Draft-Transportation-of-Dangerous-Goods-by-Road-Standard ...

© SADCSTAN – All rights reserved

Date: 2018-11-30

SADCSTAN HT [Insert number]

Secretariat: [Insert Secretariat]

Vehicle Standards – Transportation of Dangerous Goods by Road

Warning

This document is not a SADC Standard. It is distributed for review and comment. It is subject to change without notice and may not be referred to as a SADC Standard.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are aware and to provide supporting documentation.

SADCSTAN HT [Insert Number]

© SADCSTAN – All rights reserved i

© SADCSTAN All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior written permission.


© SADCSTAN – All rights reserved ii

Contents Page

Foreword

1 General provisions

1.1 Scope

1.2 Application

1.3 Structure

2 Normative references

3 Definitions and abbreviations

4 Exemptions

5 Dangerous Goods classification

6 Dangerous Goods list and special provisions

7 Transport operations

7.1 Requirements for responsible parties

7.1.1 The Consignor

7.1.2 The Operator

7.1.3 The Driver

7.1.4 The Qualified person

7.1.5 The Party contracting the operator

7.1.5 The Consignee

7.2 Operational requirements

7.2.2 Insurance

7.2.3 En route procedures

7.2.4 Application of a quality management system

7.2.5 Equipment to be carried on the vehicle

7.2.6 Training of personnel

7.3 Use of vehicles and equipment

7.3.1 Provisions applicable to all classes

7.3.2 Provisions applicable to classes 3 to 9

7.3.3 Provisions applicable to class 2

7.3.4 Vehicle types

7.3.5 Continued use of vehicles

7.4 Vehicle and equipment maintenance and inspections

7.4.1 General

7.4.2 Dangerous goods vehicles inspection schedules and requirements

7.4.3 Repair and modification of tanks


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7.4.4 Repair, refurbishment and modification of equipment

7.4.5 Maintenance, repair, inspection and test personnel and facilities

7.5 Load constraints

7.5.1 Exempt quantities for a load consisting of items with the same UN number

7.5.2 Exempt quantities for a mixed load

7.5.3 Load compatibility

7.6 Cargo handling

7.6.1 Cargo

7.6.2 Packaged goods

7.6.3 Bulk transport

7.6.4 Freight containers that contain packaged goods

8 Emergency information systems

8.1 Signage

8.2 Documentation

9 Packaging for road transport

10 Vehicles and equipment

10.1 Compliance with standards

10.2 Design and construction requirements - Vehicles

10.3 Requirements related to equipment fitted to tanks

10.4 Design and construction requirements for tanks constructed out of metal (excluding portable tanks)

10.5 Additional requirements for tanks for Class 2 product

10.6 Requirements for welded tanks for which a test pressure of at least 1 MPa is required, and of welded tanks intended for the transport of refrigerated liquefied gases of class 2

10.7 Requirements for FRP tanks

10.8 Requirements for vacuum tanks

10.9 Requirements for MEMU's

10.10 Requirements for portable tanks

10.11 Requirements for bulk containers

10.12 Responsibilities of competent authorities

11 Annexures

Annex A (Normative) Dangerous goods list and exempted quantities P provisions B provisions L provisions O provisions Additional requirements for tanks for Class 2 products

Annex B (Normative) Maintenance inspections and test schedules

Annex C (Normative) A transport emergency card

Annex D (Normative) A completed dangerous goods declaration (DGD) and a waste dangerous goods declaration (WDGD)


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Annex E Reserved for future use

Annex F (Normative) Incident report format

Annex G (Normative) Gasses and gas mixtures To be added

Annex H (Normative) Equipment standard

Annex I (Normative) Minimum requirements for non-compliant vehicles and tanks to continue operation

Bibliography


© SADCSTAN – All rights reserved v

Foreword The objective of this document is to provide a harmonised common standard governing the transportation of classified dangerous goods by road in the COMESA-EAC-SADC Tripartite Region (hereinafter referred to as the "Region". The primary function is to facilitate cross-border transportation by ensuring that all participants abide by the same rules thus ensuring a safe operation and safety of society in general. The standardised approach also allows law enforcement authorities to effectively apply a standardised set of requirements. The three Regional Economic Communities (RECs) that comprise the Tripartite are as follow (in alphabetical order): COMESA Common Market for East and Southern Africa EAC East African Community SADC Southern African Development Community The member/partner states of the three RECs are as follow (in alphabetical order): COMESA: Burundi, Djibouti, Democratic Republic of Congo, Egypt, Eritrea, Eswatini, Ethiopia, Libya, Malawi,

Rwanda, Sudan, Somalia, Tunisia, Zambia and Zimbabwe EAC: Burundi, Kenya, Rwanda, Tanzania, Uganda and South Sudan SADC: Angola, Botswana, Comoros, Democratic Republic of Congo, Eswatini, Lesotho, Madagascar, Malawi,

Mauritius, Mozambique, Namibia, South Africa, Tanzania, Zambia and Zimbabwe. It however needs to be understood that participating member states could elect to adopt more stringent requirements for domestic transport operations, but these would not be enforceable on cross-border, non-resident operators who have been granted a dangerous goods cross border operating authorisation by the designated competent authority of another Tripartite member state. The European Agreement concerning the International Carriage of Dangerous Goods by Road developed by the United Nations Economic Commission for Europe (UNECE), referred to as the ADR, was adopted by the Tripartite as the direction of harmonisation on Dangerous Goods standards by the region. The harmonised standard is similar to the ADR in approach. It has however been adapted and developed to serve as minimum requirements as a point of departure for the Region. It will be reviewed at regular intervals by notification of new compulsory requirements to all member states at regular intervals through SADCSTAN, as the region advances. This harmonised standard was developed and published in terms of the Multilateral Cross Border Road Transport Agreement (MCBRTA) entered into by the Tripartite Member/Partner States on the Continent of Africa. In accordance with the agreement amongst COMESA, EAC and SADC, it was approved by SADCSTAN on <date> and submitted to ARSO for adoption by COMESA and EAC. This document must be read in conjunction with the Model Law on the Transportation of Dangerous Goods by Road prepared by the Tripartite for adoption as national legislation by the participating member states in the Region. Where the document refers to "relevant national legislation", this means the Transportation of Dangerous Goods by Road Model Law promulgated by the participant member state as relevant to the section of the document. The standard is further supported by the introduction of various other model laws for the Region that governs Cross-Border Road Transport, Vehicle Load Management, Road Traffic, as well as Road Transport and Traffic Transgressions Model Laws and Regulations. Where reference is made to "relevant national standards bodies", this refers to the standard body of each participant member state. The document is structured as follow: Section 1 General provisions, normative references, exemptions and definitions Section 2 Normative references Section 3 Definitions and abbreviations Section 4 Exemptions Section 5 Dangerous Goods Classification Section 6 Dangerous Goods list and exempt quantities Section 7 Operational requirements


© SADCSTAN – All rights reserved vi

Section 8 Emergency information systems Section 9 Packaging of Dangerous Goods for road transport Section 10 Construction of vehicles, tanks and equipment Section 11 Annexures related to sections 1 to 6 which form an integral part of the standard


© SADCSTAN – All rights reserved 1

Section 1

General provisions

1.1 Scope

1.1.1 This standard establishes requirements for the safe operation and handling of all road vehicles used for the transport of dangerous goods: - In quantities in excess of the specified exempt quantities - In operations that are not exempt from compliance with this standard

1.1.2 The following elements of the road transport operation are included in this standard: - The classification of dangerous goods - The operation of dangerous good vehicles, which in turn, includes responsibilities and requirements for the consignor, the consignee, the operator, the driver and the qualified person as well as en route procedures - Load constraints and cargo handling - Requirements governing vehicle and equipment design and construction - Vehicle and equipment maintenance, inspections and tests - Information systems and documentation

1.2 Application

1.2.1 The document will be applied to the transportation of dangerous goods by road - Between participant member states in the Region - Within the borders of each participant member state

1.2.2 A participant member state may however apply higher standards and requirements for domestic transport, but these will not apply to vehicles transporting dangerous goods from other member states.

1.2.3 Vehicles and equipment designed and constructed to higher levels of technical standards than described in this document, may be used throughout the Region.

1.2.4 The stated requirements of the relevant national legislation on explosives (Class 1) radioactive materials (Class 7) take precedence over the requirements of this standard.

1.2.5 Goods that are not classified as dangerous goods in terms of the relevant classification requirements, do not resort under the requirements of this standard.

1.2.6 Any inclusion in the standard precede by the word "NOTE" and written in italics is not a mandatory requirement and is included for clarification purposes only.



1.3 Document structure

This document is structured as follows:

1.3.1 Section 1: This section contains the scope and describes the application of the document

1.3.2 Section 2: This section contains the normative references which form an inherent part of the requirements of the standard.

1.3.3 Section 3: This section contains the applicable definitions and abbreviations used in the standard. It must be noted that additional definitions may be included in individual sections of the standard.

1.3.4 Section 4: This section includes exemptions regarding: - The operations and conditions that are exempted from the requirements of the standard - The quantity of goods below which the application of this standard do not apply

1.3.5 Section 5: This section includes the requirements for the classification of dangerous goods.

1.3.6 Section 6: This section includes the list of classified dangerous goods. Included in this list are: - The exempt quantities - The tank design code applicable to the product - Special provisions related to the transportation of the product - Provisions related to the transportation of packaged goods, goods in bulk and the loading and off-loading of the goods

1.3.7 Section 7: This section contains the requirements governing transport operations. It includes elements such as: - Responsibilities of the various parties involved in the operation - Operational requirements which include en-route procedures, insurance, application of a quality management system and loose equipment to be carried on the vehicle - Vehicle and equipment maintenance, inspections and tests including record-keeping requirements - Use of tanks and equipment, continued use of non-compliant equipment and age limits of tanks - Load constraints including requirements for exempt quantities for single and mixed loads and product compatibility - Cargo handling which include requirements for transportation of packaged goods, goods in bulk and transportation using freight containers

1.3.8 Section 8: This section details the requirements for: - Documentation to be carried on the vehicle - Dangerous goods signage and warning signs

1.3.9 Section 9 Packaging – Reserved for future use

1.3.10 Section 10: This section contains the requirements for the design and construction of vehicles and equipment. It relates closely to the tank codes as contained in the dangerous goods list in section 6. It includes the following: - The requirements for compliance with relevant standards including equipment standards - The design and construction of the vehicles - The role of the competent authority in the approval of the vehicle - The inspection and testing of vehicles during construction and the related documentation - The responsibilities and tasks of competent authorities

1.3.11 Section 11: This section contains the various annexures related to the requirements contained in the sections. The annexure header indicates whether the Annexure is of a Normative or Informative nature.



The annexes are:

Annex A The dangerous goods list detailing the UN number, proper shipping name, class, packaging group, exempt quantity, vehicle type, tank code and special provision indicators

Annex B The in-service maintenance, inspections and test schedules including the requirements for special, non-periodic inspections and tests associated with special circumstances such as when a vehicle was involved in an accident, has been modified or has changed ownership. It also includes the requirements for record keeping and retention.

Annex C An example of the Transport Emergency Card for a listed dangerous good as carried on the vehicle

Annex D An example of a completed dangerous goods declaration and waste dangerous goods declaration carried on the vehicle whilst in-transit with a load

Annex E Reserved for future use

Annex F An example of the incident report that must be submitted to the relevant authorities when an incident has occurred.

Annex G Gasses and gas mixtures

Annex H Equipment standards

Annex I The minimum requirements applicable to vehicles and tanks that are non-compliant and that will allow them to continue operation.



Section 2

Normative references

The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. Information on currently valid harmonised and international standards can be obtained from the relevant national standards bodies.1

UN Model Regulations (Recommendations on the Transport of Dangerous Goods) – Volume I, Part 2

Emergency Response Guidebook, 2016 – US Department of Transport

ADR 2005 or later

European Agreement concerning the International Carriage of Dangerous Goods by Road, 2005 or subsequent publications

IEC 60079 Electrical apparatus for explosive gas atmospheres

IEC 60529 Degrees of protection provided by enclosures (IP Code).

ISO 1496-1 Series 1 freight containers - Specification and testing - Part 1 - General cargo containers for general purposes

ISO 1496-5 Series 1 freight containers - Specification and testing - Part 1 - Platform and platform-based containers

ISO 2878 Rubber. Antistatic and Conductive products. Determination of electrical resistance.

ISO 3795 Road vehicles, and tractors and machinery for agriculture and forestry - Determination of burning behaviour of interior materials

ISO 7638 Road vehicles - Electrical connectors for braking systems

ISO 8323 Freight containers - Air/surface (intermodal) general purpose containers - Specification and tests

ISO 11446 Road vehicles -- Connectors for the electrical connection of towing and towed vehicles -- 13-pole connectors for vehicles with 12 V nominal supply voltage

ISO 12098 Commercial vehicles with 24 V systems - 15-pole connectors between towing vehicles and trailers - Dimensions and contact allocation.

ISO 25981 Road vehicles -- Connectors for the electrical connection of towing and towed vehicles - Connectors for electronically monitored charging systems with 12 V or 24 V nominal supply voltage

EN1361 Rubber hoses and hose assemblies for aviation fuel handling – Specification.

EN1762 Rubber hoses and hose assemblies for liquefied petroleum gas

EN12079 Off-shore containers and associated lifting sets

EN12115 Rubber and thermoplastics, hoses and hoses and hose assemblies for liquid or gaseous chemicals – Specification.

EN12252 LPG equipment and accessories – Equipping of LPG road tankers.

1 Full titles of the Normative References will be verified in due course and expanded if necessary.



EN12434 Cryogenic vessels – cryogenic flexible hoses.

EN12493 LPG equipment and accessories – Welded steel tanks for Liquefied Petrol Gas (LPG) – Road tankers - Design and manufacture.

EN12972 Tanks for the transport of dangerous goods – Testing, inspection and marking of metallic tanks.

EN13081 Tanks for transport of dangerous goods – Service equipment for tanks – Vapour collection adaptor and coupler.

EN13082 Tanks for the transport of dangerous goods − Service equipment for tanks – Vapour transfer valve.

EN13083 Tanks for transport of dangerous goods. Service equipment for tanks. Adaptor for bottom loading and unloading

EN13094 Tanks for the transport of dangerous goods – Metallic tanks with a working pressure not

exceeding 0.5 bar – Design and construction.

EN13175 LPG equipment and accessories- Specification and testing for liquefied petroleum gas (LPG) pressure vessel valves and fittings.

EN13308 Tanks for transport of dangerous goods – Service equipment for tanks – Non-pressure balanced footvalve.

EN13314 Tanks for the transport of dangerous goods – Service equipment for tanks – Fill hole cover.

EN13315 Tanks for transport of dangerous goods. Service equipment for tanks. Gravity discharge coupler

EN13316 Tanks for transporting dangerous goods – Service equipment for tanks – Pressure balanced footvalve.

EN13317 Tanks for transporting dangerous goods – Service equipment for tanks – Manhole cover assembly.

EN13530-2 Cryogenic vessels – Large transportable vacuum insulated vessels – Part 2: Design, fabrication, inspection and testing.

EN13765 Thermoplastic multi-layer (non-vulcanized) hoses and hose assemblies for the transfer of

hydrocarbons, solvents and chemicals – Specification.

EN13766 Thermoplastic multi-layer (non-vulcanized) hoses and hose assemblies for the transfer of liquid

petroleum gas and liquefied natural gas – Specification.

EN13807 Transportable gas cylinders − Battery vehicles − Design, manufacture, identification and testing

EN13501 Fire classification of construction products and building elements

EN13922 Tanks for the transport of dangerous goods – Service equipment for tanks – Overfill prevention systems for liquid fuels.

EN14025 Tanks for the transport of dangerous goods – Metallic pressure tanks – Design and construction.

EN14116 Tanks for transport of dangerous goods – Digital interface for the product recognition device.



EN14129 LPG equipment and accessories – Pressure relief valves for LPG pressure vessels.

EN14398-2 Cryogenic vessels – Large transportable non-vacuum insulated vessels – Part 2 - Design, fabrication, inspection and testing.

EN14432 Tanks for the transport of dangerous goods – Tank equipment for the transport of liquid

chemicals – Product discharge and air inlet valves.

EN14433 Tanks for the transport of dangerous goods – Tank equipment for the transport of liquid

chemicals – Foot valves.

EN14595 Tanks for transport of dangerous goods – Service equipment for tanks – Pressure and Vacuum breathing vent

EN14596 Tanks for transport of dangerous goods – Service equipment for tanks – Emergency pressure relief valve

EN15207 Tanks for the transport of dangerous goods - Plug/socket connection and supply characteristics for service equipment in hazardous areas with 24 V nominal supply voltage

API-RP-1004 Bottom loading and vapour recovery for MC-306 and DOT-406 tank motor vehicles.

ECE Reg 133 Uniform provisions concerning the approval of vehicles of categories M, N and O with regard to braking

SABS1398 Road tank vehicles for petroleum-based flammable liquids

SABS1518 Transportation of dangerous goods – Design requirements for road tankers

US DOT 2005 or later

US DOT Code of Federal Regulations, 49 CFR, Chapter 1, sub-chapter C, Part 178, 2005 or subsequent publications

ECE R58 Rear under-run devices

SADCSTANs are to be developed for the following if suitable international standards cannot be identified and we do not develop specific harmonised standards for these items.

SANS 1475-1 The production of reconditioned fire-fighting equipment Part 1: Portable and wheeled (mobile) rechargeable fire extinguishers.

SANS 1567 Portable rechargeable fire extinguishers – CO2 type extinguishers.

SANS 1910 Portable refillable fire extinguishers.

SANS 10187-8 Load securement on vehicles –Part 8: Dangerous goods.

To be completed/extended as required.



Section 3

Definitions and abbreviations

3.1 Definitions

For the purposes of this document, the following definitions apply. These definitions are not necessarily those contained in any law or any international convention. They are strictly applicable to this document.2

Acceptable

Acceptable to the authority administering the standard

Battery vehicle

A vehicle containing elements (see note) that are linked to one another by a manifold, that are permanently fixed to a transport unit for the transport of gases of class 2, and that have a capacity of more than 450 l NOTE Cylinders, tubes, bundles of cylinders (frames), pressure drums and tanks are considered to be elements of a battery vehicle.

Breakdown

As applicable to a vehicle and related equipment-Any failure that causes an inability to proceed

Bulk container

Bulk container" means a containment system (including any liner or coating) intended for the carriage of solid substances which are in direct contact with the containment system. Packagings, intermediate bulk containers (IBCs), large packagings and tanks are not included. A bulk container is: - of a permanent character and accordingly strong enough to be suitable for repeated use; - specially designed to facilitate the carriage of goods by one or more means of transport - without intermediate reloading; - fitted with devices permitting its ready handling; - of a capacity of not less than 1.0 m3; Examples of bulk containers are containers, offshore bulk containers, skips, bulk bins, swap bodies, trough-shaped containers, roller containers, load compartments of vehicles "Closed bulk container" means a totally closed bulk container having a rigid roof, sidewalls, end walls and floor (including hopper-type bottoms). The term includes bulk containers withan opening roof, side or end wall that can be closed during carriage. Closed bulk containers may be equipped with openings to allow for the exchange of vapours and gases with air and which prevent under normal conditions of carriage the release of solid contents as well as the penetration of rain and splash water. "Sheeted bulk container" means an open top bulk container with rigid bottom (including hopper-type bottom), side and end walls and a non-rigid covering;

2 Individual definition paragraph numbers will be inserted once the list of definitions has been completed.



Calculation pressure

The theoretical pressure at least equal to the test pressure and which, according to the degree of danger exhibited by the substance being transported, exceeds to a greater or lesser degree the working pressure according to the degree of danger (as indicated by the packing group) exhibited by the substance being transported. The calculation pressure is used solely to determine the thickness of the walls of the shell independently of any external or internal reinforcing device

Certified clean

Descriptive of a vehicle, freight container or tank container that has classified dangerous goods, but is now free from contamination by such cargo and has been certified as such

Combination of motor vehicles

A combination of motor vehicles consisting of a prime mover and one or more trailers

Compartment

Liquid tight division of a tank

Competent authority

A national body or authority designated, or otherwise recognized, for the control or regulation of a particular aspect of the transport of dangerous goods

Competent person

A person with the necessary skills and knowledge to carry out a specific task

Consignee

A person receiving dangerous goods NOTE The waste manager is any person that re-uses, recycles, recovers, treats or disposes off waste.

Consignor

A person who offers dangerous goods for transport by road in a vehicle. The consignor can be the product manufacturer, the product owner, the product custodian or the party that contracts the operator to transport the dangerous goods.

Critical temperature

The temperature above which a substance cannot exist in the liquid state

Danger warning diamond

An orange diamond that complies with the requirements of this standard, and that is displayed on the front of the vehicle cabin.

Dangerous goods

Goods that are capable of posing a significant risk to health and safety, or to property, or the environment during transport and that are listed in the United Nations Model Regulations. Dangerous goods include waste classified in terms of this standard.

Dangerous goods declaration

A document that describes and quantifies the dangerous goods being transported from a consignor to a consignee



Dangerous goods placard

Single or split placard with separate, delineated zones for goods identification, telephonic advice numbers and hazard-class diamond, as specified in the relevant parts of this standard

Dangerous reaction

Reaction that has one or more of the following consequences: a) combustion or evolution of considerable heat; b) evolution of flammable, asphyxiant, oxidizing or toxic gases; c) formation of corrosive substances; d) formation of unstable substances; and e) dangerous rise in temperature in tanks.

Demountable tank

A tank that is not structurally attached to a vehicle, that has a capacity of more than 450 l, and that normally can only be handled when it is empty

Designated space

A container, orange in colour and marked with the word "DOCUMENTS", in black, which is securely fixed and cannot be dislodged unintentionally, and in a clearly visible space towards the front and in the centre in the vehicle cab so as to be easily accessible from either door or through a broken front window. NOTE The construction of the container and type of material used are not prescribed.

Discharge pressure

The maximum pressure built up in the shell of a tank when it is being discharged under pressure

Endurance braking

A braking system intended to stabilise vehicle speed on a long descent, without the use of service, secondary or parking braking systems

Exempt quantity

Quantity of dangerous goods which, if not exceeded in the total load, is exempt from the requirements of this standard

Filling density

The average mass of non-refrigerated liquefied gas per litre of shell capacity

Filling pressure

The maximum pressure built up in the shell of a tank when it is being filled under pressure

Fixed tank

A tank with a capacity of more than 1 000 l which is structurally attached to a vehicle to become a tank vehicle, or is an integral part of the frame of such vehicle

Flash point

The lowest temperature of a liquid at which its vapours form a flammable mixture with air

Freight container

A free-standing containment unit, used for the transport of dangerous goods, of a permanent character and strong enough for repeated use, designed specifically for the carriage of goods by more than one mode of transport and that complies with the requirements of ISO 1496-1



Gross vehicle mass

The maximum mass of the laden vehicle as specified by the vehicle manufacturer.

Hermetically closed tank

A tank intended for the carriage of liquid substances with a calculation pressure of at least 4 bar or intended for the carriage of solid substances (powdery or granular) regardless of its calculation pressure, the openings of which are hermetically closed and which: (a) is not equipped with safety valves, bursting discs, other similar safety devices or vacuum valves; or (b) is not equipped with safety valves, bursting discs or other similar safety devices, but is equipped with vacuum valves, in accordance with the requirements of section 10.4.7 (c) is equipped with safety valves preceded by a bursting disc according to section 10.4.7, but is not equipped with vacuum valves; or (d) is equipped with safety valves preceded by a bursting disc and vacuum valves, in accordance with the requirements according to section 10.4.7;

Holding time

The time that will elapse from the establishment of the initial filling condition until the pressure has risen owing to heat influx to the lowest set pressure of the pressure-limiting device(s)

Incident

An occurrence of any extra-ordinary condition or event during the transport or temporary storage of dangerous goods on a public road, which includes incidents such as leakage, spillage, fire or other unplanned events that could endanger the public or potentially cause serious pollution of or detriment to the environment whether immediately or delayed, and which results in a reduction in road capacity, or creates a hazard for road users, or if the authorities were involved

Involvement of authorities

Direct involvement of the authorities (either the emergency or police services) during the event involving dangerous goods and the evacuation of persons or closure of public traffic routes (roads/railways) for at least three hours owing to the danger posed by the dangerous goods

Jacket

The outer insulation cover or cladding which may be part of the insulation system

Large container

A receptacle with an internal volume of more than 3 m3

Leakproofness test

A test that uses gas and that subjects the shell and its service equipment to an effective internal pressure of not less than 25 % of the MWP

Load constraints

Exempt quantities, load compatibilities and exemptions applicable to the transport of dangerous goods governed by this standard.

Maximum permissible gross mass

The sum of the tare mass of the portable tank and the heaviest load authorized for transport

Maximum working pressure

The highest of the following three gauge pressures: a) the highest effective pressure allowed in the tank during filling (maximum filling pressure allowed);



b) the highest effective pressure allowed in the tank during discharge (maximum discharge pressure allowed); c) the effective gauge pressure to which the tank is subjected by its contents at the maximum working temperature

Maximum working temperature

Temperature of 50 °C NOTE An ambient temperature of 50 °C has been chosen as the maximum temperature to which tank cargo would be exposed under SADC regional conditions.

Mild steel

A steel with a guaranteed minimum tensile strength of 360 N/mm2 to 440 N/mm2 and a guaranteed minimum elongation at fracture that complies with the criteria in detailed in section 10 of this standard.

Mixed load

Compatible load of dangerous goods of different classes or different goods of the same class loaded on a vehicle (or both)

Multi-load

The terms “mixed load” and “multi-load” are synonymous. The term multi-load should be discontinued and only mixed load shall be used.

Operator

The person responsible for the use of a motor vehicle for the transport of dangerous goods as defined in the relevant national legislation

Packaging group

A group symbol that indicates the degree of danger/hazard of the primary property of a specific substance in accordance with internationally recognized classifications

Party that contracts the operator

The person who enters into a contract with the operator for the transport of dangerous goods

Person

The term "Person" used in this standard means a legal person or entity

Portable tank

A tank, other than an IBC, capable of being transported by more than one mode of transport and that has a capacity of more than 450 l, used for the transport of dangerous goods

Pressure drum

Welded, transportable pressure receptacle of capacity not less than 150 l and not more than 1 000 l

Prime mover

A vehicle with an engine used to draw a semi-trailer or trailer or combinations thereof

Professional Driving Permit (PrDP)

A PrDP of category D issued by the member state where the holder is resident authorises the holder to drive a dangerous goods vehicle



Protected area

Area located as follows related to a tank: a) the lower part of a tank in a zone which extends over a 60° angle on either side of the lower generating line; or b) the top part of a tank in a zone which extends over a 30° angle on either side of the top generating line; or c) the front end of the tank on a tank vehicle; or d) the rear end of a tank inside the protection area at the rear end of the vehicle.

Product custodian

The person who has control of the dangerous goods at a particular time, but does not necessarily own the goods

Product manufacturer

The person who manufactures or produces the product

Product owner

Person who has legal ownership of the product at a particular time

Qualified facility

A vehicle and equipment repair, maintenance and testing facility that complies with the relevant requirements of this standard

Qualified person

A person trained to perform a specific task, and nominated by the operator, the consignor or the consignee

Reference steel

A steel with a tensile strength of 370 N/mm2 and an elongation at fracture of 27 %

Responsible Competent Person (RCP)

A person in the operator organisation responsible to ensure compliance with all legal requirements and requirements of this standard are met. The RCP may also be the head of the operator organisation, a person with other duties in the organisation undertaking, or a person not directly employed by that organisation, provided that that person is contracted by the operator and is capable of performing the duties of RCP.

