kg 289333 87 55-130Anthracene ug/kg 345333 103 64-130Benzo(a)anthracene ug/kg 285333 86 50-130Benzo(a)pyrene ug/kg 282333 85 46-130Benzo(b)fluoranthene ug/kg 275333 82 43-130Benzo(g,h,i)perylene ug/kg 290333 87 48-130Benzo(k)fluoranthene ug/kg 283333 85 55-130Chrysene ug/kg 294333 88 62-130Dibenz(a,h)anthracene ug/kg 298333 89 49-130Fluoranthene ug/kg 289333 87 57-130Fluorene ug/kg 276333 83 57-130Indeno(1,2,3-cd)pyrene ug/kg 300333 90 50-130Naphthalene ug/kg 255333 76 48-130




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4012437360344843 U73


Parameter UnitsLCS



Phenanthrene ug/kg 294333 88 51-130Pyrene ug/kg 279333 84 55-1302-Fluorobiphenyl (S) % 82 39-130Terphenyl-d14 (S) % 86 37-130

Parameter UnitsMS



MSSpikeResult

40124067001

1258260

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1-Methylnaphthalene ug/kg 473 66 50-13071 7 30473<47.4 356 3802-Methylnaphthalene ug/kg 473 64 44-13072 10 3247354.1J 356 393Acenaphthene ug/kg 473 96 46-13070 21 26473189 644 519Acenaphthylene ug/kg 473 54 49-13063 10 23473118 374 414Anthracene ug/kg 473 111 52-13077 22 28473275 801 640Benzo(a)anthracene ug/kg 473 60 34-13037 18 36473362 645 539Benzo(a)pyrene ug/kg 473 65 34-13047 14 40473332 641 555Benzo(b)fluoranthene ug/kg 473 71 22-13055 13 40473293 632 553Benzo(g,h,i)perylene ug/kg M1473 17 24-13015 2 35473222 301 295Benzo(k)fluoranthene ug/kg 473 80 41-13059 16 37473293 673 571Chrysene ug/kg M1473 77 49-13028 32 33473480 846 614Dibenz(a,h)anthracene ug/kg 473 38 27-13047 17 3147343.6J 224 264Fluoranthene ug/kg M1,R1473 41 34-130-61 46 374731090 1280 799Fluorene ug/kg 473 99 45-13066 25 25473230 701 543Indeno(1,2,3-cd)pyrene ug/kg M1473 27 30-13030 4 34473155 283 295Naphthalene ug/kg 473 62 38-13064 3 3047369.0J 362 373Phenanthrene ug/kg M1,R1473 219 38-130-8 66 344731120 2160 1090Pyrene ug/kg M1,R1473 -26 35-130-152 48 354731680 1550 9562-Fluorobiphenyl (S) % 58 39-13062Terphenyl-d14 (S) % 50 37-13058




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4012437360344843 U73




OEXT/28785EPA 3546






Matrix: Solid

Analyzed

1-Methylnaphthalene ug/kg 13.7J 16.7 11/16/15 11:252-Methylnaphthalene ug/kg 13.3J 16.7 11/16/15 11:25Acenaphthene ug/kg <8.3 16.7 11/16/15 11:25Acenaphthylene ug/kg <7.5 16.7 11/16/15 11:25Anthracene ug/kg <8.6 16.7 11/16/15 11:25Benzo(a)anthracene ug/kg <5.8 16.7 11/16/15 11:25Benzo(a)pyrene ug/kg <6.0 16.7 11/16/15 11:25Benzo(b)fluoranthene ug/kg <8.3 16.7 11/16/15 11:25Benzo(g,h,i)perylene ug/kg <6.3 16.7 11/16/15 11:25Benzo(k)fluoranthene ug/kg <9.2 16.7 11/16/15 11:25Chrysene ug/kg <7.7 16.7 11/16/15 11:25Dibenz(a,h)anthracene ug/kg <6.1 16.7 11/16/15 11:25Fluoranthene ug/kg <8.3 16.7 11/16/15 11:25Fluorene ug/kg <8.3 16.7 11/16/15 11:25Indeno(1,2,3-cd)pyrene ug/kg <6.3 16.7 11/16/15 11:25Naphthalene ug/kg <8.3 16.7 11/16/15 11:25Phenanthrene ug/kg <8.3 16.7 11/16/15 11:25Pyrene ug/kg <8.3 16.7 11/16/15 11:252-Fluorobiphenyl (S) % 80 39-130 11/16/15 11:25Terphenyl-d14 (S) % 87 37-130 11/16/15 11:25

Parameter UnitsLCS







Green Bay, WI 54302(920)469-2436

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#=QC#



4012437360344843 U73


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40124085003

1259700

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1-Methylnaphthalene ug/kg 400 79 50-13076 4 30400<10.0 318 3042-Methylnaphthalene ug/kg 400 82 44-13078 4 32400<10.0 329 315Acenaphthene ug/kg 400 82 46-13078 4 26400<10.0 327 314Acenaphthylene ug/kg 400 86 49-13081 6 23400<9.0 346 324Anthracene ug/kg 400 104 52-13098 6 28400<10.4 418 393Benzo(a)anthracene ug/kg 400 81 34-13077 5 36400<6.9 325 308Benzo(a)pyrene ug/kg 400 78 34-13075 4 40400<7.2 316 302Benzo(b)fluoranthene ug/kg 400 80 22-13080 0 40400<10.0 320 320Benzo(g,h,i)perylene ug/kg 400 77 24-13073 6 35400<7.6 311 293Benzo(k)fluoranthene ug/kg 400 82 41-13075 10 37400<11.1 330 299Chrysene ug/kg 400 86 49-13082 5 33400<9.3 346 329Dibenz(a,h)anthracene ug/kg 400 80 27-13076 6 31400<7.3 322 303Fluoranthene ug/kg 400 85 34-13081 6 37400<10.0 342 323Fluorene ug/kg 400 82 45-13078 5 25400<10.0 327 312Indeno(1,2,3-cd)pyrene ug/kg 400 82 30-13077 5 34400<7.6 326 309Naphthalene ug/kg 400 74 38-13070 5 30400<10.0 299 286Phenanthrene ug/kg 400 86 38-13081 6 34400<10.0 344 325Pyrene ug/kg 400 80 35-13076 4 35400<10.0 319 3062-Fluorobiphenyl (S) % 77 39-13072Terphenyl-d14 (S) % 78 37-13074




Green Bay, WI 54302(920)469-2436

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#=QC#



4012437360344843 U73




OEXT/28813EPA 3546






Matrix: Solid

Analyzed


Parameter UnitsLCS







Green Bay, WI 54302(920)469-2436

Page 36 of 44

#=QC#



4012437360344843 U73


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40124168006

1260286

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1-Methylnaphthalene ug/kg 422 76 50-13069 9 30422<10.5 321 2942-Methylnaphthalene ug/kg 422 78 44-13072 9 32422<10.5 331 303Acenaphthene ug/kg 422 78 46-13075 4 26422<10.5 330 317Acenaphthylene ug/kg 422 84 49-13076 10 23422<9.4 353 321Anthracene ug/kg 422 99 52-13090 10 28422<10.9 422 382Benzo(a)anthracene ug/kg 422 76 34-13070 8 364228.6J 328 303Benzo(a)pyrene ug/kg 422 76 34-13071 6 404229.2J 329 310Benzo(b)fluoranthene ug/kg 422 82 22-13081 1 40422<10.5 355 352Benzo(g,h,i)perylene ug/kg 422 79 24-13074 7 35422<8.0 342 319Benzo(k)fluoranthene ug/kg 422 71 41-13065 9 37422<11.7 309 284Chrysene ug/kg 422 82 49-13077 6 3342210.5J 354 334Dibenz(a,h)anthracene ug/kg 422 83 27-13077 7 31422<7.7 352 329Fluoranthene ug/kg 422 78 34-13073 7 3742218.6J 348 326Fluorene ug/kg 422 78 45-13072 9 25422<10.5 330 303Indeno(1,2,3-cd)pyrene ug/kg 422 83 30-13077 7 34422<8.0 355 330Naphthalene ug/kg 422 74 38-13069 8 30422<10.5 315 291Phenanthrene ug/kg 422 80 38-13074 8 3442211.9J 348 323Pyrene ug/kg 422 73 35-13068 7 3542217.6J 327 3042-Fluorobiphenyl (S) % 72 39-13063Terphenyl-d14 (S) % 70 37-13064




Green Bay, WI 54302(920)469-2436

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#=QC#



4012437360344843 U73




OEXT/28836EPA 3546






Matrix: Solid

Analyzed


Parameter UnitsLCS







Green Bay, WI 54302(920)469-2436

Page 38 of 44

#=QC#



4012437360344843 U73


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40124373001

1261358

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1-Methylnaphthalene ug/kg 351 70 50-13069 0 30351<8.8 246 2462-Methylnaphthalene ug/kg 351 72 44-13071 1 32351<8.8 255 253Acenaphthene ug/kg 351 71 46-13073 3 26351<8.8 250 258Acenaphthylene ug/kg 351 74 49-13075 0 23351<7.9 262 262Anthracene ug/kg 351 92 52-13089 3 28351<9.1 323 313Benzo(a)anthracene ug/kg 351 71 34-13070 2 36351<6.1 252 246Benzo(a)pyrene ug/kg 351 72 34-13068 7 40351<6.3 255 239Benzo(b)fluoranthene ug/kg 351 71 22-13070 2 40351<8.8 251 246Benzo(g,h,i)perylene ug/kg 351 75 24-13071 6 35351<6.7 266 251Benzo(k)fluoranthene ug/kg 351 75 41-13068 10 37351<9.7 264 239Chrysene ug/kg 351 76 49-13073 5 33351<8.1 271 259Dibenz(a,h)anthracene ug/kg 351 77 27-13073 5 31351<6.4 271 256Fluoranthene ug/kg 351 74 34-13071 4 37351<8.8 264 253Fluorene ug/kg 351 71 45-13071 1 25351<8.8 250 249Indeno(1,2,3-cd)pyrene ug/kg 351 78 30-13073 6 34351<6.7 276 259Naphthalene ug/kg 351 68 38-13067 1 30351<8.8 242 239Phenanthrene ug/kg 351 76 38-13072 6 34351<8.8 269 255Pyrene ug/kg 351 69 35-13066 4 35351<8.8 244 2362-Fluorobiphenyl (S) % 67 39-13068Terphenyl-d14 (S) % 68 37-13066




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#=QC#



4012437360344843 U73




PMST/12100ASTM D2974-87

ASTM D2974-87Dry Weight/Percent Moisture


Parameter UnitsDup

ResultMaxRPD QualifiersRPDResult

401243630011255933SAMPLE DUPLICATE:

Percent Moisture % 0.14 10<0.10




Green Bay, WI 54302(920)469-2436

Page 40 of 44

#=QL#

QUALIFIERS


4012437360344843 U73

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above LOD.J - Estimated concentration at or above the LOD and below the LOQ.LOD - Limit of Detection adjusted for dilution factor and percent moisture.LOQ - Limit of Quantitation adjusted for dilution factor and percent moisture.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected at or above the adjusted LOD.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - Green BayPASI-G

BATCH QUALIFIERS

Batch: MSSV/8494Benzo(b)fluoranthene and benzo(k)fluoranthene were in the check standard but did not meet the resolution criteria inSW846 Method 8270C. Whereas sample results included are reported as individual isomers, the lab and the customermust recognize them as an isomeric pair.

[IP]

Batch: MSSV/8496Benzo(b)fluoranthene and benzo(k)fluoranthene were in the check standard but did not meet the resolution criteria inSW846 Method 8270C. Whereas sample results included are reported as individual isomers, the lab and the customermust recognize them as an isomeric pair.

[IP]

ANALYTE QUALIFIERS

Analyte was detected in the associated method blank.BSample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1RPD value was outside control limits.R1Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples.Results unaffected by high bias.

S3

Non-detect results are reported on a wet weight basis.W




Green Bay, WI 54302(920)469-2436

Page 41 of 44

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


4012437360344843 U73

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

40124373001 MPRP/12925 ICP/114871/2 5.0-6.5 EPA 3050 EPA 601040124373002 MPRP/12925 ICP/114872/5 2.5-4.0 EPA 3050 EPA 601040124373003 MPRP/12925 ICP/114875/25 0.0-1.5 EPA 3050 EPA 601040124373004 MPRP/12925 ICP/114876 OGDEN SS1 2.5-4.0 EPA 3050 EPA 601040124373005 MPRP/12925 ICP/114877 OGDEN SS2 2.5-4.0 EPA 3050 EPA 6010

40124373006 MPRP/12931 ICP/114908/1 7.5-9.0 EPA 3050 EPA 601040124373007 MPRP/12931 ICP/114907/RIVER XING 2 2.5-4.0 EPA 3050 EPA 6010

40124373001 MERP/5366 MERC/74631/2 5.0-6.5 EPA 7471 EPA 747140124373002 MERP/5366 MERC/74632/5 2.5-4.0 EPA 7471 EPA 747140124373003 MERP/5366 MERC/74635/25 0.0-1.5 EPA 7471 EPA 747140124373004 MERP/5366 MERC/74636 OGDEN SS1 2.5-4.0 EPA 7471 EPA 747140124373005 MERP/5366 MERC/74637 OGDEN SS2 2.5-4.0 EPA 7471 EPA 747140124373006 MERP/5366 MERC/74638/1 7.5-9.0 EPA 7471 EPA 747140124373007 MERP/5366 MERC/74637/RIVER XING 2 2.5-4.0 EPA 7471 EPA 7471

40124373001 OEXT/28836 MSSV/85071/2 5.0-6.5 EPA 3546 EPA 8270 by SIM



40124373004 OEXT/28785 MSSV/84966 OGDEN SS1 2.5-4.0 EPA 3546 EPA 8270 by SIM40124373005 OEXT/28785 MSSV/84967 OGDEN SS2 2.5-4.0 EPA 3546 EPA 8270 by SIM


40124373007 OEXT/28813 MSSV/85017/RIVER XING 2 2.5-4.0 EPA 3546 EPA 8270 by SIM

40124373001 MSV/31211 MSV/312131/2 5.0-6.5 EPA 5035/5030B EPA 826040124373002 MSV/31211 MSV/312132/5 2.5-4.0 EPA 5035/5030B EPA 826040124373003 MSV/31211 MSV/312135/25 0.0-1.5 EPA 5035/5030B EPA 826040124373004 MSV/31211 MSV/312136 OGDEN SS1 2.5-4.0 EPA 5035/5030B EPA 826040124373005 MSV/31211 MSV/312137 OGDEN SS2 2.5-4.0 EPA 5035/5030B EPA 826040124373006 MSV/31211 MSV/312138/1 7.5-9.0 EPA 5035/5030B EPA 826040124373007 MSV/31211 MSV/312137/RIVER XING 2 2.5-4.0 EPA 5035/5030B EPA 8260

40124373001 PMST/121001/2 5.0-6.5 ASTM D2974-8740124373002 PMST/121002/5 2.5-4.0 ASTM D2974-8740124373003 PMST/121005/25 0.0-1.5 ASTM D2974-8740124373004 PMST/121006 OGDEN SS1 2.5-4.0 ASTM D2974-8740124373005 PMST/121007 OGDEN SS2 2.5-4.0 ASTM D2974-8740124373006 PMST/121008/1 7.5-9.0 ASTM D2974-8740124373007 PMST/121007/RIVER XING 2 2.5-4.0 ASTM D2974-87




Green Bay, WI 54302(920)469-2436

Page 42 of 44

Pag

e 43

of 4

4

Data Package Options (billable)

0 EPA level Ill

0 EPA level IV

C019a(27 Jun2006)

MS/MSD 0 On your sample

(billable) 0 NOT needed on

your sample

UPPER MIDWEST REGION

MN: 612-607-1700 WI: 920-469-2436

CHAIN OF CUSTODY *Preseryation Codes

B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

!=Sodium Thiosulfate J=Other

Date!Time:

Dateffime:

Datemme:

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

Dateffime:

Dateffime:

Date/Time:

Page of

LAB COMMENTS

KSandmire

Highlight

KSandmire

Highlight

KSandmire

Highlight

KSandmire

Highlight

Page 44 of 44

a Analytical'

Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9

Green Bay, WI 54302

~~lient Name: J:secom Courier: r Fed Ex r UPS.~lent r Pace ::>ther: ------------------Tracking#: ______________ ......, ______ _

Custody Seal on Cooler/Box Present: r yes 2" no Seals intact: r yes r no ._

Custody Seal on Samples Present: r ye~o Seals intact: r yes - no

Project#:.--WQ#: 40124373

1111111111111111111111 40124373

Packing Material: r Bubble Wrap Tsubble Bags r None r Other

Thermometer Used N ,'fr Type of Ice: ~ Blue Dry None .-r--Samples on ice, cooling process has begun

Cooler Temperature Uncorr· /Carr· Q_o -~ o ogical Tissue is Frozen: r yes

Temp Blank Present: r yes_,...-;,o r no Date: \ 4____5 Person eJ(~,·~nin co-ntents:

Temp should be above freezing to 6°C for all sample except Biota. Frozen Biota Samples should be received~ ooc. Chain of Custody Present:

Chain of Custody Filled Out:

Chain of Custody Relinquished:

Sampler Name & Signature on COC:

Samples Arrived within Hold Time:

- VOA Samples frozen upon receipt

Short Hold Time Analysis (<72hr):

Rush Turn Around Time Requested:

Sufficient Volume:

Correct Containers Used:

-Pace Containers Used:

-Pace IR Containers Used:

Containers Intact:

~s 0No

.;a{es 0No

}21Yes 0No

~5 0No

..e{ves 0No

DYes 0No

DYes~

DYes Ql(o'

E1ves 0No

4Yes 0No

12fv"es 0No

DYes 0No

~s 0No

ON/A

ON/A

ON/A

ON/A

0NFA

ON/A

ON/A

ON/A

ON/A

ON/A

j:m7A

ON/A

Filtered volume received for Dissolved tests DYes 0No ~fA

Comments:

1 .

2.

3.

4 .

5.

Date/Time:

6.

7.

8.

9.

10.

11.

Sample Labels match COC: )aYes 0No ON/A 12.

-Includes date/time/ID/Analysis Matrix: .~·

Initials:--"'""'""-'~--

All containers needing preservation have been checked. _/ (Non-Compliance noted in 13.) DYes ONo .1:::1N/A 13. r HN03 r H2S04 r NaOH r NaOH +ZnAct

-------------------------------------All containers needing preservation are found to be in _ / compliance with EPA recommendation. DYes ONo Dt\i!A (~9~J::!~S_04 ~_2.i, ~<_?lj+Zn_!'.,91 ;::g.:. ~aOf:! ~12) ______________ +=~~----r~-:::-:-~::::---:------'"TI"'=r--------1 exceptions: VOA, coliform, TOC, TOX, TOH, __,.,. Initial when I lab Std #ID of IL)am~tee/·. O&G, WIDROW, Phenolics, OTHER: DYes l::::!No completed !preservative ITil

Headspace in VOA Vials ( >6mm):

Trip Blank Present:

Trip Blank Custody Seals Present

Pace Trip Blank Lot# (if purchased):

Client Notification/ Resolution:

DYes 0No

DYes 0No

DYes DNo

er~ 14.

Person Contacted: Date/Time: ----------------------Comments/ Resolution:

If checked, see attached form for additional comments D

--------------------------------------------------------

Project Manager Review: Date: _.....,1( .. -_q .... ._~'"'t .. -r ..... ___ _ F-GB-C-031-Rev.03 (9April2015) SCUR Form


Geotechnical Boring Logs

FILL: Sandy silt with bricks and roots - dark brown -dense to medium dense - moist (FILL: ML)

FILL: Sandy topsoil with cinders and wood - black andbrown - loose - moist to wet (FILL: OL)

FILL: Silt with sand, plastic, rock, and paper - brown andblack - loose - wet (FILL: ML)

FILL: Clayey silt with sand and gravel, plastic, and wood,petroleum odor noted - black - dense - wet (FILL: CL-ML)(Note: Sampler bouncing on plastic)

FILL: Poorly graded sand with wood, petroleum odornoted - dark brown - loose - wet (FILL: SP)

Poorly graded sand with gravel - brown - loose - wet (SP)

Pressuremeter Test #1: 20.5 ft - 23.0 ftPf = 6.5 tsf, Ed = 120 tsf

Sandy silt - brown - medium dense - wet (ML)


Silty sand - brown - extremely dense - wet (SM)

5.0

7.5

10.0

15.0

17.0

25.5

30.0

35.0

1

2

3

4

5

6

7

88A

9

SS

PA

SS

PA

SS

PA

SS

PA

SS

PA

SS

RB

SS

RB

SSSS

RB

SS

RB

6/OGDEN SS1 (PMT)

ARCHITECT-ENGINEER

SURFACE ELEVATION FeetRE

CO

VE

RY

CLIENT

SA

MP

LE D

IST

AN

CE

DE

PT

H(F

T)

ELE

VA

TIO

N(F

T)

STANDARDPENETRATION BLOWS/(FT)

WATERCONTENT %

DESCRIPTION OF MATERIAL

SITE LOCATION

5.0

10.0

15.0

20.0

25.0

30.0

35.0

American Transmission Company

UN

IT D

RY

WT

.

LBS

./FT

.3

1 2 3 4 5

10 20 30 40 50

600637

Ogden Street Networking Project

Marinette WI / Menominee MI

SA

MP

LE T

YP

E

LIQUIDLIMIT %

PLASTICLIMIT %

AECOMS

AM

PLE

NO

.

LOG OF BORING NUMBER

PROJECT NAME

UNCONFINED COMPRESSIVE STRENGTHTONS/FT.2

10 20 30 40 50

AE

CO

M L

OG

60

4455

40

AT

C O

GD

EN

.GP

J F

S_D

AT

AT

EM

PLA

TE

.GD

T 1

/15/

16

AECOM JOB NO. SHEET NO.1

OF60445540 2

*. . . continued

The stratification lines represent the approximate boundary lines between soil types: in situ, the transition may be gradual.

52

14

9

6

49

4

9

2/6"15

102

61.1

Calibrated Penetrometer

Lean clay - brown - very soft (CL)

Silt with clay - brown - medium dense - wet (ML)Pressuremeter Test #3: 35.5 ft - 38.0 ftPf = 5.0 tsf, Ed = 81 tsfLean clay - brown - stiff (CL)

End of boring at 40 feet below ground surface. Boringadvanced to 15 feet with solid stem augers. Mud rotarymethods used below 15 feet deep, with HW casinginstalled to 28.5 feet. Borehole grouted.

36.0

38.0

40.0

*

1010A

11

SSSS

RB

SS

6/OGDEN SS1 (PMT)

ARCHITECT-ENGINEER


CO

VE

RY

CLIENT

SA

MP

LE D

IST

AN

CE

DE

PT

H(F

T)

ELE

VA

TIO

N(F

T)


WATERCONTENT %


SITE LOCATION

40.0


UN

IT D

RY

WT

.

LBS

./FT

.3

(Continued)

1 2 3 4 5

10 20 30 40 50

600637



SA

MP

LE T

YP

E

LIQUIDLIMIT %

PLASTICLIMIT %

AECOMS

AM

PLE

NO

.


