-
From: Paul RosascoTo: Jump, Christine; Juett, Lynn; "Seabaugh,
Ryan"; Mahler, TomCc: McGahren, John; Feingold, Stephanie R.;
"Guariglia, Dale"; "Beck, Bill (LG)"; Sklenar, Scott
E:(GenCo-Nuc);
"Lintecum, Sarah E. (LG)"; Merrigan, Jessie; Dupre, Phillip R
(ENRD); Steve Miller; "Warren, Victoria"; Fanning,Erin; Dan Feezor;
"Mike Bollenbacher"; [email protected]
Subject: West Lake OU-1 Monthly Progress Report - July 2017Date:
Thursday, August 10, 2017 1:17:03 PMAttachments: 1707090_d.pdf
ATLSTDEDD_1707090.xls1706454_d.pdfATLSTDEDD_1706454.xls1706146_d.pdfATLSTDEDD_1706146.xls17061062.pdf17061062EDD.XLS1705139R.XLS1706028.xls1707070.xls7-17
West Lake LF OU-1 Mo Progress Report.pdf7-17 West Lake LF OU-1 Mo
Progress Report.pdf
Ms. Jump,The monthly status report for OU-1 is attached.
Laboratory Analytical Reports
Air Monitoring
The lab reports and the electronic data deliverables (EDDs) for
the EuroFins Air Toxics Ltd labreports 1706146, 1706454, and
1707090 are attached. No reports of results for air
monitoringsamples were received from Eberline Laboratory during
this period.Stormwater
The lab report and associated EDDs for TekLab report 17061062
are attached. The EDDs for theEberline stormwater sample lab
reports numbers 1705139R, 1706028, and 1707070 are alsoattached.
The full reports can be download using the following
links:https://db.tt/PkT9lqLqNy
https://db.tt/Crf2hvcEZI
https://db.tt/Jquqlspmwt
Stormwater Memorandum
The Feezor Engineering, Inc. memorandum regarding stormwater
monitoring and inspectionactivities conducted during July 2017 can
be downloaded from the following link:
https://db.tt/Y7psu9RPa8
Please contact us if you have any questions.Thank-you, Paul.Paul
V. Rosasco P.E.Engineering Management Support, Inc.25923 Gateway
DriveGolden, CO 80401
mailto:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]://db.tt/PkT9lqLqNyhttps://db.tt/Crf2hvcEZIhttps://db.tt/Jquqlspmwthttps://db.tt/Y7psu9RPa8
-
7/21/2017Ms. Cecilia GreeneAuxier & Associates, Inc.9821
Cogdill Road, Suite 1
Knoxville TN 37932
Project Name: Project #:
Dear Ms. Cecilia Greene
The following report includes the data for the above referenced
project for sample(s) received on 7/7/2017 at Air Toxics Ltd.
The data and associated QC analyzed by Passive S.E. RAD130/SKC
are compliant with the project requirements or laboratory criteria
with the exception of the deviations noted in the attached case
narrative.
Thank you for choosing Eurofins Air Toxics Inc. for your air
analysis needs. Eurofins Air Toxics Inc. is committed to providing
accurate data of the highest quality. Please feel freeto contact
the Project Manager: Kelly Buettner at 916-985-1000 if you have any
questions regarding the data in this report.
Regards,
Kelly Buettner
Project Manager
Workorder #: 1707090
Page 1 of 17
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Ms. Cecilia GreeneAuxier & Associates, Inc.9821 Cogdill
Road, Suite 1Knoxville, TN 37932
WORK ORDER #: 1707090
CLIENT: BILL TO:
PHONE:
Ms. Cecilia GreeneAuxier & Associates, Inc.9821 Cogdill
Road, Suite 1Knoxville, TN 37932
865-675-3669
865-675-367707/07/2017
DATE COMPLETED: 07/20/2017
P.O. #
PROJECT #
Work Order Summary
FAX:
DATE RECEIVED:CONTACT: Kelly Buettner
NAMEFRACTION # TEST01A 1 Passive S.E. RAD130/SKC02A 5 Passive
S.E. RAD130/SKC03A 7 Passive S.E. RAD130/SKC04A 8 Passive S.E.
RAD130/SKC05A 12 Passive S.E. RAD130/SKC06A DUP Passive S.E.
RAD130/SKC07A TB Passive S.E. RAD130/SKC08A Lab Blank Passive S.E.
RAD130/SKC09A LCS Passive S.E. RAD130/SKC09AA LCSD Passive S.E.
RAD130/SKC
CERTIFIED BY:
Technical Director
DATE:
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 .
(800) 985-5955 . FAX (916) 985-1020
07/20/17
Page 2 of 17
This report shall not be reproduced, except in full, without the
written approval of Eurofins Air Toxics, Inc.
-
LABORATORY NARRATIVERAD130 Passive SE by Mod EPA TO-17
Auxier & Associates, Inc.Workorder# 1707090
Seven Radiello 130 (Solvent) samples were received on July 07,
2017. The laboratory analyzed the charcoal sorbent bed of the
passive sampler following modified method EPA TO-17. The VOCs were
chemically extracted using carbon disulfide and an aliquot of the
extract was injected into a GC/MS for identification and
quantification of volatile organic compounds (VOCs).
The mass of each target compound adsorbed by the sampler was
converted to units of concentration using the sample deployment
time and the sampling rate for each VOC. If sampling rates
werecalculated by the lab or the manufacturer, the concentration
result has been flagged as an estimated value. Results are not
corrected for desorption efficiency.
The reference method used for this procedure is EPA TO-17, which
describes the collection of VOCs in ambient air using sorbents and
analysis by GC/MS. Because TO-17 describes active sample collection
using a pump and thermal desorption as the preparation step,
several modifications are required. Modifications to TO-17 are
listed in the table below:
Requirement ATL ModificationsTO-17Sample Collection Pump pulls
measured
air volume through sorbent tube
VOCs in air adsorbed onto sorbent bed passively through
diffusion
Receiving Notes
There were no receiving discrepancies.
The uptake rates were corrected based on average field
temperatures if provided. In the absence of field temperatures, the
uptake rates determined at 25 deg C were used.
To calculate ug/m3 concentrations in the Lab Blank and Trip
Blank, a sampling duration of 20280 minutes was applied. The
assumed temperature used for the uptake rate is listed on the data
page. If the field temperatures were provided, the rate was
adjusted in the same manner as the field samples.
Analytical Notes
Ten qualifiers may have been used on the data analysis sheets
and indicate as follows: B - Compound present in laboratory blank
greater than reporting limit (background subtraction not
performed). J - Estimated value. E - Exceeds instrument calibration
range. S - Saturated peak. Q - Exceeds quality control limits. U -
Compound analyzed for but not detected above the reporting limit.
UJ- Non-detected compound associated with low bias in the CCV N -
The identification is based on presumptive evidence.
Definition of Data Qualifying Flags
Page 3 of 17
-
C - Estimated concentration due to calculated sampling rate CN -
See case narrative explanation.
File extensions may have been used on the data analysis sheets
and indicates as follows: a-File was requantified b-File was
quantified by a second column and detector r1-File was requantified
for the purpose of reissue
Page 4 of 17
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VOCS BY PASSIVE SAMPLER - GC/MSSummary of Detected Compounds
Client Sample ID: 1
Lab ID#: 1707090-01A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.099 0.10 0.101,2,4-Trimethylbenzene
0.10 0.062 0.32 0.202-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.23 0.15Acetone
0.10 0.074 0.38 0.28Carbon Tetrachloride
0.10 0.066 0.10 0.066Chloroform
0.10 0.073 0.12 0.089Ethyl Benzene
0.10 0.085 0.20 0.17Heptane
0.10 0.075 0.35 0.26Hexane
0.10 0.067 0.71 0.47Toluene
0.10 0.084 0.26 0.22Tetrachloroethene
0.10 0.070 0.34 0.24m,p-Xylene
0.10 0.076 0.12 0.093o-Xylene
Client Sample ID: 5
Lab ID#: 1707090-02A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.099 0.13 0.131,2,4-Trimethylbenzene
0.10 0.062 0.28 0.182-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.26 0.17Acetone
0.10 0.074 0.35 0.26Carbon Tetrachloride
0.10 0.066 0.13 0.087Chloroform
0.10 0.091 0.10 0.092Cyclohexane
0.10 0.073 0.14 0.10Ethyl Benzene
0.10 0.085 0.17 0.15Heptane
0.10 0.075 0.44 0.33Hexane
0.10 0.067 0.94 0.62Toluene
0.10 0.070 0.42 0.29m,p-Xylene
0.10 0.076 0.15 0.12o-Xylene
Client Sample ID: 7
Lab ID#: 1707090-03A
Page 5 of 17
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VOCS BY PASSIVE SAMPLER - GC/MSSummary of Detected Compounds
Client Sample ID: 7
Lab ID#: 1707090-03A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.099 0.17 0.171,2,4-Trimethylbenzene
0.10 0.062 0.27 0.172-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.23 0.15Acetone
0.10 0.074 0.38 0.28Carbon Tetrachloride
0.10 0.091 0.10 0.095Cyclohexane
0.40 0.25 0.65 0.41Ethyl Acetate
0.10 0.073 0.18 0.13Ethyl Benzene
0.10 0.085 0.21 0.18Heptane
0.10 0.075 0.33 0.25Hexane
0.10 0.067 1.3 0.86Toluene
0.10 0.084 0.10 0.086Tetrachloroethene
0.10 0.070 0.57 0.40m,p-Xylene
0.10 0.076 0.20 0.15o-Xylene
Client Sample ID: 8
Lab ID#: 1707090-04A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.099 0.12 0.121,2,4-Trimethylbenzene
0.10 0.062 0.26 0.162-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.20 0.13Acetone
0.10 0.074 0.33 0.24Carbon Tetrachloride
0.10 0.066 0.11 0.074Chloroform
0.10 0.073 0.12 0.088Ethyl Benzene
0.10 0.085 0.16 0.14Heptane
0.10 0.075 0.33 0.24Hexane
0.10 0.067 0.71 0.48Toluene
0.10 0.070 0.35 0.25m,p-Xylene
0.10 0.076 0.13 0.097o-Xylene
Client Sample ID: 12
Lab ID#: 1707090-05A
Page 6 of 17
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VOCS BY PASSIVE SAMPLER - GC/MSSummary of Detected Compounds
Client Sample ID: 12
Lab ID#: 1707090-05A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.099 0.12 0.121,2,4-Trimethylbenzene
0.10 0.062 0.21 0.132-Butanone (Methyl Ethyl Ketone)
0.10 0.074 0.36 0.26Carbon Tetrachloride
0.10 0.072 0.12 0.089Ethyl Benzene
0.10 0.085 0.15 0.13Heptane
0.10 0.075 0.31 0.23Hexane
0.10 0.067 0.72 0.48Toluene
0.10 0.070 0.37 0.26m,p-Xylene
0.10 0.076 0.13 0.10o-Xylene
Client Sample ID: DUP
Lab ID#: 1707090-06A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.062 0.24 0.152-Butanone (Methyl Ethyl Ketone)
0.10 0.074 0.33 0.24Carbon Tetrachloride
0.10 0.073 0.11 0.080Ethyl Benzene
0.10 0.085 0.20 0.17Heptane
0.10 0.075 0.23 0.17Hexane
0.10 0.067 0.63 0.42Toluene
0.10 0.084 0.20 0.17Tetrachloroethene
0.10 0.070 0.30 0.21m,p-Xylene
0.10 0.076 0.10 0.080o-Xylene
Client Sample ID: TB
Lab ID#: 1707090-07ANo Detections Were Found.