Rigid vehicle

A vehicle where the driving unit and the cargo containment unit are mounted on a single, fixed chassis

Safety valve

A spring-loaded device which is activated automatically by pressure, and whose purpose is to protect the tank against unacceptable excess internal pressure

Self-accelerating decomposition temperature

The lowest temperature at which self-accelerating decomposition occurs in a package presented for transport, handling and storage

Service equipment

Measuring instruments and filling, discharge, venting, safety, heating and insulating devices of a tank, or the measuring instruments and filling and discharge devices, including the manifold and safety devices, of a battery vehicle



Semi-trailer

Means a trailer having no front axle and so designed that at least 15 per cent of its tare is super- imposed on and borne by a vehicle drawing such trailer;

Shell

The part of the tank that contains the substance (including the openings and their closures), but does not include service equipment or external structural equipment

Single load

A dangerous goods cargo that comprises either a single substance or goods that have the same UN number

Small container

Receptacle with an internal volume of not less than 1 m3, and not more than 3 m3

Split placard

System of placarding where a rectangle that contains the UN number and a hazard class diamond are affixed in close proximity, as required for freight containers in accordance with the IMDG regulation

Stopping

Also applies to "Stop". Bringing to a standstill of a vehicle to a parked position by the driver thereof

Structural equipment

External or internal reinforcing, fastening, protective and stabilizing members of the shell

Tank

The shell, including its service equipment and structural equipment. When used alone, the term tank means a tank-container, portable tank, demountable tank or fixed tank as defined in this section, including tanks forming elements of battery-vehicles or MEGC

Tank container

An article of transport equipment meeting the definition of a container, and comprising a shell and items of equipment, including the equipment to facilitate movement of the tank-container without significant change of attitude, used for the carriage of gases, liquid, powdery or granular substances and, when used for the carriage of gases having a capacity of more than 0.45 m3 (450 l)

Tank vehicle

Vehicle built to transport liquids, gases or powdery or granular substances in bulk and that comprises one or more fixed tanks. In addition to the vehicle proper, or the units of running gear used in its stead, a tank-vehicle comprises one or more shells, their items of equipment and the fittings for attaching them to the vehicle or to the running-gear units

Technical name

The name currently used in scientific and technical handbooks

Test pressure

The required pressure applied during a pressure test for initial or periodic inspection of a tank. NOTE. For a hydraulic test, this pressure would apply at the bottom of the tank



Transport unit

A tank vehicle without an attached trailer, or a combination consisting of a tank vehicle and attached trailer(s)

Trailer

A vehicle without any mode of self-propulsion that is drawn by a prime mover

Transport emergency card

A document which is generated in accordance with section 8 of this standard. It is a card that lists the hazards and emergency information for a dangerous substance being transported, and that is intended for use by the driver during an incident, or by the emergency services, if required

Truck tractor

A prime mover that draws a semi-trailer

UN Model Regulations

The Model Regulations annexed to the eighteenth revised edition of the Recommendations on the Transport of Dangerous Goods published by the United Nations

UN no/ or UN number

Unique four digit number allocated to an item of dangerous goods

Waste generator

Any person whose action, production process or activities, including waste management activities, result in the generation of waste NOTE Waste management activities include re-use, recovery, treat or disposal of waste.

Wet hose

A hose, closed at both ends and containing the substance during transport, and which is normally attached to the tank as a permanent fixture

3.2 Abbreviations

For the purposes of this document, the following abbreviations apply.

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

C Celsius

CMS Compliance Management System

DGD Dangerous Goods Declaration

EN European Norm

ERG Emergency Response Guidebook – Issued by the US Department of Transport

GVM Gross Vehicle Mass

IBC Intermediate Bulk Container



IMDG International Maritime code for Dangerous Goods transportation by sea

kg kilogram

l litre

m metre

mm millimetre

MEGC Multiple Element Gas Container

MPGM Maximum Permissible Gross Mass

MMU Mobile Mixing Unit

MWP Maximum Working Pressure

N Newton

N.O.S. Not Otherwise Specified

Pa Pascal

PG Packing Group

PrDP-D Professional Driving Permit of category D for dangerous goods vehicles

RCP Responsible Competent Person

SADT Self-Accelerating Decomposition Temperature

SDS Safety Data Sheet (also often referred to as an MSDS; the "M" referring to "Material")

TEC Transport Emergency Card

UN United Nations

UN ECE United Nations Economic Commission for Europe

US DOT United States of America Department of Transport

WDGD Waste dangerous goods declaration



Section 4

Exemptions

The requirements of this standard shall not apply to the following:

4.1 Exemptions related to the nature of the transport operation

4.1.1 The transport of dangerous goods by private individuals where the goods in question are packaged for retail sale and are intended for their personal or domestic use or for their leisure or sporting activities. NOTE Dangerous goods in IBCs, large packagings or tanks in excess of exempted quantities are not considered to be for personal or domestic use or for their leisure or sporting activities.

4.1.2 The transport of machinery or equipment not specified in this clause and which contain dangerous goods in their internal or operational equipment, provided that measures have been taken to prevent any leakage of contents in normal conditions of transport.

4.1.3 The transport undertaken by or under the supervision of the emergency services, insofar as such transport is necessary in relation to the emergency response, in particular transport undertaken: 1) By breakdown vehicles carrying vehicles which have been involved in accidents or have broken down and contain dangerous goods; or 2) To contain and recover the dangerous goods involved in an incident or accident and move them to a safe place.

4.1.4 Emergency transport intended to save human lives or protect the environment provided that all measures are taken to ensure that such transport is carried out in complete safety.

4.1.5 The transport of goods exempt from road transport regulations by special provision in Annex A and Table A.1 of this document.

4.1.6 The goods transported by a bona fide farmer or an employee of the farmer and are intended for use in farming operations, provided that: 1) The goods are not used for resale either in their original form or in combination with any other substance 2) The journey does not exceed 250 km of which no more than 50 km shall be on a main arterial road designated with the number appropriate to the participating member state 3) The quantity of classified dangerous goods in liquid form does not exceed 1 000 l 4) The quantity of classified dangerous goods in solid form does not exceed 1 000 kg 5) The quantity of classified dangerous goods transported in a mixed load containing goods in both liquid and solid form, in kilograms and litres, does not exceed 1 000. These exemptions should not apply to class 1 and class 7 substances. For any applicable exemptions, refer to the relevant national legislation of the participant member state.



4.2 Exemptions related to the transportation of gasses

The following exemptions related to the transportation of gasses apply

4.2.1 Gases contained in the tanks of a vehicle, performing a transport operation and destined for its propulsion, or for the operation of any of its equipment (for example refrigerating equipment). The total amount will not exceed: - LPG 2 250 l - LNG or CNG 1 080 kg

4.2.2 Gases contained in the fuel tanks of vehicles transported. The fuel cock between gas tank and engine shall be closed and the electric contact open.

4.3 Exemptions related to the transportation of liquid fuels

The following exemptions related to the transportation of liquid fuels apply

4.3.1 Fuel contained in tanks of a vehicle performing a transport operation and intended for the operation of any of its equipment with the following restrictions: 1) When contained in tanks permanently connected to the vehicle’s engine or auxiliary equipment (or both), it shall not exceed the quantities specified in the table 4.3.1 below 2) When contained in portable fuel containers (such as Jerricans), a maximum of 60 l may be carried per vehicle, or combination of vehicles

Table 4.3.1

Transport unit Maximum quantity (l)

Drawing vehicle 1 500

Combination 1 500

Trailer 500

4.3.2 Fuel contained in the tanks of vehicles or of other means of conveyance (such as boats), which are carried as a load, where it is destined for their propulsion or the operation of any of their equipment. Any fuel cocks between the engine or equipment and the fuel tank shall be closed during carriage unless it is essential for the equipment to remain operational. The load shall be loaded upright and secured against falling.

4.4 Regardless of the general exemptions provided for, the person performing the transport operation will ensure at all times that the operation takes place safely, that all general precautions and safely rules are applied to ensure the safety of all stakeholders and that generally accepted industry practices related to the transportation of dangerous goods by road are applied.



Section 5

Dangerous Goods Classification

5.1 Section scope

This section of the standard covers the identification of dangerous goods that are capable of posing a significant risk to health and safety or to property and the environment. Dangerous goods are classified in nine classes and three packing groups in accordance with the United Nations' Recommendations on the Transport of Dangerous Goods Model Regulations. The nine classes relate to the type of hazard whereas the three packing groups relate to the degree of danger posed within the class.

5.2 Normative references for the section

5.2.1 UN Model Regulations (Recommendations on the Transport of Dangerous Goods), with particular reference to Volume I, Part 2

5.3 Definitions

Definitions are contained in the UN Model Regulations as referred to in 5.2.1. However, for ease of reference, the following definitions are repeated in this standard:

5.3.1 Classes

Dangerous Goods substances (including mixtures and solutions) and articles are assigned to one of nine classes according to the hazard or the most predominant of the hazards they present. Some of these classes are subdivided into divisions. These classes and divisions are:

Class 1 Explosives Division 1.1 Substances and articles which have a mass explosion hazard

Division 1.2 Substances and articles which have a projection hazard but not a mass explosion hazard

Division 1.3 Substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard

Division 1.4 Substances and articles which present no significant hazard

Division 1.5 Very insensitive substances which have a mass explosion hazard



Division 1.6 Extremely insensitive articles which do not have a mass explosion hazard

Class 2 Gasses Division 2.1 Flammable gases

Division 2.2 Non-flammable, non-toxic gases

Division 2.3 Toxic gases

Class 3 Flammable liquids

Class 4 Flammable solids Division 4.1 Flammable solids, self-reactive substances and solid desensitized explosives

Division 4.2 Substances liable to spontaneous combustion

Division 4.3 Substances which in contact with water emit flammable gases

Class 5 Oxidizing substances and organic peroxides

Division 5.1 Oxidizing substances

Division 5.2 Organic peroxides

Class 6 Toxic and infectious substances Division 6.1 Toxic substances

Division 6.2 Infectious substances

Class 7 Radioactive material

Class 8 Corrosive substances

Class 9 Miscellaneous dangerous substances and articles, including environmentally hazardous substances

5.3.2 Packing groups

For packing purposes, substances other than those of Classes 1, 2 and 7, divisions 5.2 and 6.2 and other than self-reactive substances of Division 4.1 are assigned to three packing groups in accordance with the degree of danger they present:

Packing group I: Substances presenting high danger

Packing group II: Substances presenting medium danger

Packing group III: Substances presenting low danger

5.3.3 Subsidiary risk

Dangerous goods meeting the defining criteria of more than one hazard class or division, are assigned to a class and division and subsidiary risk(s) on the basis of the precedence of hazards

5.3.4 Proper shipping names

There are four types of entries under the proper shipping name or description heading. These are: a) Single entries for well-defined substances or articles e.g. 1090 ACETONE 1194 ETHYL NITRITE SOLUTION



b) Generic entries for well-defined group of substances or articles e.g. 1133 ADHESIVES 1266 PERFUMERY PRODUCT 2757 CARBAMATE PESTICIDE, SOLID, TOXIC 3101 ORGANIC PEROXIDE, TYPE B, LIQUID c) Specific n.o.s. entries covering a group of substances or articles of a particular chemical or technical nature e.g. 1477 NITRATES, INORGANIC, N.O.S. 1987 ALCOHOLS, N.O.S.; d) General n.o.s. entries covering a group of substances or articles meeting the criteria of one or more classes or divisions e.g. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 1993 FLAMMABLE LIQUID, N.O.S. "N.O.S" refers to "Not otherwise specified"

5.4 Classification

5.4.1 The classification shall be made by the product manufacturer, consignor or the appropriate competent authority.

5.4.2 Classification of substances will take place in accordance with the UN Model Regulations (Recommendations on the Transport of Dangerous Goods), Volume I, Part 2

5.4.3 Classification of waste Wastes shall be transported under the requirements of the appropriate class considering their hazards and the criteria in the UN Model Regulations. Wastes not otherwise subject to these Regulations but covered under the Basel Convention 1 may be transported under Class 9.



Section 6

Dangerous Goods list and special provisions

6.1 Dangerous goods list

6.1.1 The dangerous goods list is shown in table A.1 in Annexure A to this standard

6.1.2 The dangerous goods list is structured as follows:

Column Entry description

1 The UN number of the substance

2 The proper shipping name of the substance

3 The class of the substance

4 The classification code of the substance

5 The subsidiary risk (s) of the substance

6 The packing group applicable

7 The exempt quantity

8 The calculation factor for mixed loads

9 Special "P" provisions related to packaged goods

10 Special "B" provisions related to goods in bulk

11 Special "L" provisions related to loading operations

12 Special "O" provisions related to transport operations is general

13 The hazard identification number

14 The vehicle type required

15 The 4-character tank code applicable

16 The special tank provisions



6.2 Special provisions

The special provisions applicable to the road transportation of the dangerous goods are as follows:

6.2.1 Special provisions for the carriage of packaged dangerous goods are referred to a "P" provisions and are shown in Annexure A.2 These provisions are shown in column 9 of the dangerous goods list

6.2.2 Special provisions for the carriage of dangerous goods in Bulk are referred to as "B" provisions and are shown in Annexure A.3 These provisions are shown in column 10 of the dangerous goods list

6.2.3 Special provisions for the loading operation during the carriage of dangerous goods to as "L" provisions and are shown in Annexure A.4 These provisions are shown in column 11 of the dangerous goods list

6.2.4 Special provisions for the transport operation during the carriage of dangerous goods are referred to as "O" provisions and are shown in Annexure A.5 These provisions are shown in column 12 of the dangerous goods list



Section 7

Transport Operations

7.1 Requirements for responsible parties

7.1.1 Consignor By definition, the consignor can be the product manufacturer, the product owner, the product custodian or the party that contracts the operator.

The consignor of dangerous goods for transport by road vehicle shall be responsible for ensuring that:

7.1.1.1 Goods are correctly classified, in accordance with this standard

7.1.1.2 Goods are packaged in accordance with this standard Imported dangerous goods that arrive by air and that are packed in accordance with the International Civil Aviation Organization (ICAO) technical instructions for the safe transport of dangerous goods by air or the International Air Transport Association (IATA) dangerous goods regulations, or that arrive by sea and are packed in accordance with the International Maritime Dangerous Goods (IMDG) code of the International Maritime Organization (IMO), are acceptable for inland transport by road or rail, provided that marking for the UN number and shipping name are displayed in English

7.1.1.3 Loading of the dangerous goods is carried out by a qualified person(s) trained in the relevant procedures

7.1.1.4 The driver is provided with a copy of the signed DGD/WDGD

7.1.1.5 The relevant placards are displayed on the vehicle and TREC's are in the designated space. NOTE: The consignor may either supply the placards and TRECs or may supply only the information in order to enable the operator, in order to enable the operator to provide the relevant placarding and TREC's.

7.1.2 Operator

7.1.2.1 The owner of a motor vehicle is the operator thereof, unless he/she has concluded an agreement with another person or company in relation to the operation of the vehicle. In the case of such an agreement the person or company identified as such in the agreement is deemed to be the operator for the duration of that agreement.

7.1.2.2 The vehicle shall display a valid dangerous goods operator card or equivalent issued by the relevant national authority.

7.1.2.3 The operator shall: a) Agree on a basic route with the driver, incorporating any specific requirements of any local authority en route b) Ensure that the driver is instructed on the route conditions, the risks associated with the route, allowed and prohibited stopping areas, speed limits and where loading and delivery will take place. c) Ensure that the driver is fully aware of the required emergency response procedures and the relevant contact details of authorities.



7.1.2.4 The operator shall inform the local authority of the areas through which the vehicle will pass, and shall provide them with full information regarding the product to be transported (when requested by the local authority), the nature of its hazard, and the intended route. When the nature of business requires the transport of similar cargo on a regular basis, it will be sufficient to submit this information at the start of operations only. The operator shall, however, inform the appropriate local authority of the discontinuation of such operations and of any change in the operations that might influence the hazard. The local authority, if concerned about a particular product passing through a specific area may require the operator to use alternative routes to reach his destination.

7.1.2.5 The operator shall ensure that the driver of the vehicle: a) Is in possession of a valid driver's licence or PrDP-D (as relevant to the vehicle type), and b) Has been trained in accordance the requirements of this standard.

7.1.2.6. The operator shall, on being informed of an incident involving one of his vehicles covered by this standard, ensure that the relevant emergency services and the police have been informed. The operator shall prepare an incident report in accordance with the requirements of this standard as contained in Annexure F and submit it to the relevant national authority within 30 days. For the purposes of this requirement, relevant national authority means: a) Where the incident occurs in the member state where the operator is resident, the report shall be submitted to the relevant national authority in the member state in which the incident occurred. b) Where the incident occurs in a participant member state in which the operator is not resident, the report shall be submitted to the relevant national authorities of the member state in which the operator is resident and the member state in which the incident occurred. The operator shall also retain the incident report for a minimum of five years.

7.1.2.7 The relevant emergency services shall be notified by the operator before any transfer of cargo takes place between the scheduled loading and off-loading points. A competent person shall supervise the transfer of cargo. NOTE Where a vehicle transporting dangerous goods has been stopped and found to be overloaded, it may in some cases be safer to allow the vehicle to proceed under the escort of the emergency services to anothersite, where transfer of the load can be carried out without undue risk. Such action shall be performed in compliance with the vehicle load management legislation applicable in the member state where the vehicle was found to be overloaded.

7.1.2.8 If a vehicle is involved in an incident in which there is the risk of damage to its cargo containment, the operator shall, prior to placing the vehicle back into service for the transport of dangerous goods by road: a) Submit the vehicle for inspection of the tank and equipment by a qualified facility to determine accordance with the requirements of the relevant standard(s) valid at the time of manufacture of the vehicle b) Submit the vehicle to a roadworthiness testing facility for a roadworthiness test in accordance with the requirements and relevant test standards of the member state where the vehicle is registered.

7.1.2.9 The operator shall ensure that safety equipment required by the driver in accordance with the TREC, is provided, and that the driver is trained in the operation of such equipment.

7.1.2.10 The operator shall be responsible for ensuring that the vehicle and equipment fitted to the vehicle comply with all applicable statutory requirements with regard to: a) The applicable vehicle design standard b) The vehicle roadworthiness and its suitability to the consignment to be carried c) The serviceability of the consignment handling equipment and consignment containment areas

7.1.2.11 The operator will retain documentary proof of compliance, issued in accordance with the applicable standard of construction and this standard, for the vehicle.

7.1.2.12 The operator shall be responsible for ensuring that the vehicle and equipment are maintained and inspected by a competent person, in accordance with this standard.



7.1.2.13 Before deployment of a previously-owned vehicle, the operator shall ensure that an exceptional inspection and test is carried out in accordance with the requirements of this standard and that all defects and issues of non-compliance have been rectified. The operator shall not allow a non-compliant vehicle to be deployed into service.

7.1.2.14 The operator shall, upon disposing of a vehicle for further use as a dangerous goods vehicle, make available and hand all the construction and maintenance, inspection and testing records, as required to be kept by this standard, over to the next operator.

7.1.2.15 The operator shall be responsible for ensuring that measures are put in place to prevent vehicle overloading and underloading.

7.1.2.16 The operator shall employ a CMS in compliance with the requirements of the relevant section of this standard (7.4.2).

7.1.2.17 The operator shall ensure that the driver is fully trained and proved competent in all relevant requirements of this standard prior to deployment.

7.1.2.18 The operator shall ensure all relevant requirements of this standard are adhered to.

7.1.3 Driver

7.1.3.1 Skills and training The driver of a dangerous goods vehicle shall:

a) Have a PrDP of category D when driving a vehicle transporting dangerous goods and shall carry it on his person b) Be fit to drive in terms of the relevant national legislation c) Be able to interpret and implement the instructions on the transport emergency card d) Receive annual comprehensive theoretical and practical training relevant to the type of vehicle and to the dangerous goods which will be assigned to him, including training in the procedures specific to the cargo, for example flammable liquid or toxic corrosive liquid e) Carry a valid training certificate or a certified copy of the training certificate f) Receive training to perform pre-journey vehicle inspections to determine roadworthiness an suitability to load in accordance with the requirements of this standard g) Be at least 25 years of age

7.1.3.2 Vehicle and equipment checks The driver of a dangerous goods vehicle shall, before proceeding on a journey:

a) Carry out the inspection and test as contained in section 7.3 of this standard, report all defects and abnormalities found and ensure that the vehicle is fit for the journey b) Ensure that the dangerous goods operator card is displayed c) Check that vehicle is free of any product likely to contaminate the load or create a safety hazard

7.1.3.3 Pre-loading checks The driver of a dangerous goods vehicle shall, before loading is commenced, ensure that:

a) The loading site is correct as instructed by the operator, appears suitable for the operation and can be safely entered b) The vehicle is positioned as directed for loading c) Permission has been given for loading to commence

7.1.3.4 Post loading checks The driver of a dangerous goods vehicle shall, after loading has been completed, ensure that:

a) The vehicle has been correctly loaded with the correct products as per the operator instructions b) The correct TEC(s) and DGD(s)/WDGDs are stored in the designated space



c) Only emergency information documents for the current load as required by this standard and licences and permits as required by the relevant national legislation, are stored in the designated space, and all extraneous documentation is removed d) The necessary safety equipment in accordance with the TREC(s)transport emergency card(s) is on board e) He understands the information and instructions on the TREC(s) f) The orange warning signage and relevant placards are in place g) The vehicle is not overloaded or the steering and driving axles of the vehicle are not underloaded to present a safety risk, and the load is properly secured h) There are no defects that arose during the loading process that could cause un-safe conditions during the journey.

7.1.3.5 En route The driver shall follow the en route procedures in section 7.2 of this standard.

7.1.3.6 Other activities prohibited The driver shall at no stage of the transport operation participate in any activity not directly related to the transport operation.

7.1.4 Qualified Person

7.1.4.1 General a) The loading and offloading operations shall be carried out by a qualified person trained in the relevant procedures b) Qualified persons shall be appointed in writing by the relevant responsible parties c) The qualified person can be more than one person responsible for different tasks or stages during the operation. It is not intended to be a single person. Note: For example, one qualified person can perform an entry inspection for a vehicle, another can load the vehicle and another can do a post-load inspection.

7.1.4.2 Requirements that relate to loading and offloading operations The qualified person shall ensure that the following safety precautions are adhered to:

a) The vehicle is correctly parked for loading or offloading, and wheel chocks are in place for heavy vehicles with a gross vehicle mass (GVM) equal to or greater than 3 500 kg. b) Where fire extinguishers are not provided by the loading/offloading point, vehicle fire extinguishers are placed at an easily accessible position off the vehicle carrying class 1 to class 4 dangerous goods. c) The engine of the vehicle is switched off, except where the engine is required to drive pumps or hydraulic units for the purposes of loading or offloading. d) The battery isolator is turned to the "Off" position for vehicles carrying class 1 to Class 4 dangerous goods. c) The area is safe, with barricades, where applicable, and the necessary warning signs are clearly displayed. d The requisite safety and first aid equipment in accordance with the TREC(s) is provided. e) The loading or offloading operation is conducted in a safe manner and is not placed at risk by other activities in the vicinity. f) The load is secured after loading.

7.1.4.3 Requirements that relate to loading operations The qualified person shall ensure that the following safety precautions are adhered to in addition to those contained in 7.1.4.2:

a) The goods to be loaded are correctly classified, packaged and labelled b) The vehicle is suitable for its current purpose and is clean and fit to load



c) The vehicle is safe to enter the site to load NOTE: This is usually done by means of an "entry inspection", used to determine the general roadworthiness condition such as condition of tyres, lights, structural failures, etc. d) The vehicle complies with the requirements for the relevant vehicle design and construction standard NOTE: This can be done by any suitable means such as for example the use of Safe Loading Passes, compliance declarations made by the operator, etc. e) If goods different from those previously transported by the vehicle are to be loaded and in the absence of a certificate of cleaning, or a gas-free certificate, the containment area is inspected by a competent person to ensure that it is fit to receive the goods without risk f) The exempt quantity and compatibility requirements as contained in this standard are adhered to g) The correct products and quantities are loaded h) The cargo is undamaged and secured after loading i) The vehicle is not allowed to proceed on its journey without placards that reflect the correct information relevant to the goods j) The driver has the correct TREC(s) in his possession k) The necessary DGD(s)/WDGDs are issued for the load and supplied to the driver l) The special P, B, L and O provisions are adhered to m) The vehicle is in a generally safe condition to proceed on the journey NOTE: This is usually done by means of a post loading and "exit inspections", used to determine whether there are any tank leaks, leaks from equipment and general roadworthiness condition such as condition of tyres, lights, structural failures, etc.

7.4.1.4 Requirements that relate to offloading operations The qualified person shall ensure that

a) The cargo is correct and undamaged and there is no obvious spillage b) The offloading operation does not proceed, if, for any reason, he/she considers it unsafe c) In the case of bulk deliveries: 1) There is sufficient space in the tanks or bins into which the cargo is to be unloaded and that they are in a fit condition to receive the load 2) The flow can be stopped immediately in case of leakage or any other emergency 3) After offloading, the vehicle is free from spillage and all valves are closed d) After offloading, the documents reflect the change in load e After offloading no residue remains on the vehicle and that the vehicle is free of contamination f) After offloading the vehicle cannot be certified clean, the placards and relevant documents remain until cleaning of the vehicle is possible g) At the offloading site the dangerous goods that correspond with the DGD/WDGD, can be offloaded in safe conditions, which all the necessary safety equipment is provided and that he/she consults with the operator and the consignor on appropriate action with regard to containers with leaks

7.1.5 Consignee

7.1.5.1 The consignee shall be responsible for the offloading of the dangerous goods.

7.1.5.2 The consignee shall provide the qualified person to carry out the offloading procedures (unless otherwise agreed upon amongst the responsible parties).



7.1.6 Party contracting the operator

The party contracting the operator shall ensure that:

7.1.6.1 The operator is registered as a dangerous goods operator as required by the relevant legislation.

7.1.6.2 The operator complies with the requirements of this standard.

7.1.6.3 The operator has a CMS in place as required by this standard.

7.1.6.4 Compliance of the operator with this standard will be assessed: a) Prior to contracting the operator b) Periodically during the contract (if the contract is of a duration of greater than 6 months) and has been declared compliant.

7.2 Operational requirements

7.2.1 Dangerous goods declaration (DGD)

7.2.1.1 The DGD/WDGD shall comply with the requirements of the relevant section of this standard (section 8)

7.2.1.2 Copies shall be provided to the operator (the driver) and the consignee by the consignor. The waste generator shall ensure that a separate WDGD is generated to reflect a delivery to a specific consignee.

7.2.1.3 The DGD/WDGD shall be stored in the designated space.

7.2.1.4 The DGD shall be retained by the consignor for a minimum of 90 days after the date of shipment, if no incident is reported. If an incident is reported, the DGD shall be retained for the duration of the relevant investigation. The operator and consignee shall retain copies of the DGD for as long as deemed necessary by the relevant party. If waste is transported, the WDGD shall be retained by the consignor/waste generator, consignee/waste manager, and the operator/waste transporter for a minimum of five years after the date of shipment.

7.2.2 Insurance

7.2.2.1 The operator shall ensure that insurance, based on the hazard and risk of the goods or substances transported, fully covers public liability, recovery of goods and vehicle, and rehabilitation of the environment costs.

7.2.3 En-route procedures

7.2.3.1 The driver shall not allow any passengers or unauthorized persons to be in or on the vehicle at any stage during the journey.

7.2.3.2 The driver shall adhere to the agreed route and authorized stopping places, unless directed otherwise by a member of the emergency services.



7.2.3.3 Where pre-planned stops, for example those required every two hours for tyre and spillage checks, are not in designated places, the vehicle shall stop only in areas sufficiently far away from the main traffic flow so as not to present a risk to other road users.

7.2.3.4 A vehicle that carries dangerous goods shall be under constant supervision while stopped or parked if one or both of the following applies: a) The dangerous goods carried have an exempt quantity of 10 kg or 10 l, or less; or b) Any one or more of special provisions O14 to O20 (inclusive) apply. Constant supervision is the supervision of a vehicle transporting dangerous goods either by the vehicle driver or a qualified person in the employ of the operator, or the parking of the vehicle in a secure area authorized by the operator.

7.2.3.5 The opening of packages, unloading or decanting for any reason, for example for axle overloads, shall not be permitted, except in an authorized and properly equipped area under the supervision of a qualified person, and after the operator has been informed.

7.2.3.6 In the event of a mechanical breakdown, regulatory warning triangles shall be placed on the road and the operator shall be informed immediately.

7.2.3.7 In the event of an incident, the instructions on the TEC(s) shall be followed and all necessary assistance shall be given to the emergency services. The TEC(s) and the DGD(s)/WDGDs shall be handed over to the emergency services when so requested.

7.2.3.8 Good and defensive driving practice with anticipation of potential problem situations shall be exercised at all times.

7.2.4 Compliance management system (CMS)

7.2.4.1 The operator will employ a compliance management system that will that all relevant requirements related to this standard and other applicable laws and standards are complied with.

