EAS 4/8803: Experimental Methods in AQ

EAS 4/8803: Experimental Methods in AQProf. Rodney WeberWeeks 1 4 Experiments 1 & 2Prof. Michael BerginWeeks 5 8 Experiments 3 & 4Dr. Karsten BaumannWeeks 8 11 Experiments 5 & 6

Handout: AQ Management in the US, NRC, Natl Acad Press, 2004 http://books.nap.edu/catalog/10728.html

Recommended: Baumbach, AQ Control, Springer 1996Seinfeld & Pandis, Atm Chem & Phys, Wiley 1998Finlayson-Pitts & Pitts, Chem of U & L Atmos, AP 1999Warneck, Chem of Natural Atmos, 2nd Ed, AP 2000Data and Findings from SCISSAP and FAQS http://cure.eas.gatech.edu/faqs/index.html

EAS 4/8803

EAS 4/8803: Experimental Methods in AQSo far:Measurement Errors and UncertaintiesRandom (Precision), Systematic (Accuracy), Rounding (DL), Comparing (Correlations)Flow Rate Measurements (Exp 1)Volumetric (cm3/s), Mass (g/s), Fs = Fa*Ta/Ts * Ps/Pa (Ideal Gas Law)PM Size & Number Distribution (Exp 2)Dp, Modes (UF, Fine, Coarse, Primary, Secondary)Methods (SMPS, APS, OPC, SEM, TEM )Aerosol Optical Properties (Exp 3 & 4)Scattering, Absorption, Extinction (Visibility, Climate)Methods (OPC, Nephelometer)

EAS 4/8803

EAS 4/8803: Experimental Methods in AQWeeks 8 - 11:Air Quality Management (AQM)Clean Air Act (History, Objectives, NAAQS)Emissions and Atmospheric Trends (Links)Principal Measurement Techniques (O3, NOx, CO, SO2, Pb, PM)Measurement of CO (Exp 5)NDIR Method (Interferences, Stability, DL, Precision, Accuracy)Controlling O3Why controlling O3 (Agriculture, Health)Photochemical Processes (NOx vs VOC sensitivities, limitations)Ambient Measurements and Trends (World, USA, GA)Measurement of O3 (Exp 6)UV Absorption (Interferences, Stability, DL, Precision, Accuracy)

EAS 4/8803

Clean Air Act (CAA) GoalsProtecting and promoting human health & public welfare by:Mitigating potentially harmful human and ecosystem exposure to six criteria pollutants: CO, NO2, SO2, O3, PM, and lead (Pb).Limiting the sources of and risks from exposure to HAPs (air toxics).Protecting and improving visibility impairment in wilderness areas and national parks.Reducing the emissions of species that cause acid rain, specifically SO2 and NOx.Curbing the use of chemicals that have the potential to deplete the stratospheric O3 layer.

EAS 4/8803

The Air Pollutants of Concern in AQMCarbon monoxide (CO)Sulfur dioxide (SO2)Nitrogen dioxide (NO2)Particulate matter (PM)Ozone (O3)Lead (Pb)Air toxics (solvents, fuels, metals, etc.)Haze

EAS 4/8803

Federal AQM Legislation History

EAS 4/8803

History: CAAs First NAAQS

EAS 4/8803

1990 CAA AmendmentsTitle I: Non-attainment regionsNon-attainment regions for O3 are ranked in terms of pollution severity; deadlines to achieve NAAQS. New and amended NAAQS must be attained in 5 years (possible 5-yr extension).Title II: Mobile sourcesGasoline reformulation to lower toxic and VOC by 1997.Reduction in NOx (60%) and HC (40%) LDV emissions; cold T (20F) CO emissions standards > 1994.Clean car (ZEV, electric car) pilot program in California (150,000/300,000 vehicles by model year 1996/99).Title III: ToxicsEmissions of 189 HAPs controlled. EPA-approved MACT mandated.Title IV: Acid rain (Electricity Generation Facilities)NOx: cut emissions by 2.0 x 106 tons/yr; SO2: reduce to 9.2 x 106 / 8.9 x 106 tons/yr (US total) by 2000 / 10.Phase I (beginning 1995): 110 large power plants; Phase II (beginning 2000): remaining unitsPolicy: market-based cap and trade rather than command and control. If a utility reduces SO2 emissions below their emissions allowance , the utility can sell their extra allowance to another utility.Title V: PermitsNew and existing major sources must secure permits, duration 5 yr. Fees to sustain state air pollution control agencies.Title VI: Stratospheric ozonePhase out chlorofluorocarbons, halons, and carbon tetrachloride by2000; CH3CCl3 / HCFCs by 2002 / 30Title VII: EnforcementLarger penalties.

EAS 4/8803

Process of Setting/Amending NAAQS

EAS 4/8803

History: NAAQS Reviews and Revisions

EAS 4/8803

NAAQS Effective January 2003Primary Standard (Health-Based) Secondary Std (Welfare-Based)Type LevelType LevelPM10 Annual arithmetic mean50 g/m3Same as primary24-hr avg not to be exceeded150 g/m3Same as primary more than 1/yr on avg over 3yr

PM2.5Spatial and annual 15 g/m3Same as primary arithmetic mean in area 98th percentile of 24-hr avg65 g/m3Same as primaryO3Maximum daily 1-hr avg to be 0.12 ppmSame as primary exceeded no more than 1/yr averaged over 3 consec years3-yr avg of the annual fourth0.08 ppmSame as primary highest daily 8-hr average

NO2 Annual arithmetic mean0.053 ppm Same as primary

SO2 Annual arithmetic mean 0.03 ppm3-hr 0.50 ppm24-hr average 0.14 ppmCO 8-hr (not to be exceeded more9 ppmNo secondary than once per year)1-hr (not to be exceeded more35 ppm No secondary than once per year)

Lead Maximum quarterly average1.5 g/m3 Same as primary

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Role of Science in AQM

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Four Topics of Concern for AQM

EAS 4/8803

Q: Why should we care about air quality? A: Each day a typical adult may consume...2 - 10 lbs. of food (1000 - 3000 calories); 1 - 6 lbs. of fluids (12 - 96 oz.);

EAS 4/8803

Concern: Human HealthAsthma is a chronic lung disease that affects a persons fundamental ability to breathe. Its prevalence in the U.S. population is epidemic. The percentage of the population with the disease has nearly doubled since 1980. In 2000, approximately 11 million people in the U.S. experienced an asthma attack. Morbidity & Mortality: 2002 Chart Book on Cardiovascular, Lung, and Blood Diseases; National Institutes of Health, National Heart, Lung, and Blood Institute; 2002.

EAS 4/8803

Concern: EconomicsThe estimated economic cost of asthma in the U.S. in 1998 was $11.3 billion. By 2002, this estimate had increased to $14.0 billion. This latter figure includes direct costs of $3.1 billion for hospital care, $2.6 billion for physicians services, and $3.7 billion for prescription drugs. Direct medical costs of asthma account for approximately 1% of all health care expenditures in the United States. The remaining $4.6 billion in costs are estimated indirect costs that include loss of productivity due to mortality, and decreases in productivity due to absences from work or school. Asthma and the Environment: A Strategy to Protect Children; Presidents Task Force on Environmental Health Risks and Safety Risks to Children; January 28, 1999; Revised May 2000.

EAS 4/8803

Link to AQ Ozone is one of many environmental factors that can trigger asthma attacks in those that have the disease. Studies show that ERVs for treatment of asthma increase by 30 to 40% when [O3] is elevated.

Romieu I, et al.; American J. Epidemiology; 141 (6): 546-553; 1995.Stieb DM, et al.; Env. Health Perspectives; 104 (12): 1354-1360; 1996.Thurston GD, et al.; J. Exposure Analysis and Env. Epidemiology; 2 (4): 429-450; 1992.Weisel CP, et al.; Env. Health Perspecitves; 103: 97-102 Suppl. 2; 1995.White MC, et al.; Env. Research; 65 (1): 56-68; 1994.Friedman MS, et al.; J. Am. Medical Assoc.; 285 (7): 897-905; 2001.Tolbert PE, et al.; Am. J. Epidemiology; 151 (8): 798-810; 2000.EPA 454/K-02-001; US EPA Office of Air Quality Planning and Standards (OAQPS); September 2002.

EAS 4/8803

Symptom: Human HealthEvidence of health impact of ozone on human respiratory system based on an experimental study involving human subjects. Left: A healthy lung airway, and right: A lung airway inflamed from exposure to ozone.Ozone and Your Health. EPA 452/F-99-003. Office of Air and Radiation, U.S. EPA: http://www.epa.gov/airnow/brochure.html

EAS 4/8803

Symptom: Ecological HealthCotton showing chronic response to ozone on the lower leaves after exposure to rel. low concentrations (e.g. < 40 ppb), with periodic, random, intermittent episodes of rel. high ozone concentrations (e.g. > 80 ppb) throughout the plant growth season. Krupa, S.V., A.E.G. Tonneijck, and W.J. Manning. 1998. Ozone. Pp. 2-1-2-28 in Recognition of Air Pollution Injury to Vegetation: A Pictorial Atlas, 2nd Ed, R.B. Flagler, et al., eds. Pittsburgh, PA: Air & Waste Management Association.

EAS 4/8803

Symptom: Buildings, Monuments & Parks

EAS 4/8803

Symptom: Visibility

EAS 4/8803

Symptom: VisibilityStandard visual range for the period 1996-1998 in units of kilometers. Visibility Information Exchange Web System, 2003.

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Link to AQLast (O3) non-attainment designations in 1991.

More than 90% of the affected population resided in 70 metro areas.

Average Size: ~2 million(Cincinnati)Median Size: ~1 million(Louisville)Largest: ~20 million (New York)Smallest: ~87,000 (Owensboro, KY)Counties in which the 1998 2nd daily maximum 1-h [O3] exceeds the 1-h average 120 ppb NAAQS. EPA 2000.

EAS 4/8803

Consequences of New O3 NAAQSCounties in which the 1998 4th daily maximum 8-h [O3] exceeds the 8-h average 80 ppb NAAQS. EPA 2000.In addition to most of the original 70 metro areas, ca. 60 additional metro areas may be impacted.

Of these 60 new metro areas

Average Size: ~360,000 (Madison, WI)Median Size: ~290,000 (Macon, GA)Largest: ~1.3 million (San Antonio)Smallest: ~74,000 (Victoria, TX)

EAS 4/8803

PM2.5 NAAQS will also impact many smaller citiesMonitors at which the 1999 annual average [PM2.5] exceeds (yellow and red) the 15 g/m3 annual average PM2.5 NAAQS.

EAS 4/8803

Annual Average PM2.5 in Urban Areas, 2002

EAS 4/8803

Annual Average PM2.5 in Rural Areas, 2002Source: IMPROVE Network, 2002

EAS 4/8803

Measurement SitesSouthern Center for theIntegratedStudy ofSecondary AirPollutants(US EPA)

Fall-lineAirQuality Study(GA-EPD)

EAS 4/8803

PM2.5 Seasonal Comparison: Suburban vs RuralFall-99Winter-99/00Summer-99Rural DixonSuburbanHendersonville Differences in composition are insignificant regionally but not seasonally Differences in mass related to different BL dynamics and SOA (Un-ID)

EAS 4/8803

Chart5

32.5581275228

2.7460954353

12.618546291

1.6089523363

20.1202340236

8.0480936094

3.524036737

1.0072229233

17.7686911212

SO4= NO3- NH4+ EC OC OOE LOA Others UnID

24.3 +-9.3

Atl Sum99

Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6TOC.6+svocOthersUnID.4UnID.6UnID.6svMw/CwMw/Cw +svocNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6UnID.6svTOC.6+svocCheckSum

ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%][%][%]

7/287/28/99 7:507/29/99 6:00132622.142.352.290.980.857.9110.053.506.470.0850.3555.411.8243.440.093.480.000.4610.490.800.400.0912.431.36XAD4.977.461.2818.6921.180.098.876.382.1-19372183324.11.18.03.128.611.43.00.214.743.048.733.2139.7

7/307/30/99 6:007/31/99 6:00121820.344.002.173.210.416.386.822.853.880.0954.2853.950.7143.360.054.220.080.7310.530.390.730.0012.932.02XAD5.177.761.1219.2221.810.136.513.921.9-23412219-324.31.79.74.729.811.92.60.315.044.350.333.4143.0

