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Dr Stephen P Etheridge Dr Stephen P Etheridge CETESB CETESB Energy From Biogas Energy From Biogas April 23 April 23 rd rd – 24 – 24 th th 2003 2003 Biogas Applications Biogas Applications Environmental Biotechnology Limited Environmental Biotechnology Limited
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Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Feb 12, 2020

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Page 1: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Dr Stephen P EtheridgeDr Stephen P Etheridge

CETESBCETESBEnergy From BiogasEnergy From BiogasApril 23April 23rdrd – 24 – 24thth 2003 2003

Biogas ApplicationsBiogas Applications

Environmental Biotechnology LimitedEnvironmental Biotechnology Limited

Page 2: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Climate ChangeClimate Change

!! Climate is changingClimate is changing

!! Not everyone agrees it is a result ofNot everyone agrees it is a result of

human activityhuman activity

!! Carbon reserves being rapidly releasedCarbon reserves being rapidly released

into the atmosphereinto the atmosphere

Page 3: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Different countries releaseDifferent countries releasedifferent amounts….different amounts….

0 2000 4000 6000 8000 10000 12000

B ras il

C hina

F ranc e

UK

G erm any

Aus tra lia

C anada

US A

C on sum ptio n p er p erson , kg coal eq u ivavlen t

Page 4: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Kyoto ProtocolKyoto Protocol

!! 10% reduction on 1990 levels10% reduction on 1990 levels

!! Can mean >30% reduction on currentCan mean >30% reduction on currentlevels in some caseslevels in some cases

!! CDM importantCDM important

!! Not all non Appendix 1 countries agreeNot all non Appendix 1 countries agreewith tradingwith trading

!! Value of credits?Value of credits?

Page 5: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Mitigation and EnergyMitigation and Energy

Credits

Investment

21

1

Page 6: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Designers ResponsibilitiesDesigners Responsibilities

!! Understand the processUnderstand the process

!! Learn from mistakesLearn from mistakes

!! Know the wasteKnow the waste

!! UK has bitter experienceUK has bitter experience

Page 7: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Anaerobic TreatmentAnaerobic Treatment

Waste + Heat (35Waste + Heat (35OO

C/55C/55OO

C)C)

Low COD Effluent +Low COD Effluent +

Biogas (65%CHBiogas (65%CH44 + 35% CO + 35% CO22))

Energy CostsEnergy Costs Larger ReactorsLarger Reactors

Slow Growing Bugs...Slow Growing Bugs...

No Sludge, COD to BiogasNo Sludge, COD to Biogas90 % COD

90 % COD

Removal

Removal

ENDOTHERMIC

ENDOTHERMIC

Page 8: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Life and Death of a MicrobeLife and Death of a Microbe

TimeTime

Mic

rob

ial G

row

thM

icro

bia

l Gro

wth

GrowthGrowth

PlateauPlateau

DeathDeath

Activated Sludge

Extended Aeration

Page 9: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Optimum DigestionOptimum DigestionTemperaturesTemperatures

TemperatureTemperature

Mic

rob

ial G

row

thM

icro

bia

l Gro

wth

PsychrophilicPsychrophilic

MesophilicMesophilic

ThermophilicThermophilic35-3735-37ooCC

5555ooCC

Cattle Manure SeedCattle Manure Seed

Page 10: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 11: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Simplified AD ProcessSimplified AD Process

Long Chain OrganicsLong Chain Organics

Volatile Fatty AcidsVolatile Fatty Acids

Methane + Carbon DioxideMethane + Carbon Dioxide

VFA TestVFA Test< 3,000 mg/l< 3,000 mg/l

Methane %Methane %

MethanogensMethanogens

AcetogensAcetogens

Page 12: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

What Wastes Can youWhat Wastes Can youTreat with AD?Treat with AD?

!! SewageSewage

!! Animal ManuresAnimal Manures

!! Industrial Effluents:Industrial Effluents:

!! Solid Wastes: MSW etcSolid Wastes: MSW etc

!! COD/N/P = 100/5/1COD/N/P = 100/5/1

Food IndustryFood Industry

Paper & PulpPaper & Pulp

IndustryIndustry

Chemical IndustryChemical Industry

PharmaceuticalPharmaceutical

WastesWastes

PetrochemicalPetrochemical

Steel Steel WastewastersWastewasters

{

Page 13: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Digester DesignDigester Design

howhow do we do werealise realise thethepotential ofpotential of

biogas?biogas?