Page 7 of 17
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Client Sample ID: 1Lab ID#: 1707090-01A
VOCS BY PASSIVE SAMPLER - GC/MS
c071908simFile Name:Dil. Factor: 1.00
Date of Collection: 7/5/17 7:37:00 AMDate of Analysis: 7/19/17
10:12 AMDate of Extraction: 7/19/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 0.10
0.101,2,4-Trimethylbenzene0.10 0.097 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.062 0.32 0.202-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.23 0.15Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.074 0.38 0.28Carbon
Tetrachloride0.10 0.073 Not Detected Not DetectedChlorobenzene0.10
0.066 0.10 0.066Chloroform0.10 0.091 Not Detected Not
DetectedCyclohexane1.0 0.48 Not Detected Not DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.073 0.12
0.089Ethyl Benzene0.10 0.085 0.20 0.17Heptane0.10 0.075 0.35
0.26Hexane0.10 0.076 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.087 Not
Detected Not DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 0.71 0.47Toluene0.10 0.084 0.26
0.22Tetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.070 0.34 0.24m,p-Xylene0.10 0.076
0.12 0.093o-Xylene
Temperature = 77.0F , duration time = 20244 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8
Page 8 of 17
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Client Sample ID: 5Lab ID#: 1707090-02A
VOCS BY PASSIVE SAMPLER - GC/MS
c071909simFile Name:Dil. Factor: 1.00
Date of Collection: 7/5/17 7:48:00 AMDate of Analysis: 7/19/17
10:37 AMDate of Extraction: 7/19/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 0.13
0.131,2,4-Trimethylbenzene0.10 0.097 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.062 0.28 0.182-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.26 0.17Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.074 0.35 0.26Carbon
Tetrachloride0.10 0.073 Not Detected Not DetectedChlorobenzene0.10
0.066 0.13 0.087Chloroform0.10 0.091 0.10 0.092Cyclohexane1.0 0.48
Not Detected Not DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.073 0.14
0.10Ethyl Benzene0.10 0.085 0.17 0.15Heptane0.10 0.075 0.44
0.33Hexane0.10 0.076 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.087 Not
Detected Not DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 0.94 0.62Toluene0.10 0.084 Not Detected
Not DetectedTetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.070 0.42 0.29m,p-Xylene0.10 0.076
0.15 0.12o-Xylene
Temperature = 77.0F , duration time = 20242 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8
Page 9 of 17
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Client Sample ID: 7Lab ID#: 1707090-03A
VOCS BY PASSIVE SAMPLER - GC/MS
c071910simFile Name:Dil. Factor: 1.00
Date of Collection: 7/5/17 7:47:00 AMDate of Analysis: 7/19/17
11:02 AMDate of Extraction: 7/19/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 0.17
0.171,2,4-Trimethylbenzene0.10 0.097 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.062 0.27 0.172-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.23 0.15Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.074 0.38 0.28Carbon
Tetrachloride0.10 0.073 Not Detected Not DetectedChlorobenzene0.10
0.066 Not Detected Not DetectedChloroform0.10 0.091 0.10
0.095Cyclohexane1.0 0.48 Not Detected Not DetectedEthanol
0.40 0.25 0.65 0.41Ethyl Acetate0.10 0.073 0.18 0.13Ethyl
Benzene0.10 0.085 0.21 0.18Heptane0.10 0.075 0.33 0.25Hexane0.10
0.076 Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.087 Not Detected Not
DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 1.3 0.86Toluene0.10 0.084 0.10
0.086Tetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.070 0.57 0.40m,p-Xylene0.10 0.076
0.20 0.15o-Xylene
Temperature = 77.0F , duration time = 20244 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8
Page 10 of 17
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Client Sample ID: 8Lab ID#: 1707090-04A
VOCS BY PASSIVE SAMPLER - GC/MS
c071911simFile Name:Dil. Factor: 1.00
Date of Collection: 7/5/17 7:57:00 AMDate of Analysis: 7/19/17
11:27 AMDate of Extraction: 7/19/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 0.12
0.121,2,4-Trimethylbenzene0.10 0.097 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.062 0.26 0.162-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.20 0.13Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.074 0.33 0.24Carbon
Tetrachloride0.10 0.073 Not Detected Not DetectedChlorobenzene0.10
0.066 0.11 0.074Chloroform0.10 0.091 Not Detected Not
DetectedCyclohexane1.0 0.48 Not Detected Not DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.073 0.12
0.088Ethyl Benzene0.10 0.085 0.16 0.14Heptane0.10 0.075 0.33
0.24Hexane0.10 0.076 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.087 Not
Detected Not DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 0.71 0.48Toluene0.10 0.084 Not Detected
Not DetectedTetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.070 0.35 0.25m,p-Xylene0.10 0.076
0.13 0.097o-Xylene
Temperature = 77.0F , duration time = 20245 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
103 70-130Toluene-d8
Page 11 of 17
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Client Sample ID: 12Lab ID#: 1707090-05A
VOCS BY PASSIVE SAMPLER - GC/MS
c071912simFile Name:Dil. Factor: 1.00
Date of Collection: 7/5/17 8:02:00 AMDate of Analysis: 7/19/17
11:52 AMDate of Extraction: 7/19/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 0.12
0.121,2,4-Trimethylbenzene0.10 0.097 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.062 0.21 0.132-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.074
0.36 0.26Carbon Tetrachloride0.10 0.072 Not Detected Not
DetectedChlorobenzene0.10 0.066 Not Detected Not
DetectedChloroform0.10 0.091 Not Detected Not
DetectedCyclohexane1.0 0.48 Not Detected Not DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.072 0.12
0.089Ethyl Benzene0.10 0.085 0.15 0.13Heptane0.10 0.075 0.31
0.23Hexane0.10 0.076 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.086 Not
Detected Not DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 0.72 0.48Toluene0.10 0.084 Not Detected
Not DetectedTetrachloroethene0.10 0.071 Not Detected Not
DetectedTrichloroethene0.10 0.070 0.37 0.26m,p-Xylene0.10 0.076
0.13 0.10o-Xylene
Temperature = 77.0F , duration time = 20280 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8
Page 12 of 17
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Client Sample ID: DUPLab ID#: 1707090-06A
VOCS BY PASSIVE SAMPLER - GC/MS
c071913simFile Name:Dil. Factor: 1.00
Date of Collection: 7/5/17 7:37:00 AMDate of Analysis: 7/19/17
12:17 PMDate of Extraction: 7/19/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 Not
Detected Not Detected1,2,4-Trimethylbenzene0.10 0.097 Not Detected
Not Detected1,4-Dichlorobenzene0.10 0.062 0.24 0.152-Butanone
(Methyl Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.074
0.33 0.24Carbon Tetrachloride0.10 0.073 Not Detected Not
DetectedChlorobenzene0.10 0.066 Not Detected Not
DetectedChloroform0.10 0.091 Not Detected Not
DetectedCyclohexane1.0 0.48 Not Detected Not DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.073 0.11
0.080Ethyl Benzene0.10 0.085 0.20 0.17Heptane0.10 0.075 0.23
0.17Hexane0.10 0.076 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.087 Not
Detected Not DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 0.63 0.42Toluene0.10 0.084 0.20
0.17Tetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.070 0.30 0.21m,p-Xylene0.10 0.076
0.10 0.080o-Xylene
Temperature = 77.0F , duration time = 20244 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
103 70-130Toluene-d8
Page 13 of 17
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Client Sample ID: TBLab ID#: 1707090-07A
VOCS BY PASSIVE SAMPLER - GC/MS
c071907simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 7/19/17 09:47 AMDate of
Extraction: 7/19/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 Not
Detected Not Detected1,2,4-Trimethylbenzene0.10 0.097 Not Detected
Not Detected1,4-Dichlorobenzene0.10 0.062 Not Detected Not
Detected2-Butanone (Methyl Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.074
Not Detected Not DetectedCarbon Tetrachloride0.10 0.072 Not
Detected Not DetectedChlorobenzene0.10 0.066 Not Detected Not
DetectedChloroform0.10 0.091 Not Detected Not
DetectedCyclohexane1.0 0.48 Not Detected Not DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.072 Not
Detected Not DetectedEthyl Benzene0.10 0.085 Not Detected Not
DetectedHeptane0.10 0.075 Not Detected Not DetectedHexane0.10 0.076
Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.086 Not Detected Not
DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 Not Detected Not DetectedToluene0.10
0.084 Not Detected Not DetectedTetrachloroethene0.10 0.071 Not
Detected Not DetectedTrichloroethene0.10 0.070 Not Detected Not
Detectedm,p-Xylene0.10 0.076 Not Detected Not Detectedo-Xylene
Temperature = 77.0F , duration time = 20280 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8
Page 14 of 17
-
Client Sample ID: Lab BlankLab ID#: 1707090-08A
VOCS BY PASSIVE SAMPLER - GC/MS
c071906simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 7/19/17 09:18 AMDate of
Extraction: 7/19/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 Not
Detected Not Detected1,2,4-Trimethylbenzene0.10 0.097 Not Detected
Not Detected1,4-Dichlorobenzene0.10 0.062 Not Detected Not
Detected2-Butanone (Methyl Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.074
Not Detected Not DetectedCarbon Tetrachloride0.10 0.072 Not
Detected Not DetectedChlorobenzene0.10 0.066 Not Detected Not
DetectedChloroform0.10 0.091 Not Detected Not
DetectedCyclohexane1.0 0.48 Not Detected Not DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.072 Not
Detected Not DetectedEthyl Benzene0.10 0.085 Not Detected Not
DetectedHeptane0.10 0.075 Not Detected Not DetectedHexane0.10 0.076
Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.086 Not Detected Not
DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 Not Detected Not DetectedToluene0.10
0.084 Not Detected Not DetectedTetrachloroethene0.10 0.071 Not
Detected Not DetectedTrichloroethene0.10 0.070 Not Detected Not
Detectedm,p-Xylene0.10 0.076 Not Detected Not Detectedo-Xylene
Temperature = 77.0F , duration time = 20280 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
103 70-130Toluene-d8
Page 15 of 17
-
Client Sample ID: LCSLab ID#: 1707090-09A
VOCS BY PASSIVE SAMPLER - GC/MS
c071904simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 7/19/17 08:28 AMDate of
Extraction: 7/19/17
Limits%RecoveryCompoundMethod
103 70-1301,1,1-Trichloroethane94 70-1301,2-Dichloroethane94
70-1301,2,4-Trimethylbenzene74 50-1101,4-Dichlorobenzene89
70-1302-Butanone (Methyl Ethyl Ketone)99
70-1304-Methyl-2-pentanone87 70-130Acetone
102 70-130Benzene100 70-130Carbon Tetrachloride87
70-130Chlorobenzene
102 70-130Chloroform97 70-130Cyclohexane55 50-130Ethanol99
70-130Ethyl Acetate93 70-130Ethyl Benzene94 70-130Heptane
101 70-130Hexane101 70-130Methyl tert-butyl ether20
5-80Naphthalene82 70-130Propylbenzene66 20-100Styrene97
70-130Toluene98 70-130Tetrachloroethene
100 70-130Trichloroethene92 70-130m,p-Xylene99
70-130o-Xylene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8
Page 16 of 17
-
Client Sample ID: LCSDLab ID#: 1707090-09AA
VOCS BY PASSIVE SAMPLER - GC/MS
c071905simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 7/19/17 08:53 AMDate of
Extraction: 7/19/17
Limits%RecoveryCompoundMethod
112 70-1301,1,1-Trichloroethane100 70-1301,2-Dichloroethane90
70-1301,2,4-Trimethylbenzene74 50-1101,4-Dichlorobenzene96
70-1302-Butanone (Methyl Ethyl Ketone)
102 70-1304-Methyl-2-pentanone89 70-130Acetone
100 70-130Benzene109 70-130Carbon Tetrachloride87
70-130Chlorobenzene96 70-130Chloroform
108 70-130Cyclohexane55 50-130Ethanol
101 70-130Ethyl Acetate93 70-130Ethyl Benzene98 70-130Heptane92
70-130Hexane
119 70-130Methyl tert-butyl ether19 5-80Naphthalene81
70-130Propylbenzene64 20-100Styrene98 70-130Toluene98
70-130Tetrachloroethene
101 70-130Trichloroethene93 70-130m,p-Xylene96
70-130o-Xylene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
106 70-130Toluene-d8
Page 17 of 17
-
7/10/2017Ms. Cecilia GreeneAuxier & Associates, Inc.9821
Cogdill Road, Suite 1
Knoxville TN 37932
Project Name: WEST LAKE LANDFILLProject #:
Dear Ms. Cecilia Greene
The following report includes the data for the above referenced
project for sample(s) received on 6/23/2017 at Air Toxics Ltd.
The data and associated QC analyzed by Passive S.E. RAD130/SKC
are compliant with the project requirements or laboratory criteria
with the exception of the deviations noted in the attached case
narrative.
Thank you for choosing Eurofins Air Toxics Inc. for your air
analysis needs. Eurofins Air Toxics Inc. is committed to providing
accurate data of the highest quality. Please feel freeto contact
the Project Manager: Kelly Buettner at 916-985-1000 if you have any
questions regarding the data in this report.
Regards,
Kelly Buettner
Project Manager
Workorder #: 1706454
Page 1 of 17
-
Ms. Cecilia GreeneAuxier & Associates, Inc.9821 Cogdill
Road, Suite 1Knoxville, TN 37932
WORK ORDER #: 1706454
CLIENT: BILL TO:
PHONE:
Ms. Cecilia GreeneAuxier & Associates, Inc.9821 Cogdill
Road, Suite 1Knoxville, TN 37932
865-675-3669
865-675-367706/23/2017
DATE COMPLETED: 06/28/2017
P.O. #
PROJECT # WEST LAKE LANDFILL
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Kelly Buettner
NAMEFRACTION # TEST01A 1 Passive S.E. RAD130/SKC02A 5 Passive
S.E. RAD130/SKC03A 7 Passive S.E. RAD130/SKC04A 8 Passive S.E.
RAD130/SKC05A 12 Passive S.E. RAD130/SKC06A DUP Passive S.E.
RAD130/SKC07A TB Passive S.E. RAD130/SKC08A Lab Blank Passive S.E.
RAD130/SKC09A LCS Passive S.E. RAD130/SKC09AA LCSD Passive S.E.
RAD130/SKC
CERTIFIED BY:
Technical Director
DATE:
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 .
(800) 985-5955 . FAX (916) 985-1020
06/28/17
Page 2 of 17
This report shall not be reproduced, except in full, without the
written approval of Eurofins Air Toxics, Inc.
-
LABORATORY NARRATIVERAD130 Passive SE by Mod EPA TO-17
Auxier & Associates, Inc.Workorder# 1706454
Seven Radiello 130 (Solvent) samples were received on June 23,
2017. The laboratory analyzed thecharcoal sorbent bed of the
passive sampler following modified method EPA TO-17. The VOCs were
chemically extracted using carbon disulfide and an aliquot of the
extract was injected into a GC/MS for identification and
quantification of volatile organic compounds (VOCs).
The mass of each target compound adsorbed by the sampler was
converted to units of concentration using the sample deployment
time and the sampling rate for each VOC. If sampling rates were
calculated by the lab or the manufacturer, the concentration result
has been flagged as an estimated value. Results are not corrected
for desorption efficiency.
The reference method used for this procedure is EPA TO-17, which
describes the collection of VOCs in ambient air using sorbents and
analysis by GC/MS. Because TO-17 describes active sample collection
using a pump and thermal desorption as the preparation step,
several modifications are required. Modifications to TO-17 are
listed in the table below:
Requirement ATL ModificationsTO-17Sample Collection Pump pulls
measured
air volume through sorbent tube
VOCs in air adsorbed onto sorbent bed passively through
diffusion
Receiving Notes
There were no receiving discrepancies.
The uptake rates were corrected based on average field
temperatures if provided. In the absence of field temperatures, the
uptake rates determined at 25 deg C were used.
To calculate ug/m3 concentrations in the Lab Blank and Trip
Blank, a sampling duration of 19914 minutes was applied. The
assumed temperature used for the uptake rate is listed on the data
page. If the field temperatures were provided, the rate was
adjusted in the same manner as the field samples.
Analytical Notes
Ten qualifiers may have been used on the data analysis sheets
and indicate as follows: B - Compound present in laboratory blank
greater than reporting limit (background subtraction not
performed). J - Estimated value. E - Exceeds instrument calibration
range. S - Saturated peak. Q - Exceeds quality control limits. U -
Compound analyzed for but not detected above the reporting limit.
UJ- Non-detected compound associated with low bias in the CCV N -
The identification is based on presumptive evidence.
Definition of Data Qualifying Flags
Page 3 of 17
-
C - Estimated concentration due to calculated sampling rate CN -
See case narrative explanation.
File extensions may have been used on the data analysis sheets
and indicates as follows: a-File was requantified b-File was
quantified by a second column and detector r1-File was requantified
for the purpose of reissue
Page 4 of 17
-
VOCS BY PASSIVE SAMPLER - GC/MSSummary of Detected Compounds
Client Sample ID: 1
Lab ID#: 1706454-01A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.10 0.12 0.121,2,4-Trimethylbenzene
0.10 0.064 0.28 0.182-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.22 0.14Acetone
0.10 0.075 0.55 0.41Carbon Tetrachloride
0.10 0.074 0.12 0.091Ethyl Benzene
0.10 0.087 0.26 0.23Heptane
0.10 0.076 0.28 0.21Hexane
0.10 0.068 0.76 0.52Toluene
0.10 0.086 0.22 0.19Tetrachloroethene
0.10 0.072 0.32 0.23m,p-Xylene
0.10 0.078 0.10 0.081o-Xylene
Client Sample ID: 5
Lab ID#: 1706454-02A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.10 0.15 0.151,2,4-Trimethylbenzene
0.10 0.064 0.27 0.172-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.21 0.14Acetone
0.10 0.075 0.53 0.40Carbon Tetrachloride
0.40 0.26 0.51 0.33Ethyl Acetate
0.10 0.074 0.17 0.12Ethyl Benzene
0.10 0.087 0.24 0.21Heptane
0.10 0.077 0.40 0.30Hexane
0.10 0.068 1.1 0.74Toluene
0.10 0.072 0.50 0.36m,p-Xylene
0.10 0.078 0.15 0.12o-Xylene
Client Sample ID: 7
Lab ID#: 1706454-03A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.10 0.28 0.281,2,4-Trimethylbenzene
Page 5 of 17
-
VOCS BY PASSIVE SAMPLER - GC/MSSummary of Detected Compounds
Client Sample ID: 7
Lab ID#: 1706454-03A0.10 0.064 0.32 0.202-Butanone (Methyl Ethyl
Ketone)
0.20 0.13 0.28 0.18Acetone
0.10 0.075 0.45 0.34Carbon Tetrachloride
0.10 0.094 0.16 0.15Cyclohexane
0.40 0.26 1.3 0.87Ethyl Acetate
0.10 0.074 0.36 0.27Ethyl Benzene
0.10 0.087 0.32 0.28Heptane
0.10 0.077 0.45 0.35Hexane
0.10 0.068 1.9 1.3Toluene
0.10 0.086 0.16 0.14Tetrachloroethene
0.10 0.072 1.2 0.90m,p-Xylene
0.10 0.078 0.35 0.27o-Xylene
Client Sample ID: 8
Lab ID#: 1706454-04A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.064 0.22 0.142-Butanone (Methyl Ethyl Ketone)
0.10 0.075 0.40 0.30Carbon Tetrachloride
0.10 0.087 0.14 0.12Heptane
0.10 0.077 0.29 0.22Hexane
0.10 0.068 0.65 0.44Toluene
0.10 0.072 0.25 0.18m,p-Xylene
Client Sample ID: 12
Lab ID#: 1706454-05A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.10 0.18 0.181,2,4-Trimethylbenzene
0.10 0.064 0.18 0.112-Butanone (Methyl Ethyl Ketone)
0.10 0.076 0.48 0.36Carbon Tetrachloride
0.10 0.074 0.17 0.13Ethyl Benzene
0.10 0.087 0.22 0.19Heptane
0.10 0.077 0.47 0.36Hexane
Page 6 of 17
-
VOCS BY PASSIVE SAMPLER - GC/MSSummary of Detected Compounds
Client Sample ID: 12
Lab ID#: 1706454-05A0.10 0.068 0.91 0.62Toluene
0.10 0.072 0.48 0.35m,p-Xylene
0.10 0.078 0.15 0.12o-Xylene
Client Sample ID: DUP
Lab ID#: 1706454-06A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.10 0.16 0.161,2,4-Trimethylbenzene
0.10 0.064 0.30 0.192-Butanone (Methyl Ethyl Ketone)
0.20 0.15 0.31 0.234-Methyl-2-pentanone
0.20 0.13 0.23 0.15Acetone
0.10 0.076 0.41 0.31Carbon Tetrachloride
0.10 0.094 0.11 0.10Cyclohexane
0.10 0.074 0.16 0.12Ethyl Benzene
0.10 0.087 0.21 0.18Heptane
0.10 0.077 0.42 0.32Hexane
0.10 0.068 0.87 0.59Toluene
0.10 0.072 0.46 0.34m,p-Xylene
0.10 0.078 0.16 0.12o-Xylene
Client Sample ID: TB
Lab ID#: 1706454-07ANo Detections Were Found.
