Gubkin Russian State University of Oil and Gas SPE 102060 Emerging Petroleum-Oriented Nanotechnologies for Reservoir Engineering I.N. Evdokimov, N.Yu. Eliseev, A.P. Losev, M.A. Novikov
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Gubkin Russian State University of Oil and Gas
SPE 102060
Emerging Petroleum-Oriented Nanotechnologies for Reservoir Engineering
IN Evdokimov NYu Eliseev AP Losev MA Novikov
laquoBusinessmen should understand that in case they do not go into nanotechnologies today
they will miss everythingand in the best case they will
work in dirty robes at oil well-sites which will be managed by our foreign friends
and partnersraquo
15 December 2005 гRussiarsquos Council of Ministers
Prime Minister M FRADKOV
Discussions ofNANOTECHNOLOGIES
are frequently based
on persistentldquonanomythsrdquo
and on widespreadmisinterpretations
1966 гPopular Movie
laquo Fantastic Voyage raquo
after the novel
by I Asimov
NANOSUBMARINE
1986 гK Eric Drexler
laquo Engines of Creation The Coming Era of
Nanotechnology raquo
NANOBOT
Image from wwwthelensflarecomgalleryp_nanobot3_260php
laquoNANOBOTSPATROL THE PORES
OF OILRESERVOIRraquo
Website Wiredcom
Bhat S Singh P (2006)ldquoUse of Nanorobots in Oil Industryrdquo SPE Mumbai Section Maharashtra Inst Technol
Sakhawat S (2004)ldquoSurfactants-Nanorobots in EORrdquoProc Reg Symp Chem Eng Bangkok Thailand
IndustrialNanotechnologies
laquo Dry raquo
MolecularNanotechnologies (MNT)
Forced Assembly
laquo Wet raquo
SupramolecularChemistry (SMC)
Self-Assembly
MNT - Forced Assembly
ScanningTunnelingMicroscope
MechanicalManipulator
C12E5
OilWater
SMC - NANOPHASES
in a Self-Assembling System
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
laquoBusinessmen should understand that in case they do not go into nanotechnologies today
they will miss everythingand in the best case they will
work in dirty robes at oil well-sites which will be managed by our foreign friends
and partnersraquo
15 December 2005 гRussiarsquos Council of Ministers
Prime Minister M FRADKOV
Discussions ofNANOTECHNOLOGIES
are frequently based
on persistentldquonanomythsrdquo
and on widespreadmisinterpretations
1966 гPopular Movie
laquo Fantastic Voyage raquo
after the novel
by I Asimov
NANOSUBMARINE
1986 гK Eric Drexler
laquo Engines of Creation The Coming Era of
Nanotechnology raquo
NANOBOT
Image from wwwthelensflarecomgalleryp_nanobot3_260php
laquoNANOBOTSPATROL THE PORES
OF OILRESERVOIRraquo
Website Wiredcom
Bhat S Singh P (2006)ldquoUse of Nanorobots in Oil Industryrdquo SPE Mumbai Section Maharashtra Inst Technol
Sakhawat S (2004)ldquoSurfactants-Nanorobots in EORrdquoProc Reg Symp Chem Eng Bangkok Thailand
IndustrialNanotechnologies
laquo Dry raquo
MolecularNanotechnologies (MNT)
Forced Assembly
laquo Wet raquo
SupramolecularChemistry (SMC)
Self-Assembly
MNT - Forced Assembly
ScanningTunnelingMicroscope
MechanicalManipulator
C12E5
OilWater
SMC - NANOPHASES
in a Self-Assembling System
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Discussions ofNANOTECHNOLOGIES
are frequently based
on persistentldquonanomythsrdquo
and on widespreadmisinterpretations
1966 гPopular Movie
laquo Fantastic Voyage raquo
after the novel
by I Asimov
NANOSUBMARINE
1986 гK Eric Drexler
laquo Engines of Creation The Coming Era of
Nanotechnology raquo
NANOBOT
Image from wwwthelensflarecomgalleryp_nanobot3_260php
laquoNANOBOTSPATROL THE PORES
OF OILRESERVOIRraquo
Website Wiredcom
Bhat S Singh P (2006)ldquoUse of Nanorobots in Oil Industryrdquo SPE Mumbai Section Maharashtra Inst Technol
Sakhawat S (2004)ldquoSurfactants-Nanorobots in EORrdquoProc Reg Symp Chem Eng Bangkok Thailand
IndustrialNanotechnologies