Page 14: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Microbial GrowthMicrobial Growth

− =+

dSdt

kSXK Ss

S - substrate concentrationS - substrate concentrationX - mass of X - mass of microorganismsmicroorganismsk - maximum rate of substrate utilisationk - maximum rate of substrate utilisationKKss - half velocity coefficient - half velocity coefficient

MonodMonod Equation: Equation:

α α α α α α α α SubstrateSubstrate

α α α α α α α α BugsBugs

Page 15: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Digester DesignsDigester Designs

Page 16: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Biomass RetentionBiomass Retention

QV

HRT =

e

r

SS

SRT =

HRT - Hydraulic Retention TimeHRT - Hydraulic Retention TimeV - VolumeV - VolumeQ - Flow RateQ - Flow Rate

SRT - Solids Retention TimeSRT - Solids Retention TimeSr - Solids in ReactorSr - Solids in ReactorSe - Solids in EffluentSe - Solids in Effluent

Page 17: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Hydraulic LimitationsHydraulic Limitations

HRT (days)HRT (days)55

WA

SH

OU

T

Page 18: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Digester Performance CurveDigester Performance Curve

00

2020

4040

6060

8080

100100

00 55 1010 1515 2020 2525 3030

COD Organic Loading Rate (Kg COD/m3/d)COD Organic Loading Rate (Kg COD/m3/d)

CO

D R

emo

val (

%)

CO

D R

emo

val (

%)

CSTRCSTR

Anaerobic FilterAnaerobic Filter

UASBUASB

Expanded BedExpanded Bed

Lab TrialsLab Trials

Page 19: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Laboratory EvaluationLaboratory Evaluation

Page 20: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Laboratory EvaluationLaboratory Evaluation

Page 21: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Define the Problem…Define the Problem…Waste Audit - Waste Audit - Site StudySite Study

!! Stream IdentificationStream Identification

!! Effluent AnalysisEffluent Analysis

!! SamplingSampling

!! Select the Right ProcessSelect the Right Process

!! Flow ProportionalFlow Proportional

!! Time ProportionalTime Proportional

!! SpotSpot

!! VerificationVerification

Page 22: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Confectionery PlantConfectionery Plant

Page 23: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Flexible Liner DigestionFlexible Liner DigestionSystemsSystems

Page 24: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Flexible Liner DigestionFlexible Liner DigestionSystemsSystems

Page 25: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 26: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 27: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 28: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Upflow Anaerobic SludgeUpflow Anaerobic SludgeBlanket (UASB)Blanket (UASB)

Page 29: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Upflow Anaerobic Sludge Blanket (UASB)

Page 30: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

IC ReactorIC Reactor

Page 31: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

ExpandedExpandedBedBedDigesterDigester

Page 32: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

CASE STUDY:CASE STUDY:Brewery and Soft DrinksBrewery and Soft DrinksEffluentEffluent

!! ProblemProblem!! Failed effluent treatment plantFailed effluent treatment plant!! Pressure from Water Company to reducePressure from Water Company to reduce

COD/SSCOD/SS!! Very high Very high MogdenMogden charges charges!! High variation in flow, COD, SSHigh variation in flow, COD, SS

!! Due toDue to!! Plant corrosionPlant corrosion!! Poor designPoor design!! Poor waste auditPoor waste audit

Page 33: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Hall &Hall &WoodhouseWoodhouseLimitedLimited

Page 34: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Hall &Hall &WoodhouseWoodhouse

LimitedLimited

Page 35: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 36: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

CASE STUDY:CASE STUDY:Brewery and Soft DrinksBrewery and Soft DrinksEffluentEffluent!! SolutionSolution

!! Comprehensive waste audit (client owned)Comprehensive waste audit (client owned)!! Feasibility studyFeasibility study

!! sewer or riversewer or river!! aerobic or anaerobicaerobic or anaerobic!! new technologies/grantsnew technologies/grants