Page 7 of 17
-
Client Sample ID: 1Lab ID#: 1706454-01A
VOCS BY PASSIVE SAMPLER - GC/MS
c062616simFile Name:Dil. Factor: 1.00
Date of Collection: 6/21/17 6:12:00 AMDate of Analysis: 6/26/17
04:45 PMDate of Extraction: 6/26/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.081 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.066 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 0.12
0.121,2,4-Trimethylbenzene0.10 0.099 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.064 0.28 0.182-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.22 0.14Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.075 0.55 0.41Carbon
Tetrachloride0.10 0.074 Not Detected Not DetectedChlorobenzene0.10
0.067 Not Detected Not DetectedChloroform0.10 0.093 Not Detected
Not DetectedCyclohexane1.0 0.49 Not Detected Not
DetectedEthanol
0.40 0.26 Not Detected Not DetectedEthyl Acetate0.10 0.074 0.12
0.091Ethyl Benzene0.10 0.087 0.26 0.23Heptane0.10 0.076 0.28
0.21Hexane0.10 0.078 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.088 Not
Detected Not DetectedPropylbenzene0.10 0.083 Not Detected Not
DetectedStyrene0.10 0.068 0.76 0.52Toluene0.10 0.086 0.22
0.19Tetrachloroethene0.10 0.073 Not Detected Not
DetectedTrichloroethene0.10 0.072 0.32 0.23m,p-Xylene0.10 0.078
0.10 0.081o-Xylene
Temperature = 76.0F , duration time = 19914 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8
Page 8 of 17
-
Client Sample ID: 5Lab ID#: 1706454-02A
VOCS BY PASSIVE SAMPLER - GC/MS
c062617simFile Name:Dil. Factor: 1.00
Date of Collection: 6/21/17 6:25:00 AMDate of Analysis: 6/26/17
05:10 PMDate of Extraction: 6/26/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.082 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.066 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 0.15
0.151,2,4-Trimethylbenzene0.10 0.099 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.064 0.27 0.172-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.21 0.14Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.075 0.53 0.40Carbon
Tetrachloride0.10 0.074 Not Detected Not DetectedChlorobenzene0.10
0.067 Not Detected Not DetectedChloroform0.10 0.094 Not Detected
Not DetectedCyclohexane1.0 0.50 Not Detected Not
DetectedEthanol
0.40 0.26 0.51 0.33Ethyl Acetate0.10 0.074 0.17 0.12Ethyl
Benzene0.10 0.087 0.24 0.21Heptane0.10 0.077 0.40 0.30Hexane0.10
0.078 Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.089 Not Detected Not
DetectedPropylbenzene0.10 0.083 Not Detected Not
DetectedStyrene0.10 0.068 1.1 0.74Toluene0.10 0.086 Not Detected
Not DetectedTetrachloroethene0.10 0.073 Not Detected Not
DetectedTrichloroethene0.10 0.072 0.50 0.36m,p-Xylene0.10 0.078
0.15 0.12o-Xylene
Temperature = 76.0F , duration time = 19874 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8
Page 9 of 17
-
Client Sample ID: 7Lab ID#: 1706454-03A
VOCS BY PASSIVE SAMPLER - GC/MS
c062618simFile Name:Dil. Factor: 1.00
Date of Collection: 6/21/17 6:22:00 AMDate of Analysis: 6/26/17
05:35 PMDate of Extraction: 6/26/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.082 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.066 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 0.28
0.281,2,4-Trimethylbenzene0.10 0.099 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.064 0.32 0.202-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.28 0.18Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.075 0.45 0.34Carbon
Tetrachloride0.10 0.074 Not Detected Not DetectedChlorobenzene0.10
0.067 Not Detected Not DetectedChloroform0.10 0.094 0.16
0.15Cyclohexane1.0 0.50 Not Detected Not DetectedEthanol
0.40 0.26 1.3 0.87Ethyl Acetate0.10 0.074 0.36 0.27Ethyl
Benzene0.10 0.087 0.32 0.28Heptane0.10 0.077 0.45 0.35Hexane0.10
0.078 Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.089 Not Detected Not
DetectedPropylbenzene0.10 0.083 Not Detected Not
DetectedStyrene0.10 0.068 1.9 1.3Toluene0.10 0.086 0.16
0.14Tetrachloroethene0.10 0.073 Not Detected Not
DetectedTrichloroethene0.10 0.072 1.2 0.90m,p-Xylene0.10 0.078 0.35
0.27o-Xylene
Temperature = 76.0F , duration time = 19876 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8
Page 10 of 17
-
Client Sample ID: 8Lab ID#: 1706454-04A
VOCS BY PASSIVE SAMPLER - GC/MS
c062619simFile Name:Dil. Factor: 1.00
Date of Collection: 6/21/17 6:31:00 AMDate of Analysis: 6/26/17
06:00 PMDate of Extraction: 6/26/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.082 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.066 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 Not
Detected Not Detected1,2,4-Trimethylbenzene0.10 0.099 Not Detected
Not Detected1,4-Dichlorobenzene0.10 0.064 0.22 0.142-Butanone
(Methyl Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.075
0.40 0.30Carbon Tetrachloride0.10 0.074 Not Detected Not
DetectedChlorobenzene0.10 0.067 Not Detected Not
DetectedChloroform0.10 0.094 Not Detected Not
DetectedCyclohexane1.0 0.50 Not Detected Not DetectedEthanol
0.40 0.26 Not Detected Not DetectedEthyl Acetate0.10 0.074 Not
Detected Not DetectedEthyl Benzene0.10 0.087 0.14 0.12Heptane0.10
0.077 0.29 0.22Hexane0.10 0.078 Not Detected Not DetectedMethyl
tert-butyl ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10
0.089 Not Detected Not DetectedPropylbenzene0.10 0.083 Not Detected
Not DetectedStyrene0.10 0.068 0.65 0.44Toluene0.10 0.086 Not
Detected Not DetectedTetrachloroethene0.10 0.073 Not Detected Not
DetectedTrichloroethene0.10 0.072 0.25 0.18m,p-Xylene0.10 0.078 Not
Detected Not Detectedo-Xylene
Temperature = 76.0F , duration time = 19873 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8
Page 11 of 17
-
Client Sample ID: 12Lab ID#: 1706454-05A
VOCS BY PASSIVE SAMPLER - GC/MS
c062620simFile Name:Dil. Factor: 1.00
Date of Collection: 6/21/17 6:00:00 AMDate of Analysis: 6/26/17
06:25 PMDate of Extraction: 6/26/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.082 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.066 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 0.18
0.181,2,4-Trimethylbenzene0.10 0.099 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.064 0.18 0.112-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.076
0.48 0.36Carbon Tetrachloride0.10 0.074 Not Detected Not
DetectedChlorobenzene0.10 0.068 Not Detected Not
DetectedChloroform0.10 0.094 Not Detected Not
DetectedCyclohexane1.0 0.50 Not Detected Not DetectedEthanol
0.40 0.26 Not Detected Not DetectedEthyl Acetate0.10 0.074 0.17
0.13Ethyl Benzene0.10 0.087 0.22 0.19Heptane0.10 0.077 0.47
0.36Hexane0.10 0.078 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.089 Not
Detected Not DetectedPropylbenzene0.10 0.083 Not Detected Not
DetectedStyrene0.10 0.068 0.91 0.62Toluene0.10 0.086 Not Detected
Not DetectedTetrachloroethene0.10 0.073 Not Detected Not
DetectedTrichloroethene0.10 0.072 0.48 0.35m,p-Xylene0.10 0.078
0.15 0.12o-Xylene
Temperature = 76.0F , duration time = 19826 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8
Page 12 of 17
-
Client Sample ID: DUPLab ID#: 1706454-06A
VOCS BY PASSIVE SAMPLER - GC/MS
c062621simFile Name:Dil. Factor: 1.00
Date of Collection: 6/21/17 6:00:00 AMDate of Analysis: 6/26/17
06:51 PMDate of Extraction: 6/26/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.082 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.066 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 0.16
0.161,2,4-Trimethylbenzene0.10 0.099 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.064 0.30 0.192-Butanone (Methyl
Ethyl Ketone)0.20 0.15 0.31 0.234-Methyl-2-pentanone0.20 0.13 0.23
0.15Acetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.076
0.41 0.31Carbon Tetrachloride0.10 0.074 Not Detected Not
DetectedChlorobenzene0.10 0.068 Not Detected Not
DetectedChloroform0.10 0.094 0.11 0.10Cyclohexane1.0 0.50 Not
Detected Not DetectedEthanol
0.40 0.26 Not Detected Not DetectedEthyl Acetate0.10 0.074 0.16
0.12Ethyl Benzene0.10 0.087 0.21 0.18Heptane0.10 0.077 0.42
0.32Hexane0.10 0.078 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.089 Not
Detected Not DetectedPropylbenzene0.10 0.083 Not Detected Not
DetectedStyrene0.10 0.068 0.87 0.59Toluene0.10 0.086 Not Detected
Not DetectedTetrachloroethene0.10 0.073 Not Detected Not
DetectedTrichloroethene0.10 0.072 0.46 0.34m,p-Xylene0.10 0.078
0.16 0.12o-Xylene
Temperature = 76.0F , duration time = 19826 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8
Page 13 of 17
-
Client Sample ID: TBLab ID#: 1706454-07A
VOCS BY PASSIVE SAMPLER - GC/MS
c062622simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 6/26/17 07:16 PMDate of
Extraction: 6/26/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.081 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.066 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 Not
Detected Not Detected1,2,4-Trimethylbenzene0.10 0.099 Not Detected
