PWI TF meeting, Ljubljana, 13-15 November 2006 EU Plasm a-W allInteractionsTask Force Progress with tritium Progress with tritium removal and mitigation removal and mitigation 2005-6 2005-6 G Counsell 1 , D Borodin 4 , P Coad 1 , J Ferreira 8 , C Grisolia 2 , C Hopf 3 , W Jacob 3 , A Kirschner 4 , A Kreter 4 , K Krieger 3 , J. Likonen 5 , A. Litnovsky 4 , A. Markin 3 , V Philipps 4 , J Roth 3 , M Rubel 6 , E Salancon 3 , A. Semerok 7 , FL Tabares 8 , C. Tomastik 9 , A Widdowson 1 1 EURATOM/UKAEA Fusion Association, Culham Science Centre, Abingdon, OX14 3DB, UK 2 Association EURATOM-CEA, CEA/DSM/DRFC Cadarache, 13108 St.Paul lez Durance, France 3 Max-Planck-Institut für Plasmaphysik, EURATOM Association, D-85748 Garching, Germany 4 Institut für Plasmaphysik, Forschungszentrum Jülich, Association EURATOM-FZJ 5 Association EURATOM-TEKES, VTT Processes, PO Box 1608, 02044 VTT, Espoo, Finland 6 Alfvén Laboratory, Royal Institute of Technology (KTH), Association EURATOM-VR, 100 44 Stockholm, Sweden 7 CEA Saclay, DEN/DPC/SCP/LILM, Bat. 467,91191Gif sur Yvette, France 8 Association Euratom/Ciemat. Laboratorio Nacional de Fusión. 28040 Madrid, Spain 9 Institut für Allgemeine Physik, Vienna University of Technology, Wiedner Hauptstraße 8-10, A-1040 Wien, Austria
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EU-PWI TF meeting, Ljubljana, 13-15 November 2006 Progress with tritium removal and mitigation 2005-6 G Counsell 1, D Borodin 4, P Coad 1, J Ferreira 8,
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EU-PWI TF meeting, Ljubljana, 13-15 November 2006 EU Plasma-Wall Interactions Task Force
Progress with tritium removal Progress with tritium removal and mitigation 2005-6and mitigation 2005-6G Counsell1, D Borodin4, P Coad1, J Ferreira8, C Grisolia2, C Hopf3,W Jacob3, A Kirschner4, A Kreter4, K Krieger3, J. Likonen5, A. Litnovsky4,A. Markin3, V Philipps4, J Roth3, M Rubel6, E Salancon3, A. Semerok7,FL Tabares8, C. Tomastik9, A Widdowson1
1EURATOM/UKAEA Fusion Association, Culham Science Centre, Abingdon, OX14 3DB, UK2Association EURATOM-CEA, CEA/DSM/DRFC Cadarache, 13108 St.Paul lez Durance, France3Max-Planck-Institut für Plasmaphysik, EURATOM Association, D-85748 Garching, Germany4Institut für Plasmaphysik, Forschungszentrum Jülich, Association EURATOM-FZJ5Association EURATOM-TEKES, VTT Processes, PO Box 1608, 02044 VTT, Espoo, Finland6Alfvén Laboratory, Royal Institute of Technology (KTH), Association EURATOM-VR, 100 44 Stockholm, Sweden7CEA Saclay, DEN/DPC/SCP/LILM, Bat. 467,91191Gif sur Yvette, France8Association Euratom/Ciemat. Laboratorio Nacional de Fusión. 28040 Madrid, Spain9Institut für Allgemeine Physik, Vienna University of Technology, Wiedner Hauptstraße 8-10, A-1040 Wien, Austria
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EU Plasma-Wall Interactions Task ForceOutline
A reminder of the problem
Advances in modelling tritium retention with mixed materials
‘New’ challenges – retention in gaps, under layers and in the bulk
Progress with characterising de-tritiation techniques and associated problems
Can we avoid retention in the first place?
Future thoughts
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EU Plasma-Wall Interactions Task Force
• Acceptable ITER operation ~2500 shots before maintenance period
Long term T retention/shot must be< 0.14g/400s shot
Strategies for T removal essential ifCFC targets in DT phase
Removal efficiency must be 80% - 98%
Clear need for T removal schemes
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EU Plasma-Wall Interactions Task Force
Preliminary modelling using local erosion & deposition model ERO (still many open questions)
Model assumptions validated against TEXTOR C13 injection experiments
• >80% of wall area in ITER is beryllium
• Eroded Be will transport to divertor (as ions)
modify erosion and co-deposition
Be concentration in plasma plays key role Balance of inc. Be coverage on target (dec.