8/18/1/99 6:008/2/99 6:00144024.053.382.291.580.627.9616.137.049.070.0261.6459.001.9149.040.134.730.160.120.7612.760.910.550.2911.711.11XAD4.687.031.7518.1420.480.4111.128.782.3-262122661526.01.59.72.323.99.63.60.822.737.041.835.8137.2

8/38/3/99 6:038/4/99 6:01143721.3498327.30.1582.182.3824.1369.9125.52.812.471.100.523.1610.724.845.850.0342.4239.790.8132.240.033.980.000.000.5010.560.000.200.258.360.95XAD3.345.010.4512.1513.820.034.072.401.9-2218220732.71.612.32.925.910.41.40.112.637.742.945.0138.2

8/58/5/99 6:038/6/99 6:01143823.5698028.00.5572.182.5937.8355.1114.32.332.421.970.375.469.654.405.220.0363.3066.600.7750.780.025.670.060.010.6818.350.180.320.269.231.18XAD3.695.540.7613.6815.530.0911.139.282.6-314113827936.11.311.22.318.27.31.50.221.926.930.649.7129.1

8/78/7/99 6:038/7/99 18:0172012.0498330.1-0.3451.912.9825.9289.4152.22.934.460.711.089.309.313.725.580.0150.0674.190.9240.580.033.960.030.080.7613.240.460.430.027.970.653.86XAD3.194.780.9112.0813.6717.530.139.778.174.312.61.8-219122766832.61.99.81.619.77.92.20.324.129.833.744.910.643.2186.2

8/78/7/99 18:138/8/99 6:0170811.6798227.21.1622.290.0947.0228.62.521.125.310.262.9814.797.667.130.0058.8562.621.3147.810.025.090.000.000.6913.110.790.320.129.970.707.33XAD3.995.981.2315.2017.1924.530.0213.0011.013.672.71.6-28211273227.41.410.61.520.98.32.60.027.231.836.037.77.751.3191.7

8/98/9/99 6:038/10/99 6:00143723.8597827.3-0.0702.592.6726.0048.297.02.062.141.160.567.526.453.033.410.0238.1440.721.1731.300.003.380.030.000.499.850.160.320.126.000.753.55XAD2.403.600.608.9910.1913.740.037.816.613.062.71.7-18782052631.51.610.82.419.27.71.90.124.928.732.643.39.843.9183.2

8/108/10/99 18:018/11/99 5:5872011.8497925.80.4873.030.0820.4633.275.00.610.331.110.080.666.172.783.350.0458.2055.751.0745.110.016.390.020.7016.870.320.380.2010.841.120.70XAD4.346.500.9016.0718.2418.940.033.931.761.061.81.7-35411351837.41.514.22.524.09.62.00.18.735.640.451.42.342.0180.6

8/118/11/99 6:048/12/99 6:00143623.9598029.1-0.1632.542.9541.1147.0121.01.951.991.830.729.2511.495.456.020.0257.6648.642.0140.440.074.380.000.090.7411.520.750.600.249.170.873.93XAD3.675.501.5814.4216.2620.180.168.356.522.592.31.6-24312240928.51.810.82.122.79.13.90.420.635.740.239.26.449.9192.0

8/138/13/99 6:028/13/99 17:4370111.8098030.9-0.5602.772.5338.7760.8105.01.902.870.870.708.7912.645.437.210.0039.6144.491.5237.110.003.140.190.000.698.490.000.590.0010.121.582.37XAD4.056.070.5914.7516.7719.140.198.266.243.872.21.8-174111771422.91.98.54.327.310.91.60.522.339.745.231.510.451.6200.7

8/138/13/99 18:008/14/99 6:5677612.7697926.60.4732.670.0545.3733.41.200.911.950.251.717.063.393.670.0019.2620.910.6919.960.002.460.040.000.525.860.000.000.000.000.000.000.000.000.0411.0711.07-1368122-629.42.612.30.00.255.50.00.040.495.9

8/158/15/99 6:028/15/99 17:4570311.6698227.8-0.4552.033.3712.4974.1115.03.222.640.260.482.648.123.444.670.0219.9633.223.1223.080.003.000.000.000.445.700.990.810.006.650.26XAD2.663.991.8111.1112.440.002.561.231.8-1667119-4024.71.913.01.128.811.57.80.011.148.253.934.0147.2

8/158/15/99 17:598/16/99 6:0072111.9498428.70.7632.550.0735.7545.22.971.201.250.261.1710.624.915.710.0028.9543.682.7734.170.103.390.000.000.257.601.290.770.0014.360.68XAD5.748.612.0622.1525.030.10-0.00-2.871.4-1884158-2622.20.79.92.042.016.86.00.3-0.064.873.230.6168.7

8/178/17/99 6:018/18/99 6:00143923.7898427.7-0.6592.222.4840.6753.6138.02.373.181.500.556.0312.835.767.020.0540.3846.561.7542.130.113.870.000.000.6311.300.570.530.0910.550.943.82XAD4.226.331.1815.9518.0621.880.119.337.223.402.31.7-214102353126.81.59.22.225.010.02.80.322.137.942.936.98.151.9199.8

8/188/18/99 10:028/18/99 17:004187.1398033.4-1.6341.832.8817.57122.9136.01.994.670.130.286.0010.603.616.790.2028.8430.625.9435.670.003.640.000.002.069.752.671.410.247.810.401.13XAD3.134.694.3215.2616.8317.950.004.563.001.872.01.7-202332033527.35.810.21.121.98.812.10.012.842.847.237.65.250.3195.9

8/198/19/99 6:028/19/99 18:0071812.0898030.5-0.8441.872.6534.8894.3182.02.817.130.040.355.8610.833.707.020.1035.1234.755.4240.360.033.960.160.001.4910.252.950.880.278.751.634.98XAD3.505.254.1016.3518.1023.080.196.494.74-0.242.11.4-220242131825.43.79.84.021.78.710.20.516.140.544.834.9-0.657.2193.0

8/218/21/99 6:028/22/99 6:00143823.6598225.8-0.6521.693.2431.7650.6110.01.862.510.660.385.186.372.673.630.0627.8934.352.2630.140.084.300.000.030.7113.151.170.440.245.340.603.89XAD2.143.201.859.3210.3914.280.111.950.88-3.011.81.0-239112744743.62.314.32.017.77.16.10.46.530.934.560.0-10.047.4169.3

8/238/23/99 6:028/24/99 6:00143823.5998125.2-0.4752.482.2424.5049.999.01.630.350.650.212.077.413.264.090.0626.4435.862.2328.670.013.400.000.001.1110.840.320.590.266.250.614.20XAD2.503.751.179.9211.1715.370.012.791.54-2.661.81.1-188182265537.83.911.92.121.88.74.10.09.734.639.052.0-9.353.6179.6

8/258/25/99 6:028/26/99 6:00143823.4098022.9-0.5912.652.6823.1023.951.01.290.680.560.114.452.861.211.650.0019.841.2721.110.041.460.000.011.025.190.240.500.003.450.793.20XAD1.382.070.745.576.269.460.057.036.343.143.41.8-81161084324.64.86.93.716.36.53.50.233.326.429.633.814.944.8182.8

8/278/27/99 6:028/28/99 6:00143823.5098224.4-0.6651.983.0030.3344.0100.02.752.091.010.314.436.122.623.430.0735.6643.712.2837.930.004.930.080.040.8715.020.720.660.126.860.854.89XAD2.744.111.5011.1012.4717.360.125.043.67-1.222.11.2-274143135339.62.313.02.218.17.23.90.313.329.332.954.5-3.245.8172.4

8/298/29/99 6:028/30/99 6:00143823.7098226.5-0.3632.202.7119.2153.0105.04.161.701.120.252.848.033.504.530.0034.7347.090.3435.070.005.050.030.000.1016.180.140.150.046.460.453.26XAD2.593.880.329.3710.6613.930.033.892.59-0.672.01.3-28023375846.10.314.41.318.47.40.90.111.126.730.463.5-1.939.7169.5

8/318/31/99 6:029/1/99 6:00143823.2398522.4-0.2491.343.1527.1339.792.02.571.940.890.282.315.262.133.130.0013.6815.680.8715.550.051.090.000.040.312.220.280.280.105.470.561.22XAD2.193.280.658.319.4010.620.092.981.890.661.91.6-60546-914.32.07.03.635.114.14.20.619.253.460.419.64.368.3225.2

AVG28-Jul-9931-Aug-992318.698126.8-0.2632.232.4030.2052.3112.82.452.181.300.435.078.923.885.000.0435.720.043.860.040.030.6811.010.590.480.148.420.913.553.375.051.2013.0314.7116.420.106.614.621.032.11.50-214112292630.52.010.72.623.59.43.60.317.236.441.141.93.049.4171.999.7

StDev6.022.30.4120.400.818.1915.729.80.831.070.820.222.443.381.571.870.039.910.041.270.050.040.304.060.510.210.112.820.381.241.131.690.694.174.734.270.103.253.112.520.70.2770585288.41.12.30.95.82.31.90.27.48.59.611.68.27.832.7

AVG for XAD days w/ backup33.760.033.750.030.020.7410.950.630.490.137.260.793.552.904.361.2511.4112.8616.420.086.034.581.032.271.50-208122283230.81.910.82.623.69.43.40.318.536.541.242.441.246.0189.1101.3

23Site: Atlanta, GA, Jefferson St

Blue Numbers indicate Final Results KB data where denuder inefficiencies were taken into accountMeasurement Period: July 28 through August 31, 1999

Bold blue numbers indicate HONO/HNO3 calculated from nitrite/nitrate difference between D1 and D2# of samples: 23

Plum numbers indicate consideration of average denuder inefficiencies, average of ion conc from both teflons, and partial IC reruns

AVGSTD

35.729.91

5.072.44ppbv

2.181.07ppbv

2.450.83ppbv

Atl Sum99

2.34678894412.28683295210.97772454990.84562942557.91223506873.50156305556.47085822030.0765893682

4.00219015332.16849783323.20640800480.40749074156.38018603132.85123273573.87781345290.0883025194

3.37594874652.29172404481.58229778230.61814296867.96011580167.03584266979.07209957430.0204955413

2.81258805012.47411345771.10497193470.51882845263.1631719714.83965452515.85229151880.0300714198

2.33319872562.41799374361.96790782620.36626809025.45680780354.40392041475.21955592570.0259711338

2.92509266654.46036261030.71129399441.0775606039.29940792293.72197946275.582136350.0104519182

2.51521007341.11622587045.30965512720.25532697152.98125476447.66300891797.12644525470

2.06319448792.14291264611.15623005370.5574050577.52117530073.02696598213.40741971760.0176340078

0.61374762060.32549243021.11374815260.08205061430.66302420692.77504313613.35352970170.0383351196

1.94917295231.98915647591.83042634780.71545457679.24525653365.44685308136.02327279420.0159274761

1.89614319022.86570152460.86883093260.69753928378.78969917165.42641364267.21015300490.0027263035

1.20004835340.91277123251.94843033780.25097511441.70980449373.38600904543.6728643510

3.21806759692.64331609870.26420627030.48315888692.63797071063.43542449214.66658815450.0167294128

2.97411528661.2008438051.25089041660.25929544441.17044897994.9118922675.70679727580

2.36696766893.17683761431.50239346070.55252254416.02504814755.76331559647.01700865740.046998373

1.98922852054.67455170670.13228096850.28207900225.99906504373.61134708766.78789781450.2045324704

2.80831678337.12548512190.04464248470.35167209795.86052905513.70316515967.02475478230.0998055999

1.85858734042.51008136690.66200875990.37717129395.17899793362.66815317263.63370157710.0647210519

1.6290925230.3483210820.65004045840.20590813622.07076060313.25863186734.09392890860.057285096

1.28949934590.67577460330.55691531060.11410523774.45163533721.20852284671.6475009950.0044395037

2.75359021632.09037559051.01056430060.31331347694.42774128972.62279346383.4339177920.0665727426

4.16264720871.69541099761.11907095480.24621879722.83981755153.50049842144.52850906670

2.57310339541.94002434590.89066739110.2765083352.30524533772.13150631833.1282136390

2.45433825072.17736095551.29887824020.43121503795.06657967393.87894252065.00369266680.0353501879

AM

PM

AM

AM

PM

PM

NH3

HNO3

HONO

HCl

SO2

Acetic

Formic

Oxalic

[ppbv]

Gases - Atlanta Summer '99

HV Sum99

0.09265561467/283.47861602200.456405023710.49073957510.79896698170.39580341850.08705868412.43386530114.97354612041.36347215078.8695430715

