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++- Gordon Conferences were supported by AFOSR during i90 h
Cneecon Inorganic Chemistry was held in Wolfboro. NH July 30 to
August 3. Totalattendance was 98. 22 papers and 40) posters were
presented. The Conferenceon Glass was held in Tifton, NH, June
25-29. Total attendance was 80including 5 from Europe and Japan. 18
talks and 24 posters were presented.The Conference on Biocatalysis
was held in Plymouth, NH, June 24--29. Totalattendance was 113. 26
papers and 30 posters were presented. The Conferenceon Dielectric
Phenomena was held in Plymouth, NH, July 22-27 . Totalattendance
was 76. 20 papers and 15 posters were presented. The Conferenceon
Physical Electrochemistry was held in New London, NH, July 29 to
August 3.The Conference on Organometallic Chemistry was held in
Newport, RI. June24-29. Total attendance was 134. 26 papers and 57
posters were presented.
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-
THE GORDON CONFERENCE ON INORGANIC CHEMISTRY 1990
Final Program Report
The 1990 Gordon Conference on Inorganic Chemistry was held
atBrewster Academy, Wolfboro, New Hampshire from July 30 to August
3 1990and had as its themes: the chemistry of inorganic molecular
clusters,the chemistry of supermolecular inorganic materials,
chemistry atinorganic surfaces, and reactive intermediates in
inorganic chemistry.Twenty two papers were presented, plus an
unscheduled contribution fromthe vice-chair at the end of the final
session. Two poster sessiciis wereheld, comprising about forty
posters. Invited speakers and sessionchairs were drawn from
research groups in academia, industry and NationalLaboratories, and
the program brought together world class chemists fromthe United
States, Britain, France, West Germany, Canada and theU.S.S.R., in
keeping with the worldwide level of research activity inthese
areas. The international scope of the program was greater than
hadbeen attempted in previous years for this conference.
The Conference was attended by ninety-eight registrants, and
inaddition to the customary mix of academic and industrial
scientists, asignificant number of graduate students and
post-doctoral fellowsattended. This was undoubtedly due to a well
publicised offer offinancial support for selected students and
post-docs, awarded on thebasis of poster presentations. As a result
the poster sessions were of auniformly high quality and gave to
junior conferees a good oportunity toexpose their work in an
informal but scientifically rigorous atmosphere.
The Conference was characterized by particularly
stimulatingdiscussions between chemists in related but distinct
areas of inorganicchemistry. Both after the formal talks and in the
free discussionperiods these interactions were evident, and they
will lead to newinitiatives, particularly in the areas of inorganic
materials, clusterchemistry and catalysis. This was made clear to
the organizers in thecomments of the attendees, many of whom were
delighted to find their workso relevant to chemists in what had
previously seemed unrelated fields.
ix
91-05932
-
GORDON RESEARCH CONFERENCE
Inorganic ChemistryBrewster Academy, Wolfboro, NH
July 30 - August 3 1990
John S. Bradley, Chairman Richard D. Adams, Vice Chairman
July 30, 1990
8:45 a.m. The Chemistry of Inorganic Clusters
Duward F. Shriver, Discussion Leader
1. Larry F. Dahl Experimental - Theoretical Studies ofUniversity
of Wisconsin Small to Giant Transition Metal Clusters:Madison
Problems and Solutions
2. Boon Teo Gold Fusion: From Clusters to ClustersUniversity of
Illinois of ClustersChicago
3. D. Michael P. Mingos Synthesis, Structure and Bonding
inOxford University Metal Clusters
7:30p.m.
4. Richard Finke Polyoxoanions as New Materials forUniversity of
Oregon Atomically Dispersed Transition MetalEugene Catalysts:
Synthesis, Characterization,
Catalytic Activity and Mechanism
5. Pierre Braunstein Molecular Aspects of the Metal-MetalLouis
Pasteur University BondStrasbourg
July 31, 1990
9:00 a.m. The Chemistry of Inorganic Clusters (contd.)
Wayne Gladfelter, Discussion Leader
1. Thomas P. Fehlner Transition Metal-Main Group Clusters
andUniversity of Notre Dame Solid State Materials
2. Suzanne Harris Bonding in Heterometallic ClustersExxon
Corporate Research
-
Supermolecular Inorganic Chemistry
3. Brian F. G. Johnson Metal Clusters, Particles and
CrystallitesCambridge University
7:30p.m.
4. Michael Steigerwald Molecular Routes to Solid State
CompoundsAT&T Bell Laboratories
5. Thomas Bein Synthesis and Characterization ofUniversity of
New Mexico Clusters and Organometallics in ZeolitesAlberquerque
August 1, 1990
Supermolecular Inorganic Chemistry(contd.)
9:00 a.m. John Bradley, Discussion Leader
1. Reinhard Kremer Electronic Delocalization and SpinMax Plank
Institute Properties in Lanthanide Compounds withStuttgart Discrete
and Condensed Clusters
2. Jeremy K. Burdett Some New Theoretical Ideas
LinkingUniversity of Chicago Molecules,Surfaces and Solids
3. Ilya I. Moiseev Synthesis, Structure and CatalyticN. S.
Kurnakov Institute of Activity of Giant Palladium Cluft orfGeneral
and Inorganic ChemistryMoscow
7:30 p.m.
4. Larry Lewis Preparation and Characterization ofGeneral
Electric Corporate Platinum Group Metal Colloids:Research and
Development Crossroads Between Clusters and Surfaces
5. GUnther Schmid Large Transition Metal Clusters andInstitute
for Inorganic Colloids: Bridges between HomogeneousChemistry and
Heterogeneous CatalysisEssen
-
August 2, 1990
Inorganic Chemistry On and In Inorganic Solids
9:00 a.m. Robert J. Madix, Discussion Leader
1. Ralph Nuzzo Structure-Reactivity Correlations inAT&T Bell
Laboratories Surface Organometallic Chemistry
2. Cynthia M. Friend Mechanistic and Structural SurfaceHarvard
University Chemistry
3. Laurent Bonneviot Preparation, Structure and StabilityLaval
University of Transition Metal Ion Deposits onQuebec Amorphous
Silica
7:30p.m. RoLert J. Madix, Discussion Leader
4. Thomas E. Mallouk Light Driven Electron TransferUniversity of
Texas Reactions in Microporous SolidsAusten
5. Shirley Chiang Scanning Tunneling Microscopy ofIBM Research
Division Adsorbed Molecules on SurfacesAlmaden
August 3, 1990
Mechanistic Investigations in Inorganic Chemistry
9:00 a.m. R. D. Adams, Discussion Leader
1. Robin N. Perutz Plotting the Course of C-H
ActivationUniversity of York Reactions-Reactive Intermediates
in
Organometallic Chemistry
2. John R. Shapley Pressure Tuning Spectroscopy -University of
Illinois Applications in Metal-Metal BondedUrbana Systems
3. Wrap-up and Discussion
-
INORGANIC CHEMISTRYBrewster Academy, Wolfeboro, New
Hampshire
JULY 30-AUGUST 3, 1990
REGISTRATION LIST
Adams, Richard D. Afzal, DawoodUniv. of South Carolina Northeast
Missouri State Univ.Dept. of Chemistry Dept. of ChemistryMain &
Devine Streets Division of Science, NMSUColumbia SC 29208
Kirksville MO 63501
Anderson. Wayne P. Aufdembrink, BrentBloomsburg University Mobil
Research & DevelopmentOept. of Chemistry Billingsport
RoadBloomsburg, PA 17815 Paulsboro, NJ 08066
Babin, James E. Barron, Andrew R.Union Carbide Corporation
Harvard UniversityPO Box 8361 Dept. of ChemistryBuilding 770/450 !
2 Oxford St.South Charleston WV 25303 Cambridge MA 02138
Basolo. Fred Bein, ThomasChemistry Dept. Univ. of New
MexicoNorthwestern University Dept. of ChemistryEvanston, IL 60201
Clark Hall
Albuquerque NM 87131
Bolinger, C. Mark Bonneviot, LaurentShell Development Company
Universite LavalPO Box 1380 Dept. of ChemistryHouston, TX 77251
Cite Universitaire
Quebec Canada G IK 7P4
Bradley, John Braunstein, PierreExxon Research & Engineering
Co. ULP/CNRSRt. 226 Institut Le BelAnnandale, NJ 08801 4 Rue Blaise
Pas,,al
F-Strasbourg France F-67070
Briggs, John Burdett, Jeremy K.Union Carbide Corporation
University of ChicagoPO Box 8361 5747 S. EllisCharleston, WV 25303
Chemistry Dept.
Chicago IL 60637
Chan, Edith Chiang, ShirleyCornell University IBM Almaden
Research CenterBox 334. Baker Lab K33/801Dept. of Chemistry 650
Harry RoadIthaca NY 14853 San Jose CA 95120
-
REGISTRATION LISTINORG AN IC CHEMISTRY
Collins, Gary S. Cowley, AlanWashinqton State University Univ.
of Texas
Dept. of ChemistryAustin, TX 78712
Czech, Paul T. Dahl, Lawrence F.Univ. of Chicago Univ. of
Wisconsin-Madison5735 E. EllisChicago, IL 60637
Dahmen, K.H. Deaton, Joseph C.Laboratorium fur Anorganische
Chemie Eastman Kodak CompanyE.T.H. Zentrum Research Laboratories6
Universitatstrasse 2nd Floor B-2Zurich Switzerland CH-8092
Rochester NY 14652-3208
Diebold, Michael P. Dunham, StephenDupont De Nemours Montana
State UniversityJackson Laboratory 2101B Dept. of ChemistryChambers
Works Bozeman, MT 59717Deepwater NJ 08023
Elliott, Denton Ernst, Richard D.6312 Kirby Road Univ. of
UtahBethesda, MD 208317 Dept. of Chemistry
Salt Lake City, UT 84112
Fackler, John P. Faessler, Thomas F.Texas AX4'" Univ. Univ. of
ChicagoCollege of Science Dept. of ChemistryDean's College 5735 S.
Ellis Ave.College Station TX 77843-3257 Clicaqo IL 60637
Farr, James Fehlner, Thomas P.Clorox Technical Center Univ. of
Notre Dame
Chemistry Dept.Notre Dame, IN 46556
Finke, Richard 0. Fisher, BarbaraUniv. of Oregon Eastman Kodak
CompanyDept. of Chemistry 7181 HSD/RLEugene, OR 97403 Rochester, NY
14650-0233
Friend, Cynthia Furuya, Frederic R.Harvard University
Brookhaver. National LaboratoryDept. of Chemistry Biologj Dept.12
Oxford St. Utpon, flY 11973Cambridge t1A 02138
-
REG ISTR AT ION L ISTINORG ANI'C CHEMISTRY
Glafeltet-, Wayne L. Hagen, Karl S.Univ. of Minnesota Emory
UniversityChemistry Dept. Dept. of Chemistry207 Pleasant St. SE 5
15 Pierce Dr.Minneapolis MN 55455 Atlanta GA 30322
Han, Scott Harris, SuzanneMobil Research & Development Exxon
Research & EngineeringPaulsboro Research Lab. Route 22
EastPaulsboro, NJ 08066 Annandale, NJ 08801
-Hawk, Eric L. Hembre, Robert T.Suny at Stony Brook Univ. of
Nebraska-LincolnChemistry Dept. Dept. o; CietejltryStony Brook, NY
11794 746 Hamilton Hall
Lincoln NE 68588-0304
Horvath, Istvan T. Howe-Grant, MaryExxon Research &
Engineering John Wiley & Sons, Inc.Route 22 East 605 Third
Ave.Annandale, NJ 08901 Sci-Tech
New York NY -10158
Hubert-Pfalzgraf, Liliane Jackson, Sarah A.Laboratoire De Chimie
Moleculaire Univ. of Paris-SudURAAU CNRS Laboratoire De Chimie
TheoriqueUniv. De Nice, Parc Vairose Batiment 490Nice France 06034
Orsay Cedex France 91405
Jasinski, Jerry P. Jensen, Craig9Keene State College Univ. of
HawaiiDept. of Chemnistry Dept. of ChemistryKeene, NH 03431 2545
The Mal
Honolulu HI 96822
Johnson, Brian F. Johnson, Kimberly A.Univ. of Cambridge Univ.
of MinnesotaUniversity Chemn. Lab. Dept. of ChemistryLensfield Road
2407 Pleasant St. S.E.Cambridge UK C82 1 EW ftiaolis MN 55455
Kanis, David R. Kemp, Richard A.Northwestern University Shell
Development Co.Dept. of Chemistry PO Box 13802145 Sheridan Road
Houston, TX 77251Evanston IL 60208
Kiaaras., Kari o-LX Koteswara Rao, A.Allied Signal Pq AA Tech.