7.2.4.2 The system will include at least the following:

7.2.4.2.1 An organisational structure that will facilitate compliance.

7.2.4.2.2 Formal procedures, processes and controls to cover at least the following: a) Route and journey planning and management (risks, stopping, speed, etc) b) Prevention of over/under-loading c) Vehicle and equipment specification d) Vehicle and equipment maintenance, inspection and testing e) Defect reporting and repair f) Driver management and control (briefing, en-route behaviour, de-briefing) g) Control of 3rd party resources such as maintenance facilities h) Emergency response and incident management i) Documentation and record-keeping j) Continual monitoring and implementation of new/updates of standards, laws and industry best practice

7.2.4.2.3 Effective and on-going training off all parties and in specific drivers.

7.2.4.3 The operator will appoint an RCP in compliance with the relevant legislation. The responsibilities of the RCP, in addition to those specified by the relevant legislation will be: a) Ensure compliance by the operator with all legal requirements b) Ensure compliance by the operator with all requirements of this standard c) Ensure that all personnel are trained in accordance with the requirements of this standard



7.2.4.4 The RCP will be: a) Trained and declared competent in the contents and application of this standard b) Trained and declared competent in the contents and application of all relevant legislation c) Have at least 10 years of experience in all aspects regarding the operation, specification and maintenance of dangerous goods vehicles

7.2.4.5 The party contracting the operator will ensure that: a) The operator has a CMS in place as required by this standard b) The operator is assessed for compliance and has been declared competent

7.2.5 Equipment to be carried on the vehicle

7.2.5.1 Vehicles shall be fitted with the following portable, dry powder type fire extinguishers suitable for inflammability classes A, B and C:

a) Truck tractors 1 × 9 kg minimum externally mounted fire extinguisher.

b) Freight carriers (with fixed or demountable tanks or packaged goods bodies)

2 × 9 kg minimum externally mounted fire extinguishers

c) Trailers (with fixed or demountable tanks or packaged goods bodies)

2 × 9 kg minimum externally mounted fire extinguishers

d) Light motor vehicles (GVM less than 3 500kg)

2 × 4.5 kg or 1 × 9 kg fire extinguishers

7.2.5.2 All fire extinguishers shall be mounted in easily accessible, quick-release holders, in an area where they are protected against negative environmental and operational influences such as corrosive products.

7.2.5.3 All fire extinguishers shall be provided with: a) A seal on the operating mechanism verifying that the extinguisher has not been used b) A gauge or indicator that clearly indicates whether the extinguisher is ready for use at the required operating charge pressure c) A label showing last test date, period of validity and next test date. The label shall be applied in a position where it shall remain legible for the entire validity period d) A mark indicating compliance with the relevant standard 3

7.2.5.4 The fire extinguishers shall be maintained, tested and labelled periodically, in accordance the relevant standard.3

7.2.5.5 Warning triangles A minimum of two reflective red warning triangles will be carried. Care must be taken to ensure that a vehicle travelling on a public road, will at all times have two triangles available. A sufficient number of triangles shall thus be carried to ensure to cater for parts combinations of vehicles being un-coupled/off-hooked, for whatever purpose.

3 In the absence of appropriate regional standards for fire extinguishers, SADCSTAN to be developed - see comment in section for normative references



7.2.5.6 Personal protective equipment The driver will have available at all times, at least the following personal protection equipment whilst on a journey: a) A protective overall (Flame retardant for Classes 1 to 4, inclusive) b) Safety-footwear with non-skid soles c) Protective work gloves suitable for the dangerous goods being carried d) Safety goggles or a facial splash shield suitable for the dangerous goods being carried Other protective equipment required by the TEC(s)

7.2.5.7 Wheel chocks (Not applicable to vehicles with a GVM of 3500kg or less) Each vehicle in a combination shall be provided with two wheel chocks of sufficient strength and made from non-sparking material. Wheel chocks are not required to be fitted to a truck tractor.

7.2.5.8 Spill kits 4

7.2.5.9 First aid kits 4

7.2.5.10 Other loose equipment Any other loose equipment required by the TREC(s) or operation, such as reverse cones demarcation tape, and portable safety signage, will be carried and available on the vehicle.

7.2.6 Training of personnel

7.2.6.1 All personnel involved in the activities that are covered by this standard, will be trained in the following as relevant to their positions and tasks: a) The contents of this standard b) The contents or related laws and standards c) Application of the standard

7.2.6.2 Drivers of dangerous goods vehicles will receive specific training in at least the following aspects (but not limited to): a) Defensive driving b) Responsibilities of the driver in terms of this standard c) Operation and use of specific equipment related to the vehicle makes, types and cargo d) Specific cargo-related procedures e) Interpretation and implementation of the instructions on TREC f) General duties of the driver before proceeding on a route concerning, specifically, but not limited to, the condition of the vehicle, the documents to be kept in the vehicle, instructions regarding the route to be taken and the warning signs and warning devices to be displayed or stored in the vehicle g) Use of protective clothing and equipment h) Emergency response and incident procedures i) The correct type and number of fire extinguishers to be fitted to the vehicle and the correct use thereof j) General behaviour expected of the driver on the route, amongst other things, planning of stops for deliveries or checking of the tyres and vehicle, procedure to be followed in the event of stops and, driving and work time limits k) General procedure to be followed by the driver on reaching his or her destination l) General and cargo-specific procedures to be followed when loading or offloading dangerous goods m) Vehicle and equipment inspection and defect reporting n) General workplace safety

4 Is a regional requirement needed? If so, in the absence of appropriate regional standards, SADCSTAN to be developed.



o) Knowledge, characteristics and handling of the dangerous goods in the cargo p) Correct loading and unloading of vehicles to prevent over- and under-loading and ensure vehicle stability

7.2.6.3 Vehicle and equipment maintenance, inspection and testing personnel will receive specific training in at least the following: a) Requirements of this standard in terms of maintenance, inspection and testing b) Functions and operation of the tank and related equipment c) Vehicle and equipment inspection and testing related to the specific equipment in the operation d) Inspection and testing of critical equipment including, but not limited to, valves, overfill prevention, manhole covers, pressure relief systems, vehicle brakes, trailer couplings and wheels and tyres

7.2.6.4 Personnel involved in the loading and off-loading will receive specific training in at least the following: a) General loading and off-loading procedures b) Loading and off-loading procedures related to the specific dangerous goods, facilities, vehicles and equipment used in the operation c) Related general safety and emergency response procedures

7.2.6.4 All trainees will undergo proof of competence testing during the training and training certificates will be issued.

7.2.6.5 Training records will be kept of all training done in terms of this standard.

7.2.7.6 Re-training will be done at as follows: a) When refresher training is due b) When necessitated by changes in equipment or procedures c) When the standard or related laws or standards are revised

7.2.6.7 Refresher training will be conducted as follows: a) Dangerous goods vehicle drivers Annually b) All other personnel Whenever a revision to the standard occurs with a maximum period of 24 months between training

7.3 Use of vehicles and equipment

7.3.1 Provisions applicable to all classes

7.3.1.1 Vehicle registration The vehicle shall be recorded for the transport of dangerous goods in compliance with the relevant national legislation.

7.3.1.2 The design and construction of a vehicle used for the transport of dangerous goods shall comply with the design requirements covered by the relevant standard(s) valid at the time of manufacture of the vehicle. If no legal requirements existed at the time of construction, vehicles will comply with all applicable future requirements as required by this standard.

7.3.1.3 Vehicles, equipment and tanks will be suitable for the dangerous goods being carried in all regards, in terms of: a) The product class (such as flammable liquid, corrosive product, flammable gas, etc) b) The product phase being liquid, solid or gas c) The product transport type being bulk or packaged d) The product characteristics such as being a strong solvent, a very corrosive liquid, a very toxic gas, etc



7.3.1.4 Portable tanks designed and constructed, and certified as such, to relevant IMDG or IMO standards may be used for road transportation throughout the Region.

7.3.1.5 A substance may be transported in tank vehicles and battery vehicles only when provision is made for a tank code as shown in column 14 of the dangerous goods list (Section 6 of this standard)

7.3.1.6 In the event that the listed tank code requirements cannot be met for operational, design or practical reasons, the competent authority may allow construction of the tank to a different tank code providing the same level of safety. Such deviation will be indicated on the certificate of compliance issued for the construction. This also applies when no tank code is shown in column 14 of the dangerous goods list.

7.3.1.7 Tanks built to a standard that did not take the tank code into account or was not built to standard, may be upgraded to include the tank code in accordance with the requirements and allowances as contained in this standard. The competent authority will allocate the tank code taking into account all safety requirements and will: a) Issue a certificate stating the following - The tank serial number - The manufacturer of the tank - The construction standard of the tank - A statement that the tank code has been issued in accordance with SADCSTAN XXX 7.3.1.7 - The date of allocation of the tank code - The name and signature of the competent authority b) Enforce a supplementary plate to be affixed adjacent to the manufacturer's plate and containing the following information: - The tank serial number - The allocated tank code - A statement that the tank code has been issued in accordance with SADCSTAN XXX.7.3.1.7 - The date of allocation of the tank code - The name and mark of the competent authority.

7.3.1.8 Continued use of non-compliant vehicles and tanks

7.3.1.8.1 Targets for re-certification Tanks that do not comply with the standards listed below shall be re-certified as detailed in section 10 of this standard within 5 years of publication of the standard: SADCSTAN [insert number] ADR 2005 or later US DOT 2005 or later SANS1518:2004 or later

7.3.1.8.2 Certification will take place in accordance with section 10.1 of this standard.

7.3.1.8.3 Minimum re-certification standard for the tank The tank and equipment will be certified for minimum compliance to the relevant requirements contained in Annexure I of this standard.

7.3.1.8.4 Minimum certification standard for the vehicle The vehicle (excluding the tank and related equipment) will be certified for minimum compliance to the relevant requirements contained in Annexure I of this standard.



7.3.1.8.5 Recertification validity and intervals Re-certification of a non-compliant tank will be valid for a period of three years only, after which it can be re-certified for further periods of 36 months at a time.

7.3.1.8.6 Re-certification will be witnessed and approved by a competent authority within the member state where the vehicle is registered.

7.3.1.8.7 Procedure for registration of a tank vehicle that do not comply with 7.3.1.8.1 of this standard Fixed tank vehicles and vehicles carrying portable tanks will require submission of the re-certification certificate upon expiry of the vehicle license when applying for license renewal after expiry of the 5-year period referred to in 7.3.1.8.1.

7.3.1.9 Certain substances, tanks or battery vehicles are subject to additional provisions, which are included as special tank provisions in column 16 of the dangerous goods list in annexure A to this standard.

7.3.1.10 The required tank type in terms of 7.3.1.5 corresponds to the least stringent construction requirements which are acceptable for the transport of dangerous goods. Dangerous goods may be transported in tanks with higher level tank codes in accordance with the hierarchy of tank codes described below. Special provisions applicable to a substance may prevent the application of the hierarchy of codes.

a) Liquids Unless otherwise specified by the relevant tank design standard or allowed for by the competent authority, tank codes of a higher level may be used than the code specified for the product as follows: G, 1,5, 2,65, 4, 10, 15, 21 May use any of the next higher numbers A, B, C, D May use any of the next following characters V, F, N, H May use any of the next following characters For example: LGBF May use L1,5BN, L1,5BH or higher pressure rating tanks with the last character of N or H L4BN May use L10BH and higher pressure rating tanks with last character of N or H

b) Solids Unless otherwise specified by the relevant tank design standard or allowed for by the competent authority, tank codes of a higher level may be used than the code specified for the product as follows: G, 1,5, 2,65, 4, 10, 15, 21 May use any of the next higher numbers A, B, C, D May use any of the next following characters V, F, N, H May use any of the next following characters For example: LGBF May use S1,5BN,SL1,5BH or higher pressure rating tanks with the last character of N or H S4BN May use S10BH and higher pressure rating tanks with last character of N or H



c) Gasses Unless otherwise specified by the relevant tank design standard or allowed for by the competent authority, the following hierarchy of tank codes may be applied:

Required code Allowed hierarchy

C*BN C*BH C*CN C*CH C*DN C*DH P*BN P*BH P*CN P*CH P*DN P*DH R*BN R*CN R*DN

C#BN, C#CN, C#DN, C#BH, C#CH, C#DH C#BH, C#CH, C#DH C#CN, C#DN, C#CH, C#DH C#CH, C#DH C#DN, C#DH C#DH P#BN, P#CN, P#DN, P#BH, P#CH, P#DH P#BH, P#CH, P#DH P#CN, P#DN, P#CH, P#DH P#CH, P#DH P#DN, P#DH P#DH R#BN, R#CN, R#DN R#CN, R#DN R#DN

The figure indicated by "#" shall be equal to or greater than the figure indicated by "*"

7.3.1.11 Tanks and battery vehicles shall not be loaded with any dangerous substances other than those for the transport of which they have been approved in terms of this standard and which, when in contact with the materials of the shell, gaskets, equipment and protective linings, are not likely to react dangerously with them to form dangerous products or to weaken these materials appreciably.

7.3.2 Provisions applicable to Classes 3 to 9

7.3.2.1 Coding of tanks

The four parts of the tank codes given in column 15 of the dangerous goods list in Annex A to this standard shall have the meanings given in of table 7.3.2.1 below.

Table 7.3.2.1 Coding of tanks for classes 3 to 9

Part Description Code Meaning

1 Type of tank L Tank for substances in the liquid state (liquids, or solids handed over for transport in the molten state)

S Tank for substances in the solid state (powdery or granular)

2 Calculation pressure G Minimum calculation pressure as specified or where "X" is minimum calculation pressure in bar: 1,5; 2,65; 4; 10; 15; or 21

3 Openings and closures A Tank with bottom filling and discharge openings with two closures



B Tank with bottom filling or discharge openings with three closures

C Tank with top filling or discharge openings with only cleaning openings below the surface of the liquid

D Tank with top filling and discharge openings with no openings below the surface of the liquid

4 Safety valves/devices A Tank with venting system in accordance with 10.4.7 but no flame trap; or non-explosion-pressure-proof tank

F Tank with venting system fitted with a flame trap in accordance with10.4.7; or explosion-pressure-proof tank

N Tank with safety valve in accordance with10.4.7 and not hermetically closed; these tanks may be fitted with pressure-relief valves

H Hermetically closed tank or battery vehicle.

Substances where "+" appears next to the tank code are subject to special provisions, and alternative tanks for other substances or groups of substances shall not be used unless such use is approved by the competent authority and it is indicated accordingly on the certificate of compliance for the tank.

7.3.2.2 Filling of tanks, tank vehicles and battery vehicles

The following degrees of filling shall not be exceeded in shells.

7.3.2.2.1 Liquids transported at ambient temperatures

a) For flammable, toxic or corrosive liquids without subsidiary risks in shells with a venting system or safety valves (even where preceded by a bursting disc):

b) For slightly toxic or slightly corrosive liquids in hermetically closed shells without a safety device:



See a) above for α, df and tF

c) For highly toxic, toxic, highly corrosive or corrosive liquids in hermetically closed shells without a safety device

See a) above for α, df and tF

7.3.2.2.2 The provisions of 7.3.12 shall not apply to tanks whose shells are, by means of a heating device, maintained above 50 °C during transport. In such a case the filling shall be such, and the temperature shall be so regulated, that the shell is not filled to more than 95 % of its capacity at any time during transport, and that the filling temperature is not exceeded.

7.3.2.2.3 Where shells intended for the transport of liquids are not divided by partitions or surge plates into sections of capacity 7 500 l or less, they shall be filled either to at least 80 % or to less than 20 % of capacity. Under this provision, liquids are deemed to be substances whose kinematic viscosity at 20 °C is below.

7.3.2.3 Special provisions

7.3.2.3.1 The substances where "+" appears next to the tank code are subject to special provisions, and alternative tanks for other substances or groups of substances shall not be used.

7.3.2.4 General provisions

7.3.2.4.1 Where hot substances are loaded, the temperature of the outer surface of the tank or of the thermal insulation shall not exceed 70 °C during transport.

7.3.2.4.2 The connecting pipes between independent but interconnected tanks of a transport unit shall be empty during transport. Flexible filling and discharge pipes which are not permanently connected to the shells shall be empty during transport. A wet hose is excluded from this requirement.

7.3.3 Provisions applicable to Class 2

7.3.3.1 Coding of tanks

The four parts of the tank codes given in column 15 of the dangerous goods list in Annex A to this standard shall have the meanings given in of table 7.3.3.1 below



Table 7.3.3.1 Coding of tanks for class 2

Part Description Code Meaning

1 Type of tank/battery vehicle/MECG

C Tank or battery vehicle for compressed gases

P Tank or battery vehicle for liquefied gases or gases dissolved under pressure

R Tank for refrigerated liquefied gases

2 Calculation pressure "X" Value of the minimum test pressure as specified in this standard. Test pressures to be included in future in annexure G

22 Minimum calculation pressure, in bars

3 Openings and closures B Tank with bottom filling or discharge openings with three closures, or battery vehicle with openings below the surface, or any tank vehicle for the transport of compressed gases

C Tank with top filling or discharge openings with three closures with only cleaning openings below the surface of the liquid

D Tank or battery vehicle for compressed gases tank with top filling or discharge openings with three closures, or battery vehicle with no openings below the surface of the liquid

4 Safety valves/devices N Tank or battery vehicle with safety valves in accordance with 10.4.7.6 and which are not hermetically closed

H Hermetically closed tank or battery vehicle

7.3.3.2 Filling conditions and test pressures of class 2 tanks and battery vehicles

7.3.3.2.1 The test pressure for tanks intended for the transport of compressed gases with a critical temperature below −50 °C shall be at least 1,5 times the filling pressure at 15 °C.

7.3.3.2.2 The test pressure for tanks intended for the transport of a) Compressed gases with a critical temperature of −50 °C or above, or b) Liquefied gases with a critical temperature below 70 °C, or c) Gases dissolved under pressure shall be such that, when the shell is filled to the maximum mass of the contents calculated per litre of capacity, the pressure reached in the shell by the substance at 55 °C (for tanks with thermal insulation) or 65 °C (for shells without thermal insulation) does not exceed the test pressure.

7.3.3.2.3 The test pressure for tanks intended for the transport of liquefied gases with a critical temperature of 70 °C or above shall be as follows: a) If the tank is equipped with thermal insulation, the test pressure shall be at least equal to the vapour pressure, less 100 kPa, of the liquid at 60 °C, but not less than 1 MPa. b) If the tank is not equipped with thermal insulation, the test pressure shall be at least equal to the vapour pressure, less 100 kPa, of the liquid at 65 °C, but not less than 1 MPa.



The maximum permissible mass of contents per litre of capacity, MPM, is calculated as follows:

MPM = 0,95 × dol

where

dol is the density of the liquid phase at 50 °C, in kilograms per litre

provided that the vapour phase does not disappear below 60 °C.

The test pressure for tanks intended for the transport of refrigerated liquefied gases shall be at least 1,3 times the maximum working pressure indicated on the tank, but not less than 300 kPa gauge pressure. For tanks with vacuum insulation, the test pressure shall be at least 1,3 times the maximum working pressure plus 100 kPa.

7.3.4 Vehicle type With reference to the Dangerous goods list, annexure A to this document, column 14.

7.3.4.1 The vehicle will comply with the requirements detailed in this standard applicable to Vehicle Type code associated with dangerous goods substance as contained in column 14 of annexure A.

7.3.4.2 The vehicle type codes are:

Type code Description and application

FL FL vehicle" means: A vehicle intended for the carriage of liquids having a flash-point of not more than 60°C (with the exception of diesel fuel complying with standard EN 590:2009 + A1:2010, gas oil, and heating oil (light) - UN No. 1202 - with a flash-point as specified in standard EN 590:2009 + A1:2010, both of which require a type FL vehicle type) in fixed tanks or demountable tanks with a capacity exceeding 1 m3 or in tank-containers or portable tanks with an individual capacity exceeding 3 m3; or A vehicle intended for the carriage of flammable gases in fixed tanks or demountable tanks with a capacity exceeding 1 m3 or in tank-containers, portable tanks or MEGCs with an individual capacity exceeding 3 m3; or A battery-vehicle with a total capacity exceeding 1 m3 intended for the carriage of flammable gases.

AT A vehicle, other than EX, FL or OX vehicle or than an MEMU, intended for the carriage of dangerous goods in fixed tanks or demountable tanks with a capacity exceeding 1 m3 or intank-containers, portable tanks or MEGCs with an individual capacity exceeding 3 m3; or A battery-vehicle with a total capacity exceeding 1 m3 other than an FL vehicle.

OX A vehicle intended for the carriage of hydrogen peroxide, stabilized or hydrogen peroxide, aqueous solution stabilized with more than 60% hydrogen peroxide (Class 5.1, UN No 2015) in fixed tanks or demountable tanks with a capacity exceeding 1 m3 or in tank-containers or portable tanks with an individual capacity exceeding 3 m3.

EX A vehicle intended for the carriage of explosive substances and articles (Class 1).



7.3.5 Continued use of tanks and age limits

7.3.5.1 Tanks may be continued in use a) Subject to the inspection and test requirements contained in this standard b) Age restriction and re-certification requirements contained in this standard

7.3.5.2 The requirements and allowances detailed and referred to in 7.3.5.1 only apply to tanks that are compliant with the requirements of this standard, either: a) Being fully compliant with this standard or b) Being certified as compliant with the other requirements allowed by this standard

7.3.5.3 Regardless of compliance as per 7.3.5.2, all tanks will be required a major periodic inspection every three years after the last major periodic inspection done from the 15th year of age onwards,

7.4 Vehicle and equipment maintenance and inspections

For the purpose of this section, the term "tank" includes fixed tanks, demountable tanks and battery vehicles tank containers, swap bodies, portable tanks, multiple-element gas containers (MEGCs) and vacuum operated tanks.

7.4.1 General

7.4.1.1 All goods vehicles used for the transport of dangerous goods shall undergo regular inspection in accordance with annex B to this standard

7.4.1.2 Defects and items non-compliance found shall be rectified in order to ensure their sound mechanical condition and ability to operate safely.

7.4.1.3 Regular preventive maintenance shall be built into the working schedule of the operator and carried by suitably qualified staff, under the control of a competent person. Maintenance, Inspection, testing and repairs may be carried out by the operator own personnel or by appointed qualified 3rd parties

7.4.1.4 Detailed records shall be kept of all maintenance, inspection, test and repair work on every vehicle and will at least include the following: a) Preventive periodic inspection reports with associated test reports as required b) Defect repairs and rectification of issues of non-compliance carried out with associated test reports as required c) Specific inspection and test reports carried out on critical equipment as detailed in annex B to this standard d) Reconditioning of equipment governed by individual standards, for example bottom valves, manhole covers, pressure relief valves, etc e) Modifications carried out on tanks that could influence compliance requirements

7.4.1.5 Records shall be retained for the periods indicated in table 7.4.1.5 below.



Table 7.4.1.5: Record retention periods

Type of maintenance activity Retention period

Daily inspections 6 months

Monthly inspections 1 year

Annual inspections Life of vehicle

Intermediate periodic inspections Life of vehicle

Major periodic inspections Life of vehicle

Exceptional inspections Life of vehicle

Ad-hoc repairs carried out to tanks and product containments structures Life of vehicle

Ad-hoc repairs carried out to service equipment governed by separate standards

Life of vehicle

Repairs required due to in-service breakdowns of brake systems, foundation brakes, endurance brakes and trailer coupling equipment (meaning tow hitches, 5th wheels, kingpins, A-frames, tow eyes, turntables, etc))

24 months

The records referred to in table 7.4.1.5 include any test reports, defect repairs and rectification of issues of non-compliance.

7.4.2 Dangerous goods vehicle inspection schedules and requirements

7.4.2.1 Dangerous goods vehicles are subject to the types of inspections done subsequent to the initial construction of the vehicle, shown in table 7.4.2.1 (Inspections and tests related to vehicle construction are contained in Section 10 of this standard:

Table 7.4.2.1 Dangerous goods vehicle inspection types

Inspection Type Description

Operational Normal inspections that would be done as part of the in-operation and maintenance inspections and apply to the vehicle and tank/product containment structure.

Intermediate periodic Subsequent inspection related to the initial inspection and applies to the tank/product containment structure only.5 It occurs every 2.5 years to 3 years, depending on the tank type.

Major periodic Subsequent inspection related to the initial inspection and applies to the tank/product containment structure only.6 It occurs every 5 years to 6 years depending on the tank type.

5 This term is in keeping with the term used in the European Agreement concerning the ADR. 6 This term is in keeping with the ADR.



Exceptional Additional inspections required during major structural repair work that would involve all of the elements of an intermediate or periodic inspection or when a previously owned vehicle is procured and deployed in an operation.

7.4.2.2 The various inspection types are shown in table 7.4.2.2, together with the intervals, applicability and responsibilities. Details of the inspection requirements are contained in the indicated annexures to this standard.

Table 7.4.2.2 Dangerous goods vehicles inspection types, intervals, applicability and responsibilities

Inspection Type Interval Annex Applicable to Responsibility

Operational Daily B.1 All Driver

Monthly* B.2 All Competent person

12-months B.3 All Competent person

Intermediate periodic 30-months B.4 Tank containers, swap bodies, Portable tanks and Multi-element Gas Containers (MEGCs)

Competent person

36-months B.4 Fixed tanks, demountable tanks and battery vehicles

Competent person

Major periodic 60-months B.5 Tank containers, swap bodies, Portable tanks and Multi-element Gas Containers (MEGCs)

Competent authority

72-months B.5 Fixed tanks, demountable tanks and battery vehicles

Competent authority

Exceptional As required B.6 All tanks, product containment structures and related equipment governed by specific separate standards

Competent authority

* Monthly means a 4 to 6 week interval

7.4.2.3 The schedules and requirements state the minimum requirements.

7.4.2.4 Cognisance needs to be taken of the relevant requirements of other applicable statutory requirements that could influence the required inspection schedule.

7.4.2.3 Periodic inspection requirements are stated in intervals. Should a periodic inspection or a repair involving such an inspection be carried out at shorter intervals than those required, the following inspection will then occur at the next periodic interval.

7.4.2.5 The intermediate periodic inspection is applicable to all tanks that fall outside the scope of pressure vessels in terms of the relevant national legislation For pressure vessel tanks governed by such legislation, the intermediate periodic inspection shall be replaced the relevant inspection regime determined by the by a major periodic inspection. National legislation could require a different inspection and test regime for pressure vessels or other specific type of tanks. Cognisance must be taken of any such statutory requirements that could impose more stringent requirements when compared with this standard.



7.4.2.6 Intermediate periodic and major periodic inspections may be performed within a period of three months before or after the due date. However, should the inspection take place more than three months before the due date, the next due periodic inspections will be performed at the required intervals after the date of the actual periodic inspection being carried out

7.4.2.7 If an exceptional inspection covering structural repair or modification of tanks and cargo containment areas that will require verification of adherence to design, construction and material requirements as stated in the applicable standard of construction is carried out, and it includes all the elements of an intermediate periodic inspection or a major periodic inspection, the next periodic inspection will be performed at the required intervals after the date of the actual exceptional inspection being carried out.

7.4.3 Repair and modification of tanks

7.4.3.1 All tanks shall be repaired and modified in accordance with the requirements of the original construction standard of the vehicle and tank in all respects.

7.4.3.2 Such repairs and modifications carried out to the tank shall be verified, tested and certified strictly in accordance with the requirements of the original standard of construction of the product containment area and the exceptional inspections and tests as required by this standard.

7.4.3.3 All repairs and modifications to the tank shall be logged and held on record by the operator of the equipment. The records shall contain the following detail: a) the name of the organization that affected the repair; b) the date of the repair; c) a brief description of the work done; and d) all relevant test and inspection documentation issued by the manufacturer, tank builder or tank repair facility that proves that the repair or modification was done in accordance with the original design and manufacturing standard. The records shall be kept for the lifetime of the tank and if the equipment is sold to a future owner, the records shall be carried over to the next owner and continued to be kept by such next owner.

7.4.3.4 Modifications and repairs to tanks shall only be carried out by an organisation or facility that is skilled and competent to do so and complies with the relevant parts of this standard.

7.4.4 Repair, refurbishment and modification of equipment

7.4.4.1 Any repairs, modification and refurbishment of equipment governed by specific requirements contained in any specific standard (being this standard, by reference or directly, or the original standard of manufacture of the relevant equipment) shall be carried out in such a manner that the equipment complies with the relevant requirements in all respects.

7.4.4.2 Organizations or persons carrying out such work shall ensure that: a) the work is carried out strictly in accordance with the instructions and requirements of the original manufacturer, and b) a certificate of compliance with these requirements is issued upon completion of the work.

7.4.4.3 When existing equipment is replaced with new equipment, any such replacement shall be done using equipment in compliance with the relevant requirements.