!! New treatment plantNew treatment plant!! Novel heating and mixing systemNovel heating and mixing system!! THERMIE GrantTHERMIE Grant!! EBL design & project managementEBL design & project management!! Client direct purchase of all equipmentClient direct purchase of all equipment

Page 37: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 38: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Brewery EffluentBrewery Effluent

!! 3,300 m3 insulated Tank3,300 m3 insulated Tank

!! 600-700 m3/d, COD = 3,000-6,000 mg/l600-700 m3/d, COD = 3,000-6,000 mg/l

!! >98%COD Removal>98%COD Removal

!! Variable Volume Reactor (Monday = 1,800Variable Volume Reactor (Monday = 1,800

m3, Friday = 3,300mm3, Friday = 3,300m33))

!! Stirred Tank ReactorStirred Tank Reactor

!! Heated with Submerged CombustionHeated with Submerged Combustion

!! VenturiVenturi Mixing Mixing

Page 39: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 40: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Submerged CombustionSubmerged Combustion

SubmergedSubmergedCombustionCombustion

60-75%60-75%

25-40%25-40%

waste heatwaste heathot waterhot water

Boiler UseBoiler Use

99%99%

Page 41: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Submerged CombustionSubmerged Combustion

Air

B iogas

D igester

Exhaust

VenturiVenturi

Page 42: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Venturi Mixing SystemVenturi Mixing System

Page 43: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 44: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 45: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Hall & Woodhouse LimitedHall & Woodhouse Limited

Page 46: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

CASE STUDY:CASE STUDY:Textile Industry EffluentTextile Industry Effluent

!! Mill on Site for more than 190 Years (PartMill on Site for more than 190 Years (Part

of of AxminsterAxminster Carpet Group) Carpet Group)

!! 140 Staff140 Staff

!! 2,900 tonnes Wool processed2,900 tonnes Wool processed

!! 2,000 tonnes Spun Yarn produced2,000 tonnes Spun Yarn produced

!! Lanolin wool grease and sheep dipLanolin wool grease and sheep dip

pesticides in the fleecespesticides in the fleeces

Page 47: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

BuckfastBuckfast Spinning Limited Spinning Limited

!! BuckfastBuckfast Spinning has operated a Spinning has operated a

flocculation effluent treatment process forflocculation effluent treatment process for

25 years25 years

!! Wool scouring and dyeing effluentsWool scouring and dyeing effluents

combined to give overall discharge CODcombined to give overall discharge COD

of 4,000 mg/lof 4,000 mg/l

Page 48: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Effluent CharacteristicsEffluent Characteristics

!! High COD (3,500 mg/l)High COD (3,500 mg/l)

!! Flow 420 mFlow 420 m33/d/d

!! pH 6 - 8pH 6 - 8

!! High Temperature Effluent (25-40ºC)High Temperature Effluent (25-40ºC)

!! Trace Organophosphate PesticidesTrace Organophosphate Pesticides

!! ColourColour

!! Grease, Dirt, Sweat Salts, Trace Sheep Dip,Grease, Dirt, Sweat Salts, Trace Sheep Dip,Oils, Dyes, DetergentsOils, Dyes, Detergents

Page 49: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

!! Effluent stored in Holding TanksEffluent stored in Holding Tanks

!! PretreatmentPretreatment by Acid Cracking/Flocculation by Acid Cracking/Flocculation

!! Effluent is Centrifuged and ResultingEffluent is Centrifuged and Resulting

Sludge is Sludge is LandfilledLandfilled

!! Final Effluent is Discharged to SewerFinal Effluent is Discharged to Sewer

!! COD and SS MonitoredCOD and SS Monitored

!! 70% of COD is removed by 70% of COD is removed by PretreatmentPretreatment

Pre-treatment of EffluentPre-treatment of Effluent

Page 50: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

ProblemsProblems

!! £311,000 for Discharge of Effluent to Sewer in£311,000 for Discharge of Effluent to Sewer in

1997 (23% increase in last two years)1997 (23% increase in last two years)

!! £113,000 for on- site Effluent Treatment in£113,000 for on- site Effluent Treatment in

1997(excl. maintenance & parts)1997(excl. maintenance & parts)