Osmania UniversityMaterials *,cience Dept.50 East Algonquin RoadDes
Plaines IL 60017-5016
-
REGISTR AT ION L ISTINORGANIC CHEMISTRY
Kremer, Reinhard Lattman, MichaelMax Planck Inst. fur
Festkorperforschung Southern Methodist UniversixyHeisenbergstr. 1
Chemistry Dept.7000 Stuttgart 80, West Germany Dallas, TX 75275
Lauher, Joseph W. Lewis, LarryState Univ. of New York GE
Corporation Res. & Dev.Chemistry Dept. K1 5AI5 1 River
RoadStony Brook, NY 11794 Schenectady, NY 12301
Li, Yong-Xi Lissy, Daria N.Kansas State Univ. Mobil R&D
Corp.Dept. of Chemistry Billingsport RoadWillard Hall Pauls'boro,
NJ 08066Manhattan KS 6650A
Lookenmeyer. John Lyon, David K.Shell Development Co. Univ. of
OregonWesthollow Research Center Dept. of Chemistry3333 Highway 6
S. '.ugene, OR 97403Houston TX 77082
Madan, Stanley K. Madix, Robert J.State Univ. of New York,
Binghamton Stanford UniversityDept. of rhamidr Dept. of Chemilal
EngineeringVestal Parkway East Stanford, CA 94305Binghamton NY
13901
Mallouck. Torn Marcus, M.Univ. of Texas at Austin AT&T Bell
LabsDept. of Chemistry Room 1E-62Austin, TX 78712 600 Mountain
Ave.
Murray Hill NJ 07974
Martin, Andrea E. Matuszko, Anthony J.Hercules Incorporated 4210
Elizabeth LaneResearch Center Annandale, VA 220038136/359Wilmington
DE 19894
Mazany, Anthony M. Millar, John M.BF Goodrich R&D Center
Exxon Research & Engineering9921 Brecksville Road Route 22 East
Clinton TWPBrecksville, OH 44141 Annandale, NJ 08801
Mingos, D.iP. loiseev, llya I.Oxford Ur'versit. N.S. Kurnakov
Inst. of r3enera, andInorganic Chemistry Inorganic Chem., Academy
of SciencesSouth P.arks Road USSR, Leninsky Prospect, 31O-Aford UK
OXI 30R Moscow USSR 117907
-
REGISTRATION LISTINORGANIC CHEMISTRY
Nuzzo, Ralph 0. Parry, RobertAT&T Bell Laboratories Univ. of
Utah600 Mountain Ave. Dept. of Chemistry1 D-258 Salt Lake City, UT
84112Murray Hill NJ 07974
Perutz, Robin N. Pignolet, Louis H.Univ. of New York Univ. of
MinnesotaDept. of Chemistry Chemsitry Dept.York, UK YOI 5DD 207
Pleasant St.
Minneapolis MN 55455
Poli, Rinaldo Porterfield, William W.Univ. of Maryland College
Park Hampden-Sydney CollegeDept. of Chemistry & Biochemistry
Dept. of ChemistryCollege Park, MD 20742 Harnpden-Sydney, VA
29343
Proserpio, David M. Ramprasad, DoraiCornell University Air
Products and ChemicalsBaker Lab Box 538Dept. of Chemistry 7201
Hamilton BoulevardIthaca NY 14853-1301 Allentown PA 18195-1501
Reid, Austin H. Richard, Michael A.Du Pont Catalytica, Inc.Du
Pont Co. Chemicals & Pigments Dept. 430 Ferguson
DriveJohnsonville R&D I Du Pont Rd. Mountain View, CA 94043New
Iohnsonville TN 37134
Samkoff, Deborah E. Schauer, Cynthia K.Univ. of Minnesota-
Duluth Univ. of North CarolinaDept. of Chemistrj CB *3290 Venable
& Kenan Labs.10 University Drive 'epi. of ChemistrVDuluth MN
55812 Chapel Hill NC 27599-3290
Schmid, Gunter Shapley, John R.Univ. of Essen Univ. of
IllinoisUniversitatsstrasse 5-7 Dept. of ChemistryInstitut fur
Anorgan. Chemie 505 S. MathewsD-4300 Essen 1 West Germany Urbana IL
61801
Shore, Sheldon G. Shriver, D.F.Ohio State University
Northwestern UniversityDept. of Chemistry Chemistry Dept.120 Id
18th Ave. 2145 Sheridan RoadColumbus OH 43210 Evanston IL
,0208-3113
Steggerda, Jan J. Steigerwald, MichaelUniv. of Nijmegen AT&T
Bell LaboratoriesDept. of Chemistry 600 Mountain Ave.Toerrooiveld
Room I D 345Nijmegen The Netherlands 6525 ED Murray Hill NJ
07974
-
REGISTRA I iJN LISTINORGANIC CHEMISTRYStrauss, Steven H. Tanke,
R' bi S.Colorado State University Yale UniversitDept. of Chemistry
Dept. of ChemistryFt. Collins, CO 80523 flew Haven, CT 06551
Teo, Boon K. hor-steinson, ErlUniv. of Illinois at Chicago Union
Carbide CorporationDept. of Chemistry', t/C IIIBox 4348Chicago IL
60680
Tindall, James Wagner, Klaus P.Exxon Research & Engineering
nobil Chemical Co.Route 22 East LA 329 Edison Research
LaboratoryAnnanda ,jw'-mn Route 27 and Viney ard Road
V I= Gt-l: Cif NEdison NJ 08818Wigeand,Benjamin C. '0ong,
attirHarvard University Cornell UniversityDept. of Chemistry Baker
Laboratory12 Oxford St. Box 353 Dept. of Chemistry;,mvbridqe MA
02138 Ithaca NY 14853
Zhang, HongChemistry Dept.Univ. of Illinois at ChicagoChicago,
IL 60680
-
Adams, Richard D. House 2 6 Lattman, Michael Vaughn 6Afzal,
Dawood Lamb 4 Lauhor, Joseph V. Vaughn 4Anderson, Wayne P. Sargent
201 Lewis, Larnj off siteAufdembrink, Brent off site Li, Yong-Xi
Lamb 3Babin, James E. off site Lissy, Dar" N. House 3 6Barron,
Andrew R. Sargent 304 Lockenmeyer, John Sargent 302Basolo, Fred
House 1 6 Lyon, David K. Sargent 310Bein, Thomas Brown 7 Madan,
Stanley K. Sargent 203Bolinger, C. Mark Sargent 301 Madix, Robert
J. Lamb 5Bonneviot, Laurent Brown 4 Maliouck, Tom Brown 5Bradley,
John Kupper 1 Marcus, M. Sargent 202Braunstein, Pierre House 1 3
Martin, Andrea E. House 3 7Briggs, John off site Matuszko, Anthony
J. House 2 5Burdett, Jeren K. Kupper 2 Mazanj, Anthony M. Sargent
204Chan, Edith House 3 1 Millar, John M. Sargent 205Chiang, Shirley
off site Mingos, D.MP. Brown 10Collins, Gary S. Sargent 107
Moisety, Ilya I. Vaughn ICowley, AlWn House 1 7 Nuzzo, Ralph G.
Brown 3Czech, Paul T. Vaughn 3 Parry, Robert Kupper 5Dahl, Lawrence
F. Brown 9 Perutz, Robin N. Estabrook 4Dahmen, K H. House 2 4
Pignolet, Louis H. Lamb 6Deaton, Joseph C. Harris 2 Poli, Rinaldo
House 2 2Diebold, Michael P. off site Porterfield, 'ffltam V Lamb
2Dunham, Stephen Sargent 305 Proserpio, David M. Vaughn 5Elliott,
Denton House 1 5 Rampresa, Dorai Lamb 7Ernst, Richard D. Harris I
Reid, Austin H. Sargent 311Fackler, John P. Kupper 4 Richard,
Michael A. Sargent 206Faessler, Thomas F. Vaughn 3 Samkoff, Deborah
E. House 3 1Farr, James Sargent 107 Schauer, Cynthia K. House 3
2Fehbner, Thomas P. Estabrook 6 Schmid, Gunter House I IFinke,
Richard G. House 1 4 Shapley, John R. Harris 3Fisher, Barbara
Estabrook 2 Shore, Sheldon 0. Sargent 303Friend, Cynthia Lamb 5
Shriver, D.F. Lamb IFuruya, Frederic R. Sargent 306 Steggerda, Jan
J. Sargent 207Gladfelter, Wayne L. Vaughn 2 Steigerwald, Michael
Estabrook 5Hagen, Karl S. Sargent 307 Strauss, Steven H. Harris
2Han, Scott Sargent 308 Tanke, Robin S. House 3 2Harris, Suzanne
Estabrook 1 Teo, Boon K. off siteHawk, Eric L. Vaughn 4
Thorsteinson, Erl Sargent 108Hembre, Robert T. Harris 1 Tindall,
James Sargent 108Horvath, Istvan T. House 2 I Wagner, Klaus P.
Sargent 208Howe-Grant, Marj Estabrook 3 Vieland, Benjamin C.
Sargent 209Hubert-Pfalzgraf, Liliane House 3 4 Wong, Yatting House
2 2Jackson, Sarah A. House 3 3 Zhmng, Hong off siteJasinski, Jerry
P. House 2 7Jensen, Craig Sargent 309Johnson, Brian F. Brown
6Johnson, Kimberly A. House 3 5Kanis, David R. House 2 3Kemp,
Richard A. Vaughn 6Kharas, Karl C.C. House 2 3Koteswara Rao, A.
Sargent 109
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190_GORDON CONFERENCE ON GLASSTILTON, NEW HAMPSHIRE
JUNE 25-29. 1990
FINAL REPORTRobert J. Eagan, Chair
The 1990 Gordon Conference on Glass, entitled "Defects in Glass"
successfully integratedscientific studies performed by scientists
in the "classical" glass community, thesemiconductor community, and
several involved in peripheral work, e.g., the surface
forceinteractions of water with inorganic materials. Several
previously unreported orunrecognized observations were reported.
Three examples are:
1) The possible relationship of E' (optical defect) centers to
fracture propagationemerged for the first time and will lead to
further collaborative studies.
2) New nucleation and crystallization data for zinc fluoride
glasses, obtained with a novelheating stage and optical microscope,
were presented.
3) Surface force interaction measurements may lead to
understanding electronic defectsin silica films-a surprise to the
presenter! New collaborations will undoubtedlydevelop.
The attendees and presenters represented industry, academia
(students and faculty),national laboratories, and several
scientists from Europe and Japan. Eighteen speakerswere joined by
twenty-four participants in two poster sessions. The nine
discussion leadersdid a good job leading frequently spirited
discussions. Total attendance was eighty,including five from Europe
and Japan.
Enclosure:Program
-
WK=Vest Knowles
EK=East Knowles
M=Moore Hall
P=Pheiffer
GORDON RESEARCH CONFERENCES
Glass
Tilton School, Tilton, New Hampshire 03276
June 17 - 22, 1990
Xllan, Douglas off campus Cerqua, Kathleeu 115M
,orning, Inc. NYS College of Ceramics
SP PR 02 2 Alfred University
,orning NY 14831 Binns-Merrill Hall
Alfred NY 14802
krai, Kazuo 217EK
Electrotechnical Laboratory Chaiyasena, Izra 18P
qaterials Science Division Engineering Science & Mech.