7.4.5 Maintenance, repair, inspection and test personnel and facilities

7.4.5.1 All personnel involved in the maintenance, repair, inspection and test of dangerous goods vehicles and related equipment, governed by this standard, will be thoroughly trained and be proved competent with regards to: a) The contents and requirements of this standard as relevant to the tasks and work carried out b) Function and operation of equipment as governed by this standard c) Repair and reconditioning of equipment governed by this standard including specific training provided by the manufacturer of the equipment or the appointed agent. d) Repair and modification of tanks, and in specific the weld procedures, and testing of the tank and equipment

7.4.5.2 Facilities used for the repair and modification of vehicles tanks will be suitable for the purpose.

7.4.5.3 Work conditions shall take into account the risk associated with the dangerous goods substance that have been or are being transported (for vehicles not in a certified clean condition).

7.4.5.4 Vehicles and tanks presented for all inspections, other than the daily inspection, will be in a reasonable clean condition. It is not the intention for the operator to make a tank safe for entry or for hot work. The maintenance/ inspection/ test facility is responsible for this unless otherwise arranged.

7.5 Load constraints

7.5.1 Exempt quantities

7.5.1.1 Exempt quantity for a load consisting of items with the same UN number. If the total quantity loaded is less than the quantity (in kilograms or litres, as appropriate) given in column 6 of table A.1, the requirements of this standard do not apply.

7.5.1.2 Exempt quantity for a mixed load If no single item of dangerous goods in the load exceeds the quantity (in kilograms or litres, as appropriate) given in column 6 of table A.1, use the following equation to calculate each item of dangerous goods in the load: A = Q × F where Q is the quantity of the dangerous goods being transported, in kilograms (kg) or litres (l), as applicable; F is the factor shown in column 7 of table A.1 If the sum of A for all the calculations does not exceed 1 000, the requirements of this standard do not apply.

7.5.1.3 Exempt quantities are given in a simple figure without an associated unit. Unless otherwise indicated: - for substances transported in the liquid or gaseous states this must be interpreted as referring to a quantity in litres and; - for products transported in a solid state, this must be interpreted as referring to a quantity in kilograms.



7.5.2 Load compatibility

7.5.2.1 Where more than one item of dangerous goods (mixed load) is transported per vehicle/combination of vehicles, the load shall conform to the requirements shown in the load compatibility chart and special provisions according to the hazard class, in accordance with this section of the standard

7.5.2.2 Load compatibility and segregation shall be based on the hazard class and subsidiary risk diamonds, displayed on packages and containers. Both the hazard class and any subsidiary risks shall be considered, on an equal basis, in the segregation of cargo. Cargo segregation on mixed load vehicles shall conform to the requirements of the load compatibility chart in table 7.5.2.2 and the special provisions according to hazard class in this section. Furthermore, cognisance shall be taken of the reactivity of individual substances with each other, even if allowed in accordance with the load compatibility chart in table 7.5.2.2

Table 7.5.2.2

The following aspects are denoted: a) A white empty square indicates permitted mixed loading. b) A black shaded square indicates that loading on the same vehicle is prohibited. c) "A" indicates that loading on the same vehicle is permitted, but the goods shall be kept at least 1 m apart. Special provisions according to the hazard class (see 7.5.2.3) shall be considered in conjunction with the compatibility chart.

7.5.2.3 Special provisions according to hazard class



7.5.2.3.1 Provision applicable to all classes Unless otherwise specified, goods of different hazard classes shall be segregated by an air space of at least 100 mm or by an approved segregation device, or non-dangerous goods.

7.5.2.3.2 Provision applicable to class 1 Dangerous goods of class 1 may only be transported or conveyed by prior written permission from the competent authority on explosives unless specifically excluded in terms of the relevant national legislation

7.5.2.3.3 Provisions applicable to class 2 a) Packages of class 2 shall not be thrown or be subjected to impact. b) Packages of class 2 shall be so stowed that they cannot roll, fall, or be subjected to impact. c) When class 2.1 and class 2.3 goods are transported in closed vehicles, sufficient ventilation shall be provided to prevent the build-up of gases. d) Cylinders of class 2 not standing upright shall not be stowed with their valve-protecting devices facing outwards. e) Aluminium cylinders shall be kept apart from class 8 bases.

7.5.2.3.4 Provisions applicable to class 3 If the class 3 substance is nitro-methane, UN 1261, it shall not be transported in the same load as substances of hazard class 6.1.

7.5.2.3.5 Provisions applicable to class 4 a) A self-reactive substance of class 4.1 shall be shielded from direct sunlight. b) When self-reactive substances of class 4.1 are transported in vehicles covered with sheets, the sheets shall be of a material that is impermeable and non-combustible. c) Self-reactive substances of class 4.1 shall be stowed so as to be readily accessible during all stages of transportation and not be stacked on top of other goods. d) Flammable solids of class 4.1, transported in loads in excess of 5 000 kg, shall be subdivided in stacks of not more than 5 000 kg with a space of at least 500 mm between stacks, or subdivided by non-hazardous goods. e) Substances of class 4.2 shall be transported in closed vehicles with the containment space constructed of metal. f) Substances of class 4.3 shall be transported in closed vehicles or in hermetically sealed containers. g) Contact with water shall be avoided during all stages of transportation of class 4.3 substances, including loading and unloading.

7.5.2.3.6 Provisions applicable to class 5 a) For the transportation of class 5.2 peroxides, the cargo containment area shall be constructed entirely of metal and there shall be no exposed wood in or on any part of the cargo. b) Packages of class 5.2 shall be so stowed as to be readily accessible during all stages of transportation. c) Substances of class 5.2, transported in loads in excess of 5 000 kg, shall be subdivided in stacks of not more than 5 000 kg with an air space of at least 500 mm between stacks.

7.5.2.3.7 Provisions applicable to class 6 a) Substances of class 6.1 shall not be transported together with foodstuffs or stockfeeds. b) Cyanides of class 6.1 shall not be transported together with substances of class 8 acids. c) Substances of class 6.2 shall not be transported together with foodstuffs or stockfeeds. d) Packages of class 6.2 shall be stowed so that they are readily accessible during all stages of transportation.

7.5.2.3.8 Provision applicable to class 7 The transportation, by road, of radioactive material shall be in accordance with the relevant national legislation on radioactive material.



7.5.2.3.9 Provisions applicable to class 8 a) Concentrated acids and bases in quantities that exceed the exempt quantities shall be kept at least 1 m apart. b) Substances of class 8 acids shall not be transported together with cyanides of class 6.1.



Section 8

Emergency information systems7

8.1 Placarding and documentation of vehicles

8.1.1 General requirements

8.1.1.1 The vehicle placarding and documentation shall at all times be an accurate reflection of the dangerous goods being transported

8.1.1.2 The full placard shall be clearly visible from the roadside, whether directly fixed on the vehicle, or supported by means of a permanently fixed frame. The placard shall at all times be clean, legible and not defaced. If the placards affixed to the containers, MEGCs, tank-containers or portable tanks are not visible from outside the carrying vehicles, the same placards shall also be affixed to both sides and at the rear of the vehicle. Otherwise, no placard need be affixed on the carrying vehicle.

8.1.1.3 Empty uncleaned packagings (including IBCs and large packagings), tanks (including tank-vehicles, battery-vehicles, demountable tanks, portable tanks, tank-containers, MEGCs), MEMUs, vehicles and containers for carriage in bulk having contained dangerous goods of the different classes, shall be marked and labelled as if they were full.

8.1.1.4 Containers, MEGCs, MEMUs, tank-containers, portable tanks or vehicles containing goods of more than one class need not bear a subsidiary risk placard if the hazard represented by that placard is already indicated by a primary or subsidiary risk placard.

8.1.1.5 Placards which do not relate to the dangerous goods being carried, or residues thereof, shall be removed or covered.

8.1.1.6 When the placarding is affixed to folding panels, they shall be designed and secured so that they cannot unfold or come loose from the holder during carriage (especially as a result of impacts or unintentional actions).

8.1.1.7 Placards shall be affixed to both sides and at the rear of the vehicle. When the tank-vehicle or the demountable tank carried on the vehicle has multiple compartments and carries two or more dangerous goods, the appropriate placards shall be displayed along each side at the position of the relevant compartments and one placard for each product at the rear of the vehicle. However, in such case, if all compartments have to bear the same placards, these placards need be displayed only once along each side and at the rear of the vehicle. Where more than one placard is required for the same compartment, these placards shall be displayed adjacent to each other.

8.1.1.8 Transport units carrying dangerous goods shall display two rectangular orange-coloured plates conforming to 8.3, set in a vertical plane. They shall be affixed one at the front and the other at the rear of the transport unit, both perpendicular to the longitudinal axis of the transport unit. They shall be clearly visible. If a trailer containing dangerous goods is detached from its drawing vehicle during carriage of dangerous goods, the orange-coloured plate shall remain affixed to the rear of the trailer. When tanks are marked in accordance with 8.1.1.7, this plate shall correspond to the most hazardous substance carried in the tank.

7 This section is based on the current ADR requirements with regards to the dangerous goods placarding whilst retaining the current industry format and terminology for the Transport Emergency Card and DGD.



When a hazard identification number is indicated in the dangerous goods list (Annexure A to this standard) tank-vehicles, battery vehicles or transport units having one or more tanks carrying dangerous goods shall in addition display on the sides of each tank, each tank compartment or each element of battery vehicles, clearly visible and parallel to the longitudinal axis of the vehicle, orange-coloured plates identical with those prescribed in 8.3 and 8.4. These orange-coloured plates shall bear the hazard identification number and the UN number prescribed for each of the substances carried in the tank, in a compartment of the tank or in an element of a battery vehicle. MEMUs with tanks and bulk containers shall be placarded in accordance with this section.

For transport units carrying only one dangerous substance and no non-dangerous substance, the orange-coloured plates prescribed in 8.3 and 8.4 shall not be necessary provided that those displayed at the front and rear in accordance with 8.3 bear the hazard identification number and the UN number for that substance prescribed in Annexure A to this standard.

8.1.1.9 Dangerous goods that are transported at a temperature in excess of 100 °C (in the case of liquids) or 240 °C (in the case of solids) shall have three elevated temperature warning triangles attached to the cargo unit, one on either side and one on the rear of the unit, so as to be clearly visible from the roadside.

8.1.1.10 Vehicles shall, in the designated space, carry the following documents: a) A TEC for each dangerous goods item b) One or more dangerous goods declaration(s) to cover all the goods that comprise the load c) Confirmation of classified waste, if applicable d) Container packing certificate, if applicable e) A nominally empty packaging certificate if applicable (applicable to re-processed certified packing

8.1.2 Road tankers and bulk carriers

8.1.2.1 In the case of road tankers and bulk carriers, the placards, DGD/WDGD and TEC(s) shall be retained until the vehicle has been certified clean.

8.1.3 Packaged goods and intermediate bulk containers (IBCs)

8.1.3.1 In the case of packaged goods and IBCs all the placards shall be removed from the sides and rear of the vehicle and the documents shall be removed from the designated area immediately after all the goods have been off-loaded, provided no spillage has occurred.

8.1.3.2 If spillage occurred during the transport operation, the placards, DGD/WDGD(s) and TEC(s) shall be retained after the goods have been off-loaded, until the vehicle has been cleaned and certified as such.

8.1.4 Freight containers (see ISO 1496-1 to ISO 1496-5 and ISO 8323)

8.1.4.1 Vehicles that transport freight containers shall comply with 8.1.1

8.1.4.2 Freight containers that are being transported by road as part of a journey that includes movement by sea freight or across borders, shall carry split placards that consist of the appropriate hazard class and subsidiary risk diamonds and goods identification rectangle affixed to either side and each end of the container so that they are clearly visible from both the rear and the roadside during transport and also meet the requirements of the IMDG regulations. Freight containers not intended to be carried as sea freight or across national borders shall carry the normal dangerous goods placards on either side and each end so that they are clearly visible from both the rear and the roadside during transport and also meet the requirements of the IMDG regulations.



8.1.4.3 The danger warning diamond; placards and the documentation shall remain on the vehicle until all the freight containers have been removed or dangerous goods off-loaded. If spillage occurred during the transport operation, the placards, DGD(s)/WDGD(s) and transport emergency information shall be retained after the goods have been off-loaded, until the vehicle or goods containment area has been cleaned and certified as such.

8.1.5 Waste products classified as dangerous goods

8.1.5.1 Vehicles that transport waste products classified as dangerous goods shall comply with the requirements of 8.1 to 8.5 (inclusive).

8.1.5.2 The word "WASTE" shall be added above the UN No. in the goods identification zone of the dangerous goods placard

8.1.5.3 A container used for the transport of dangerous goods that has not been cleaned and is not accompanied by a nominally empty packaging certificate shall be classified as a dangerous goods waste product and shall comply with the requirements in 8.6

8.1.5.4 Empty triple rinsed pesticide containers that have been rendered unserviceable shall be classified as non-dangerous.

8.1.6 Transport of petroleum-based products

8.1.6.1 For tank-vehicles or transport units having one or more tanks carrying substances with UN Nos. 1202, 1203 or 1223, or aviation fuel classified under UN Nos. 1268 or 1863, but no other dangerous substance, the orange-coloured plates prescribed in 5.3.2.1.2 need not be affixed if the plates affixed to the front and rear in accordance with 5.3.2.1.1 bear the hazard identification number and the UN number prescribed for the most hazardous substance carried, i.e. the substance with the lowest flash-point.

8.1.6.2 When transporting petroleum-based products as in 8.1.6.1, the DGD(s) and TEC(s) shall reflect the actual substance(s) on the vehicle.

8.1.7 Transport of gases

8.1.7.1 When transporting a single gas, the relevant placard and TEC shall apply.

8.1.7.2 Mixed loads of gases may be transported under the following 5 group TEC(s): a) Compressed gases, oxidizing. b) Compressed gases, toxic. c) Compressed gases, flammable. d) Compressed gases (except Air, compressed), asphyxiant. e) Liquefied gas, flammable.

8.2 Requirements for placards

8.2.1 General



8.2.1.1 Provision is made for three types of placarding, namely: a) Dangerous goods placards b) Danger warning orange rectangle

8.2.2 Dangerous goods placard

8.2.2.1 General

8.2.2.1.1 Except as provided for the Class 7 placard and for the environmentally hazardous substance mark, a placardshall be configured as shown below.

8.2.2.1.2 The placard shall be in the form of a square set at an angle of 45° (diamond-shaped). The minimum dimensions shall be 250 mm x 250 mm (to the edge of the placard). The line inside the edge shall be parallel and 12.5 mm from the outside of that line to the edge of the placard. The symbol and line inside the edge shall correspond in colour to the label for the class or division of the dangerous goods in question. The class or division symbol/numeral shall be positioned and sized in proportion to those prescribed for the corresponding class or division of the dangerous goods in question. The placard shall display the number of the class or division (and for goods in Class 1, the compatibility group letter) of the dangerous goods in question in the manner prescribed for the corresponding label, in digits not less than 25 mm high. Where dimensions are not specified, all features shall be in approximate proportion to those shown.

8.2.2.1.3 The Class 7 placard shall be not less than 250 mm by 250 mm with a black line running 5 mm inside the edge and parallel with it and is otherwise as shown below (Model No. 7D). The number "7" shall not be less than 25 mm high. The background colour of the upper half of the placard shall be yellow and of the lower half white, the colour of the trefoil and the printing shall be black. The use of the word "RADIOACTIVE" in the bottom half is optional to allow the use of this placard to display the appropriate UN number for the consignment.

(No.7D)



Symbol (trefoil): black; Background: upper half yellow with white border, lower half white; The lower half shall show the word "RADIOACTIVE" or alternatively, the appropriate UN Number, and the figure "7" in the bottom corner.

8.2.2.1.4 For tanks with a capacity of not more than 3 m3 and for small containers, placards may be replaced by reduced sized labels with a side length of 100mm

8.2.2.1.5 Any dangerous goods placard shall be constructed as follows: a) The material of construction shall be sufficiently rigid to prevent any distortion when the placard is exposed to forces encountered during transportation by the relevant mode of transport; b) Provision shall have been made for attachment of the dangerous goods placard to the vehicle, and the means of attachment shall be of sufficient strength to resist distortion or disruption when exposed to the forces encountered during the normal road use of the vehicle; c) The background colour of the zones, letters, numbers and graphic designs may be of silk-screened or painted metal plate or rigid plastics, or may be formed by the application of peel-and-stick plastics material or coated paper; and d) The characters on the placard shall be printed, and not written by hand.

8.2.3 Hazard class diamond

As applicable to use on the dangerous goods placard as described in 8.2.2

8.2.3.1 The hazard class diamonds will visually match the colour reference numbers Pantone 151 or NCS S 0570-Y50R (orange), Pantone 192 or NCS S 0580-Y90R (red), Pantone 361 or NCS S 1565-G (green), Pantone 300 or NCS S 2065-B (blue), and Pantone 109 or NCS S 0570 G90Y (yellow). In case of a dispute the NCS colours shall take precedence.

8.2.3.2 The permissible hazard class diamonds are shown in table 8.2.3.2 below:

Table 8.2.3.2 Hazard class diamonds

Hazard class Hazard class diamond

1.1, 1.2, or 1.3

(See NOTES 1 and 2)

1.4

(See NOTE 2)



1.5

(See NOTE 2)

1.6

(See NOTE 2)

2.1

NOTE 1: Insert the division for explosives (refer the dangerous goods list), in the space marked " * * ". To be left blank if explosive is the subsidiary risk. NOTE 2: Insert the compatibility group (refer the dangerous goods list), in the space marked " * ", denoted by a letter A to N (excluding I and M) and S. To be left blank if explosive is the subsidiary risk.

2.2

2.3

3

2



4.1

4.2

4.3

5.1

5.2

6.1

6.2

7



7

7

8

9

8.2.3.3 For substance classified as environmentally hazardous, the diamond will be as shown below, except with the sides a minimum of 250mm:

8.2.3.4 Elevated temperature warning triangle

8.2.3.4.1 An elevated temperature warning triangle shall be an equilateral triangle with each side of length 250 mm and of design as shown below. The colour is red on a white background

8.2.3.4.2 The colour red shall visually match Pantone 192 or NCS S 0580-Y90R (red)



8.2.3.5 Environmentally hazardous substance mark

8.2.3.5.1 When a placard is required to be displayed in accordance with the provisions of section 8.2, containers, MEGCs, tank-containers, portable tanks and vehicles containing environmentally hazardous substances meeting the criteria of classification shall be marked with the environmentally hazardous substance mark shown in 8.2.3.3 All other relevant requirements of 8.2 shall apply.

8.3 Rectangular orange warning plate

8.3.1 The orange-coloured plates shall be reflectorized and shall be of 40 cm base and of 30 cm high; they shall have a black border of 15 mm wide. The material used shall be weather-resistant and ensure durable marking. The plate shall not become detached from its mount in the event of 15 minutes’ engulfment in fire. It shall remain affixed irrespective of the orientation of the vehicle. The orange-coloured plates may be separated in their middle with a black horizontal line of 15 mm thickness. If the size and construction of the vehicle are such that the available surface area is insufficient to affix these orange-coloured plates, their dimensions may be reduced to a minimum of 300 mm for the base, 120 mm for the height and 10 mm for the black border. In this case, a different set of dimensions within the specified range may be used for the two orange-coloured plates. When reduced dimensions of orange-coloured plates are used for a packaged radioactive material carried under exclusive use, only the UN number is required and the size of the digits stipulated in 8.3.2 may be reduced to 65 mm in height and 10 mm in stroke thickness. For containers carrying dangerous solid substances in bulk and for tank-containers, MEGCs and portable tanks, the plates may be replaced by a self-adhesive sheet, by paint or by any other equivalent process. This alternative marking shall conform to the specifications set in this sub-section except for the provisions concerning resistance to fire. The colour of the orange plates in conditions of normal use should have chromaticity co-ordinates lying within the area on the chromaticity diagram formed by joining the following co-ordinates:

Luminance factor of reflectorized colour: β > 0.12. Reference centre E, standard illuminant C, normal incidence 45°, viewed at 0°. Co-efficient of reflex luminous intensity at an angle of illumination of 5°, viewed at 0.2°: not less than 20 candelas per lux per m2

8.3.2 The hazard identification number and the UN number shall consist of black digits 100 mm high and of 15 mm stroke thickness. The hazard-identification number shall be inscribed in the upper part of the plate and the UN number in the lower part; they shall be separated by a horizontal black line, 15 mm in stroke width, extending from side to side of the plate at mid-height.The hazard identification number and the UN number shall be indelible and shall remain legible after 15 minutes’ engulfment in fire. Interchangeable numbers and letters on plates presenting the hazard identification number and the UN number shall remain in place during carriage and irrespective of the orientation of the vehicle.



8.3.4 The permitted tolerances for dimensions specified in this sub-section are ± 10%.

8.3.5 When the orange-coloured plate is affixed to folding panels, they shall be designed and secured so that they cannot unfold or come loose from the holder during carriage (especially as a result of impacts or unintentional actions).

8.3.6 The hazard identification number

8.3.6.1 The hazard identification number consists of two or three figures. In general, the figures indicate the following hazards: 2 Emission of gas due to pressure or to chemical reaction 3 Flammability of liquids (vapours) and gases or self-heating liquid 4 Flammability of solids or self-heating solid 5 Oxidizing (fire-intensifying) effect 6 Toxicity or risk of infection 7 Radioactivity 8 Corrosivity 9 Risk of spontaneous violent reaction NOTE: The risk of spontaneous violent reaction within the meaning of figure 9 include the possibility following from the nature of a substance of a risk of explosion, disintegration and polymerization reaction following the release of considerable heat or flammable and/or toxic gases.

Doubling (meaning for example if the first figure is a 3 and the next is also a 3) of a figure indicates an intensification of that particular hazard. Where the hazard associated with a substance can be adequately indicated by a single figure, this is followed by zero. The following combinations of figures, however, have a special meaning: 22, 323, 333, 362, 382, 423, 44, 446, 462, 482, 539, 606, 623, 642, 823, 842, 90 and 99, see 8.3.6.2 below. If a hazard identification number is prefixed by the letter "X", this indicates that the substance will react dangerously with water. For such substances, water may only be used by approval of experts. For substances of Class 1, the classification code in accordance with Column 4 of the table in Annexure A shall be used as the hazard identification number.

8.3.6.2 The hazard identification numbers have the following meanings:

20 asphyxiant gas or gas with no subsidiary risk 22 refrigerated liquefied gas, asphyxiant 223 refrigerated liquefied gas, flammable 225 refrigerated liquefied gas, oxidizing (fire-intensifying)



23 flammable gas 238 gas, flammable corrosive 239 flammable gas, which can spontaneously lead to violent reaction 25 oxidizing (fire-intensifying) gas 26 toxic gas 263 toxic gas, flammable 265 toxic gas, oxidizing (fire-intensifying) 268 toxic gas, corrosive 28 gas, corrosive 30 flammable liquid (flash-point between 23 °C and 60 °C, inclusive) or flammable liquid or solid in the molten state with a flash-point above 60 °C, heated to a temperature equal to or above its flash-point, or self-heating liquid 323 flammable liquid which reacts with water, emitting flammable gases X323 flammable liquid which reacts dangerously with water, emitting flammable gases 33 highly flammable liquid (flash-point below 23 °C) 333 pyrophoric liquid X333 pyrophoric liquid which reacts dangerously with water 336 highly flammable liquid, toxic 338 highly flammable liquid, corrosive X338 highly flammable liquid, corrosive, which reacts dangerously with water 339 highly flammable liquid which can spontaneously lead to violent reaction 36 flammable liquid (flash-point between 23 °C and 60 °C, inclusive), slightly toxic, or self-heating liquid, toxic 362 flammable liquid, toxic, which reacts with water, emitting flammable gases X362 flammable liquid toxic, which reacts dangerously with water, emitting flammable gases 368 flammable liquid, toxic, corrosive 38 flammable liquid (flash-point between 23 °C and 60 °C, inclusive), slightly corrosive or self-heating liquid, corrosive 382 flammable liquid, corrosive, which reacts with water, emitting flammable gases X382 flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gases 39 flammable liquid, which can spontaneously lead to violent reaction 40 flammable solid, or self-reactive substance, or self-heating substance 423 solid which reacts with water, emitting flammable gases, or flammable solid which reacts with water, emitting flammable gases or self-heating solid which reacts with water, emitting flammable gases X423 solid which reacts dangerously with water, emitting flammable gases, or flammable solid which reacts dangerously with water, emitting flammable gases, or self-heating solid which reacts dangerously with water, emitting flammable gases 43 spontaneously flammable (pyrophoric) solid X432 spontaneously flammable (pyrophoric) solid which reacts dangerously with water, emitting flammable gases 44 flammable solid, in the molten state at an elevated temperature 446 flammable solid, toxic, in the molten state, at an elevated temperature 46 flammable or self-heating solid, toxic 462 toxic solid which reacts with water, emitting flammable gases X462 solid which reacts dangerously with water, emitting toxic gases 48 flammable or self-heating solid, corrosive 482 corrosive solid which reacts with water, emitting flammable gases X482 solid which reacts dangerously with water, emitting corrosive gases 50 oxidizing (fire-intensifying) substance 539 flammable organic peroxide 55 strongly oxidizing (fire-intensifying) substance 556 strongly oxidizing (fire-intensifying) substance, toxic 558 strongly oxidizing (fire-intensifying) substance, corrosive 559 strongly oxidizing (fire-intensifying) substance, which can spontaneously lead to violent reaction 56 oxidizing substance (fire-intensifying), toxic 568 oxidizing substance (fire-intensifying), toxic, corrosive 58 oxidizing substance (fire-intensifying), corrosive 59 oxidizing substance (fire-intensifying) which can spontaneously lead to violent reaction 60 toxic or slightly toxic substance 606 infectious substance 623 toxic liquid, which reacts with water, emitting flammable gases 63 toxic substance, flammable (flash-point between 23 °C and 60 °C, inclusive) 638 toxic substance, flammable (flash-point between 23 °C and 60 °C, inclusive), corrosive 639 toxic substance, flammable (flash-point not above 60 °C) which can spontaneously lead to violent reaction



64 toxic solid, flammable or self-heating 642 toxic solid, which reacts with water, emitting flammable gases 65 toxic substance, oxidizing (fire-intensifying) 66 highly toxic substance 663 highly toxic substance, flammable (flash-point not above 60 °C) 664 highly toxic solid, flammable or self-heating 665 highly toxic substance, oxidizing (fire-intensifying) 668 highly toxic substance, corrosive X668 highly toxic substance, corrosive, which reacts dangerously with water 669 highly toxic substance which can spontaneously lead to violent reaction 68 toxic substance, corrosive 69 toxic or slightly toxic substance, which can spontaneously lead to violent reaction 70 radioactive material 78 radioactive material, corrosive 80 corrosive or slightly corrosive substance X80 corrosive or slightly corrosive substance, which reacts dangerously with water 823 corrosive liquid which reacts with water, emitting flammable gases 83 corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 60 °C, inclusive) X83 corrosive or slightly corrosive substance, flammable, (flash-point between 23 °C and 60 °C, inclusive), which reacts dangerously with water 839 corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 60 °C inclusive) which can spontaneously lead to violent reaction X839 corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 60 °C inclusive), which can spontaneously lead to violent reaction and which reacts dangerously with water 84 corrosive solid, flammable or self-heating 842 corrosive solid which reacts with water, emitting flammable gases 85 corrosive or slightly corrosive substance, oxidizing (fire-intensifying) 856 corrosive or slightly corrosive substance, oxidizing (fire-intensifying) and toxic 86 corrosive or slightly corrosive substance, toxic 88 highly corrosive substance X88 highly corrosive substance, which reacts dangerously with water 883 highly corrosive substance, flammable (flash-point between 23 °C and 60 °C inclusive) 884 highly corrosive solid, flammable or self-heating 885 highly corrosive substance, oxidizing (fire-intensifying) 886 highly corrosive substance, toxic X886 highly corrosive substance, toxic, which reacts dangerously with water 89 corrosive or slightly corrosive substance, which can spontaneously lead to violent reaction 90 environmentally hazardous substance; miscellaneous dangerous substances 99 miscellaneous dangerous substance carried at an elevated temperature

8.4 Emergency information documents

8.4.1 Transport emergency card (TEC)

Examples of a TEC and the associated requirements and information related to a TEC is contained in annexure C to this standard.

8.4.1.1 General requirements

8.4.1.1.1 A TEC is intended for use by the driver of the dangerous goods vehicle but might also be required by the emergency services in the absence of other information, or in support of available information. Any vehicle used for the transport of dangerous goods shall have a TEC for each dangerous goods item in the load.

