Chin-Kai Meng Agilent Technologies, Inc. 2850 Centerville Road Wilmington, DE 19808-1610 USA (ESI) (APCI) (APPI) / ( ) ( ) ESI APPI APCI APCI APPI ESI (S/N) ESI APCI APPI S/N APPI ESI- APPI- APCI/MSD / (GC/MS) UV (API) / (LC/MS) LC/MS (DAD) LC/MS 3 API (ESI) (APCI) [1] (APPI) [2] ESI APCI APPI APCI APPI / 10.6 eV
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ESI- APPI- APCI/MSD · 3 2. 7 ESI APCI APPI Zorbax Eclipse XDB-C8, 4.6 x 50 mm, 3.5 µm ( 935967-906) 30°C 30°C 30°C 1 mL/min 1 mL/min 1 mL/min A , 0.1% B 0.1% 40µL/min
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Chin-Kai Meng
Agilent Technologies, Inc.
2850 Centerville Road
Wilmington, DE 19808-1610
USA
(ESI) (APCI)
(APPI) /
( ) ( ) ESI APPI
APCI
APCI APPI ESI (S/N)
ESI
APCI APPI S/N APPI
ESI- APPI- APCI/MSD
/ (GC/MS)
UV
(API) /
(LC/MS)
LC/MS (DAD)
LC/MS
3 API
(ESI) (APCI) [1]
(APPI) [2] ESI
APCI APPI
APCI
APPI / 10.6 eV
10 ppm (ng/µL)
AccuStandard (New Haven, CT)
1 2
2 G1946D LC/MSD
ESI APCI/APPI 1
LC/MS
2
1. 12
(Aminocarb)
(Chlorpropham)
(Oxamyl) (Propham) (Propoxur) (Swep)
(Methiocarb)(Methomyl)
(Mexacarbate)
(Barban) (Carbaryl) (Carbofuran)
3
2. 7
ESI APCI APPI
Zorbax Eclipse XDB-C8, 4.6 x 50 mm, 3.5 µm ( 935967-906)
30°C 30°C 30°C
1 mL/min 1 mL/min 1 mL/min
A , 0.1%
B 0.1%
40µL/min
B: 0 min10%, 4 min 30%, B: 0 min 30%, 4 min 40%, 13 min 70%, 16 min 80% 16 min 80%