0.05295218237/304.21948685270.08000616010.729032544110.52778283570.38860553760.7320086122012.92965655035.17186262012.01976184736.5064266754

0.12811473360.16343150384.73372998930.11740151560.755958279912.76165807290.90818190210.54908707280.28825646111.71124119994.684496481.112832874211.1208313887

0.02875119690.0022945823.981519659700.503234455210.559419971900.20335700670.2494342828.35530673373.34212269350.94901418824.0690175362

0.0238181570.05878216815.67187654610.00735879320.68338914718.35021825350.17506141990.31799078150.26369269649.2336137793.69344551161.177637290311.1257625895

0.02699908850.02828780583.9596196010.07741839510.756092176213.24089655030.46395326580.42942885080.01743840537.97451598233.18980639290.64747384249.7651305945

0.017124170405.089560720400.688392092713.11164826230.78592704770.32286909210.12462377619.97369708513.98947883410.701057153113.0025114521

00.02830795283.381863374100.49392754519.85261245510.15689241780.31754431770.12378533925.99537873262.39815149310.747984417.8052485454

0.01254711538/106.39107928580.01654381040.695567962616.87239797110.31619799650.37993570710.198917571810.84070460214.33628184081.12266196533.9297211159

0.074160503704.37934886540.08896971290.743601660811.51817632870.74565324980.59682497830.23883633759.17159108093.66863643240.86603954748.3502847564

00.19486490273.142485407900.6931140598.490151911700.5864348512010.11577915644.04631166261.58023003938.2645510598

00.03572960942.461805594100.52155389885.86330011120008/1308/1311.073484433

003.000156865600.44457296795.70451310850.99403712190.811472165306.64864070422.65945628170.25751777382.5550173501

0.096897104303.389675705100.24951469117.5986475351.28598435450.769201097014.35658311425.74263324570.6808990384-0

0.114763565603.865701791700.628093833411.29856185050.5670839410.52964081210.087303379910.55050589324.22020235730.94077268089.3299415984

003.636053575102.06053718379.75073577062.67337256751.40936879080.24207040677.81283982173.12513592870.39534852114.5600515975

0.02772392510.16205491063.962771051901.486910423110.24808955342.9456065860.88199687140.27015582888.75068210413.50027284161.62881759326.492321524

0.083874453604.30303234330.02732961090.70834256813.15240585851.16777062250.44160630120.24159658385.33755211382.13502084550.59887567291.9475347894

0.009825999703.39762765101.106673283710.83691921860.32272282660.58829186770.25956807696.24931346192.49972538480.60854737832.7923589662

0.041358058701.46483402610.01083776181.02007095455.19339899680.23525393210.50324847203.44909408711.37963763490.78684307657.0297622544

00.07970569564.93396240630.03795205780.870485652415.02394327630.72052660350.66150925830.11595428766.85778664522.74311465810.8513519385.0382154193

00.02520324575.053012782800.102427753716.1833281160.13621429490.14732439370.03737053736.46307612422.58523044970.45212550463.8857570615

0.045673060501.09030149410.04054086380.30561076722.22146572180.28072033210.27509749010.09811313745.46531323432.18612529370.5646924172.9788537408

0.04269186130.03590467183.86214005160.02504335560.682300585311.00881446210.58876137650.47588278420.13608544418.42041594213.36816637680.91397285776.6145144549

AM

AM

AM

PM

PM

PM

Na+

Ca++

NH4+

Cl-

NO3-

SO4=

Acetate

Formate

Oxalate

OC

OOE.4

EC

UnID.4

[mg m-3]

Atlanta PM2.5 Summer 1999

DX Sum99

218.42056163127.3601842237-192.82793913332.952806722-192.827939133

219.191814193111.7566931797-233.8961669984-2.9476596256-233.8961669984

265.701812885312.190909206-262.401884107515.4908379839-262.4018841075

219.85050951258.1153758294-220.70508091657.2608044253-220.7050809165

382.057427722111.0206280757-314.405573507478.6724822904-314.4055735074

275.679711644312.1930684767-219.491108704268.3816714168-219.4911087042

272.988720847311.1013077366-282.12642574171.9636028422-282.1264257417

205.13455038827.9652885842-187.464710313625.6351286588-187.4647103136

351.288735604811.2170289087-354.2726876838.2330768305-354.272687683

239.812124271311.991641039-242.75769763719.0460676731-242.7576976371

176.767685023111.1774562004-174.195421723513.7497195-174.1954217235

122.0757882838.4108030774-136.4637247284-5.9771333681-136.4637247284

118.76979197397.1693753891-166.3058129491-40.3666455861-166.3058129491

158.20627805474.0237815054-187.8977663606-25.6677068005-187.8977663606

235.23968041910.1289120041-214.285021712431.0835707107-214.2850217124

203.013445151533.2291111713-201.555076225434.6874800973-201.5550762254

213.368510376923.9785586691-219.665801105217.6812679408-219.6658011052

273.837307067911.4230377039-238.527291756746.7330530151-238.5272917567

225.628132804917.8466905938-188.338561583755.1362618151-188.3385615837

108.128232287816.4501040878-81.199225395143.3791109804-81.1992253951

312.803316184714.0378270017-273.501242032453.3399011539-273.5012420324

336.94208028251.6517941256-280.100486852458.4933875558-280.1004868524

46.25162860394.928411017-60.4379985667-9.2579589458-60.4379985667

229.207046888411.0030734607-214.08758600726.1225343422-214.087586007

AM

AM

AM

PM

PM

PM

SO4=

NO3-

NH4+

Net Acidity

[ne m-3]

Net Acidity/Components of Acidity - Atlanta Summer '99

HV Fall99

30.469458752

2.0245884923

10.7032098963

2.5589559363

23.4886330542

9.3954532217

3.5583380689

0.2717656869

17.2284733195

Atlanta Supersite Mass Composition Summer 1999

DX Fall99

Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwOOEsv/OCNet AcidityECOCOOELOAOthersUnIDTOC.4TOC.6CheckSum

ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]

7/27/2/99 10:407/3/99 6:00115519.13100426.626.182801.03.515116131.00.330.450.250.251.795.182.182.930.0721.6419.613.9919.980.241.930.000.763.301.521.660.183.630.16XX1.452.183.368.439.160.245.174.442.8-1071269-2616.53.89.60.818.17.316.81.225.942.245.822.7136.6

7/47/4/99 6:007/5/99 6:00144023.92100928.427.973720.71.116211180.02.230.580.540.502.635.982.503.480.0045.9642.711.5236.390.164.190.231.1210.230.260.510.006.490.26XX2.603.890.779.8611.150.3910.349.053.0-23218213-128.13.111.50.717.87.12.11.128.427.130.738.7124.8

7/67/6/99 6:007/7/99 6:00144024.03100928.627.869691.12.029830093.01.801.540.270.312.046.422.913.410.1123.7924.080.6519.280.051.220.070.000.474.110.000.230.005.770.47XX2.313.460.238.319.460.124.583.432.2-688862521.32.46.32.429.912.01.20.623.843.149.129.3145.2

7/87/8/99 9:007/9/99 6:0084014.01100527.526.673731.02.318918980.00.692.130.250.425.196.892.654.060.1835.1437.741.2929.800.001.770.120.000.109.050.450.720.005.590.52XX2.243.361.179.0010.120.129.248.123.1-9821889230.40.36.01.818.87.53.90.431.030.233.941.8136.9

7/107/10/99 6:007/11/99 6:00144025.1352.01.890.620.320.072.136.163.003.090.0731.4626.620.5423.340.002.340.000.070.606.390.000.020.004.280.32XX1.712.570.026.016.870.077.606.743.2-130101331327.42.610.01.418.37.30.10.332.625.829.437.7125.4

7/127/12/99 6:007/13/99 6:00144025.1369.01.091.120.530.132.314.031.582.400.0535.2441.391.1231.380.003.580.090.070.5110.040.290.430.045.040.50XX2.023.030.777.828.830.168.777.773.1-19882091932.01.611.41.616.16.42.40.528.024.928.144.0125.1

7/147/14/99 6:007/15/99 6:00144025.1391.00.670.830.830.202.883.411.411.900.1045.1547.650.7637.160.004.630.020.020.5615.670.120.770.174.200.59XX1.682.521.066.947.780.058.727.883.5-25693267942.21.512.51.611.34.52.80.123.518.720.958.0121.1

7/167/16/99 6:007/17/99 6:00144025.1386.00.570.260.430.370.351.860.631.220.0017.5218.490.4514.390.013.200.000.000.245.220.000.000.002.270.22XX0.911.360.003.173.630.012.321.872.4-1784109-6536.31.722.31.515.76.30.00.116.222.025.249.9113.3

7/197/19/99 6:457/20/99 6:005509.19100928.727.872720.61.719723478.01.611.601.010.313.499.293.236.060.0030.7067.360.1925.530.001.510.000.000.198.561.950.000.008.781.02XX3.515.271.9514.2416.000.00-0.00-1.761.4-8431789733.50.75.94.034.413.87.60.0-0.055.862.746.1164.6

7/227/22/99 6:007/22/99 18:30550.84100929.027.873740.51.422424373.02.322.450.740.315.8621.416.8814.530.0040.5536.1118.6059.380.000.000.000.007.102.0212.2317.500.0013.371.82XX5.358.0229.7348.4551.120.000.00-2.671.40114421573.412.00.03.122.59.050.10.00.081.686.14.7172.4

7/257/25/99 7:307/26/99 1:204307.17101331.429.264681.22.1182167103.04.593.210.471.1618.718.874.164.710.0047.0249.422.2739.860.004.740.040.001.5010.360.000.001.097.010.30XX2.804.211.0910.9012.300.0412.0010.603.1-26324216-2326.03.811.90.817.67.02.70.130.127.330.935.8124.1

7/277/27/99 12:107/28/99 6:003956.52101027.928.471640.71.5299209109.03.031.311.540.370.607.984.393.590.0037.8142.021.1431.310.002.830.590.142.547.190.000.000.009.690.61XX3.885.820.0013.5715.510.733.851.911.8-157411503422.98.19.01.931.012.40.02.312.343.349.531.6136.7

7/317/31/99 7:008/1/99 2:003055.08101832.931.459610.82.422124689.02.671.690.850.412.0117.026.4010.620.0040.5343.423.9436.100.002.260.070.000.677.172.552.292.9411.500.91XX4.606.907.7823.8826.180.071.14-1.161.5-125111493519.91.86.32.531.912.721.50.23.266.172.527.3169.1

8/68/6/99 7:508/6/99 17:155659.38101231.128.837401.32.018417398.01.282.840.100.395.146.642.713.920.0026.4631.190.8523.290.022.200.100.000.677.590.000.270.004.260.42XX1.702.550.276.237.080.126.065.212.8-122111584732.62.99.41.818.37.31.10.526.026.730.444.8128.0

8/118/11/99 12:208/12/99 9:00124020.61100426.625.982830.71.419316279.02.620.481.640.234.296.263.262.990.0028.5122.101.2420.990.002.641.710.041.185.460.170.100.013.870.44XX1.552.320.285.696.471.753.833.062.4-14619114-1326.05.612.62.118.47.41.38.318.327.130.835.8112.0

8/158/15/99 6:008/16/99 6:00144023.7499421.922.570631.32.4184255.00.860.660.650.130.881.840.850.980.0019.7318.390.4915.490.002.220.000.000.246.210.060.140.002.750.39XX1.101.650.204.054.600.002.381.832.3-12341291040.11.514.42.517.87.11.30.015.426.229.755.1126.4

8/218/21/99 6:008/22/99 6:00144023.70100023.424.257491.11.9164769.01.321.060.670.391.723.151.531.580.0416.8414.560.6913.000.001.560.010.000.294.050.370.210.003.590.22XX1.432.150.585.606.320.011.260.541.8-87584331.22.312.01.727.611.04.50.19.743.148.642.9144.3

8/278/27/99 6:008/28/99 18:00160526.44100825.726.064591.01.7296891.00.762.240.480.356.503.931.632.300.0043.1346.771.1536.540.005.870.020.000.4318.600.340.160.214.970.47XX1.992.980.717.678.660.023.482.492.1-32573876950.91.216.11.313.65.41.90.09.521.023.770.0124.3

9/29/2/99 18:009/3/99 18:00144023.63100525.826.452450.91.434273104.01.271.870.350.252.847.643.274.370.0022.9524.990.6820.120.003.370.100.050.497.700.640.000.005.230.44XX2.093.140.647.979.010.15-0.00-1.051.4-1878160-1838.32.416.72.226.010.43.20.7-0.039.644.852.7137.1