8.4.1.1.2 The TEC shall be stored in the designated space.



8.4.1.1.3 The TEC shall be in English.

8.4.1.1.4 The TEC shall be reproduced on paper of size A4, with a left and a right border, consisting of 10 mm wide vertical lines in red.

8.4.1.1.5 The TEC shall be clean and legible.

8.4.1.1.6 The validity of the TEC shall be three years from the preparation date in the bottom right hand corner.

8.4.1.1.7 The operator shall discuss the contents of the TEC with the driver/s prior to departure on a journey/trip and the operator will ensure that the instructions are understood.

8.4.1.1.8 The driver will familiarise himself with the contents of the TEC and required actions prior to departure on a journey and ensure that the instructions are understood.

8.4.1.2 Requirements for the format of the TEC

8.4.1.2.1 The TEC document shall be prepared in a standardized format in conjunction with an SDS that complies with ANSI Z400.1.

8.4.1.2.2 Size and borders a) The TEC document shall consist of one or more A4 size sheet of white paper with information printed on one side only b) The information shall be entered in Arial font, in the following minimum font sizes: headings 14 pt bold, subheadings 10 pt bold and contents 10 pt regular c) The sheet shall have a left and a right border in red, of which the length shall at least frame the text. The length of the red lines shall be the length of the printable page and extend to within 20 mm or less from the top and bottom edges of the A4 page

8.4.1.2.3 Layout The layout of the TEC shall conform to the format shown in annex C. The main headings and lines, from top to bottom, shall be as follows: a) Proper shipping name b) Appearance c) Danger d) Personal protective equipment e) Emergency response equipment f) A solid black line g) Driver first actions h) Driver special/additional actions i) Driver actions in case of fire j) A solid black line k) First aid l) A solid black line m) Special information for emergency services n) A solid black line o) Additional information p) Emergency telephone numbers q) Prepared by The title: “TRANSPORT EMERGENCY CARD – Road transport” shall appear in the top left hand corner, with the words “In accordance with "SADCSTANXXX-Section 8” directly underneath. The dangerous goods references consisting of the UN No., the class, the subsidiary risk, the packing group and the ERG number shall appear in the top right-hand corner. The date (month and year) that the TEC was prepared, and the issuer’s own reference or serial number (if any), shall appear in the bottom right-hand corner



Note: It is recommended to include the relevant guide age from the ERG as an attachment to the TEC.

.

8.4.1.3 Requirements for information provided

8.4.1.3.1 The information for the TEC provided under the various action headings shall be taken from the ERG.

8.4.1.3.2 The TEC is intended for the use of the driver, and every effort shall be made to present the information in a clear and concise manner.

8.4.1.3.3 In order to ensure that the potential risk of the load and the emergency provisions to be taken in the event of an accident or leakage are adequately communicated, the TEC shall be available to all other persons who might come into contact with the dangerous goods in the course of transport.

8.4.1.3.4 The TEC shall, at the time of transportation of the goods, be based on the current properties, classification, and SDS information of the goods that are being transported.

8.4.1.3.5 The proper shipping name Only the proper shipping name in accordance with the dangerous goods list (annexure A to this standard) shall appear under this heading. Wording shall be printed in capital letters. NOTE Any trade name, or technical name for the product may be entered under the ADDITIONAL INFORMATION heading if this information is deemed necessary.

8.4.1.3.6 Appearance One or two phrases shall be inserted under this heading to assist in the identification of the dangerous goods in the case of a spill. Examples of appropriate phrases are: a) Clear colourless liquid with ammoniacal odour, or b) White granular powder. The information under the relevant section of the SDS may be used to select the appropriate phrases.

8.4.1.3.7 Danger The phrases as used in the ERG will be used in the TEC. The information under the relevant sections of the SDS shall be used as a guideline in selecting the most appropriate phrases.

8.4.1.3.8 Protective equipment a) Personal protective equipment No person shall make any attempt to approach a spill or suspected leakage unless he is equipped with the appropriate personal protective clothing in accordance with the information given under the heading “Public safety” of the appropriate ERG. b) Emergency response equipment Only the ER phrases as used in the ERG shall be used.. Phrases that describe equipment that are kept on board the vehicle, will be followed by the words "On board" The information under the relevant sections of the SDS shall be used as a guideline in selecting the most appropriate phrases.

8.4.1.3.9 Driver first actions The safety precautions outlined in the Emergency Response Guidebook shall be strictly adhered to.



8.4.1.3.10 Driver special/additional actions Only the phrases from the ERG shall be used. Compilation of the TEC will take into account the most appropriate phrases associated with the product within the capabilities of the driver.

8.4.1.3.11 Driver actions in case of fire Only the phrases from the ERG shall be used. Compilation of the TEC will take into account the most appropriate phrases associated with the product within the capabilities of the driver. If a fire extinguisher is used (see phrase F2), only drivers trained in fire-fighting using the appropriate equipment shall be employed.

8.4.1.3.12 First aid Only the phrases from the ERG shall be used. Compilation of the TEC will take into account the most appropriate phrases associated with the product within the capabilities of the driver. NOTE The emergency services would normally have much more detailed first-aid information and facilities. The intention here is not to provide a large amount of information but to draw attention to any special procedures or precautions that might be necessary.

8.4.1.3.13 Special information for emergency services Only the phrases not used in the aforegoing sections in the TEC from the ERG shall be used. Compilation of the TEC will take into account the most appropriate phrases associated with the product. NOTE: The emergency services would normally have much more detailed information and facilities. The intention here is not to provide a large amount of information but to draw attention to any special procedures or precautions that might be necessary.

8.4.1.3.14 Additional information Typical information included under the heading ADDITIONAL INFORMATION would be: a) Supplier’s/organization’s name b) The trade and technical names of the product c) Any special information not adequately covered by the available phrases under the various headings d) Pictograms in accordance this standard The date shall not exceed a period of three years prior to the date of transport. If preferred, this period could even be shortened to one year without much inconvenience.

8.4.1.3.15 Emergency telephone numbers This shall be the telephone number, available on a 24-hour basis firstly used to report the incident and secondly where more detailed technical information on the specific dangerous goods could be obtained.

8.4.1.3.15 Prepared by Either the name of the person, or the organization, or both, responsible for the preparation and accuracy of the contents of the TEC under the heading PREPARED BY in the appropriate space.

8.4.1.4 Requirements for revision

8.4.1.4.1 The TEC shall be revised every three years from the preparation date, which is on the bottom right hand corner of the card.



8.4.2 Dangerous Goods Declaration (DGD)

8.4.2.1 The dangerous goods declaration shall contain the following information (see annexure D.1 for an example): a) proper shipping name in accordance with the dangerous goods list b) UN No c) hazard class and the packing group, where the latter is applicable d) quantity and type of packaging, or the word "bulk", where applicable e) volume or mass of goods carried in bulk or the gross and net mass of packaged goods f) names, addresses and contact details of the following parties (where applicable): consignor (which can be the product manufacturer, product owner, product custodian) party contracting the operator operator consignee g) any additional information on handling, transport or storage h) the following declaration signed by the consignor: "I hereby declare that the content of this consignment is fully and accurately described above by the proper shipping name, and is classified, packaged, marked and labelled/placarded, and is in all respects in proper condition for transport in accordance with SADCSTAN XXX Section 8." i) the following declaration signed by the driver: “The consignment above has been received into my vehicle. My vehicle is correctly placarded and I am in possession of all necessary transport documentation pertaining to the transport of dangerous goods, including information to be followed in the case of an emergency.” NOTE: See Section 3 of this standard for the definitions applicable to the various parties referred. The use of upper or lower case is optional except for the packing group under item c) above. The information on the DGD shall be legible.

8.4.2.2 The DGD shall be stored in the designated space.

8.4.2.3 Copies of the DGD shall be retained by the consignor for a minimum of 90 days after the date of shipment, if no incident is reported. If an incident is reported the DGD shall be retained for the duration of the relevant investigation.

8.4.2.4 A consignment note, a delivery note or a waybill may be used as a dangerous goods declaration, provided it contains the information required by this standard.

8.4.2.5 A separate dangerous goods declaration for each consignment should be generated by the consignor to reflect a delivery to a specific consignee.

8.4.2.6 Written operational agreements a may be concluded by the responsible parties listed on the DGD to confirm accepted duties and responsibilities, if deemed necessary by any of the relevant parties.

8.4.2.7 In the case where the consignor does not know the exact details of the consignee (see note below), the consignee details may be included by means of: - an annexure to the DGD. This annexure may be in the form of a delivery note or delivery instruction issued by the Operator. All required details of the consignee shall however be included on the annexure. In such a case, the "Consignee" section on the DGD may include wording that will indicate that the contact details for the consignee are shown on an annexure. or - when dangerous goods are carried to be delivered to multiple consignees who cannot be identified at the start of the carriage, the words "Delivery Sale" may be given instead



Note: In many cases, the operator is required to load product at a 3rd part facility. The 3rd party seldom knows the details of the consignee. The party contracting the operator knows the details of the consignee, but is not present at the loading facility to issue and sign the DGD and also does not provide the exact details of the consignee to the loading facility (for example, the 3rd part loading facility is often a company in opposition to the party contracting the operator). Hence the reason for the allowance contained in this paragraph.

8.4.3 Waste Dangerous Goods Declaration (WDGD)

8.4.3.1 The waste dangerous goods declaration shall bear the following heading “WASTE DANGEROUS GOODS DECLARATION” and shall contain the following information (see annex D.2 for an example) a) proper shipping name in accordance with the dangerous goods list (Annexure A) b) UN No. c) hazard class and the packing group, where applicable d) quantity and type of packaging, or the word "bulk", where applicable e) volume or mass of goods carried in bulk or the gross and net mass of packaged goods f) names, addresses and contact details of the following parties (where applicable): consignor (waste generator, waste manager, waste holder, product owner, product custodian) party contracting the operator operator consignee g) origin/source of the waste (process or activity that generated the waste) h) waste classification i) type of waste management applied (re-use/recycling/recovery/treatment/disposal) j) details of any waste diverted and details of the diverting facility k) discrepancies in information (waste quantity, type, classification, physical and chemical properties) l) reporting description and code in terms of the relevant legislation. m) Waste Management Facility License Number (if applicable) n) The following declaration signed by the consignor/waste generator/waste manager: "I hereby declare that the contents of this consignment is fully and accurately described, classified, marked and labelled/placarded and in all respects in proper condition for transport in accordance with SADCSTANXXX Section 8." o) The following declaration signed by the driver/operator: "I hereby declare that the classified waste described above has been received into my vehicle. My vehicle is correctly placarded and I am in possession of all necessary transport documentation including information to be followed in case of an emergency." p) The following declaration signed by the consignee/waste manager: "I hereby confirm that the hazardous waste described above has been received at the waste site and the waste has been treated and disposed of as indicated."

Requirements and allowances contained under 8.4.2.2 to 8.4.2.6 (inclusive), excluding 8.4.2.3 hall apply to the WDGD.

8.4.3.3 Copies of WDGD shall be retained by the consignor, consignee and the operator for a minimum of 5 years after the date of shipment.



8.4.4 Waste classification confirmation

8.4.4.1 In cases where a vehicle transports waste that contains any material listed as a dangerous good in the dangerous goods list (Annexure A) and where the total quantity of such material, either by itself or in combination with other such materials, exceeds the exempt quantity, that vehicle shall carry written confirmation of the hazardous waste. NOTE: The confirmation can be included in the WDGD, or other delivery documentation.

8.4.5 Other licences and permits

8.4.5.1 In cases where a vehicle transports explosives, licences and permits shall be obtained from the relevant competent authority as required by the relevant national legislation as applicable.

8.4.5.2 In cases where a vehicle transports radio-active materials, licences and permits shall be obtained from the relevant competent authority as required by the relevant national legislation as applicable



Section 9

Packaging for road transport

9.1 Sectional scope

9.1.1 This section identifies the various methods of packaging suitable for the prescribed maximum quantities of dangerous goods, the various types of large packaging and various types of intermediate bulk container (IBC) suitable for the transport of dangerous goods by road and rail. It describes minimum performance requirements for these different types of packaging, the procedures to be followed to obtain approval from testing or certification authorities and gives details of the labels and marking to be displayed on the packaging.

9.2 Requirements

9.2.1 The requirements in the relevant sections of the UN Model Regulations (Recommendations on the transport of dangerous goods) will apply.

9.3 Test and accreditation authorities and facilities

9.3.1 Accreditation of testing facilities will be carried out by facilities and organisations recognised by the standards organisations of the member states participating in the application of this standard.

9.3.2 Testing will be done by facilities and organisations accredited in terms of 9.3.1



Section 10

Standards and specifications for vehicles and equipment

10.1 Compliance with standards

10.1.1 Acceptance of other standards

10.1.1.1 Tanks which are not designed, constructed and tested in accordance with the standards and requirements set out in this standard shall be designed, constructed and tested in accordance with the provisions of a technical code providing the same level of safety and recognised by the competent authority. Tanks shall, however, comply with the minimum requirements of the relevant parts of this standard.

10.1.1.2 A competent authority may allow tanks and related equipment constructed to the following internationally accepted standards to be used: - ADR 2005 or later - US DOT 2005 or later Such tanks and equipment shall however provide the same level of safety.

10.1.1.3 Portable tanks and tank containers constructed and approved to ADR, RID or IMDG are allowed to be used for road transportation

10.1.2 Allocation of a tank code to an existing tank

10.1.2.1 A tank constructed under any of the accepted tank standards, may be allocated with a tank code (refer section 7 of this standard) if it complies with the relevant requirements in terms of this standard. NOTE: The allocation of the tank code is necessary in order for the tank to be allowed to operate in accordance with section 7 of this standard.

10.1.2.2 The tank code allocation will be approved by a competent authority by means of issuing a certificate that states the following: a) tank serial number b) manufacturer of the tank c) construction standard of the tank d) statement that the tank code has been issued in accordance with the relevant section of this standard e) date of allocation of the tank code f) name and signature of the competent authority

10.1.2.3 The tank code allocated under this provision will be displayed on a supplementary plate adjacent to the manufacturer's plate and will contain the following information: a) tank serial number b) allocated tank code c) statement that the tank code has been issued in accordance with this standard d) date of allocation of the tank code e) name and mark of the competent authority



10.1.3 Certification of a tank that does not comply with an accepted standard

10.1.3.1 A tank that does not comply with any standard, may be re-certified to comply with a standard.

10.1.3.2 A competent authority may re-certify such a tank by performing the following checks, inspections and tests to the chosen standard covering (but not limited to): a) Verification of the design requirements b) Verification of material used c) Verification of welded joints by suitable non-destructive tests and inspections d) Compliance of equipment fitted e) Allocation of a suitable tank code. f) Hydraulic pressure tests g) Elements covered by a major periodic inspection as included in section 7 of this standard

10.1.3.3 The competent authority will ensure that the re-certification process takes into account all safety aspects of the chosen standard.

10.1.3.4 The tank will be plated in accordance with the requirements of the chosen standard.

10.1.3.5 When satisfied that compliance has been achieved, the competent authority will issue a certificate of compliance in accordance with section 10.3.18 of this standard including a statement that the tank has been re-certified in accordance with the indicated standard. The competent authority will also indicate any special provisions and restrictions applicable.

10.1.3.6 The tank life cycle will commence from the time of re-certification in terms of the periodic inspections and tests required.

10.1.4 Upgrading of tanks

10.1.4.1 Tanks may be upgraded from one specification level to another, which could include modification to the tank and equipment.

10.1.4.2 Such an upgrade shall require the competent authority to: a) fully perform all design, inspection and testing functions in terms of all the applicable parameters as contained in the standard being upgraded to b) issue a new certificate of compliance for the tank as approved by the competent authority c) re-plate the tank in accordance with the new applicable standard

10.1.4.3 The tank life cycle will commence from the time of upgrade in terms of the periodic inspections and tests required.

10.1.5 Re-mounting of existing tanks

10.1.5.1 Tanks may be remounted from one fixed tank vehicle to a new chassis.

10.1.5.2 For such a remounting action to be allowed, the following shall be adhered to: a) the compliance certificate for the new vehicle shall indicate that the tank has been remounted b) the original compliance or manufacturer's certificate and the original tank plating shall be available at the time of remounting c) the remount shall be approved by the competent authority based on a verification of the design which shall include internal inspections, material thickness verifications, non-destructive tests of tank welded joints, pressure testing of the tank and general compliance with the original design standard



c) the vehicle itself shall comply with the requirements of the construction standard at the time of the remounting d) when a tank is remounted and undergoes no standard upgrade the life cycle of the tank is determined in accordance with the original manufacturing date, in order to determine future periodic tests in accordance with section 7 of this standard

10.2 Design and construction requirements - Vehicles

10.2.1 Requirements for vehicles The construction requirements are summarized in table 10.2.1. An "X" in the respective "Vehicle type" column indicates that compliance is required with the relevant individual requirements of this part of the standard.

Note: For the purpose of this part, the term "vehicle" excludes the tank and related equipment.

Table 10.2.1. Vehicle construction requirements

Technical specification Vehicle types

Clause Requirement AT FL OX EX

10.2.2.1 Electrical wiring - General X X X X

10.2.2.2 Electrical wiring - Wiring to the rear of the cab X X X X

10.2.2.3 Battery master switch X X

10.2.2.4 Batteries X X X X

10.2.2.5 Permanently energised circuits X X

10.2.2.6 Lighting X X

10.2.2.7 Electrical connections for trailers X X X X

10.2.2.8 Location of electrical equipment X X

10.2.3 Exhaust system protection X X

10.2.4.1 Cab X X

10.2.4.2 Cab roof hatch X X X X

10.2.4.3 Cab rear wall X X

10.2.4.4 Engine shielding X X

10.2.4.5 In-cab electrical sockets X X

10.2.5 Front charge connection X X X X

10.2.6 Fuel tank X X X X



10.2.7 Engine X X X X

10.2.8 Braking system X X X X

10.2.9 Endurance braking X X X X

10.2.10 Electrical continuity X X

10.2.11 Wheel chocks X X X X

10.2.12 Mudguards X X X X

10.2.13 Side under-run protection X X X X

10.2.14 Ground clearance X X X X

10.2.2 Electrical equipment

10.2.2.1 Electrical wiring - General a) The conductors shall be large enough to avoid overheating and shall be adequately insulated. All circuits shall be protected by fuses or by automatic circuit breakers, except for the following: - from the battery to the cold start and stopping systems of the engine - from the battery to the alternator - from the alternator to the fuse or circuit breaker box - from the battery to the starter motor - from the battery to the power control housing of the endurance braking system if this system is electrical or electromagnetic The above protective systems shall be as short as possible. b) Cables shall be securely fastened and positioned in such a way that the conductors are adequately protected against mechanical and thermal stresses. c) The installation shall be so designed, constructed and protected that it cannot provoke any ignition or short circuit under normal conditions of use of vehicles, and that these risks can be minimized in the event of impact or deformation.

10.2.2.2 Electrical wiring to the rear of the cab Electrical installations to the rear of the cab shall comply with the following requirements: a) electrical junction boxes and other equipment shall not be installed in positions where there is a risk of product spillage onto such equipment from leaking valves, pipelines and product handling activities, such as loading and discharge b) all connections shall be made in secure junction boxes using fixed terminals or in moulded conduit branches c) cable entry into the junction boxes shall be by means of suitable glands d) electrical connections shall not make use of open contacts and push-in connections, unless the latter are fitted with a durable mechanical latch. Pierced contacts shall only be used if the relevant circuits are intrinsically safe and the insulation of the electrical cables are of a self-sealing type when pierced e) wiring, fittings and equipment used shall be suitable for the operating environment and resistant to degradation by contact with the products transported f) electrical equipment installed adjacent to equipment and areas that might vent to the atmosphere, including the bottom loading and vapour recovery adaptors, shall comply with the requirements in table 10.2.1 g) wiring located to the rear of the driver's cab shall be protected against impact, abrasion and chafing during normal vehicle operation. Examples of appropriate protection are given in figures 1, 2, 3, and h) sensor cables of anti-lock braking devices do not need additional protection.



Figure 1 — Corrugated polyamide conduit

Figure 2 — Corrugated polyamide conduit with insulating sheath

Figure 3 — Polyurethane sheath with inner sheath

Figure 4 — Metal-threaded protection layer

10.2.2.3 Battery master switch a) An isolating switch for breaking the electrical circuits shall be placed as close to the battery as is practicable. It shall be protected against inadvertent operation, and shall be easily operated by someone standing next to the vehicle. A control device to facilitate the disconnecting and the reconnecting functions of the switch may be installed in the driver's cab in a position where the driver can operate the mechanism from the driving position. Additional control devices may also be installed. All control devices shall be distinctively marked and protected against inadvertent operation. b) The switch shall have a casing with protection degree IP65. c) The cable connections on the switch shall be of protection degree IP54. However, this does not apply if these connections are contained in a housing, such as the battery enclosure. In this case it is sufficient to insulate the connections against short circuits, for example with a rubber cap.

d) Where a single pole (also referred to a two pole) isolator is used, it will isolate the positive (live) cable from the battery.

10.2.2.4 Batteries a) Truck batteries shall be fitted inside a suitable enclosure with a lid. b) The battery terminals shall be electrically insulated or covered by an insulating battery box cover. If the batteries are not located under the engine bonnet, they shall be fitted inside a vented enclosure. c) Where jump-start sockets are fitted, these shall be connected to the switched side of the battery master switch and shall either be installed inside the battery enclosure or in a separate enclosure.



10.2.2.5 Permanently energized circuits a) Those parts of the electrical installation (including the leads) that remain energized when the battery master switch is open shall be suitable for use in hazardous areas in accordance with the zone of use. b) Fuses and circuit breakers for unprotected (permanently live) circuits shall be fitted in a suitable enclosure and rated for the smallest conductor being protected, marked with the maximum fuse/circuit breaker rating. Such fuses and circuits breakers shall open-circuit within 10 ms and 30 ms respectively when a current of twice the relevant rating is passed. c) Permanently energized electrical equipment, including the leads for which there are no specific other requirements shall meet the requirements for zone 1 for electrical equipment in general, or shall meet the requirements for zone 2 for electrical equipment situated in the driver's cab. d) Power for permanently live equipment will be taken from the "live" terminals of the battery isolator (and not from the battery terminals). The supply leads for permanently energised equipment shall either comply with the provisions of IEC 60079, part 7 ("Increased safety") and be protected by a fuse or automatic circuit breaker placed as close to the source of power as practicable or, in the case of "intrinsically safe equipment", they shall be protected by a safety barrier placed as close to the source of power as practicable. Bypass connections to the battery master switch for electrical equipment which must remain energized when the battery master switch is open shall be protected against overheating by suitable means, such as a fuse, a circuit breaker or a safety barrier (current limiter).

10.2.2.6 Lighting Lamp bulbs with screw caps shall not be used

10.2.2.7 Electrical connections for trailers a) Electrical connections between motor vehicles and trailers shall have a protection degree IP54 in accordance with IEC 60529 and be designed to prevent accidental b) Connectors shall be in conformity with ISO 25981:20082, ISO 12098:20042, ISO 7638:20032 and EN 15207:2006 as appropriate c) Connections between the motor vehicle and the trailer used for power and communication to and from auxiliary equipment shall comply with EN 15607 or ISO 11446. (The connection diagram for the ISO11446 socket is the same as that for EN15607 except with pins 14 and 15 removed). d) The connection used for auxiliary equipment shall be a dedicated connection. Connections used for trailer electrics (ISO 12098) and ABS braking (ISO 7638) shall not be used for any function associated with permanently powered equipment.

10.2.2.8 Location of electrical equipment Electrical equipment installed adjacent to equipment and areas that might vent to the atmosphere, including the bottom loading and vapour recovery adaptors, shall comply with the requirements in table 10.2.2.8. This does not include permanently energized equipment which are governed be separate specific requirements.

Table 10.2.1 Distances from source of vapour/liquid release to electrical equipment

Distance from source of vapour/liquid release Equipment requirement

Less than 500 mm Suitable for Zone 2 operation

From 500 mm to 1000 mm IP 65

Greater than 1000 mm No restriction



10.2.3 Exhaust system protection

10.2.3.1 Where the rear cab engine compartment splash shield does not afford the required protection, additional shields shall be fitted to prevent any product spillage from making contact with any hot part of the exhaust system. The shielding shall be designed and fitted in such a manner that the surface temperature remains lower than 200 °C.

10.2.3.2 Where un-shielded sections of the exhaust system have surface temperatures that remain below 200 °C, no additional shielding is required.

10.2.3.4 A vertical exhaust may be used provided that there is effective shielding and an effective method of preventing ingress of spilt flammable liquid is used. The exhaust system (including the exhaust pipes) shall be so directed or protected to avoid any danger to the load through heating or ignition. Parts of the exhaust system situated directly below the fuel tank (diesel) shall have a clearance of at least 100 mm or be protected by a thermal shield.

10.2.4 Truck cab

10.2.4.1 Cab Unless the driver's cab is made of materials which are not readily flammable, a shield made of metal or other suitable material of the same width as the tank shall be fitted at the rear of the cab. Any windows in the rear of the cab or in the shield shall be hermetically closed and made of fire-resistant safety glass with fire-resistant frames. Furthermore, there shall be a clear space of not less than 15 cm between the tank and the cab or the shield.

10.2.4.2 Cab roof hatch If a hatch is fitted to the cab roof, it shall be permanently closed by suitable means to prevent the driver from opening it.

10.2.4.3 Cab rear wall The rear wall of the cab shall consist of a solid bulkhead and no rear window will be allowed. Should a window be fitted. It will be of a steel re-inforced type and will be mounted in a steel frame or a frame that will ensure that the window will remain in place in the event of a fire.

10.2.4.4 Engine shielding As far as practical, a fire– and spill-protection shield, made of metal or other suitable non-absorbent material, shall be fitted at the rear of the cab to: a) protect the cargo from a fire in the engine compartment, and b) prevent product spillage from entering the engine compartment. Other suitable equipment fitted in or to the rear of the engine aperture that would fulfil a similar function, may take the place of the shield. The inlet of an air intake system shall face away from the tank in order to reduce the risk of spilt product entering the air intake system.

10.2.4.5 In-cab electrical sockets a) Vehicles shall not be equipped with cigarette lighters. b) If auxiliary electrical sockets (such as for charging of cell phones) are required inside the cab, these shall be provided with effective blanking caps. c) Auxiliary sockets shall be protected by a fuse or other device to prevent overheating.



10.2.5 Front air charge connection

10.2.5.1 All truck tractors and freight carrier chassis shall be fitted with a suitable brake coupler at the front of the vehicle. The coupler shall be used in an emergency to charge the vehicle air system should the vehicle operating system run out of air, or to move a broken-down or immobile vehicle away from a hazardous situation. The coupling will be easily visible from outside if the vehicle and easily accessible for the intended use.

10.2.6 Fuel tank The fuel tanks for supplying the engine of the vehicle shall meet the following requirements:

10.2.6.1 In the event of any leakage, the fuel shall drain to the ground without coming into contact with hot parts of the vehicle or the load.

10.2.6.2 Fuel tanks containing petrol shall be equipped with an effective flame trap at the filler opening or with a closure enabling the opening to be kept hermetically sealed.

10.2.7 Engine

10.2.7.1 The engine propelling the vehicle shall be so equipped and situated to avoid any danger to the load through heating or ignition. In the case of EX vehicles. the engine shall be of compression-ignition type

10.2.8 Braking systems

10.2.8.1 Motor vehicles and trailers intended for use as transport units for dangerous goods shall fulfil all relevant technical requirements of ECE Regulation No.133. EX, FL, OX and AT vehicles shall fulfil the requirements of ECE Regulation No.133, Annex 5.8

10.2.9 Endurance braking

10.2.9.1 Vehicles equipped with endurance braking systems emitting high temperatures placed behind the rear wall of the driver's cab shall be equipped with a thermal shield securely fixed and located between this system and the tank or load so as to avoid any heating, even local, of the tank wall or the load. In addition, the thermal shield shall protect the braking system against any outflow or leakage, even accidental, of the load. For instance, a protection including a twin-shell shield shall be considered satisfactory.

10.2.10 Electrical continuity

10.2.10.1 Metal-to-metal connections shall have a continuity of less than 10 Ω.

8 Consideration should be given to increase the endurance brake requirement in Annex 5 due to the higher laden mass/ combination mass in the region.



10.2.10.2 Non-metallic conductive components shall be installed such that that electrical continuity with the adjacent component is less than 106 Ω.