PROJECT NAME


10 20 30 40 50

AE

CO

M L

OG

60

4455

40

AT

C O

GD

EN

.GP

J F

S_D

AT

AT

EM

PLA

TE

.GD

T 1

/15/

16

AECOM OFFICENORTHING

EASTING

WL

469172

2587410

W.L. @ 8.0' A.B.

AMHENTERED BY

11/3/15

BORING STARTED Grand Rapids

D-50 Truck/John D. (SES)

OF

APP'D BY

2AECOM JOB NO.

BORING COMPLETED SHEET NO.

60445540RIG/FOREMAN

2


11/3/15

WOH/12"9/6"

12


*

*

<0.25

Topsoil (2")FILL: Silty sand with roots - dark reddish brown - loose -wet (FILL: SM)

FILL: Sandy topsoil - dark brown to black - loose - moistto wet (FILL: OL)

FILL: Poorly graded sand with organic silt - dark brown -very loose - wet (FILL: SP)

FILL: Organic sand with gravel - dark brown and black -loose -wet (FILL: SP)

Poorly graded sand with gravel, organic odor noted - darkgray to dark brown - loose - wet (SP)



Silt with sand - light brown - medium dense to loose - wet(ML)



0.2

2.5

7.5

10.0

15.0

25.0

35.0

1

2

3

4

5

6

7

8

9

SS

PA

SS

PA

SS

PA

SS

PA

SS

HW

RB

SS

RB

SS

RB

SS

RB

SS

RB

7/OGDEN SS2 (PMT)

ARCHITECT-ENGINEER


CO

VE

RY

CLIENT

SA

MP

LE D

IST

AN

CE

DE

PT

H(F

T)

ELE

VA

TIO

N(F

T)


WATERCONTENT %


SITE LOCATION

5.0

10.0

15.0

20.0

25.0

30.0

35.0


UN

IT D

RY

WT

.

LBS

./FT

.3

1 2 3 4 5

10 20 30 40 50

600637



SA

MP

LE T

YP

E

LIQUIDLIMIT %

PLASTICLIMIT %

AECOMS

AM

PLE

NO

.


PROJECT NAME


10 20 30 40 50

AE

CO

M L

OG

60

4455

40

AT

C O

GD

EN

.GP

J F

S_D

AT

AT

EM

PLA

TE

.GD

T 1

/15/

16


OF60445540 2

*. . . continued


4

3

5

3

5

7

6

16

4


Clayey silt - light brown - loose - wet (CL-ML)

Sandy lean clay - brown - very stiff (CL)


38.5

40.0

*

10

11

SS

RB

SS

7/OGDEN SS2 (PMT)

ARCHITECT-ENGINEER


CO

VE

RY

CLIENT

SA

MP

LE D

IST

AN

CE

DE

PT

H(F

T)

ELE

VA

TIO

N(F

T)


WATERCONTENT %


SITE LOCATION

40.0


UN

IT D

RY

WT

.

LBS

./FT

.3

(Continued)

1 2 3 4 5

10 20 30 40 50

600637



SA

MP

LE T

YP

E

LIQUIDLIMIT %

PLASTICLIMIT %

AECOMS

AM

PLE

NO

.


PROJECT NAME


10 20 30 40 50

AE

CO

M L

OG

60

4455

40

AT

C O

GD

EN

.GP

J F

S_D

AT

AT

EM

PLA

TE

.GD

T 1

/15/

16


EASTING

WL

468988

2587361

W.L. @ 7.5' W.S.

AMHENTERED BY

11/3/15



OF

APP'D BY

2AECOM JOB NO.


60445540RIG/FOREMAN

2


11/3/15

7

33

Calibrated Penetrometer*

FILL: Silt with topsoil - reddish brown - medium dense -moist (FILL: ML)

FILL: Poorly graded sand with silt - tan - medum dense -moist to wet (FILL: SP-SM)

FILL: SIlty sand with organics and wood - gray to darkgray - loose to very loose - wet (FILL: SM)

Organic silt with sand - black and dark brown - loose -wet (OL)

Note: Hard drilling from 10 ft to 14.5 ft

Poorly graded sand with silt, organics and roots noted -dark brown - medium dense - wet (SP-SM)


Dark brown sand with silt, peat or wood stuck in sampler- loose - wet (SP-SM)

End of boring at 21.5 feet below ground surface due torefusal on debris inferred to be wood piling. Boringadvanced to 10 feet with solid stem augers. Mud rotarymethods used below 10 feet deep, with HW casinginstalled to 15.5 feet. Borehole grouted. Relocated boring5 feet south for boring 7/River Crossing 2A.

2.5

5.0

10.0

15.0

20.0

21.5

1

2

3

4

5

6

7

SS

PA

SS

PA

SS

PA

SS

PA

SS

RB

SS

RB

SS21.5

7/RIVER XING 2 (PMT)

ARCHITECT-ENGINEER


CO

VE

RY

CLIENT

SA

MP

LE D

IST

AN

CE

DE

PT

H(F

T)

ELE

VA

TIO

N(F

T)


WATERCONTENT %


SITE LOCATION

5.0

10.0

15.0

20.0


UN

IT D

RY

WT

.

LBS

./FT

.3

1 2 3 4 5

10 20 30 40 50

600643



SA

MP

LE T

YP

E

LIQUIDLIMIT %

PLASTICLIMIT %

AECOMS

AM

PLE

NO

.


PROJECT NAME


10 20 30 40 50

AE

CO

M L

OG

60

4455

40

AT

C O

GD

EN

.GP

J F

S_D

AT

AT

EM

PLA

TE

.GD

T 1

/15/

16


EASTING

WL

114702

26091152

W.L. @ 4.2' B.C.I.

AMHENTERED BY

11/4/15



OF

APP'D BY

1AECOM JOB NO.


60445540RIG/FOREMAN

1


11/4/15

12

12

9

1

4

22

6

87.1

Blind drilling (no sampling). Refer to boring 7/River Xing2 for stratigraphy.

Poorly graded sand - brown and gray - medium dense -wet (SP)

Pressuremeter Test #1: 21.0 ft - 23.5 ftPf = 50 tsf, Ed = 89 tsf

Clayey silt - brown - loose to very loose -wet (CL-ML)



20.5

25.0

1

2

3

PA

RB

SS

RB

SS

RB

SS

RB

7/RIVER XING 2A (PMT)

ARCHITECT-ENGINEER


CO

VE

RY

CLIENT

SA

MP

LE D

IST

AN

CE

DE

PT

H(F

T)

ELE

VA

TIO

N(F

T)


WATERCONTENT %


SITE LOCATION

5.0

10.0

15.0

20.0

25.0

30.0

35.0


UN

IT D

RY

WT

.

LBS

./FT

.3

1 2 3 4 5

10 20 30 40 50

600643



SA

MP

LE T

YP

E

LIQUIDLIMIT %

PLASTICLIMIT %

AECOMS

AM

PLE

NO

.


PROJECT NAME


10 20 30 40 50

AE

CO

M L

OG

60

4455

40

AT

C O

GD

EN

.GP

J F

S_D

AT

AT

EM

PLA

TE

.GD

T 1

/15/

16


OF60445540 2

*. . . continued


12

3

5


Clayey silt - brown - loose to very loose -wet (CL-ML)

Lean clay - brown - stiff (CL)

Poorly graded gravel with lean clay - brown and gray -extremely dense - wet (GP-GC)End of boring at 44.2 feet below ground surface. Boringadvanced to 15 feet with solid stem augers. Mud rotarymethods used below 15 feet deep, with HW casinginstalled to 20.5 feet. Sampling not performed fromground surface to depth of 20.5 feet, refer to boring7/River Crossing 2 for soil information in this depthinterval. Borehole grouted.

38.5

43.544.2

*

4

5

6

SS

RB

SS

RB

SS44.2

7/RIVER XING 2A (PMT)

ARCHITECT-ENGINEER


CO

VE

RY

CLIENT

SA

MP

LE D

IST

AN

CE

DE

PT

H(F

T)

ELE

VA

TIO

N(F

T)


WATERCONTENT %


SITE LOCATION

40.0


UN

IT D

RY

WT

.

LBS

./FT

.3

(Continued)

1 2 3 4 5

10 20 30 40 50

600643



SA

MP

LE T

YP

E

LIQUIDLIMIT %

PLASTICLIMIT %

AECOMS

AM

PLE

NO

.


PROJECT NAME


10 20 30 40 50

AE

CO

M L

OG

60

4455

40

AT

C O

GD

EN

.GP

J F

S_D

AT

AT

EM

PLA

TE

.GD

T 1

/15/

16


EASTING

WL

114702

26091152

W.L. @ 4.0' A.B.

AMHENTERED BY

11/4/15



OF

APP'D BY

2AECOM JOB NO.


60445540RIG/FOREMAN

2


11/4/15

WOH/6"

4

50/2"


*

FILL: Silty sand with gravel - dark brown - medium dense- moist (FILL: SM)

FILL: Silty sand with gravel, clay, wood, and cinders -reddish brown - medium dense to loose - moist to wet(FILL: SM)

FILL: Poorly graded sand with gravel - reddish brown -medium dense - wet (FILL: SP)

FILL: Clayey silt with wood, glass, gravel, and plastic -dark gray - loose - wet (FILL: CL-ML)

FILL: Organic clayey sand with roots - black - very loose- wet (FILL: SC)

Poorly graded sand with gravel - brown to dark gray -loose to medium dense - wet (SP)

Silty sand - light brown - dense - wet (SM)


5.0

11.0

12.5

15.0

17.5

27.5

29.0

1

2

3

4

55A

6

7

8

9

10

11

SS

PA

SS

PA

SS

PA

SS

PA

SSSSRB

SS

RB

SS

RB

SS

RB

SS

RB

SS

RB

SS29.0

8/1

ARCHITECT-ENGINEER


CO

VE

RY

CLIENT

SA

MP

LE D

IST

AN

CE

DE

PT

H(F

T)

ELE

VA

TIO

N(F

T)


WATERCONTENT %


SITE LOCATION

5.0

10.0

15.0

20.0

25.0


UN

IT D

RY

WT

.

LBS

./FT

.3

1 2 3 4 5

10 20 30 40 50

600643



SA

MP

LE T

YP

E

LIQUIDLIMIT %

PLASTICLIMIT %

AECOMS

AM

PLE

NO

.


PROJECT NAME


10 20 30 40 50

AE

CO

M L

OG

60

4455

40

AT

C O

GD

EN

.GP

J F

S_D

AT

AT

EM

PLA

TE

.GD

T 1

/15/

16


EASTING

WL

114368

26090877

W.L. @ 6.1' W.S.

AMHENTERED BY

11/2/15



OF

APP'D BY

1AECOM JOB NO.


60445540RIG/FOREMAN

1


11/2/15

21

12

10

27

3/6"

6/6"

5

2

8

10

11

46

96.2





Appendix D

GEI – 2018-2019 Subsurface Assessment Documentation


2018 - GEI Groundwater Sampling

Laboratory Report

Well Installation Diagrams


Laboratory Report

#=CL#

February 15, 2018

LIMS USE: FR - PAUL KILLIANLIMS OBJECT ID: 40164423


RE:

Paul KillianGEI Consultants, Inc.3159 Voyager DriveGreen Bay, WI 54311

1700952 ATC-MARINETTE

Dear Paul Killian:Enclosed are the analytical results for sample(s) received by the laboratory on February 07, 2018.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,

Christopher [email protected]

Project Manager(920)469-2436

Enclosures


without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC1241 Bellevue Street - Suite 9

Green Bay, WI 54302(920)469-2436

Page 1 of 24

#=CP#

CERTIFICATIONS



Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky UST Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334New York Certification #: 12064North Dakota Certification #: R-150

Virginia VELAP ID: 460263South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1Wisconsin Certification #: 405132750Wisconsin DATCP Certification #: 105-444USDA Soil Permit #: P330-16-00157Federal Fish & Wildlife Permit #: LE51774A-0




Green Bay, WI 54302(920)469-2436

Page 2 of 24

#=SS#

SAMPLE SUMMARY



Lab ID Sample ID Matrix Date Collected Date Received

40164423001 S-PZ Water 02/07/18 08:42 02/07/18 15:03

40164423002 S-MW Water 02/07/18 10:00 02/07/18 15:03

40164423003 N-MW Water 02/07/18 11:30 02/07/18 15:03

40164423004 N-PZ Water 02/07/18 12:00 02/07/18 15:03




Green Bay, WI 54302(920)469-2436

Page 3 of 24

#=SA#

SAMPLE ANALYTE COUNT



Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

40164423001 S-PZ EPA 6010 7 PASI-GJLD

EPA 7470 1 PASI-GAJT

EPA 8260 64 PASI-GLAP

40164423002 S-MW EPA 6010 7 PASI-GJLD



40164423003 N-MW EPA 6010 7 PASI-GJLD



40164423004 N-PZ EPA 6010 7 PASI-GJLD






Green Bay, WI 54302(920)469-2436

Page 4 of 24

#=HO#

SUMMARY OF DETECTION



Parameters AnalyzedResultLab Sample ID

Report Limit QualifiersUnitsMethodClient Sample ID

40164423001 S-PZArsenic 627 ug/L 02/13/18 13:3325.0EPA 6010Barium 332 ug/L 02/13/18 13:335.0EPA 6010Chromium 16.0 ug/L 02/13/18 13:3310.0EPA 6010Lead 23.3 ug/L 02/13/18 13:3313.0EPA 6010

40164423002 S-MWArsenic 27.9 ug/L 02/13/18 13:35 1q25.0EPA 6010Barium 285 ug/L 02/13/18 13:355.0EPA 6010Cadmium 1.6J ug/L 02/13/18 13:355.0EPA 6010Chromium 20.4 ug/L 02/13/18 13:3510.0EPA 6010Lead 798 ug/L 02/13/18 13:3513.0EPA 6010Mercury 0.46 ug/L 02/13/18 08:450.42EPA 7470Benzene 1.4 ug/L 02/08/18 17:291.0EPA 8260n-Butylbenzene 1.3 ug/L 02/08/18 17:291.0EPA 8260Chlorobenzene 18.9 ug/L 02/08/18 17:291.0EPA 82601,4-Dichlorobenzene 1.7 ug/L 02/08/18 17:291.0EPA 8260Dichlorodifluoromethane 0.29J ug/L 02/08/18 17:291.0EPA 8260Isopropylbenzene (Cumene) 5.0 ug/L 02/08/18 17:291.0EPA 8260Styrene 5.8 ug/L 02/08/18 17:291.0EPA 8260Toluene 4.7 ug/L 02/08/18 17:291.0EPA 82601,2,4-Trimethylbenzene 9.2 ug/L 02/08/18 17:291.0EPA 8260m&p-Xylene 1.8J ug/L 02/08/18 17:292.0EPA 8260

40164423003 N-MWArsenic 12.8J ug/L 02/13/18 13:37 1q25.0EPA 6010Barium 292 ug/L 02/13/18 13:375.0EPA 6010Chromium 20.4 ug/L 02/13/18 13:3710.0EPA 6010Lead 35.6 ug/L 02/13/18 13:3713.0EPA 6010Mercury 0.15J ug/L 02/13/18 08:480.42EPA 7470

40164423004 N-PZArsenic 20.3J ug/L 02/13/18 13:40 1q25.0EPA 6010Barium 270 ug/L 02/13/18 13:405.0EPA 6010Chromium 2.9J ug/L 02/13/18 13:4010.0EPA 6010Lead 12.9J ug/L 02/13/18 13:4013.0EPA 6010




Green Bay, WI 54302(920)469-2436

Page 5 of 24

#=AR#

ANALYTICAL RESULTS



Sample: S-PZ Lab ID: 40164423001 Collected: 02/07/18 08:42 Received: 02/07/18 15:03 Matrix: Water



Arsenic 627 ug/L 02/13/18 13:33 7440-38-202/12/18 07:5325.0 8.3 1Barium 332 ug/L 02/13/18 13:33 7440-39-302/12/18 07:535.0 1.5 1Cadmium <1.3 ug/L 02/13/18 13:33 7440-43-902/12/18 07:535.0 1.3 1Chromium 16.0 ug/L 02/13/18 13:33 7440-47-302/12/18 07:5310.0 2.5 1Lead 23.3 ug/L 02/13/18 13:33 7439-92-102/12/18 07:5313.0 4.3 1Selenium <16.6 ug/L 02/13/18 13:33 7782-49-202/12/18 07:5350.0 16.6 1Silver <3.3 ug/L 02/13/18 13:33 7440-22-402/12/18 07:5310.0 3.3 1


Mercury <0.13 ug/L 02/13/18 08:39 7439-97-602/12/18 10:550.42 0.13 1

Analytical Method: EPA 82608260 MSV

Benzene <0.50 ug/L 02/08/18 16:45 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 02/08/18 16:45 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 02/08/18 16:45 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 02/08/18 16:45 75-27-41.0 0.50 1Bromoform <0.50 ug/L 02/08/18 16:45 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 02/08/18 16:45 74-83-95.0 2.4 1n-Butylbenzene <0.50 ug/L 02/08/18 16:45 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 02/08/18 16:45 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 02/08/18 16:45 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 02/08/18 16:45 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 02/08/18 16:45 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 02/08/18 16:45 75-00-31.0 0.37 1Chloroform <2.5 ug/L 02/08/18 16:45 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 02/08/18 16:45 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 02/08/18 16:45 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 02/08/18 16:45 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 02/08/18 16:45 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 02/08/18 16:45 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 02/08/18 16:45 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 02/08/18 16:45 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 02/08/18 16:45 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 02/08/18 16:45 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 02/08/18 16:45 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 02/08/18 16:45 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 02/08/18 16:45 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 02/08/18 16:45 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 02/08/18 16:45 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 02/08/18 16:45 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 02/08/18 16:45 156-60-51.0 0.26 11,2-Dichloropropane <0.23 ug/L 02/08/18 16:45 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 02/08/18 16:45 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 02/08/18 16:45 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 02/08/18 16:45 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 02/08/18 16:45 10061-01-51.0 0.50 1


without the written consent of Pace Analytical Services, LLC.Date: 02/15/2018 07:31 AM


Green Bay, WI 54302(920)469-2436

Page 6 of 24

#=AR#

ANALYTICAL RESULTS






trans-1,3-Dichloropropene <0.23 ug/L 02/08/18 16:45 10061-02-61.0 0.23 1Diisopropyl ether <0.50 ug/L 02/08/18 16:45 108-20-31.0 0.50 1Ethylbenzene <0.50 ug/L 02/08/18 16:45 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 02/08/18 16:45 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 02/08/18 16:45 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 02/08/18 16:45 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 02/08/18 16:45 75-09-21.0 0.23 1Methyl-tert-butyl ether <0.17 ug/L 02/08/18 16:45 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 02/08/18 16:45 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 02/08/18 16:45 103-65-11.0 0.50 1Styrene <0.50 ug/L 02/08/18 16:45 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 02/08/18 16:45 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 02/08/18 16:45 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 02/08/18 16:45 127-18-41.0 0.50 1Toluene <0.50 ug/L 02/08/18 16:45 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 02/08/18 16:45 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 02/08/18 16:45 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 02/08/18 16:45 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 02/08/18 16:45 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 02/08/18 16:45 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 02/08/18 16:45 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 02/08/18 16:45 96-18-41.0 0.50 11,2,4-Trimethylbenzene <0.50 ug/L 02/08/18 16:45 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 02/08/18 16:45 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 02/08/18 16:45 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 02/08/18 16:45 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 02/08/18 16:45 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 95 % 02/08/18 16:45 460-00-461-130 1Dibromofluoromethane (S) 99 % 02/08/18 16:45 1868-53-767-130 1Toluene-d8 (S) 98 % 02/08/18 16:45 2037-26-570-130 1




Green Bay, WI 54302(920)469-2436

Page 7 of 24

#=AR#

ANALYTICAL RESULTS



Sample: S-MW Lab ID: 40164423002 Collected: 02/07/18 10:00 Received: 02/07/18 15:03 Matrix: Water



Arsenic 27.9 ug/L 02/13/18 13:35 7440-38-2 1q02/12/18 07:5325.0 8.3 1Barium 285 ug/L 02/13/18 13:35 7440-39-302/12/18 07:535.0 1.5 1Cadmium 1.6J ug/L 02/13/18 13:35 7440-43-902/12/18 07:535.0 1.3 1Chromium 20.4 ug/L 02/13/18 13:35 7440-47-302/12/18 07:5310.0 2.5 1Lead 798 ug/L 02/13/18 13:35 7439-92-102/12/18 07:5313.0 4.3 1Selenium <16.6 ug/L 02/13/18 13:35 7782-49-202/12/18 07:5350.0 16.6 1Silver <3.3 ug/L 02/13/18 13:35 7440-22-402/12/18 07:5310.0 3.3 1


Mercury 0.46 ug/L 02/13/18 08:45 7439-97-602/12/18 10:550.42 0.13 1


Benzene 1.4 ug/L 02/08/18 17:29 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 02/08/18 17:29 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 02/08/18 17:29 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 02/08/18 17:29 75-27-41.0 0.50 1Bromoform <0.50 ug/L 02/08/18 17:29 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 02/08/18 17:29 74-83-95.0 2.4 1n-Butylbenzene 1.3 ug/L 02/08/18 17:29 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 02/08/18 17:29 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 02/08/18 17:29 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 02/08/18 17:29 56-23-51.0 0.50 1Chlorobenzene 18.9 ug/L 02/08/18 17:29 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 02/08/18 17:29 75-00-31.0 0.37 1Chloroform <2.5 ug/L 02/08/18 17:29 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 02/08/18 17:29 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 02/08/18 17:29 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 02/08/18 17:29 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 02/08/18 17:29 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 02/08/18 17:29 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 02/08/18 17:29 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 02/08/18 17:29 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 02/08/18 17:29 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 02/08/18 17:29 541-73-11.0 0.50 11,4-Dichlorobenzene 1.7 ug/L 02/08/18 17:29 106-46-71.0 0.50 1Dichlorodifluoromethane 0.29J ug/L 02/08/18 17:29 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 02/08/18 17:29 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 02/08/18 17:29 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 02/08/18 17:29 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 02/08/18 17:29 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 02/08/18 17:29 156-60-51.0 0.26 11,2-Dichloropropane <0.23 ug/L 02/08/18 17:29 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 02/08/18 17:29 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 02/08/18 17:29 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 02/08/18 17:29 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 02/08/18 17:29 10061-01-51.0 0.50 1




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ANALYTICAL RESULTS






trans-1,3-Dichloropropene <0.23 ug/L 02/08/18 17:29 10061-02-61.0 0.23 1Diisopropyl ether <0.50 ug/L 02/08/18 17:29 108-20-31.0 0.50 1Ethylbenzene <0.50 ug/L 02/08/18 17:29 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 02/08/18 17:29 87-68-35.0 2.1 1Isopropylbenzene (Cumene) 5.0 ug/L 02/08/18 17:29 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 02/08/18 17:29 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 02/08/18 17:29 75-09-21.0 0.23 1Methyl-tert-butyl ether <0.17 ug/L 02/08/18 17:29 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 02/08/18 17:29 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 02/08/18 17:29 103-65-11.0 0.50 1Styrene 5.8 ug/L 02/08/18 17:29 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 02/08/18 17:29 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 02/08/18 17:29 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 02/08/18 17:29 127-18-41.0 0.50 1Toluene 4.7 ug/L 02/08/18 17:29 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 02/08/18 17:29 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 02/08/18 17:29 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 02/08/18 17:29 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 02/08/18 17:29 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 02/08/18 17:29 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 02/08/18 17:29 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 02/08/18 17:29 96-18-41.0 0.50 11,2,4-Trimethylbenzene 9.2 ug/L 02/08/18 17:29 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 02/08/18 17:29 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 02/08/18 17:29 75-01-41.0 0.18 1m&p-Xylene 1.8J ug/L 02/08/18 17:29 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 02/08/18 17:29 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 97 % 02/08/18 17:29 460-00-461-130 1Dibromofluoromethane (S) 97 % 02/08/18 17:29 1868-53-767-130 1Toluene-d8 (S) 97 % 02/08/18 17:29 2037-26-570-130 1