9/89/8/99 18:009/9/99 18:00144023.91100426.626.045431.93.533834770.02.211.150.630.235.834.802.202.600.0012.9912.550.8211.990.002.210.260.000.834.320.640.000.002.660.004.94XX1.061.600.644.364.900.26-0.00-0.531.4-1221390-1936.16.918.40.022.28.95.32.2-0.036.440.949.6126.9

AVG2-Jul-998-Sep-992018.1100526.626.465621.02.180.01.451.180.580.293.265.262.282.940.0429.3330.431.1324.340.032.940.160.030.638.040.410.370.104.680.390.331.872.810.897.448.380.224.683.742.4-163101671432.62.712.61.620.18.03.51.017.831.735.744.8130.0100.0

StDev8.552.41.812140.30.819.20.740.670.330.142.272.080.941.190.0511.2013.160.829.270.061.360.390.060.354.700.440.460.211.490.181.320.600.900.912.512.790.403.503.390.775698418.91.74.30.75.72.33.81.910.79.310.412.210.8

2033.02.612.11.619.27.73.60.919.230.634.445.4130.0100.0

Site: Hendersonville, TN

Measurement Period: July 2 through September 8, 1999

# of samples: 20

AVGSTD

24.349.27

3.262.27ppbv

1.180.67ppbv

1.450.74ppbv

Karsten Baumann:only til 9/1 00:00

DX Fall99

SO4= NO3- NH4+ EC OC OOE LOA Others UnID

24.3 +-9.3

HV Win99

0.33052790050.45117594620.25215962350.24602027051.79418215462.17695927352.92833705560.0725174182

2.22531133440.58055380560.53649167940.49633443392.6269864792.49950690773.4774767260

1.80407464741.54044713190.26793483670.30600435432.03690137132.90737400183.40972591960.1060385782

0.69038514022.13122010780.24827878080.41756254565.18869199512.65487011894.05901237910.180195821

1.88648761220.62062100250.32232385420.07242945092.12933590993.00057295423.09160225620.0706711707

1.0863304791.11716588160.530141940.12752479742.31058992211.58132836152.40215330940.0506313336

0.67234444430.83289426910.83311809860.20244420512.88304770311.4149370081.89924200750.0987313922

0.56810058260.26320370820.42726354240.36641766470.34955443080.63299037181.22356863990

1.60803637641.60280701561.00734314830.30869873813.48857468833.22864147426.06451987040

2.31731538122.45463864880.74439467990.30841014625.85912393286.880458637314.52832915720

4.59074270053.21451039230.46584083711.159904163818.7123196864.16216558364.70925650260

3.03468066141.30991313161.53830807650.37266871440.60384617174.39209308323.59019327770

2.66699869221.68527096450.84682056290.41318203762.01026438146.395850678110.62400892480

1.27924900032.84068952310.10497220230.38935858635.13657009262.71159887593.92433403760

2.62145697360.48075473381.64082264890.23158023054.29478139473.2616389382.98984265760.0036920566

0.8614909630.6648382550.64695572330.12566845080.88374143520.85263802490.98353781360

1.32171349591.06498309460.67294357880.38866817081.72191137371.52849487561.5804982020.0437769001

0.75728776362.2350749680.48342852570.34561358956.49999929351.62618000042.29983015240

1.26802741261.87293782110.3493882440.24701188032.84414991483.26941141324.36608430020

2.21110192521.14563358530.63407259190.2300585215.83187120742.19764167372.60359809340

1.44715473461.18396874590.58256953360.29459528063.26090696532.28387899372.93777324880.0358534521

SO2 = 18.6 ppbv

#REF!

#REF!

#REF!

#REF!

#REF!

#REF!

#REF!

#REF!

[ppbv]

Hendersonville Gases Summer 1999

DX Win99

7/20.23821929961.925640143700.75917759843.29706094031.51580253611.661411710.18050371293.62511315551.45004526220.15918660565.1673253716

7/40.15798617154.18569442450.23352703571.123053571710.22928616560.26310169810.509880686706.48757049542.59502819810.259502819810.3429813904

0.07421369070.0466826051.221930580100.47214903194.112320696400.233374304405.76552096862.30620838750.4651466124.5795337695

0.121392506101.773952171800.09585353289.05025855910.44759262210.718575880805.59414722392.23765888960.52290970529.241347606

002.33671580260.07173945130.6043873716.393234697500.021640053904.2795683591.71182734360.323710947.6009105754

0.091740708803.57684489880.06820445380.505493408110.04126616080.28839573520.43371886550.04376423875.04220938712.01688375480.49928297528.7734725938

0.0247785604.62649244610.02171537740.563282831915.67199879940.1184601540.76950685990.16895358084.20275559361.68110223740.58706899288.7205882019

00.00845947523.204313377700.24208220965.22147759770002.26597657980.90639063190.21946504412.3249072973

001.513255021700.1868226338.55796657151.951105476008.78101580593.51240632241.0224470459-0

00007.09770334262.02230608712.232919078317.5005515373013.3677622475.34710489881.815375120

0.044158250304.744353452601.503157233710.3635084525001.08696716087.00857977492.80343190990.304720859811.997413346

0.591020483502.83079836050.13999366992.53622908697.18521908140009.69437845413.87775138170.60984159473.8468872439

0.069991879402.262321612500.66692518317.17177605212.55174585232.28931923332.937452254311.50072609754.6002904390.91360908251.1373058629

0.10287263910.01632812132.200058324800.67378034117.588236961500.265654050704.25805842731.70322337090.41779055016.0621601593

1.70932106302.63609596540.04022491941.17875732515.46338502460.16661164740.0996464480.01196434693.86801799751.5472071990.43649508653.8336384007

002.223640619300.2386355826.21074578260.05694683170.139198106602.75379659361.10151863740.38506477792.3825295439

0.01414588701.561312738300.29338009924.05064149140.36647849390.214707227903.58737395521.43494958210.21547538371.2566156912

0.015534177105.868614366600.434784718518.60448941820.34084340070.15584826520.21251063544.97113617911.98845447160.46603620413.4819680517

0.103911179603.36752173720.04525595750.4913291117.70265004660.6416347901005.23143064652.09257225860.4407857307-0

0.261085823202.209019233200.82648458174.32469995110.6410913509002.65951541711.06380616680-0

0.15779912270.02745001682.94266980150.03432745020.62957511538.03771738730.40975765630.37376124220.10371539584.68242423591.87296969440.3876825794.6767449565

#REF!

#REF!

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[mg m-3]

Hendersonville PM2.5 Summer 1999

Mac Jun00

68.645865924312.2428253246-106.7428017561-25.8541105073-106.7428017561

212.977017814918.1108461809-232.0229725306-0.9351085348-232.0229725306

85.6198354447.614078889-67.734511093825.4994032393-67.7345110938

188.42928501051.5457754041-98.334377594291.6406828203-98.3343775942

133.10919628419.7466113692-129.529700808113.3261068453-129.5297008081

209.06238102828.1518046776-198.272998825518.9411868802-198.2729988255

326.29603996159.0837418463-256.457452668978.9223291389-256.4574526689

108.71283776273.9039221027-177.6226927784-65.005932913-177.6226927784

178.17960798393.012782341-83.883316060397.3090742646-83.8833160603

42.1050611483114.46062477960156.56568592790

215.771568862524.2405617434-262.9907678825-22.9786372766-262.9907678825

149.59856509240.9003239296-156.917869209133.5810198124-156.9178692091

149.318676912310.755123094-125.405854353134.6679456531-125.4058543531

157.989526577210.8656723293-121.954452592646.9007463138-121.9544525926

113.749427952519.0091489298-146.1250535153-13.366476633-146.1250535153

129.30971856423.8483402998-123.26167512989.8963837342-123.2616751298

84.33565461954.7311739911-86.54726930512.5195593055-86.5472693051

387.3514348997.0115258595-325.311217661969.0517430965-325.3112176619

160.37164369467.9233851156-186.6697193547-18.3746905445-186.6697193547

90.041639623313.3282467615-122.4511770055-19.0812906207-122.4511770055

167.347853160810.152799796-163.119168600114.3814843566-163.1191686001

#REF!

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[ne m-3]

Hendersonville Net Acidity/Components of Acidity Summer 1999

Aug Junl00

Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID6svMw/CwOOEsv/OCNet AcidityECOCOOELOAOthersUnIDTOC.4TOC.6CheckSum


6/156/15/99 6:006/16/99 6:00144024.001.2823.3823.330.3318.780.001.880.000.000.905.690.190.112.340.17XAD0.941.400.303.584.050.006.556.084.2-104151192930.34.810.00.912.55.01.60.034.919.121.641.7117.2

6/186/18/99 6:006/19/99 6:00144024.0099019.0571.3561.440.920.170.202.655.431.073.750.6125.0022.710.3619.260.001.700.000.000.866.700.000.000.002.700.29XAD1.081.620.003.784.320.005.935.393.6-94141405934.84.58.81.514.05.60.00.030.819.622.447.9120.7

7/27/2/99 16:197/3/99 6:0082213.82100424.6901.016424.01.450.340.111.672.931.261.680.0023.5821.821.2718.980.000.430.000.001.352.340.000.760.002.500.00XX1.001.500.764.264.760.0010.6010.105.6-2422494712.37.12.30.013.25.34.00.055.822.525.117.0120.4

7/47/4/99 6:007/5/99 6:00143823.85100926.1830.619051.01.300.500.170.271.217.002.804.200.0026.1726.042.5323.060.092.050.000.000.535.691.861.740.005.330.00XX2.133.203.6011.0712.130.093.642.572.1-11491181324.72.38.90.023.19.315.60.415.848.052.633.9150.3

7/67/6/99 6:007/7/99 6:00142923.57100926.8820.828653.01.350.920.220.330.818.223.504.580.1425.1111.601.7321.440.081.350.000.000.421.970.420.810.096.660.00XX2.664.001.3110.6411.970.086.995.662.4-75741-279.21.96.30.031.112.46.10.432.649.655.812.7150.7

7/107/10/99 6:007/11/99 6:00132622.4199422.8921.430139.01.110.490.150.071.995.102.252.740.1223.8624.170.7919.690.001.800.050.000.515.550.000.430.003.650.14XX1.462.190.435.546.270.056.105.373.1-10081152428.22.69.10.718.67.42.20.231.028.231.938.8129.8

7/127/12/99 7:207/13/99 7:19129921.68100421.9741.232570.00.931.430.000.275.254.561.642.810.1140.2845.590.8134.540.023.690.120.000.4713.320.160.330.250.150.00XX0.060.090.740.950.970.1415.9715.94111.0-20582778038.61.410.70.00.40.22.10.446.22.72.853.1104.9

7/147/14/99 6:007/15/99 6:00137022.84100222.7860.720474.00.470.290.390.151.706.452.843.530.0968.1475.002.1058.610.005.630.040.000.3722.970.740.980.496.040.49XX2.413.622.2110.6611.870.0418.4417.244.5-312647817239.20.69.60.810.34.13.80.131.518.220.353.9123.8

7/167/16/99 6:007/17/99 6:00143623.78101424.6830.816573.00.241.470.250.252.076.802.893.910.0055.3659.150.7645.860.085.260.000.010.3218.650.190.170.007.340.43XX2.934.400.3610.6312.100.0910.489.012.8-291538810240.70.711.50.916.06.40.80.222.923.226.455.9128.3

7/197/19/99 6:007/20/99 6:00139623.21101226.8781.024065.00.780.710.190.121.2410.264.086.180.0031.1030.821.3725.660.001.530.030.000.186.151.790.360.495.730.00XX2.293.442.6410.6711.820.037.115.962.6-8531284624.00.76.00.022.38.910.30.127.741.646.033.0148.3

7/227/22/99 6:007/23/99 6:00143023.8399727.8761.126863.01.090.990.280.180.6311.834.557.070.2133.1433.712.2428.650.001.830.000.000.516.140.650.681.276.320.07XX2.533.792.6011.4412.700.008.657.392.8-10281283521.41.86.40.222.08.89.10.030.239.944.329.5143.9

7/257/25/99 6:007/26/99 6:00139522.81101126.6830.726979.01.581.590.190.222.5510.494.386.110.0050.9253.330.9642.040.003.980.000.000.4216.740.660.320.432.220.19XX0.891.331.414.534.970.0016.1815.738.7-221734913539.81.09.50.55.32.13.40.038.510.811.854.8115.9