10.2.10.3 Tanks shall be mounted such that the electrical conductivity between the tank and the wheels does not exceed 10 Ω and between the tank and the road surface does not exceed 106 Ω.

10.2.10.4 Tanks mounted on rubber or in such a manner that it is insulated from the vehicle chassis shall be provided with bonding cables fitted between the tank and the vehicle chassis.

10.2.10.5 Vehicle tyres will have a maximum electrical resistance of 106 Ω when tested in accordance with ISO 2878

10.2.11 Wheel chocks Not applicable to vehicles with a GVM of 3500kg or less.

10.2.11.1 Each vehicle in a combination shall be provided with two wheel chocks of sufficient strength and made from non-sparking material. Wheel chocks are not required to be fitted to a truck tractor.

10.2.12 Mudguards Not applicable to vehicles with a GVM of 3500kg or less.

10.2.12.1 All wheel positions on the vehicle or combination of vehicles shall be fitted with effective mudguards covering at least the full width of the tyres on the wheel position.

10.2.12.2 All rearmost wheels on an axle or axle group shall be fitted with mud flaps or stone guards that cover at least the width of the tyres.

10.2.13 Side under-run protection Not applicable to vehicles with a GVM of 3500kg or less.

10.2.13.1 All vehicles shall be equipped with efficient side under-run protection devices along unprotected areas of the sides of the vehicle to prevent pedestrians and cyclists from accidentally entering into the space between the axles or axle units or underneath the vehicle.

10.2.13.2 The bottom edge of the lower rail shall be approximately 400 mm from the ground and the gap to the top rail shall not exceed 300 mm.

10.2.13.3 The outer surface of the side under-run protection rails shall not be further than 50 mm.

10.2.13.4 The unprotected areas at the front and rear of the rails shall not exceed 250 mm.

10.2.13.5 Where equipment has been fitted in such areas and is deemed to fulfil the intended function of the side under-run rails, no additional side under-run protection needs to be fitted over and above such equipment.

10.2.13.6 Single rail side under-run devices may be used where the design of the vehicle makes it impractical to fit a dual rail installation.



10.2.14 Ground clearance related to equipment

10.2.14.1 Any equipment fitted that may contain product or product vapours, or that is used to house or attach such product- or vapour-containing equipment, shall have sufficient ground clearance, taking into account the location of the equipment on the vehicle and the potential hazards associated with such locations. Under no circumstances shall this ground clearance be less than 300 mm.

10.2.14.2 If a vehicle is fitted with a system that allows the height of the vehicle to be varied by means of raising or lowering the vehicle, it will be provided with a facility that will automatically reset to the correct height once the vehicle starts to move off.

10.3 General requirements related to equipment fitted to road tank vehicles

The following general requirements apply to vehicles with tanks.

10.3.1 Overfill protection

10.3.1.1 All vehicles constructed to be bottom loaded with liquid products in bulk shall be fitted with an effective overfill prevention system, which shall terminate loading when an overfill situation is reached, by either shutting the bottom valves on the vehicle and the loading facility or both. If operational considerations render the installation of overfill prevention impractical, agreement has to be reached between the competent authority and the manufacturer and any deviation shall be indicated as such on the manufacturer's certificate.

10.3.1.2 The overfill prevention system shall be installed such that product spillage is prevented, taking into account the flow rates of the loading facility and the reaction time of the various system elements. In no case shall an overfill system "trigger" when the remaining ullage in the compartment being loaded is: a) less than 200 litres for a vehicle fitted with pneumatic sensors. b) less than 150 litres for a vehicle fitted with electronic sensors.

10.3.1.3 The trigger level shall be measured between the product level and the inlet to the compartment vapour vent.

10.3.1.4 Each individual compartment shall be fitted with a separate overfill sensor.

10.3.1.5 The overfill system shall be configured such that when any one sensor senses an overfill condition, the complete bottom loading action for the vehicle is terminated. No further loading shall be allowed until the overfill condition has been rectified in the relevant compartments.

10.3.1.6 Where overfill sensors are of an adjustable type, means shall be provided to seal the adjustment mechanism with a seal that shall indicate tampering after initial adjustment. NOTE An example of a typical seal used is a "meter" seal.

10.3.1.7 Overfill protection systems shall not be fitted with over-ride mechanisms (which can be used to de-activate or by-pass the system whilst loading the vehicle) in such a way that an overfill condition can occur un-detected or can result in a product spillage or dangerous condition whilst bottom loading the tanker.

10.3.1.8 Where overfill protection systems are fitted with a standard open (electrical contact open when air pressure is not applied) pressure switch which serves to provide the electrical signal that an overfill sensor has triggered, the pressure setting of the switch shall be such that the switching to the open position occurs at 110 % of the minimum pneumatic control system operating pressure on the vehicle.



10.3.1.9 Electronic overfill systems a) Electronic overfill prevention systems shall comply with EN 13922. b) Where an electronic overfill sensor has been fitted together with a pneumatic sensor to a tank compartment, the electronic sensor shall be set to trigger at an approximate 20 mm height before the pneumatic sensor triggers.

10.3.2 Emergency venting Applicable only to tanks for Class 3 product or products with a Class 3 subsidiary risk and that are not constructed as pressure vessels.

10.3.2.1 Each compartment of a tank shall be fitted with an emergency vent in accordance with EN 14596 to relieve internal pressure surges, which might cause the tank to rupture in the case of an accident, and to relieve internal pressure build-up due to excessive product temperature in the case of a fire.

10.3.2.2 The vent may be fitted as part of the manhole cover or it may be fitted directly to the top of the compartment shell.

10.3.3 Pipelines and bottom loading adaptors

10.3.3.1 Pipelines shall be sized to ensure that product flow speeds do not exceed 7 m/s at any time, during either loading or discharge operations.

10.3.3.2 Installed pipeline systems complete with equipment in place shall be able to withstand operating, test and surge pressures that are at least equal to those of the bottom valves used. In no case shall the design pressure be less than 500 kPa, the test pressure 1.5 times the design pressure, and the surge pressure 5 times the design pressure.

10.3.3.3 On vehicles fitted with pressure balanced bottom valves that can close against the product flow whilst being bottom loaded, loading adaptors shall be able to withstand surge pressures of up to 2500 kPa.

10.3.3.4 "API" type bottom-loading adaptors shall comply with EN 13083.

10.3.4 Spill containment

10.3.4.1 Tanks shall be provided with an effective spill containment area enclosing all equipment mounted on the tank top from which product can spill during either loading operations or transport.

10.3.4.2 The spill containment area shall be so designed and constructed to fully contain any spillage and be seal-welded or otherwise attached to the tank top so that any spillage is directed to the ground via the provided spillage drains only

10.3.4.3 Adequate spillage drains, compatible with the product transported, shall be provided to drain any spillage occurring into the spill containment area to the ground into areas where the drained product cannot cause any safety hazard and away from any road tanker equipment such as pumps, meters, brakes and electrical equipment.



10.3.5 Permanently enclosed areas of entrapment

10.3.5.1 All areas that are permanently enclosed, such as hollow-section overturn protection members welded to the tank, and in which product or vapour can become entrapped through spillage and leakage from within the tank, shall be provided with sufficiently sized degassing ports. These degassing ports shall be plugged by means of screw plugs.

10.3.5.2 Internal structures, such as cleaning rings and double bulkheads between compartments, forming a void inside the tanker, shall be provided with a vent at the highest point permanently open to atmosphere, and a drain at the lowest point. It is not recommended to fit an isolating valve to the drain. The ports for the vent and drain shall be sufficiently sized to allow for degassing.

10.3.6 Vapour recovery systems

10.3.6.1 Where vapour recovery systems are fitted, these systems shall be in accordance with API RP 1004 with regards to the following: a) collector manifolds and down pipes shall be of a cross sectional area at least equal to that of a pipe with inside diameter 100 mm b) each individual compartment vapour transfer valve shall be connected into the control system in such a manner as to ensure that the compartment vent has opened before the compartment bottom valve opens c) the vapour transfer valve shall comply with EN 13082 d) the coaming vent shall close to the atmosphere upon coupling of the vapour recovery coupler from the loading or discharge installation. It shall have sufficient venting capacity to ensure that the tank maximum working pressure and vacuum ratings shall not be exceeded whilst the maximum rated number of compartments are being loaded or discharged at the maximum applicable operational flow rates simultaneously without the vapour recovery adaptor coupled to the loading or discharge facility. If the vapour transfer vent includes the EN 14595 PV vent function, the coaming vent shall include a PV venting function e) the maximum back pressure of the entire vapour recovery system shall not exceed 5.5 kPa

10.3.6.2 The vapour recovery adaptor shall be in a location suitable to local operations and may fall outside the requirements of the recommended API standard.

10.3.6.3 The vapour recovery adaptor shall comply with EN 13081.

10.3.7 Vapour venting Applicable to tanks for liquid products being bottom loaded or discharged with open manhole covers.

10.3.7.1 Each compartment shall be provided with sufficient pressure and vacuum venting capacity by means of the compartment vapour vent, to ensure that the tank is not over- or under-pressurized during both bottom loading and discharge operations.

10.3.7.2 Such venting capacity shall be over and above the standard pressure/vacuum breathing vent required in terms of the tank design standard.



10.3.8 Bottom valve installations

10.3.8.1 Bottom valves shall be fastened to the companion flange in the tank floor or sump by means of studs fitted into blind and tapped holes, or bolts fitted from the inside of the sump flange and seal-welded to the flange on the inside of the tank.

10.3.8.2 Where the bottom valve does not provide effective means of spray deflection, such as in the case of a remotely mounted bottom valve and product entering a compartment via an external trough, the entry port shall be provided with an internal deflection plate. This plate shall effectively minimize jetting or spraying of product, with the consequential risk of the generation of static electricity and spillage from an open manhole cover. This requirement applies to tanks being bottom-loaded only.

10.3.8.3 If a risk exists that the front-most bottom valve can be damaged during coupling of a semi-trailer to a truck tractor, effective measures shall be taken to prevent such damage.

10.3.8.4 Bottom valves and associated pipelines fitted at the rear of the tank that contain product during transport shall be provided with adequate protection to minimise risk of damage during a rear end collision.

10.3.9 Internal compartment bonding Applicable to class 3 and 4 products only and products with class 3 and 4 subsidiary risks

10.3.9.1 In order to dissipate static electrical charges that develop during loading, each compartment of a tank shall be fitted with a static electricity central conductor with an electrical connectivity with the tank shell of less than 10 Ω. This may be a cable, chain or fixed rod, connected between the tank roof and tank floor.

10.3.9.2 Each protruding fixture into the compartment, such as ullage markers, overfill sensors or dipstick guides, that could act as dissipating points for static electricity to discharge to from the product surface shall be electrically bonded to this central conductor.

10.3.10 Emergency shut-down device

10.3.10.1 The bottom valve control system shall be fitted with an emergency shut-down device which, when activated, will shut down the complete bottom valve control system and all the compartment bottom valves simultaneously.

10.3.10.2 Such a mechanism shall be located away from the area of standard operation, such as the bottom valve, loading and discharge control panel, as these areas are regarded as the most hazardous during the loading and discharge operation.

10.3.11 Tank-top access

10.3.11.1 Where tank-top access is required, it shall be done by means of a sturdy and safe access ladder, provided with handholds at the top to allow the operator to easily and safely access the tank top.

10.3.11.2 Fixed tank-top access ladders shall be fitted against the tank at an angle of 90° max, measured between the vertical ladder and the ground. The angle shall be measured in the space between the ladder and the tank.

10.3.11.3 Ladder rungs shall be of a non-skid design. The minimum clearance between the inboard edge of any rung and the tank and any fixture immediately inboard of it shall be 150 mm.



10.3.11.4 The tank-top walkway area shall be free from obstructions and care shall be taken to minimize stumbling hazards. The walking area shall incorporate non-skid features.

10.3.12 Product recognition systems

10.3.12.1 All product recognition (cross-over prevention) systems fitted shall comply with EN 14116.

10.3.13 Valve control system

10.3.13.1 Air supply to the valve control system (or any other product-related operating system), shall be such that the main vehicle air system is fully protected and remains intact should a failure occur in any of the control system air lines or at the point from which the air is drawn from the main air system.

10.3.13.2 Operating system air capacity shall be provided through the installation of auxiliary air reservoirs of sufficient capacity to allow for all loading and off-loading operations to take place without having to recharge the air during the operation.

10.3.13.3 The bottom valve operators shall be clearly identified by compartment.

10.3.13.4 The position of the bottom valve (open or closed) shall be clearly indicated by the valve operating mechanism.

10.3.14 Drive-away prevention

10.3.14.1 Vehicles being bottom-loaded or discharged in bulk, shall be equipped with drive-away prevention mechanisms (interlocks) to prevent the vehicle from being loaded or discharged when the park brake has not been applied.

10.3.14.2 Any such mechanism shall be installed in such a way that it will not apply the park brake, but that application of the park brake will allow for effective operation of the mechanism.

10.3.15 Pumping systems Applicable to class 3 and 4 products only and products with class 3 and 4 subsidiary risks.

10.3.15.1 One of the following drive systems for product pumps shall be used: a the engine of the vehicle b) an air or hydraulic motor c) a flameproof electric motor d) an auxiliary compression ignition engine

10.3.15.2 A spark-ignition engine shall not be used.

10.3.15.3 An auxiliary compression ignition engine shall comply with the following requirements: a) The air intake shall be fitted with the applicable flame-arrestor.



b) The drive engine shall be installed away from the loading and discharge areas. It shall be located and screened such that flammable vapours are not drawn to the engine and that any product spillage shall not come into contact with the engine or exhaust system. The location shall be well ventilated and shall not pose any risk of overheating the engine. c) Any electrical system related to the drive engine shall be suitable for the area of operation (zone 1). d) The controls shall be clearly marked and located as far from the loading and discharge points and the pump as possible. e) The engine shall be provided with a clearly identified, easily accessible emergency stop control in the discharge area of the vehicle. This mechanism shall be suitable for the area of operation.

10.3.15.4 The operating speed shall be so controlled that the maximum rating of the pump cannot be exceeded.

10.3.15.5 The type of pump used shall be compatible with the product passing through it and the body shall be made from a non-porous, non-flammable material.

10.3.16 Labelling and signage

10.3.17 The following equipment shall be clearly labelled with regards to their function and operating positions: a) earth lugs and bonding reels b) emergency release c) battery isolator activation devices d) jump start socket (where fitted) e) product pump drive operation

10.3.18 Certificate of approval

10.3.18.1 Upon completion of construction of the vehicle, the manufacturer shall issue a certificate of compliance confirming that the vehicle complies with the requirements of this standard.

10.3.18.2 The certificate of compliance shall be approved by the competent authority for tanks.

10.3.18.3 For a truck tractor, a chassis for a freight carrier, a packaged goods body, a dry goods body that is not governed by specific requirements in this standard and any other vehicle designed to carry removable tanks of any kind, the manufacturer shall issue the certificate and compliance and the competent authority is not required to approve the certificate.

10.3.18.4 The certificate of compliance shall contain at least the following requirements, as applicable: a) Certificate number b) Description of the vehicle a) Name of the vehicle manufacturer d) VIN of the vehicle e) Name of the body/tank manufacturer f) Body/tank manufacturer's serial number g) Vehicle designation in accordance with dangerous goods list (refer section 6 of this standard) h) Year of manufacture of the tank/body i) Approval number of the tank/body j) Tank code in accordance with the dangerous goods list (refer section 6 of this standard) k) Relevant special provisions m) Name and business addresses of the owner and operator n) Confirmation of compliance with this standard o) Confirmation of compliance with relevant national legislation (as applicable) p) Details of any deviation in to the standard allowed by the competent authority as agreed to between the manufacturer and the competent authority



10.3.18.5 A copy of the compliance certificate and all other documentation relating to the type approval and the initial tests done, as relevant, will be retained by the manufacturer for a period of 20 years.

10.3.18.6 The vehicle shall not be registered as a dangerous goods vehicle without the certificate of compliance being presented.

10.3.19 Cargo containment for packaged goods vehicles

10.3.19.1 The cargo containment area of the vehicle shall be suitably equipped for the transportation, stowage and containment of the type of packaged goods to be transported. Body sides at the rear and both sides of the vehicle shall be at least 600 mm high, or the stowage area for dangerous goods shall be in compliance with SADCSTAN [insert number].9 Body sides are only required if transporting gas cylinders or unsecured dangerous goods.

10.3.19.2 The cab shall be separated from the cargo containment area by an effective bulkhead. A factory-fitted rear windscreen may be used in the rear bulkhead of an LDV cab, but shall not be of the sliding type.

10.3.20 Hoses

10.3.20.1 Hoses shall be compatible with the products being transported in all respects.

10.3.20.2 Hoses shall comply with the following standards as listed in table 10.3.20.2

Table 10.3.20.2 Hose standards

Type of hose Applicable standard

Thermoplastic Multilayer ("Composite") hoses for hydrocarbons, solvents and chemicals

EN 13765

Rubber hoses for liquid and gaseous chemicals EN 12115

Aviation fuel hoses EN 1361

LPG hoses EN 1762

Cryogenic flexible hoses EN 12434

10.3.20.3 Hoses shall have working pressure ratings of at least 1.5 times the maximum pressure being experienced during the normal use of the hose.

10.3.20.4 Hoses (not hose installations designed as wet hoses), related couplers and stowage areas, shall be self-draining into areas where drainage of spilt product cannot cause any safety hazard.

9 SADCSTAN or section for load securement for packaged goods to be added. SANS10187-8 applies in South Africa.



10.3.21 Combustion heaters

10.3.21.1 Combustion heaters and their exhaust gas routing shall be so designed, located, and protected or covered as to prevent any unacceptable risk of heating or ignition of the load. This requirement shall be considered to have been complied with if the fuel tank and the exhaust system of the appliance comply with requirements equivalent to those prescribed for fuel tanks and exhaust systems in this standard.

10.3.21.2 Combustion heaters shall be capable of being put out of operation by at least the following methods: a) intentional manual switching off from the driver’s cab b) stopping of the vehicle engine, in which case the heating device may be restarted manually by the driver c) start-up of a feed pump on the vehicle for the dangerous goods carried

10.3.21.3 The combustion heater shall be switched on manually. Programming devices shall not be used.

10.3.22 Additional requirements concerning type EX vehicles

10.3.22.1 Materials to be used in the construction of vehicle bodies No materials likely to form dangerous compounds with the explosive substances carried shall be used in the construction of the body.

10.3.22.2 Combustion heaters Combustion heaters may only be installed on EX vehicles for heating of the driver’s cab or the engine and shall comply with the requirements for combustion heaters in 10.3.21. No combustion heaters or fuel tanks, power sources, combustion air or heating air intakes as well as exhaust tube outlets required for the operation of the combustion heater shall be installed in the load compartment.

10.3.22.3 EX/II vehicles The vehicles shall be designed, constructed and equipped so that the explosives are protected from external hazards and the weather. They shall be either closed or sheeted. Sheeting shall be resistant to tearing and be of impermeable material, not readily flammable1. It shall be tautened so as to cover the loading area on all sides. All openings in the load compartment of closed vehicles shall have lockable, close-fitting doors or rigid covers. The driver’s compartment shall be separated from the load compartment by a continuous wall.

10.3.22.4 EX/III vehicles The vehicles shall be designed, constructed and equipped so that the explosives are protected from external hazards and the weather. These vehicles shall be closed. The driver’s compartment shall be separated from the load compartment by a continuous wall. The loading surface shall be continuous. Load restraint anchorage points may be installed. All joints shall be sealed. All openings shall be capable of being locked. They shall be so constructed and placed as to overlap at the joints. The body shall be made from heat and flame resistant materials with a minimum thickness of 10 mm. Materials classified as Class B-s3-d2 according to standard EN 13501-1:2007 + A1:2009 are deemed to fulfil this requirement. If the material used for the body is metal, the complete inside of the body shall be covered with materials fulfilling the same requirement. In the case of flammability, this requirement will be deemed to be met if, in accordance with the procedure specified in ISO standard 3795:1989 ‘Road vehicles, and tractors and machinery for agriculture and forestry - Determination of burning behaviour of interior materials’, samples of the sheeting have a burn rate not exceeding 100 mm/minute.



10.3.22.5 Engine and load compartment The engine propelling an EX vehicle shall be placed forward of the front wall of the load compartment; it may nevertheless be placed under the load compartment, provided this is done in such a way that any excess heat does not constitute a hazard to the load by raising the temperature on the inner surface of the load compartment above 80 ºC.

10.3.22.6 External heat sources and load compartment The exhaust system of EX vehicles or others parts of these complete or completed vehicles shall be so constructed and situated that any excess heat shall not constitute a hazard to the load by raising the temperature on the inner surface of the load compartment above 80 ºC.

10.3.22.7 Electrical equipment a) The rated voltage of the electrical system shall not exceed 24V. b) Any lighting in the load compartment of EX vehicles shall be on the ceiling and covered, i.e. with no exposed wiring or bulb. c) In the case of Compatibility Group J, the electrical installation shall be at least IP65 (e.g. flame-proof Eex d). d) Any electrical equipment accessible from the inside of the load compartment shall be sufficiently protected from mechanical impact from the inside. e) The electrical installation in the load compartment shall be dust-protected (at least IP54 or equivalent) or, in the case of Compatibility Group J, at least IP65 (e.g. flame-proof Eex d).

10.3.23 Additional requirements concerning the construction of the bodies of complete or completed vehicles intended for the carriage of dangerous goods in packages (other than EX vehicles)

10.3.23.1 There shall be no design features, structures or equipment inside the load-carrying compartment that will pose a risk to the cargo.

10.3.23.2 Vehicles with open, flat load beds shall be fitted with sides of adequate height to prevent goods from tipping or spilling.

10.3.24 Additional requirements concerning the construction of the bodies of complete or completed vehicles intended for the carriage of dangerous solids in bulk

Reserved for future use

10.3.25 Additional requirements concerning complete or completed vehicles intended for the carriage of temperature controlled self-reactive substances of division 4.1 and organic peroxides of division 5.2

10.3.25.1 The vehicle shall be so equipped with regard to its insulation and means of refrigeration that the control temperature is not exceeded. The overall heat transfer coefficient shall not exceed 0.4 W/(m2 • K).

10.3.25.2 The vehicle shall be so equipped that vapours from the substances or from the coolant carried cannot penetrate the driver’s cab.

10.3.25.3 A suitable device shall be provided that enables the temperature prevailing in the loading space to be determined from the cab at any time.

10.3.25.4 The loading space shall be provided with vents or ventilating valves if there is any risk of dangerous excess pressure arising in it. Care shall be taken, when relevant, to ensure that refrigeration is not impaired by the vents or ventilating valves.



10.3.25.5 The refrigerant shall not be flammable.

10.3.25.6 The refrigerating appliance of a mechanically refrigerated vehicle shall be capable of operating independently of the engine used to propel the vehicle.

10.3.26 Additional requirements concerning tank-vehicles, battery-vehicles and complete or completed vehicles used for the carriage of dangerous goods in demountable tanks with a capacity greater than 1 m3 or in tank-containers, portable tanks or MECGs of a capacity greater than 3 m3 (EX, FL, OX and AT vehicles)

10.3.26.1 Once the demountable tank has been attached to the carrier vehicle, the entire vehicle shall meet the requirements for road tank vehicles in accordance with the relevant sections of this standard.

10.3.26.2 Stability of road tank vehicles The overall width of the ground-level bearing surface (distance between the outer points of contact with the ground of the right-hand tyre and the left-hand tyre of the same axle) shall be at least 106 % of the height of the centre of gravity of the laden vehicle. In an articulated vehicle, the mass on the axles of the load-carrying unit of the laden semi-trailer shall not exceed 60 % of the nominal total laden mass of the complete articulated vehicle.

10.3.26.3 Rear protection of road tank vehicles a) Road tank vehicles of GVM exceeding 3 500 kg shall be fitted with rear underrun protection devices that comply with the requirements of ECE R58. b) In order to protect the rear end of a road tank vehicle, the rear end of the vehicle chassis of a fixed road tank vehicle or the rear axle unit subframe of a trailer or a semi-trailer shall extend a minimum of 300 mm beyond the rear end of the tank. c) Vehicles with a tilting shell for the carriage of powdery or granular substances and a vacuum- operated waste tank with a tilting shell with rear discharge do not require a bumper if the rear fittings of the shell are provided with a means of protection which protects the shell in the same way as a bumper.

10.3.26.4 Fastenings Fastenings shall be designed to withstand static and dynamic stresses in normal conditions of carriage, and minimum stresses as defined in the relevant sections governing the construction of tanks.

10.3.26.5 Earthing of FL vehicles Tanks made of metal or of fibre-reinforced plastics material of FL tank-vehicles and battery elements of FL battery-vehicles shall be linked to the chassis by means of at least one good electrical connection. Any metal contact capable of causing electrochemical corrosion shall be avoided.

10.3.27 Additional requirements concerning complete and completed MEMUs

10.3.27.1 Earthing of MEMUs Tanks, bulk containers and special compartments for packages of explosives made of metal or of fibre-reinforced plastics material shall be linked to the chassis by means of at least one good electrical connection. Any metal contact capable of causing electro-chemical corrosion or reacting with the dangerous goods carried in the tanks and bulk containers shall be avoided.

10.3.27.2 Stability of MEMUs The overall width of the ground-level bearing surface (distance between the outer points of contact with the ground of the right-hand tyre and the left-hand tyre of the same axle) shall be at least equal to 90% of the height of the centre of gravity of the laden vehicle. In an articulated vehicle the mass on the axles of the load-



carrying unit of the laden semi-trailer shall not exceed 60% of the nominal total laden mass of the complete articulated vehicle.

10.3.27.3 Rear protection of MEMUs A bumper sufficiently resistant to rear impact shall be fitted over the full width of the tank at the rear of the vehicle. There shall be a clearance of at least 100 mm between the rear wall of the tank and the rear of the bumper (this clearance being measured from the rearmost point of the tank wall or from protecting fittings or accessories in contact with the substance being carried). Vehicles with a tilting shell with rear discharge do not require a bumper if the rear fittings of the shell are provided with a means of protection which protects the shell in the same way as a bumper. NOTE: This provision does not apply to MEMUs where the tanks are protected adequately against rear impact by other means, e.g. machinery or piping not containing dangerous goods.

10.3.27.4 Combustion heaters No fuel tanks, power sources, combustion air or heating air intakes as well as exhaust tube outlets required for the operation of the combustion heater shall be installed in the load compartments containing tanks. It shall be ensured that the heating air outlet cannot be blocked. The temperature to which any equipment is heated shall not exceed 50 ºC. Heating devices installed inside the compartments shall be designed so as to prevent the ignition of any explosive atmosphere under operating conditions.

10.3.27.5 Additional safety requirements MEMUs shall be equipped with automatic fire extinguisher systems for the engine compartment. Protection of the load by metal thermal shields against tyre fire shall be provided.

10.3.27.6 Additional security requirements Process equipment and special compartments in MEMUs shall be fitted with locks.

10.4 Requirements for the construction, Type approval, inspections and tests, and marking of fixed tanks (tank-vehicles), demountable tanks and tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple element gas containers (MECG's)

This section applies to the design and construction of tanks, as part of a tank vehicle or on its own. It does not include requirements for portable tanks which are contained in section 10.10. See the definition of tank and tank vehicle.

10.4.1 Construction principles

10.4.1.1 Shells, their attachments, and their service and structural equipment shall be designed to withstand without loss of contents, other than quantities of gas escaping through degassing vents: a) the static and dynamic stresses in normal conditions of transport in accordance with 10.4.1.2 and 10.4.3.1 b) and the prescribed minimum stresses in accordance with 10.4.3.4

10.4.1.2 Tanks and their fastenings shall be capable of absorbing, under the maximum permissible load, the following forces exerted: a) in the direction of travel: twice the total mass, b) at right angles to the direction of travel: the total mass, c) vertically upwards: the total mass, and d) vertically downwards: twice the total mass.



10.4.1.3 The walls of the shells shall have at least the thickness specified in 10.4.4.1 to 10.4.4.5.(inclusive).

10.4.1.4 The shell thickness shall be determined taking into account maximum filling and working temperatures, but the minimum requirements of 10.4.1.5 to 10.4.6.5 (inclusive) shall be met.

10.4.1.5 For some dangerous substances, additional protection might be required in the form of additional shell thickness (increased calculation pressure) in accordance with the special tank provisions of table A.1.

10.4.1.6 Welds shall be made to afford the fullest protection, and shall comply with the requirements of 10.4.5.

10.4.1.7 Effective measures shall be taken to protect the shells against risk of deformation caused by negative internal pressure.