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ANALYTICAL RESULTS



Sample: N-MW Lab ID: 40164423003 Collected: 02/07/18 11:30 Received: 02/07/18 15:03 Matrix: Water



Arsenic 12.8J ug/L 02/13/18 13:37 7440-38-2 1q02/12/18 07:5325.0 8.3 1Barium 292 ug/L 02/13/18 13:37 7440-39-302/12/18 07:535.0 1.5 1Cadmium <1.3 ug/L 02/13/18 13:37 7440-43-902/12/18 07:535.0 1.3 1Chromium 20.4 ug/L 02/13/18 13:37 7440-47-302/12/18 07:5310.0 2.5 1Lead 35.6 ug/L 02/13/18 13:37 7439-92-102/12/18 07:5313.0 4.3 1Selenium <16.6 ug/L 02/13/18 13:37 7782-49-202/12/18 07:5350.0 16.6 1Silver <3.3 ug/L 02/13/18 13:37 7440-22-402/12/18 07:5310.0 3.3 1


Mercury 0.15J ug/L 02/13/18 08:48 7439-97-602/12/18 10:550.42 0.13 1






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ANALYTICAL RESULTS










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ANALYTICAL RESULTS



Sample: N-PZ Lab ID: 40164423004 Collected: 02/07/18 12:00 Received: 02/07/18 15:03 Matrix: Water



Arsenic 20.3J ug/L 02/13/18 13:40 7440-38-2 1q02/12/18 07:5325.0 8.3 1Barium 270 ug/L 02/13/18 13:40 7440-39-302/12/18 07:535.0 1.5 1Cadmium <1.3 ug/L 02/13/18 13:40 7440-43-902/12/18 07:535.0 1.3 1Chromium 2.9J ug/L 02/13/18 13:40 7440-47-302/12/18 07:5310.0 2.5 1Lead 12.9J ug/L 02/13/18 13:40 7439-92-102/12/18 07:5313.0 4.3 1Selenium <16.6 ug/L 02/13/18 13:40 7782-49-202/12/18 07:5350.0 16.6 1Silver <3.3 ug/L 02/13/18 13:40 7440-22-402/12/18 07:5310.0 3.3 1


Mercury <0.13 ug/L 02/13/18 08:50 7439-97-602/12/18 10:550.42 0.13 1






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ANALYTICAL RESULTS










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#=QC#







280982EPA 7470


Associated Lab Samples: 40164423001, 40164423002, 40164423003, 40164423004



METHOD BLANK: 1647988Associated Lab Samples: 40164423001, 40164423002, 40164423003, 40164423004

Matrix: Water

Analyzed

Mercury ug/L <0.13 0.42 02/13/18 08:34

Parameter UnitsLCS



Mercury ug/L 5.35 106 85-115

Parameter UnitsMS



MSSpikeResult

40164423001

1647813

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Mercury ug/L 5 109 85-115105 4 205<0.13 5.5 5.3




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#=QC#







280893EPA 3010

EPA 60106010 MET





Matrix: Water

Analyzed

Arsenic ug/L <8.3 25.0 02/14/18 11:01Barium ug/L <1.5 5.0 02/14/18 11:01Cadmium ug/L <1.3 5.0 02/14/18 11:01Chromium ug/L <2.5 10.0 02/14/18 11:01Lead ug/L <4.3 13.0 02/14/18 11:01Selenium ug/L <16.6 50.0 02/14/18 11:01Silver ug/L <3.3 10.0 02/14/18 11:01

Parameter UnitsLCS



Arsenic ug/L 480500 96 80-120Barium ug/L 491500 98 80-120Cadmium ug/L 486500 97 80-120Chromium ug/L 488500 98 80-120Lead ug/L 476500 95 80-120Selenium ug/L 473500 95 80-120Silver ug/L 244250 98 80-120

Parameter UnitsMS



MSSpikeResult

40164377001

1647146

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Arsenic ug/L 500 99 75-12599 1 20500<8.3 494 498Barium ug/L 500 101 75-125102 1 2050022.2 529 534Cadmium ug/L 500 98 75-12599 1 20500<1.3 489 495Chromium ug/L 500 98 75-12599 0 205003.1J 495 496Lead ug/L 500 93 75-12595 2 20500<4.3 469 477Selenium ug/L 500 95 75-12598 3 20500<16.6 474 489Silver ug/L 250 99 75-125100 1 20250<3.3 248 251




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280763EPA 8260

EPA 82608260 MSV





Matrix: Water

Analyzed

1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 02/08/18 07:471,1,1-Trichloroethane ug/L <0.50 1.0 02/08/18 07:471,1,2,2-Tetrachloroethane ug/L <0.25 1.0 02/08/18 07:471,1,2-Trichloroethane ug/L <0.20 1.0 02/08/18 07:471,1-Dichloroethane ug/L <0.24 1.0 02/08/18 07:471,1-Dichloroethene ug/L <0.41 1.0 02/08/18 07:471,1-Dichloropropene ug/L <0.44 1.0 02/08/18 07:471,2,3-Trichlorobenzene ug/L <2.1 5.0 02/08/18 07:471,2,3-Trichloropropane ug/L <0.50 1.0 02/08/18 07:471,2,4-Trichlorobenzene ug/L <2.2 5.0 02/08/18 07:471,2,4-Trimethylbenzene ug/L <0.50 1.0 02/08/18 07:471,2-Dibromo-3-chloropropane ug/L <2.2 5.0 02/08/18 07:471,2-Dibromoethane (EDB) ug/L <0.18 1.0 02/08/18 07:471,2-Dichlorobenzene ug/L <0.50 1.0 02/08/18 07:471,2-Dichloroethane ug/L <0.17 1.0 02/08/18 07:471,2-Dichloropropane ug/L <0.23 1.0 02/08/18 07:471,3,5-Trimethylbenzene ug/L <0.50 1.0 02/08/18 07:471,3-Dichlorobenzene ug/L <0.50 1.0 02/08/18 07:471,3-Dichloropropane ug/L <0.50 1.0 02/08/18 07:471,4-Dichlorobenzene ug/L <0.50 1.0 02/08/18 07:472,2-Dichloropropane ug/L <0.48 1.0 02/08/18 07:472-Chlorotoluene ug/L <0.50 1.0 02/08/18 07:474-Chlorotoluene ug/L <0.21 1.0 02/08/18 07:47Benzene ug/L <0.50 1.0 02/08/18 07:47Bromobenzene ug/L <0.23 1.0 02/08/18 07:47Bromochloromethane ug/L <0.34 1.0 02/08/18 07:47Bromodichloromethane ug/L <0.50 1.0 02/08/18 07:47Bromoform ug/L <0.50 1.0 02/08/18 07:47Bromomethane ug/L <2.4 5.0 02/08/18 07:47Carbon tetrachloride ug/L <0.50 1.0 02/08/18 07:47Chlorobenzene ug/L <0.50 1.0 02/08/18 07:47Chloroethane ug/L <0.37 1.0 02/08/18 07:47Chloroform ug/L <2.5 5.0 02/08/18 07:47Chloromethane ug/L <0.50 1.0 02/08/18 07:47cis-1,2-Dichloroethene ug/L <0.26 1.0 02/08/18 07:47cis-1,3-Dichloropropene ug/L <0.50 1.0 02/08/18 07:47Dibromochloromethane ug/L <0.50 1.0 02/08/18 07:47Dibromomethane ug/L <0.43 1.0 02/08/18 07:47Dichlorodifluoromethane ug/L <0.22 1.0 02/08/18 07:47Diisopropyl ether ug/L <0.50 1.0 02/08/18 07:47Ethylbenzene ug/L <0.50 1.0 02/08/18 07:47




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Matrix: Water

Analyzed

Hexachloro-1,3-butadiene ug/L <2.1 5.0 02/08/18 07:47Isopropylbenzene (Cumene) ug/L <0.14 1.0 02/08/18 07:47m&p-Xylene ug/L <1.0 2.0 02/08/18 07:47Methyl-tert-butyl ether ug/L <0.17 1.0 02/08/18 07:47Methylene Chloride ug/L <0.23 1.0 02/08/18 07:47n-Butylbenzene ug/L <0.50 1.0 02/08/18 07:47n-Propylbenzene ug/L <0.50 1.0 02/08/18 07:47Naphthalene ug/L <2.5 5.0 02/08/18 07:47o-Xylene ug/L <0.50 1.0 02/08/18 07:47p-Isopropyltoluene ug/L <0.50 1.0 02/08/18 07:47sec-Butylbenzene ug/L <2.2 5.0 02/08/18 07:47Styrene ug/L <0.50 1.0 02/08/18 07:47tert-Butylbenzene ug/L <0.18 1.0 02/08/18 07:47Tetrachloroethene ug/L <0.50 1.0 02/08/18 07:47Toluene ug/L <0.50 1.0 02/08/18 07:47trans-1,2-Dichloroethene ug/L <0.26 1.0 02/08/18 07:47trans-1,3-Dichloropropene ug/L <0.23 1.0 02/08/18 07:47Trichloroethene ug/L <0.33 1.0 02/08/18 07:47Trichlorofluoromethane ug/L <0.18 1.0 02/08/18 07:47Vinyl chloride ug/L <0.18 1.0 02/08/18 07:474-Bromofluorobenzene (S) % 97 61-130 02/08/18 07:47Dibromofluoromethane (S) % 97 67-130 02/08/18 07:47Toluene-d8 (S) % 99 70-130 02/08/18 07:47

Parameter UnitsLCS



1,1,1-Trichloroethane ug/L 52.050 104 70-1301,1,2,2-Tetrachloroethane ug/L 46.050 92 70-1301,1,2-Trichloroethane ug/L 50.550 101 70-1301,1-Dichloroethane ug/L 51.250 102 71-1321,1-Dichloroethene ug/L 48.350 97 75-1301,2,4-Trichlorobenzene ug/L 48.850 98 70-1301,2-Dibromo-3-chloropropane ug/L 44.350 89 63-1231,2-Dibromoethane (EDB) ug/L 49.550 99 70-1301,2-Dichlorobenzene ug/L 49.650 99 70-1301,2-Dichloroethane ug/L 51.250 102 70-1311,2-Dichloropropane ug/L 53.150 106 80-1201,3-Dichlorobenzene ug/L 49.850 100 70-1301,4-Dichlorobenzene ug/L 49.050 98 70-130Benzene ug/L 51.650 103 73-145Bromodichloromethane ug/L 50.650 101 70-130Bromoform ug/L 50.250 100 67-130Bromomethane ug/L 39.050 78 26-128




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Parameter UnitsLCS



Carbon tetrachloride ug/L 54.350 109 70-133Chlorobenzene ug/L 52.550 105 70-130Chloroethane ug/L 49.050 98 58-120Chloroform ug/L 51.250 102 80-121Chloromethane ug/L 38.550 77 40-127cis-1,2-Dichloroethene ug/L 46.850 94 70-130cis-1,3-Dichloropropene ug/L 51.850 104 70-130Dibromochloromethane ug/L 49.750 99 70-130Dichlorodifluoromethane ug/L 31.550 63 20-135Ethylbenzene ug/L 54.450 109 87-129Isopropylbenzene (Cumene) ug/L 50.750 101 70-130m&p-Xylene ug/L 114100 114 70-130Methyl-tert-butyl ether ug/L 46.650 93 66-143Methylene Chloride ug/L 46.750 93 70-130o-Xylene ug/L 54.250 108 70-130Styrene ug/L 48.850 98 70-130Tetrachloroethene ug/L 53.450 107 70-130Toluene ug/L 51.650 103 82-130trans-1,2-Dichloroethene ug/L 48.450 97 75-132trans-1,3-Dichloropropene ug/L 50.850 102 70-130Trichloroethene ug/L 54.050 108 70-130Trichlorofluoromethane ug/L 49.450 99 76-133Vinyl chloride ug/L 44.450 89 57-1364-Bromofluorobenzene (S) % 102 61-130Dibromofluoromethane (S) % 98 67-130Toluene-d8 (S) % 97 70-130

Parameter UnitsMS



MSSpikeResult

40164425007

1646719

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 102 70-134104 1 2050<0.50 51.2 51.81,1,2,2-Tetrachloroethane ug/L 50 94 70-13092 2 2050<0.25 46.8 46.01,1,2-Trichloroethane ug/L 50 100 70-130100 1 2050<0.20 50.1 49.81,1-Dichloroethane ug/L 50 101 71-133101 0 2050<0.24 50.7 50.61,1-Dichloroethene ug/L 50 94 75-13696 1 2050<0.41 47.2 47.91,2,4-Trichlorobenzene ug/L 50 100 70-13099 1 2050<2.2 49.9 49.61,2-Dibromo-3-chloropropane

ug/L 50 89 63-12386 4 2050<2.2 44.4 42.8

1,2-Dibromoethane (EDB) ug/L 50 97 70-13098 1 2050<0.18 48.4 48.91,2-Dichlorobenzene ug/L 50 100 70-13098 1 2050<0.50 49.8 49.21,2-Dichloroethane ug/L 50 100 70-131101 1 2050<0.17 50.1 50.71,2-Dichloropropane ug/L 50 106 80-120106 0 2050<0.23 53.1 52.91,3-Dichlorobenzene ug/L 50 100 70-130100 0 2050<0.50 50.1 50.01,4-Dichlorobenzene ug/L 50 99 70-13097 2 2050<0.50 49.6 48.6




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Parameter UnitsMS



MSSpikeResult

40164425007

1646719

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Benzene ug/L 50 102 73-145103 1 2050<0.50 50.8 51.5Bromodichloromethane ug/L 50 101 70-130102 1 2050<0.50 50.4 51.0Bromoform ug/L 50 99 67-13099 1 2050<0.50 49.7 49.4Bromomethane ug/L 50 78 26-12980 2 2050<2.4 39.0 39.8Carbon tetrachloride ug/L 50 106 70-134108 2 2050<0.50 53.1 54.0Chlorobenzene ug/L 50 104 70-130105 1 2050<0.50 51.8 52.5Chloroethane ug/L 50 98 58-12097 0 2050<0.37 48.8 48.7Chloroform ug/L 50 101 80-121102 1 2050<2.5 50.3 50.9Chloromethane ug/L 50 74 40-12874 1 2050<0.50 37.1 36.9cis-1,2-Dichloroethene ug/L 50 93 70-13093 0 20501.1 47.6 47.5cis-1,3-Dichloropropene ug/L 50 102 70-130104 1 2050<0.50 51.1 51.8Dibromochloromethane ug/L 50 99 70-13099 0 2050<0.50 49.3 49.5Dichlorodifluoromethane ug/L 50 58 20-14661 4 2050<0.22 29.2 30.3Ethylbenzene ug/L 50 107 87-129108 1 2050<0.50 53.3 54.1Isopropylbenzene (Cumene) ug/L 50 99 70-130101 2 2050<0.14 49.4 50.3m&p-Xylene ug/L 100 110 70-130112 1 20100<1.0 110 112Methyl-tert-butyl ether ug/L 50 92 66-14390 2 2050<0.17 45.9 45.0Methylene Chloride ug/L 50 92 70-13092 0 2050<0.23 46.1 46.0o-Xylene ug/L 50 106 70-130107 1 2050<0.50 53.0 53.5Styrene ug/L 50 96 70-13096 1 2050<0.50 47.9 48.2Tetrachloroethene ug/L 50 105 70-130108 3 2050<0.50 52.3 54.0Toluene ug/L 50 101 82-131103 2 2050<0.50 50.7 51.6trans-1,2-Dichloroethene ug/L 50 96 75-13597 1 2050<0.26 47.8 48.3trans-1,3-Dichloropropene ug/L 50 100 70-130101 1 2050<0.23 50.1 50.5Trichloroethene ug/L 50 107 70-130108 2 2050<0.33 53.3 54.1Trichlorofluoromethane ug/L 50 96 76-15098 3 2050<0.18 47.8 49.1Vinyl chloride ug/L 50 86 56-14388 3 20500.21J 43.1 44.24-Bromofluorobenzene (S) % 101 61-130101Dibromofluoromethane (S) % 97 67-13097Toluene-d8 (S) % 97 70-13098




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#=QL#

QUALIFIERS



DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above LOD.J - Estimated concentration at or above the LOD and below the LOQ.LOD - Limit of Detection adjusted for dilution factor and percent moisture.LOQ - Limit of Quantitation adjusted for dilution factor and percent moisture.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected at or above the adjusted LOD.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES


ANALYTE QUALIFIERS

Analyte was detected in the associated method blank at a concentration of -11.1 ug/L.1q




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#=CR#





40164423001 280893 281064S-PZ EPA 3010 EPA 601040164423002 280893 281064S-MW EPA 3010 EPA 601040164423003 280893 281064N-MW EPA 3010 EPA 601040164423004 280893 281064N-PZ EPA 3010 EPA 6010

40164423001 280982 281036S-PZ EPA 7470 EPA 747040164423002 280982 281036S-MW EPA 7470 EPA 747040164423003 280982 281036N-MW EPA 7470 EPA 747040164423004 280982 281036N-PZ EPA 7470 EPA 7470

40164423001 280763S-PZ EPA 826040164423002 280763S-MW EPA 826040164423003 280763N-MW EPA 826040164423004 280763N-PZ EPA 8260




Green Bay, WI 54302(920)469-2436

Page 21 of 24

Page

22

of 2

4(Please Print Clearly) UPPER MIDWEST REGION Page 1 of/ Company Name: Ge 1 t...onsvlk:-ll~rnt.. MN: 612-607-1700 WI: 920-469-2436

~t~b~~u Branch/Locatio n : GrerL" /3 tL(;V

, ceAnalytical• www.pacelabs.oom )Jh Project Contact : Me-l}{_,/ J,a n Quote#: Su_ cAr/; /-I I

Phone : CJ JA} 1./ ) 5' 5' z,t>o CHAIN OF CUSTODY Mail To Contact:

Project Number: / 7 00951- I; 'Prtoern!lon Cod!• Mall To Company: AsNone B=HCL C•H2S04 D=HN03 EcOf Water F=Methanol G=NaOH

Projec t Name: A I C · rtl ttr{fle.. i+e H•Sodium Bisulfate Solution !=Sodium Thiosulfate J=Othor Mall To Address:

Project State: \VI FILTERED? (YES/NO) Y / N

Sampled By (Print): R Ga-rv~ PRESERVATION Plett Invoice To Contact: (CODE)" ~

Sampled By (Sign): RvJ>~~.._-, ~ Invoice To Company:

PO#: I Regulatory I Program: ~£ Invoice To Address:

Data Package O"tions MS/MSD Matrix Codes l -~1:. (billable) 0 On your sample A•Aw W • Watet

0 EPA Level Ill B•Biola OW • Drinking Water

l ~ .......

(billable) C• Charoool GW • Ground Water ~'4: \..) Invoice To Phone:

0 EPA Level IV 0 NOT needed on 0•0~ SW • Surface Water S•Soil ww • Weste Water J ~ ~ ~ LAB COMMENTS your sample SI•SIOdge WP • Wipe ~ CLIENT Profile #

COU..EC'TIOH ~-...:: PACE LAB# CLIENT FIELD 10 MATRIX COMMENTS (Lab Use Only) DATE lWE Clt::.

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Transmit Prelim Rush Results by (complete what you want): Receipt Temp • ~ •c

Emalll1: ReQnquoshed By Oatetnme: Received By: Oaterrome:

Emall#2: ~Receipt pH Telephone: Relinquished By: Date/Time: Received By: Dato/Time: lt.djusted

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SampiM on HOLD ,,.. aubjec;t to Relinquished By Dato/Tlme Reoerved By: Dale/Tome: Presant(!!ot Pres~ opec: fat ptlclng and,..,. ... of liability Intact I Nonm:rct

... , ... _...._Q ... .. C019a(27Jun2006) ORIGINAL

Page

23

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4

Sample Preservation Receipt Form Pace Analytical Services. LLC 1241 Bellevue Street. Suite 9

Green Bay, WI 54302

Client Name: Project# Lf'6f faL{lf2..S Initial whe~ate/

- . . . r • ~

- Ill

I Glass I I Plastic j I Vials I ! Jars I ; General I ~ N ~ N ~ v 1 ~ -- . - VI <( Ai ~ .2. o ume .!!!. :a_ c 1: 1: -g (ml)

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010 2.5 I 5 I 10

011 2.5 I 5 I 10

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013 2.5 I 5 I 10

014 2.515110

015 2.5 I 5 I 10

016 2.s I 5 I 10

017 2.515110

018 2.515110

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020 2.5 I 5 I 10

olumn I

. AGlU 11iter amber glass BPlU 11iter plastic unpres DG9A 40 ml amber ascorbic JGFU 4 oz amber jar unpres

AGlH 1 liter amber glass HCL BP2N 500 ml plastic HN03 DG9T 40 ml amber Na Thio WGFU 4 oz clear jar unpres AG4S 125 mL amber glass H2S04 BP2Z 500 ml plastic NaOH, Znact VG9U 40 ml clear vial unpres WPFU 4 oz plastic jar unpres

AG4U 120 ml amber glass unpres BP3U 250 ml plastic unpres VG9H 40 mL clear vial HCL

AGSU 100 mL amber glass unpres BP3C 250 ml plastic NaOH VG9M 40 ml clear vial MeOH SPST 120 ml plastic Na Thiosulfate

AG2S 500 ml amber glass H2S04 BP3N 250 mL plastic HN03 VG90 40 ml clear vial 01 ZPLC ziploc bag BG3U 250 ml clear glass unpres BP3S 250 ml plastic H2S04 GN:

F-GB-C-046-Rev.OO (30Jan2018) Sample Preservation Receipt Form

·-. Page..!... of ~

Page 24 of 24

Document Name:

peAnalytica( Sample Condition Upon Receipt (SCUR) Document Revised: 31 Jan2018

Document No.: Issuing Authority: 1241 Bellevue Street, Green Bay, Wl54302 F-GB-C-<131-rev.06 Pace Green Bay Quality Office

Sample Condition Upon Receipt Form (SCUR)

Client Name: GEI Project#:

r UPS r Waltco Courier: r CS Logistics r Fed Ex r Speedee

f'1-Ciient r Pace Other: ·--------------------------Tracking#: ---------------------------------Custody Seal on Cooler/Box Present: r yes ~o Seals intact: r yes r no

Custody Seal on Samples Present: r yes JJ'(.oo Seals intact: r yes r no

Packing Material: r Bubble Wrap ~ubble Bags r None r Other

Thermometer Used SR • !lt±fr Type of Ice: @Yiue Dry None

Cooler Temperature Uncorr: _ Corr:

W0#:40164423 1111 II I 111111111111111 40164423

T Samples on fee, cooling process has begun

Temp Blank Present: r yes ,P""no

Temp should be above freezing to s•c. Biological Tissue Is Frozen: r yesr no

Date: t&.- 2=:::!._ 1

Person ex::ioing co~ntents:

Biota Samples may be received at s o•c.