Dept.
L-1-4 LME IONO 227 Hammone Bldg.
rsukuba-Shi KBARAKI 305 Penn State University
Japan University Park
State College PA 16802
kraujo, Roger 248WK
Corning Inc. Chen, Din-Guo 247WK
SP FR 3-1 University of Florida
Corning NY 14831 Materials Science & Engineering
Room 166, Rhines Hall
Batey, John 203EK Gainesville FL 32611
IMB Corp., T.J. Watson Research Center
P.O. 3ox 704 Cheng, J. Joseph
forktown Heights NY 10598 L 0 F
Brinker, Jeff 205EK
Sandia National Labs
)iv 1846, P.O. Box 5800 Chiu-Sarourin, Martina 216M
klbuquerque NM 87185 AT&T Bell Labs
600 Mountain Ave.
Brow, Richard 206EK RM 60305
Sandia National Labs Murray Hill NJ 07974
Div. 1845
klbuquerque NM 87185 Cooper, A. 214EK
CWRU
Bruce, Allan 218EK White 500
kT&T Bell Labs Cleveland OH 44106
500 Mountain Avenue
4urray Hill NJ 07976 Cooper, Reid 102EK
University of Wisconsin
:apozzi, Carol -ff campus Dept. Material Science &
Engineering
Institute of Glass Science & Engineering 1509 University
Avenue
klfred University Madison WI 53706
klfred NY 14802
-
-3-
Knight, Diane 1IIM Lou, Victor I19EK
Penn State University GE Corporate Research &
Development
209 Materials Research Lab. River Road
University Park PA 16802 Bldg. Ki, MB-177Schenectady NY
12309
Kohli, Jeffrey 107EK
NYS College of Ceramics McKinnis, Charles I5EK
Binn-Merrill Hall Owens Corning Fiberglass
Alfred NY 14802 109 Mt. Parnassus, Box 46Granville OH 43023
Kozlowski, Maureen 112M
Rensselaer Polytechnic Institute Michalske, Terry 233WK
Materials Research Center Sandia National Lab
Troy, NY 12180 Division 1114Box 5800
Kreidl, Norbert 109EK Albuquerque NM 87008
MTA and University of Arizona1433 Can-on Road Moddeman, William
221EK
Santa Fe, NM 87501 Mound LaboratoriesMound Road
Kruger, Albert 242WK Miamisburg OH 45443
Battelle-PNLMS P8-37 Nagasawa, Kaya 230WK
Materials & Chemical Sciences Shonan Institute of
Technology
Richland WA 99352 1-1-25, Tiuido-Nishi-KaiganFujisawa Kanagawa
251, Japan
Kurkjian, C.R. 11OEKATfT Bell Lab. Nattermann, K. 229WK
600 Mountain Avenue Schott GlaswerkeRoom 2C261 Hattenbergstr
10Murray Hill NJ 07974 Mainz, FRG 6500
Lehman, Richard 232WK Perea, WillorageRutgers University
RPICeramic EngineeringP.O. Box 909/Brett & Browser
RoadsPiscataway NJ 08855-0909
Phifer, Carol 212Moore
Lenahan, Patrick 19P Sandia National Laboratories
Dept. Engineering Science division 1845Hammond Bldg. Albuquerque
NM 87185Pennsylvania State UniversityUniversity Park PA 16827 Pye,
L. David off campus
Institute of Glass Science & EngineeringLevin, Victor 244WK
Alfred UniversityCase Western Reserve University Alfred NY
1480210900 Euclid AvenueMatl. Science & Engineering Dept.
Rabinovich, Eliezer 9PWhite Bldg #502 AT& T Bell Labs
Cleveland OH 44106 600 Mountain Avenue, Room 7A-313Murray Hill
NJ 07974
Li, Jie 245WKRutgers UniversityDept. of CeramicsPiscataway NJ
08855-0909
-
- 5-
t, Jon 231WKversity of Florida
-C #14Progress Blvd.
chua FL 32615
, ManT Bell Laboratories
nt, James 18Pt. Engr. Science & MechanicsHammond Bldg.
n State University
versity Park PA 16802
1, David 126WKgers University. Box 909cataway, NJ 08855-0909
Irone, R. K. lOP
..SNY 12180
-
GORDON CONFERENCE ON GLASS
Senior Poster Session - Tuesday Evening
Author/Institution Poster Title
R. J. Araujo Statistical MechanicalCorning, Inc. Calculation of
Peroxyl
in Silica
R. Cooper Chemical Diffusion andUniversity of Wisconsin
Crystalline Nucleation in
Transition-Metal-DopedAluminosilicates
J. T. Dickinson, S. C. Langford, Consequences ofand L. C. Jensen
Simultaneous BombardmentWashington State University of Sodium
Trisilicate Glass
With UV Excimer Irradiationand keV Electrons
D. Inniss, D. Brownlow, C. Kurkjian The Strength and Fatigue
ofAT&T Bell Laboratories Silica Fibers in Sodium
Chloride Solutions
A. A. Kruger The Effect of SurfaceBattelle Pacific Northwest
Lab. Treatments of Silica and
Silicate Glass Fibers onTheir Mechanical Properties
C. Kurkjian, R Farrow, D. Inniss High Resolution
ScanningAT&T Bell Laboratories Microscopy of Glass Fiber
Surfaces
W. Moddeman Zero Valent NickelEG&G Mound Applied
Technologies in Glass
K. Nagasawa The Cause of the IntrinsicSagami Institute of
Technology Luminescence at 2.7 eV in
Pure Silica Glass
S. V. Raman and K. Matsuishi Glass-like Structural
RelaxationTexas Center for Superconductivity in Crystalline
YBa2Cu307-v
Perovskite Structure
J. Simmons XPS Studies of FluorideUniversity of Florida Glass
Films
P. A. Tick, T. Kanamori Hot Stage Optical MicroscopyS. Mitachi,
S. Takahashi, (includes video presentation)R. Maschmeyer, K.
LuCorning, Inc.
-
1990 Gordon Conference on GlassJune 24-29, 1990The Tilton
School
Tilton, New Hampshire
PROGRAM
Chair: Robert J. Eagan Vice-Chair- Marv~n J, Weber
Monday, June 25, 1990
Discussion Leder Robert J. Eagan
Spoaxer C. Jeffrey Brinker Stru.eturt of Sol Gal Silicate
ClassesSpeaaker John Batty Structursl Plopertied of Thin Film,
PZCV0 Si0 2
Discussion Leader Richard K. Brow
sr@OI1iF 4'a~ti . Kiiftl 2lefiiS' & PUh"& SaUE2 r.. a
IuJhdn G Sflii6Speaker Minoru 1ioinoi&*i Water &S IJCecc
its -jusi;
Tuesday, June 26, 1990
Discustion Leader Suresh Oulati
Speaker Terry A. M4KhiaiI.e The Role ei S3tvain Induced Det'ects
in the Fraciure of Silica Gias3pat . Thornaa Dickinson
Fracto-emnisaion irorn Glans Surisces ik lntrfa.as -
Speaker Charles R. Kurkj~an Strength Dcgrdationi n Hish
Strengti. Fzbcre
Diacusio;n Leader Ma.-Yin 3. Weber
Poster Seaib, sirnlor SeientitjI' aduity rosters shno
isiuior.
Wednesday, June 27, 1990
Discussion Leader Raoert J. Eagan
SptAker Douglas T. Sinith Surface F'orcms Int SiG2 -Water
ints,'ctor.4Speaker Jon K. West Silica Cluster Models
Di~~inLea-dcr jares E. ghc!by. jr.
PO~ter Sessici '.2:Aiern postezs a.-d simio
Thursday, June 28, 1990Discussion Leader J~th$inn
Spea.ker DOUglas1 Allan Siruciurs it aDei'ecis i ZO xides 67
Fiazironi. Siructurei~otsi Zn~rgy WecnodisSpeaker lrazik L.
Galeener X-ray Induction~ oi 3pin Active Deftctz in Vitreouii
SilicaSpeaker K~auo Arai Nature of Defects of Doping in Silica
Glaoses
Dilscua3ion~ Leadar Norbert J. Krcldl
S3pc.kte Delbert E. Day Tarceted Radiation Trierapy in Hurnuns
Uairg G.,isis Mixcrosphercs
Friday, June 29, 1990
Diieussion Ltader Tetsuro hsumitani
speaker DJavid L. C..scom rnysIia ' ';.ffu'fitry 01 -Usactf in
Silica Gtimi &1 At dfs i,311 . 2 'alareSpeaker Patrick Lenahan
Detection of Defects in Clan.: Electron~ic NfeauremontsSpeaker
Andrej. R. Sili Point Defects: Resdiation Inducei D.iec.ta in
S0O2
-
Senior Poster Particii~ants:
Fibers on Their NMechanicaI Properrics
K Nagasawa T1he Cause of ihe I nti-ic Ly-u m'.seic aa 2. V 0 re
3.cGlass
S.v.im.nan ~ jasslK e 'ruut W IN UsLM1d.Xdii iFs k-1 1).1k11. I
O.,.L~J-Perovskite Structure
P. A. Tick Hot Stage Optical MNIUC73copy
D. Inniss title unavailable
R. J. Araujo Statisuical Mechanical Calculatiion of Peroxyl in
Silica
Reid Cooper Chemical Diffusion and CrysialIline 'INucleafion in
'I ransion -Metal-Doped Alurninosilicates
VV. IVILJ(U~kdler ZLcI V aICIIL 141xrIIKI 1 d1 b
J. Sim-mons title unavailable
-
StudepI Postgr P~axtciggtits:
C. A- Capozzi title unavailable
Kathleen Cerqua The Role of Defect Processes in IA'w-T,
Chaicugenide GlaSses
I. 1-uang Str-ucturatl Relaxation in 'ifi Glas Fibers
Mark lupina A Nz~Si Hyperfine Srudy of' the rb Center and
E'Center iri Metal-Oxide-Semiconductor Devices
Sriraman Karinan Excimer Laser Damoage Studies or 'Synithetic
Silica Glasses andFibers
Jeffrey Kohli, fitle uinavailable
Vicor Levn title unavailable
i~ iDraw induced iect/ui tr avioiet X.ad a ion
ResponseMechanisms in Synthetic Silica Optical 'Fibers
,Vviuorage rerera i t: aurlacc %oirrubMui UL IJI~b~
H-ema Slenapati Effects of Anion 'Mi~ng on Siru ciural
"Mehaxauion andU V; 0S-11yDecoupling in Agl-Ag 2SO4-Ag2\V0 4
Glasses
Cathy Shaw Oxygen Related Defects in 113ariurn Galiosilicate
GlassesI n .. . I,- I T.I om. Swier Molecular Llynamlucs rkracture
or C..rysta1ine and vitreous S., hcon
Dioide
'Willia m, WYa r re n F-11ect ron 14uicl e ar Dli uble "Aesor.
ance dd Ei 'ct ron Param agne ticResonance Study of Silicon
Dan~ling-Bond Centers in SiliconNitride
David Zirl Simulations of 'be Structure and Properties of
Sodiumr-Aluminosilicate Glasses
-
GORDON RESEARCH CONFERENCE
BIOCATALYSIS
PLYMOUTH STATE COLLEGE - NORTH
JUNE 24-29, 1990
Anton, David 201/203 Caruso, Andrew 223
El Dupont De Nemours General Electric Corp.
Experimental Station Pn Rox 8
PO Box 80328 KI 5B15
Wilmington, DE 19850-0328 Schenectady, NY 12301
Arnold, Frances 526 Chang, Ho Nam 703
Caltech Kaist/ Dept. of Chem. Engineering
Chem. & Engineering PO Box 150
210-41 Seoul, Kzrea 130-650
Pasadena, CA 91125Cheung, Alex 210
Baresi, Larry 622 Coors Biotech
4800 Oak Grove Dr. 6204 South College Ave
MS 125-112 Fort Collins, CO 80525
Pasadena, CA 91109
Chmurny, A.B. 217
Bhupathy, M. 317 WR Grace & Co./ Research Div.