7/277/27/99 11:307/28/99 6:00101616.79101527.4690.823066.01.900.740.430.140.2912.245.067.160.0328.7929.891.9124.670.001.740.120.000.404.590.870.730.047.520.33XX3.014.511.6412.1713.680.125.323.822.1-96696618.61.67.11.330.512.26.70.521.649.355.425.6152.0

7/317/31/99 6:008/1/99 6:00128421.03101828.8711.324494.01.501.370.420.293.4414.115.718.360.0441.1840.300.4232.470.002.030.000.000.358.380.000.000.068.640.30XX3.465.180.0612.1513.880.009.247.512.5-11361756725.81.16.30.926.610.60.20.028.537.442.835.5144.2

8/68/6/99 6:008/7/99 6:00141023.27100524.1580.834293.01.181.470.400.254.217.933.674.250.0031.8229.370.7224.740.002.410.230.000.499.310.140.230.175.800.33XX2.323.480.558.679.830.233.312.142.0-13481946837.62.09.81.323.59.42.20.913.435.139.751.7139.9

8/158/15/99 6:008/16/99 6:00143023.8499520.5741.22957.01.360.750.280.230.943.821.991.830.0020.5918.000.5615.720.001.900.230.000.466.520.130.000.003.270.26XX1.311.960.134.705.350.231.661.011.9-10571363841.52.912.11.720.88.30.81.410.629.934.157.1131.6

8/218/21/99 18:008/22/99 18:00137822.78100022.7530.86388.01.401.480.130.192.555.142.172.860.1114.6614.560.9914.270.001.880.020.000.154.240.990.850.004.240.19XX1.702.551.847.788.630.020.00-0.851.4-104288-1429.71.113.21.329.711.912.90.10.054.560.540.9155.9

8/278/27/99 18:008/28/99 18:00143023.69100424.9600.92178.01.272.210.300.303.8311.667.464.200.0042.3245.000.5437.680.006.890.030.000.3121.060.000.710.785.510.19XX2.203.301.499.2010.300.030.00-1.101.4-38254386155.90.818.30.514.65.83.90.10.024.427.376.9128.6

9/29/2/99 18:009/3/99 18:00142922.99100725.1450.96997.00.632.300.181.063.2813.887.236.570.0725.6927.391.2925.980.003.810.250.060.579.240.600.440.117.540.33XX3.024.531.1511.7113.220.31-0.00-1.511.4-2119192-935.62.214.71.329.011.64.41.2-0.045.150.948.9144.9

9/89/8/99 18:009/9/99 18:00128721.33100423.8541.934285.02.350.840.580.203.546.142.993.120.0313.1714.681.5816.780.001.860.080.001.114.490.000.420.036.020.353.94XX2.413.610.448.8810.080.080.00-1.201.4-1031894826.86.611.12.135.914.42.70.50.052.960.136.8149.9

AVG15-Jun-998-Sep-992022.3100524.5721.069.41.211.120.260.252.207.733.404.250.0832.4432.531.1527.640.012.750.060.000.529.200.480.500.225.240.220.192.103.151.208.199.190.086.235.182.9-15281914731.32.39.80.920.98.44.70.321.734.138.343.1136.7100.2

StDev2.672.6140.319.60.470.580.130.221.403.761.982.050.1514.0216.620.6811.590.031.660.090.010.266.230.580.440.351.920.150.840.771.151.033.413.830.095.285.321.89241305010.81.73.30.68.13.24.50.414.313.515.014.813.1

2033.31.99.90.819.07.64.30.322.529.633.245.8137.299.6

Site: Dickson, TN

Measurement Period: July 2 through September 8, 1999

# of samples: 20

AVGSTD

27.6411.59

2.201.40ppbv

1.120.58ppbv

1.210.47ppbv

Aug Junl00

27.6 +-11.6

Col Jul00

Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwOOEsv/OCNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6CheckSum


9/149/14/99 18:009/15/99 18:00144023.7699221.821.632311.84.4153164.02.171.250.090.1712.622.401.051.360.007.308.240.187.790.001.380.050.000.182.660.000.000.002.520.00XX1.011.510.003.524.020.05-0.00-0.501.4-77355-1834.12.317.70.032.312.90.00.6-0.045.251.647.0143.8

9/269/26/99 18:009/27/99 18:00144023.6699722.723.172680.92.711712761.01.630.770.780.112.074.151.902.250.0019.9324.020.6920.620.002.710.170.000.485.451.010.360.004.250.39XX1.702.551.377.328.170.174.093.242.4-1508114-2926.42.413.11.920.68.26.60.819.835.539.636.4131.3

10/210/2/99 18:0010/3/99 18:00144023.5898618.219.470650.81.532510061.01.360.861.060.1619.335.542.542.960.0420.8322.521.2121.420.003.170.140.000.665.791.000.540.726.540.23XX2.623.922.2711.4212.730.140.00-1.311.4-17511120-4427.03.114.81.130.512.210.60.70.053.359.437.2149.9

11/111/1/99 19:0011/2/99 18:59144022.7699411.911.970704.06.832233329.00.750.200.150.071.330.860.480.380.005.164.780.896.520.000.860.080.000.551.140.000.140.002.680.003.95XX1.071.610.143.904.430.080.00-0.541.4-48924-1517.48.413.20.041.116.42.21.30.059.868.024.0151.7

11/1911/19/99 19:0011/20/99 18:59144025.53100115.014.985841.53.018818942.02.160.180.700.176.781.420.780.650.0016.0220.351.8823.660.062.590.050.112.403.850.790.630.015.520.185.28XX2.213.311.429.1510.250.225.284.172.4-1433980-2516.310.110.90.823.39.36.00.922.338.743.322.4126.7

11/2511/25/99 19:0011/26/99 18:59144025.029978.38.076771.83.429229527.00.500.270.440.083.570.850.240.570.037.0813.963.7512.460.111.720.070.162.631.982.210.520.022.130.06XX0.851.282.745.726.150.34-0.00-0.431.4-954241-1215.921.113.80.517.16.822.02.7-0.045.949.421.9117.2

12/112/1/99 19:0012/2/99 18:59144024.4510095.48.259451.63.019816441.01.020.271.170.264.851.481.010.480.0013.1414.905.0518.500.000.540.000.200.780.883.341.360.057.790.44XX3.124.684.7515.6617.220.20-0.00-1.561.4-30131814.84.22.92.442.116.925.71.1-0.084.693.16.6184.3

AVG14-Sep-991-Dec-99724.199714.815.366631.83.546.41.370.540.630.157.222.391.141.230.0112.7815.541.9515.850.021.850.080.071.103.111.190.510.114.490.194.611.801.818.109.000.171.341.7-1031865-2020.37.412.40.929.611.810.51.26.051.957.827.9143.6100.0

StDev0.976.66.217181.11.715.60.660.420.420.076.531.800.811.010.026.427.251.796.890.041.000.060.090.991.981.210.440.272.200.180.940.881.644.364.790.102.310.5551641149.76.84.60.99.83.99.80.710.316.618.313.322.0

719.66.911.71.228.311.311.41.18.451.156.827.0143.6100.0

numbers with a yellow background are taken from Percy Priest, east of downtown NashvilleSite: Hendersonville, TN

Measurement Period: September 14 through December 1, 1999

# of samples: 7

AVGSTD

15.856.89

7.226.53ppbv

0.540.42ppbv

1.370.66ppbv

Col Jul00

15.9 +-6.9

LP Sum00



9/149/14/99 18:009/15/99 18:00122520.2499319.0401.71163.02.421.130.110.144.714.922.911.950.0513.2211.150.7113.930.001.880.170.001.033.010.000.210.004.770.00XX1.912.860.216.897.840.170.95-0.001.6-1041763-2521.67.413.50.034.313.71.51.26.849.456.329.7142.3

9/269/26/99 18:009/27/99 18:00143023.8799721.9730.813549.01.300.790.440.121.336.072.913.160.0019.7327.271.0120.740.002.900.000.000.715.911.160.410.002.830.00XX1.131.701.575.536.100.005.685.113.4-16112123-2628.53.414.00.013.65.57.60.027.426.729.439.2122.7

10/210/2/99 18:0110/3/99 18:00142923.8998718.1690.817574.01.990.850.630.278.269.064.044.680.3449.5950.243.9753.880.003.070.000.001.186.731.161.200.2519.100.21XX7.6411.462.6029.3533.170.0013.349.522.1-17019140-1112.52.25.70.435.514.24.80.024.854.561.617.2158.0

11/111/1/99 19:0011/2/99 18:59142823.00100110.8723.733027.00.270.270.060.040.990.540.240.300.006.256.520.787.020.000.710.000.000.611.200.000.000.001.250.001.45XX0.500.750.001.752.000.002.752.503.6-391025-517.28.710.10.017.87.10.00.039.124.928.523.6116.1

11/711/7/99 19:0011/8/99 18:59131821.72100619.4691.725258.01.660.740.190.283.902.771.071.700.0012.9917.000.8713.870.191.930.000.020.504.210.000.000.024.200.00XX1.682.520.025.896.730.211.110.271.7-107888-1130.43.614.00.030.312.10.11.58.042.548.641.8140.9

11/1311/13/99 19:0011/14/99 18:59137123.65100018.1533.025665.01.240.780.210.131.312.541.151.390.0021.0821.450.5021.580.182.210.130.070.485.820.000.000.056.830.004.05XX2.734.100.059.6110.980.383.071.711.8-1238121627.02.210.30.031.712.70.21.814.244.550.937.1146.7

11/2511/25/99 19:0011/26/99 18:59129921.539976.6832.127135.00.370.220.350.053.521.360.680.670.0112.9216.641.1615.120.011.920.000.054.671.920.270.000.004.470.03XX1.792.680.276.537.420.06-0.00-0.891.4-1067540912.730.912.70.229.511.81.80.4-0.043.249.117.5109.7

12/112/1/99 19:0012/2/99 18:59135422.3910099.2381.817024.00.761.100.109.061.490.710.750.039.599.421.0112.080.170.801.520.010.981.430.000.000.025.050.09XX2.023.030.027.098.101.700.00-1.011.4-441630211.88.16.60.741.816.70.214.10.058.767.116.3142.0

AVG14-Sep-991-Dec-99822.599915.4632.049.41.240.730.290.144.123.621.721.850.0618.4220.261.2720.050.071.930.230.021.253.820.340.240.046.130.042.722.453.680.629.2010.420.313.502.272.2-1072079-820.28.110.80.229.111.62.12.315.642.848.627.8134.8100.0

StDev1.375.6161.118.80.740.330.200.093.192.981.411.520.1214.1514.461.1615.160.090.880.530.031.352.250.540.440.095.780.081.802.313.471.008.8710.030.584.593.690.9492247137.79.23.30.39.63.82.94.814.312.414.310.616.9

819.06.29.60.230.612.23.11.617.445.952.026.2134.8100.0

Site: Dickson, TN

Measurement Period: September 14 through December 1, 1999

# of samples: 8

AVGSTD

20.0515.16

4.123.19ppbv

0.730.33ppbv

1.240.74ppbv

LP Sum00

20.1 +-15.2

WT Sum00



1/101/10/00 10:351/11/00 9:30137523.5910035.97.940281.43.13282836.00.520.100.040.820.790.480.310.004.985.580.215.800.030.220.110.040.110.090.000.000.073.560.1510.62XX1.422.130.075.045.760.190.00-0.711.4-1222-81.62.03.82.661.324.51.13.20.086.999.22.2188.3

1/161/16/00 18:001/17/00 18:00144024.4310115.75.766661.53.2465515.00.620.190.206.240.840.510.330.0010.8616.221.7114.340.102.150.010.033.062.170.190.390.084.310.128.67XX1.722.590.666.707.560.14-0.00-0.861.4-1194945-2415.121.315.00.930.112.04.61.0-0.046.752.720.8120.2

1/221/22/00 18:001/23/00 18:00144024.379991.51.690921.12.3113926.00.000.180.003.520.710.250.450.0011.9512.961.5813.520.031.340.000.011.493.010.000.000.124.690.007.23XX1.882.810.126.697.630.030.960.021.6-7524631222.311.09.90.034.713.90.90.37.149.556.430.6143.5

1/281/28/00 18:001/29/00 18:00144024.3924.00.170.240.305.701.520.980.540.008.906.540.969.860.000.640.000.010.660.740.200.190.063.840.196.03XX1.542.300.465.836.600.011.791.031.9-351115-97.56.76.51.938.915.64.60.118.259.166.910.4154.6