Samples Arrived within Hold Time:

Sufficient Volume: D Yes A No O N/A

Correct Containers Used:

-Pace Containers Used:

-Pace IR Containers Used:

Containers Intact:

es ONo

0No

0 No

0 No

,;mes ONo

D Yes D No

D Yes No

DYes t0No

MS/MSD D Yes No

~Yes DNo

~es ONo

Filtered volume received for Dissolved tests

Sample Labels match COC:

-Includes date/time/ID/Anal sis

Trip Blank Present:

Trip Blank Custody Seals Present

Project Manager Review:

Matrix:

Initials:-----......,.,.,.=

ON/A 1.

ON/A 2.

O N/A 3.

O N/A 4.

ON/A 5.

Date/Time:

O N/A 6.

O N/A 7.

O N/A 8.

ON/A 9.

ON/A

Date: 2(1{( ~ ---{~~~~-------

Page __ of __

#=CL#

July 16, 2019

LIMS USE: FR - KYLE SANDMIRELIMS OBJECT ID: 40190553


RE:

Kyle SandmireGEI Consultants, Inc3159 Voyager DrGreen Bay, WI 54311

1902287 ATC OGDEN STREET

Dear Kyle Sandmire:Enclosed are the analytical results for sample(s) received by the laboratory on July 02, 2019. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 32

#=CP#

CERTIFICATIONS



Duluth Minnesota Cerification ID's4730 Oneota St., Duluth, MN 55807Minnesota Dept of Health Certification #: 1610186Montana DHHS Certification #: CERT0102

Wisconsin DNR Certification # : 999446800North Dakota Certification #: R-105






Green Bay, WI 54302(920)469-2436

Page 2 of 32

#=SS#

SAMPLE SUMMARY




40190553001 S-MW Water 07/02/19 08:00 07/02/19 17:05

40190553002 N-MW Water 07/02/19 08:35 07/02/19 17:05

40190553003 TRIP BLANK Water 07/02/19 00:00 07/02/19 17:05




Green Bay, WI 54302(920)469-2436

Page 3 of 32

#=SA#





40190553001 S-MW EPA 1664A OG (1999) 1 PASI-DULDJD2

EPA 420.1 (1983 & 1993) 1 PASI-DULKJD

EPA 6020 10 PASI-GDS1


EPA 8260 64 PASI-GSMT

SM 2540D 1 PASI-GKTS

SM 5210B 1 PASI-GJXM

EPA 9040 1 PASI-GALY

EPA 335.4 1 PASI-GDAW


40190553002 N-MW EPA 1664A OG (1999) 1 PASI-DULDJD2

EPA 420.1 (1983 & 1993) 1 PASI-DULKJD

EPA 6020 10 PASI-GDS1


EPA 8260 64 PASI-GSMT

SM 2540D 1 PASI-GKTS

SM 5210B 1 PASI-GJXM

EPA 9040 1 PASI-GALY



40190553003 TRIP BLANK EPA 8260 64 PASI-GSMT




Green Bay, WI 54302(920)469-2436

Page 4 of 32

#=HO#






40190553001 S-MWArsenic 21.0 ug/L 07/06/19 21:051.0EPA 6020Chromium 2.0J ug/L 07/06/19 21:053.4EPA 6020Copper 2.8J ug/L 07/06/19 21:053.6EPA 6020Lead 67.8 ug/L 07/06/19 21:051.0EPA 6020Nickel 1.6 ug/L 07/06/19 21:051.3EPA 6020Selenium 0.39J ug/L 07/06/19 21:051.1EPA 6020Zinc 132 ug/L 07/06/19 21:0515.3EPA 6020Benzene 0.28J ug/L 07/08/19 22:141.0EPA 8260Bromomethane 1.3J ug/L 07/08/19 22:145.0EPA 8260Chlorobenzene 1.3J ug/L 07/08/19 22:142.4EPA 8260Chloromethane 6.4J ug/L 07/08/19 22:147.3EPA 82601,2,4-Trimethylbenzene 0.91J ug/L 07/08/19 22:142.8EPA 8260Total Suspended Solids 27.1 mg/L 07/03/19 14:282.9SM 2540DBOD, 5 day 5.3 mg/L 07/08/19 11:392.0SM 5210BpH at 25 Degrees C 7.2 Std. Units 07/09/19 11:08 H60.10EPA 9040Cyanide 0.019J mg/L 07/08/19 15:13 B0.023EPA 335.4Phosphorus 1.9 mg/L 07/12/19 12:100.40EPA 365.4

40190553002 N-MWArsenic 10.1 ug/L 07/06/19 21:181.0EPA 6020Lead 0.52J ug/L 07/06/19 21:181.0EPA 6020Nickel 0.76J ug/L 07/06/19 21:181.3EPA 6020Bromomethane 1.2J ug/L 07/08/19 22:345.0EPA 8260Chloromethane 7.8 ug/L 07/08/19 22:347.3EPA 8260Total Suspended Solids 32.6 mg/L 07/03/19 14:282.0SM 2540DBOD, 5 day 6.1 mg/L 07/08/19 11:402.0SM 5210BpH at 25 Degrees C 7.2 Std. Units 07/09/19 11:11 H60.10EPA 9040Cyanide 0.026J mg/L 07/08/19 15:13 B,D30.045EPA 335.4Phosphorus 0.13J mg/L 07/12/19 12:110.40EPA 365.4




Green Bay, WI 54302(920)469-2436

Page 5 of 32

#=AR#

ANALYTICAL RESULTS





Analytical Method: EPA 1664A OG (1999)1664 HEM, Oil and Grease

Oil and Grease <0.71 mg/L 07/15/19 09:422.4 0.71 1

Analytical Method: EPA 420.1 (1983 & 1993) Preparation Method: EPA 420.1 (1983 & 1993)Phenolics, Total Recoverable

Phenolics, Total Recoverable <0.0096 mg/L 07/12/19 14:5107/12/19 10:310.032 0.0096 1

Analytical Method: EPA 6020 Preparation Method: EPA 30106020 MET ICPMS

Arsenic 21.0 ug/L 07/06/19 21:05 7440-38-207/05/19 06:351.0 0.28 1Beryllium <0.18 ug/L 07/06/19 21:05 7440-41-707/05/19 06:351.0 0.18 1Cadmium <0.15 ug/L 07/06/19 21:05 7440-43-907/05/19 06:351.0 0.15 1Chromium 2.0J ug/L 07/06/19 21:05 7440-47-307/05/19 06:353.4 1.0 1Copper 2.8J ug/L 07/06/19 21:05 7440-50-807/05/19 06:353.6 1.1 1Lead 67.8 ug/L 07/06/19 21:05 7439-92-107/05/19 06:351.0 0.24 1Nickel 1.6 ug/L 07/06/19 21:05 7440-02-007/05/19 06:351.3 0.40 1Selenium 0.39J ug/L 07/06/19 21:05 7782-49-207/05/19 06:351.1 0.32 1Silver <0.10 ug/L 07/06/19 21:05 7440-22-407/05/19 06:350.50 0.10 1Zinc 132 ug/L 07/06/19 21:05 7440-66-607/05/19 06:3515.3 4.6 1


Mercury <0.084 ug/L 07/09/19 08:31 7439-97-607/08/19 10:300.28 0.084 1


Benzene 0.28J ug/L 07/08/19 22:14 71-43-21.0 0.25 1Bromobenzene <0.24 ug/L 07/08/19 22:14 108-86-11.0 0.24 1Bromochloromethane <0.36 ug/L 07/08/19 22:14 74-97-55.0 0.36 1Bromodichloromethane <0.36 ug/L 07/08/19 22:14 75-27-41.2 0.36 1Bromoform <4.0 ug/L 07/08/19 22:14 75-25-213.2 4.0 1Bromomethane 1.3J ug/L 07/08/19 22:14 74-83-95.0 0.97 1n-Butylbenzene <0.71 ug/L 07/08/19 22:14 104-51-82.4 0.71 1sec-Butylbenzene <0.85 ug/L 07/08/19 22:14 135-98-85.0 0.85 1tert-Butylbenzene <0.30 ug/L 07/08/19 22:14 98-06-61.0 0.30 1Carbon tetrachloride <0.17 ug/L 07/08/19 22:14 56-23-51.0 0.17 1Chlorobenzene 1.3J ug/L 07/08/19 22:14 108-90-72.4 0.71 1Chloroethane <1.3 ug/L 07/08/19 22:14 75-00-35.0 1.3 1Chloroform <1.3 ug/L 07/08/19 22:14 67-66-35.0 1.3 1Chloromethane 6.4J ug/L 07/08/19 22:14 74-87-37.3 2.2 12-Chlorotoluene <0.93 ug/L 07/08/19 22:14 95-49-85.0 0.93 14-Chlorotoluene <0.76 ug/L 07/08/19 22:14 106-43-42.5 0.76 11,2-Dibromo-3-chloropropane <1.8 ug/L 07/08/19 22:14 96-12-85.9 1.8 1Dibromochloromethane <2.6 ug/L 07/08/19 22:14 124-48-18.7 2.6 11,2-Dibromoethane (EDB) <0.83 ug/L 07/08/19 22:14 106-93-42.8 0.83 1Dibromomethane <0.94 ug/L 07/08/19 22:14 74-95-33.1 0.94 11,2-Dichlorobenzene <0.71 ug/L 07/08/19 22:14 95-50-12.4 0.71 11,3-Dichlorobenzene <0.63 ug/L 07/08/19 22:14 541-73-12.1 0.63 11,4-Dichlorobenzene <0.94 ug/L 07/08/19 22:14 106-46-73.1 0.94 1Dichlorodifluoromethane <0.50 ug/L 07/08/19 22:14 75-71-85.0 0.50 1


without the written consent of Pace Analytical Services, LLC.Date: 07/16/2019 04:13 PM


Green Bay, WI 54302(920)469-2436

Page 6 of 32

#=AR#

ANALYTICAL RESULTS






1,1-Dichloroethane <0.27 ug/L 07/08/19 22:14 75-34-31.0 0.27 11,2-Dichloroethane <0.28 ug/L 07/08/19 22:14 107-06-21.0 0.28 11,1-Dichloroethene <0.24 ug/L 07/08/19 22:14 75-35-41.0 0.24 1cis-1,2-Dichloroethene <0.27 ug/L 07/08/19 22:14 156-59-21.0 0.27 1trans-1,2-Dichloroethene <1.1 ug/L 07/08/19 22:14 156-60-53.6 1.1 11,2-Dichloropropane <0.28 ug/L 07/08/19 22:14 78-87-51.0 0.28 11,3-Dichloropropane <0.83 ug/L 07/08/19 22:14 142-28-92.8 0.83 12,2-Dichloropropane <2.3 ug/L 07/08/19 22:14 594-20-77.6 2.3 11,1-Dichloropropene <0.54 ug/L 07/08/19 22:14 563-58-61.8 0.54 1cis-1,3-Dichloropropene <3.6 ug/L 07/08/19 22:14 10061-01-512.1 3.6 1trans-1,3-Dichloropropene <4.4 ug/L 07/08/19 22:14 10061-02-614.6 4.4 1Diisopropyl ether <1.9 ug/L 07/08/19 22:14 108-20-36.3 1.9 1Ethylbenzene <0.22 ug/L 07/08/19 22:14 100-41-41.0 0.22 1Hexachloro-1,3-butadiene <1.2 ug/L 07/08/19 22:14 87-68-35.0 1.2 1Isopropylbenzene (Cumene) <0.39 ug/L 07/08/19 22:14 98-82-85.0 0.39 1p-Isopropyltoluene <0.80 ug/L 07/08/19 22:14 99-87-62.7 0.80 1Methylene Chloride <0.58 ug/L 07/08/19 22:14 75-09-25.0 0.58 1Methyl-tert-butyl ether <1.2 ug/L 07/08/19 22:14 1634-04-44.2 1.2 1Naphthalene <1.2 ug/L 07/08/19 22:14 91-20-35.0 1.2 1n-Propylbenzene <0.81 ug/L 07/08/19 22:14 103-65-15.0 0.81 1Styrene <0.47 ug/L 07/08/19 22:14 100-42-51.6 0.47 11,1,1,2-Tetrachloroethane <0.27 ug/L 07/08/19 22:14 630-20-61.0 0.27 11,1,2,2-Tetrachloroethane <0.28 ug/L 07/08/19 22:14 79-34-51.0 0.28 1Tetrachloroethene <0.33 ug/L 07/08/19 22:14 127-18-41.1 0.33 1Toluene <0.17 ug/L 07/08/19 22:14 108-88-35.0 0.17 11,2,3-Trichlorobenzene <0.63 ug/L 07/08/19 22:14 87-61-65.0 0.63 11,2,4-Trichlorobenzene <0.95 ug/L 07/08/19 22:14 120-82-15.0 0.95 11,1,1-Trichloroethane <0.24 ug/L 07/08/19 22:14 71-55-61.0 0.24 11,1,2-Trichloroethane <0.55 ug/L 07/08/19 22:14 79-00-55.0 0.55 1Trichloroethene <0.26 ug/L 07/08/19 22:14 79-01-61.0 0.26 1Trichlorofluoromethane <0.21 ug/L 07/08/19 22:14 75-69-41.0 0.21 11,2,3-Trichloropropane <0.59 ug/L 07/08/19 22:14 96-18-45.0 0.59 11,2,4-Trimethylbenzene 0.91J ug/L 07/08/19 22:14 95-63-62.8 0.84 11,3,5-Trimethylbenzene <0.87 ug/L 07/08/19 22:14 108-67-82.9 0.87 1Vinyl chloride <0.17 ug/L 07/08/19 22:14 75-01-4 L11.0 0.17 1m&p-Xylene <0.47 ug/L 07/08/19 22:14 179601-23-12.0 0.47 1o-Xylene <0.26 ug/L 07/08/19 22:14 95-47-61.0 0.26 1Surrogates4-Bromofluorobenzene (S) 93 % 07/08/19 22:14 460-00-470-130 1Dibromofluoromethane (S) 125 % 07/08/19 22:14 1868-53-770-130 1Toluene-d8 (S) 104 % 07/08/19 22:14 2037-26-570-130 1

Analytical Method: SM 2540D2540D Total Suspended Solids

Total Suspended Solids 27.1 mg/L 07/03/19 14:282.9 1.4 1




Green Bay, WI 54302(920)469-2436

Page 7 of 32

#=AR#

ANALYTICAL RESULTS





Analytical Method: SM 5210B Preparation Method: SM 5210B5210B BOD, 5 day

BOD, 5 day 5.3 mg/L 07/08/19 11:3907/03/19 06:002.0 2.0 1

Analytical Method: EPA 90409040 pH

pH at 25 Degrees C 7.2 Std. Units 07/09/19 11:08 H60.10 0.010 1

Analytical Method: EPA 335.4 Preparation Method: EPA 335.4335.4 Cyanide, Total

Cyanide 0.019J mg/L 07/08/19 15:13 57-12-5 B07/08/19 11:150.023 0.0068 1

Analytical Method: EPA 365.4 Preparation Method: EPA 365.4365.4 Total Phosphorus

Phosphorus 1.9 mg/L 07/12/19 12:10 7723-14-007/12/19 07:300.40 0.052 1




Green Bay, WI 54302(920)469-2436

Page 8 of 32

#=AR#

ANALYTICAL RESULTS





Analytical Method: EPA 1664A OG (1999)1664 HEM, Oil and Grease

Oil and Grease <0.71 mg/L 07/15/19 09:422.4 0.71 1

Analytical Method: EPA 420.1 (1983 & 1993) Preparation Method: EPA 420.1 (1983 & 1993)Phenolics, Total Recoverable

Phenolics, Total Recoverable <0.0096 mg/L 07/12/19 14:5207/12/19 10:310.032 0.0096 1

Analytical Method: EPA 6020 Preparation Method: EPA 30106020 MET ICPMS

Arsenic 10.1 ug/L 07/06/19 21:18 7440-38-207/05/19 06:351.0 0.28 1Beryllium <0.18 ug/L 07/06/19 21:18 7440-41-707/05/19 06:351.0 0.18 1Cadmium <0.15 ug/L 07/06/19 21:18 7440-43-907/05/19 06:351.0 0.15 1Chromium <1.0 ug/L 07/06/19 21:18 7440-47-307/05/19 06:353.4 1.0 1Copper <1.1 ug/L 07/06/19 21:18 7440-50-807/05/19 06:353.6 1.1 1Lead 0.52J ug/L 07/06/19 21:18 7439-92-107/05/19 06:351.0 0.24 1Nickel 0.76J ug/L 07/06/19 21:18 7440-02-007/05/19 06:351.3 0.40 1Selenium <0.32 ug/L 07/06/19 21:18 7782-49-207/05/19 06:351.1 0.32 1Silver <0.10 ug/L 07/06/19 21:18 7440-22-407/05/19 06:350.50 0.10 1Zinc <4.6 ug/L 07/06/19 21:18 7440-66-607/05/19 06:3515.3 4.6 1


Mercury <0.084 ug/L 07/09/19 08:34 7439-97-607/08/19 10:300.28 0.084 1


Benzene <0.25 ug/L 07/08/19 22:34 71-43-21.0 0.25 1Bromobenzene <0.24 ug/L 07/08/19 22:34 108-86-11.0 0.24 1Bromochloromethane <0.36 ug/L 07/08/19 22:34 74-97-55.0 0.36 1Bromodichloromethane <0.36 ug/L 07/08/19 22:34 75-27-41.2 0.36 1Bromoform <4.0 ug/L 07/08/19 22:34 75-25-213.2 4.0 1Bromomethane 1.2J ug/L 07/08/19 22:34 74-83-95.0 0.97 1n-Butylbenzene <0.71 ug/L 07/08/19 22:34 104-51-82.4 0.71 1sec-Butylbenzene <0.85 ug/L 07/08/19 22:34 135-98-85.0 0.85 1tert-Butylbenzene <0.30 ug/L 07/08/19 22:34 98-06-61.0 0.30 1Carbon tetrachloride <0.17 ug/L 07/08/19 22:34 56-23-51.0 0.17 1Chlorobenzene <0.71 ug/L 07/08/19 22:34 108-90-72.4 0.71 1Chloroethane <1.3 ug/L 07/08/19 22:34 75-00-35.0 1.3 1Chloroform <1.3 ug/L 07/08/19 22:34 67-66-35.0 1.3 1Chloromethane 7.8 ug/L 07/08/19 22:34 74-87-37.3 2.2 12-Chlorotoluene <0.93 ug/L 07/08/19 22:34 95-49-85.0 0.93 14-Chlorotoluene <0.76 ug/L 07/08/19 22:34 106-43-42.5 0.76 11,2-Dibromo-3-chloropropane <1.8 ug/L 07/08/19 22:34 96-12-85.9 1.8 1Dibromochloromethane <2.6 ug/L 07/08/19 22:34 124-48-18.7 2.6 11,2-Dibromoethane (EDB) <0.83 ug/L 07/08/19 22:34 106-93-42.8 0.83 1Dibromomethane <0.94 ug/L 07/08/19 22:34 74-95-33.1 0.94 11,2-Dichlorobenzene <0.71 ug/L 07/08/19 22:34 95-50-12.4 0.71 11,3-Dichlorobenzene <0.63 ug/L 07/08/19 22:34 541-73-12.1 0.63 11,4-Dichlorobenzene <0.94 ug/L 07/08/19 22:34 106-46-73.1 0.94 1Dichlorodifluoromethane <0.50 ug/L 07/08/19 22:34 75-71-85.0 0.50 1




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ANALYTICAL RESULTS






1,1-Dichloroethane <0.27 ug/L 07/08/19 22:34 75-34-31.0 0.27 11,2-Dichloroethane <0.28 ug/L 07/08/19 22:34 107-06-21.0 0.28 11,1-Dichloroethene <0.24 ug/L 07/08/19 22:34 75-35-41.0 0.24 1cis-1,2-Dichloroethene <0.27 ug/L 07/08/19 22:34 156-59-21.0 0.27 1trans-1,2-Dichloroethene <1.1 ug/L 07/08/19 22:34 156-60-53.6 1.1 11,2-Dichloropropane <0.28 ug/L 07/08/19 22:34 78-87-51.0 0.28 11,3-Dichloropropane <0.83 ug/L 07/08/19 22:34 142-28-92.8 0.83 12,2-Dichloropropane <2.3 ug/L 07/08/19 22:34 594-20-77.6 2.3 11,1-Dichloropropene <0.54 ug/L 07/08/19 22:34 563-58-61.8 0.54 1cis-1,3-Dichloropropene <3.6 ug/L 07/08/19 22:34 10061-01-512.1 3.6 1trans-1,3-Dichloropropene <4.4 ug/L 07/08/19 22:34 10061-02-614.6 4.4 1Diisopropyl ether <1.9 ug/L 07/08/19 22:34 108-20-36.3 1.9 1Ethylbenzene <0.22 ug/L 07/08/19 22:34 100-41-41.0 0.22 1Hexachloro-1,3-butadiene <1.2 ug/L 07/08/19 22:34 87-68-35.0 1.2 1Isopropylbenzene (Cumene) <0.39 ug/L 07/08/19 22:34 98-82-85.0 0.39 1p-Isopropyltoluene <0.80 ug/L 07/08/19 22:34 99-87-62.7 0.80 1Methylene Chloride <0.58 ug/L 07/08/19 22:34 75-09-25.0 0.58 1Methyl-tert-butyl ether <1.2 ug/L 07/08/19 22:34 1634-04-44.2 1.2 1Naphthalene <1.2 ug/L 07/08/19 22:34 91-20-35.0 1.2 1n-Propylbenzene <0.81 ug/L 07/08/19 22:34 103-65-15.0 0.81 1Styrene <0.47 ug/L 07/08/19 22:34 100-42-51.6 0.47 11,1,1,2-Tetrachloroethane <0.27 ug/L 07/08/19 22:34 630-20-61.0 0.27 11,1,2,2-Tetrachloroethane <0.28 ug/L 07/08/19 22:34 79-34-51.0 0.28 1Tetrachloroethene <0.33 ug/L 07/08/19 22:34 127-18-41.1 0.33 1Toluene <0.17 ug/L 07/08/19 22:34 108-88-35.0 0.17 11,2,3-Trichlorobenzene <0.63 ug/L 07/08/19 22:34 87-61-65.0 0.63 11,2,4-Trichlorobenzene <0.95 ug/L 07/08/19 22:34 120-82-15.0 0.95 11,1,1-Trichloroethane <0.24 ug/L 07/08/19 22:34 71-55-61.0 0.24 11,1,2-Trichloroethane <0.55 ug/L 07/08/19 22:34 79-00-55.0 0.55 1Trichloroethene <0.26 ug/L 07/08/19 22:34 79-01-61.0 0.26 1Trichlorofluoromethane <0.21 ug/L 07/08/19 22:34 75-69-41.0 0.21 11,2,3-Trichloropropane <0.59 ug/L 07/08/19 22:34 96-18-45.0 0.59 11,2,4-Trimethylbenzene <0.84 ug/L 07/08/19 22:34 95-63-62.8 0.84 11,3,5-Trimethylbenzene <0.87 ug/L 07/08/19 22:34 108-67-82.9 0.87 1Vinyl chloride <0.17 ug/L 07/08/19 22:34 75-01-4 L11.0 0.17 1m&p-Xylene <0.47 ug/L 07/08/19 22:34 179601-23-12.0 0.47 1o-Xylene <0.26 ug/L 07/08/19 22:34 95-47-61.0 0.26 1Surrogates4-Bromofluorobenzene (S) 92 % 07/08/19 22:34 460-00-470-130 1Dibromofluoromethane (S) 122 % 07/08/19 22:34 1868-53-770-130 1Toluene-d8 (S) 104 % 07/08/19 22:34 2037-26-570-130 1