!! Pesticide Emissions at least < 8.0 ppbPesticide Emissions at least < 8.0 ppb

!! Future Direct Toxicity AssessmentFuture Direct Toxicity Assessment

!! Sensitive LocationSensitive Location

Page 51: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Pilot PlantPilot Plant

!! Two 50mTwo 50m33 Reactors Reactors

!! De-gas Tank prior to DischargeDe-gas Tank prior to Discharge

!! Flare/Boiler for Biogas HandlingFlare/Boiler for Biogas Handling

!! pH ControlpH Control

!! Gas Compressor for MixingGas Compressor for Mixing

Page 52: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Pilot PlantPilot Plant

Page 53: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Pilot PlantPilot Plant

Page 54: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Pilot PlantPilot Plant

Page 55: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Status and ObjectivesStatus and Objectives

!! Biotechnology is the key to eliminating andBiotechnology is the key to eliminating anddegrading potentially harmful effluentdegrading potentially harmful effluent

!! Future ObjectivesFuture Objectives

-- Demonstrate successful Treatment of Demonstrate successful Treatment of Textile Effluent by Anaerobic DigestionTextile Effluent by Anaerobic Digestion

-- COD Removal (>50%)COD Removal (>50%)

-- Degradation of Toxic Organics and Degradation of Toxic Organics and Pesticide (40-80%)Pesticide (40-80%)

-- Colour ReductionColour Reduction

Page 56: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

CASE STUDY:CASE STUDY:Cassava Processing in AsiaCassava Processing in Asia

!! ProblemProblem!! 6000m3/d effluent 6000m3/d effluent discahrgeddiscahrged to 72 open to 72 open

lagoonslagoons!! Massive methane emissions to atmosphereMassive methane emissions to atmosphere!! No energy captureNo energy capture

!! SolutionSolution!! New Flexible Liner DigesterNew Flexible Liner Digester!! Third Party design, install, own operateThird Party design, install, own operate!! Natural Gas to run plantNatural Gas to run plant!! Excess electricity to GridExcess electricity to Grid

Page 57: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Cassava Deliveryand washing

Digester Volume = 100,000m3

Page 58: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Washing and Processing

Page 59: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Pretreatment

Page 60: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 61: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Flexible LinerDigester

Page 62: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Digester Volume = 100,000m3

Page 63: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

150 150 °°CC

3 hours3 hours 4 bar4 bar

pH14pH14

Alkaline HydrolysisAlkaline Hydrolysis

Page 64: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

WRE SystemWRE System

Page 65: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

! 20 years experience in Europe

! Well understood & proven in Denmark, Scandinavia & Germany

! 7 out of 20 biogas plants in Denmark take sewage sludge (1999)

! Track record of no disease spread (human or animal)

! Final Product is integrated into European “composting”

networks

! Used to solve variety of waste management and public

acceptance issues (e.g. Energy from Waste, landfill emissions,

poor use of CHP, odours from spreading raw slurry, disposal of

sewage sludge, food supply chain quality assurance)

Centralised Digesters

Page 66: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Hashøj Biogas Plant (DK) - 140 tonnes/day – startedoperation 1994 (also takes Isopropanol & MSW finesfrom Copenhagen)

Page 67: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

! Digester 3000m3 operated at 37C

! 10 pig farms + 6 cattle farms feed 100t/d manure (onevacuum tanker)

! Industrial and other waste (abattoir, grease traps, fishprocessors etc.) 38t/d

! Pasteurisation at 70C (sterilised returned effluent)

! 2,200m3 gas storage

! Owned by cooperative, 17 members all stakeholders

! Electricity and hot water to two communities (38% ofneeds)

Hashøj Biogas Plant (1994)

Page 68: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

KristianstadKristianstad Biogas Plant (S) - 200 tonnes/day Biogas Plant (S) - 200 tonnes/day - started operation 1996 - started operation 1996(takes source separated kitchen wastes, manures)(takes source separated kitchen wastes, manures)

Page 69: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

LoickLoick Digester Digester

Page 70: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

! Digester 970m3 operated at 38C

! 35t/d @ 14% TS biomass from 700pigs, greasetraps, food processing wastes, corn and ryesilage

! 25-30 days HRT with 75% organic removalefficiency

! 2,640m3/d biogas to 249kWe CHP

Loick Digester (2001)

Page 71: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 72: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Witte Digester (1998)