laquo Dry raquo
MolecularNanotechnologies (MNT)
Forced Assembly
laquo Wet raquo
SupramolecularChemistry (SMC)
Self-Assembly
MNT - Forced Assembly
ScanningTunnelingMicroscope
MechanicalManipulator
C12E5
OilWater
SMC - NANOPHASES
in a Self-Assembling System
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
1966 гPopular Movie
laquo Fantastic Voyage raquo
after the novel
by I Asimov
NANOSUBMARINE
1986 гK Eric Drexler
laquo Engines of Creation The Coming Era of
Nanotechnology raquo
NANOBOT
Image from wwwthelensflarecomgalleryp_nanobot3_260php
laquoNANOBOTSPATROL THE PORES
OF OILRESERVOIRraquo
Website Wiredcom
Bhat S Singh P (2006)ldquoUse of Nanorobots in Oil Industryrdquo SPE Mumbai Section Maharashtra Inst Technol
Sakhawat S (2004)ldquoSurfactants-Nanorobots in EORrdquoProc Reg Symp Chem Eng Bangkok Thailand
IndustrialNanotechnologies
laquo Dry raquo
MolecularNanotechnologies (MNT)
Forced Assembly
laquo Wet raquo
SupramolecularChemistry (SMC)
Self-Assembly
MNT - Forced Assembly
ScanningTunnelingMicroscope
MechanicalManipulator
C12E5
OilWater
SMC - NANOPHASES
in a Self-Assembling System
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
1986 гK Eric Drexler
laquo Engines of Creation The Coming Era of
Nanotechnology raquo
NANOBOT
Image from wwwthelensflarecomgalleryp_nanobot3_260php
laquoNANOBOTSPATROL THE PORES
OF OILRESERVOIRraquo
Website Wiredcom
Bhat S Singh P (2006)ldquoUse of Nanorobots in Oil Industryrdquo SPE Mumbai Section Maharashtra Inst Technol
Sakhawat S (2004)ldquoSurfactants-Nanorobots in EORrdquoProc Reg Symp Chem Eng Bangkok Thailand
IndustrialNanotechnologies
laquo Dry raquo
MolecularNanotechnologies (MNT)
Forced Assembly
laquo Wet raquo
SupramolecularChemistry (SMC)
Self-Assembly
MNT - Forced Assembly
ScanningTunnelingMicroscope
MechanicalManipulator
C12E5
OilWater
SMC - NANOPHASES
in a Self-Assembling System
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
laquoNANOBOTSPATROL THE PORES
OF OILRESERVOIRraquo
Website Wiredcom
Bhat S Singh P (2006)ldquoUse of Nanorobots in Oil Industryrdquo SPE Mumbai Section Maharashtra Inst Technol
Sakhawat S (2004)ldquoSurfactants-Nanorobots in EORrdquoProc Reg Symp Chem Eng Bangkok Thailand
IndustrialNanotechnologies
laquo Dry raquo
MolecularNanotechnologies (MNT)
Forced Assembly
laquo Wet raquo
SupramolecularChemistry (SMC)
Self-Assembly
MNT - Forced Assembly
ScanningTunnelingMicroscope
MechanicalManipulator
C12E5
OilWater
SMC - NANOPHASES
in a Self-Assembling System
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
IndustrialNanotechnologies
laquo Dry raquo
MolecularNanotechnologies (MNT)
Forced Assembly
laquo Wet raquo
SupramolecularChemistry (SMC)
Self-Assembly
MNT - Forced Assembly
ScanningTunnelingMicroscope
MechanicalManipulator
C12E5
OilWater
SMC - NANOPHASES
in a Self-Assembling System
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
MNT - Forced Assembly
ScanningTunnelingMicroscope
MechanicalManipulator
C12E5
OilWater
SMC - NANOPHASES
in a Self-Assembling System
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
C12E5
OilWater
SMC - NANOPHASES
in a Self-Assembling System
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Nanotechnologies for
Reservoir Engineering
laquo MNT raquo
Forced Assembly
laquo SMC raquo
Trigger
Self-Assembly
in a Nanosystem
ControlInitiate
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Content of С12Е5 1000
0
100Te
mpe
ratu
re ordmС
ККМ КР
T ndash C Diagram of Nanophase Boundaries in a Self-Assembling System
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
In this Presentation we Report the Resultsof Our Long-Term Research
and of Literature Analysis
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