Analytical Method: SM 2540D2540D Total Suspended Solids

Total Suspended Solids 32.6 mg/L 07/03/19 14:282.0 0.95 1




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ANALYTICAL RESULTS





Analytical Method: SM 5210B Preparation Method: SM 5210B5210B BOD, 5 day

BOD, 5 day 6.1 mg/L 07/08/19 11:4007/03/19 06:002.0 2.0 1

Analytical Method: EPA 90409040 pH

pH at 25 Degrees C 7.2 Std. Units 07/09/19 11:11 H60.10 0.010 1

Analytical Method: EPA 335.4 Preparation Method: EPA 335.4335.4 Cyanide, Total

Cyanide 0.026J mg/L 07/08/19 15:13 57-12-5 B,D307/08/19 11:150.045 0.014 1

Analytical Method: EPA 365.4 Preparation Method: EPA 365.4365.4 Total Phosphorus

Phosphorus 0.13J mg/L 07/12/19 12:11 7723-14-007/12/19 07:300.40 0.052 1




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ANALYTICAL RESULTS



Sample: TRIP BLANK Lab ID: 40190553003 Collected: 07/02/19 00:00 Received: 07/02/19 17:05 Matrix: Water



Benzene <0.25 ug/L 07/08/19 21:55 71-43-21.0 0.25 1Bromobenzene <0.24 ug/L 07/08/19 21:55 108-86-11.0 0.24 1Bromochloromethane <0.36 ug/L 07/08/19 21:55 74-97-55.0 0.36 1Bromodichloromethane <0.36 ug/L 07/08/19 21:55 75-27-41.2 0.36 1Bromoform <4.0 ug/L 07/08/19 21:55 75-25-213.2 4.0 1Bromomethane <0.97 ug/L 07/08/19 21:55 74-83-95.0 0.97 1n-Butylbenzene <0.71 ug/L 07/08/19 21:55 104-51-82.4 0.71 1sec-Butylbenzene <0.85 ug/L 07/08/19 21:55 135-98-85.0 0.85 1tert-Butylbenzene <0.30 ug/L 07/08/19 21:55 98-06-61.0 0.30 1Carbon tetrachloride <0.17 ug/L 07/08/19 21:55 56-23-51.0 0.17 1Chlorobenzene <0.71 ug/L 07/08/19 21:55 108-90-72.4 0.71 1Chloroethane <1.3 ug/L 07/08/19 21:55 75-00-35.0 1.3 1Chloroform <1.3 ug/L 07/08/19 21:55 67-66-35.0 1.3 1Chloromethane <2.2 ug/L 07/08/19 21:55 74-87-37.3 2.2 12-Chlorotoluene <0.93 ug/L 07/08/19 21:55 95-49-85.0 0.93 14-Chlorotoluene <0.76 ug/L 07/08/19 21:55 106-43-42.5 0.76 11,2-Dibromo-3-chloropropane <1.8 ug/L 07/08/19 21:55 96-12-85.9 1.8 1Dibromochloromethane <2.6 ug/L 07/08/19 21:55 124-48-18.7 2.6 11,2-Dibromoethane (EDB) <0.83 ug/L 07/08/19 21:55 106-93-42.8 0.83 1Dibromomethane <0.94 ug/L 07/08/19 21:55 74-95-33.1 0.94 11,2-Dichlorobenzene <0.71 ug/L 07/08/19 21:55 95-50-12.4 0.71 11,3-Dichlorobenzene <0.63 ug/L 07/08/19 21:55 541-73-12.1 0.63 11,4-Dichlorobenzene <0.94 ug/L 07/08/19 21:55 106-46-73.1 0.94 1Dichlorodifluoromethane <0.50 ug/L 07/08/19 21:55 75-71-85.0 0.50 11,1-Dichloroethane <0.27 ug/L 07/08/19 21:55 75-34-31.0 0.27 11,2-Dichloroethane <0.28 ug/L 07/08/19 21:55 107-06-21.0 0.28 11,1-Dichloroethene <0.24 ug/L 07/08/19 21:55 75-35-41.0 0.24 1cis-1,2-Dichloroethene <0.27 ug/L 07/08/19 21:55 156-59-21.0 0.27 1trans-1,2-Dichloroethene <1.1 ug/L 07/08/19 21:55 156-60-53.6 1.1 11,2-Dichloropropane <0.28 ug/L 07/08/19 21:55 78-87-51.0 0.28 11,3-Dichloropropane <0.83 ug/L 07/08/19 21:55 142-28-92.8 0.83 12,2-Dichloropropane <2.3 ug/L 07/08/19 21:55 594-20-77.6 2.3 11,1-Dichloropropene <0.54 ug/L 07/08/19 21:55 563-58-61.8 0.54 1cis-1,3-Dichloropropene <3.6 ug/L 07/08/19 21:55 10061-01-512.1 3.6 1trans-1,3-Dichloropropene <4.4 ug/L 07/08/19 21:55 10061-02-614.6 4.4 1Diisopropyl ether <1.9 ug/L 07/08/19 21:55 108-20-36.3 1.9 1Ethylbenzene <0.22 ug/L 07/08/19 21:55 100-41-41.0 0.22 1Hexachloro-1,3-butadiene <1.2 ug/L 07/08/19 21:55 87-68-35.0 1.2 1Isopropylbenzene (Cumene) <0.39 ug/L 07/08/19 21:55 98-82-85.0 0.39 1p-Isopropyltoluene <0.80 ug/L 07/08/19 21:55 99-87-62.7 0.80 1Methylene Chloride <0.58 ug/L 07/08/19 21:55 75-09-25.0 0.58 1Methyl-tert-butyl ether <1.2 ug/L 07/08/19 21:55 1634-04-44.2 1.2 1Naphthalene <1.2 ug/L 07/08/19 21:55 91-20-35.0 1.2 1n-Propylbenzene <0.81 ug/L 07/08/19 21:55 103-65-15.0 0.81 1Styrene <0.47 ug/L 07/08/19 21:55 100-42-51.6 0.47 11,1,1,2-Tetrachloroethane <0.27 ug/L 07/08/19 21:55 630-20-61.0 0.27 1




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ANALYTICAL RESULTS



Sample: TRIP BLANK Lab ID: 40190553003 Collected: 07/02/19 00:00 Received: 07/02/19 17:05 Matrix: Water



1,1,2,2-Tetrachloroethane <0.28 ug/L 07/08/19 21:55 79-34-51.0 0.28 1Tetrachloroethene <0.33 ug/L 07/08/19 21:55 127-18-41.1 0.33 1Toluene <0.17 ug/L 07/08/19 21:55 108-88-35.0 0.17 11,2,3-Trichlorobenzene <0.63 ug/L 07/08/19 21:55 87-61-65.0 0.63 11,2,4-Trichlorobenzene <0.95 ug/L 07/08/19 21:55 120-82-15.0 0.95 11,1,1-Trichloroethane <0.24 ug/L 07/08/19 21:55 71-55-61.0 0.24 11,1,2-Trichloroethane <0.55 ug/L 07/08/19 21:55 79-00-55.0 0.55 1Trichloroethene <0.26 ug/L 07/08/19 21:55 79-01-61.0 0.26 1Trichlorofluoromethane <0.21 ug/L 07/08/19 21:55 75-69-41.0 0.21 11,2,3-Trichloropropane <0.59 ug/L 07/08/19 21:55 96-18-45.0 0.59 11,2,4-Trimethylbenzene <0.84 ug/L 07/08/19 21:55 95-63-62.8 0.84 11,3,5-Trimethylbenzene <0.87 ug/L 07/08/19 21:55 108-67-82.9 0.87 1Vinyl chloride <0.17 ug/L 07/08/19 21:55 75-01-4 L11.0 0.17 1m&p-Xylene <0.47 ug/L 07/08/19 21:55 179601-23-12.0 0.47 1o-Xylene <0.26 ug/L 07/08/19 21:55 95-47-61.0 0.26 1Surrogates4-Bromofluorobenzene (S) 93 % 07/08/19 21:55 460-00-470-130 1Dibromofluoromethane (S) 123 % 07/08/19 21:55 1868-53-7 HS70-130 1Toluene-d8 (S) 107 % 07/08/19 21:55 2037-26-570-130 1




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#=QC#







170383EPA 1664A OG (1999)

EPA 1664A OG (1999)1664 HEM, Oil and Grease





Matrix: Water

Analyzed

Oil and Grease mg/L <0.76 3.0 07/15/19 09:42

Parameter UnitsLCS



Oil and Grease mg/L 36.440 91 78-114

Parameter UnitsMS



MSSpikeResult

12131496002

673563

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Oil and Grease mg/L 39.6 78 78-11485 8 1839.6<0.74 31.2 33.9

Parameter UnitsMS



MSSpikeResult

12131496003

673565

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


Parameter UnitsMS



MSSpikeResult

12131606003

673567

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





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#=QC#







170284EPA 420.1 (1983 & 1993)

EPA 420.1 (1983 & 1993)420.1 Phenolics





Matrix: Water

Analyzed

Phenolics, Total Recoverable mg/L <0.0096 0.060 07/12/19 14:49

Parameter UnitsLCS



Phenolics, Total Recoverable mg/L 0.390.4 98 90-110

Parameter UnitsMS



MSSpikeResult

12131946001

673041

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Phenolics, TotalRecoverable

mg/L M10.4 69 80-12065 5 100.4<9.6 ug/L 0.28 0.26




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#=QC#







326720EPA 7470






Matrix: Water

Analyzed

Mercury ug/L <0.084 0.28 07/09/19 07:36

Parameter UnitsLCS



Mercury ug/L 4.95 98 85-115

Parameter UnitsMS



MSSpikeResult

40190418001

1897403

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Mercury ug/L 5 98 85-11595 4 205<0.084 4.9 4.7




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#=QC#







326586EPA 3010

EPA 60206020 MET





Matrix: Water

Analyzed

Arsenic ug/L <0.28 1.0 07/06/19 19:35Beryllium ug/L <0.18 1.0 07/06/19 19:35Cadmium ug/L <0.15 1.0 07/06/19 19:35Chromium ug/L <1.0 3.4 07/06/19 19:35Copper ug/L <1.1 3.6 07/06/19 19:35Lead ug/L <0.24 1.0 07/06/19 19:35Nickel ug/L <0.40 1.3 07/06/19 19:35Selenium ug/L <0.32 1.1 07/06/19 19:35Silver ug/L <0.10 0.50 07/06/19 19:35Zinc ug/L <4.6 15.3 07/06/19 19:35

Parameter UnitsLCS



Arsenic ug/L 465500 93 80-120Beryllium ug/L 482500 96 80-120Cadmium ug/L 483500 97 80-120Chromium ug/L 478500 96 80-120Copper ug/L 479500 96 80-120Lead ug/L 473500 95 80-120Nickel ug/L 478500 96 80-120Selenium ug/L 495500 99 80-120Silver ug/L 250250 100 80-120Zinc ug/L 481500 96 80-120

Parameter UnitsMS



MSSpikeResult

40190260001

1896638

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Arsenic ug/L 500 94 75-12594 0 205003.1 471 471Beryllium ug/L 500 99 75-12598 1 20500<0.18 494 491Cadmium ug/L 500 96 75-12596 0 20500<0.15 480 480Chromium ug/L 500 96 75-12597 0 20500<1.0 482 483Copper ug/L 500 94 75-12594 0 205002.0J 471 471Lead ug/L 500 96 75-12595 1 20500<0.24 479 476Nickel ug/L 500 95 75-12595 1 20500<0.40 477 474Selenium ug/L 500 99 75-12599 0 20500<0.32 495 494Silver ug/L 250 98 75-12598 0 20250<0.10 244 245




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#=QC#





Parameter UnitsMS



MSSpikeResult

40190260001

1896638

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Zinc ug/L 500 96 75-12595 1 205005.5J 486 480




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#=QC#







326604EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40190553001, 40190553002, 40190553003



METHOD BLANK: 1896696Associated Lab Samples: 40190553001, 40190553002, 40190553003

Matrix: Water

Analyzed

1,1,1,2-Tetrachloroethane ug/L <0.27 1.0 07/08/19 17:221,1,1-Trichloroethane ug/L <0.24 1.0 07/08/19 17:221,1,2,2-Tetrachloroethane ug/L <0.28 1.0 07/08/19 17:221,1,2-Trichloroethane ug/L <0.55 5.0 07/08/19 17:221,1-Dichloroethane ug/L <0.27 1.0 07/08/19 17:221,1-Dichloroethene ug/L <0.24 1.0 07/08/19 17:221,1-Dichloropropene ug/L <0.54 1.8 07/08/19 17:221,2,3-Trichlorobenzene ug/L <0.63 5.0 07/08/19 17:221,2,3-Trichloropropane ug/L <0.59 5.0 07/08/19 17:221,2,4-Trichlorobenzene ug/L <0.95 5.0 07/08/19 17:221,2,4-Trimethylbenzene ug/L <0.84 2.8 07/08/19 17:221,2-Dibromo-3-chloropropane ug/L <1.8 5.9 07/08/19 17:221,2-Dibromoethane (EDB) ug/L <0.83 2.8 07/08/19 17:221,2-Dichlorobenzene ug/L <0.71 2.4 07/08/19 17:221,2-Dichloroethane ug/L <0.28 1.0 07/08/19 17:221,2-Dichloropropane ug/L <0.28 1.0 07/08/19 17:221,3,5-Trimethylbenzene ug/L <0.87 2.9 07/08/19 17:221,3-Dichlorobenzene ug/L <0.63 2.1 07/08/19 17:221,3-Dichloropropane ug/L <0.83 2.8 07/08/19 17:221,4-Dichlorobenzene ug/L <0.94 3.1 07/08/19 17:222,2-Dichloropropane ug/L <2.3 7.6 07/08/19 17:222-Chlorotoluene ug/L <0.93 5.0 07/08/19 17:224-Chlorotoluene ug/L <0.76 2.5 07/08/19 17:22Benzene ug/L <0.25 1.0 07/08/19 17:22Bromobenzene ug/L <0.24 1.0 07/08/19 17:22Bromochloromethane ug/L <0.36 5.0 07/08/19 17:22Bromodichloromethane ug/L <0.36 1.2 07/08/19 17:22Bromoform ug/L <4.0 13.2 07/08/19 17:22Bromomethane ug/L <0.97 5.0 07/08/19 17:22Carbon tetrachloride ug/L <0.17 1.0 07/08/19 17:22Chlorobenzene ug/L <0.71 2.4 07/08/19 17:22Chloroethane ug/L <1.3 5.0 07/08/19 17:22Chloroform ug/L <1.3 5.0 07/08/19 17:22Chloromethane ug/L <2.2 7.3 07/08/19 17:22cis-1,2-Dichloroethene ug/L <0.27 1.0 07/08/19 17:22cis-1,3-Dichloropropene ug/L <3.6 12.1 07/08/19 17:22Dibromochloromethane ug/L <2.6 8.7 07/08/19 17:22Dibromomethane ug/L <0.94 3.1 07/08/19 17:22Dichlorodifluoromethane ug/L <0.50 5.0 07/08/19 17:22Diisopropyl ether ug/L <1.9 6.3 07/08/19 17:22Ethylbenzene ug/L <0.22 1.0 07/08/19 17:22




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#=QC#







METHOD BLANK: 1896696Associated Lab Samples: 40190553001, 40190553002, 40190553003

Matrix: Water

Analyzed

Hexachloro-1,3-butadiene ug/L <1.2 5.0 07/08/19 17:22Isopropylbenzene (Cumene) ug/L <0.39 5.0 07/08/19 17:22m&p-Xylene ug/L <0.47 2.0 07/08/19 17:22Methyl-tert-butyl ether ug/L <1.2 4.2 07/08/19 17:22Methylene Chloride ug/L <0.58 5.0 07/08/19 17:22n-Butylbenzene ug/L <0.71 2.4 07/08/19 17:22n-Propylbenzene ug/L <0.81 5.0 07/08/19 17:22Naphthalene ug/L <1.2 5.0 07/08/19 17:22o-Xylene ug/L <0.26 1.0 07/08/19 17:22p-Isopropyltoluene ug/L <0.80 2.7 07/08/19 17:22sec-Butylbenzene ug/L <0.85 5.0 07/08/19 17:22Styrene ug/L <0.47 1.6 07/08/19 17:22tert-Butylbenzene ug/L <0.30 1.0 07/08/19 17:22Tetrachloroethene ug/L <0.33 1.1 07/08/19 17:22Toluene ug/L <0.17 5.0 07/08/19 17:22trans-1,2-Dichloroethene ug/L <1.1 3.6 07/08/19 17:22trans-1,3-Dichloropropene ug/L <4.4 14.6 07/08/19 17:22Trichloroethene ug/L <0.26 1.0 07/08/19 17:22Trichlorofluoromethane ug/L <0.21 1.0 07/08/19 17:22Vinyl chloride ug/L <0.17 1.0 07/08/19 17:224-Bromofluorobenzene (S) % 93 70-130 07/08/19 17:22Dibromofluoromethane (S) % 117 70-130 07/08/19 17:22Toluene-d8 (S) % 104 70-130 07/08/19 17:22

Parameter UnitsLCS



1,1,1-Trichloroethane ug/L 53.250 106 70-1301,1,2,2-Tetrachloroethane ug/L 54.850 110 70-1301,1,2-Trichloroethane ug/L 53.850 108 70-1301,1-Dichloroethane ug/L 54.150 108 73-1501,1-Dichloroethene ug/L 66.550 133 73-1381,2,4-Trichlorobenzene ug/L 46.850 94 70-1301,2-Dibromo-3-chloropropane ug/L 44.250 88 64-1291,2-Dibromoethane (EDB) ug/L 49.650 99 70-1301,2-Dichlorobenzene ug/L 48.550 97 70-1301,2-Dichloroethane ug/L 55.350 111 75-1401,2-Dichloropropane ug/L 49.150 98 73-1351,3-Dichlorobenzene ug/L 49.150 98 70-1301,4-Dichlorobenzene ug/L 49.550 99 70-130Benzene ug/L 59.550 119 70-130Bromodichloromethane ug/L 51.950 104 70-130Bromoform ug/L 41.850 84 68-129Bromomethane ug/L 41.850 84 18-159




Green Bay, WI 54302(920)469-2436

Page 20 of 32

#=QC#





Parameter UnitsLCS



Carbon tetrachloride ug/L 53.050 106 70-130Chlorobenzene ug/L 51.650 103 70-130Chloroethane ug/L 66.650 133 53-147Chloroform ug/L 56.750 113 74-136Chloromethane ug/L 47.250 94 29-115cis-1,2-Dichloroethene ug/L 54.550 109 70-130cis-1,3-Dichloropropene ug/L 45.850 92 70-130Dibromochloromethane ug/L 44.450 89 70-130Dichlorodifluoromethane ug/L 51.050 102 10-130Ethylbenzene ug/L 53.250 106 80-124Isopropylbenzene (Cumene) ug/L 55.350 111 70-130m&p-Xylene ug/L 109100 109 70-130Methyl-tert-butyl ether ug/L 46.950 94 54-137Methylene Chloride ug/L 55.150 110 73-138o-Xylene ug/L 53.550 107 70-130Styrene ug/L 54.850 110 70-130Tetrachloroethene ug/L 53.450 107 70-130Toluene ug/L 53.550 107 80-126trans-1,2-Dichloroethene ug/L 58.550 117 73-145trans-1,3-Dichloropropene ug/L 42.250 84 70-130Trichloroethene ug/L 54.150 108 70-130Trichlorofluoromethane ug/L 65.250 130 76-147Vinyl chloride ug/L 62.5 L150 125 51-1204-Bromofluorobenzene (S) % 106 70-130Dibromofluoromethane (S) % 115 70-130Toluene-d8 (S) % 106 70-130

Parameter UnitsMS



MSSpikeResult

40190580003

1896788

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 103 70-130109 6 2050<0.24 51.6 54.71,1,2,2-Tetrachloroethane ug/L 50 106 70-130106 1 2050<0.28 52.8 53.21,1,2-Trichloroethane ug/L 50 101 70-137103 2 2050<0.55 50.7 51.61,1-Dichloroethane ug/L 50 104 73-153110 5 2050<0.27 52.1 54.91,1-Dichloroethene ug/L 50 127 73-138131 3 2050<0.24 63.6 65.41,2,4-Trichlorobenzene ug/L 50 90 70-13093 3 2050<0.95 44.9 46.41,2-Dibromo-3-chloropropane

ug/L 50 89 58-12995 7 2050<1.8 44.4 47.5

1,2-Dibromoethane (EDB) ug/L 50 98 70-13099 1 2050<0.83 48.8 49.41,2-Dichlorobenzene ug/L 50 94 70-13095 2 2050<0.71 46.9 47.71,2-Dichloroethane ug/L 50 102 75-140109 7 2050<0.28 51.0 54.71,2-Dichloropropane ug/L 50 97 71-138103 6 2050<0.28 48.7 51.51,3-Dichlorobenzene ug/L 50 93 70-13094 2 2050<0.63 46.3 47.21,4-Dichlorobenzene ug/L 50 95 70-13095 0 2050<0.94 47.5 47.6




Green Bay, WI 54302(920)469-2436

Page 21 of 32

#=QC#





Parameter UnitsMS



MSSpikeResult

40190580003

1896788

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Benzene ug/L 50 112 70-130115 2 2050<0.25 56.1 57.3Bromodichloromethane ug/L 50 100 70-130108 7 2050<0.36 50.1 53.9Bromoform ug/L 50 79 68-12980 1 2050<4.0 39.7 40.2Bromomethane ug/L 50 93 15-17087 7 2050<0.97 46.6 43.6Carbon tetrachloride ug/L 50 102 70-130108 5 2050<0.17 51.1 53.9Chlorobenzene ug/L 50 98 70-130101 3 2050<0.71 49.1 50.5Chloroethane ug/L 50 134 51-148140 4 2050<1.3 67.0 69.9Chloroform ug/L 50 108 74-136111 3 2050<1.3 54.0 55.6Chloromethane ug/L 50 92 23-11596 4 2050<2.2 46.9 48.7cis-1,2-Dichloroethene ug/L 50 107 70-131110 3 20506.6 59.8 61.4cis-1,3-Dichloropropene ug/L 50 88 70-13092 4 2050<3.6 44.2 46.0Dibromochloromethane ug/L 50 86 70-13088 2 2050<2.6 43.0 44.0Dichlorodifluoromethane ug/L 50 98 10-132105 7 2050<0.50 49.0 52.4Ethylbenzene ug/L 50 101 80-125104 3 2050<0.22 50.6 52.1Isopropylbenzene(Cumene)

ug/L 50 103 70-130106 2 2050<0.39 51.6 52.8

m&p-Xylene ug/L 100 103 70-130106 4 20100<0.47 103 106Methyl-tert-butyl ether ug/L 50 88 51-14589 1 2050<1.2 44.1 44.6Methylene Chloride ug/L 50 107 73-140111 3 2050<0.58 53.5 55.3o-Xylene ug/L 50 101 70-130105 4 2050<0.26 50.5 52.4Styrene ug/L 50 103 70-130104 1 2050<0.47 51.4 51.8Tetrachloroethene ug/L 50 100 70-130103 3 2050<0.33 49.9 51.6Toluene ug/L 50 103 80-131105 2 2050<0.17 51.3 52.5trans-1,2-Dichloroethene ug/L 50 116 73-148119 2 20504.3 62.3 63.6trans-1,3-Dichloropropene ug/L 50 81 70-13081 0 2050<4.4 40.4 40.3Trichloroethene ug/L 50 107 70-130114 6 20500.55J 54.2 57.8Trichlorofluoromethane ug/L 50 126 74-147128 1 2050<0.21 63.2 63.9Vinyl chloride ug/L 50 119 41-129124 4 20501.2 60.9 63.44-Bromofluorobenzene (S) % 103 70-130106Dibromofluoromethane (S) % 114 70-130115Toluene-d8 (S) % 105 70-130107




