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UNIT-3
ELECTR0-CHEMICAL PROCESSES
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Electro-chemical Machining
Latest and potentially available methodMichael faraday Electroplating
ECM Reverse of Electroplating
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Chemistry of Electroplating
Metal to be plated by metal negative charge- cathode
Metal used plate positive Charge Anode
Put in the same solution
Electrons flow from + to where the metal to beplated is being reduced and the metal being used inthe process is being oxidized.
The positive ions from the salt solution and the metalbeing used to plate "stick" onto the object being plated
since it has a negative charge. The thickness of themetal plating depends on how long you leave it in thesolution, and the flow of electrons.
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ECM Reverse of Electroplating
ECM uses a shaped tool or Electrode
Tool Cathode Work piece Anode
Electrolyte is pumped
Chemical properties of the electrolytes
Constituents go into the electrolyte
By proper design the cavity or hole which is
exactly produced reproduces the tool shape.
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Shaped tool is connected to negative terminal(cathode)
Tool should be made up of materials have enoughthermal and electrical conductivity, high Chemical
resistance to electrolyte.Stainless steel, titanium, Brass, copper,
Reinforced plastics.
Shaping the tool is not a problem, Easy tomachine
Cold forging, electroforming Favorablemethods.
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No restriction except to be a good conductorof electricity
Chemical characteristics of the work material
affect MRR. MRR atomic weight and 1/ to the valency
of the work material.
Fixtures should be of insulating material.Epoxy resin 0r glass fibres
For cheapest purpose Perspex , PVC
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Low voltages 2 to 20v
Rare time 30v
Current 800 amp/cm
2
three phase 440v, ACpower supply converted by a step down
transformer, Rectifier
Protective circuits is given Mishandling,Incorrect fitting.
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Electrolyte
completing the electric circuit between thetool and the work piece
Allowing desirable machining reactions tooccur
Carrying away heat generated during the
chemical reactionCarrying away products of reaction from the
zone of machining
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Commonly used electrolyte
Most application-sodium chloride in water isused
Corrosive is a problem
Sodium nitrate solution less corrosive innature
Potassium nitrate, sodium chromate, sodium
hydroxide, sodium fluoride and potassiumchloride.
Mixture of two or more is efficient
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Working life of the
electrolyte
Composition of the electrolyte changes duringuse
Main changes are
Loss of hydrogen Reduces the electricalconductivity of the electrolyte
Loss of water due to evaporation
Precipitate formation
Salt absorption by the precipitate
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Temperature and pressure
Difference in temperature is an important factor
Kubeth & Heitmann recorded 45C Decreases the specific resistance of the electrolyte
Precautions taken to overheating of the electrolyte
An increase in temperature speed up theelectrode reactions, reduces the over voltages
required
Voltage required is reduces with increase intemperature
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In order to obtain good results
Remove the contaminated electrolyte from the
working Gap
Minimize polarization.
Limit the rise in temperature of the electrolyte.
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Working of ECM
Is a method of removing metal particles by an
electrochemical process instead of standard
machining methods.
First introduction of ECM in 1929 by Gusseff, its
industrial applications
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The workpiece is made anode of the setup and
material is removed by anodic dissolution.Tool is made cathode and kept in close proximity
to the workpiece and current is passed throughthe circuit.
Both electrodes are immersed into the electrolytesolution.
This works on the basis of Faradays law ofelectrolysis. The cavity machined is the mirror
image of the tool. MRR in this process can easily be calculatedaccording to Faradays law.
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Mechanism of Electrolysis
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First Law The quantity of a substance
produced by electrolysis is proportional to the
quantity of electricity used.
Second Law For a given quantity of electricity
the quantity of substance produced is
proportional to its weight.
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Advantages
There is no cutting forces therefore clamping
is not required except for controlled motion of
the work piece.
There is no heat affected zone.
Very accurate.
Relatively fast
Can machine harder metals than the tool.
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Disadvantages
More expensive than conventional machining.
Need more area for installation.
Electrolytes may destroy the equipment.
Not environmentally friendly (sludge and
other waste)
High energy consumption.
Material has to be electrically conductive.
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Applications
The most common application of ECM is highaccuracy duplication. Because there is no tool wear,it can be used repeatedly with a high degree ofaccuracy.
It is also used to make cavities and holes in variousproducts.
It is commonly used on thin walled, easilydeformable and brittle material because they wouldprobably develop cracks with conventionalmachining.
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Economics
The process is economical when a largenumber of complex identical products need tobe made (at least 50 units)
Several tools could be connected to a cassetteto make many cavities simultaneously. (i.e.cylinder cavities in engines)
Large cavities are more economical on ECMand can be processed in 1/10 the time ofEDM.
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Products
The two most common products of ECM areturbine/compressor blades and rifle barrels. Each of thoseparts require machining of extremely hard metals with certainmechanical specifications that would be really difficult to
perform on conventional machines. Some of these mechanical characteristics achieved by ECM
are:
Stress free grooves.
Any groove geometry.
Any conductive metal can be machined. Repeatable accuracy of 0.0005.
High surface finish.
Fast cycle time.
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Safety Considerations
Several sensors are used to control short circuit, turbulence,passivation, contact and overcurrent sensors. In case ofcontact, immense heat would be generated melting the tool,evaporating the electrolyte and cause a fire.
The worker must be insulated to prevent electrocution. The tool and the work piece must be grounded before any
handling is performed.
Hydrogen gas emitted is very flammable, so it should bedisposed of properly and fire precautions should be taken.
The waste material is very dangerous and environmentallyunfriendly (metal sludge) so it must be recycle or disposed of
properly.
Electrolyte is highly pressurized and worker must check for
minor cracks in piping before operating