Not Detected1,4-Dichlorobenzene0.10 0.064 Not Detected Not
Detected2-Butanone (Methyl Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.075
Not Detected Not DetectedCarbon Tetrachloride0.10 0.074 Not
Detected Not DetectedChlorobenzene0.10 0.067 Not Detected Not
DetectedChloroform0.10 0.093 Not Detected Not
DetectedCyclohexane1.0 0.49 Not Detected Not DetectedEthanol
0.40 0.26 Not Detected Not DetectedEthyl Acetate0.10 0.074 Not
Detected Not DetectedEthyl Benzene0.10 0.087 Not Detected Not
DetectedHeptane0.10 0.076 Not Detected Not DetectedHexane0.10 0.078
Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.088 Not Detected Not
DetectedPropylbenzene0.10 0.083 Not Detected Not
DetectedStyrene0.10 0.068 Not Detected Not DetectedToluene0.10
0.086 Not Detected Not DetectedTetrachloroethene0.10 0.073 Not
Detected Not DetectedTrichloroethene0.10 0.072 Not Detected Not
Detectedm,p-Xylene0.10 0.078 Not Detected Not Detectedo-Xylene
Temperature = 76.0F , duration time = 19914 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8
Page 14 of 17
-
Client Sample ID: Lab BlankLab ID#: 1706454-08A
VOCS BY PASSIVE SAMPLER - GC/MS
c062609simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 6/26/17 01:49 PMDate of
Extraction: 6/26/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.081 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.066 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 Not
Detected Not Detected1,2,4-Trimethylbenzene0.10 0.099 Not Detected
Not Detected1,4-Dichlorobenzene0.10 0.064 Not Detected Not
Detected2-Butanone (Methyl Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.075
Not Detected Not DetectedCarbon Tetrachloride0.10 0.074 Not
Detected Not DetectedChlorobenzene0.10 0.067 Not Detected Not
DetectedChloroform0.10 0.093 Not Detected Not
DetectedCyclohexane1.0 0.49 Not Detected Not DetectedEthanol
0.40 0.26 Not Detected Not DetectedEthyl Acetate0.10 0.074 Not
Detected Not DetectedEthyl Benzene0.10 0.087 Not Detected Not
DetectedHeptane0.10 0.076 Not Detected Not DetectedHexane0.10 0.078
Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.088 Not Detected Not
DetectedPropylbenzene0.10 0.083 Not Detected Not
DetectedStyrene0.10 0.068 Not Detected Not DetectedToluene0.10
0.086 Not Detected Not DetectedTetrachloroethene0.10 0.073 Not
Detected Not DetectedTrichloroethene0.10 0.072 Not Detected Not
Detectedm,p-Xylene0.10 0.078 Not Detected Not Detectedo-Xylene
Temperature = 76.0F , duration time = 19914 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8
Page 15 of 17
-
Client Sample ID: LCSLab ID#: 1706454-09A
VOCS BY PASSIVE SAMPLER - GC/MS
c062607simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 6/26/17 12:59 PMDate of
Extraction: 6/26/17
Limits%RecoveryCompoundMethod
125 70-1301,1,1-Trichloroethane116 70-1301,2-Dichloroethane96
70-1301,2,4-Trimethylbenzene87 50-1101,4-Dichlorobenzene110
70-1302-Butanone (Methyl Ethyl Ketone)110
70-1304-Methyl-2-pentanone110 70-130Acetone102 70-130Benzene124
70-130Carbon Tetrachloride102 70-130Chlorobenzene108
70-130Chloroform122 70-130Cyclohexane76 50-130Ethanol114
70-130Ethyl Acetate110 70-130Ethyl Benzene118 70-130Heptane101
70-130Hexane124 70-130Methyl tert-butyl ether17 5-80Naphthalene101
70-130Propylbenzene72 20-100Styrene107 70-130Toluene113
70-130Tetrachloroethene119 70-130Trichloroethene105
70-130m,p-Xylene99 70-130o-Xylene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8
Page 16 of 17
-
Client Sample ID: LCSDLab ID#: 1706454-09AA
VOCS BY PASSIVE SAMPLER - GC/MS
c062608simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 6/26/17 01:24 PMDate of
Extraction: 6/26/17
Limits%RecoveryCompoundMethod
122 70-1301,1,1-Trichloroethane112 70-1301,2-Dichloroethane98
70-1301,2,4-Trimethylbenzene89 50-1101,4-Dichlorobenzene106
70-1302-Butanone (Methyl Ethyl Ketone)110
70-1304-Methyl-2-pentanone103 70-130Acetone100 70-130Benzene123
70-130Carbon Tetrachloride105 70-130Chlorobenzene105
70-130Chloroform122 70-130Cyclohexane69 50-130Ethanol110
70-130Ethyl Acetate112 70-130Ethyl Benzene119 70-130Heptane96
70-130Hexane120 70-130Methyl tert-butyl ether17 5-80Naphthalene105
70-130Propylbenzene73 20-100Styrene109 70-130Toluene115
70-130Tetrachloroethene119 70-130Trichloroethene107
70-130m,p-Xylene99 70-130o-Xylene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8
Page 17 of 17
-
7/12/2017Ms. Cecilia GreeneAuxier & Associates, Inc.9821
Cogdill Road, Suite 1
Knoxville TN 37932
Project Name: West Lake LandfillProject #:
Dear Ms. Cecilia Greene
The following report includes the data for the above referenced
project for sample(s) received on 6/8/2017 at Air Toxics Ltd.
The data and associated QC analyzed by Passive S.E. RAD130/SKC
are compliant with the project requirements or laboratory criteria
with the exception of the deviations noted in the attached case
narrative.
Thank you for choosing Eurofins Air Toxics Inc. for your air
analysis needs. Eurofins Air Toxics Inc. is committed to providing
accurate data of the highest quality. Please feel freeto contact
the Project Manager: Kelly Buettner at 916-985-1000 if you have any
questions regarding the data in this report.
Regards,
Kelly Buettner
Project Manager
Workorder #: 1706146
Page 1 of 17
-
Ms. Cecilia GreeneAuxier & Associates, Inc.9821 Cogdill
Road, Suite 1Knoxville, TN 37932
WORK ORDER #: 1706146
CLIENT: BILL TO:
PHONE:
Ms. Cecilia GreeneAuxier & Associates, Inc.9821 Cogdill
Road, Suite 1Knoxville, TN 37932
865-675-3669
865-675-367706/08/2017
DATE COMPLETED: 06/22/2017
P.O. #
PROJECT # West Lake Landfill
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Kelly Buettner
NAMEFRACTION # TEST01A 1 Passive S.E. RAD130/SKC02A 5 Passive
S.E. RAD130/SKC03A 7 Passive S.E. RAD130/SKC04A 8 Passive S.E.
RAD130/SKC05A 12 Passive S.E. RAD130/SKC06A Dup Passive S.E.
RAD130/SKC07A TB Passive S.E. RAD130/SKC08A Lab Blank Passive S.E.
RAD130/SKC09A LCS Passive S.E. RAD130/SKC09AA LCSD Passive S.E.
RAD130/SKC
CERTIFIED BY:
Technical Director
DATE:
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 .
(800) 985-5955 . FAX (916) 985-1020
06/22/17
Page 2 of 17
This report shall not be reproduced, except in full, without the
written approval of Eurofins Air Toxics, Inc.
-
LABORATORY NARRATIVERAD130 Passive SE by Mod EPA TO-17
Auxier & Associates, Inc.Workorder# 1706146
Seven Radiello 130 (Solvent) samples were received on June 08,
2017. The laboratory analyzed thecharcoal sorbent bed of the
passive sampler following modified method EPA TO-17. The VOCs were
chemically extracted using carbon disulfide and an aliquot of the
extract was injected into a GC/MS for identification and
quantification of volatile organic compounds (VOCs).
The mass of each target compound adsorbed by the sampler was
converted to units of concentration using the sample deployment
time and the sampling rate for each VOC. If sampling rates were
calculated by the lab or the manufacturer, the concentration result
has been flagged as an estimated value. Results are not corrected
for desorption efficiency.
The reference method used for this procedure is EPA TO-17, which
describes the collection of VOCs in ambient air using sorbents and
analysis by GC/MS. Because TO-17 describes active sample collection
using a pump and thermal desorption as the preparation step,
several modifications are required. Modifications to TO-17 are
listed in the table below:
Requirement ATL ModificationsTO-17Sample Collection Pump pulls
measured
air volume through sorbent tube
VOCs in air adsorbed onto sorbent bed passively through
diffusion
Receiving Notes
The uptake rates were corrected based on average field
temperatures if provided. In the absence of field temperatures, the
uptake rates determined at 25 deg C were used.
To calculate ug/m3 concentrations in the Lab Blank and Trip
Blank, a sampling duration of 20306 minutes was applied. The
assumed temperature used for the uptake rate is listed on the data
page. If the field temperatures were provided, the rate was
adjusted in the same manner as the field samples.
All Quality Control Limit exceedances and affected sample
results are noted by flags. Each flag isdefined at the bottom of
this Case Narrative and on each Sample Result Summary page.
Analytical Notes
Ten qualifiers may have been used on the data analysis sheets
and indicate as follows: B - Compound present in laboratory blank
greater than reporting limit (background subtraction not
performed). J - Estimated value. E - Exceeds instrument calibration
range. S - Saturated peak. Q - Exceeds quality control limits.
Definition of Data Qualifying Flags
Page 3 of 17
-
U - Compound analyzed for but not detected above the reporting
limit. UJ- Non-detected compound associated with low bias in the
CCV N - The identification is based on presumptive evidence. C -
Estimated concentration due to calculated sampling rate CN - See
case narrative explanation.