Green Bay, WI 54302(920)469-2436

Page 22 of 32

#=QC#







326502SM 2540D

SM 2540D2540D Total Suspended Solids





Matrix: Water

Analyzed

Total Suspended Solids mg/L <0.48 1.0 07/03/19 14:28

Parameter UnitsLCS



Total Suspended Solids mg/L 96.0100 96 80-120

Parameter UnitsDup



Total Suspended Solids mg/L 176 R123 10140

Parameter UnitsDup



Total Suspended Solids mg/L 510 1 10515




Green Bay, WI 54302(920)469-2436

Page 23 of 32

#=QC#







326452SM 5210B

SM 5210B5210B BOD, 5 day





Matrix: Water

Analyzed

BOD, 5 day mg/L <2.0 2.0 07/08/19 11:18




Matrix: Water

Analyzed

BOD, 5 day mg/L <2.0 2.0 07/08/19 11:48

Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1895719

BOD, 5 day mg/L 207198 105 84.6-115105208 0 20

Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1895721

BOD, 5 day mg/L 207198 105 84.6-115103204 2 20

Parameter UnitsDup



BOD, 5 day mg/L 445 5 20425




Green Bay, WI 54302(920)469-2436

Page 24 of 32

#=QC#







326857EPA 9040

EPA 90409040 pH


Parameter UnitsDup



pH at 25 Degrees C Std. Units 7.5 H61 207.4

Parameter UnitsDup



pH at 25 Degrees C Std. Units 7.2 H60 207.2




Green Bay, WI 54302(920)469-2436

Page 25 of 32

#=QC#







326708EPA 335.4

EPA 335.4335.4 Cyanide, Total





Matrix: Water

Analyzed

Cyanide mg/L 0.0078J 0.023 07/08/19 14:45

Parameter UnitsLCS



Cyanide mg/L 0.100.1 102 90-110

Parameter UnitsMS



MSSpikeResult

40190348025

1897355

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Cyanide mg/L 0.1 95 90-11093 2 200.10.0080J 0.10 0.10

Parameter UnitsMS



MSSpikeResult

40190553002

1897357

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Cyanide mg/L 0.2 92 90-11095 2 200.20.026J 0.21 0.22




Green Bay, WI 54302(920)469-2436

Page 26 of 32

#=QC#







327306EPA 365.4

EPA 365.4365.4 Phosphorus





Matrix: Water

Analyzed

Phosphorus mg/L <0.052 0.40 07/12/19 11:54

Parameter UnitsLCS



Phosphorus mg/L 5.25 104 90-110

Parameter UnitsMS



MSSpikeResult

40190294001

1900497

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Phosphorus mg/L 50 103 90-11096 5 205019.0 70.7 67.1

Parameter UnitsMS



MSSpikeResult

40190563001

1900499

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Phosphorus mg/L M020 103 90-11089 4 202046.2 66.8 64.0




Green Bay, WI 54302(920)469-2436

Page 27 of 32

#=QL#

QUALIFIERS



DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above LOD.J - Estimated concentration at or above the LOD and below the LOQ.LOD - Limit of Detection adjusted for dilution factor, percent moisture, initial weight and final volume.LOQ - Limit of Quantitation adjusted for dilution factor, percent moisture, initial weight and final volume.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected at or above the adjusted LOD.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - DuluthPASI-DULPace Analytical Services - Green BayPASI-G

BATCH QUALIFIERS

Batch: 170383Batch extracted by solid phase extraction (SPE).[1]

ANALYTE QUALIFIERS

Analyte was detected in the associated method blank.BSample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3Analysis initiated outside of the 15 minute EPA required holding time.H6Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).HSAnalyte recovery in the laboratory control sample (LCS) was above QC limits. Results may be biased high.L1Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1RPD value was outside control limits.R1




Green Bay, WI 54302(920)469-2436

Page 28 of 32

#=CR#





40190553001 170383S-MW EPA 1664A OG (1999)40190553002 170383N-MW EPA 1664A OG (1999)

40190553001 170284 170313S-MW EPA 420.1 (1983 & 1993) EPA 420.1 (1983 & 1993)40190553002 170284 170313N-MW EPA 420.1 (1983 & 1993) EPA 420.1 (1983 & 1993)

40190553001 326586 326682S-MW EPA 3010 EPA 602040190553002 326586 326682N-MW EPA 3010 EPA 6020

40190553001 326720 326784S-MW EPA 7470 EPA 747040190553002 326720 326784N-MW EPA 7470 EPA 7470

40190553001 326604S-MW EPA 826040190553002 326604N-MW EPA 826040190553003 326604TRIP BLANK EPA 8260

40190553001 326502S-MW SM 2540D40190553002 326502N-MW SM 2540D

40190553001 326452 326787S-MW SM 5210B SM 5210B40190553002 326452 326787N-MW SM 5210B SM 5210B

40190553001 326857S-MW EPA 904040190553002 326857N-MW EPA 9040

40190553001 326708 326774S-MW EPA 335.4 EPA 335.440190553002 326708 326774N-MW EPA 335.4 EPA 335.4

40190553001 327306 327325S-MW EPA 365.4 EPA 365.440190553002 327306 327325N-MW EPA 365.4 EPA 365.4




Green Bay, WI 54302(920)469-2436

Page 29 of 32

Page

30

of 3

2

(Please Print Clearly) !JPPEB MIDWE~T RE210N Page 1 of I Company Name: Gt;I f."'s~ //,-.,.-/.:. :r;,.r. MN: 612..007-1700 WI: 920469-2436

ceAnalytical• l/ o !Gt a c:s-< Branch/Location: Gr..::..c.."' ~y IA/.1 t<.~t. (,,lfV"f.)Wt I AA

www.~oom

Project Contact: Quote#:

Phone: I CHAIN OF CUSTODY q?o ,t(f<;.~ ??co Mail To Contact: t/..y'-' ~1'\"'\JW\ ,i4._

Project Number : terazz n I: 'f'""YIIIon Codtt r..er (c.,r, ~JJ,...,~ -;:;, <:. AsNone B»HCL C•H2S04 D•HN03 E•DI Weier F=Methonol G• NeOH Mall To Company:

Project Name: A-JL. &>td~M ~J.v~1 H.oSodlom Bisulfate Solution I•Sodlum Thiosulfate J=Othor

Mall To Address: s\P1 UI'AY;' ()Y'tk..

Project State: //A/'1" FILTERED? YIN ;v tv tv N tv t1.! tv Gr~ (!;... y_ W~ '>Ln II (YE&INO)

Sampled By (Print): K.v~ ( P" vt) W1. , ;........_ PRESERVATION .... 6 6 0 b c t/A A Invoice To Contact:

(COOE}' a... Sampled By (Sign): ~ _...,~ ,.

""' ~'v. Invoice To Company:

~ r-"' Regulltory I s -PO #I: Proa,..m: ~ ~ "' """" Invoice To Address:

-s. ~ \/"\

D!ta Pack1ge Ogtlgns MS/MSD Matrix Codes ~ -{ ~ ~

l-

(billable) A • AJr W•Welet V\

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0 EPALevellll 0 On your sample B • Biola OW • Drinking Wator

J ;....._) " (billable) C • Charoool GW • Ground Water :5. ~ _£ ·~ ' ::::t Invoice To Phone:

0 EPA Level IV 0 NOT needed on 0 • 011 SW • Sulface Water ~ ~ -- ~ S•Soll WW • Wute Water '-.::.. -i ~ your sample SI • Siudae WP • Wloe ~ <::> CLIENT LAB COMMENTS Profile #I

COL~CTION <:5 l-! ~ PACE LAB #I CLIENT FIELD 10 MATRDI COMMENTS (Lab Use Only) OATI! TIME

Oot 5-MW 7/-t{lCi ~~ oCl 6w )<.. ?< /< . ?< ;><. X. ~ ·~1-r..h: As~ CJ 0()1).. jv,M~ ~hit~ <;!: S)"" 61).) ... -..,£. ;;<. X ?" x ,X. y Ct Pb H"~ c. '

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Rush Turnaround Time Requested - Prelims

~~ ?~~·;n""" /7.! tJf R7'~a~ :;1 hZ;"mo: /::/f)':> lto(ct;rs) (Rush TAT subject to approval/surcharge) ~~

Date Needed: . OaWTlme: Reco'"tocl 87 l/ r · I Oete.mme:

Transmit Prelim Rush Results by (complete what you want): R-lpt Temp • 6:z::. oc

Emalllf'l: Re~nqulthed By: Datolllme: Received By: D-atemme:

EmaiJ.n: Sample Receipt pH

!Telephone: Relinquished By: OatefTime: Received By: Date.mme: OK I Adjusted

Fu: Cooler ,., ··•-..... r Seal

8amp!M on HOLD are aubject to Retlnqulthed By: Oat6111me: Received By: DalaiTlme: Presen~ ~ot ~ant af*:lal pricing and ,..._ ... of liability Intact I

\i-"-An t"rA/• .t.trr'Wl

Page

31

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2

. Sample Preservation Receipt Form CLient Name: ~1. Project# lfu lq 65 5~

Pace Analytical Sel\lices, LLC 1241 Bellevue Street, Suite 9

Green Bay. WI 54302

All contamers needmg preservation have been checked and noted below:~es oNo oN/A

Lab Lot# of pH paper: l Oll.S.:h"iS/ Lab Std 1110 of preservation (tfpli adjusted)·

[ Glass I [ Plastic

;:J = 00 ;;;;> ;:J 00 ;;;;> ;:J Z N ;;;;> = Z oo Pace "'"'"'"'~~ tn NM ...-lf:"'NMMMM

Lab# ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 001 ' ( + 2 t J I 002 l L 1---t- 2 l l \ 003 004 /1 AI I 1 005 l 'J..\' I :.u~ 006

, IV

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013 ./" ' /

014 / 015 /

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Date/ Time: -

..,

~ I Volume

! (mL) ., 'l; X

2.5151 10

2.515110

2.5 I 5 I 10

2.5/ S I 10

2.5 I 5 I 10

2.5151 10

2.5 I 5 I I 0

2.515110

2.5 I 5 I 10

2.515110

2.5 I 5 I 10

2.515110

2.5/5/10

2.515110

2.5 I 51 10

2.5 I S / 10

2.5 I 5/10

2.5/5 I 10

2.515/ 10

2.5151 10

Exceptions to preservation chec@ olifonn, TOC, TOX, TOH. O&G. WI DRO, Phenolics, Other: lleadspace in VOA Vials (>6mm) ~Yes oNo o N/A • I r yes look In headspace column

AGJ U I liter amber glass BPI U I liter plastic unpres DG9A 40 mL amber 11scorbic JGFU 4 oz amber jar unpres AGJ H 1 liter amber glass HCL BP2N 500 mL plastic I IN03 DG9T 40 mL amber Na Thio WGFU 4 oz clear jar unpres AG4S 125 mL amber glass H2S04 BP2Z 500 mL plastic NaOH, Znact VG9U 40 mL clear vial unpres WPFU 4 oz plastic jar unpres AG4U 120 mL amber glass unprcs OP3U 250 mL plastic unpres VG911 40 mL clear vial I ICL

AGSU I 00 mL amber glass unpres BP30 250 mL plastic NaOH VG9M 40 mL clear vial MeOH SP5T 120 mL plastic Na Thiosulfate AG2S 500 mL amber glass H2S04 BP3N 250 mL plastic HN03 VG90 40 mL clear vial 01 ZPLC ziploc bag BG3U 250 mL clear glass unprcs BP3S 250 mL plastic H2S04 GN:

F-GB-C-046-Rev.02 (29Mar20 18) Sample Preservation Receipt Form Page _L of!)

Page 32 of 32

peAna/ytieaF Document Name: Document Revised: 25Apr2018

Sample Condition Upon Receipt (SCUR) Document No. : Issuing Authority:

1241 Bellevue Street, Green Bay, Wl54302 F-GB-C-031-Rev.07 Pace Green Bay Quality Office


Project#·

W0#:40190553 Client Name: &£-.1-~~~~----------------------

1111111111111111111111 40190553

Courier: r 9S Logistics r Fed Ex r Speedee

yclient r Pace Other:. ________________ _

Tracking #: -------------------------r-----------Custody Seal on Cooler/Box Present: r yes no Seals intact: r yes r no

Custody Seal on Samples Present: r yes:;( no Seals intact r yes r no

Packing Material: ~Bubble '("_2P ~ubble Bags r None r Other ------:.-----------------------------Thermometer Used SR -~· ./tt Ty~ of Ice: @slue Dry None Samples on Ice. cooling process has begun

Cooler Temperature Uncorr: ~'J../Corr: 1/ll/l q J v

r UPS r Waltco

Temp Blank Present: r yes J( no Biological Tissue is Frozen: r yesr no Perso7 j:3"1:J~g lo;ents:

Date: () Temp should be above freezing to s•c. Initials:( ·""*· ,

Biota Samples may be received at < o•c.

Chain of Custody Present V ves ONo ON/A 1.

Chain of Custody Filled Out ~es ONo ON/A 2.

Chain of Custody Relinquished: ¢es 0No ON/A 3.

Sampler Name & Signature on COC: b('ves ONo ON/A 4.

Samples Arrived within Hold Time: 'Jives ONo 5.

- VOA Samples frozen upon receipt DYes 0No Dateffime:

Short Hold Time Analysis (<72hr): 7JJQO llf {..f:l}es~ 6.

Rush Tum Around Time Requested: )v' DYes ~o 7.

Sufficient Volume: :'Jtv, MSIMSD: OY~No

8.

For Analysis: Yes DNo ON/A

Correct Containers Used: ~Yes 0No 9.

-Pace Containers Used: ~Yes DNo ON/A

-Pace IR Containers Used: DYes 0No ~N/A Containers Intact ·~es 0No 10.

Filtered volume received for Dissolved tests }dYes 0No 'iN/A 11 .

Sample Labels match COC: \~ols~o ON/A 12. No A+<.- ·~ ~'J:l~ -Includes date/time/10/Analysis Matrix: 7J ~/o/

Trip Blank Present: v

0No ~A 13. ':V DYes

Trip Blank Custody Seals Present DYes ONo A

Pace Trip Blank Lot# (if purchased): Chent Notification/ Resolut1on : If checked, see attached form for additional comments D

Person Contacted: Datemme. --------------------------Comments! Resolution: -----------------------------------------------------------------------------

Project Manager Review: Date: -:;}- '-/f -----------------------

Page~of?._

ANALYTICAL REPORTEurofins TestAmerica, Sacramento880 Riverside ParkwayWest Sacramento, CA 95605Tel: (916)373-5600

Laboratory Job ID: 320-51979-1Client Project/Site: ATC Ogden Networking - PFAS

For:GEI Consultants, Inc.3159 Voyager DriveGreen Bay, Wisconsin 54311

Attn: Kyle Sandmire

Authorized for release by:7/19/2019 2:27:10 PMSandie Fredrick, Project Manager II(920)[email protected]

The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

123456789

101112131415

Table of ContentsClient: GEI Consultants, Inc.Project/Site: ATC Ogden Networking - PFAS

Laboratory Job ID: 320-51979-1

Page 2 of 27Eurofins TestAmerica, Sacramento

7/19/2019

Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27

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~

Euroflns TestAmerica, Sacramento WI R"""s.de P•ol<way West SilO'atMrUo, CA 9S60S Phone 511W7J..S600 Fax 5116-372·1059

CHant Information """ COoOoa l<yte Sandrrwe

""""""" GEl Consulran;s. tnc -... 3159 Voyagg Onve

""' Gn!ei!Bay

"""'0 !M. 543t t ,,_ 92Q.241·272S(Teij .... .ksandmlf'e-~geiconst.d'tancs com ~,.,:.,.._

ATC Og- NotWO!l<;,g • PFAS

.,./lTr. • O.,b ~fvtA 11.../-.. w/c '""' J /

Sample l~ntffieation

sne. ll.lsm /'S - M ~v rr1 ilf<;l'(l /A/- M W

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Po$$lble Hctnrd Jd.ntlfkallon

Chain of Custody Record .:·. curonns

--Ke-c;. IAoPII c.m. TJaCblv ~a) COCI<o Freortclc. San<lle 500-734 12·342471

""""'q?o·l'-1(- 272 S"""" £·lo'..ll. . ... sand..e ftedrlck@tu.~c:om Page 1 ol 1 ,.,.

f1oz-zn Analysis Raquested CV. o.u Requ91.ect: Pruetv&tion COdes;

•·= .......... TAl fl:cquUIH j4a)'a): • 8-NIOH N•NON

~ c ·Zn AcC'Q 0 ·A»t•O'l 0-NV.CAod ,. -fi12Gt$

c E • NIIH$04 Q.NIQSOJ • e , .1,411(',)(1 R · Ha2S20l PO• 0·- s . ....,. Pwthose OrOer not required l s li . AIOQtt)c Ace ""·TsPO f'tj~ . ..,. t '0 I

.... U--• z ! J-DVIft# Y·I/CM .._. ~ ·;s ! I( .(QTA w .- plot 4-~

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Sample Matrix .i ~--

E Typo f ~ .. , .. _

Q z Somple (OI:comp, o-.......... :!! l! -;,• 3

SamoleOate Time Gearlbl • • II: ~ Spoeiallnsuuc-cioni/Note: ... ,...., .... it ..

:>< Ptc&MVa!G'l Code: XXN X 7h/<ct1 <l'. Ci0 G wa~et !I )(

7f2/Zci'1 <;r·.>) c Water "' )(

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water

Waler

l~llilllU!II~ I I I I I I I

D Non-HniJITJ ° Ff.ammaolt D SkM'IItn~•nt 0 Poison B 0 Un.,.,.·m D RD<IitJiogOQ/ Si2dlo Dl.spoul (A lee may be usessed if samples ilr• ret.~ I ned longer rhon 1 monrlt)

R•wm To C8om CRI Omxml Bv Lab ~ IUd>Ne F01: I Monll>s Doltllerlllle fl«<uested·l, P Ill, IV. OOler(,_ly) S_.llnoinJct;ons/OC Roqulromems

Empty Kit Rehnq.ti>htd bl' (001> (Timo. • Y.lt1lcd Cll Sl'lil'o'TIIItlt

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#=CL#

July 19, 2019

LIMS USE: FR - KYLE SANDMIRELIMS OBJECT ID: 40190949


RE:

Kyle SandmireGEI Consultants, Inc3159 Voyager DrGreen Bay, WI 54311


Dear Kyle Sandmire:Enclosed are the analytical results for sample(s) received by the laboratory on July 10, 2019. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 17

#=CP#

CERTIFICATIONS








Green Bay, WI 54302(920)469-2436

Page 2 of 17

#=SS#

SAMPLE SUMMARY




40190949001 S-MW Water 07/10/19 09:51 07/10/19 12:41

40190949002 S-PZ Water 07/10/19 09:58 07/10/19 12:41

40190949003 N-MW Water 07/10/19 10:27 07/10/19 12:41

40190949004 N-PZ Water 07/10/19 10:34 07/10/19 12:41




Green Bay, WI 54302(920)469-2436

Page 3 of 17

#=SA#





40190949001 S-MW EPA 6020 10 PASI-GKXS


40190949002 S-PZ EPA 6020 10 PASI-GKXS


40190949003 N-MW EPA 6020 10 PASI-GKXS


40190949004 N-PZ EPA 6020 10 PASI-GKXS





Green Bay, WI 54302(920)469-2436

Page 4 of 17

#=HO#






40190949001 S-MWArsenic, Dissolved 16.0 ug/L 07/17/19 20:271.0EPA 6020Lead, Dissolved 1.1 ug/L 07/17/19 20:271.0EPA 6020

40190949002 S-PZArsenic, Dissolved 16.1 ug/L 07/17/19 20:541.0EPA 6020Nickel, Dissolved 0.73J ug/L 07/17/19 20:541.3EPA 6020Zinc, Dissolved 6.4J ug/L 07/17/19 20:5415.3EPA 6020

40190949003 N-MWArsenic, Dissolved 14.6 ug/L 07/17/19 21:081.0EPA 6020Nickel, Dissolved 0.49J ug/L 07/17/19 21:081.3EPA 6020

40190949004 N-PZArsenic, Dissolved 19.9 ug/L 07/17/19 21:151.0EPA 6020




Green Bay, WI 54302(920)469-2436

Page 5 of 17

#=AR#

ANALYTICAL RESULTS





Analytical Method: EPA 6020 Preparation Method: EPA 30106020 MET ICPMS, Dissolved

Beryllium, Dissolved <0.18 ug/L 07/17/19 20:27 7440-41-707/11/19 07:031.0 0.18 1Chromium, Dissolved <1.0 ug/L 07/17/19 20:27 7440-47-307/11/19 07:033.4 1.0 1Nickel, Dissolved <0.40 ug/L 07/17/19 20:27 7440-02-007/11/19 07:031.3 0.40 1Copper, Dissolved <1.1 ug/L 07/17/19 20:27 7440-50-807/11/19 07:033.6 1.1 1Zinc, Dissolved <4.6 ug/L 07/17/19 20:27 7440-66-607/11/19 07:0315.3 4.6 1Arsenic, Dissolved 16.0 ug/L 07/17/19 20:27 7440-38-207/11/19 07:031.0 0.28 1Selenium, Dissolved <0.32 ug/L 07/17/19 20:27 7782-49-207/11/19 07:031.1 0.32 1Silver, Dissolved <0.10 ug/L 07/17/19 20:27 7440-22-407/11/19 07:030.50 0.10 1Cadmium, Dissolved <0.15 ug/L 07/17/19 20:27 7440-43-907/11/19 07:031.0 0.15 1Lead, Dissolved 1.1 ug/L 07/17/19 20:27 7439-92-107/11/19 07:031.0 0.24 1

Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury, Dissolved

Mercury, Dissolved <0.084 ug/L 07/16/19 10:58 7439-97-607/15/19 10:150.28 0.084 1