Page 73: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

! Digester 1206m3 operated at 42C

! 16t/d @ 20% TS biomass from 80 cows, 1,100 turkeys,food processing wastes, fat , grease traps, vegetables

! 60 days HRT

! 2,000m3/d biogas to 3 x 110kWe CHP sets

! US$ 600,000 cost with 25% grant

! Revenue is US$12,000/month electric and US$1,000fertiliser sales

! 7 year payback quoted

Witte Digester (1998)

Page 74: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Holsworthy Plant, DevonHolsworthy Plant, Devon

Page 75: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

Page 76: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 77: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark
Page 78: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

• 146,000 tonne/y of cattle, pig & poultry manure and foodwaste

• Manure from 30 farmers within approx. 5 miles radius

• Pasteurisation at 70°C for one hour

• Digestion (37°C) for 20 days HRT

• Gas production: 6 million m3 biogas (equivalent to 39mkWh)

• CHP provides on-site heat for treatment requirements

• Continual N, P & K monitoring for bio-fertiliser taken tosupplying farmers

Holsworthy Biogas CompanyHolsworthy Biogas Company

Page 79: Environmental Biotechnology Limited · 2014-05-24 · !20 years experience in Europe! Well understood & proven in Denmark, Scandinavia & Germany! 7 out of 20 biogas plants in Denmark

1 2 3

21

3

21

Heat exchangers

Pasteurisation tanks

Receivingtank

Mixingtank

hotwatertank

Gas engines

manure& waste

to farmersbio-fertilizer

2002 / 2003planned from

District heating

to the gridElectricity

HOLSWORTHY BIOGAS - Flow sheet

Storagetank unit

Desulphurisation

17.10.2001, Geb.

21

Digesters

substratehot watercold waterbiogas

legend:

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Reception HallReception Hall

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!! Totally enclosed (& pressurised) system afterTotally enclosed (& pressurised) system after

unloadingunloading

!! Only manually controlled at point of ‘reception pit’ toOnly manually controlled at point of ‘reception pit’ to

ensure right mixture goes into ‘mixing tank’ viaensure right mixture goes into ‘mixing tank’ via

chopper pumpschopper pumps

!! Automatic return (re-start) if parameters ofAutomatic return (re-start) if parameters of

‘pasteurisation unit’ not reached‘pasteurisation unit’ not reached

!! Farmers usually operate 3 week no grazing systemFarmers usually operate 3 week no grazing system

!! Constant MonitoringConstant Monitoring

The ProcessThe Process

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Tankered EffluentTankered Effluent

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!! Complexity of legislation increasingComplexity of legislation increasing!! Limited understanding by Regulators of relativelyLimited understanding by Regulators of relatively

new conceptnew concept!! Increasing requirements for involvement withIncreasing requirements for involvement with

farmers and monitoring of spreading practicesfarmers and monitoring of spreading practices!! UK has narrow focus on “composting” industry –UK has narrow focus on “composting” industry –

poor awarenesspoor awareness!! Physical contamination problems when using sourcePhysical contamination problems when using source

separated kitchen wastes (MSW)separated kitchen wastes (MSW)!! Classification of what is a “waste” and when does itClassification of what is a “waste” and when does it

become a productbecome a product

Barriers to Co-Digestion inBarriers to Co-Digestion inthe UKthe UK

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Feasibility Study Funded by the UK Foreign &Commonwealth Office (FCO)! Waste Study! Site Review

- Characterisation of Benefits- Collection- Impact on Local Community

! Design Options! Selection, Costing and Funding

CASE STUDY: CASE STUDY: BaguioBaguio

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IrisanIrisan Dumpsite Dumpsite

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Waste Sampling

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Waste CharacteristicsWaste Characteristics

Waste Category White Truck(kg) Yellow Truck (kg)Paper 37 146Plastic 53 479Rubber/Leather 0 0Vegetable/Organic Waste 4,564 1,193Food Waste 0 0Glass 14 2Metal/Tin Cans 8 12Textile 4 0Inert 0 0Wood 16 435Special Waste/Fish & Meat Waste 0 20Total 4,696 2,287Bulk Density 470 kg/m3 229 kg/m3