File extensions may have been used on the data analysis sheets
and indicates as follows: a-File was requantified b-File was
quantified by a second column and detector r1-File was requantified
for the purpose of reissue
Page 4 of 17
-
VOCS BY PASSIVE SAMPLER - GC/MSSummary of Detected Compounds
Client Sample ID: 1
Lab ID#: 1706146-01A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.10 0.19 0.201,2,4-Trimethylbenzene
0.10 0.064 0.47 0.302-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.37 0.24Acetone
0.10 0.075 0.39 0.29Carbon Tetrachloride
0.10 0.067 0.15 0.10Chloroform
0.10 0.074 0.22 0.16Ethyl Benzene
0.10 0.087 0.29 0.25Heptane
0.10 0.076 0.43 0.33Hexane
0.10 0.068 1.0 0.71Toluene
0.10 0.085 0.35 0.30Tetrachloroethene
0.10 0.072 0.57 0.41m,p-Xylene
0.10 0.077 0.19 0.15o-Xylene
Client Sample ID: 5
Lab ID#: 1706146-02A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.099 0.18 0.181,2,4-Trimethylbenzene
0.10 0.063 0.41 0.262-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.41 0.27Acetone
0.40 0.25 0.45 0.28Benzene
0.10 0.074 0.43 0.32Carbon Tetrachloride
0.10 0.066 0.12 0.082Chloroform
0.10 0.092 0.14 0.12Cyclohexane
0.40 0.25 0.45 0.29Ethyl Acetate
0.10 0.073 0.21 0.15Ethyl Benzene
0.10 0.085 0.30 0.25Heptane
0.10 0.075 0.58 0.43Hexane
0.10 0.067 1.3 0.86Toluene
0.10 0.084 0.10 0.086Tetrachloroethene
0.10 0.071 0.54 0.38m,p-Xylene
0.10 0.076 0.18 0.13o-Xylene
Page 5 of 17
-
VOCS BY PASSIVE SAMPLER - GC/MSSummary of Detected Compounds
Client Sample ID: 7
Lab ID#: 1706146-03A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.10 0.25 0.251,2,4-Trimethylbenzene
0.10 0.063 0.34 0.212-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.40 0.26Acetone
0.40 0.25 0.42 0.26Benzene
0.10 0.074 0.37 0.28Carbon Tetrachloride
0.10 0.066 0.14 0.096Chloroform
0.10 0.092 0.15 0.14Cyclohexane
0.40 0.26 1.0 0.66Ethyl Acetate
0.10 0.073 0.27 0.20Ethyl Benzene
0.10 0.086 0.36 0.31Heptane
0.10 0.075 0.69 0.52Hexane
0.10 0.067 1.6 1.1Toluene
0.10 0.084 0.14 0.11Tetrachloroethene
0.10 0.071 0.77 0.55m,p-Xylene
0.10 0.077 0.25 0.19o-Xylene
Client Sample ID: 8
Lab ID#: 1706146-04A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.099 0.13 0.131,2,4-Trimethylbenzene
0.10 0.063 0.32 0.202-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.28 0.18Acetone
0.10 0.074 0.32 0.24Carbon Tetrachloride
0.10 0.073 0.16 0.12Ethyl Benzene
0.10 0.085 0.20 0.17Heptane
0.10 0.075 0.30 0.23Hexane
0.10 0.067 0.89 0.59Toluene
0.10 0.071 0.41 0.29m,p-Xylene
0.10 0.076 0.14 0.10o-Xylene
Page 6 of 17
-
VOCS BY PASSIVE SAMPLER - GC/MSSummary of Detected Compounds
Client Sample ID: 12
Lab ID#: 1706146-05A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.099 0.15 0.151,2,4-Trimethylbenzene
0.10 0.063 0.32 0.202-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.44 0.28Acetone
0.10 0.074 0.38 0.28Carbon Tetrachloride
0.10 0.066 0.11 0.073Chloroform
0.10 0.092 0.11 0.10Cyclohexane
0.40 0.25 0.54 0.34Ethyl Acetate
0.10 0.073 0.18 0.13Ethyl Benzene
0.10 0.085 0.29 0.24Heptane
0.10 0.075 0.39 0.29Hexane
0.10 0.067 1.2 0.79Toluene
0.10 0.071 0.51 0.36m,p-Xylene
0.10 0.076 0.16 0.12o-Xylene
Client Sample ID: Dup
Lab ID#: 1706146-06A
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.099 0.14 0.141,2,4-Trimethylbenzene
0.10 0.063 0.32 0.202-Butanone (Methyl Ethyl Ketone)
0.20 0.13 0.31 0.20Acetone
0.10 0.074 0.33 0.24Carbon Tetrachloride
0.10 0.073 0.18 0.13Ethyl Benzene
0.10 0.085 0.21 0.18Heptane
0.10 0.075 0.71 0.53Hexane
0.10 0.067 0.94 0.63Toluene
0.10 0.071 0.45 0.32m,p-Xylene
0.10 0.076 0.14 0.11o-Xylene
Client Sample ID: TB
Lab ID#: 1706146-07ANo Detections Were Found.
Page 7 of 17
-
Client Sample ID: 1Lab ID#: 1706146-01A
VOCS BY PASSIVE SAMPLER - GC/MS
c062120simFile Name:Dil. Factor: 1.00
Date of Collection: 6/7/17 10:13:00 AMDate of Analysis: 6/21/17
03:36 PMDate of Extraction: 6/20/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.081 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.065 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 0.19
0.201,2,4-Trimethylbenzene0.10 0.098 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.064 0.47 0.302-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.37 0.24Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.075 0.39 0.29Carbon
Tetrachloride0.10 0.074 Not Detected Not DetectedChlorobenzene0.10
0.067 0.15 0.10Chloroform0.10 0.093 Not Detected Not
DetectedCyclohexane1.0 0.49 Not Detected Not DetectedEthanol
0.40 0.26 Not Detected Not DetectedEthyl Acetate0.10 0.074 0.22
0.16Ethyl Benzene0.10 0.087 0.29 0.25Heptane0.10 0.076 0.43
0.33Hexane0.10 0.077 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.088 Not
Detected Not DetectedPropylbenzene0.10 0.082 Not Detected Not
DetectedStyrene0.10 0.068 1.0 0.71Toluene0.10 0.085 0.35
0.30Tetrachloroethene0.10 0.073 Not Detected Not
DetectedTrichloroethene0.10 0.072 0.57 0.41m,p-Xylene0.10 0.077
0.19 0.15o-Xylene
Temperature = 72.0F , duration time = 20194 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8
Page 8 of 17
-
Client Sample ID: 5Lab ID#: 1706146-02A
VOCS BY PASSIVE SAMPLER - GC/MS
c062121simFile Name:Dil. Factor: 1.00
Date of Collection: 6/7/17 11:08:00 AMDate of Analysis: 6/21/17
04:02 PMDate of Extraction: 6/20/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 0.18
0.181,2,4-Trimethylbenzene0.10 0.097 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.063 0.41 0.262-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.41 0.27Acetone0.40 0.25
0.45 0.28Benzene0.10 0.074 0.43 0.32Carbon Tetrachloride0.10 0.073
Not Detected Not DetectedChlorobenzene0.10 0.066 0.12
0.082Chloroform0.10 0.092 0.14 0.12Cyclohexane1.0 0.48 Not Detected
Not DetectedEthanol
0.40 0.25 0.45 0.29Ethyl Acetate0.10 0.073 0.21 0.15Ethyl
Benzene0.10 0.085 0.30 0.25Heptane0.10 0.075 0.58 0.43Hexane0.10
0.076 Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.087 Not Detected Not
DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 1.3 0.86Toluene0.10 0.084 0.10
0.086Tetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.071 0.54 0.38m,p-Xylene0.10 0.076
0.18 0.13o-Xylene
Temperature = 75.0F , duration time = 20275 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8
Page 9 of 17
-
Client Sample ID: 7Lab ID#: 1706146-03A
VOCS BY PASSIVE SAMPLER - GC/MS
c062122simFile Name:Dil. Factor: 1.00
Date of Collection: 6/7/17 11:00:00 AMDate of Analysis: 6/21/17
04:29 PMDate of Extraction: 6/20/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.065 Not Detected Not Detected1,2-Dichloroethane0.10 0.10 0.25
0.251,2,4-Trimethylbenzene0.10 0.098 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.063 0.34 0.212-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.40 0.26Acetone0.40 0.25
0.42 0.26Benzene0.10 0.074 0.37 0.28Carbon Tetrachloride0.10 0.073
Not Detected Not DetectedChlorobenzene0.10 0.066 0.14
0.096Chloroform0.10 0.092 0.15 0.14Cyclohexane1.0 0.49 Not Detected
Not DetectedEthanol
0.40 0.26 1.0 0.66Ethyl Acetate0.10 0.073 0.27 0.20Ethyl
Benzene0.10 0.086 0.36 0.31Heptane0.10 0.075 0.69 0.52Hexane0.10
0.077 Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.087 Not Detected Not
DetectedPropylbenzene0.10 0.082 Not Detected Not
DetectedStyrene0.10 0.067 1.6 1.1Toluene0.10 0.084 0.14
0.11Tetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.071 0.77 0.55m,p-Xylene0.10 0.077
0.25 0.19o-Xylene
Temperature = 73.0F , duration time = 20273 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8
Page 10 of 17
-
Client Sample ID: 8Lab ID#: 1706146-04A
VOCS BY PASSIVE SAMPLER - GC/MS
c062123simFile Name:Dil. Factor: 1.00
Date of Collection: 6/7/17 11:16:00 AMDate of Analysis: 6/21/17
04:56 PMDate of Extraction: 6/20/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 0.13
0.131,2,4-Trimethylbenzene0.10 0.097 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.063 0.32 0.202-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.28 0.18Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.074 0.32 0.24Carbon
Tetrachloride0.10 0.073 Not Detected Not DetectedChlorobenzene0.10
0.066 Not Detected Not DetectedChloroform0.10 0.092 Not Detected
Not DetectedCyclohexane1.0 0.48 Not Detected Not
DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.073 0.16
0.12Ethyl Benzene0.10 0.085 0.20 0.17Heptane0.10 0.075 0.30
0.23Hexane0.10 0.076 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.087 Not
Detected Not DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 0.89 0.59Toluene0.10 0.084 Not Detected
Not DetectedTetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.071 0.41 0.29m,p-Xylene0.10 0.076
0.14 0.10o-Xylene
Temperature = 75.0F , duration time = 20277 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8
Page 11 of 17
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Client Sample ID: 12Lab ID#: 1706146-05A
VOCS BY PASSIVE SAMPLER - GC/MS
c062124simFile Name:Dil. Factor: 1.00
Date of Collection: 6/7/17 11:27:00 AMDate of Analysis: 6/21/17
05:23 PMDate of Extraction: 6/20/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 0.15
0.151,2,4-Trimethylbenzene0.10 0.097 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.063 0.32 0.202-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.44 0.28Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.074 0.38 0.28Carbon