Merck & Co. 7379 Route 32
Rahway, NJ 08820 Columbia, MD 21044
Bjorklong, Frederick 205 Crans, Debbie 502
Novonordisk A/S Colorado State U.
Dept. of Natural Products Dept. of Chemistry
Novoave Ft. Collins, CO 80523
Bagovaero, Denmark 2880
Dalton, H. 717
Boaz, Neil 206 University of Warwick
Eastman Kodak Lab/Corp. Research Lab Coventry, England
CV311TA
Bldg. 82, 5th Floor
Rochester, NY 14650-2110 Dicosimo, Robert 218
E1 Dupont De Nemours
Bommarius, Andy 302 Central R & D Dept.
Degussa AG Sect. FCO PO Box 80328
PO Box 1345 Wilmington, DE 19880-0328
6450 Hanau
West Germany Dodds, David 219
Sepracor Inc.
Bratzler, Robert OC 33 Locke Dr.
Sepracor Inc. Marborough, MA 01752
33 Locke Dr.
Marlborough, MA 01752 Dordick, Jonathan 303
University of Iowa
Bray, Brian 208 Dept of Chemical & Biochem. Eng.
Glaxo Inc. 125 B Chemistry Bldg.
5 Moore Dr. Iowa City, IOWA 52242
Synthetic Organic Chem.
RTP, NC 27709 Elferink, V H M 220
Burgess, Kevin 209 Andeno B.V.
Rice University Grubbenvorsterweg 8
Chem. Box 1892 5928 NX Venlo, The Netherlands
Houston, TX 77251
-
BIOCATALYSISGORDON RESEARCH CONFERENCE
Plymouth State CollegeJune 25-29, 1990
Co-Chairmen: Co-Vice Chairmen:J.B. Jones & D.L. Anton J.
Frost, J.D. Rozzell
Sunday, June 24 4:00-6:00 p.m.Chairmen's Reception
Monday, June 25 9:00 a.m. Chiral Synthesis
Discussion Leader: Larry Baresi
Charles Sih Chemo-enzvnmatic Synthesis of Natural Products
Keith Kyler Chemoenzymatic Synthesis
Manfred Schneider Enzymic Preparation of Enantiomerically
PureCompounds
Monday, 4:00 - 6:00 p.m. Poster Session I.
Monday, 7:30 p.m. Synthesis of Commercially Important
Compounds
Discussion Leader: John Frost
Hideaki Yamada Enzymatic Conversion of Nitriles into Useful
Amidesand Acids
Hans Schoemaker Chemo-enzymatic synthesis of enantiomerically
pureamino acids and related compounds
Tuesday, 9:00 a.m. Synthesis of Useful Compounds
Discussion Leader: Terry Lieb
Cary Morrow Enzymatic polymerizations
David Rozzell Cis-muconic Acid biosynthesis
George Whitesides Carbohydrate Synthesis
Tuesday 4:00 - 6:00 p.m, Poster Session I.
Tuecdrv 7:30 p.m. Mutagenesis
Discussion Leader: Byron Rubin
Frances Arnold Enzyme Engineering for non Aqueous solvents
Jeremy Knowles Manipulative Mutagenesis
-
Wednesday 9:00 a.m. Enzyme Models
Discussion Leader: Carl Johnson
T. Ross Kelly Bisubstrate Reaction Templates
Fraser Stoddart Enzyme Mimics to Molecular Self Assembly
Al Tramontano Catalytic Antibodies
Wednesday 4:00 - 6:00 p.m. Poster Session II.
Wednesday 7:30 p.m. Enzyme Structural Aspects
Discussion Leader: David Anton
Arieh Warshel Mutagenesis Calculations
Alexander Klibanov Irreversible Enzyme Inactivation
Thursday 9:00 a.m. Synthesis with Pathways
Discussion Leader: Bryan Jones
Greg Petsko Mandelate Racemase, Evolution of Metabolic
Pathways
Charles Goodhue Pentaerythritol Pathway
Juan Ramos Metabolic Pathway Engineering
Thursday 4:00 - 6:00 p.m. Poster Session II.
Thursday 7:30 p.m. Alkane Activation
Discussion Leader: Jonathan Dordick
Howard Dalton Methane mono-oxygenase
John Lipscomb Methane mono-oxygenase
Friday 9:00 a.m. Engineering Aspects
Paul van Eikeren Membrane-Assisted Regeneration of NAD
Cofactors
Jonathan Dordick Kinetics and Thermodynamics of Non-aqueous
Enzvolog;-
Christian Wandrey Enzyme Reaction Engineering
-
Biocatalysis Gordon ConferencePoster Session Participants
Name Title Affiliation
Monday-Tuesday
Fredrik Bjorkling "Indirect Lipase Catalyzed Novo Nordisk
A/SEpoxidation" Denmark
Debbie C. Crans "Spontaneously Formed Organic Colorado State
Univ.Vandates Bind Better than Organic
Phosphates to Selective Enzymes:
Clucose-6-Phosphate Dehydro-
genase"
V. H. M. Elferink "Biotechnological Production of Andeno B.
V.
S-2,2-dimethyl-l,3-dioxolane-4- The Netherlandsmethanol
(S-DDM)"
Mark W. Empie "Biotechnological Resolution of International
Bio-Racemic Isopropylidene Clycerol" Synthetics, Inc.
Kurt Faber "On the Catalytic Activity of Craz Univ. of
Tech.Solid Enzymes in Organic Austria
Solvents"
Thomas Graycar "The Functional Consequences of Genencor,
Int.
Introducing a Positive Chargein Close Proximity to theCatalytic
Serine of Subtilisin"
A. B. Hanley I) "The Enzymic Production of AFRC Institute
ofl-methoxyindolyl-3-methyl Food Research
isothiocyanate - An Unstable
Intermediate in Indole
Glucosinolate Breakdown"
2) "The Intrinsic ProteolyticActivity of Ubiquitin"
Ronald L. Hanson "Synthesis of L-P-Hydroxyvaline Bristol-Myers
Squibb
by Leucine Dehydrogenase from
Bacillus Species"
David L. Hughes "Lipasc-Catalyzed Asymmetric Merck, Sharp &
Dohme
Hydrolysis of Esters Having Research Laboratories
Remote Chiral/Prochiral Centers"
Ronald J. Huss "Biological Production of Bio-Technical
Phenylacetylene Cis-Dihydrodiol" Resources
-
Carl R. Johnson "Immobilization of Enzymes Wayne State Univ.
on Azlactone Beads"
Jerald K. Rasmussen "Azlactone-Functional ?olymer 3-M Heal-.i
are
(to be adjacent Beads - A New Reactive Supportto Carl R.
Johnson) for Proteins and Enzymes"
Romas J. Kazlauskas "A Rule to Predict Which McGill
UniversitySecondary Alcohols areEfficiently Resolved byCholesterol
Esterase, Lipase
from Pseudomonas cepacia, andLipase from Candida
cylindracea"
Yu-Yen Iinko "Ester Synthesis by Various Helsinki UniversityH.
-C. Yu Lipases" of Technology
FinlandWednesday-Thursday
Kevin Burgess "Biocatalytic Resolutions of Rice
UniversitySulfoxide Esters"
Koji Kubota "Enzymatic Synthesis of Nucleo- Ajinomoto Co.,
Inc.side Analogs having Antiviral JapanActivity"
Terry K. Leib I) "Tyrosinase-catalyzed General Electric
Co.Hydroxylations of AminoaromaticCompounds"
2) "Biological Reduction ofNitroaromatic Compounds"
David Mobley "Aspergillus-Catalyzed General Electric
Co.Hydroxillations ofRiphenyls and Terphenyls"
Monica Palcic "Use of Glycosyltransferases Univ. of Albertafor
the Synthesis of Oligo-saccharide Analogs"
Manfred Philipp "The Catalytic Hydrolysis CUNYof
Mandelonitrile"
Sergio Riva "Regioselective Chemo- Instituto di Chimicaenzymatic
Acylation of Degli OrmoniFlavonoid Glycosides" Italy
Enzo Santaniello "Enzymes in Organic Solvents: Univ. of
MilanoEnantioselective Transesterifi- Italycation of A-Methyl
SubstitutedPrimary Alcohols Catalyzed bya Lipase"
-
Peter Seifer-Wasserthal "Facile Preparation of Both Graz Univ.
of Tech.Enantiomers of the UsefulIntermediate Dimethyl Maleic
Acid"
D. Stevenson "Enzymic Catalysis in Nitrile National
ResearchChemistry" Council, Canada
Takayuki Uwajima "Chemo-Enzymatic Synthesis of Kyowa Hakko Kogyo
Co.2-Leucovorin, an Augmentor of Tokyo, Japan5-Fluorouacil
CytotoxicityAgainst Cancer"
Gregg Whited "Acyltransferase: A New Eastman KodakEnzyme for
Chiral Synthesis" Research Laboratories
Edmund Ziomek "Aminoadipoyl Amidohydrolases: National ResearchA
Use of Chromogenic Cephalo- Council, Canadasporin C Analogues"
Milton J. Zmijewski, Jr. "Enantioselective Acylation of Eli
Lilly and Co.a Key Chemical Intermedi;.ce inthe Synthesis of
Loracarbef, aNew Beta-lactam Antibiotic,Using Penicillin G
Amidase"
-
Biocatalysis Sordon Conference
Poster Session Participants
Late Additions
Name r2itle Affiliation
Monday - Tuesday
M. Catriona Tedford "Novel Protein-Based Catalysts" Univ.
ofStrathcyde
Thomas Roetig "Synth3sis of Hydrophobic FraunkhofesSubstances in
Enzyme Membrane InstituteReactors"
Wednesday - Thursday
Ho Nam Chang "Continuous Production of Kaist,Penicillin Acylase
from High South KoreaDensity Cell (ulture"
-
GORDON RESEARCH CONFERENC
BIOCATALYSIS
PLYMOUTH STATE COLLEGE - NORTH
JUNE 24-29, 1990
Anton, David 201/203 Caruso, Andrew 223
El Dupont De Nemours General Electric Corp.
Experimental Station PO Box 8
PO Box 80328 KI 5B15
Wilmington, DE 19850-0328 Schenectady, NY 12301
Arnold, Frances 526 Chang, Ho Nam 703
Caltech Kaist/ Dept. of Chem. Engineering
Chem. & Engineering PO Box 150
210-41 Seoul, Korea 130-650
Pasadena, CA 91125Cheung, Alex 210
Baresi, Larry 622 Coors Biotech
4800 Oak Grove Dr. 6204 South College Ave
MS 125-112 Fort Collins, CO 80525
Pasadena, CA 91109
Chmurny, A.B. 217
Bhupathy, M. 317 WR Grace & Co./ Research Div.
Merck & Co. 7379 Route 32
Rahway, NJ 08820 Columbia, MD 21044
Bjorklong, Frederick 205 Crans, Debbie 502
Novonordisk A/S Colorado State U.
Dept. of Natural Products Dept. of Chemistry
Novoave Ft. Collins, CO 80523
Bagovaero, Denmar 2880Dalton, H. 717
Boaz, Neil 206 University of Warwick
Eastman Kodak Lab/Corp. Research lab Coventry, England
CV311TA
Bldg. 82, 5th Floor
Rochester, NY 14650-2110 Dicosimo, Robert 218
E1 Dupont De Nemours
Bommarius, Andy 302 Central R & D Dept.
Degussa AG Sect. FCO PO Box 80328
PO Box 1345 Wilmington, DE 19880-0328
6450 Hanau
West Germany Dodds, David 219
Sepracor Inc.
Bratzler, Robert OC 33 Locke Dr.
Sepracor Inc. Marborough, MA 01752
33 Locke Dr.
Marlborough, MA 01752 Dordick, Jonathan 303
University of Iowa
Bray, Brian 208 Dept of Chemical & Biochem. Eng.
Glaxo Inc. 125 B Chemistry Bldg.
5 Moore Dr. Iowa City, IOWA 52242
Synthetic Organic Chem.