Green Bay, WI 54302(920)469-2436

Page 6 of 17

#=AR#

ANALYTICAL RESULTS






Arsenic, Dissolved 16.1 ug/L 07/17/19 20:54 7440-38-207/11/19 07:031.0 0.28 1Beryllium, Dissolved <0.18 ug/L 07/17/19 20:54 7440-41-707/11/19 07:031.0 0.18 1Cadmium, Dissolved <0.15 ug/L 07/17/19 20:54 7440-43-907/11/19 07:031.0 0.15 1Chromium, Dissolved <1.0 ug/L 07/17/19 20:54 7440-47-307/11/19 07:033.4 1.0 1Copper, Dissolved <1.1 ug/L 07/17/19 20:54 7440-50-807/11/19 07:033.6 1.1 1Lead, Dissolved <0.24 ug/L 07/17/19 20:54 7439-92-107/11/19 07:031.0 0.24 1Nickel, Dissolved 0.73J ug/L 07/17/19 20:54 7440-02-007/11/19 07:031.3 0.40 1Selenium, Dissolved <0.32 ug/L 07/17/19 20:54 7782-49-207/11/19 07:031.1 0.32 1Silver, Dissolved <0.10 ug/L 07/17/19 20:54 7440-22-407/11/19 07:030.50 0.10 1Zinc, Dissolved 6.4J ug/L 07/17/19 20:54 7440-66-607/11/19 07:0315.3 4.6 1






Green Bay, WI 54302(920)469-2436

Page 7 of 17

#=AR#

ANALYTICAL RESULTS






Arsenic, Dissolved 14.6 ug/L 07/17/19 21:08 7440-38-207/11/19 07:031.0 0.28 1Beryllium, Dissolved <0.18 ug/L 07/17/19 21:08 7440-41-707/11/19 07:031.0 0.18 1Cadmium, Dissolved <0.15 ug/L 07/17/19 21:08 7440-43-907/11/19 07:031.0 0.15 1Chromium, Dissolved <1.0 ug/L 07/17/19 21:08 7440-47-307/11/19 07:033.4 1.0 1Copper, Dissolved <1.1 ug/L 07/17/19 21:08 7440-50-807/11/19 07:033.6 1.1 1Lead, Dissolved <0.24 ug/L 07/17/19 21:08 7439-92-107/11/19 07:031.0 0.24 1Nickel, Dissolved 0.49J ug/L 07/17/19 21:08 7440-02-007/11/19 07:031.3 0.40 1Selenium, Dissolved <0.32 ug/L 07/17/19 21:08 7782-49-207/11/19 07:031.1 0.32 1Silver, Dissolved <0.10 ug/L 07/17/19 21:08 7440-22-407/11/19 07:030.50 0.10 1Zinc, Dissolved <4.6 ug/L 07/17/19 21:08 7440-66-607/11/19 07:0315.3 4.6 1






Green Bay, WI 54302(920)469-2436

Page 8 of 17

#=AR#

ANALYTICAL RESULTS






Arsenic, Dissolved 19.9 ug/L 07/17/19 21:15 7440-38-207/11/19 07:031.0 0.28 1Beryllium, Dissolved <0.18 ug/L 07/17/19 21:15 7440-41-707/11/19 07:031.0 0.18 1Cadmium, Dissolved <0.15 ug/L 07/17/19 21:15 7440-43-907/11/19 07:031.0 0.15 1Chromium, Dissolved <1.0 ug/L 07/17/19 21:15 7440-47-307/11/19 07:033.4 1.0 1Copper, Dissolved <1.1 ug/L 07/17/19 21:15 7440-50-807/11/19 07:033.6 1.1 1Lead, Dissolved <0.24 ug/L 07/17/19 21:15 7439-92-107/11/19 07:031.0 0.24 1Nickel, Dissolved <0.40 ug/L 07/17/19 21:15 7440-02-007/11/19 07:031.3 0.40 1Selenium, Dissolved <0.32 ug/L 07/17/19 21:15 7782-49-207/11/19 07:031.1 0.32 1Silver, Dissolved <0.10 ug/L 07/17/19 21:15 7440-22-407/11/19 07:030.50 0.10 1Zinc, Dissolved <4.6 ug/L 07/17/19 21:15 7440-66-607/11/19 07:0315.3 4.6 1






Green Bay, WI 54302(920)469-2436

Page 9 of 17

#=QC#







327467EPA 7470

EPA 74707470 Mercury Dissolved





Matrix: Water

Analyzed

Mercury, Dissolved ug/L <0.084 0.28 07/16/19 10:23

Parameter UnitsLCS



Mercury, Dissolved ug/L 4.85 96 85-115

Parameter UnitsMS



MSSpikeResult

40190971001

1901825

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Mercury, Dissolved ug/L 5 97 85-11598 1 205<0.084 4.9 5.0




Green Bay, WI 54302(920)469-2436

Page 10 of 17

#=QC#







327172EPA 3010

EPA 60206020 MET Dissolved





Matrix: Water

Analyzed

Arsenic, Dissolved ug/L <0.28 1.0 07/17/19 14:59Beryllium, Dissolved ug/L <0.18 1.0 07/17/19 14:59Cadmium, Dissolved ug/L <0.15 1.0 07/17/19 14:59Chromium, Dissolved ug/L <1.0 3.4 07/17/19 14:59Copper, Dissolved ug/L 6.7 3.6 07/17/19 14:59Lead, Dissolved ug/L <0.24 1.0 07/17/19 14:59Nickel, Dissolved ug/L <0.40 1.3 07/17/19 14:59Selenium, Dissolved ug/L <0.32 1.1 07/17/19 14:59Silver, Dissolved ug/L <0.10 0.50 07/17/19 14:59Zinc, Dissolved ug/L <4.6 15.3 07/17/19 14:59

Parameter UnitsLCS



Arsenic, Dissolved ug/L 486500 97 80-120Beryllium, Dissolved ug/L 498500 100 80-120Cadmium, Dissolved ug/L 514500 103 80-120Chromium, Dissolved ug/L 482500 96 80-120Copper, Dissolved ug/L 490500 98 80-120Lead, Dissolved ug/L 492500 98 80-120Nickel, Dissolved ug/L 488500 98 80-120Selenium, Dissolved ug/L 503500 101 80-120Silver, Dissolved ug/L 260250 104 80-120Zinc, Dissolved ug/L 503500 101 80-120

Parameter UnitsMS



MSSpikeResult

40190949001

1899498

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Arsenic, Dissolved ug/L 500 102 75-125103 1 2050016.0 524 532Beryllium, Dissolved ug/L 500 90 75-12592 2 20500<0.18 452 461Cadmium, Dissolved ug/L 500 99 75-125101 2 20500<0.15 494 504Chromium, Dissolved ug/L 500 97 75-12599 1 20500<1.0 488 494Copper, Dissolved ug/L 500 97 75-12599 2 20500<1.1 487 496Lead, Dissolved ug/L 500 96 75-12597 1 205001.1 481 487Nickel, Dissolved ug/L 500 97 75-125100 2 20500<0.40 487 498Selenium, Dissolved ug/L 500 104 75-125106 2 20500<0.32 520 530Silver, Dissolved ug/L 250 96 75-12598 2 20250<0.10 240 245




Green Bay, WI 54302(920)469-2436

Page 11 of 17

#=QC#





Parameter UnitsMS



MSSpikeResult

40190949001

1899498

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Zinc, Dissolved ug/L 500 101 75-125103 2 20500<4.6 508 517




Green Bay, WI 54302(920)469-2436

Page 12 of 17

#=QL#

QUALIFIERS



DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above LOD.J - Estimated concentration at or above the LOD and below the LOQ.LOD - Limit of Detection adjusted for dilution factor, percent moisture, initial weight and final volume.LOQ - Limit of Quantitation adjusted for dilution factor, percent moisture, initial weight and final volume.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected at or above the adjusted LOD.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES





Green Bay, WI 54302(920)469-2436

Page 13 of 17

#=CR#





40190949001 327172 327279S-MW EPA 3010 EPA 602040190949002 327172 327279S-PZ EPA 3010 EPA 602040190949003 327172 327279N-MW EPA 3010 EPA 602040190949004 327172 327279N-PZ EPA 3010 EPA 6020

40190949001 327467 327542S-MW EPA 7470 EPA 747040190949002 327467 327542S-PZ EPA 7470 EPA 747040190949003 327467 327542N-MW EPA 7470 EPA 747040190949004 327467 327542N-PZ EPA 7470 EPA 7470




Green Bay, WI 54302(920)469-2436

Page 14 of 17

Page

15

of 1

7(Please Print Clearly)

~.~ UPPER MIDWEST REGION Page 1 of (

Company Name: GG~ c<M .... I~ ... ~ ~c.. MN: 612~07-1700 WI: 920-469-2436

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Phone: 4vrk ~~,. 82t:>e:. CHAIN OF CUSTODY Mall To Contact: ff'lb. );.vo.J.,. I A-t. Proj ect Number: /t:fo'2z~7 I: 'PR!trvt!!on C9du Mall To Company: .k-:;:. a....s~ /),~ ::M.t. A• Nont BaHCL CaH2S04 D-HN03 Et OI Water F•Me!Mnol GaNIIOH {Sf::>

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PRESERVATION ..... 0 Inv oice To Contact: (CODE)' ~

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i -t (billable) C • Chara>el GW • Ground Water

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your sample SI • Sfudae WP • Wlpe CLIENT LAB COMMENTS Profile I

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v. .. C019a(27Jun2006)

ORIGINAL

Page

16

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7• • Pace Analytical Services, LLC Sample Preservation Receipt Form 1241 Bellevue Street, Suite 9

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009 ............. .......... 2.5 I 5 I 10

010 ............. r-..... 2.5/5 I 10

011 ............. r-......... 2.5 I 51 10

012 ............ ............ 71 bll ~~6, 2.515110

013 .......... r--...... 2.5151 10

014 -r--. 2.515 I 10

015 --.. r-... 2.5/5 /10

016 ---r-- 2.5/5/ 10

017 -r-- 1-. 2.5/5/ .1 0

018. ............... ............ 2.5/51 10

019 ............. r-.... 2.5151 10

020 i4 ~ 2 .5 /5110

Exceptions to preservation check: VOA, Colifom1, TOC, TOX, TOH. O&G, WI ORO, Phenolics, Other: Hcadspacc in VOA Vials (>6mm): oYes oNo f tA *Jfyes look in hu dspace colu1

AGIU I liter amber glass BPIU I liter plastic unpres DG9A 40 mL amber ascorbic JGFU 4 oz amber jar unpres AGlH I liter amber glass HCL BP2N 500 mL plastic HN03 DG9T 40 mL amber Na Thio WGFU 4 oz clear jar unpres AG4S 125 mL amber glass H2S04 BP2Z 500 mL plastic NaOH, Znact VG9U 40 mL clear vial unpres WPFU 4 oz pla:stic jar unpres AG4U 120 mL amber glass unpres BP3U 250 mL plastic unpres VG9H 40 mL clear vial HCL

AGSU I 00 mL amber glass unpres BP3B 250 mL plastic NaOH VG9M 40 mL clear vial MeOH SPST 120 mL plastic Na Thiosulf.'lte AG2S 500 mL amber glass H2S04 BP3N 250 mL plastic HN03 VG9D 40 mL clear vial Dl ZPLC ziploc bag BG3U 250 mL clear glass unpres BP3S 250 mL plastic H2S04 GN:

F-GB-C-046-Rev.02 (29Mar2018) Sample Preservation Receipt Form Page j_ o~

Page 17 of 17

PAnalytical· Document Name: Document Revised: 25Apr2018

Sample Condition Upon Receipt (SCUR)

Document No.: Issuing Authority:

1241 Bellevue Street, Green Bav. W l 54302 F-GB-C·031-Rev.07 Pace Green Bay Quality Office


Project #· I

Client Name: 6f:( LI0#:40190949 Courier : r CS logistics r Fed Ex r Speedee r UPS r Waltco

II II II Jill II 111111 1111 t Client r Pace Other:

Tracking#: 40190949

Custody Seal on Cooler/Box Present: r yes r( no Seals intact r yes r no I I

Custody Seal on Samples Present: r yes rj no Seals intact: r yes r no

Packing Material: r Bubble ]p rt' Bubble Bags r None r Other

Thermometer Used SR - )J A Type of Ice: C)t Blue Dry None if Samples on ice, cooling process has begun

Cooler Temperature uncorr: f,:o ( /Corr: ---Temp Blank Present: ryes J7no Biological Tissue is Frozen: r yesr no Person 7fi:"Jn~contents: Date: 611 Temp should be above freezing to s·c. Initials: //<'~ Biota Samples may be rereived at s o·c.

Chain of Custody Present ¢Yes DNo O N/A 1.

Chain of Custody Filled Out DYes ~No ON/A 2./J 1) ; "'" n ,-u J/m/1' J '""' Chain of Custody Relinquished: if~es DNo ON/A 3.

I

Sampler Name & Signature on COC: ~es DNo ON/A 4.

Samples Arrived within Hold Time: Jlfves 0No 5.

- VOA Samples frozen upon receipt DYes ONo Date/Time:

Short Hold Time Analysis (<72hr): DYes ¢No 6.

Rush Turn Around Time Requested: DYes ¢'No 7.

Sufficient Volume: 8.

For Analysis: rJves DNo MS/MSD: DYes J?]No ONIA

Correct Containers Used: 12J'ves 0No 9.

-Pace Containers Used: rives 0No ON/A

-Pace IR Containers Used: DYes ONo r;1NIA

Containers Intact: ~es 0No 10.

Filtered volume received for Dissolved tests r/ves DNo 0 NJA 11 .

Sample Labels match COC: yrYes 0No O N/A 12.

-Includes date/time/ID/Analysis Matrix: w Trip Blank Present: DYes 0No

~: 13.

Trip Blank Custody Seals Present DYes DNo

Pace Trip Blank Lot# {if purchased): Client Notification/ Resolution: If checked, see attached form for additional comments D

Person Contacted: Date/Time: Comments/ Resolution:

Project Manager Review: CfJ- Date: c::;J. ., I o -11 Page..Q_ot


Well Installation Diagrams

0 COLEMAN ENGINEERING COMPANY 0 635 CIRCLE DRIVE OFFICE ALSO LOCATED AT:

IRON MOUNTAIN, MICHIGAN 49801 200 E. AVER ST.

FIELD BORING LOG IRONWOOD. MICHl~ 49938

\ OF ( BORING NO.\ O,,"Jo PAGE

PROJEcTGU L·) I JOB NO .!Z_6 "J ft SURFACE ELEVATION BENCH MARK DRILLER:~ HELPER _,2\1\_ RIG NO~

DATE START: :J-(,-(8 BORIN() LOCA TI()N OfFSET

hi?J HSA. SIZE ':h..l.5. FROM.().!.lL. TO~ 5" CFA FROM

% DATE END.· CASINO.SIZE. FROM TO __ CASING ADVANCER. SIZE FROM RB. SlZE FROM __ TO __ MUO TYPE FROM

0

ROCK CORE. SIZE FROM TO - OTHER FROM T

SAMPLE SOIL DESCRIPTION DRILLING AND DEPll<

SAMPLE NOTES HO !LOW COIMS I 6" DEPTH riPE AEC

I Br: v) I' "

0·0

WP ~

•' t8 ( {)5.lj I

THICKNESS OF: DEPTH TO:

TOPSOIL ~} WEATHERED ROCK

CONCRETE SOLID

ASPHALT -1 ROCK

eono~§:. BASE COURSE .,£. WELL

BOTIOM£lF FROST BORING )r

BACKFILLING INFORMATION: FROM TO

SOIL CUTIINGS -8ENTONITE __ --NEAT CEMENT -CEMENT/BENTONITE -GROUT (RATIO). -

HARD DfiiLUNG: FROM TO

-- ---

COBBLES AND/OR BOULDERS

GROUNDWATER SAMPLE WET FROM TO FROM TO FROM TO

MEASUREMENTS FROM TO

DEPTH DURING DRILLING f/1 (\ -- -- -- -- -- --DEPTH AT COMPLETION ' -- - - -- -- -- --AFTER AUGER REMOVAL FT.

WITH CAVE IN DEPTH OF FT -- -- -- -- -- -AFTER HAS. FT. ~

LWCAL GBOUNDWAII:B MONITOBING WELL CONSIBUCIION DEIAII.

~- ........... Bl I

LOCMeLE COVIA • "-...

WELL NO. I .,... ' ,..

ICAEWONCAP

~ fYt.J8 /"LOCK 'j. ~~I ER $1 EIC"OUit:c; :.~ FlUSH MOUHT MTAIL

VEHT 3'

1'1· ·I· I CHECK F A.USH MOUHT l HAnMAL~

• . COHCHEIE - : f • r . ·r-

~!:d o.o-d o'

. . . SOJCA ..... . • - -;),Z> t' . . --~ . • ~

r~-.•.p.:::, ().rJ-•J.o' . . • ~ . . s::;: f%

• . ~ ~ . ll.~ SIUCASANO

~~ ANNULAR SPACE &e:Al NOTES:

(SPEC'""' ~~ A.,, I !f'CJ. l-2 17!

~~ <@:_SCH<DUL£ 40 P.v.c:;;_,. ~~ TOTAL LENGTH

OF WELL RISER&

~ew-JOWT-,.P&.OA-OTH1!

~~ '""''"" (SPECIFY) n ;; ~

~ ~ ~ TOTAL DEPTH

~ OF WELL

Bf.LOW ORAOE

~ J•i' l

~ s.,"c ;;l.l\- (, ,,.., . )'I,..,

<!:~~CITHEA . . /' LJ, (l '), () . . . ..,_ -. : . G\o'-'t ("' Lf.o . . .. d . . _..,.. c "'jl ' . r ~c - (1 1 ;J

SPECIFY $am ~.~ ..,..;(1'('~ 74CJ- ;J<, r

~ .!!1" S&JCA...., ""'CFY - < d 1·1 -_...r ~r.r c c:

I-' r......,.,... 40 ,,;:e:r "7"A . ..,_: ,,((,..J. f • J ( ant<A Was well developed on lhli' date by YES

(SPE well Installation crew? NO ./

QOTSIZE II\ q, (I ' Water Level

CAPOROTHEA ':J. L ~~ \ ~

c~rew

""" ~

f'.. ~ 'f?Dt,.1 A JOB NO. G· (I. ..

SPECI')~'l('IU. MA .... IAl DATE J I lX' .- r

JOB NAME (.;/ I - (._ft._ tC)J COLEMAN EJ!OINEEAINO COMPANY 835 CIRCLE DAIVS IRON MOUNTAIN, MtCtiiOAN •UII01

0 COLEMAN ENGINEERING COMPANY 0 635 CIRCLE DRIVE OFFICE ALSO LOCI\TED AT: IRON MOUNTAIN, MICHIGAN 49801 200 "' AYE>! ST.

FIELD BORING LOG IRONWOOD, MICHt f 49938 W ) BORING NO. 8 c\ PAGE_' _OF_

I eel"\ reo GrT JOB NO. I~D.t.~/1 l!!:r ELEVATION: BENCHMARK DRILLER: ... ":t. HELPER:,~ 1"\ RIG NO. 150-::l

!DATE START:;) - {, - /~ BORING LOCATION: OFFSET:

!DATE ~ .. n ..J h / '[< 1~ !!SA; SIZE 4 FROM . : !Q .),'..._ ~ ~~~ FROM TO/

;SIZE FROM ."'-, /~-~ =~~~RE; SIZE

:::;:, '~ r MUD TYPE FROM ~g . FROM~ ~-0 OTHER FROM

SAMPLE SOIL DESCRIPTION DRILLING AND u c r

SAMPLE NOTES NO. 1 BlO\\ COUNTS ' 6' IDEPTI TYPE IREC.

I i\ :. ·• Jr.ll ~ i II

t:~e I') r ,,

OF: ~~o_n TO_:

i.N:r< =-~ ~~~~ -O<:P ... AI

fBASE COURSE __ ~~rro~~9F ~~.!. '.u~I9Fo ' MU:>I

INFORMATION: FROM TO

SOIL CUTIINGS -BENTONITE - ---NEAT CEMENT ----CEMENTISENTONITE ---GROUT (RATIO); __ -- --

HARD DRILLING: FROM TO

--/~

, / COBBLES AND/OR BOULDER S

GROUNDWATER SAMPLE WET FROM T O FROM T O FROM TO FROM TO

l"'"r oc DURING DRILLING $ -0 ' -- -- -- -- -- --1 u~.- 1 n AT COMPLETION

.IFTER AUGER REMOVAL FT. ,/ -- -- -- -- - - --,

WITH CAVE IN DEPTH OF-- FT. -- -- -- -- -- --/

AFTER HAS ~FT -- -- -- -- -- --

IYeJ.CALJ:iB.QUt:HlWAIEB MONIIQBING WELL CONSTRUCTION DETAIL

~ID LOCKAIILI COYIA WELL NO. B I II 11)11

~ ICRIWON

""' , ):. ~ .., ~....,.ET.;. .... ,.......,=

FWSH MOUKT O£TAA.

' I , .; J

CHE~ F R.USH MOUNT l COHCHEIE-1:· t

[ • ~I- 1-

~ SILICA

E: SAIIO

17; r: -- -~ ~ r=

~ '% ~ ~ L.:

v,-:

~~ M '\: J -L~ NOTES:

~ de~ IQ(l~o!. J- 7 - I'll ~

~~ w -~ ... ~ ~~ ·~f~h'

~~ SC:AEEH

15 .0 "' ,../ 'l ll - I' . [\ ~,. -

~~ ('h fl ' h.o- J.O

·~<>!~~':."' / qld !~.~ - b.n

~@ , ..., ' ,Q; Df

;" i ,(J I" __.;/" 5. f: c t ,,

If •

I·.

~ ~ .. I:·. 1:: I •

::;- '\ • ~. -r FMSAIIO • ' ' SPECFYSQ£

UCKfU ~ IIICA SAJC) SPEC# I

,., ~.~ &CMW ..o..T Wii I::,~ ~~nation c.::1n this date by Y~~

SPECIFY SlOT SIZE !0 Water Level 0 ('\

=~OAOTHER .) L:, \1"'

""" Crew

l'j r-<.n IJoa NO. G· 12t h 3 fl SPECWJ~~RLL MATERIAL

DATE v (~ 1'3 13 . ~ 0 COLEMAN ENQIN£5AINQ COMPANY

JOB NAME (.., (-l . \

13.!1 CtRCU! OIUVE ~

lOON MOUNTAIN, MtCHIGAN 49101

0 COLEMAN ENGINEERING COMPANY 0 635 CIRCLE DRIVE OFFICE ALSO LOCATED AT:

IRON MOUNTAIN, MICHIGAN 49801 200 E. AVER ST. IRONWOOD, MICHIGAN 49938

PAGE_\ _OF j_ FIELD BORING LOG BORING NO. '16":1

IPRn. (;[l l.. . . :.. JOB No. l'llbk, 3 A

l!=:l ELEVATION: BENCH MARK DRILLER: )_ HELPER : ~~ RIGNO. n?.~

IDATE START:r'} 5. I':>$ BORING LOCATION:. OFFSE'T:

IDATE ENo, 'l- ~- r11 w HSA: SIZE "I • 85 FROM~ TO JlhOw S"CFA FROM~ TO/ o CASING:SIZE FROM ~ T~_;;z-w CASINGAOVANCER. SIZE FROio! rii.. '1 RB1 SIZE FRQI.I '-' MUD TYPE FROM 0 ROCK CORE; SIZE FRQI.I ~C' OTHER~

SAMPLE SOIL DESCRIPTION DRILLING AND SAMPLE NOTES NO I BLOY. COUNTS ' 6" IOEPTl TYPE IREC.