C erosion) and inc. C erosion due to Be flux For a range of Be conc., T/C and T/Be ratios
0.5g – 6.4gT/400s shot
Be transport will impact C erosion
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EU Plasma-Wall Interactions Task Force
Assumptions: Maximum possible stochiometric combination of Be2C formed No chemical erosion for Be2C
Leads to non-linear evolution of relaxation time for reduction in chemical erosion- as observed
Be2C formation potentially significant
ERO modelling of erosion mitigation with Be seeding in PISCES
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EU Plasma-Wall Interactions Task Force
• All ITER plasma facing components will be castellated
• >2,000,000 Gaps in ITER (typ. 0.5-1mm x 10mm)
• Increases plasma exposed areas by factor 2 - 5
aC:H co-deposits form in tile gaps
CxHy molecules and radicals form a:C:H co-deposits deep in gaps – how much and how deep is on-going research
CFC tile segments from JET Mk1 divertor, 6mm gaps
Retention in gaps twice that on plasma-facing surfaces (protected from re-erosion)
CFC target (90,000 monoblocks): 50 m2 215 m2
W baffle & dome (1.2M rods): 100 m2 460 m2
Be main wall (300,000 tiles): 680 m2 1290 m2
ITER mock-up
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EU Plasma-Wall Interactions Task ForcePotential for significant T inventory
TZM castellated monoblocks exposed to plasma for 200s in TEXTOR
D retention fall-off dependent on D and Ttile
Dgap ~ 0.4% - 4% of D, between low and high D at Ttile ~200- 260C
Factor 10 decrease in Dgap, 30 Ttile 200C
• Extrapolation to ITER based on D from B2-EIRENE modelling (Kukushkin, 2005): 0.5 – 5gT/400s shot
• Maybe other factors, however:
strong function of gap width carbon source (local or remote) period of exposure
TZM monoblocks from TEXTOR, 0.5mm gaps
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EU Plasma-Wall Interactions Task Force
Planar and imbricated castellated tungsten blocks exposed in TEXTOR
Co-deposition significantly reduced for imbricated blocks
Also of note -• Metal intermixing noted in deposits• Some deposits ‘buried’ under W layer
Shaped castellations may help
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EU Plasma-Wall Interactions Task Force
N11
ToreSupra:
• 75-85% D retention in short shots (<30s)
• Up to 100% D retention in long shots (>100s)
• Retention in short shots easily recovered by He glow
• Measurements of C erosion suggest co-deposition alone may not explain retention
more than 1 mechanism?
Retention in bulk CFC being considered for high fluence conditions
Lab studies indicate D retention to several m in bulk
D inventory fluence0.5
Calcs. suggest this may initially exceed co-deposition in Tore Supra
D/T retention in CFC bulk
could affect choice of CFC for ITER
• Flux and time dependence needs more study
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EU Plasma-Wall Interactions Task Force
• Tritium trapped in aC:D/T co-deposits • Oxidation an obvious candidate for detritiation through the reaction :
aC:D/T + O COx + DTO:D2O:T2O
• In-situ – no need for vessel entry
• Volatile products pumped from vessel
• Several schemes under investigation:
Baking in O2
ECR or ICR -wave plasma in O2 or He/O2 mix
DC Glow discharge cleaning in He/O2 mix
• Studies on-going in both laboratory and tokamak environments and both laboratory produced and tokamak co-deposited films
T-removal through oxidation
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EU Plasma-Wall Interactions Task Force
RF Antenna protection tile from TEXTOR180 m thick aC:D co-deposit
O2 baking efficient, but at high Twall
Molecular chemistry – O2 penetrates all regions of deposition but ….