THE MAIN CONCLUSIONS -Important properties
of native crudesare determined by
SELF-ASSEMBLINGNANOPHASES
Native crude oils arelaquo association nanofluids raquo
hence they are natural objects ofSMC NANOTECHNOLOGIES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Self-Assembling Constituents of Petroleum NANOPHASES
Asphaltenes naphthenic acids
resins waxes diamondoilds
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Images from Website FACT (Fouling and Coking Technology Inc)
The well-known phase transformation ndashprecipitation into a microscopic solid phase
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
We have constructedthe FIRST
T-C phase diagramfor NANOPHASES
of petroleum asphaltenessuspended in a fluid media
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
120
20 40 60 80 100
90
60
30
0
Asphaltene Content gL
Plas
tic V
isco
sity
mPaс
Identification of CONCENTRATION phase boundaries at the T-C diagram
Abrupt change
of measured
properties
at
a phase boundary
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
n
10 20 30
095
100
105
Temperature ordmС
τ = τk + KγnHerschelndashBulkley
Evdokimov I N Eliseev N Yu Eliseev D YuJournal of Petroleum Science and Engineering 30(3-4) 199-211 2001
Abrupt change
of measured
properties
at
a phase boundary
Identification of TEMPERATURE phase boundaries at the T-C diagram
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Т-С diagram of asphaltene nanophases
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Expected Skepticism
All these nice - lookinglaboratory exercises with ldquoNANOPHASESrdquo
have little relevance to honestindustrial reservoir fluidshellip
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Worldrsquos Crudes ViscosityEvdokimov I N Fuel 84(1) 13-28 2005
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Asphaltene Content gL001 01 1 10 100
095
Oil
Spec
ific
Gra
vity
22 3a3a
3b3b
44 55
090
085
080
100
Evdokimov I N Fuel 84(1) 13-28 2005
Worldrsquos Crudes Specific Gravity
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Asphaltene Content
Tem
pera
ture
ordmС
CrudesCrudes
CondensatesSolutions Crudes
Heavy fuels
Bitum
ensM
onom
ers
Olig
omer
s
Poly
amor
phic
nano
collo
ids
Solid
asp
halte
nes
MeltingDecomposition
А
В
С
1 23а
3b
4 5
1 10 100 10 1 100 1000 mgL gL
1
10
100
500
α
β
γ
Nanophase Diagram
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Asphaltene Content gL01 1 10 100
Oil
Spec
ific
Gra
vity
090
080
100
Limited Database (20 Worldrsquos Crudes)
3a3a 44
55
http tiggeruicedu ~mansoori AsphalteneDepositionandItsControl_html
22
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
EMERGINGPETROLEUM
NANOTECHNOLOGIES
First of all these are conventional technologies
for reservoir engineeringoptimized with an account for
nanophase diagramsof intrinsic petroleum nanocolloids
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Industrial Processesin the vicinity of
CONCENTRATION
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
favorable effect
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Asphaltene Content gL001 01 1 10 100
1
10
100
Oil
Visc
osity
сSt
22
3a3a3b3b
4455
Blending of Crudes -
unfavorable effect
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Industrial Processesin the vicinity of
TEMPERATURE
NANOPHASE boundaries
EMERGINGPETROLEUM NANOTECHNOLOGIES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
10 30 50 70
- 40
- 20
0
20
Pour
Poi
nt ordmС
Pre-treatment Temperature ordmС
Thermal treatment close to NANOPHASE boundary
Strong increase
of pour point
in a Tatarstancrude
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
30 40 20 Temperature ordmС
Dep
osite
d M
ass