RTP, NC 27709 Elferink, V H M 220
Burgess, Kevin 209 Andeno B.V.
Rice University Grubbenvorsterweg 8
Chem. Box 1892 5923 NX Venlo, The Netherlands
Houston, TX 77251
-
Knowles, Jeremy olL Linko, Yu-Yen o7
Harvard University/Dept of Chemistry Helsinki University of
Tech.
12 Oxford St. Dept of Chem. Eng./Lab of Biotech & Food
Eng.
Cambridge, MA 02138 Espoo, Finland SF-02150
Koritalla, S. 618 Lipscomb, John 305
Northern Reg. Research Ctr. University of Minnesota, Dept of
Biochem.
1815 N. University 4-225 Millard Hall
Peoria, IL 61604 435 Delaware St., SEMinneapolis, IMN
55455-0326
Kurt, Faber 702
Graz University of Technology Margolin, Alexey 624
Stremaygasse 16/ Inst. of Org. Chem. Merrel Dow Research
Institute
Graz, Austria 9550 N. Zionville Rd.
Indianapolis, IN 46268
Kubota, Koji OC
Ajinomoto Co. Masilamani, Divakar 625
Central Research Allieg-Signal, Inc./Biotech Dept.
1-1, Suzukicho, Kawasaki PO Box 1021R
Kawasaki, Japan 210 Morristown, NJ 07962
Kyler, Keith 306 Matuszko, Anthony 626
University of Miami/Dept of Chem. 4210 Elizabeth Lane
PO Box 249118 Annandale, VA 22003
Coral Gables, FL 33124McGarrity, John 402
Ladner, Wolfgang 711 Lonza AG
BASF AG COFO-3
Ludwigshafen, West Germany 6700 CH-3930 VISP Switzerland
Landis, Bryan 619 Mobley, David 403
Monsanto GE Corporate R & D700 Chesterfield Village Pkwy PO
Box 8, KI/CEB-455
BPX, GG3N Schenectady, 14Y 12301
St. Louis, MO 63198
Morrow, Cary 404
Langrand, George 620 University of Mexico/Dept. of Chem.
State University of Utrecht Albuquerque, NM 87131
CBLE N 607
Padualaan 8, PO Box 80054 Nakamura, Charles 405
Utrecht 3508 TB The Netherlands Dupont CR & DPO Box
80328
Lanser, Alan 621 Wilmington, DE 19880-0328
USDA, NRRC
1815 N. University Navia, Manuel 706
Peoria, IL 61604 Vertex Pharmaceuticals Inc.40 Allison St.
Leib, Terry 622 Cambridge, MA 02139-4211
GE-CRD, Bio. Sciences Lab
PO Box 8 K-I 3B42 Nicholds, MJ 704
Schenetady, NY 12301 ICI Biological Products
PO Box 1
Lilly, Malcolm 517 Billingham, Cleveland UK
University College LondonDept of Chem. & Bio. Eng. Okumura,
Masami GCTorrington Place Nitto Chem. Industry Co., Ltd
London, England WCIE 7JE 1-5-1 Marunouchi, Chiyoda-KuTokyo,
Japan 100
-
Sauber, Klaus 418 Owajima, Takavuki 25Hoechst AG Tokyo Research
Lab
PGE AI; H 780 Postfach 80 03 20 Kyowa Hakko Co., Ltd.
6000 Frankfurt, FRG 6230 3-6-6 Asahimachi
Machidashi, Tokyo Japan 194
Shutts, Bruce OCSchering-Plough Van Eikeren, Paul 3091011 Morris
Ave Bend Research Inc.
U-2-B 64550 Research Rd.
Union, NJ 07083 Bend, OR 97701
Sih, Charles 422 Wallick, Dave 426
University of Wisconsin Dow Chemical Co.
School of Pharmacy Central Research
425 N. Charter St. 1707 Bldg.
Madison, WI 53706 Midland, MI 48674
Stevenson, David 519 Walts, Alan OC
Biotech Research Institute Genzyme Corp.
6100 Royal Mount Ave 75 Kneeland St.
Montreal Que. Canada H4P 2R2 Boston, MA 02111
Stoddard, Fraser 710 Wandrey, Christian 326
Sheffield University/Dept of Chem. Institute of Biotech/at
Research Ctr Julich
Sheffield, England 53 7HF PO Box 1913, Leo-Brandt Strasse
D-5170 Julich FRG
Swanson, Paul 718
Dow Chemical Co./Central Research Co. Warshel, Arieh 325
Bldg. 1707 University of Southern CaliforniaMidland, MI 48674
Dept of Chemistry/University Park
Los Angeles, CA 90089
Tarbell, James OCE1 Dupont De Nemours & Co. Inc Wedekind,
Frank 323
Engineering Dept. Boehringer Mannheim Corp.PO Box 6090
Bahnhofstrabe 9-15
Newark, DE 19714-6090 Tutzing, West Germany 8132
Tautvvdas, Kestutis 423 West, J. Blair 309
3M Biosciences Lab, 3M Center Bend Research Inc.
Bldg 270-2S-09 64550 Research Rd.
St. Paul, M2 55144 Bend, OR 97701
Tedford, Catriona 504 Whited, Gregory 322
University of Strathclyde Eastman Kodak Co.
Thomas Graham Bldg. Bldg. 82B, 4th Floor
Dept of P&A Chem, 295 Cathedral St. Life Sciences Research
LabGlasgow, Scotland GI IXL Rochester, NY 14650-2118
Thompson, Jeffery 304 Whitesides, George 321
E1 DuPont De Nemours & Co. Harvard University/Dept. of
Chem.
PO Box 80328 12 Oxford St.
Wilmington, DE 19880-0328 Cambridge, MA 02138
Tramontano, Alfonso 424 Yamada, Hideaki OC
Scripps Clinic & Research Fdn Kyoto University/Dept of
Agricultureal Chem.Molecular 3iology Kitashirakawa-Oiwakecho
Sakyo-Ku
10666 N. Torrey Pines Rd Kyoto, Japan 606
La Jolla, CA 92124
-
1990 GORDON RESEARCH CONFERENCE ON DIELECTRIC PHENOMENI
Final Progress Report
AFOSR Grant 69-oa27
The 1990 Gordon Conference on Dielectric Phenomena was heldat
Holdermess School, Plymouth, New Hampshire from July 22 to 27.The
conference had 76 participants of which 31% were fromoverseas.
Countries represented included Great Britain, Germany,Argentina,
Hungary, Canada, Japan, Italy as well as the U.S.Conferees were a
mixture of scientists from universities,industries and national
laboratories. A significant fractionwere first-time attendees at
the Dielectric Phenomena conference.
As always in this Conference, there was a mix of
scientistsinterested in microscopic (e.g. relaxation) and
macroscopic (e.g.dielectric breakdown) phenomena in macromolecular
and lowmolecular weight systems. The program consisted of twenty
formalpresentations and a poster session of fifteen papers.
Asignificant number of papers dealt (as usual at this
Conference)with relaxation in glasses; new experimental techniques
weredescribed which extended the frequencies into the
gigahertzrange. Liquid crystals, both high and low molar mass, were
dealtwith in three presentations. One session (3 papers) dealt
withdielectric studies of the interaction of water with
bothsynthetic and naturally-occurring polymers. Two papers
dealtwith non-linear optical phenomena including applications
toprocessing devices. The role of polymers and non-polar liquidsas
dielectric insulators was covered from different points ofview in
four contributions.
An informal assessment concluded that the Conference was
asuccess in terms of quality of presentation, topics covered
andaudience participation. At the business meeting there was
aunanimous vote of approval for the Dielectric Phenemena
GordonResearch Conference to be held again in the summer of
1992.
-
GORDON RESEARCH CONFERENCE 7/19
Dielectric Phenomena
Holdarness School
Frank E. Karasz (Chairman) J.T. Bendler (Vice-Chairman)
July 22-27, 1990
MONDAY A.M.
J.E. Anderson (Discussion Leader)
C. Austen Angell "Relation Between Structure and Non-exponential
Relaxation(Arizona State) in Liquids and Glasses*
S. Sridhar (Northeastern "Dielectric Spectroscopy at Gigahertz
Frequencies inUniversity) Liquids and Solids"
Marc L. Mansfield "Dielectric Relaxations of Dilute Polymer
Solutions with(Michigan Molecular Application to the Poly(alkene
sulfones)"Institute)
MONDAY P.M.
John T. Bendler (Discussion Leader)
Poster Session
TUESDAY A.M.
William J. MacKnight (Discussion Leader)
F. Kremer (Max Planck "Molecular Dynamics in Low Molar Mass and
PolymericInstitute) Ferroelectric Liquid Crystals"
Graham Williams "Molecular Dynamics and Microscopic Alignment
Behaviour of(Swansea, UK) Liquid Crystalline Polymers as Studied by
Dielectric
Relaxation Spectroscopy"
Armand R. Tanguay (Univ. "The Critical Role of Dielectric
Materials in Opticalof S. California) Information Processing and
Computing Devices"
TUESDAY P.M.
Shiro Matsuoka (Discussion Leader)
Richard H. Boyd (Utah) "Subglass Dielectric Relaxations in
Polymers"
H. Block (Cranfield Inst. "Fluid Flow, Polarization and
Rheology"of Technology, UK)
-
WEDNESDAY A.M.
P. Keith Watson (Discussion Leader)
Erich E. Kunhardt "Electron Macro Kinetics in
Liquids"(Polytechnic Univ.)
Martin A. Abkowitz "Electronic Transport in Polymeric
Insulators"(Xerox)
T. Mizutani (Nagoya "High Field Phenomena in Insulating
Polymeric Films"University)
WEDNESDAY P.M.
Robert L. Fulton (Discussion Leader)
P. Hedvig (Research "Dielectric and Mechanical Relaxation in
CrosslinkedInst. for Plastics, Polymers"Budapest)
S. Havriliak (Rohm and "Dielectric Relaxation and Molecular
Dynamics"Haas)
THURSDAY A.M.
Gyorgy Banhegyi (Discussion Leader)
Polykarpos Pissis "Dielectric Studies of Water in Polymers and
Biopolymers"(National TechnicalUniv., Athens)
R. Pethig "Dielectric Studies of Protein-Water Interactions
and(Bangor, UK) Associated Proton Transport Processes"
Douglas Kell "Linear and Nonlinear Dielectric Properties of
Biological(Aberystwyth, UK) Materials"
THURSDAY P.M.
J.D. Hoffman (Discussion Leader)
David W. McCall "National Commission on Superconductivity"(Bell
Labs)
FRIDAY A.M.
J. Pochan (Discussion Leader)
J. Keith Nelson "A Physical Basis for the Dielectric Design of
Solid/Liquid(R.P.I.) Structures"
James M. O'Reilly "Study of Miscible and Immiscible Polymer
Blends by(Kodak) Dielectric Relaxation"
George Stegeman (Univ. "Nonlinear Optical Phenomena in Thin
Films"of Arizona)
-
B = BREWER GORDON RESEARCH CONFERENCE? M = MARSHALLC = COTTAGE.
HOLDERNESS SCHOOL, PLYMOUTH, N,, , N = NiLESHAM = HMMO DIELECTRIC
PHE(U A O L = URSEH = HOIT JULY 23-27, 1990 0 = OFF CAMPUSK =
KELSER R = RATHBUNL = LIVERMORE S = SARGENTLo = LOOKWOOD W =
WEBSTER
Abkowitz, Martin B4 Bendler, John H4Xerox Corp. GE R&D
Center800 Phillips Road KI, Room 4BMWebster, NY 14580 Schenectady,
NY 12301
Al Iinn. .John N27 Berborinn, lob, 1121Microwaves Research Group
Saint Joseph's Univ.Dept. Physics, Kings College Chemistry
DeptLondon, WC2 5600 City Line AveUK Philadelphia, PA 19131
Anderson, James N6 Block, H. N24Ford Motor Company Cranfield
Inst. of Tech.Scientific Research School of Industrial ScienceP.O.