2/32/3/00 18:002/4/00 18:00144024.4010012.53.166642.34.931031225.00.280.170.111.260.730.530.0010.4713.150.9111.380.031.730.010.062.572.090.290.050.052.650.0010.07XX1.061.590.394.104.630.100.780.251.7-964144-1118.422.615.20.023.39.33.40.96.936.040.725.3108.9

2/152/15/00 18:002/16/00 18:00144025.29100312.513.652481.94.131826435.00.770.430.214.081.871.180.690.0012.4315.931.3513.790.051.840.000.051.662.790.220.110.085.040.007.54XX2.023.020.417.468.470.10-0.07-1.081.4-1022758-1720.212.113.40.036.514.63.00.7-0.554.161.427.8142.9

2/212/21/00 18:002/22/00 18:00144025.09101012.212.947381.84.714315548.00.570.600.242.991.320.730.590.008.629.630.829.440.020.150.000.000.292.140.160.190.124.280.009.52XX1.712.570.476.467.310.020.39-0.471.5-85444122.63.11.60.045.318.14.90.24.168.477.431.1181.0

3/43/4/00 18:003/5/00 18:00144024.9210017.99.865541.01.731131043.00.750.360.164.581.721.090.630.0012.6516.452.3515.000.012.140.000.021.382.360.090.120.025.230.6616.89XX2.093.140.247.558.600.030.88-0.171.6-1192249-4715.79.214.34.434.813.91.60.25.950.457.321.6135.1

3/173/17/00 18:003/18/00 18:00144024.8410068.68.353531.63.7909847.00.350.320.133.111.120.540.570.015.666.461.597.510.041.200.000.031.011.880.230.100.061.940.247.89XX0.781.170.393.113.500.07-0.00-0.391.4-671639-1125.013.416.03.225.910.45.30.9-0.041.546.734.4122.5

3/243/24/00 18:003/25/00 18:00144026.00100019.120.065601.43.229425461.01.100.700.255.733.421.731.660.0321.7221.312.4924.210.082.640.010.050.676.120.690.850.285.360.496.01XX2.143.211.829.3110.390.144.833.762.3-14611127-825.32.810.92.022.18.87.50.620.038.542.934.8136.1

3/303/30/00 18:003/31/00 18:00144025.29100112.213.052441.32.73582653.00.460.390.182.511.510.630.870.019.069.603.1612.570.081.820.150.061.492.800.910.130.123.180.555.23XX1.271.911.175.626.260.280.00-0.641.4-1012458-1922.311.814.54.425.310.19.32.30.044.849.830.7125.2

4/54/5/00 18:004/6/00 18:00144026.1199518.618.349473.45.51962171.460.650.152.954.643.211.400.027.999.650.579.090.000.810.000.140.221.910.280.000.114.020.003.04XX1.612.410.396.026.830.140.00-0.801.4-45440-121.02.48.90.044.217.74.31.50.066.275.128.9170.2

AVG10-Jan-005-Apr-001224.910039.710.459541.73.637.50.590.360.163.851.731.010.720.0110.4611.981.4812.230.041.390.020.041.222.350.270.180.104.010.208.221.602.410.556.166.970.100.80-0.001.6-772049-918.19.910.81.635.114.04.21.05.153.460.425.0143.9100.0

StDev0.755.95.914170.71.214.20.400.200.091.611.170.800.410.014.304.850.864.720.030.800.050.040.921.450.270.240.071.050.243.490.420.630.491.641.840.081.401.320.3441530217.07.04.81.711.14.42.50.97.214.416.69.724.8

1219.210.011.41.632.813.14.50.96.550.456.926.4143.9100.0

numbers with a yellow background are taken from Percy Priest, east of downtown NashvilleSite: Hendersonville, TN

Measurement Period: January 10 through April 5, 2000

# of samples: 12

AVGSTD

12.234.72

3.851.61ppbv

0.360.20ppbv

0.590.40ppbv

WT Sum00

12.2 +-4.7

GF Jul01



1/101/10/00 19:001/11/00 18:59143024.0999811.2292.925138.00.730.340.002.690.690.280.410.015.406.400.165.560.050.290.040.060.140.900.130.000.041.610.00XX0.640.960.172.422.740.151.671.352.4-16219516.12.55.10.028.911.53.12.630.143.549.322.1145.1

1/161/16/00 19:001/17/00 18:59124420.1610114.5752.36215.00.320.140.013.280.910.370.510.0216.710.330.4217.130.071.340.000.062.011.150.090.000.040.00XX0.000.130.130.130.1312.3712.37-743224-186.711.77.80.00.80.872.20.80.89.283.0

1/221/22/00 19:001/23/00 18:59108217.479990.7961.21334.00.250.240.004.251.330.840.470.029.8510.291.8911.740.031.030.000.001.192.740.440.600.004.130.00XX1.652.481.056.827.650.03-0.06-0.891.4-5719571923.310.28.80.035.114.18.90.2-0.558.165.132.1154.8

2/32/3/00 19:002/4/00 18:59142923.181000.52.3622.830338.00.380.220.261.710.850.490.360.005.657.141.498.730.001.540.000.042.001.730.230.170.042.140.00XX0.861.280.443.433.860.04-0.00-0.431.4-853236-1719.822.917.60.024.59.85.00.4-0.039.344.227.3110.7

2/92/9/00 19:002/10/00 18:59143024.32996.513.8453.219555.01.120.890.082.332.431.141.280.0110.3210.750.8511.640.041.210.000.000.752.840.150.000.234.590.00XX1.842.750.376.807.710.040.00-0.921.4-671259424.46.510.40.039.415.83.20.30.058.466.333.6158.2

2/152/15/00 19:002/16/00 18:59142924.02100312.4552.830918.00.800.580.203.241.810.880.920.0017.021.4115.120.012.340.080.042.683.550.180.230.094.230.00XX1.692.540.516.437.280.130.00-0.851.4-1304374-1323.517.715.50.028.011.23.40.80.042.548.132.3123.0

2/212/21/00 19:002/22/00 18:59142923.98101013.8342.116259.00.570.810.233.501.470.780.690.007.187.410.9710.820.041.080.000.010.501.950.400.130.104.620.14XX1.852.770.637.108.030.050.00-0.921.4-60841-1118.04.69.91.342.717.15.90.50.065.774.224.8164.7

2/272/27/00 19:002/28/00 18:59137922.7310099.2550.93361.00.390.410.132.010.920.400.530.003.343.490.965.380.090.670.040.010.261.490.390.320.051.470.00XX0.590.880.752.813.100.150.00-0.291.4-37431-227.74.812.40.127.310.914.02.80.052.257.638.1147.9

3/43/4/00 19:003/5/00 18:59142923.7610019.5570.828168.07.230.430.094.231.330.530.800.007.467.623.6712.410.021.940.000.012.852.540.430.140.083.150.00XX1.261.890.655.065.690.020.00-0.631.4-1074653-920.522.915.60.025.410.25.20.20.040.845.928.2114.8

3/303/30/00 19:003/31/00 18:59143124.2699211.5492.161.450.460.162.942.091.061.030.006.8410.612.6410.350.021.370.000.020.992.840.330.370.112.690.55XX1.071.610.814.575.110.030.00-0.541.4-761659-127.49.613.25.425.910.47.80.30.044.149.337.7131.1

4/54/5/00 19:004/6/00 18:59143924.8998318.0513.32121.530.620.121.612.530.991.510.027.037.511.128.150.000.930.000.040.311.860.430.480.122.040.00XX0.811.221.043.894.290.041.110.711.9-52539-822.93.811.40.025.010.012.70.513.747.752.731.5145.5

AVG10-Jan-005-Apr-001123.0100010.0542.242.91.380.480.122.861.500.710.790.017.838.111.4210.550.031.250.010.031.242.140.290.220.083.040.071.221.830.594.905.510.071.390.781.6-692045-521.010.711.70.630.112.06.40.94.549.055.028.9139.297.9

StDev2.285.0170.919.02.050.240.090.900.660.310.380.013.464.211.033.560.030.580.030.021.010.820.130.190.061.250.170.500.750.291.762.000.051.311.390.4321617105.67.73.71.76.62.64.10.910.28.910.17.718.8

1120.311.711.90.628.811.55.60.713.246.552.328.0137.4104.4

Site: Dickson, TN

Measurement Period: January 10 through April 5, 1999

# of samples: 11

AVGSTD

10.553.56

2.860.90ppbv

0.480.24ppbv

1.382.05ppbv

GF Jul01

10.6 +-3.6

GF Jan02

Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6TOC.6+svocOthersUnID.4UnID.6UnID.6svMw/CwMw/Cw +svocNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6TOC.6+svocCheckSum

ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%][%]

11-Jun-008:16:007:00:001364Macon ML61.73.010.670.290.402.617.343.264.010.0711.6816.47CH1, deh; SC13.780.210.660.030.040.723.700.000.680.554.890.34XX1.962.931.238.089.069.060.280.00-0.98-0.981.41.4-3712775226.95.24.82.535.514.28.92.00.058.665.765.737.0227.0

12-Jun-008:06:007:05:001379Macon Sat55.41.810.580.470.225.322.442.850.0412.25CH1; deh12.250.250.380.110.010.611.240.150.110.133.430.19XX1.372.060.395.195.885.880.374.283.593.592.62.6-2110261510.14.93.11.628.011.23.23.034.942.448.048.013.9187.1

13-Jun-007:24:007:19:001435Macon Sat47.51.120.410.220.153.091.141.930.0211.939.06CH2; deh9.060.110.690.000.000.871.660.910.120.301.770.51Qdiff0.711.061.333.814.164.160.111.411.051.052.22.2-3814351018.39.67.65.619.57.814.71.315.542.146.046.025.2174.8

14-Jun-007:43:0018:39:00656Macon Sat42.40.990.620.280.464.621.642.950.039.388.33CH2; deh8.330.210.630.040.000.142.000.470.090.151.440.180.00XAD0.580.860.712.723.013.010.252.402.112.113.13.1-35242924.11.67.62.217.36.98.53.028.832.736.136.133.1166.9

14-Jun-0019:17:007:05:00708Macon ML1.160.190.120.054.382.122.250.0215.1114.51CH2; deh14.510.071.170.000.001.112.720.340.080.172.120.080.00XAD0.851.270.593.563.983.980.075.815.395.394.14.1-6518571018.77.78.00.614.65.84.10.540.024.527.427.425.8145.1




18-Jun-007:50:006:50:001380Macon ML38.00.310.160.190.393.551.641.880.0310.8913.25CH1; deh10.890.110.000.000.000.211.210.240.270.093.070.04XX1.231.840.604.905.525.520.114.423.813.812.82.803252811.11.90.00.428.211.35.51.040.645.050.750.715.2202.2




AVG11-Jun-0021-Jun-001248.71.330.410.230.190.503.901.652.220.0314.9511.9811.410.160.770.020.010.692.370.340.200.202.700.220.131.081.620.744.515.056.110.182.662.120.842.51.68-4311491821.05.86.82.123.19.27.01.723.339.343.955.0728.8180.4100.0

StDev7.60.700.150.090.150.741.500.730.780.015.553.092.750.050.440.040.010.441.010.250.180.141.110.130.310.440.670.341.591.810.260.091.531.560.530.60.0525721147.13.13.21.46.42.64.01.012.18.69.83.029.821.2

1220.86.06.82.023.69.46.51.623.339.544.353.528.6190.4100.0

Site: Macon, GA

Measurement Period: 6/11/00 - 6/21/00

# of samples: 12

AVGSTD

11.412.75

0.500.74ppbv

0.410.15ppbv

1.330.70ppbv

12.06

GF Jan02

20.9525849929

5.8439419028

6.7721223009

2.0959558156

23.1118512911

9.2447405165

6.9607896926

1.7231957446

23.294817743

Macon-ML Avg Mass Composition

Summary

Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwMw/Cw +svocNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6CheckSum


27-Jun-007:01:009:10:00156941.81.310.280.090.147.053.321.281.990.058.3913.80CH1; deh8.390.130.650.000.000.411.750.040.090.072.520.00XX1.011.510.203.734.240.131.721.221.222.12.1-36736720.94.87.70.030.112.02.41.620.544.550.528.7144.2

29-Jun-009:05:0018:50:0058546.81.210.350.291.783.311.092.180.0420.18CH1; deh20.180.051.100.000.080.067.070.000.000.152.530.340.00XAD1.011.520.153.684.190.137.817.307.304.54.5-6111478735.00.35.41.712.55.00.70.638.718.320.848.2125.9