Long-term
increase of
deposits
from
a Siberian crude
Thermal treatment close to NANOPHASE boundary
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
BOTTOM
TOP
20 30 35 25 40 Tempetrature ordmС
1460
1462
1464
Ref
ract
ive
Inde
x
Yuzhno-Tarasovskaja
crude
Room-temperatureldquodistillationrdquo
Thermal treatment close to NANOPHASE boundary
Gravitation ndashinduced
separation
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
(M-r JOURDAIN) Well what do youknow about that These forty years now Ive been speaking in prose withoutknowing it How grateful am I to you forteaching me that
Jean - Batist Moliere
laquoThe Bourgeois Gentlemanraquo
EXISTINGPETROLEUM NANOTECHNOLOGIES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Zhujko P VDEVELOPMENT OF METHODS FOR
CONTROLLING RHEOLOGICAL PROPERTIESOF ANOMALOUS CRUDES- thesis (Doctor Tech Sci)
Ukhta 2003г
Technical documentation of NANOTECHNOLOGY
The STANDARD by Head Office of Northern Oil Trunk Pipelines ldquoTemporary regulations for exploitation of oil trunk pipeline ldquoUsa-Ukhta hellip
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Traditional technology of thermal treatment- heat up to 80-90 0С and cool downto до transport temperature ( 0 0С)
with a rate lt 20 0С per hour
Oil pipeline ≪Usa-Ukhta≫with a capacity of 18 bln tons year
Required volumeof storage tanks
100 000 tons
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
NANOTECHNOLOGY of thermal treatment- heat up to 80-900С and cool down
with a rate lt 20 0С per hourto the temperature NANOPHASE boundary
at 35 ndash 40 оС Subsequent cooling ndashwith an arbitrary rate
Storage tanksmay be reducedto 40 000 tonsor liquidated
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
NANO ndash resemblingphase transformations
in petroleum-based fluids
NATIVEWATER -INndash OIL
DISPERSIONS EMULSIONS
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
dTdt is inversely related to specific heat hence to phase structure of WO emulsion
20
15
10
05
0 04 06 02 10
Water Cut
Initi
al H
eatin
g Rat
e d
T
dt
08
Percolation BicontinuousPhase
Phenomena common in true NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
15 water 20 water
25 water
Percolating clustersof
water droplets
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
ldquoNANOTECHNOLOGYrdquo ndash perform thermal demulsification at specific water cuts
8
6
4
2 0 04 06 02
Water Cut
Dem
ulsi
ficat
ion
Effic
ienc
y a
u
08
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
IN Evdokimov - Professor
NYu Eliseev - Docent
AP Losev ndash MEng student
MA Novikov ndash MEng student
Gubkin Russian State University of Oil and Gas
httpeeegubkinruphysexpgubkinru
THANK YOU THANK YOU FOR YOUR ATTENTION FOR YOUR ATTENTION
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
ANYQUESTIONS
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
APPENDIX
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
2-Phase Diagram of Oil Reservoir
Bubble pointline
Liquid Vapour
Vapour0
Dew pointline
1020
40
2-phase Region
0
1000
2000
3000
4000
5000
6000
7000
8000
20 40 60 80 100 120 140 160 180 200Temperature (
oC)
Pres
sure
(psi
a)
Critical Point
Dew Point RegionBubble Point Region
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Path of Production at 2-Phase Diagram
Temperature
Pres
sure
Initial Reservoir Conditions
CP
Path of Production
Separator Conditions
75
5025
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
3-Phase Diagram of Oil Reservoir
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
Phase Diagrams of Oil Reservoirsand Proper Production Paths
Taking into AccountMultiple NANOPHASES
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