Box 2053 Drop 3083 Centre for Molecular ElectronicsDearborn, MI
48121-2053 Cranfield, Bedford MK43 01K
EnglandAngell, C.A. N21Arizona State Univ., Chemistry Boyd,
Richard Lo4Tempe, AZ 85287 Univ. of Utah
Science Dept. 304 EMRUArenbeck, Helmut H1 Salt Lake City, UT
84124Papierfabrik Oberschmitten GMBHRhoenstr. 13 Carlini, Carlo
N506478 Nidda, Hessen 6478 Univ. of BolognaWest Germany Dipt Di
Chimica Ind Le E Dei Materiali
Viale Risorgimento 4Avakian, Peter B3 Bologna 40136Dupont
Company ItalyCRD, Experimental StationP.O. Box 80356 Cole, Robert
RIOWilmington, DE 19880-0356 Brown Univ.
Chemistry Dept., Box HBanhegyi, Gyorgy N6 Providence, RI
02912Bio-Pharm Research & Development Ltd.Konyves Kalamn KRT.
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Sciences, Inc.
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Leonard N4Buenos Aires 1428 Kings CollegeArgentina Dept. of
Physics
StrandBeatty, C.L. NI London WC2R 2LC101 Rhines Hall
EnglandDept. of Mat. Sci. & Eng.Univ. of Fl. Fulton, Robert
R8GainesviI c, FT 32A'1 Florida State Univ.
Dept. of ChemistryTallahassee, FL 32306-3006
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Graybeal, Jark R9 Jonscher, Andrew N23Virginia Tech. Royal
Holloway CollegeDept. of Chemistry Physics Dept.Davidson Hall Egham
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Ham3ChImile Physique Iloechst-Celanese Co.Bat 490 Research
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Industries Univ. of MassachusettsResearch & Development Polymer
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Douglas N2Bristol Research Labs Univ. College of WhalesP.O. Box 219
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Research InstituteBudapest XIV Hungaria KRT 114 Kennedy, Alvin
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Hoffman, Drew M8 Kremer, F. M6Stanford Univ. Max Planck Institut
F. PolmerforschungChemical Engineering Dept. Postfach 3148Stanford,
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FRGHoffman, John LolMichigan Molecular Inst. Kunhardt, Erich
H71910 W. St. Andrews Rd. Polytechnic UniversityMidland, MI 48640
Weber Research Institute
Route 110Ichikawa, Kimio M7 Farmingdale, NY 11735Univ of
Massachusettsc/o Dr. MacKnight, Room 701, PSE, LGRC MacKnight,
William R30Amherst, MA 01003 Univ. Of Mass.
Amerst, MA 01003Johnson, Edward H3AT&T Bell Labs Mansfield,
Marc MlRoom 70-214 Michigan Molecular Institute600 Mountain Ave.
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Center Chemistry Dept.Bldg. 260-3-02 Blacksburg, VA 24060St. Paul,
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at OswegoPhysice Dept.Oswego, NY 13126
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Shlesinger, Michael R21 Wei, Yanzhen Ham6
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TEXAS A&M UNIVERSITYDEPARTMENT OF CHEMISTRY
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FAX (409) 845-4205
THE CHAIRMAN'S REPORT ON THE GORDON CONFERENCE
ON PHYSICAL ELECTROCHEMISTRY
JULY 29 - AUGUST 3, 1990
COLBY JUNIOR COLLEGE
NEW LONDON, NEW HAMPSHIRE
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Report on Gordon Con. :ence:
The meeting was divided into five sections: the first was on the
structureof the interfacial region, (Dr. David Schiffrin from the
University ofSouthhampton chaired this session.)
The second section was on experimental approaches to quantum
aspects of thedouble layer. This section was chaired by Professor
Joseph Hupp fromNorthwestern University. The session on nuclear
electrochemistry, an unusualtopic, was chaired by Dr. Fritz Will,
and that on new experimental methods byWilliam O'Grady. Finally,
the bioelectrochemistry section on the Friday morningwas chaired by
Professor Adam Heller from the University of Texas.
All these sectior had their outstanding moments and a few of
these may berelated. Dr. McLaughlin, for example, speaking on the
structure of interfaces,made clear that he thought that the
Gouy-Chapman relationship was still true,even though it was not
applicable to double layers at the metal-solutioninterface or the
semiconductor interface. He managed to apply it by moving
thefiducial plain out into the solution.
Dr. Heegar at the University of California was electrifying in
the eveningwhen he told us about the progress that had been made
with electronicallyconducting polymers and made clear that he
thought it likely that the polymerswould exceed metals and their
conductivity. It was a m.tter of the length of thesegment in which
the electron was allowed to flow. If the segment was longenough
then eventually the conductance of a fiber could rise to about 5
ordersof magnitude greater than that of a metal! This would make
hot superconductivityunnecessary.
The new field of nuclear electrochemistry was, of course, as
usual, one ofgreat controversy but the encouraging thing was that
the Chairman had justreturned from a trip to Japan where he had got
to talk to some of the 50 JapanesegrouM, amounting to 1000 workers
who are now researching cold fusion in thatcountry. Dr. Will
reported the neutron bursts about one million per second (l0greater
than observed here) and he told us of the formation of tritium by
gomeof these groups.
Then, on the Thursday, the most impressive paper turned out to
be that inthe evening by Dr. Bruce Schardt. The Chairman described
it as a tour de forcebecause of the vigorous way in which Dr.
Schardt described the best way to obtaingood pictures at atomic
resolution.
On the Friday morning the most outstanding paper was that given
by Dr.Hill, - who has recently been appointed a Fellow of the Royal
Society, - who toldus of his researches in electron transfer
kinetics to substances of biologicalorigin.
The Gordon Conference in Physical Electrochemistry of 1990 was
said by someto be the most outstanding of the three conferences
which have been held so farand it is hoped that the new Chairman,
Professor Hector Abruna from the CornellUniversity, will be joined
by the freshly elected Vice Chairman, Dr. WilliamO'Grady, of the
Naval Research Laboratory in Washington, for the 1992
Conference.
1ci
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2 8 AUG N40
Chairman's Final Progress Report
1990 Gordon Research Conference on Organometallic Chemistry
Air Force Office of Scientific Research Contract No.
90-NC-047
The 1990 Gordon Research Conference on Organometallic Chemistry
was held from June24 - 29, 1990 at Salve Regina College in Newport,
R. I. A total of 134 participants wasselected from approximately
150 applications. Attendance was well divided betweenacademic (88),
industrial (43) and national laboratory (3) participants. Thirteen
participantswere from countries outside the United States, and 12
were women. A copy of theparticipants list is attached.
Based on its success in last year's program, the conference
retained the policy of schedulinga relatively large number of short
(30-minute) invited talks combined with substantialamount of time
for discussion following each presentation. This format minimized
thetendency of speakers to rehash published work and (as the Gordon
Conferenceadministration suggests) encourages them to focus on
their most important and timelyresults. In addition, 57
participants chose to present recent research results in poster
form.Because of the large number of posters a full poster session
was arranged for each eveningof the conference except Sunday. These
sessions were held in the informal discussion area,which has been
equipped by Salve Regina college with air conditioning, tables,
excellentlighting, and a refreshment facility. Because of the
quality of the contributions andfacilities, the posters attracted a
great deal of attention and generated much lively discussionduring
the conference.
Another successful policy continued from last year was the six
speaking slots open until thefirst evening of the meeting. At that
time, the best poster submissions were selected by acommittee
appointed by the chairman, and the authors of these posters were
invited to givetalks rather than poster presentations in the open
time slots. One change from last year wasthat these "poster talks"
were distributed throughout the five days of the meeting, rather
thanbeing cc-centrated on Friday morning. This procedure was again
very successful; some ofthe most exciting and timely discoveries
presented at the meeting appeared in these last-minute selections.
Including the poster talks, 32 oral presentations were made at
themeeting. A copy of the complete program is enclosed with this
report.
Individuals were invited to the conference in three categories:
invited speakers, sessionchairs, and members of the committee to
select the six poster talks. Because almost all theinvitations were
accepted, this resulted in attendance by many of the most
importantscientists in organometallic chemistry and allied fields.
In assembling the speaker list weworked to maintain a balance of
mainstream topics (e.g., transition metal and main
grouporganometallic synthesis and reaction mechanisms; homogeneous
catalysis- applications toorganic synthesis) withi new areas in
which organometallic chemistry is currently orpotentially having a
significant impact (synthesis of new materials such as thin films
andpolymers, interfacial phenomena, surface science, new physical
techniques).
Judging from informal comments of participants, the best talks
at the meeting came fromboth mainstream organometailic and
interdisciplinary areas. Highlights of the meeting wereJohn Ellis
and John Cooper's presentations on the preparation of novel new
anionic"negative oxidation state" organometallic complexes, Robert
Miller's talk on the chemistryof polysilanes, the lecture by Tobin
Marks on the use of lanthanide complexes as catalystsuseful in
organic synthesis, Eric Jacobsen's poster talk on a dramatic new
method forcatalytic asymmetric epoxidation of unfunctionalized
alkenes, Morris Bullock's poster talk
i n , mu m m m mmun n n mamimu e nnnn m uam muulnn nuY
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on radical intermediates involved in the reactions of metal
hydrides with alkenes, SylviaCeyer's presentation on the mechanism
of methane activation on metal surfaces, andBradford Wayland's
lecture on C-H bond reactions of porphyrin complexes. Two
invitedspeakers also received important awards just before the
meeting--Harry Gray received thePriestly medal of the American
Chemical Society, and Susan Thomas was awarded theMeldola medal of
the Royal Society of Chemistry. We were especially gratified that
Dr.Gray was able to participate. In true Gordon Conference
tradition, he arrived Saturdayevening, spent the entire week at the
meeting, and gave an excellent talk Thursday eveningon platinum
photochemistry and photocatalysis. Gray's enthusiasm was mirrored
by thehigh degree interaction of the other participants.
To provide an indication of the quality of the conference, as
well as the sort of interactionstimulated among the attendees,
attached to this report are copies of letters received by
thechairman from several of the participants in early July.
Although we have not yet receivedthe formal questionnaires filled
out at the meeting, it seems clear from these letters and
othercomments made to the organizers that the 1990 Gordon
Conference on OrganometallicChemistry was exceptionally
successful.
Attachments
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GORDON CONFERENCE ON ORGANOMETALLIC CHEMISTRY
Salve Regina College, Newport, R. I.
June 24 -29, 1990
Chair: Robert G. Bergman; Vice Chair: Alfred P. Sattelberger
Poster talk selection committee: Maurice Brookhart, Henry E.
Bryndza,Nancy M. Doherty, John A. Gladysz, Jack R. Norton, Peter T.
Wolczanski
Monday, June 25
Session 1: Exploratory Organometallic Synthesis, Reactivity,
andMechanisms
Chair: Denis Forster (Monsanto Company)
Heinz Berke (University ef Zurich)"How to Make Transition Metal
Hydrogen Bonds More Reactive: A Conceptual Approachand Its
Experimental Consequences"
Thomas C. Flood (University of Southern California)"Mechanisms
of Bond Activations by Soluble Complexes of Iridium and Osmium"
John E. Ellis (University of Minnesota)
"New Synthetic Routes to Highly Reduced Organometallics"
Two papers selected from poster submissions
Session 2: Applications to Organic Synthesis and/or Chiral
OrganometallicChemistry
Chair: Richard J. Piccolini (Rohm and Haas Company)
Yoshihiko Ito (Kyoto University)"Asymmetiric Aldol Reactions of
a-Isocyanocarboxylates and Related IsocyanoDerivatives Catalyzed by
Chiral IB Metal Complexes"
N. John Cooper (University of Pittsburgh)"The Application of
Diastereomeric Tungstenocene Complexes Containing Chiral
MetalCenters to the Study of Organometallic Reactions"
S.E. Thomas (University of Warwick)"Reactivity of Heterodiene
Metal Cabonyl Complexes"
Tuesday, June 26
Session 3: Main Group Organometallic Chemistry
Chair: John E. Bercaw (California Institute of Technology)
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2
Dr. Peter Jutzi (University of Bielefeld)"Tt-Complexation in
Main-Group-Chemistry - Some Recent Results"
Lawrence R. Sita (Carnegie Mellon University)"New Chemistry of
Polycyclic Organostannanes"
Gerard Parkin (Columbia University)"Poly(pyrazolyl)hydroborato
Alkyl Derivatives of the s- and p-block Metals"
Two papers selected from poster submissions
Session 4: Organometallic Sulfur Chemistry
Chair: Eric R. Evitt (Catalytica Associates, Inc.)