29-Jun-0019:01:007:00:007190.570.140.070.001.760.790.960.0210.54CH1; deh10.540.001.070.360.000.352.290.000.000.083.100.061.29XAD1.241.860.084.435.050.361.981.360.082.01.4-59648-621.73.310.20.529.511.80.83.418.842.047.929.9138.6

2-Jul-009:05:0019:05:0060074.10.671.081.160.296.752.604.120.0336.51CH1; deh36.510.452.660.000.120.1910.510.020.000.302.720.050.00XAD1.091.630.324.134.670.5718.4017.8617.868.28.2-14832197428.80.57.30.17.43.00.91.650.411.312.839.6114.1

2-Jul-0019:15:007:06:007110.490.400.170.076.342.683.620.0330.05CH1; deh30.050.133.330.210.000.1110.790.130.870.295.780.221.71XAD2.313.471.299.3810.530.345.884.733.022.41.9-18422254235.90.411.10.719.27.74.31.119.631.235.149.4135.2

5-Jul-009:01:0018:59:0059872.60.651.541.150.4711.754.587.070.1029.54CH1; deh29.541.482.560.283.230.2310.031.881.480.315.110.640.00XAD2.043.063.6710.8211.844.980.28-0.74-0.741.51.5-14242097034.00.88.72.217.36.912.416.90.936.640.146.7124.4

5-Jul-0019:10:007:17:007270.880.590.280.007.793.204.560.0424.59CH1; deh24.590.131.820.000.200.725.581.391.190.353.100.790.00XAD1.241.862.937.277.890.348.087.467.464.04.0-101121162722.72.97.43.212.65.011.91.432.829.632.131.2125.7

8-Jul-009:01:0018:38:0057769.64.371.621.041.245.831.953.830.0627.70CH1; deh27.700.342.120.000.590.419.270.860.180.303.190.260.00XAD1.281.911.335.806.440.928.928.288.284.24.2-11771938233.51.57.60.911.54.64.83.332.220.923.246.0122.4

28-Jun-0010:35:008:18:00130241.01.620.310.140.083.441.262.160.0314.9210.80CH2; deh10.800.190.890.000.020.852.540.460.280.141.150.26Qdiff0.460.690.882.492.720.213.553.313.314.54.5-4914531723.57.98.22.410.74.38.22.032.823.125.232.4113.6

29-Jun-009:00:007:00:00132044.01.000.340.061.542.591.101.460.0215.76CH1; deh15.760.091.450.000.020.575.400.400.390.182.960.360.00XAD1.181.780.975.125.710.112.752.152.152.32.3-8091124134.33.69.22.318.87.56.10.717.432.536.247.1133.3

30-Jun-009:00:007:00:00132067.00.900.480.570.653.631.562.050.0261.6724.86CH2; deh24.860.002.860.000.030.228.480.530.290.174.750.48Qdiff1.902.850.997.648.590.045.154.204.202.52.5-15841772234.10.911.51.919.17.64.00.220.730.734.546.9132.9

1-Jul-009:00:007:00:00132074.00.960.480.200.483.801.502.280.0230.9425.86CH2; deh25.860.013.040.060.000.419.640.590.540.264.060.37Qdiff1.622.431.397.077.890.075.254.444.442.72.7-16972013937.31.611.81.415.76.35.40.320.327.430.551.3129.4

2-Jul-009:00:007:00:00132071.00.770.610.340.655.642.333.290.0339.12CH1; deh39.120.103.380.000.060.0711.240.620.450.245.240.350.00XAD2.103.151.308.649.690.1615.2714.2214.224.34.3-18712344828.70.28.60.913.45.43.30.439.022.124.839.5125.4

3-Jul-009:00:007:00:00132065.50.700.620.910.285.712.223.460.0333.2125.60CH2; deh25.600.062.380.000.000.298.181.971.010.364.320.33Qdiff1.732.593.349.3910.250.064.974.114.112.62.6-13251704331.91.19.31.316.96.813.00.219.436.740.043.9140.1

4-Jul-009:00:007:00:00132069.40.610.650.270.977.412.794.590.0341.6032.40CH2; deh32.400.173.180.000.110.5110.781.800.840.315.660.40Qdiff2.273.402.9510.8812.010.286.375.245.242.52.5-17682255633.31.69.81.217.57.09.10.919.733.637.145.8136.1

5-Jul-009:00:007:00:00132072.61.210.940.420.557.802.854.910.0429.12CH1; deh29.120.292.020.170.420.457.203.281.080.244.170.400.00XAD1.672.504.6010.4411.270.887.726.896.893.33.3-11271504524.71.56.91.414.35.715.83.026.535.838.734.0135.1

6-Jul-009:00:007:00:00132066.01.550.690.250.185.862.323.500.0427.3023.96CH2; deh23.960.101.900.060.030.446.530.890.770.192.870.50Qdiff1.151.721.865.876.440.208.527.957.954.44.4-10571363827.21.87.92.112.04.87.70.835.624.526.937.5124.4

7-Jul-009:00:007:00:00132081.91.610.700.351.764.391.792.570.0327.5322.51CH2; deh22.510.352.950.020.510.248.491.350.640.182.550.30Qdiff1.021.532.185.756.260.873.923.413.412.92.9-16441771737.71.013.11.311.34.59.73.917.425.527.851.8122.6

8-Jul-009:41:007:00:00127870.02.990.660.391.564.541.792.710.0338.81CH1; deh38.810.303.870.000.211.578.570.620.330.172.900.220.00XAD1.161.741.125.185.760.5118.9018.3218.327.97.9-21425178-1122.14.010.00.67.53.02.91.348.713.314.830.4107.3

9-Jul-009:00:007:00:00132053.00.940.710.460.335.702.143.540.0330.1118.33CH2; deh18.330.192.160.000.350.438.171.070.370.303.260.53Qdiff1.311.961.746.316.960.540.18-0.47-0.471.51.5-11971705844.62.411.82.917.87.19.53.01.034.438.061.3134.7

AVG27-Jun-009-Jul-002063.51.230.610.090.391.155.152.013.110.0330.2021.8624.280.192.290.040.220.457.460.950.540.223.580.340.221.432.151.716.737.440.466.555.831.543.41.65-12771553630.52.39.41.516.06.47.01.925.029.432.642.0129.0100.0

StDev12.90.690.260.000.271.981.850.691.160.0115.656.739.400.190.970.080.410.352.960.860.350.081.230.170.490.490.741.222.512.730.635.155.102.081.70.3054662236.92.01.90.96.12.44.22.212.08.49.59.510.1

2030.71.99.41.414.85.97.01.927.027.730.742.3129.0100.0

Site: Augusta, GA


# of samples: 20

AVGSTD

24.289.40

1.151.98ppbv

0.610.26ppbv

1.230.69ppbv

Summary

30.5185434427

2.3069375102

9.3866289564

1.4723449722

16.0220957092

6.4088382837

6.9514242268

1.9150944913

25.0180924076

Augusta Avg Mass Composition

PMhisto



18-Jul-007:21:006:59:0013312.311.090.513.398.093.134.900.0628.15CH1; deh28.150.002.070.000.000.366.640.941.010.287.990.693.08XAD3.194.792.2413.4215.010.004.973.370.292.01.5-11561382923.61.37.42.428.411.37.90.017.647.753.332.5151.1

19-Jul-007:16:006:59:00142386.61.661.370.520.491.8117.756.9110.750.0925.67CH1; deh25.670.132.030.030.000.275.170.490.680.459.100.54XX3.645.461.6314.3716.190.173.111.291.291.71.7-1134108-120.11.17.92.135.514.26.30.612.156.063.127.7158.9

20-Jul-007:23:006:59:00141680.01.091.280.120.351.538.083.394.630.0717.3524.34CH1; deh17.350.001.720.000.000.245.090.570.470.175.570.25XX2.233.341.209.0110.120.001.04-0.07-0.071.61.6-9541061529.41.49.91.432.112.86.90.06.051.958.340.4156.6

21-Jul-007:36:0018:59:0068376.81.301.090.281.335.121.783.290.0616.98CH1; deh; SC27.130.890.960.081.270.303.221.131.040.2512.740.168.78XAD5.107.652.4220.2722.812.240.00-2.55-11.331.40.8-535671911.91.13.50.647.018.88.98.30.074.784.116.3175.1

22-Jul-007:27:006:59:00141276.21.290.940.320.291.218.083.654.370.0517.4529.42CH1; deh17.450.121.830.000.000.325.290.120.420.176.160.37XX2.473.700.719.3410.570.120.18-1.05-1.051.41.4-10151101430.31.810.52.135.314.14.10.71.153.560.641.7156.9

23-Jul-007:31:006:59:00140879.00.040.770.080.271.255.902.713.130.0613.8523.23CH1; deh13.850.721.500.290.000.314.300.250.330.133.760.26XX1.512.260.715.986.731.000.50-0.26-0.261.51.5-835901231.12.310.81.827.210.95.27.23.643.248.642.7138.1

24-Jul-007:38:0018:59:0068157.21.570.710.180.204.891.523.310.0615.37CH1; deh; SC15.870.061.440.000.080.325.330.470.330.205.190.392.20XAD2.083.121.008.279.310.14-0.00-1.04-3.231.41.0-8051113633.62.09.02.432.713.16.30.9-0.052.158.646.2156.9

24-Jul-0021:22:006:59:005771.200.310.010.873.441.362.050.0317.99CH1; deh; SC23.830.002.270.000.000.366.310.420.330.209.820.196.54XAD3.935.890.9514.7016.660.000.00-1.96-8.511.40.8-12661311226.51.59.50.841.216.54.00.00.061.769.936.4168.0

25-Jul-007:30:006:59:00140967.20.750.160.310.775.912.553.310.0619.5135.02CH1; deh19.510.002.150.000.120.187.890.000.110.144.760.20XX1.902.860.246.917.860.122.061.111.111.81.8-11931644840.40.911.01.024.49.81.20.610.635.440.355.6141.9

16-Jul-009:00:0019:00:0060073.33.421.890.912.198.452.815.570.0624.8820.83CH2; deh20.830.761.730.141.080.365.672.990.820.284.430.00Qdiff1.772.664.0910.2911.181.980.79-0.09-0.091.61.6-9661182827.21.78.30.021.38.519.69.53.849.453.737.5144.4

17-Jul-009:00:007:00:00131487.31.210.970.472.315.892.273.580.0522.9018.39CH2; deh18.390.001.440.000.000.464.282.150.630.185.201.05Qdiff2.083.122.9610.2411.280.000.92-0.12-0.121.61.6-807891623.32.57.95.728.311.316.10.05.055.761.332.0154.0

18-Jul-008:23:007:00:00135699.81.651.100.503.718.904.284.560.0736.63CH1; deh; TEOM30.640.002.550.000.000.487.521.790.670.227.270.541.21XAD2.914.362.6912.8614.310.006.705.244.032.32.0-14181562324.51.68.31.823.79.58.80.021.942.046.733.7144.3

19-Jul-008:20:007:00:00135686.62.281.140.481.1615.738.077.590.0834.6126.58CH2; deh26.580.041.970.000.000.476.061.390.420.365.320.53Qdiff2.133.192.179.6210.690.047.896.836.832.92.9-10981262422.81.87.42.020.08.08.20.129.736.240.231.4137.5

20-Jul-008:19:007:00:00135680.03.081.990.523.059.473.336.060.0918.46CH2; deh18.460.262.040.300.320.075.660.140.140.013.460.34Qdiff1.382.070.295.135.820.894.333.633.632.72.7-1131118630.70.411.01.918.77.51.64.823.427.831.542.2124.9

21-Jul-009:20:007:00:00129674.00.000.500.520.067.365.521.630.2157.23CH1; deh; TEOM33.780.002.650.000.030.108.850.310.030.117.270.251.81XAD2.914.360.4510.6212.080.0311.289.828.023.02.4-14721843926.20.37.90.721.58.61.30.133.431.535.836.0136.6

22-Jul-008:45:007:00:00133276.21.240.950.222.285.232.133.050.0524.5219.59CH2; deh19.590.151.760.000.050.385.481.180.590.244.140.35Qdiff1.652.482.017.808.630.203.612.782.782.32.3-9861142328.01.99.01.821.18.410.31.018.439.844.038.5140.8

23-Jul-008:26:007:00:00135079.00.540.370.100.884.882.282.540.0621.2714.10CH2; deh14.100.221.450.050.150.244.690.370.580.162.470.28Qdiff0.991.481.124.585.070.422.441.951.952.42.4-804982133.31.710.32.017.57.07.93.017.332.536.045.8131.6