10.4.2 Materials for construction of shells

10.4.2.1 Shells shall be made of acceptable metallic materials which, unless other temperature ranges are prescribed, are resistant to brittle fracture and to stress corrosion cracking between −20°C and +50°C.

10.4.2.2 The materials of shells or of their protective linings that are in contact with the contents shall not contain substances that are likely to react dangerously with the contents to form dangerous compounds, or are likely to weaken the material substantially. If contact between the substance being transported and the material used for the construction of the shell results in a progressive decrease in the shell thickness, this thickness shall be increased by an appropriate amount for the lifespan of the shell. The additional thickness to allow for corrosion shall not be taken into consideration when the shell thickness is calculated.

10.4.2.3 For welded shells, only materials capable of acceptable weldability whose adequate impact strength at an ambient temperature of −20°C can be guaranteed, particularly in the weld seams and adjacent zones, shall be used. If fine-grained steel is used, the guaranteed value of the yield stress Re shall not exceed 460 N/mm2 and the guaranteed value of the upper limit of tensile strength Rm shall not exceed 725 N/mm2, in accordance with the specifications of the material.

10.4.2.4 Steels which have an Re/Rm ratio exceeding 0.85 shall not be used in the construction of welded tanks. Re is the apparent yield stress, in N/mm2, for steels with a clearly defined yield point, or guaranteed 0,2 % proof stress for steels with no clearly defined yield point (1 % for austenitic steels). Rm is the tensile strength, in N/mm2.

10.4.2.5 For steel, the elongation at fracture, as a percentage, shall be at least

where - Rmd is the determined tensile strength, N/mm2 but in any case for fine-grained steels it shall be at least 16 % and for other steels at least 20 %. For aluminium alloys, the elongation at fracture shall be at least 12 %. In the case of sheet metal, the axis of the tensile test piece shall be at right angles to the direction of rolling. The permanent elongation at fracture shall be measured on test pieces of circular cross section in which the



gauge length is equal to five times the diameter. If test pieces of rectangular section are used, the gauge length shall be calculated by the formula:

where - I is is the gauge length, in mm - F0 is the initial area of cross section of the test piece, in mm2

10.4.3 Calculation of shell thickness

10.4.3.1 Stress allowance

The pressure on which the shell thickness is based shall not be less than the calculation pressure, but the stresses referred to 10.4.1.1 shall also be taken into account, and, if necessary, the following stresses: a) In the case of vehicles in which the tank constitutes a stressed self-supporting member, the shell shall be designed to withstand the stresses thus imposed in addition to the stresses from other sources. b) Under these stresses, the stress at the most severely stressed point of the shell and its fastenings

shall not exceed the value of σ given in 10.4.3.4.

10.4.3.2 Vapour pressure allowance

10.4.3.2.1 When "G" appears in the tank code, the requirements in 10.4.3.2.2 to 10.4.3.2.5 (inclusive) shall apply.

10.4.3.2.2 Gravity-discharge shells intended for the transport of substances with a vapour pressure not exceeding 110 kPa absolute pressure at 50 °C shall be designed for a calculation pressure of twice the static pressure of the substance to be transported, but not less than twice the static pressure of water.

10.4.3.2.3 Pressure-filled or pressure-discharge shells intended for the transport of substances with a vapour pressure not exceeding 110 kPa absolute pressure at 50 °C shall be designed for a calculation pressure equal to 1.3 times the filling or discharge pressure. When the numerical value of the minimum calculation pressure is given in the tank code (see column 12 of table A.1), the shell shall be designed for this pressure, which shall not be less than 1.3 times the filling or discharge pressure. The minimum requirements in 10.4.3.2.4 and 10.4.3.2.5 shall apply in these cases.

10.4.3.2.4 Shells intended for the transport of substances with a vapour pressure of more than 110 kPa but not more than 175 kPa absolute pressure at 50 °C shall, whatever their filling or discharge system, be designed for a calculation pressure of at least 150 kPa gauge pressure or 1.3 times the filling pressure or discharge pressure, whichever is the higher.

10.4.3.2.5 Shells intended for the transport of substances with a vapour pressure of more than 175 kPa absolute pressure at 50 °C shall, whatever their filling or discharge system, be designed for a calculation pressure equal to 1.3 times the filling or discharge pressure but not less than 400 kPa gauge pressure.



10.4.3.3 Material dependant allowance

At the test pressure, the stress, σ, at the most severely stressed point of the shell shall not exceed the

material-dependent limits specified in 10.4.3.4. Allowance shall be made for any weakening due to welds.

10.4.3.4 Strengths of materials of construction

For metals and alloys, the stress σ at the test pressure shall be lower than the smaller of the values given by

the following formula: σ < 0,75 Re or σ < 0,5 Rm where - Re is the apparent yield stress, in N/mm2, for steels with a clearly defined yield point, or guaranteed 0,2 % proof stress for steels with no clearly defined yield point (1 % for austenitic steels); - Rm is the tensile strength, in N/mm2. The values of Re and Rm to be used shall be specified minimum values according to material standards. When austenitic steels are used, the specified minimum values according to the material standards may be exceeded by up to 15 % if these higher values are attested in the inspection certificate.

10.4.4 Minimum shell thickness

10.4.4.1 General

Subject to the provisions of 10.4.4.4, the shell thickness shall not be less than the value determined by the following formula:

where - e is the minimum shell thickness, in mm - PT is the test pressure, in MPa - D is the internal diameter of the shell, in mm

- σ is the permissible stress in accordance with 5.4.4, in N/mm2;

- λ is a coefficient of value between 0,8 and 1,0, allowing for any weakening due to welds, and linked to the inspection methods in accordance with 5.6. The thickness shall in no case be less than that defined in 5.5.2 to 5.5.5 inclusive.



10.4.4.2 Shells of circular cross section

10.4.4.2.1 Subject to the provisions of 10.4.4.4, shells of circular cross section not more than 1 800 mm in diameter shall not be less than 5 mm thick if of mild steel (see Definitions, section 3), or shall be of equivalent thickness (10.4.4.2.4) if of another metal.

10.4.4.2.2 When the diameter is more than 1.8 m, this thickness shall be increased to 6 mm except in the case of shells intended for the transport of powdery or granular substances, if the shell is of mild steel, or to an equivalent thickness, if of another metal.

10.4.4.2.3 When tanks are constructed from steels with a higher strength than mild steel and are thermally insulated, the minimum shell thickness for shells of circular cross section shall not be less than 5 mm.

10.4.4.2.4 The equivalent thickness shall mean the thickness obtained by the following formula:

where - e is the minimum shell thickness, in mm, of the metal to be used - e0 is the minimum shell thickness, in mm, of mild steel - Rm1 is the minimum tensile strength, in N/mm2, of the metal to be used - A1 is the minimum elongation at fracture, as a percentage, of the metal to be used under stress

10.4.4.3 Shells not of circular cross section

For shells not of circular cross section, for example shells of box-shaped or elliptical cross section, the indicated diameter shall correspond to that calculated on the basis of a circular cross section of the same area. For such shapes of cross section, the radius of convexity of the shell wall shall not exceed 2 000 mm at the sides or 3 000 mm at the top and bottom.

10.4.4.4 Allowance for tanks and shells with damage protection

10.4.4.4.1 Where protection of the tank against damage through lateral impact or overturning is provided in accordance with 10.4.4.5, the minimum thickness may be reduced in proportion to the protection provided. However, the said thickness shall not be less than 3 mm in the case of mild steel, or less than an equivalent thickness in the case of other materials, for shells not more than 1.8 m in diameter. For shells with a diameter exceeding 1800 mm, the minimum thickness shall be 4 mm in the case of mild steel and an equivalent thickness in the case of other materials.

10.4.4.4.2 The thickness of shells with protection against damage in accordance with 10.4.4.5.2 and 10.4.4.5. shall not be less than the values given in table 10.4.1.



Table 10.4.1 Minimum shell thickness

1 2 3

Metal Shell diameter =< 1800mmmm

Shell diameter > 1800mmmm

Stainless steel-Austenitic 2,5 3

Other steels 3 4

Aluminium alloys 4 5

Pure aluminium, 99,8% 6 8

10.4.4.5 Requirements for damage protection

10.4.4.5.1 General

Damage protection shall be provided in accordance with the requirements described in 10.4.4.5.2 and 10.4.4.5.3.

10.4.4.5.2 Tanks transporting powdery or granular substances

For tanks intended for the transport of powdery or granular substances, the manufacturer shall give written and verifiable certification that adequate damage protection has been provided for the substances for which the tank was designed.

10.4.4.5.3 Tanks transporting other substances

a) General For tanks intended for the transport of other substances, damage protection is deemed to exist when the relevant requirements in 10.4.4.5.3 b) to g) (inclusive) have been met. b) Shells with circular or elliptical cross sections A shell with a circular or an elliptical cross section with a maximum radius of curvature of 2 000 mm shall be equipped with strengthening members comprising partitions, surge plates or external or internal rings, so placed that at least one of the following conditions is met: i) the distance between two adjacent strengthening elements is not more than 1 750 mm; and ii) the volume contained between two partitions or surge plates does not exceed 7 500 L. c) Shells of form other than circular or elliptical cross section Shells of form other than that described in 10.4.4.5.3 b) especially box-shaped shells, shall be provided, all around the midpoint of their vertical height and over at least 30 % of their height, with a protection designed in such a way as to offer specific resilience at least equal to that of a shell



constructed in mild steel of a thickness of 5 mm for a shell diameter not exceeding 1 800 mm or 6 mm for a shell diameter exceeding 1800 mm. The protection shall be applied in a durable manner to the outside of the shell. This requirement shall be considered to have been met without further proof of the specific resilience when the protection consists of the welding of a plate of the same material as the shell to the area to be strengthened, provided that the minimum wall thickness is in accordance with 10.4.4.2. This protection is dependent upon the possible stresses exerted on mild steel shells in the event of an accident, where the ends and walls have a thickness of at least 5 mm for a diameter not exceeding 1800 mm or of at least 6 mm for a diameter exceeding 1800 mm. If another metal is used, the equivalent thickness in accordance with the formula in 10.4.4.2.4 shall apply. d) Vertical cross section of a ring The vertical cross section of a ring, with the associated coupling, shall have a section modulus of at least 10 cm3. e) External rings An external ring shall not have a projecting edge with a radius of less than 2.5 mm. f) Partitions and surge plates i) Partitions and surge plates shall comply with the requirements of 10.4.4.6. ii) The thickness of each partition and surge plate shall in no case be less than that of the shell. g) Tanks with double walls i) For tanks made with double walls, where the space between the walls is devoid of air, the aggregate thickness of the outer shell wall shall correspond to the wall thickness specified in 10.4.4.2, and the thickness of the wall of the shell itself shall correspond to the minimum thickness specified in 10.4.4.4. ii) For tanks made with double walls with an intermediate layer of solid materials at least 50 mm thick, the outer wall shall have a thickness of at least 0.5 mm of mild steel or of at least 2 mm of a plastics material reinforced with glass fibre. Solid foam with an impact absorption capacity similar to that of, for example, polyurethane foam, may be used as the intermediate layer of solid material.

10.4.4.6 Partitions and surge plates

Partitions and surge plates shall be dished, with a depth of dish of at least 10 cm, or shall be corrugated, profiled or otherwise reinforced to give equivalent strength. The area of the surge plate shall be at least 80 % of the cross-sectional area of the tank in which it is fitted.

10.4.5 Welding

10.4.5.1 Welding shall be performed by skilled welders using a welding process whose effectiveness, including any required heat treatment, has been demonstrated by test. Non-destructive tests shall be carried out by radiography or by ultrasound, and shall confirm that the quality of the welding is appropriate to the stresses.

The following tests shall be carried out in accordance with the value of the coefficient λ used in determining the thickness of the shell (see 10.4.4.1).

a) When λ = 0,8, the weld beads shall, as far as possible, be inspected visually on both faces and shall be subjected to a non-destructive spot check with particular attention being paid to connections.



b) When λ = 0,9, all longitudinal beads throughout their length, all connections, 25 % of circular beads and welds for the assembly of large diameter items of equipment shall be subjected to non- destructive spot checks. Beads shall be visually checked on both sides as far as possible.

c) When λ = 1,0, all beads shall be subjected to non-destructive spot checks and shall, as far as possible, be inspected visually on both sides. A weld test piece shall be taken.

10.4.6 Additional construction requirements

10.4.6.1 The protective lining shall be so designed that its leakproofness remains intact, whatever deformation is likely to occur in normal conditions of transport.

10.4.6.2 The thermal insulation shall be so designed as not to hinder access to, or the operation of, filling and discharge devices and safety valves.

10.4.6.3 If shells intended for the transport of flammable liquids with a flash point of not more than 60.5 °C are fitted with non-metallic protective linings (inner layers), the shells and protective linings shall be so designed that there is no danger of ignition from electrostatic charges.

10.4.6.4 Shells intended for the transport of liquids with a flash point of not more than 60,5 °C or for the transport of flammable gases, or of carbon (UN No. 1361, packing group II), shall be linked to the chassis by means of at least one good electrical connection. Any metal contact capable of causing electrochemical corrosion shall be

avoided. Tanks shall be provided with at least one earth fitting marked with the symbol " ", capable of being electrically connected.

10.4.6.5 The fittings and accessories mounted on the upper part of the tank shall be protected against damage caused by overturning. This protection may take the form of strengthening rings, protective canopies, or transverse or longitudinal members so shaped that protection is given.

10.4.7 Items of equipment

10.4.7.1 General Items of equipment shall comply with the requirements contained in this section and, where relevant, to the list of standards contained in Annexure H.

10.4.7.2 Service and structural equipment

10.4.7.2.1 Acceptable non-metallic materials may be used to manufacture service and structural equipment.

10.4.7.2.2 The items of equipment shall be so arranged as to be protected against the risk of being wrenched off or damaged during transport and handling. They shall exhibit an acceptable degree of safety comparable to that of the shells themselves, and shall in particular: a) be compatible with the substances being transported, and b) meet the requirements of 10.4.1.1.

10.4.7.2.3 As many parts as possible shall be served by the smallest possible number of openings in the shell.

10.4.7.2.4 The leakproofness of the service equipment, including the closure (cover) of the inspection openings, shall be ensured even in the event of overturning of the tank, taking into account the forces generated by an impact



such as acceleration and dynamic pressure. Limited release of the tank contents due to a pressure peak during impact is however allowed.

10.4.7.2.5 The gaskets shall be made of a material compatible with the substance being transported and shall be replaced as soon as their effectiveness is impaired, for example as a result of ageing.

10.4.7.2.6 Gaskets that ensure leakproofness of fittings that require manipulation during normal use of tanks shall be so designed and arranged that manipulation of the fittings that incorporate them does not damage them.

10.4.7.3 Openings and closures

10.4.7.3.1 Each bottom-filling or bottom-discharge opening in tanks with the 3rd character in the tank code being an "A" shall be equipped with at least two mutually independent closures, mounted in series, comprising: a) an external stop-valve with piping made of malleable metal material, and b) a closing device at the end of each pipe, which may be a screw-threaded plug, a blank flange, a self-sealing dust cover, or an equivalent device.

10.4.7.3.2 Each bottom-filling or bottom-discharge opening in tanks with the 3rd character in the tank code being "B" shall be equipped with at least three closures, each of which functioning independently, mounted in series, comprising: a) an internal stop-valve (i.e. a stop-valve mounted inside the shell, or in a welded flange or companion flange), b) an external stop-valve or an equivalent device, one at the end of each pipe, and c) a closing device at the end of each pipe, which may be a screw-threaded plug, a blank flange, a self-sealing dust cover, or an equivalent device.

10.4.7.3.3 In the case of tanks intended for the transport of crystallizable or highly viscous substances and shells fitted with an ebonite or a thermoplastics coating, the internal stop-valve may be replaced by an external stop-valve provided with additional protection.

10.4.7.3.4 The internal stop-valve shall be operable from above or below. Its setting, open or closed, shall, as far as possible, in each case be capable of being verified from the ground. Internal stop-valve control devices shall be so designed as to prevent any unintended opening through impact or an inadvertent act.

10.4.7.3.5 The internal shut-off device shall continue to be effective in the event of damage to the external control device.

10.4.7.3.6 In order to avoid any loss of contents in the event of damage to the external fittings (pipes and lateral shut-off devices), the internal stop-valve and its seating shall be protected against the danger of being wrenched off by external stresses or shall be so designed as to resist them. The filling and discharge devices, including langes or threaded plugs and protective caps (if any), shall be capable of being secured against any unintended opening.

10.4.7.3.6 The position or direction of closure of shut-off devices (or both) shall be clearly apparent.

10.4.7.3.7 All openings of tanks with the 3rd character in the tank code being a "C" or "D shall be situated above the surface level of the liquid. These tanks shall have no pipes or pipe connections below the surface level of the liquid. Cleaning openings (fist-holes) are however permitted in the lower part of the shell of tanks referred to by a tank code including the letter "C". Such openings shall be capable of being sealed by a flange so closeable as to be leakproof.

10.4.7.4 Provision for negative internal pressure

10.4.7.4.1 Tanks that are not hermetically closed may be fitted with vacuum valves to avoid an unacceptable negative internal pressure; these vacuum-relief valves shall be set to relieve at a vacuum setting not greater than the



vacuum pressure for which the tank has been designed. Hermetically closed tanks may not be fitted with vacuum valves, unless otherwise prescribed special provision.

10.4.7.5 Provision for inspection openings

10.4.7.5.1 The shell or each of its compartments shall be provided with an opening large enough to permit internal inspection.

10.4.7.6 Venting systems for vapour pressure

10.4.7.6.1 Venting system for vapour pressure < 110 kPa Each tank intended for the transport of liquids with a vapour pressure not exceeding 110 kPa (absolute) at 50 °C shall have a venting system and a safety device to prevent the contents from spilling out if the tank overturns; otherwise the tank shall comply with 10.4.7.6.2 or 10.4.7.6.3.

10.4.7.6.2 Safety valves for vapour pressure 110 kPa to 175 kPa Each tank intended for the transport of liquids with a vapour pressure exceeding 110 kPa (absolute) but not exceeding 175 kPa (absolute) at 50 °C shall have a safety valve set at at least 150 kPa (gauge pressure) and which shall be fully open at a pressure not exceeding the test pressure; otherwise the tank shall comply with 10.4.7.6.3.

10.4.7.6.3 Safety valves for vapour pressure greater than 175 kPa Each tank intended for the transport of liquids with a vapour pressure exceeding 175 kPa (absolute) but not exceeding 300 kPa (absolute) at 50 °C shall have a safety valve set at at least 300 kPa (gauge pressure) and which shall be fully open at a pressure not exceeding the test pressure; otherwise the tank shall be hermetically closed.

10.4.7.7 Primary-relief valve pressure

10.4.7.7.1 The set pressure of each primary-relief valve shall be not less than 120 % of the MWP and not more than 132 % of the MWP. The valve shall reclose at at least 108 % of the MWP and shall remain closed at lower pressures.

10.4.7.8 Material for covers and closures

10.4.7.8.1 Movable parts such as covers, closures, etc., which are likely to come into frictional or percussive contact with aluminium shells intended for the transport of flammable liquids with a flash point not exceeding 61 °C or for the transport of flammable gases shall not be made of unprotected corrodible steel

10.4.8 Tank plating



10.4.8.1 Tank data plate Except as provided for below, every tank shall be fitted with a durable, corrosion-resistant metal plate permanently attached to the tank in a place readily accessible for inspection. At least the following particulars shall be legibly and indelibly marked on the plate by stamping or by any similar method: a) approval number b) manufacturer’s name or mark c manufacturer’s serial number d) year of manufacture e) test pressure on the shell as a whole and the test pressure by compartment in kPa or MPa (as appropriate) where the pressure by compartment is lower than the pressure on the shell (gauge pressures) f) capacity and, in the case of multiple-compartment/element shells, the capacity of each compartment/ element followed by the symbol "S" when the shells or the compartments of more than 7 500 litres are divided by surge plates into sections of not more than 7 500 litres capacity g) design temperature, if above +50 °C or below −20 °C h) date (month and year) of initial test i) stamp of the competent authority who carried out the tests j) material of the shell and reference to material standards k) where relevant the material of the protective lining l) maximum working pressure for pressure-filled or pressure-discharge tanks m) reference to compliance with this standard n) four character tank code o) name of the operator p) any special provisions, indicated by the code for the provision (refer section 6 of this standard) NOTE These particulars may be engraved directly on the wall of the shell itself, if the walls are so reinforced that the strength of the shell is not impaired

10.4.8.2 Capacity and loading plates Durable and clearly legible plates will be fitted in appropriate, easily accessible positions. Indicating: a) for tanks transporting liquids, the maximum load allowed in litres for each product that may be loaded into each compartment In the case where a range of products can be loaded, only the products of highest and lowest densities may be indicated on the plates. b) maximum number of compartments that may be loaded simultaneously (i.e., maximum number of loading arms that may be coupled simultaneously). This is especially important for tanks fitted with vapour recovery systems and a separate loading point for each compartment as it has a bearing on the required venting capacity. c) for tanks fitted with a separate loading point per compartment, a compartment identification plate per loading point. d) for tanks fitted with branched one-to-multiple manifolds and a manually operated isolating valve per compartment line, a compartment identification plate per isolating valve. e) description of the type of overfill sensors fitted to the vehicle. f) overfill sensor setting dimensions measured from the overfill sensor reference dimension.

10.4.8.3 Plates may be combined into one. Compartment loading plates and compartment identification plates (for loading points and isolating valves) shall remain separate.

10.4.9 Approval of tanks

10.4.9.1 In the event that: a) the requirements of the 4-character tank code requirements cannot be met b) no tank code is shown in column 15 of the dangerous goods list in annexure A c) no vehicle type is shown in column 14 of the dangerous goods list in annexure A a suitable tank design will be agreed upon between the competent authority and the manufacturer and this will be indicated as such on the type approval documentation and the compliance certificate.



10.4.9.2 Type approval - General

10.4.9.2.1 Type approvals authorise the manufacture of pressure receptacles, tanks, battery-vehicles or MEGCs within the period of validity of that approval. Validity of the type approval could be reduced due to the introduction of revised standards or requirements.

10.4.9.2.2 The request for type approval will be lodged with a single competent authority in the member state of residence of the manufacturing facility.

10.4.9.2.3 The application shall include: a) name and address of the applicant b) for conformity assessment where the applicant is not the manufacturer, the name and address of the manufacturer c) written declaration that the same application has not been lodged with any other competent authority, its delegate or inspection body d) relevant technical documentation specified in 10.4.9.3.3 e) statement allowing the competent authority, its delegate or inspection body access for inspection purposes to the locations of manufacture, inspection, testing and storage and providing it with all necessary information

10.4.9.2.4 Where the applicant can demonstrate to the satisfaction of the competent authority or its delegated inspection body conformity with the requirements of this standard the applicant may establish an in-house inspection service which may perform part or all of the inspections and tests required.

10.4.9.2.5 Design type approval certificates and certificates of conformity - including the technical documentation - shall be retained by the manufacturer or by the applicant for the type approval, if he is not the manufacturer, and by the inspection body, who issued the certificate, for a period of at least 20 years starting from the last date of production of products of the same type.

10.4.9.2.6 When a manufacturer or owner intends to cease operation, he shall send the documentation to the competent authority. The competent authority shall then retain the documentation for the rest of the period specified in 10.4.9.2.4.

10.4.9.3 Type approval - Process

10.4.9.3.1 The manufacturer will design the tank by performing all necessary calculations in order to ensure that the tank and equipment will conform to this standard.

10.4.9.3.2 The manufacturer shall ensure that all compliance certification for equipment (for example valves, manhole covers and vapour vents) subject to compliance with this standard are obtained from the manufacturers of such equipment.

10.4.9.3.3 The applicant shall submit the following documents to the competent authority for approval: (a) list of standards used for the design and manufacture (b) description of the type including all variations (c) instructions according to the relevant column of the dangerous goods list or a list of dangerous goods to be transported for dedicated products (d) general assembly drawing or drawings (e) detailed drawings, including the dimensions used for the calculations, of the product, the service equipment, the structural equipment, the marking and/or the labelling necessary to verify the conformity (f calculation notes, results and conclusions (g) list of the service equipment with the relevant technical data and information on the safety devices including the calculation of the relief capacity if relevant



(h) list of material requested in the standard for manufacture used for every part, sub-part, lining, service and structural equipment and the corresponding material specifications or the corresponding declaration of conformity to this standard (i approved qualification of permanent joining process (j) description of the heat treatment process(es) (k) procedures, descriptions and records of all relevant tests listed in the this standard and relevant related standards for the type approval and for the manufacture

10.4.9.3.4 The competent authority shall: (a) examine the technical documentation specified in 10.4.9.3.3 to verify that the design is in accordance with the relevant provisions of this standard (b) perform the examinations and witness the tests specified in this standard to determine that the provisions have been applied and fulfilled, and the procedures adopted by the manufacturer meet the requirements (c) check the certificate(s) issued by the materials manufacturer(s) against the relevant provisions of this standard (d) as applicable, approve the procedures for the permanent joining of parts or check that they have been previously approved, and verify that the staff undertaking the permanent joining of parts and the non-destructive tests are qualified or approved (e) agree with the applicant the location and testing facilities where the examinations and necessary tests are to be carried out The competent authority will issue a type examination report.

10.4.9.3.5 Where the type satisfies all applicable provisions, the competent authority, its delegate or the inspection body, shall issue a type approval certificate to the applicant. This certificate shall contain: (a) name and address of the issuer (b) name and address of the manufacturer and of the applicant when the applicant is not the manufacturer (c) reference to the version of this standard and related standards used for the type examination (d) any requirements resulting from the examination (e) necessary data for identification of the type and variation, as defined by the relevant standard (f) reference to the type examination report(s) (g) maximum period of validity of the type approval A list of the relevant parts of the technical documentation shall be annexed to the certificate.

10.4.9.3.6 The type approval shall be valid for a maximum of ten years. If within that period the relevant technical requirements of this standard (including referenced standards) have changed so that the approved type is no longer in conformity with them, the relevant body which issued the type approval shall withdraw it and inform the holder of the type approval.

10.4.9.3.7 In the case of a modification of a pressure receptacle, tank, battery-vehicle or MEGC with a valid, expired or withdrawn type approval, the testing, inspection and approval are limited to the parts of the pressure receptacle, tank, battery-vehicle or MEGC that have been modified. The modification shall meet the provisions of this standard applicable at the time of the modification. For all parts of the pressure receptacle, tank, battery-vehicle or MEGC not affected by the modification, the documentation of the initial type approval remains valid. A modification may apply to one or more pressure receptacles, tanks, battery-vehicles or MEGCs covered by a type approval. A certificate approving the modification shall be issued to the applicant by the competent authority or by a body designated by this authority. For tanks, battery-vehicles or MEGCs, a copy shall be kept as part of the tank record. Each application for an approval certificate for a modification shall be lodged by the applicant with a single competent authority or body designated by this authority.

10.4.9.3.8 Upon expiry of the type approval certificate, an application for extension may be lodged in accordance with 10.4.9.3.3, with the competent authority. The competent authority may extend the validity after review in accordance with 10.4.9.3.4.



10.4.10 Inspections and test

10.4.10.1 Shells and their equipment shall either together or separately undergo an initial inspection before being put into service.

10.4.10.2 This inspection shall include the following: a) check for conformity to the approved type b) check of the design characteristics c examination of the internal and external conditions d) hydraulic pressure test on the tank shell at the test pressure indicated on the tank data plate e) leakproofness test and a check of satisfactory operation of the equipment The hydraulic pressure test depends on the calculation pressure and shall be at least equal to the pressure indicated below:

Table 10.4.2 Hydraulic test pressure requirements

Calculation pressure (bar) Minimum hydraulic test pressure (bar)

G Minimum calculation pressure according to the general requirements of this section

1.5 1.5

2.65 2.65

4 4

10 4

15 4

21 4

10.4.10.3 The hydraulic pressure test shall be carried out on the shell as a whole at the test pressure, and separately on each compartment of compartmented shells at a pressure of at least 1.3 times the maximum working pressure.

10.4.10.4 The hydraulic pressure test shall be carried out before the installation of such thermal equipment as might be necessary. If the shells and their equipment are tested separately, they shall be jointly subjected to a leakproofness test after assembly.