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Low Solids Digester Option

Effluent120m /d

3

Flare

Solids 10.7t/d

3m /d UnthickenedSewage Sludge

+117m /d Sewage

3

3

20m 3

Feed Tank

1500m3

Digester

B iogas1960m /d

3

SolidsSeparator

25t/d W etMarket Waste

CHP

160kW e

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High Solids Digester Option

CHP

Effluent15m /d

3

F lare

Solids 10.7t/d

1.2m /d ThickenedSewage S ludge

3

550m3

D igester

B iogas1960m /d

3

SolidsSeparator

25t/d W etMarket Waste

10m /d Recycle Liquor3

160kW e

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Two Stage Digester Option

100m3

S torage Tank

Solids 10.7t/d

Flare

1.2m /d ThickenedSewage S ludge

1,100m3

Total BatchReactor Volume

Biogas1960m /d

3

4 Concrete vessels or 20 Cargo Containers

CHP160kW e

25t/d W etMarket Waste

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Oxidation D

itches

Ba lili R

ive r

InfluentPipe

Grit Chambers

PrimarySettlement

Tank

S ludge

Thickeners

F inalSedimen

-tation

Tanks

ControlRoom

M SW Digestion Area

New B ridgeand Roadway

Squatter Area

Site RoadBalili R iver

M a in E n trance to S ite

Hand Pick

Line

RejectsIncoming waste

Waste for D igestion

Static P ile Com postingSite for Phase 2Development?

1,500m d igester fo r Low Solids Option3

550m digester for H igh Solids Option3

220m digester for Two Stage Option3

Batch D igesters(8m x 17m x 2m deep) S

ite R

oad

Mai

n R

oad

CHP Unit and Control Room

Location atLocation atBaguioBaguio STW STW

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Composting DigComposting Digesestatetate

A ir

M a tu re C om post

D igesta te and Bu lk in g Ag en t

A era tion P ipew o rkB low e rC o nd en sa te

Trap

F ilte r fromM atu re

C o m post

E xhaust A ir

R o ofed S lu dge D ry ing A re a

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Process CharacteristicsProcess Characteristics

Characteristic ValueBaguio Wet Market Waste 14 t/dLa Trinidad Wet Market Waste 11 t/dTotal 25 t/dAssumed average Bulk Density 470 kg/m3Volume of waste per day 53.2m3Average Total Solids 26%Average Volatile Solids 64%Total Volatile Solids 16.64%Projected Biogas Potential (at 65% CH4) 1955m3/dElectrical Energy 160 kWeSolid Digestate at 60% solids recovery 3,900t/yCompost including bulking agent 7,800t/y

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Process EconomicsProcess Economics

PhP (million) £'000Revenues- Tipping Fee 3.47 50- Electricity 4.42 63- Compost 8.18 117

16.07 230Operating Costs 10.72 153Revenue 5.3 230Total Project Costs 42.11 601

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BaguioBaguio Project Development Project Development

Phase 1 : 25t/d Wet Market WastePhase 1 : 25t/d Wet Market Waste

Phase 2 : + 70t/d 50% Baguio MSWPhase 2 : + 70t/d 50% Baguio MSW

Phase 3 : +70t/d 50% Baguio MSWPhase 3 : +70t/d 50% Baguio MSW

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MSW TreatmentMSW Treatment

MixedWaste Separation Composting

RecycledMaterial

Anaerobic

Digestion

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Akras Herb & Essence WasteAkras Herb & Essence Waste

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Anaerobic Digestion of HighAnaerobic Digestion of HighSolids WastesSolids Wastes

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Anaerobic Digestion of MSWAnaerobic Digestion of MSW

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Overview of renewables supportmeasures to date

! NFFO introduced in 1990 Electricity Act

! 5 Orders (& 3 in Scotland, 2 in NI)

! over 3600 MW contracted

! only 950 MW built so far

! low prices

! long period of consultation

! Start of Renewables Obligation

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NFFO – non fossil fuel obligation

• Competitive tendering for banker-friendly

contracts

• Bankers became familiar with renewables

and NFFO contracts

• Supported range of technologies

• kick started industry & brought prices down

• but commissioning very slow

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NFFO (1 - 3) and ADNFFO (1 - 3) and AD

!! NFFO1NFFO1

!! 3 contracts awarded for AD projects (NI3 contracts awarded for AD projects (NISG) All commissioned.SG) All commissioned.