Thomas B. Rauchfuss (University of Illinois at
Urbana-Champaign)"Studies on Organoruthenium and Organorhodium
Sulfides"
Robert J. Angelici (Iowa State University)"Reactions of
Thiophene in Organometallic Complexes"
E.J.M. de Boer (Koninklijke/Shell-Laboratorium)
"Reactions of Rhenium Oxides with Alkynes"
Wednesday, June 27
Session 5: Materials, Solid State, Polymers
Chair: John P. Fackler Jr. (Texas A&M University)
Herbert D. Kaesz (University of California, Los
Angeles)"Deposition of Transition Metal Thin Films from
Organometallic Precursors"
R.D. Miller (IBM)"Soluble High Molecular Weight Polysilanes:
Science and Applications"
Ralph G. Nuzzo (AT&T)"The Molecular Self-Assembly of Organic
Thiols on Au(l 11) and the Application of TheseMaterials in
Condensed Phase Studies"
One paper selected from poster submissions
Session 6: Lanthanides, Actinides, etc.
Chair: B. Duane Dombeck (Union Carbide Corporation)
Tobin J. Marks (Northwestern University)"New Homogeneous
Catalysis with Organo-Lanathanides"
James C. Stevens (Dow Chemical Company)"Selective Propylene
Dimerization Catalyzed by Organouranium Compounds"
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3
F. G. N. Cloke (University of Sussex)"High and Low Oxidation
State Organo-f-element Compounds Derived from BulkyAromatic
Ligands"
Thursday, June 28
Session 7: Techniques, Theory
Chair: Cynthia M. Friend (Harvard University)
John D. Simon (University of Colorado)"Picosecond Studies of the
Photodissociation of Chromium Hexacarbonyl"
Sylvia T. Ceyer (Massachusetts Institute of Technology)"The
Activation of CH4 and the Synthesis of C6H6 from CH4 on
Ni(1lI)"
Charles M. Lieber (Columbia University)"Scanning Tunneling
Microscopy Studies of the Structural and Electronic Effects of
MetalSubstitution in Inorganic Materials"
One paper selected from poster submissions
Session 8: Inspirations
Chair: Malcolm LH. Green (University of Oxford)
John A. Osborn (University of Strasbourg)"Catalysts for the
Chemo- and Enantio- Selective Reduction of Imines"
Harry B. Gray (California Institute of Technology)"Binuclear
Iridium and Platinum Photochemistry and Photocatalysis"
Friday, June 29
Session 9: Methane, Aikane Chemistry
Chair: Patricia L. Watson (E.I. duPont de Nemours)
Bradford B. Wayland (University of Pennsylvania)"C-H Bond
Reactions of Rh(II) and Ir(II) Porphyrin Complexes"
D. Michael Heinekey (Yale University)"Reactions of Methane with
Rhenium Complexes"
Jay A. Labinger (California Institute of Technology)"Practical
Approaches to Alkane Activation: From Methane Mono-Oxygenase
toOrganometallic"
Wrap-up session
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1990 Organometallic Gordon Research Conference Poster
Schedule
Chair: Robert G. Bergman
Vice-Chair: Alfred P. Sattelberger
Session 1 - Monday, June 25
1. "Metal-Catalyzed Oxidation of Para-Substituted Phenolics.
Approaches toBenzoquinones"Joseph J. BozellChemical Conversion
Research BranchSolar Energy Research Institute
2. "Synthesis, Structure and Reactivity of Metallabenzenes"John
R. BleekeDepartment of ChemistryWashington University
3. "Some Applications of Diolate-Derived Chiral Auxiliaries in
Organo-TransitionMetal Chemistry"Joseph A. HeppertDepartment of
ChemistryUniversity of Kansas
4. "The Binding of Heteroaromatic Nitrogen Compounds with Cp*Rh
2+, CpRu + , andCp*Ru+ Complexes and the Role of T11, N-Bonded
Complexes in theRegioselective Hydrogenation of the Nitrogen
Ring"Richard FishDepartment of ChemistryLawrence Berkeley
Laboratory
5. "A New Carbon-Hydrogen Bond Activation Reaction: 'Vinylic'
Deprotonation ofCationic Rhenium Alkene Complexes"John A.
GladyszDepartment of ChemistryUniversity of Utah
6. "Unprecedented Reactions Between Transition Metal Alkynyl
Complexes andNucleophiles: Synthesis and Crystal Structures of
Fe2(CO)(I-CO){*i.-G:T13-
C(O)C(R)-CIC(O)R'])(TI 5-C5H5 )(I5 -C5 R"5) (R = CH3, C-CSiMe 3
; R'= n-Bu, CH3 ,C6H5; R" = H, CH 3 )"Andrew WongDepartment of
ChemistryOccidental College
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7. "Photooxidation of Metal Carbynes: Metal Radical Reactivity
VersusRearrangement of the Carbyne Ligands in the 17-Electron
Intermediates"Lisa McElwee-WhiteDepartment of ChemistryStanford I
Inivrsity
8. "Quantum Mechanical Exchange of Hydrides in Solution.
Proton-ProtonExchange Couplings and Rotational Tunneling in
Transition Metal Polyhydrides"Kurt W. ZilmDepartment of
ChemistryYale University
9. "Metal Alkyl Versus Metal Vinyl Insertion Reactions"Kenneth
M. DoxseeDepartment of ChemistryUniversity of Oregon
10. "Catalytic Hydroboration: The Study of a Model Iridium
System"Joseph S. MerolaDepartment of ChemistryVirginia Polytechnic
Institute and State University
11. "Transformations of Organo-Iridium Phosphide
Complexes"Michael D. FryzukDepartment of ChemistryUniversity of
British Columbia
12. "Synthesis, Structure and Reactivity of the Encapsulated
Metallocenes[(i-Pr)4C5H]2Ca and [(i-Pr)4CsH]2 Ba"Timothy P.
HanusaDepartment of ChemistryVanderbilt University
13. "Oxygen Containing Metallacycles From Ruthenium
Enolates"Robert G. BergmanDepartment of ChemistryUniversity of
California, Berkeley
14. "Formation of 2,3-Butanedione in the Carbonylation of a
Binuclear RhodiumMethyl Complex Under Extremely Mild
Conditions"Richard EisenbergDepartment of ChemistryUniversity of
Rochester
15. "Carbon-Oxygen Bond Activation. The Deoxygenation of Phenols
by OxygenAtom Transfer to CO"Clifford P. KubiakDepartment of
ChemistryPurdue University
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16. "Mass Spectroscopic Studies of Large Gold Clusters"John P.
FacklerDepartment of ChemistryTexas A&M University
Session 2 - Tuesday, June, 26
17. "Asymmetric Synthesis and Applications of C2-Symmetrical
ChiralCyclopentadienyl Metal Complexes"Ronald L.
HaltermanDepartment of ChemistryBoston University
18. "Characterization of the Cationic Radicals
{H3RU3[CXI(CO)9.nLn} + , where X =OMe, SEt or NMe 2 ; L = PPh3 ,
AsPh3 ; n = 2 or 3"Jerome B. KeisterDepartment of ChemistrySUNY
Buffalo
19. "Mechanism of Alkyl Migration in Iron-Manganese
Alkoxy-CarbeneDecomposition"William H. HerschCUNY Queens
College
20. "The First Electron-Transfer Catalyzed Ligand Substitution
Which is Faster for anEven- Versus the Parent Odd-Electron
System"Rinaldo PoliDepartment of ChemistryUniversity of
Maryland
21. "Rhodium-Catalyzed C-H Bond Functionalization. I. Thermal
AldehydeDecarbonylation (and Alkene Carbonylation?) I1. Insertion
of Acetylenes inBenzene C-H Bonds."Alan S. GoldmanDepartment of
ChemistryRutgers University
"2. "Air-Sensitive Procatalysts for Ring-Opening Metathesis
Polymerization ofNorbornene-Type Monomers"Larry F. RhodesResearch
and Development CenterBF Goodrich Company
23. "Synthesis of Tungsten Oxo and Alkylidene Complexes Using
OrganosiliconReagents"James M. MayerDepartment of
ChemistryUniversity of Washinton
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24. "Structure and Reactivity of Bimetallic Fischer Carbene
Complexes"M. G. FinnDepartment of ChemistryUniversity of
Virginia
25. "Hydrogen Atom Transfer Reactions of Transition Metal
Hydrides. Kinetics andMechanism of the Hydrogenation of
c-Cyclopropyl Styrene"R. Morris BullockDepartment of
ChemistryBrookhaven National Laboratory
26. "Evidence for an c-Agostic Transition State for Olefin
Insertion"John E. BercawDivision of Chemistry and Chemical
EngineeringCalifornia Institute of Technology
27. "Bimetallic Hydroformylation: A Dramatic Example of
HomobimetallicCooperativity"George G. StanleyDepartment of
ChemistryLouisiana State University
28. "Cleavage of Dialkylsiloxanes by Trimethylaluminum"Andrew R.
BarronDepartment of ChemistryHarvard University
29. "Transition Metal S20 Complexes and Transition
Metal-Mediated ThiosulfinateEster Synthesis"Mark E.
WelkerDepartment of ChemistryWake Forest University
30. "C-S Bond Cleavage by Rhodium: A Homogeneous Model for
MechanisticStudies of the Hydrodesulfurization (HDS)
Reaction"William D. JonesDepartment of ChemistryUniversity of
Rochester
31. "Reactions of Mo/Co/S Clusters Relevant to HDS Catalysis"M.
David CurtisDepartment of ChemistryThe University of Michigan
32. "Reactions of 1-Sila-3-Metallacyclobutane Complexes of
Zirconium"Jeffrey L. PetersenDepartment of ChemistryUniversity of
West Virginia
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Session 3 - Wednesday, June 27
33. "C-C Bond Cleavage Reactions in Platinum Glycolate
Complexes"Mark AndrewsDepartment of ChemistryBrookhaven National
Laboratory
34. "E-H Activation Chemistry: Marked Differences in Ir-H
Reactivity in ComplexesResulting From 9-H, C-H, N-H and O-H
Oxidative Addition to Iridium"Joseph S. MerolaDepartment of
ChemistryVirginia Polytechnic Institute and State University
35. "Simple Molybdenum and Tungsten Carbyne Complexes"Joseph L.
TempletonDepartment of ChemistryUniversity of North Carolina
36. "Alkylation of Highly Reduced r-henium Oxo Complexes
[Re(O)(RC-CR) 2]Na:Evidence for Radical and SN2 Pathways"James M.
MayerDepartment of ChemistryUniversity of Washington
37. "Molecular Analogs of Multiple Quantum Wells?"Paul J.
FaganCentral Research and Development DepartmentE. I. DuPont de
Nemours and Company
38. "Chemical Vapor Deposition of Gold"Fred McCormickCorporate
Research3M
39. "Molecular Precursors for Iridium Phosphide and the
Synthesis of SmallSemiconductor Clusters in Solution"Klaus H.
TheopoldDepartment of ChemistryCornell University
40. "Organometallic Complexes with Sterically Distressed
Ligands: The 1,2,3-tri-t-butylcyclopentadienyl Ligand"Russell P.