Tetrachloride0.10 0.073 Not Detected Not DetectedChlorobenzene0.10
0.066 0.11 0.073Chloroform0.10 0.092 0.11 0.10Cyclohexane1.0 0.48
Not Detected Not DetectedEthanol
0.40 0.25 0.54 0.34Ethyl Acetate0.10 0.073 0.18 0.13Ethyl
Benzene0.10 0.085 0.29 0.24Heptane0.10 0.075 0.39 0.29Hexane0.10
0.076 Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.087 Not Detected Not
DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 1.2 0.79Toluene0.10 0.084 Not Detected
Not DetectedTetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.071 0.51 0.36m,p-Xylene0.10 0.076
0.16 0.12o-Xylene
Temperature = 75.0F , duration time = 20306 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8
Page 12 of 17
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Client Sample ID: DupLab ID#: 1706146-06A
VOCS BY PASSIVE SAMPLER - GC/MS
c062125simFile Name:Dil. Factor: 1.00
Date of Collection: 6/7/17 11:16:00 AMDate of Analysis: 6/21/17
05:49 PMDate of Extraction: 6/20/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 0.14
0.141,2,4-Trimethylbenzene0.10 0.097 Not Detected Not
Detected1,4-Dichlorobenzene0.10 0.063 0.32 0.202-Butanone (Methyl
Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 0.31 0.20Acetone0.40 0.25 Not
Detected Not DetectedBenzene0.10 0.074 0.33 0.24Carbon
Tetrachloride0.10 0.073 Not Detected Not DetectedChlorobenzene0.10
0.066 Not Detected Not DetectedChloroform0.10 0.092 Not Detected
Not DetectedCyclohexane1.0 0.48 Not Detected Not
DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.073 0.18
0.13Ethyl Benzene0.10 0.085 0.21 0.18Heptane0.10 0.075 0.71
0.53Hexane0.10 0.076 Not Detected Not DetectedMethyl tert-butyl
ether0.10 0.20 Not Detected Not DetectedNaphthalene0.10 0.087 Not
Detected Not DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 0.94 0.63Toluene0.10 0.084 Not Detected
Not DetectedTetrachloroethene0.10 0.072 Not Detected Not
DetectedTrichloroethene0.10 0.071 0.45 0.32m,p-Xylene0.10 0.076
0.14 0.11o-Xylene
Temperature = 75.0F , duration time = 20277 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8
Page 13 of 17
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Client Sample ID: TBLab ID#: 1706146-07A
VOCS BY PASSIVE SAMPLER - GC/MS
c062119simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 6/21/17 03:09 PMDate of
Extraction: 6/20/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 Not
Detected Not Detected1,2,4-Trimethylbenzene0.10 0.097 Not Detected
Not Detected1,4-Dichlorobenzene0.10 0.063 Not Detected Not
Detected2-Butanone (Methyl Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.074
Not Detected Not DetectedCarbon Tetrachloride0.10 0.073 Not
Detected Not DetectedChlorobenzene0.10 0.066 Not Detected Not
DetectedChloroform0.10 0.092 Not Detected Not
DetectedCyclohexane1.0 0.48 Not Detected Not DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.073 Not
Detected Not DetectedEthyl Benzene0.10 0.085 Not Detected Not
DetectedHeptane0.10 0.075 Not Detected Not DetectedHexane0.10 0.076
Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.087 Not Detected Not
DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 Not Detected Not DetectedToluene0.10
0.084 Not Detected Not DetectedTetrachloroethene0.10 0.072 Not
Detected Not DetectedTrichloroethene0.10 0.071 Not Detected Not
Detectedm,p-Xylene0.10 0.076 Not Detected Not Detectedo-Xylene
Temperature = 75.0F , duration time = 20306 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8
Page 14 of 17
-
Client Sample ID: Lab BlankLab ID#: 1706146-08A
VOCS BY PASSIVE SAMPLER - GC/MS
c062118simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 6/21/17 02:43 PMDate of
Extraction: 6/20/17
(ug/m3)(ug)(ug/m3)(ug)CompoundAmountAmountRpt. LimitRpt.
Limit
0.10 0.080 Not Detected Not Detected1,1,1-Trichloroethane0.10
0.064 Not Detected Not Detected1,2-Dichloroethane0.10 0.099 Not
Detected Not Detected1,2,4-Trimethylbenzene0.10 0.097 Not Detected
Not Detected1,4-Dichlorobenzene0.10 0.063 Not Detected Not
Detected2-Butanone (Methyl Ethyl Ketone)0.20 0.15 Not Detected Not
Detected4-Methyl-2-pentanone0.20 0.13 Not Detected Not
DetectedAcetone0.40 0.25 Not Detected Not DetectedBenzene0.10 0.074
Not Detected Not DetectedCarbon Tetrachloride0.10 0.073 Not
Detected Not DetectedChlorobenzene0.10 0.066 Not Detected Not
DetectedChloroform0.10 0.092 Not Detected Not
DetectedCyclohexane1.0 0.48 Not Detected Not DetectedEthanol
0.40 0.25 Not Detected Not DetectedEthyl Acetate0.10 0.073 Not
Detected Not DetectedEthyl Benzene0.10 0.085 Not Detected Not
DetectedHeptane0.10 0.075 Not Detected Not DetectedHexane0.10 0.076
Not Detected Not DetectedMethyl tert-butyl ether0.10 0.20 Not
Detected Not DetectedNaphthalene0.10 0.087 Not Detected Not
DetectedPropylbenzene0.10 0.081 Not Detected Not
DetectedStyrene0.10 0.067 Not Detected Not DetectedToluene0.10
0.084 Not Detected Not DetectedTetrachloroethene0.10 0.072 Not
Detected Not DetectedTrichloroethene0.10 0.071 Not Detected Not
Detectedm,p-Xylene0.10 0.076 Not Detected Not Detectedo-Xylene
Temperature = 75.0F , duration time = 20306 minutes.Container
Type: Radiello 130 (Solvent)
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8
Page 15 of 17
-
Client Sample ID: LCSLab ID#: 1706146-09A
VOCS BY PASSIVE SAMPLER - GC/MS
c062116simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 6/21/17 01:50 PMDate of
Extraction: 6/20/17
Limits%RecoveryCompoundMethod
111 70-1301,1,1-Trichloroethane102 70-1301,2-Dichloroethane96
70-1301,2,4-Trimethylbenzene86 50-1101,4-Dichlorobenzene97
70-1302-Butanone (Methyl Ethyl Ketone)120
70-1304-Methyl-2-pentanone77 70-130Acetone97 70-130Benzene112
70-130Carbon Tetrachloride110 70-130Chlorobenzene92
70-130Chloroform130 70-130Cyclohexane41 Q 50-130Ethanol99
70-130Ethyl Acetate106 70-130Ethyl Benzene114 70-130Heptane89
70-130Hexane113 70-130Methyl tert-butyl ether26 5-80Naphthalene114
70-130Propylbenzene79 20-100Styrene106 70-130Toluene106
70-130Tetrachloroethene109 70-130Trichloroethene103
70-130m,p-Xylene98 70-130o-Xylene
Q = Exceeds Quality Control limits.Container Type: NA - Not
Applicable
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8
Page 16 of 17
-
Client Sample ID: LCSDLab ID#: 1706146-09AA
VOCS BY PASSIVE SAMPLER - GC/MS
c062117simFile Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 6/21/17 02:17 PMDate of
Extraction: 6/20/17
Limits%RecoveryCompoundMethod
98 70-1301,1,1-Trichloroethane93 70-1301,2-Dichloroethane105
70-1301,2,4-Trimethylbenzene96 50-1101,4-Dichlorobenzene86
70-1302-Butanone (Methyl Ethyl Ketone)116
70-1304-Methyl-2-pentanone69 Q 70-130Acetone102 70-130Benzene98
70-130Carbon Tetrachloride114 70-130Chlorobenzene101
70-130Chloroform111 70-130Cyclohexane38 Q 50-130Ethanol94
70-130Ethyl Acetate115 70-130Ethyl Benzene109 70-130Heptane101
70-130Hexane101 70-130Methyl tert-butyl ether27 5-80Naphthalene128
70-130Propylbenzene83 20-100Styrene105 70-130Toluene109
70-130Tetrachloroethene106 70-130Trichloroethene110
70-130m,p-Xylene101 70-130o-Xylene
Q = Exceeds Quality Control limits.Container Type: NA - Not
Applicable
Limits%RecoverySurrogatesMethod
103 70-130Toluene-d8
Page 17 of 17
-
http://www.teklabinc.com/
July 19, 2017
WorkOrder: 17061062West Lake NPDES AnalysisRE:
Dear Paul V. Rosasco, P.E.:
TEKLAB, INC received 3 samples on 6/15/2017 6:40:00 PM for the
analysis presented in the following report.
Samples are analyzed on an as received basis unless otherwise
requested and documented. The sample results contained in this
report relate only to the requested analytes of interest as
directed on the chain of custody. NELAP accredited fields of
testing are indicated by the letters NELAP under the Certification
column. Unless otherwise documented within this report, Teklab Inc.
analyzes samples utilizing the most current methods in compliance
with 40CFR. All tests are performed in the Collinsville, IL
laboratory unless otherwise noted in the Case Narrative.
All quality control criteria applicable to the test methods
employed for this project have been satisfactorily met and are in
accordance with NELAP except where noted. The following report
shall not be reproduced, except in full, without the written
approval of Teklab, Inc.
If you have any questions regarding these tests results, please
feel free to call.
Sincerely,
25923 Gateway DriveGolden, CO 80401
(303) 940-3426TEL:FAX:
Paul V. Rosasco, P.E.Engineering Management Support, Inc.
Emily PohlmanProject Manager(618)344-1004 ex
[email protected]
Page 1 of 25
-
This reporting package includes the following:
Report Contents
Client Project: West Lake NPDES Analysis
Client: Engineering Management Support, Inc.
Report Date: 19-Jul-17
Work Order: 17061062
http://www.teklabinc.com/
Cover Letter 1
Report Contents 2
Definitions 3
Case Narrative 4
Accreditations 5
Laboratory Results 6
Sample Summary 12
Dates Report 13
Quality Control Results 16
Receiving Check List 25
Chain of Custody Appended
Page 2 of 25
-
____TeklabHdrP
Definitions
Client Project: West Lake NPDES Analysis
Client: Engineering Management Support, Inc.
Report Date: 19-Jul-17
Work Order: 17061062
http://www.teklabinc.com/
Abbr DefinitionCCV Continuing calibration verification is a
check of a standard to determine the state of calibration of an
instrument between recalibration.