• Low D removal efficiency below ~300C (cf ITER wall bakeout temp 240C)
• High O2 pressure needed for high removal efficiency
• Co-deposit not fully removed – becomes flaky and peels off
Inhibited O penetration and release of volatiles due to carbide formation with impurities? WC and BeC may form in ITER …
• O3/O2 mix effective at <200C and low pressure but damage to bulk CFC seems to be too high
800m
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EU Plasma-Wall Interactions Task ForceO-Plasma – effective at room temp
Erosion rate, E
• increases with Tsurf chemical reactions• and with bias volts collisions
2 step process: surface damage by ion bombardment then chemical erosion
ECR plasma in 100% O2
Products: CO, CO2, H2, H2O
He/O2 mixture:
• E limited by He ion flux at high %O2
E saturates above few %O2
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EU Plasma-Wall Interactions Task ForceHe/O GDC in the tokamak environment
• Three positions treated (with varying co-deposit thickness and tritiation)
• Tritium release monitored and tile sent for SIMS/IBA/SEM analysis
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EU Plasma-Wall Interactions Task Force1st demonstration of T-removal
• Total T release ~9g.
• Decreasing efficiency with number of pulses
• 40% of T inventory & 70-90 m co-deposit, removed (off gas & SEM)
0.075g T/h over 150m2
Untreated Treated
7m de-tritiation at surface of treated zone
Consistent with FE calcs of bulk heating above 700K
Build-up of Ni at surface explanation for roll-over of tritium release/pulse? (similar
results for Be on other treated tiles)
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EU Plasma-Wall Interactions Task ForceCould prevention be the best cure?
• Hot liner added to PSI-2 linear plasma device
• CH4/H2 added to H2 plasma column
Cold liner – CH4 decomposes to form co-deposted layers on liner walls
Hot liner – co-deposit re-eroded to form CH4, C2H2 and heavier species
- ~100% C pumped through duct or returned to main chamber
Relies on presence of sufficient atomic hydrogen (C2H2 production saturates at high CH4 flows)
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EU Plasma-Wall Interactions Task ForceThe year that was ….
Significant advances during 2005-6 but also growing recognition of new challenges -
Improvements in modelling of retention and co-deposition, including with beryllium fluxes
Importance of retention in gaps, castellations and bulk CFC now better understood and characterised
More machines prepared to run with oxidising plasmas but difficulties of shadowed regions, mixed materials and oxide formation now clear
Further studies into alternative chemistry (apart from oxygen)
Technological approaches continue to develop and first trials with tritiated samples
A growing understanding that ITER may require a combination of techniques to operate within the inventory limit
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EU Plasma-Wall Interactions Task Force
• No single T-removal scheme likely to be sufficient – let’s not close any doors
• Integration of different schemes on different timescales will probably be required – the ‘good housekeeping’ approach
Big ‘toolbox’ needed for ITER
Example of T-removal integrated into ITER operating schedule Extrapolated from predicted/measured T-removal rates allowing for future optimisation
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EU Plasma-Wall Interactions Task Force
Characterise the impact of Beryllium Carbide formation in ITER relevant conditions
CFC bulk retention – is it real? Need for confirmation of the effect and improved characterisation (impact of surface temperature, morphology etc.)
Tile gaps – how does deposition in gaps scale the ITER? Resolve issue of shadowing on plasma removal schemes (e.g. how many wall collisions can the chemically ‘active’ atoms survive)
Demonstrate impact of repetitive oxidising plasmas and plasma recovery on Beryllium surfaces
Explore further the impact of surface temperature on deposition in ITER relevant conditions
Begin to develop a serious scheme for operating ITER with a CFC/Be/Wmaterials mix in the DT phase
Start to characterise retention in an all metal ITER – is it a problem or not?
Key issues for the near future
How can the EU-PWIand the SEWG help?
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Not a comprehensive list! -
G Counsell et al 33rd EPS, 11th PFMCD Borodin et al 11th PFMCP Coad et al 17th PSIJ Ferreira et al 11th PFMCC Grisolia, et al 24th SOFT, 17th PSIC Hopf, et al 17th PSIW Jacob, et al 17th PSIA Kirschner, et al 17th PSIA Kreter, et al 17th PSIK Krieger, et al 17th PSIJ. Likonen, et al 17th PSIA. Litnovsky, et al 11th PFMCA Markin, et al 11th PFMCV Philipps, et al 17th PSIJ Roth, et al 17th PSIM Rubel, et al 17th PSI, 21st IAEAE Salancon, et al 17th PSIA. Semerok, et al 21st IAEAFL Tabares et al 17th PSI, 21st IAEAC. Tomastik, et al 11th PFMCA Widdowson, et al 17th PSI