HughesDepartment of ChemistryDartmouth University
41. "The Ladder Structure of [ButCH 2)2TaN]5.NH 3.C7H8 and its
Relationship toCubic Tantalum Nitride"Peter T. Wolczanski
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Department of ChemistryCornell University
42. "Surface Organometallic Chemistry"Jeffrey SchwartzDepartment
of Ch'enistryPrinceton University
43. "Cp* 2V2Br4 - A New Synthon in Mid-Valent Vanadium
Chemistry. Preparation ofof Cp* 2V2(CH 3)4, a Complex with Four
Bridging Methyl Groups"Louis MesserleDepartment of
ChemistryUniversity of Iowa
44. "Cobalt Half-Sandwich Complexes with Intramolecular C-C
Double BondCoordination"Jun OkudaAnorganisch-Chemisches
InstitutTechnische Universit~t Mnchen
45. "KineticZs and Mechanism of Electron-Transfer from
Pentacarbonylrhenate to MetalCarbonyl Dimers'Jim D.
AtwoodDepartment of ChemistrySUNY Buffalo
46. "Acyclic Diene Metathesis Polymerization Chemistry"James M.
BoncellaDepartment of ChemistryUniversity of Florida
Session 4 - Thursday, June 28
47. "A Puzzle in Para-Hydrogen-Induced Polarization. Signal
Enhancement inAsymmetric Hydrogenation by Addition of a Second
Substrate"Richard EisenbergDepartment of ChemistryUniversity of
Rochester
48. Hydrogen Bonding Properties of Transition Metal
Fluorides"Thomas RichmondDepartment of ChemistryUniversity of
Utah
49. "Metal Tellurates: Synthesis, Structure and Reactivity"John
ArnoldDepartment of ChemistryUniversity of California, Berkeley
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50. "Interaction of Aldehydes with Monomeric Aluminum
Complexes"Andrew BarronDepartment of ChemistryHarvard
University
51. "Unsaturated Mixed-Metal Complexes: Synthesis, Structures
and Reactivity"Michael J. ChetcutiDepartment of ChemistryUniversity
of Notre Dame
52. "Rearrangement and C-X Bond Formation Using Nickel
Complexes"Allan R. PinhasDepartment of ChemistryUniversity of
Cincinnati
53. "Electrocyclic Reactions of (C5H5)Fe(pentadienoyl)
Complexes"Neil T. AllisonDepartment of ChemistryUniversity of
Arkansas
54. "IR Analysis of Anion Metathesis. Lability of Low Valent d6
Complexes"Norris W. HoffmanDepartment of ChemistryUniversity of
South Alabama
55. "Reaction of Cyclopropylcarbene-Tungsten Complexes with
Alkynes: A NewSeven-Membered Ring Synthesis"James W.
HerndonDepartment of ChemistryUniversity of Maryland
56. "Structural Data from Solid -State Deuterium NMR
Spectroscopy"Leslie ButlerDepartment of ChemistryLouisiana State
University
57. "Neutral Dihydrogen Complexes of Iridium"Craig
JensenDepartment of ChemistryUniversity of Hawaii
-
GORDON RESEAR CH CONFERENCES
ORGANOETALLIC CHEMISTRY
June 25-29, 1990
Salve Regina College, Newport, RI
Registration List
Anthony G. Abatjoglou non-resident Andrew R. Barron Miley
104
Union Carbide Corporation Chemistry Department
Tech Center, 770-420 Harvard University
P. 0. Box 8361 12 Oxford Street
South Charleston, WV 25303 Cambridge, MA 02138
Neil T. Allison 102B Thomas R. Beattie 314A
Dept. of Chemistry & Biochemistry Merck Sharp & Dohme
Research Laboratories
University of Arkansas Basic Medicinal Chemistry Dept.
Fayetteville, AR 72701 125 East Lincoln AvenueRahway, NJ
07065
Mark Andrews 102B
Dept. of Chemistry John E. Bercaw 106B
Brookbaven National Laboratory Dept. of Chemistry. 127-72
Bldg. 555 California Institutes of Technology
Upton, NY 11973 Pasadena, CA 91125
Robert J. Angelici 103B Robert G. Bergman 209A
Dept. of Chemistry Dept. of Chemistry
Iowa State University University of California
Ames, IA 50011 Berkeley, CA 94720
Libby Angelici 103B Heinz Berke 107BAnorganisch-Chemisches
Institut
John Arnold 211A University of Zurich
Chemistry Department Winterthurerstr. 190
University of California CH-8057 Zurich, Switzerland
Berkeley, CA 94720John R. Bleeke 201B
Jim D. Atwood 205A Dept. of Chemistry, Box 1134
Dept. of Chemistry Washington University
SUNY at Buffalo One Brookings Drive
Buffalo, NY 14214 St. Louis, MO 63130
Owen Bailey 05B Amy I. Blough 303A
Amoco Chemical Company Research Center
Research & Development Dept. Hercules, Inc.
P. 0. Box 3011 Wilmington, DE 19894
Naperville, IL 60566James M. Boncella 202B
Tina Bailey 05B Dept. of ChemistryUniversity of Florida
Alan C. Barker 314A Gainesville, FL 32611
ICI PharmaceuticalsHurdsfield Industrial Estate Joseph J. Bozell
107B
Macclesfield, Cheshire SK1O 2NA Solar Energy Research
Institute
England 1617 Cole Blvd.Golden, CO 80401
-
-2-
Maurice Brookhart 203B E. J. M. DeBoer 101BDept. of Chemistry
Koninklijke/Shell LaboratoriumUniversity of North Carolina PX
DepartmentChapel Hill, NC 27599-3290 Postbus 3003
1003 AA Amsterdam, The Netherlands
Henry E. Bryndza 309AE. I. du Pont de Nemours & Co. Nancy M.
Doherty 208BExperimental Station, E262/219 Dept. of ChemistryP. 0.
Box 80262 University of CaliforniaWilmington, DE 19880-0262 Irvine,
CA 92717
R. Morris Bullock 204B B. D. Dombek 208ADept. of Chemistry Union
Carbide Corporation
Brookhaven National Laboratory P. 0. Box 8361Upton, NY 11973
South Charleston, WV 25303
Mark J. Burk 312A Kenneth It. Doxsee 313AE. I. du Pont de
Nemours & Co. Dept. of ChemistryCRD, Experimental Station
University of OregonWilmington, DE 19880-0328 Eugene, OR 97403
Leslie Butler Miley 111 Richard Eisenberg 210BLouisiana State
University Dept. of ChemsitryDept. of Chemistry University of
RochesterBaton, Rouge, LA 70803 Rochester, NY 14627
Stephen A. Butter non-resident John E. Ellis 209BU. S.
Department of Energy Dept. of ChemistryChemical Sciences Division
University of MinnesotaOffice of Basic Energy Sciences 207 Pleasant
Street, SEWashington, DC 20545 Minneapolis, MN 55455
Sylvia T. Ceyer 305B Paul E. Ellis, Jr. non-residentDept. of
Chemistry, Room 6-225 Sun Oil Co.Massachusetts Institute of
Technology Research & Development77 Massachusetts Avenue P. 0.
Box 1135
Cambridge, MA 02139 Marcus Hook, PA 19061
Michael J. Chetcuti 206B Eric R. Evitt 211B
Dept. of Chemistry & Biochemistry Catalytica, Inc.University
of Notre Dame 430 Ferguson Drive, Bldg. 3Notre Dame, IN 46556
Mountain View, CA 94043
F. G. N. Cloke 207B John P. Fackler, Jr. 101ASchool of Chemistry
Dept. of ChemistryUniversity of Sussex Texas A&M
UniversityBrighton BNI 9QJ, England College Station, TX 77843
N. John Cooper 107A Paul J. Fagan 202BDept. of Chemistry E. I.
du Pont de Nemours & Co.
University of Pittsburgh Experimental Station, CR&DD234
Chevron Science Center Box 80328Pittsburgh, PA 15260 Wilmington, DE
19809
M. Da',id Curtis 211A J. W. Faller Milev 102
Dept. of Chemistry Dept. of ChemistryUniversity of Michigan Yale
University
Ann Arbor, MI 48109-1055 P. 0. Box 6666
New Haven, CT 06511-8118
-
-3-
Frank J. Feher 208B Alan S. Goldman 214BDept. of Chemistry Dept.
of ChemistryUniversity of California Rutgers UniversityIrvine, CA
92717 P. 0. Box 934
Piscatowdy, NJ 08855
I. G. Finn 313ADept. of Chemistry Harry Gray 204AUniversity of
Virginia Chemistry 127072McCormick Road California Institute of
TechnologyCharlottesville, VA 22901 Pasadena, CA 91125
Richard H. Fish non-resident Malcolm L. Green 207BLawrence
Berkeley Laboratory Inorganic Chemistry Lab70-1IOA Oxford
UniversityUniversity of California South Parks RoadBerkeley, CA
94720 Oxford OXI 3QR, England
Thomas C. Flood 213A Marifaith Hackett 205BDept. of Chemistry
Amoco Chemical CompanyUniversity of Southern California Research
& Development Dept.Los Angeles, CA 90089-0744 P. 0. Box
3011
Naperville, IL 60566PeterC. Ford Miley 103Dept. of Chemistry
Ronald L. Halterman Miley 107University of California Dept. of
ChemistrySanta Barbara, CA 93106 Boston University
590 Commonwealth AvenueDenis Forster 207A Boston, MA
02215Monsanto CompanyR&D Timothy P. Hanusa 312A800 North
Lindbergh Blvd. Dept. of ChemistrySt. Louis, MO 63167 Vanderbilt
University
Box 1822BCynthia Friend 212B Nashville, TN 37235Dept. of
ChemistryHarvard University Michael Heinekey 214B12 Oxford Street
Dept. of ChemistryCambridge, MA 02138 Yale University
225 Prospect Street11. D. Fryzuk 214A New Haven, CT
06511-8118Dept. of ChemistryUniversity of British Columbia Joseph
A. Heppert 206B2036 Main Mall Dept. of ChemistryVancouver, BC V6T
1Y6, Canada- University of Kansas
Lawrence, KS 66045Kevin P. Gable 215BDept. of Chemistry James W.
Herndon 215BOregon State University Dept. of Chemistry &
BiochemsitLyCorvallis, OR 97331-4003 University of Maryland
College Park, MD 207.2John A. Gladysz 213BDept. of Chemistry
William H. Hersh 213BUniversity of Utah Dept. of Chemistry &
BiochemistrySalt Lake City, UT 84112 'ns College of CUNY
65-30 Kissena Blvd.Stephen Godleski 305A Flushing, NY
11367-0904Eastman Kodak CompanyResearch Labs6th Floor, Bldg.
82CRochester, NY 14650-0211
-
-4-
Norris W. Hoffman 301B P. Jutzi 304BDept. ofChemistry Faculty of
ChemistryUniversity of South Alabama University of BielefeldMobile,
AL 36688 4800 Bielefeld, West Germany
Jeffrey B. lloke 311A Herbert D. Kaesz 301BEnglehard Corporation
Dept. of Chemistry & BiochemistryRCD Room 312 University of
CaliforniaMenlo Park, CN 28 Los Angeles, CA 90024-1569Edison, NJ
08818
William C. Kaska Miley 113Istvan T. Horvath Miley 114 Dept. of
ChemistryExxon Research & Engineering University of
CaliforniaRoute 22 E Santa Barbara, CA 93106Annandale, NJ 08801
Susan Kegley 210AM. S. Howie 302B Dept. of ChemistryEthyl
Corporation Williams CollegeTechnical Center, Research &
Development Williamstown, MA 01267P. 0. Box 14799Baton Rouge, LA
70898 Jerry Keister 205A
Dept. of ChemistryHarriett C. Howie 302B University of
Buffalo
Buffalo, NY 14214Russell P. Hughes 309BChemistry Department
Donald R. Kelsey 104BDartmouth College Shell Development
CompanyHanover, NH 03755 New Chemical Technology
Exploratory PolymersYoshihiko Ito 206A P. 0. Box 1380Dept. of
Syntheti . Chemistry Houston, TX 77251Kyoto UniversityKyoto 606,
Japan Rein U. Kirss 308A
Dept. of ChemistryEric N. Jacobsen 303B Northeastern
UniversityDept. of Chemistry, Box 55-5 Boston, MA 02115University
of Illinois470 Roger Adams Lab Cliff Kubiak 210BUrbana,