!! 0.88 MW, Heathfield, Devon0.88 MW, Heathfield, Devon

!! 0.17 MW, Ham Sewage Treatment Works,0.17 MW, Ham Sewage Treatment Works,SomersetSomerset

!! 3MW, Avonmouth Sewage Treatment Works,3MW, Avonmouth Sewage Treatment Works,AvonAvon

!! NFFO2 & 3 No ADNFFO2 & 3 No AD

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!! NFFO4, 6 contracts awarded for AD projectsNFFO4, 6 contracts awarded for AD projects

Status as of April 2002Status as of April 2002!! LRZ LtdLRZ Ltd

!! Eye AirfieldEye Airfield 1.051.05 No PA madeNo PA made

!! AGTEC LtdAGTEC Ltd

!! Spalford ADS, LincsSpalford ADS, Lincs 11 No PA madeNo PA made

!! Whitchurch Hydro ADS, ShropshireWhitchurch Hydro ADS, Shropshire 22 No PA madeNo PA made

!! Hydro Leeming AD, N. YorkshireHydro Leeming AD, N. Yorkshire 0.50.5 PA approvedPA approved

!! Hydro Seamer ADS, N YorkshireHydro Seamer ADS, N Yorkshire 0.60.6 No PA madeNo PA made

!! Holsworthy Biogas CompanyHolsworthy Biogas Company

!! Holdsworthy, DevonHoldsworthy, Devon 1.431.43 CommissionedCommissioned

!! NFFO5 AD not eligible to enterNFFO5 AD not eligible to enter

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Which RE sources are eligible?Which RE sources are eligible?

!! All non thermal RE sources (excluding hydro >20MW)All non thermal RE sources (excluding hydro >20MW)

!! Various restrictions on BiomassVarious restrictions on Biomass

!! Where MSW is a fuel only gasification, pyrolysis or ADWhere MSW is a fuel only gasification, pyrolysis or AD

technology qualifies.technology qualifies.

!! With exception of certain hydro projects, nothing builtWith exception of certain hydro projects, nothing built

before 1990, unless refurbishedbefore 1990, unless refurbished

!! If it has a NFFO contract which was not terminatedIf it has a NFFO contract which was not terminated

properlyproperly

!! AD in - (provided OK re. bullet points 4 & 5)AD in - (provided OK re. bullet points 4 & 5)

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Biogas incentives in GermanyBiogas incentives in Germany

!! German Renewable Energy Act (1.4.2000) German Renewable Energy Act (1.4.2000)

!! Electricity 20 year min price Electricity 20 year min price

!! 30% capital refund after construction (grant) 30% capital refund after construction (grant)

!! Long term soft loan Long term soft loan

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Biogas incentives in GermanyBiogas incentives in Germany

!! 150 developers and installers of new systems 150 developers and installers of new systems

!! 1000 new plants installed 1000 new plants installed

!! > 2000 new jobs > 2000 new jobs

!! now stopped… now stopped…

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GermanyGermany

BiogasBiogasDevelopmentDevelopment

02 0 04 0 06 0 08 0 0

1 0 0 01 2 0 01 4 0 01 6 0 01 8 0 0

19921993

19941995

19961997

19981999

20002001

No

. P

lan

ts I

nst

alle

d

0

2 0

4 0

6 0

8 0

1 0 0

1 2 0

1 4 0

1 6 0

Inst

alle

d C

apac

ity

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Biogas incentives in GermanyBiogas incentives in Germany

8.48.48.58.6Up to 20 MWe

8.88.99.09.1Up to 5 MWe

9.89.910.010.1Up to 500 kWe

2005200420032002

Compensation in Cent including 1% annual reduction

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ConclusionsConclusions

!! Technology available and developingTechnology available and developing

!! Poor Poor implementionimplemention – lack of understanding – lack of understanding

!! Needs careful Needs careful incentivisationincentivisation

!! Barriers – public perception, scale, costBarriers – public perception, scale, cost

!! Developments – new forms of ownership, projectDevelopments – new forms of ownership, projectdevelopment and operationdevelopment and operation

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The EndThe End