24-Jul-008:43:007:00:00133269.00.840.540.091.293.091.201.860.0420.39CH1; deh20.390.131.870.000.160.306.040.750.310.164.710.251.14XAD1.882.821.237.828.760.293.822.871.732.21.8-10451262729.61.59.21.223.19.26.01.418.738.343.040.8140.8

25-Jul-008:31:007:00:00134463.00.910.510.240.395.332.552.740.0424.7916.90CH2; deh16.900.002.020.000.000.236.880.410.410.213.210.14Qdiff1.281.931.045.536.170.002.091.451.452.12.1-11241433540.71.411.90.819.07.66.10.012.432.736.556.0137.7

AVG18-Jul-0025-Jul-001977.11.360.960.240.351.617.743.414.260.0719.7822.6421.390.151.890.050.120.305.880.770.470.205.670.380.912.273.401.459.3810.520.323.232.100.502.01.61-10551222228.51.59.21.826.310.56.81.713.743.749.039.2145.5100.0

StDev10.00.860.420.180.161.053.951.872.350.048.746.365.880.220.370.100.210.121.330.670.260.102.120.231.550.851.270.903.363.780.453.002.955.500.50.5220228136.30.61.71.16.72.73.92.49.710.311.68.611.0

1927.51.48.91.826.510.66.81.515.143.949.237.8145.5100.0

Site: Columbus, GA


# of samples: 19

AVGSTD

21.395.88

1.611.05ppbv

0.960.42ppbv

1.360.86ppbv

PMhisto

28.4872865594

1.4678672787

9.1699564421

1.8131057469

26.3262172619

10.5304869048

6.8448773271

1.6960182678

13.6641842112

Columbus Avg Mass Composition

GAShisto



8/168/16/00 0:008/17/00 0:001424.0011.62102229.266.52.240.470.290.131.744.043.180.740.1221.7927.870.5722.081.490.160.810.670.011.201.762.290.220.070.050.660.690.43XAD0.260.400.341.271.403.5311.7211.5911.1619.111.6-4528483110.48.03.73.13.01.21.616.053.15.76.314.379.4

8/178/17/00 0:008/18/00 0:001438.0023.22101929.499.43.130.570.100.382.932.540.771.680.0927.7830.201.1628.940.640.081.420.460.010.191.383.780.190.310.151.510.320.38XAD0.600.900.652.763.061.3817.8917.5917.2113.310.6-7922792213.14.84.91.15.22.12.24.861.89.510.618.099.9

8/188/18/00 0:008/20/00 0:032876.0024.01101928.597.61.560.550.250.411.034.201.412.730.0622.4531.241.2623.710.270.102.640.150.040.110.858.740.430.340.212.030.401.10XAD0.811.220.983.834.230.676.576.175.074.63.0-147141824936.93.611.21.78.63.44.12.827.716.117.950.7112.5

8/208/20/00 0:008/21/00 0:001436.0011.83101928.373.92.830.000.260.280.803.010.732.210.0715.8819.910.8516.730.130.022.280.010.010.020.437.320.030.060.173.270.181.14XAD1.311.960.254.835.480.191.490.84-0.301.91.4-12671523343.72.613.61.119.57.81.51.18.928.932.860.2130.7

8/218/21/00 0:008/22/00 0:001438.0023.82101928.8116.62.470.340.110.521.744.091.352.670.0715.8919.981.0916.980.140.022.900.090.010.020.477.690.020.230.151.650.360.11XAD0.660.990.402.723.050.282.552.222.112.92.8-1618160745.32.817.12.19.73.92.41.715.016.018.062.3111.3

8/228/22/00 0:008/23/00 0:001383.0011.48102128.269.83.750.000.350.231.535.201.673.470.0617.9123.755.2223.130.120.073.060.030.010.070.737.853.181.350.153.750.681.06XAD1.502.254.689.9310.690.300.58-0.17-1.231.61.2-17012163533.93.213.22.916.26.520.21.32.542.946.246.7138.3

8/238/23/00 0:008/24/00 0:001440.0023.83102027.481.83.010.660.500.342.632.611.211.370.0413.2117.312.2215.430.160.062.170.030.020.000.945.050.490.310.161.960.630.32XAD0.791.180.963.714.110.272.662.271.952.82.4-12015105032.76.114.04.112.75.16.21.717.324.126.645.0112.9

8/248/24/00 7:038/25/00 0:001019.005.65102026.8132.73.090.430.490.472.305.071.973.040.0611.5013.820.8912.390.080.001.640.050.100.230.644.020.090.090.272.810.571.97XAD1.121.680.454.384.940.470.670.11-1.861.61.0-911084332.45.213.24.622.69.13.63.85.435.339.944.6125.2

8/258/25/00 0:008/26/00 0:001438.0020.57101927.6122.81.020.150.401.273.451.491.920.046.176.524.4110.930.070.000.980.760.010.000.791.652.390.960.142.091.061.13XAD0.841.263.496.426.840.84-0.81-1.23-2.361.00.7-541334-715.17.28.99.719.17.731.97.7-7.458.762.620.8134.7

8/268/26/00 0:008/27/00 0:001434.007.95101628.279.33.660.700.470.521.144.591.812.700.086.638.771.5510.320.070.000.960.000.020.000.552.290.520.490.461.740.580.67XAD0.701.041.473.904.250.091.941.600.922.51.8-53948322.25.39.35.616.96.714.20.918.837.841.230.5128.4

8/278/27/00 0:008/28/00 0:001438.0020.70101528.463.12.120.500.230.381.293.441.322.090.039.0510.533.0312.070.130.001.540.000.000.000.613.721.610.520.160.630.292.59XAD0.250.382.293.173.290.132.602.48-0.125.51.1-861078230.85.112.82.45.22.118.91.121.626.227.342.4117.5

8/288/28/00 0:008/29/00 0:001377.0011.41101628.659.26.140.390.170.371.182.881.021.840.0212.2612.480.0012.260.260.021.070.060.010.000.423.680.030.060.151.290.551.56XAD0.520.780.242.052.310.364.133.872.314.62.1-597772430.03.48.74.510.54.22.02.933.716.718.841.3110.5

8/298/29/00 0:008/30/00 0:001438.0020.88101728.994.44.130.730.110.580.864.042.111.890.0511.5511.645.2016.750.250.021.360.090.000.290.643.503.081.300.231.110.190.35XAD0.450.674.616.176.400.654.234.013.665.24.0-751073820.93.88.11.26.72.727.53.925.336.938.228.7129.1

8/308/30/00 0:008/31/00 0:021434.008.03101430.4219.73.551.200.290.725.505.772.802.900.069.6810.7210.720.140.050.840.160.010.000.302.630.070.050.183.721.462.22XAD1.492.230.315.526.260.37-0.40-1.14-3.361.30.8-475551324.52.87.913.634.713.92.93.4-3.751.458.433.8139.9

8/318/31/00 0:049/1/00 0:021438.0021.26101032.5198.03.3611.3211.5011.320.200.001.120.110.010.000.133.390.010.020.042.700.743.03XAD1.081.620.073.854.390.321.771.23-1.802.11.0-622711029.91.19.96.623.99.60.62.815.634.038.841.2129.7

9/19/1/00 0:049/2/00 0:021436.0012.15101131.3100.31.360.330.360.130.473.471.901.560.0216.2718.0516.270.170.001.450.040.000.000.125.200.020.030.174.441.253.90XAD1.782.660.216.427.310.211.620.73-3.171.80.9-8021083032.00.78.97.727.310.91.31.310.039.544.944.0138.4

9/29/2/00 0:049/3/00 0:021438.0020.90101131.4134.32.561.000.150.471.434.281.672.580.0315.0516.7415.050.270.051.950.000.000.000.236.260.010.010.122.550.422.99XAD1.021.530.143.714.220.322.161.65-1.352.21.0-10841302641.61.513.02.817.06.80.92.114.324.728.057.2124.3

9/39/3/00 0:049/4/00 0:021438.0018.01101032.4127.72.6514.2314.4114.410.290.001.000.070.000.020.373.320.010.000.106.080.654.16XAD2.433.650.118.629.830.390.07-1.15-5.311.40.8-566691923.02.67.04.542.216.90.82.70.559.868.231.7160.2

9/49/4/00 13:249/5/00 0:02638.009.39100935.711323.5023.1123.502.180.051.880.060.060.000.165.860.020.030.365.620.990.76XAD2.253.370.418.279.402.344.002.872.112.11.9-10431222024.90.78.04.223.99.61.710.017.035.240.034.3126.5

9/59/5/00 0:049/6/00 0:021432.006.11101032.6127.15.8126.1035.0826.101.340.352.550.260.420.030.356.390.721.780.267.811.023.90XAD3.124.692.7613.6915.262.40-0.30-1.86-5.761.40.9-1416133-324.51.39.83.929.912.010.69.2-1.252.558.433.7143.4

9/69/6/00 0:049/7/00 0:021438.0020.88101128.2107.537.1143.3740.240.240.163.790.080.340.410.1812.200.010.010.0014.191.113.68XAD5.678.510.0219.8822.721.221.86-0.98-4.651.51.2-21032544730.30.49.42.835.314.10.13.04.649.456.541.7152.2

9/79/7/00 0:049/8/00 0:011435.0011.97101027.565.814.3215.2514.780.460.001.160.070.040.000.033.190.020.030.116.240.651.12XAD2.503.750.168.9010.140.570.28-0.97-2.091.41.2-64166321.60.27.84.442.216.91.03.91.960.268.629.7160.4

9/89/8/00 0:039/9/00 0:011438.0020.67101025.448.711.0514.1112.580.060.001.320.020.000.000.063.890.010.010.045.030.000.00XAD2.013.020.067.098.100.080.13-0.87-0.871.41.4-73181931.00.510.50.040.016.00.50.71.056.464.442.6164.4

9/99/9/00 0:039/10/00 0:011436.0011.97101026.758.15.169.127.820.100.000.830.000.000.000.112.730.010.010.041.580.630.21XAD0.630.950.062.272.580.111.160.840.632.11.9-462571334.81.410.68.020.28.10.71.414.829.033.047.9124.7

9/109/10/00 0:039/11/00 0:021439.0020.90101128.661.410.3215.1810.320.230.001.300.040.000.030.174.650.030.020.061.530.421.31XAD0.610.920.102.242.550.301.240.93-0.372.21.2-723972745.01.612.64.014.85.91.02.912.021.724.762.0120.4

9/119/11/00 0:039/12/00 0:021436.008.03101128.238.97.048.587.040.120.000.950.110.000.050.262.770.010.000.031.120.260.21XAD0.450.670.051.611.830.290.890.670.462.21.9-53458939.43.713.53.815.96.30.74.112.722.926.154.2115.8

9/139/13/00 0:039/14/00 0:011436.0013.94101325.129.84.635.155.150.090.000.480.090.000.080.201.330.000.000.181.290.570.55XAD0.520.780.181.992.250.250.320.07-0.481.71.2-26328525.74.09.211.125.110.13.54.96.338.743.735.4124.1

AVG16-Aug-0013-Sep-002715.6101528.995.83.100.560.260.401.693.911.632.230.0614.8718.002.0716.350.320.051.640.130.040.100.504.780.500.310.153.190.601.511.281.910.965.426.060.652.772.130.623.52.3-918991629.83.110.34.419.87.96.13.614.933.837.741.0127.5100.0

StDev6.242.044.11.310.310.120.141.150.860.620.670.037.709.991.647.710.370.080.850.190.100.230.412.740.890.460.092.800.341.281.121.681.324.004.530.754.044.254.873.82.647757189.22.02.93.211.74.78.53.115.816.318.412.718.9

2729.23.010.03.719.57.85.84.016.933.137.040.2127.5100.0

For light org. acids experimental denuder efficiencies are taken into account; for all other species, efficiencies of 1 are assumed.Site: LaPorte, Houston, TX


# of samples: 48

AVGSTD

16.357.71

1.691.15ppbv

0.560.31ppbv

3.101.31ppbv

GAShisto

29.8122667835

3.1400621334

10.3074417845

4.4049777578

19.7980173963

7.9192069585

6.0586860142

3.6156278288

4.871436349

EAS 4/8803: Experimental Methods in AQ

Documents

gameasurement of o3

o3 agriculture

stratospheric o3

haps air toxics

experimental methods

tonsyr so2

air pollutants of concern

emissions standards