DF Dilution factor is the dilution performed during analysis
only and does not take into account any dilutions made during
sample preparation. The reported result is final and includes all
dilutions factors.
DNI Did not ignite
DUP Laboratory duplicate is an aliquot of a sample taken from
the same container under laboratory conditions for independent
processing and analysis independently of the original aliquot.
ICV Initial calibration verification is a check of a standard to
determine the state of calibration of an instrument before sample
analysis is initiated.
IDPH IL Dept. of Public Health
LCS Laboratory control sample, spiked with verified known
amounts of analytes, is analyzed exactly like a sample to establish
intra-laboratory or analyst specific precision and bias or to
assess the performance of all or a portion of the measurement
system. The acceptable recovery range is in the QC Package
(provided upon request).
LCSD Laboratory control sample duplicate is a replicate
laboratory control sample that is prepared and analyzed in order to
determine the precision of the approved test method. The acceptable
recovery range is listed in the QC Package (provided upon
request).
MBLK Method blank is a sample of a matrix similar to the batch
of associated sample (when available) that is free from the
analytes of interest and is processed simultaneously with and under
the same conditions as samples through all steps of the analytical
procedures, and in which no target analytes or interferences should
present at concentrations that impact the analytical results for
sample analyses.
MDL Method detection limit means the minimum concentration of a
substance that can be measured and reported with 99% confidence
that the analyte concentration is greater than zero.
MS Matrix spike is an aliquot of matrix fortified (spiked) with
known quantities of specific analytes that is subjected to the
entire analytical procedures in order to determine the effect of
the matrix on an approved test method’s recovery system. The
acceptable recovery range is listed in the QC Package (provided
upon request).
MSD Matrix spike duplicate means a replicate matrix spike that
is prepared and analyzed in order to determine the precision of the
approved test method. The acceptable recovery range is listed in
the QC Package (provided upon request).
MW Molecular weight
ND Not Detected at the Reporting Limit
NELAP NELAP Accredited
PQL Practical quantitation limit means the lowest level that can
be reliably achieved within specified limits of precision and
accuracy during routine laboratory operation conditions. The
acceptable recovery range is listed in the QC Package (provided
upon request).
RL The reporting limit the lowest level that the data is
displayed in the final report. The reporting limit may vary
according to customer request or sample dilution. The reporting
limit may not be less than the MDL.
RPD Relative percent difference is a calculated difference
between two recoveries (ie. MS/MSD). The acceptable recovery limit
is listed in the QC Package (provided upon request).
SPK The spike is a known mass of target analyte added to a blank
sample or sub-sample; used to determine recovery deficiency or for
other quality control purposes.
Surr Surrogates are compounds which are similar to the analytes
of interest in chemical composition and behavior in the analytical
process, but which are not normally found in environmental
samples.
TIC Tentatively identified compound: Analytes tentatively
identified in the sample by using a library search. Only results
not in the calibration standard will be reported as tentatively
identified compounds. Results for tentatively identified compounds
that are not present in the calibration standard, but are assigned
a specific chemical name based upon the library search, are
calculated using total peak areas from reconstructed ion
chromatograms and a response factor of one. The nearest Internal
Standard is used for the calculation. The results of any TICs must
be considered estimated, and are flagged with a "T". If the
estimated result is above the calibration range it is flagged
"ET"
TNTC Too numerous to count ( > 200 CFU )
Qualifiers# - Unknown hydrocarbon B - Analyte detected in
associated Method Blank
E - Value above quantitation range H - Holding times
exceeded
I - Associated internal standard was outside method criteria J -
Analyte detected below quantitation limits
M - Manual Integration used to determine area response ND - Not
Detected at the Reporting Limit
R - RPD outside accepted recovery limits S - Spike Recovery
outside recovery limits
T - TIC(Tentatively identified compound) X - Value exceeds
Maximum Contaminant Level
Page 3 of 25
-
Case Narrative
Client Project: West Lake NPDES Analysis
Client: Engineering Management Support, Inc.
Report Date: 19-Jul-17
Work Order: 17061062
http://www.teklabinc.com/
Cooler Receipt Temp: 3.42 °C
Field pH was provided by Feezor Engineering.
Uranium analysis was performed by Pace, PA. See attached report
for results and QC.
Locations
___________________________________Collinsville
5445 Horseshoe Lake Road
Collinsville, IL 62234-7425
(618) 344-1004
(618) 344-1005
[email protected]
___________________________________Springfield
3920 Pintail Dr
Springfield, IL 62711-9415
(217) 698-1004
(217) 698-1005
[email protected]
___________________________________Kansas City
8421 Nieman Road
Lenexa, KS 66214
(913) 541-1998
(913) 541-1998
[email protected]
___________________________________Collinsville Air
5445 Horseshoe Lake Road
Collinsville, IL 62234-7425
(618) 344-1004
(618) 344-1005
[email protected]
___________________________________Chicago
1319 Butterfield Rd.
Downers Grove, IL 60515
(630) 324-6855
[email protected]
Page 4 of 25
-
____TeklabHdrP
Accreditations
Client Project: West Lake NPDES Analysis
Client: Engineering Management Support, Inc.
Report Date: 19-Jul-17
Work Order: 17061062
http://www.teklabinc.com/
NELAPState Cert # Exp Date LabDept
Illinois 100226 1/31/2018 CollinsvilleNELAPIEPA
Kansas E-10374 4/30/2018 CollinsvilleNELAPKDHE
Louisiana 166493 6/30/2018 CollinsvilleNELAPLDEQ
Louisiana 166578 6/30/2018 CollinsvilleNELAPLDEQ
Texas T104704515-12-1 7/31/2018 CollinsvilleNELAPTCEQ
Arkansas 88-0966 3/14/2018 CollinsvilleADEQ
Illinois 17584 5/31/2017 CollinsvilleIDPH
Indiana C-IL-06 1/31/2018 CollinsvilleISDH
Kentucky 98006 12/31/2017 CollinsvilleKDEP
Kentucky 0073 1/31/2018 CollinsvilleUST
Louisiana LA170027 12/31/2017 CollinsvilleLDPH
Missouri 930 1/31/2018 CollinsvilleMDNR
Missouri 00930 5/31/2017 CollinsvilleMDNR
Oklahoma 9978 8/31/2017 CollinsvilleODEQ
Page 5 of 25http://www.teklabinc.com/
-
TeklabHdrP
Laboratory Results
Client Project: West Lake NPDES Analysis
Client: Engineering Management Support, Inc.
Report Date: 19-Jul-17
Work Order: 17061062
http://www.teklabinc.com/
Analyses Result Units Date AnalyzedRL DFCertification Qual
Collection Date: 06/15/2017 8:49
Lab ID: 17061062-001 Client Sample ID: OU-1-001
Matrix: AQUEOUS
Batch
STANDARD METHOD 4500-H B FIELDpH 06/15/2017 8:491.00 17.93
R234055
EPA 1664AHexane Extractable Material J 06/20/2017 12:035 mg/L
14NELAP R234236
EPA 600 375.2 REV 2.0 1993 (TOTAL)Sulfate S 06/16/2017 16:22200
mg/L 20214NELAP R234083
MS and MSD did not recover within control limits. Result is
verified by re-analysis at a dilution.
STANDARD METHODS 2540 DTotal Suspended Solids 06/20/2017 14:066
mg/L 136NELAP R234218
STANDARD METHODS 2540 FSolids, Settleable 06/16/2017 10:370.1
ml/L 10.1NELAP R234070
STANDARD METHODS 3500-CR BChromium, Hexavalent 06/15/2017
21:140.010 mg/L 2< 0.010NELAP R234036
Elevated reporting limit due to sample composition.
STANDARD METHODS 4500-CL E (TOTAL)Chloride 06/20/2017 17:0310
mg/L 258NELAP R234261
STANDARD METHODS 4500-NH3 H MODIFIED (TOTAL)Nitrogen, Ammonia
(as N) S 06/19/2017 18:100.10 mg/L 10.15NELAP R234156
MS and/or MSD did not recover within control limits due to
matrix interference.
STANDARD METHODS 5210 BBiochemical Oxygen Demand 06/16/2017
11:295 mg/L 117NELAP 131299
STANDARD METHODS 5220 D (TOTAL)Chemical Oxygen Demand 06/21/2017
11:1350 mg/L 1104NELAP R234246
TRIVALENT CHROMIUMTrivalent Chromium 06/15/2017 21:110.010 mg/L
2< 0.010 R234036
Elevated reporting limit due to sample composition.
EPA 600 245.1 R3.0 (TOTAL)Mercury 06/20/2017 8:260.00020 mg/L
1< 0.00020NELAP 131337
EPA 600 4.1.4, 200.7R4.4, METALS BY ICP (TOTAL)Aluminum
06/19/2017 18:170.0250 mg/L 10.448NELAP 131300Antimony 06/20/2017
17:230.0500 mg/L 1< 0.0500NELAP 131300Arsenic 06/19/2017
18:170.0250 mg/L 1< 0.0250NELAP 131300Beryllium 06/19/2017
18:170.0005 mg/L 1< 0.0005NELAP 131300Cadmium 06/19/2017
18:170.0020 mg/L 1< 0.0020NELAP 131300Cobalt J 06/19/2017
18:170.0050 mg/L 10.0038NELAP 131300Copper 06/19/2017 18:170.0050
mg/L 10.0122NELAP 131300Iron 06/19/2017 18:170.0200 mg/L 11.05NELAP
131300Magnesium 06/21/2017 11:270.0500 mg/L 122.6NELAP 131300Nickel
06/19/2017 18:170.0050 mg/L 10.0112NELAP 131300Selenium 06/19/2017
18:170.0400 mg/L 1< 0.0400NELAP 131300Silver 06/19/2017
18:170.0050 mg/L 1< 0.0050NELAP 131300Thallium 06/19/2017
18:170.0500 mg/L 1< 0.0500NELAP 131300Zinc 06/19/2017
18:170.0100 mg/L 10.0609NELAP 131300
STANDARD METHODS 2340 B, HARDNESS (TOTAL)Hardness, as ( CaCO3 )
06/21/2017 0:001.00 mg/L 1375NELAP 131300
EPA 600 624 (MODIFIED), VOLATILE ORGANIC COMPOUNDS BY
GC/MSBenzene 06/19/2017 14:542.0 µg/L 1NDNELAP 131405
Page 6 of 25
-
TeklabHdrP
Laboratory Results
Client Project: West Lake NPDES Analysis
Client: Engineering Management Support, Inc.
Report Date: 19-Jul-17
Work Order: 17061062
http://www.teklabinc.com/
Analyses Result Units Date