I u .,1 ~ .II ~ J'b.{'

.{:', \\

(L~ 10.0

OF: I DE_PT_.H _T_o~

- I Roc•t~ I T

1r;, - ~ ~~~ -

BASE COURSE .:=.._ ~~~: r.~ ~F

I ~!":() ~,· ({7> rMU'> I

BACKFILLING INFORMATION: FROM TO

SOIL CUTTINGS --D C. I< 0 VI'U C. ---"c." ' ----

0 V"" c. ---'""'UT (RATIO);


~j\ o!",i)


GROUNDWATER SAMPLE WET FROM TO FROM TO FROM TO FROM TO

DEPTH DURING DRILLING ~ -- -- -- -- - - --DEPTH AT COMPLETION

IAFTER AUGER REMOVAL FT. -- -- -- -- -- --WITH CAVE IN DEPTH OF -- FT. -- -- -- -- -- --

[AFTER HAS. eFT. -- -- -- -- -- --

:.0 '"'"' ·~"''

-

l:Y~ICALGRQUNDWAIEB MQflJIIOBI~G WELL CQflJSTBUCTIQN DETAIL

G I(!GED <DC"""'" cov;-- WELL NO. Q,~f}·.)

~ SCAEWOHCU ~ ~

;)'IN....:~~ S"'otAMETEA snn GUAAO PIN: FUI$H UOUHT DETAil.

V(HT

- I·,. . ,· I ctt'ECit ~ t\.USH MOUH'T

' ~ NAI'UOAL-

• . :: ._......-~· T . . ....-. ::

eanoNITE IWG . IIIJCA CONCAEIE P\..UG

. ~ $AND PLUG OR . •

OT><ER ($PEart) . :: ..__. • .o'L~ . ~ . . . ~ ~ ~ .

• . V,t 1.:

SIUCASAHD

~ ~ ANNULAR $PACE SEAL NOTES:

~ r,;•Eclfvo Wcl!t c!r.ljlS

~ (Je~ dP•IRff~ ~ J - I? .

~ ~ TOTAl. lENGTH ~

~ OFWEU.

2" Dt.A. SCH!OOL! 40 P.V.C.

~ RISER &

SCREW JOINT PIPE OR OTHER SCREEN (SPE(:IFY) 1a,s

~ ' 3.' :;i±kt::. "e l!!> si~~

~ ~ ~I'., L.f, ~ q,_r

~ TOTAL DEPTH _5q..,J -\;1( C'M o.c--J.S

~ Of WELL BELOWORADE t-1\-hr.;.! I' ~~.g. if.ll· l ,,s: - 3.S

~ ~ ~ .<; ";a~ ~~i:::ll4' ~. L) - lQ,D . .

~,~ • • • . ( ~EHTOJn£::.. -OTHER . . . . . . . . . .

-~..,. SP£CIFY l ') ~ \1. ..i . . I -BACKFIU. wmt SIUCA SAND SP£CIFYSttf ,.c

~~-5 ! (SCREW JOINT WEU SCREEN~ OT'M[R Was well developed on this dele by YES

welllnstaUaUon crew? NO .r

~10 Water level ll, 0

OTHER Crew :JL _)f"' c

"' '< 1 ,"') JOB NO. G· lZO (o ~ t I

SPECIFY BACKFU. MATERIAL DATE J ·r I ,)

10 I[)

JOB NAME Gf'J - I ' ~ COLEMAN EHOINEERINQ COMPANY

63$ CIRCLf: DRIVE IRON MOUNTAIN, MK:HIOAN •111101

COLEMAN ENGINEERING COMPANY 635 CIRCLE DRIVE OFFICE ALSO LOCATED AT:

IRON MOUNTAIN, MICHIGAN 49801 200 E. AVER ST. IRONWOOD, MICH¥~AN ·~38 I (

FIELD BORING LOG BORING NO . .Od tt i;<~<f'AGE __ OF _

IPRn. G .?"L - V:\s JOB 1110. 1 '1\o£. ;, , ls1 ELEVATION: MARK DRILLER: )J HELPER: , ) t'\ RIG NO. -m~

IDATE START:;:}. ·6 •/"g BORINGLOCAT!: v rroc "

lr>A-rc END:9 b ·If ~ ~SA; SIZE 1./,~ : ~=g~~TC ...C:::: : '-' [A~;: ; SIZE ~=~ ~ v l~n' ~ 0 RB: SIZE " MUD TYPE FROM p

.o ;;;;;.;;,-,.-;., : s1z~o OTHER-

SAMPLE SOIL DESCRIPTION DRILLING AND v c•'" SAMPLE NOTES

•'0. I BI.O'~ COUNTS ' 6" IOEP~ TYPE I REC

~NJ'~~~~~ SAMPLE WET FROM FROM TO

;vcr , n DURING DRILLING t.J .o --\ jUCt'IM AT COMPLETION --

IAFTER AUGER REMOVAL FT. WITH CAVE IN DEPTH OF FT. /

--!AFTER HAS . FT. --_L

/

OF: IP~!_HTO:

·~~:~~.~~E~d_/= I ROCK lc '"' "'-1 ~ ~~'='o I ASPHAL'l T ~ ~~q ~· BASE COURSE L;_ :wm ~ ?~ rnv;, I ,-, !~!.!.':'!" s~

BACKALLING INFORMATION: FROM TO

SOIL CUTIINGS - -DC" OV"H C - -NEAT CEMENT . -

WDCO" V"H c - -" (RATIO);


Q,D ~0


TO FROM TO FROM TO

-- -- -- -- ---- -- -- -- ---- - -- -- - --- -- -- -- - -

-

Jxei.CAL GBOUNDWAIEB MONIIOBJNG WELL CONSIBUCIIOf:!! DEIAII.

RaA -(:, I <'I ( HINGED LOC:·K.t.8Ll C~ WEll NO.

' SCAEWOHCAr ~ ;n'?>. C•

{ s- DIAMET'ER ST!lL QUAJIIO ,,_ FLUSH MOUNT OITAa ..

VENT 3'

CttECK W FLUSH MOUNT 1',. ., I l HAMW-. . WIE-: T . r: . i<" f-.

eem>NTtPl.UG . [· SILICA

ir~PE • ......,

/ . . . .__.. -l% . .

~ . r. ....,. ~ . ~ • . SfA1. , , . ~ (' \..-'. Li"-

. I ~:S

v,~

I.:

~ ~ 3~o ANNULAR SPACE S£AL NOTES: (SPECIFY} fZ,o1,0)' f.<-.,,"\ ~ ~ Qc\l'f I ~f: ~-1- 11J

~ ~ < / 0 I '

i 1-

~ ~ TOTAL LEHGTM ' ..... •' ~~"t"iff<'tm. ••

OFWEU.

~ ~ RlSER& SCREEN

(SPECIFY) da-:5 ~ ~

~ 1%

~ TOTAL DEPTH .s,.~ /),D- I~"'" OF WELL

~ 8EL.OWGAAOE

Cl--\2'- I I s '3 .Q ~ f'.) ,Q

(,to..A 3 0 -15()

iS~··" ·. IS:o I' "~""' 15 '0 - aa 11) ;j-c~anteA I:·. I:: S,,J. lb .o -Jo.o I •

-~..,. SPECIFY - ,J. (J J(.,,r ":". v~ 1l 'I

BACKA..l. W1TM SI.JCA SAHI) SPECIFY SZlE

·' ~~~

j y Was well c!eveloped on this date by YES well installation crew? NO .r ;:) s:'

SPEQFY SlOT SIZE r.o Water level 1 ..

~~~~~OTHER Crew \~,-. )!~

""" " JOB NO. G- 19f' t, ~ r• 1'1 • 0

SPECIFY ~KF&U. DATE ? - ("(-~ ...

;)rJ ' l " ' -1 ' 0 COLEMAN EHOINEERIHO COMPAHV JOB NAME r' • ~ 635 CIRCLE DRIVE IRON MOUNTAIN, M ICtitOAN •11101



Appendix E

Development at Historic Fill Site Exemption Application and Supporting Documentation

Development at Historic Fill Site or Licensed Landfill Exemption Application

Page 1 of 6Form 4400-226 (R 05/16)

Notice: Use of this form is required by the DNR for any application to develop at a historic fill site or licensed landfill pursuant to secs. NR 506.085 and NR 500.08(4), Wis. Adm. Code. The Department will not consider your application unless you provide complete information requested. Personally identifiable information collected will be used to process your application and will also be accessible by request under Wisconsin's Open Records law [ss.19.31 - 19.39, Wis. Stats.]

Instructions: See Development at Historic Fill Sites and Licensed Landfills: What you need to know (PUB-RR-683, November 2013) for detailed instructions.• All Exemption Application materials should be sent to the region where the site is located, as listed on page 6. • Include $700 fee payment with this application. If the site is a licensed landfill and the Waste and Materials Management program

is doing the review, submit no fee now. You will be sent an invoice upon receipt of this application. • Determine the appropriate exemption type for the site and check appropriate box below. • Provide complete information requested for each type of exemption. Include the following attachments:

Required: Summary of Existing and Potential Impacts described in Section V as an attachment, under the seal of a professional engineer or geologist registered to practice in Wisconsin.

Optional: Site Visit Summary Comments (Section IX) including any photos, sketches or site visit notes.

State of Wisconsin Department of Natural Resources PO Box 7921, Madison WI 53707-7921 dnr.wi.gov

Exemption TypeRemediation and Redevelopment Program NR 700 Rule Series Process Exemption: Site with remedial actions conducted in accordance with NR 700 series Required: Sections I - VI Optional: Sections VII - XCase-by-Case Evaluation: Sites with anticipated environmental impacts or wastes of special concerns Required: Sections I - VI Optional: Sections VII - X Expedited Exemption: Site with no expected environmental impact Required: Sections I - VI and Form 4400-226A Expedited Exemption Application Optional: Sections VII - X

I. Applicant InformationOwner - Last Name

Waupaca Foundry (Property) ATC (Easement)First

Bryant Esch (WFI)MI

(715) 258-6674Contact Name (if different)

American Transmission Company (ATC) - Crystal Koles (ATC) - (920) 338-6530Street Address

805 Ogden StreetCity

MarinetteDeveloper - Last Name

ATC & (WPS)First

Crystal Koles (ATC)MI

Street Address

P.O. Box 6113 - 801 O’Keefe RoadCity

De Pere

(920) 338-6530

State

WI

State

WI

ZIP Code

54143

ZIP Code

54115 II. Site Name and Location

Does the site have a license number?

Site Name

ATC Ogden Street Substation and N-14 Transmission LineIs the site known by another name(s)? Yes No Unknown

Yes No UnknownHistoric landfill site (Site ID 885300)

If yes, License Number:

Location / Address

805 Ogden StreetCity Town Villageof Marinette

State

WIZIP Code

54143County

MarinetteA. Attach a map with site location and limits of fill/waste disposal area.B. Global Positioning System Coordinates

Latitude

45 05 N

Longitude

-87 36 W

Describe method for collecting GPS CoordinatesGoogle earth aerial interpolation and measurement. Conversion from DD to DMS.

Program Lead, Fee Status and Regulatory ID Numbers (This area for DNR use only)Waste Management BureauRemediation and Redevelopment Bureau - Exemption is part of remedy under NR 700 program

Fee already paid for review of remedial design report.Review of remedial design report not requested and payment is attached.

Payment AttachedAmount

$Hazardous Waste Facility License ID #:(5 digits) DNR FID #: (9 digits) USEPA ID #:(used for both RCRA & CERCLIS #s) (WI+Alpha+9 digits)

Region Project Manager Telephone Number

Previous Owner- Last Name

of Marinette Street Address

Responsible Municipal/ Private Operator- Last Name (if applicable)

Address

Development at Historic Fill Site or Licensed Landfill Exemption Application Form 4400-226 (R 05/16) Page 2 of 6

A. Analytical data for the following media have been collected and/or examined before completing this application :

1. Groundwater: @ Yes 0 No

2. Soil : @Yes 0 No

3. Surface water I sediment: 0 Yes @ No

4. Air: 0 Yes @ No

5. Methane or other explosive gases: 0 Yes @ No

B. Based on known or suspected sources and wastes, their physical characteristics , containment and geologic environment, do you suspect a release of pollutants to the environment?

@ Yes I:8J Groundwater I:8J Soil D Surface Water I Sediment D Methane or Other Explosive Gases

0 No

C. If there is NOT a likelihood of a release of pollutants or evidence of a release, would the impact of the proposed development be likely to cause a release to the environment?

0 Yes: If yes, be sure to summarize actions to be taken to prevent adverse environmental impacts in V. Part C below.

@No

V. Summary of Existing and Potential Impacts. See Development at Historic Fill Sites and Licensed Landfill: Guidance for lnvesti!:Jation and Development at Historic Fill Sites and Licensed Landfill: Potential Problems and Considerations.

Describe the following in an attached narrative under the signature of a qualified professional. Organize, label and package as listed below.

A. Existing Site Conditions

1. existing site conditions including waste types,

2. potential for impacts, and

3. evaluation of existing impacts.

B. Proposed Development Summary. Include explanation for overall site decision.

C. Summary of actions to be taken and engineering controls that will prevent or minimize adverse environmental impacts and potential threats to human health and welfare, including worker safety.

VI. Certification of A lication Information

I certify that information in this application and all its attachments is true and correct and in conformity with applicable Wis. statutes.

Print I Type Name of Applicant

Crystal Koles - American

Date Signed _'g-+--t -1!3 L'----'-!9...__ I I


Page 3 of 6Form 4400-226 (R 05/16)

Sections VII - IX are optional for all Applicants. VII. Current and Historic Type of Waste Disposal Site (Check all that apply)

Licensed LandfillNon-approved {See s.289.01(3)}, Wis Stats.Approved

One-time DisposalConstruction / DemolitionHistoric Fill Site

Liner Total Landfill VolumeUnlinedLinedComposite LinerOther Liner (Describe):

Clay LinerUnengineered

< 50,000 yd ³ 50,000-500,000 yd> 500,000 yd ³

Does the landfill have a closure plan?

Does the landfill have a groundwater monitoring plan?

Have groundwater monitoring wells been installed?

Yes No Unknown

Yes No Unknown

Yes No Unknown

Was a cover installed? Yes: No If no, go to Past Land Uses.

Composite capLayered soil cap with clay barrierClay capSoil cap - not recompacted clayOther coverUnknown

What is the thickness of the cover? < 6 in 6-12 in 12-24 in > 24 in Unknown

Past Land Uses. (Check all that apply)

Agricultural co-opBrush pileBulk plantCoal gas manufacturerDeer pitDry cleaner

ElectroplaterLagoonManufacturing Type:Old burn pitPipelineRCRA generator

Salvage yardService StationTanneryUnknownOther: Ag. & coal storage

(1938)

Date(s) of Site Operation

From: To: UnknownNo. of Years

VIII. Waste Information & Geologic Environment. See Development at Historic Fill Sites and Licensed Landfills: Guidance for Investigation

A. Known or Suspected Sources/Wastes. (Check all that apply)

B. Physical Characteristics of Sources/Wastes

Liquid Solid Liquid & Solid Unknown

Abandoned containersAbove ground pipeline or tankAnimal carcasses Buried drumsBurning of materialsFoundry sandIndustrial accident

Known or suspected hazardous materialsMunicipal wastePaper mill sludgeTransformerTrees/brushSurface spillsFly ash

Demolition/construction wasteSurface impoundment/lagoonsUnderground pipeline or tankExempted fill [NR 500.08(1) and (2)]UnknownOther:


Page 4 of 6Form 4400-226 (R 05/16)

VIII. Waste Information & Geologic Environment (continued)C. Waste Containment Liner Unknown Not applicable

Engineered cover

Maintained Not maintained

Functioning leachate collection & removal system Functioning & maintained run-off management system Functioning groundwater monitoring system

D. Soil Type: Estimate distances or determinations based on regional or site specific information.

Regional Site specific

Clay, silt or other fine grained soils present? (lacustrine, tills, etc.) Yes No

At surface? Yes No At depth? Yes No feet25

Sand & gravel, coarse grained soils present? Yes No

At surface? Yes No At depth? Yes No feet15

E. Depth to Groundwater

Regional Site specific feet4

F. Direction of Groundwater Flow

Regional Site specific directionradially toward surface water

G. Depth to Bedrock

Regional Site specific direction~50 feet

H. Bedrock Type

Regional Site specific Metamorphic/IgneousLimestone/DolomiteSandstone

General site conditions: Document any observed releases and note whether or not you were able to walk the site. Examples of things to be aware of include the following:

• leachate seeps or evidence of seeps such as stained soil/vegetation• stressed vegetation as a sign of gas migration to the surface or of leachate seeps;• quality and coverage of vegetation on the cap;• odors which may indicate gas migration to the atmosphere;• erosion of the cap;• maintenance of positive drainage over the capped area;• visual desiccation cracks in the cap.

Attach the following to your application:

IX. Site Visit Conduct a site visit to complete site screening and determine general site conditions, on-site activities and adjacent land use encroachment issues. As appropriate to document the site, take photos, sketch the site and prepare a Site Visit Report.

On-site visit conducted?

Photographs, regular or digital Site sketch

Name(s) of Person(s) Conducting Site Visit

Site Visit Report

Yes No

Date of Site Visit


Page 5 of 6Form 4400-226 (R 05/16)

IX. Site Visit (continued)A. Adjacent Land Uses. Indicate all directions. (Check all that apply)

Agricultural N S E W NE NW SE SWIndustrial N S E W NE NW SE SWRecreational N S E W NE NW SE SWResidential N S E W NE NW SE SWUndeveloped N S E W NE NW SE SWCommercial N S E W NE NW SE SWOther: N S E W NE NW SE SW

B. Potential Groundwater Receptors. Estimate distances. (1 mile = 5,280 ft)

Distance to and direction of nearest municipal well: feet direction

Distance to and direction of nearest other-than-municipal well: feet direction

Distance to and direction of nearest non-community well: feet direction

Distance to and direction of nearest private well: feet direction

Distance to and direction of nearest private well: feet direction

C. Potential For Gas Migration

No. of homes within 300 feet of waste (gas migration potential)

No. of homes between 300 & 1,000 ft to waste (gas migration potential)

Distance to and direction of nearest building: feet direction

Type of building: UnknownIndustrialCommercialResidentialMunicipalOn-site building

D. Potential Surface Water Receptors. Estimate distances.

Creek feet Drainage ditch: feet Intermittent stream: feet

River feet50 Lake feet Wetland: feet

E. Based on the site visit, did you visually observe…

1. a release to a surface water body? Yes No Unknown2. a leachate seep? Yes No Unknown3. a release to soils? Yes No Unknown

X. Comments: Use this section to provide comments on any aspect of the site visit. Attach any information or explanations labeled with the appropriate section number to which the material applies.

See Attached Comments.


Page 6 of 6Form 4400-226 (R 05/16)

Region MapNORTHERN REGION Remediation & Redevelopment Team Supervisor Department of Natural Resources 107 Sutliff Avenue Rhinelander, WI 54501 (715) 365-8976

ORRegional Waste Program Manager Department of Natural Resources 107 Sutliff Avenue Rhinelander WI 54501 (715) 365-8946

NORTHEAST REGION Remediation & Redevelopment Team Supervisor Department of Natural Resources 2984 Shawano Avenue Green Bay, WI 54313-6727 (920) 662-5160

ORRegional Waste Program Manager Department of Natural Resources 2984 Shawano Avenue Green Bay, WI 54313-6727 (920) 662-5120

SOUTHEAST REGION Remediation & Redevelopment Team Supervisor Department of Natural Resources 2300 N. Martin Luther King Drive Milwaukee, WI 53212 (414) 263-8561 or (414) 263-8714 OR Regional Waste Program Manager Department of Natural Resources 2300 N. Martin Luther King Drive Milwaukee, WI 53212 (414) 263-8694 or (414) 263-8697

WEST CENTRAL REGION Remediation & Redevelopment Team Supervisor Department of Natural Resources 1300 West Clairemont Avenue Eau Claire, WI 54701 (715) 839-3710

ORRegional Waste Program Manager Department of Natural Resources 1300 West Clairemont Avenue Eau Claire, WI 54701 (715) 839-3708

Regional Waste Program Manager Department of Natural Resources 3911 Fish Hatchery Road Fitchburg, WI 53711 (608) 275-3466

SOUTH CENTRAL REGION Remediation & Redevelopment Team Supervisor Department of Natural Resources 3911 Fish Hatchery Road Fitchburg, WI 53711 (608) 275-3241

OR

Page 1 of 1

Section X – Comments to Application Sections

Sections I & II

American Transmission Company (ATC) and Wisconsin Public Service (WPS) are completing a joint utility upgrade project for the Ogden Street Substation located on the west side of the Waupaca Foundry Plant 4 facility (island) on property owned by Waupaca Foundry. WPS will be completing an expansion of the existing Ogden Street Substation and installing new substation equipment and associated foundations. ATC will be completing the installation of transmission line foundations for structures 145388 and 145387. Construction activities will be completed on a known historical fill site. Soil and groundwater testing were completed at proposed transmission line structure foundation locations to determine appropriate soil and groundwater management during construction starting on or about September 9, 2019. ATC and WPS are jointly applying for this exemption to build transmission line structure foundations and substation equipment foundations on an historical fill site (former City of Mariette municipal fill site).

Section IV

On July 26, 2019, ATC submitted the available soil and groundwater testing data to Waupaca Foundry (owner) for the proposed structure locations on the west side of property for the owner’s review.

Section V

The report to which this application is appended describes subsurface assessment activities including fill and groundwater analytical results to characterize materials to be removed during construction for proper management and ultimately treatment and/or disposal at off-site licensed facilities. The report also describes how the removed materials (fill, soil, and groundwater) will be managed and the foundations will be constructed to limit the potential for adverse environmental impacts. Workers would be protected through applicable OSHA requirements for crews exposed to subgrade materials for the new construction.

Section VII.

As described in the report to which this application is appended, groundwater monitoring wells (two water table observation wells and two piezometers) were installed to assess groundwater conditions at transmission structure locations prior to construction. These wells will be properly abandoned in conjunction with upcoming construction activities.

Section IX.

Potential gas migration to homes is not applicable due to the fill site being located on an island in the Menominee River.

Observations of current conditions on the historic fill site were limited to areas in and near where new construction for the electrical utility upgrade project is planned.

PHOTOGRAPHIC LOG

PHOTOGRAPH NO: 1 DATE: May 7, 2019

GEI PROJECT NO: 1902287

CLIENT: American Transmission Company

DIRECTION: N SITE LOCATION: STRUCTURE LOCATION 145387, MARINETTE, WISCONSIN

DESCRIPTION:

N-MW and N-PZ locations at structure location 145387 (staked).

PHOTOGRAPH NO: 2 DATE: May 7, 2019

GEI PROJECT NO: 1902287

CLIENT: American Transmission Company

DIRECTION: NW SITE LOCATION: STRUCTURE LOCATION 145388, MARINETTE, WISCONSIN

DESCRIPTION:

S-MW and S-PZ locations at structure location 145388 (staked).

Fill Conditions and Planned Fill/Soil Disposal & Groundwater ...

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