10.4.10.5 If the shells and their equipment are tested separately, they shall be jointly subjected to a leakproofness test after assembly as described below. The leakproofness test shall be carried out separately on each compartment of compartmented shells. For this purpose the tank shall be subjected to an effective internal pressure at least equal to the maximum working pressure. For tanks intended for the carriage of liquids or solids in the granular or powdery state, when a gas is used for the leakproofness test it shall be carried out at a pressure at least equal to 25 % of the maximum working pressure. In all cases, it shall not be less than 20 kPa (0.2 bar) (gauge pressure). For tanks equipped with venting systems and a safety device to prevent the contents spilling out if the tank overturns, the pressure test shall be equal to the static pressure of the filling substance.



10.4.10.6 With the agreement of the competent authority, the hydraulic pressure test may be replaced by a pressure test using another liquid or gas, where such an operation does not present any danger.

10.5 Additional special requirements – Class 2

10.5.1 Construction of shells

10.5.1.1 Shells intended for the transport of compressed or liquefied gases or gases dissolved under pressure shall be made of steel. In the case of weldless shells, notwithstanding the requirements in section 10.4, elongation at fracture of at least 14 % and also a stress (σ) lower than or equal to the following limits, given according to the material, is allowed: a) when the ratio Re/Rm (of the minimum guaranteed characteristics after heat treatment) is higher than 0.66 without exceeding 0.85: σ < 0.75 Re; and b) when the ratio Re/Rm (of the minimum guaranteed characteristics after heat treatment) is higher than 0.85: σ < 0.5 Rm

10.5.1.2 The requirements of clause 10.6 shall apply to the materials and construction of welded shells.

10.5.2 Construction of battery vehicles

10.5.2.1 Tanks as elements of battery vehicles shall be constructed in accordance with 10.4.1 and 10.5.1

10.5.2.2 Elements and their fastenings shall be capable of absorbing, under the maximum permissible load, the forces in accordance with 5.2.2. Under each force, the stress at the most severely stressed point of the element and its fastenings shall not exceed the allowable values for cylinders, tubes, pressure drums and bundles of cylinders, and the value σ as specified in 10.4.3.4 for tanks.

10.5.3 General items of equipment

10.5.3.1 The discharge pipes of tanks shall be capable of being closed by blank flanges or by some other equally effective device. For tanks intended for the transport of refrigerated liquefied gases, these blank flanges or other equally effective devices may be fitted with pressure release openings of diameter not exceeding 1.5 mm

10.5.3.2 Shells intended for the transport of liquefied gases may, in addition to the openings prescribed in 10.4, be provided with openings for the fitting of gauges, thermometers and manometers, and with bleed holes, as required, for their operation and safety. Openings in the shell may be minimized by the incorporation of such equipment in the manhole covers.

10.5.3.3 Filling and discharge openings of a tank intended for the transport of liquefied flammable or toxic (or both) gases shall be equipped with an instant-closing internal safety device which closes automatically in the event of an unintended movement of the shell or of fire. It shall also be possible to operate the closing device by remote control.

10.5.3.4 Each opening (other than those openings that accommodate safety valves and closed bleed holes) of a tank intended for the transport of liquefied flammable or toxic (or both) gases shall, if its nominal diameter is more than 1,5 mm, be equipped with an internal shut-off device.

10.5.3.5 Notwithstanding the requirements of 10.5.3.2, 10.5.3.3 and 10.5.3.4, tanks intended for the transport of refrigerated liquefied gases may be equipped with external devices in place of internal devices if the external devices do not affect the integrity of the system.



10.5.3.6 If the tanks are equipped with gauges in direct contact with the substance being transported, the gauges shall not be made of a transparent material. If there is a thermometer, it shall not project directly into the gas or liquid through the shell, i.e. it shall be enclosed within a sheath.

10.5.3.7 In addition to what is specified in 10.5.3.3, each filling and discharge opening situated in the upper part of a tank shall be equipped with a second, external, closing device. This device shall be capable of being closed by a blank flange or some equally effective device.

10.5.3.8 Tanks intended for the transport of compressed or liquefied gases or gases dissolved under pressure may be fitted with more than two safety valves whose aggregate clear cross-sectional area of passage at the seating or seatings shall be at least 20 cm2/30 m3 (or part thereof) of the shell’s capacity. These valves shall be capable of opening under a pressure of between 0.9 and 1.0 times the test pressure of the tank to which they are fitted. They shall be of such a type as to resist dynamic stresses, including liquid surge. Dead-weight or counter-weight valves shall not be used.

10.5.3.9 Each tank intended for the transport of refrigerated liquefied gases shall be equipped with two independent safety valves, each so designed as to allow the gases formed by evaporation during normal operation to escape from the tank in such a way that the pressure does not at any time exceed by more than 10 % the working pressure indicated on the tank. One of the two safety valves may be replaced by a bursting disc, which shall be such as to burst at the test pressure. In the event of loss of the vacuum in a double-walled tank, or of destruction of 20 % of the insulation of a single-walled tank, the safety valve and bursting disc shall permit an outflow such that the pressure in the shell cannot exceed the test pressure.

10.5.3.10 The safety valves of a tank intended for the transport of refrigerated liquefied gases shall be capable of opening at the working pressure indicated on the tank. They shall be so designed as to function faultlessly even at their lowest working temperature. The reliability of their operation at that temperature shall be established and checked either by the testing of each valve or by the testing of a specimen valve of each design type.

10.5.4 Thermal insulation

10.5.4.1 If a tank intended for the transport of liquefied gases is equipped with thermal insulation, such insulation shall consist of either a) a sun shield covering not less than the upper third but not more than the upper half of the tank surface and separated from the shell by an air space of at least 4 cm across "at all points", or b) a complete lagging, of adequate thickness, of insulating materials.

10.5.4.2 A tank intended for the transport of refrigerated liquefied gases shall be thermally insulated. Thermal insulation shall be ensured by means of continuous sheathing. If the space between the shell and the sheathing is under vacuum (vacuum insulation), the protective sheathing shall be so designed as to withstand, without deformation, an external pressure of at least 100 kPa gauge pressure. Notwithstanding the definition for calculation pressure, external and internal reinforcing devices may be taken into account in the calculations. If the sheathing is so closed as to be gas-tight, a device shall be provided to prevent any dangerous pressure from developing in the insulating layer in the event of inadequate gas-tightness of the shell or of its items of equipment. The device shall prevent the infiltration of moisture into the heat-insulating sheath.

10.5.4.3 A tank intended for the transport of liquefied gases (other than argon (UN No. 1951), helium (UN No. 1963) and nitrogen (UN No. 1977)) with a boiling point below −182 °C at atmospheric pressure shall not include any combustible material either in the thermal insulation or in the means of attachment. The means of attachment of a vacuum-insulating tank may contain plastics substances between the shell and the sheathing.

10.5.4.4 Notwithstanding the requirements of 10.4, shells intended for the transport of refrigerated liquefied gases need not have an inspection opening.



10.5.5 Items of equipment for battery vehicles

10.5.5.1 Items of equipment shall comply with the requirements of this section and any applicable standards referenced in this standard.

10.5.5.2 The manifold shall be designed for service in a temperature range of −20 °C to +50 °C. The manifold shall be so constructed and installed as to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. All piping shall be of acceptable metallic material. Welded pipe joints shall be used wherever possible. Joints in copper tubing shall be brazed or shall have an equally strong metal union. The melting point of brazing materials shall be no lower than 525 °C. The joints shall not decrease the strength of tubing, as might happen when threads are cut.

10.5.5.3 Except for acetylene, dissolved (UN No. 1001), the permissible maximum stress (σ) of the manifold arrangement at the test pressure of the receptacles shall not exceed 75 % of the guaranteed yield stress of the material.

10.5.5.4 Notwithstanding the requirements of 10.5.3 for cylinders, tubes, pressure drums and bundles of cylinders that form a battery vehicle, the required closing devices may be provided for within the manifold arrangement.

10.5.5.5 If one of the cylinders is equipped with a safety valve and shut-off devices are provided between the elements, every element shall be so equipped.

10.5.5.6 The filling and discharge devices may be affixed to a manifold.

10.5.5.7 Each element, including each individual cylinder of a bundle, intended for the transport of toxic gases shall be capable of being isolated by a shut-off valve.

10.5.5.8 Battery vehicles intended for the transport of toxic gases shall not have safety valves, unless each safety valve is preceded by a bursting disc.

10.5.5.9 Receptacles which are elements of a battery vehicle intended for the transport of flammable gases shall be combined in groups each of capacity not exceeding 5 000 l and each of which is capable of being isolated by a shut-off valve.

10.5.5.10 Each element of a battery vehicle intended for the transport of flammable gases and consisting of tanks that comply with this part of this standard shall be capable of being isolated by a shut-off valve.

10.5.6 Inspection and tests for tanks and shells

10.5.6.1 The materials of every welded shell (with the exception of cylinders, tubes, pressure drums and cylinders, and bundles of cylinders which are elements of a battery vehicle) shall be tested in accordance with the method described in 10.6.3.

10.5.6.2 The requirements for minimum test pressure will be as shown on the tank data plate.

10.5.6.3 The first hydraulic pressure test shall be carried out before thermal insulation is placed in position.

10.5.6.4 The capacity of each shell intended for the transport of compressed gases filled by mass, or of gases dissolved under pressure, shall be determined by weighing, or by volumetric measurement of, the quantity of water that fills the shell. The measurement of shell capacity shall be accurate to within 1 %. Determination shall not be made by means of a calculation based on the dimensions of the shell.

10.5.6.5 Checking of the welds shall be carried out in accordance with the λ = 1.0 requirements in 10.4

10.5.6.6 In the case of vacuum-insulated tanks, the hydraulic pressure test and the check of the internal condition may be replaced by a leakproofness test and measurement of the vacuum.

10.5.6.7 Leakproofness tests of tanks intended for the transport of compressed liquefied gases or of gases dissolved under pressure shall be performed at a pressure of not less than 0.4 MPa and not more than 0.8 MPa gauge pressure.



10.5.7 Inspection and tests for battery vehicles

10.5.7.1 The elements and items of equipment of each battery vehicle shall be inspected and tested either together or separately before being put into service for the first time (initial inspection and test

10.5.7.2 The initial inspection and test shall include the following: a) check for conformity to the approved type b) check of the design characteristics c) examination of the internal and external conditions d) hydraulic pressure test at the test pressure indicated on the plate in accordance with 6.9.1 e) leakproofness test at the maximum working pressure f check for satisfactory operation of the equipment When the elements and their fittings have been pressure tested separately, they shall be subjected together, after assembly, to a leakproofness test. The pressure test of the manifold may be performed as a hydraulic test or by using another liquid or gas. The test pressure for the manifold of a battery vehicle shall be at least 300 bars for acetylene, dissolved (UN No. 1001).

10.5.7.3 A certificate shall be issued to show that the tests, inspections and checks have been carried out. The certificate shall refer to the list of substances permitted for transport in the battery vehicle.

10.5.8 General marking requirements

10.5.8.1 The additional particulars in this section shall be marked on a plate as specified in 10.4 or directly on the walls of the shell itself if the walls are so reinforced that the strength of the tank is not impaired.

10.5.8.2 On a tank for the transport of only one substance, the shipping name of the gas shall be given and, in addition for gases classified under an N.O.S. entry, the technical name. The following information shall also be shown: a) in the case of a tank for the transport of compressed gases filled by volume (pressure), an indication of the maximum filling pressure at 15 °C permitted for the tank; and b) in the case of a tank intended for the transport of compressed gases filled by mass, and liquefied gases, refrigerated liquefied gases or gases dissolved under pressure, an indication of the maximum permissible load mass, in kilograms, and of the filling temperature if below −20 °C.

10.5.8.3 On a multipurpose tank, the proper shipping names of the gases shall be shown and, in addition for gases classified under an N.O.S. entry, the technical names of the gases for whose transport the tank is approved. This information shall be supplemented by an indication of the maximum permissible load mass, in kilograms, for each gas.

10.5.8.4 On a tank intended for the transport of refrigerated liquefied gases, the maximum working pressure shall be shown.

10.5.8.5 On a tank equipped with thermal insulation, the inscription "thermally insulated" or "thermally insulated by vacuum" shall be shown.

10.5.8.6 In addition to the particulars specified in 10.4, the following shall be inscribed on the tank itself or on a plate: a) tank code according to the certificate with the actual test pressure of the tank; and b) inscription: "minimum filling temperature allowed:", followed by the minimum filling temperature allowed, in degrees Celsius.



10.5.9 Marking of battery vehicles

10.5.9.1 Every battery vehicle shall be fitted with a plate as specified in 10.4 showing the following information: a) approval number b) manufacturer’s name or mark c) manufacturer’s serial number d) year of manufacture e) test pressure f) design temperature (only if above +50 °C or below −20 °C) g) date (month and year) of initial test h) stamp of the competent authority who carried out the test

10.5.9.2 The following particulars shall be inscribed on the vehicle itself or on a plate: a) name of the owner or operator b) number of elements c) total capacity of the elements

10.5.9.3 The frame of the battery vehicle shall bear, near the filling point, a plate specifying: a) maximum filling pressure at 15 °C allowed for elements intended for compressed gases b) proper shipping name of the gas and, in addition for gases classified under an N.O.S. entry, the technical name c) in the case of liquefied gases, the maximum permissible load per element, in kg

10.6 Requirements and tests for materials and construction of welded tanks for which a test pressure of at least 1 MPa is required, and of welded tanks intended for the transport of refrigerated liquefied gases of class 2

10.6.1 Materials and shells

10.6.1.1 Shells intended for the transport of the following substances shall be made of steel: a) compressed liquefied gases of class 2 that are dissolved under pressure b) substances under UN Nos 1366, 1370, 1380, 2003, 2005, 2445, 2845, 2870, 3049, 3050, 3051, 3052, 3053, 3076, 3194 and 3203 of division 4.2; and c) substances under UN Nos 1052 and 1790 of class 8

10.6.1.2 Shells constructed of fine-grained steels for the transport of the following substances shall be heat treated for thermal stress relief: a) corrosive gases of class 2 b) ammonia solution (UN No. 2073) c) substances under UN Nos. 1052 and 1790 of class 8

10.6.1.3 Shells intended for the transport of refrigerated liquefied gases of class 2 shall be made of steel, aluminium, aluminium alloy, copper or copper alloy (for example brass). However, shells made of copper or copper alloy shall be allowed only for gases containing no acetylene or, in the case of ethylene, containing not more than 0,005 % acetylene by volume. Only materials suited to the lowest and highest working temperatures of the shells and their fittings and accessories shall be used.

10.6.1.4 The following materials shall be allowed for the manufacture of shells: a) steels not subject to brittle fracture at the lowest working temperature): 1) mild steels (except for the transport of refrigerated liquefied gases of class 2); 2) fine-grained steels, down to a temperature of −60 °C; 3) nickel steels (with a nickel content of 0,5 % to 9 %), down to a temperature of −196 °C; and



4) austenitic chrome-nickel steels, down to a temperature of −270 °C; b) aluminium at least 99,5 % pure or aluminium alloys c) deoxidized copper at least 99,9 % pure, or copper alloys with a copper content of over 56 %

10.6.1.5 Shells made of steel, aluminium or aluminium alloys shall be either seamless or welded. Shells made of austenitic steel, copper or copper alloy may be hard soldered.

10.6.1.6 Fittings and accessories may be either screwed to the shells or secured to the shells as follows: a) shells made of steel, aluminium or aluminium alloy: by welding; and b) shells made of austenitic steel, copper or copper alloy: by welding or by hard soldering.

10.6.1.7 The construction of shells and their attachment to the vehicle or to the underframe shall be such as to preclude with certainty any such reduction in the temperature of the load-bearing components as would be likely to render them brittle. The means of attachment of shells shall themselves be so designed that even when the shell is at its lowest temperature they still possess the necessary mechanical properties.

10.6.2 Test requirements

10.6.2.1 Steel shells The materials used for the manufacture of shells and the weld beads shall, at their lowest working temperature, or at −20 °C, whichever is lower, meet at least the following requirements for impact strength. a) The tests shall be carried out on test pieces with a V-shaped notch. b) The minimum impact strength for test pieces with the longitudinal axis at right angles to the direction of rolling and a V-shaped notch (complying with ISO 148) perpendicular to the plate surface shall be 34 J/cm2 for mild steel (which, because of existing ISO standards, may be tested on test pieces with the longitudinal axis in the direction of rolling), finegrained steel, ferritic alloy steel Ni < 5 %, ferritic alloy steel > 5 % Ni and < 9 % Ni, or austenitic Cr-Ni steel. c) In the case of austenitic steels, only the weld bead need be subjected to an impact-strength test. d) For working temperatures below −196 °C, the impact-strength test is not performed at the lowest working temperature, but at −196 °C.

10.6.2.2 Aluminium or aluminium alloy shells The seams of shells shall meet the requirements of the relevant legislation.

10.6.2.3 Copper or copper alloy shells It is not necessary to carry out tests to determine whether the impact strength is adequate.

10.6.3 Impact-strength tests

10.6.3.1 1 Sheet < 10 mm > 5 mm For sheets less than 10 mm but not less than 5 mm thick, use test pieces with a cross section of 10 mm × e mm, where "e" represents the thickness of the sheet. Machining to 7.5 mm or 5 mm is permitted when necessary. The minimum value of 34 J/cm2 shall be required in every case. Do not carry out impact tests on sheets less than 5 mm thick, or on their weld seams.

10.6.3.2 Test pieces For the purpose of testing sheets, determine the impact strength on three test pieces. Take test pieces at right angles to the direction of rolling; however, for mild steel, they may be taken in the direction of rolling. For the purpose of testing weld seams, take the test pieces in accordance with 10.6.3.3 to 10.6.3.5 inclusive.



10.6.3.3 For e < 10 mm Take three test pieces with the notch at the centre of the weld and three test pieces with the notch at the centre of the heat-affected zone (the V-notch to cross the fusion boundary at the centre of the specimen) as shown in figure 1. Figure 1 — Centre of weld and heat-affected zones for e < 10 mm

10.6.3.4 For 10 mm < e < 20 mm Take three test pieces from the centre of the weld and three test pieces from the heat-affected zone (the V-notch to cross the fusion boundary at the centre of the specimen) as shown in figure 2. Figure 2 — Centre of weld and heat-affected zones for 10 mm < e < 20 mm

10.6.3.5 For e > 20 mm Take two sets of three test pieces, one set on the upper face and one set on the lower face, at each of the points indicated in figure 3 (the V-notch to cross the fusion boundary at the centre of the specimen for those taken from the heat-affected zone). Figure 3 — Centre of weld and heat-affected zones for e > 20 mm

10.6.3.6 Requirements for impact-strength test Subject to the requirements of 10.6.3.7, for sheets, the average of the three tests shall meet the minimum value of 34 J/cm2. Not more than one of the individual values shall be below the minimum value, and then it shall not be below 24 J/cm2.



For welds, the average value obtained from the three test pieces taken at the centre of the weld shall not be below the minimum value of 34 J/cm2. Not more than one of the individual values shall be below the minimum value, and then it shall not be below 24 J/cm2. For the heat-affected zone (the V-notch to cross the fusion boundary at the centre of the specimen) the value obtained from not more than one of the test pieces shall be below 34 J/cm2, and then it shall not be below 24 J/cm2.

10.6.3.7 Retest If the requirements specified in 10.6.3.6 are not met, one retest only may be done if: a) the average value of the first three tests is below the minimum of 34 J/cm2, or b) more than one of the individual values is less than the minimum value of 34 J/cm2, but not below 24 J/cm2.

10.6.3.8 Requirements for repeated impact-strength test In a repeated impact-strength test on sheets and welds, none of the individual values shall be below 34 J/cm2. If the average value of all the results of the original test and of the retest is not equal to or greater than the minimum of 34 J/cm2, deem the specimens to have failed the test. On a repeated impact-strength test on the heat-affected zone, none of the individual values shall be below 34 J/cm2.

10.7 Requirements for fibre-reinforced plastics (FRP) tanks

10.7.1 General

10.7.1.1 FRP tanks shall not be used for the transport of flammable substances.

10.7.1.2 For the design and testing of FRP tanks, the provisions of 10.4.1.1, 10.4.1.7, 10.4.3.1, 10.4.3.2.2, 10.4.3.2.3, 10.4.6.2, 10.4.6.4, 10.4.6.7 and 10.4.7 shall also apply.

10.7.1.3 Heating elements shall not be fitted to FRP tanks.

10.7.2 Construction

10.7.2.1 General Shells shall consist of the following three layers: a) internal liner b) structural layer c) external layer

10.7.2.2 Internal liner

10.7.2.2.1 The internal liner is the inner shell wall zone designed as a primary barrier to provide for the long-term chemical resistance to the substance to be transported, and to prevent any dangerous reaction with the contents or the formation of dangerous compounds and any substantial weakening of the structural layer owing to the diffusion of products through the internal layer. The internal layer may be either an FRP liner or athermoplastic liner.



10.7.2.2.2 FRP liners shall consist of the following: a) adequate resin-rich surface layer ("gel-coat"), reinforced with gauze, compatible with the resin and contents – this layer shall have a fibre mass content not exceeding 30 % and shall have a thickness of between 0.25 mm and 0.60 mm; and b) strengthening layers consisting of several layers, each with a thickness of at least 2 mm, and containing at least 900 g/m2 of glass mat or chopped fibres with a mass content of glass of at least 30 %.

10.7.2.2.3 Thermoplastic liners shall consist of thermoplastic sheet material in accordance with 10.7.3, welded together in the required shape, to which the structural layers are bonded. Durable bonding between the liners and the structural layer shall be achieved by means of appropriate adhesives.

10.7.2.3 Structural layer The structural layer shall be designed in accordance with 10.7.4 to withstand the mechanical stresses. This part normally consists of several fibre-reinforced layers in predetermined orientations.

10.7.2.4 External layer The external layer is the part of the shell which is directly exposed to the atmosphere. It shall consist of a resin-rich layer with a thickness of at least 0.2 mm. For a thickness that exceeds 0.5 mm, a mat shall be used. This layer shall have a mass content in glass of less than 30 % and shall be capable of withstanding exterior conditions, in particular the occasional contact with the substance to be transported. The resin shall contain fillers or additives to provide protection against deterioration of the structural layer of the shell by ultraviolet radiation.

10.7.3 Raw materials

10.7.3.1 General Shells shall be made of acceptable materials, which shall be compatible with the substances to be transported in a service temperature range of between −40 °C and +50 °C. All the materials used for the manufacture of FRP tanks shall be of known origin and specifications.

10.7.3.2 Resins The processing of the resin mixture shall be carried out in strict compliance with the recommendations of the supplier. This concerns mainly the use of hardeners, initiators and accelerators. These resins can be any of the following: a) unsaturated polyester resins b) vinyl ester resins c) epoxy resins d) phenolic resins The heat distortion temperature (HDT) of the resin, determined in accordance with ISO 75-1, shall be at least 20 °C higher than the maximum service temperature of the tank, but shall in any case not be lower than 70 °C.

10.7.3.3 Reinforcement fibres The reinforcement material of the structural layers shall be a suitable grade of fibres such as glass fibres of type E or type ECR in accordance with ISO 2078. For the internal surface liner, glass fibres of type C in accordance with ISO 2078 may be used. Thermoplastic gauzes may only be used for the internal liner when their compatibility with the intended contents has been demonstrated.

10.7.3.4 Thermoplastic liner material Thermoplastic liners, such as unplasticized polyvinyl chloride (PVC-U), polypropylene (PP), polyvinylidene fluoride (PVDF), and polytetrafluoroethylene (PTFE), may be used as lining materials



10.7.3.5 Additives Additives necessary for the treatment of the resin, such as catalysts, accelerators, hardeners and thixotropic substances, and materials used to improve the tank, such as fillers, colours, pigments, etc., shall not cause weakening of the material, taking into account the lifespan and temperature expectancy of the design.

10.7.4 Design

10.7.4.1 Shells, their attachments, and their service and structural equipment shall be designed to withstand, without loss of contents other than quantities of gas escaping through degassing vents, during the design lifespan a) the static and dynamic loads in normal conditions of transport, and b the described minimum loads as defined in 10.7.4.2 to 10.7.4.7 inclusive.

10.7.4.2 At the pressures as indicated in 10.4.3.2.2 and 10.4.3.2.3, and under the static gravity forces caused by the contents with maximum density specified for the design and at maximum filling, the design stress (σ) in longitudinal and circumferential direction of any layer of the shell shall not exceed the following value:

where Rm is the value of the tensile strength given by taking the mean value of the test results minus twice the standard deviation of the test results. The tests shall be carried out on at least six samples representative of the design type and construction method; K is a factor (with a minimum value of 4) determined as follows:

K = K0 × K1 × K2 × K3 × S where K0 is a factor related to the deterioration in the material properties due to creep and ageing and as a result of the chemical action of the substances to be transported. It shall be determined by the formula:

where α is the creep factor β is the ageing factor NOTE These factors are determined in accordance with EN 978 after performance of the test in accordance with EN 977. Alternatively, a conservative value of K0 = 2 may be applied. In order to determine α and β, the initial deflection corresponds to 2σ. K1 is a factor related to the service temperature and the thermal properties of the resin, determined by the following equation, with a minimum value of 1:

K1 = 1,25 − 0,0125 (HDT − 70) where HDT is the heat distortion temperature of the resin, in degrees Celsius



K2 is a factor related to the fatigue of the material; the value of K2 = 1.75 shall be used unless otherwise specified. For the dynamic design in accordance with 10.7.4.3 , the value of K2 = 1.1 shall be used K3 is a factor that is related to the curing and that has the value 1.1 where the curing is carried out in accordance with a documented process and a value of 1.5 in other cases S is the safety coefficient For the general design, if the tank code includes the letter "G" in its second part, the value of S shall be equal to or greater than 1.5. For tanks intended for the transport of substances which require an increased safety level, i.e. if the tank code includes the number "4" in its second part, the value of S shall be multiplied by a factor of 2, unless the shell is provided with protection against damage consisting of a complete metal skeleton including longitudinal and transverse structural members

10.7.4.3 At the dynamic forces, as indicated in 10.4.1.2, the design stress shall not exceed the value specified in 10.7.4.2, divided by the factor α.

10.7.4.4 At any of the stresses defined in 10.7.4.2 and 10.7.4.3, the resulting elongation in any direction shall not exceed 0.2 %, or one tenth of the elongation at fracture of the resin, whichever is lower.

10.7.4.5 At the specified test pressure, which shall be equal to at least the relevant calculation pressure as specified in 10.4.3.2.2 and 10.4.3.2.3, the maximum strain in the shell shall not exceed the elongation at fracture of the resin.

10.7.4.6 The shell shall be capable of withstanding the ball drop test in accordance with 10.7.6.3.4 without any visible internal or external defects.

10.7.4.7 The overlay laminates used in joints, including the end joints, the joints of the surge plates and the partitions within the shell, shall be capable of withstanding the static and dynamic stresses mentioned above. In order to avoid concentrations of stresses in the overlay lamination, the applied taper shall not be steeper than 1:6. The shear strength T, in N/mm2, between the overlay laminate and the tank components to which it is bonded shall not be less than

where Q is the load per unit width, in kilograms, that the joint shall be capable of carrying under the static and dynamic loads TR is the bending strength with a minimum TR = 10 N/mm2, if no measured values are available I is the length of the overlay laminate, in mm K is the factor calculated in accordance with 10.7.4.2 for the static and dynamic stresses

10.7.4.8 Openings in the shell shall be reinforced to provide at least the same safety factors against the static and dynamic stresses as specified in 10.7.2 and 10.7.4.3 for the shell itself. The number of openings shall be minimized. The axis ratio of oval-shaped openings shall be not more than 2.

10.7.4.9 For the design of flanges and pipework attached to the shell, handling forces and the fastenings of bolts shall also be taken into account.

10.7.4.10 The tank shall be designed to withstand, without significant leakage, the effects of a full engulfment in fire for 30 min as specified by the test requirements in 10.7.6.3.5. The testing may be waived where sufficient proof can be provided by tests with comparable tank designs.




10.7.5.1 The requirements of 10.4.7.1 to 10.4.7.3 (inclusive) and 10.4.7.5 to 10.4.7.8 (inclusive) shall apply.

10.7.5.2 In addition, when they are shown in dangerous goods list, all the special tank provisions with "E" numbers shall apply.

10.7.5.3 Items of equipment shall comply with the requirements of any relevant standards referenced in this standard.

10.7.6 Testing

10.7.6.1 General For any design of an FRP tank type, its materials and representative prototype shall be subjected to the testing specified in 10.7.6.2 to 10.7.6.3 inclusive

10.7.6.2 Material testing

10.7.6.2.1 The elongation at fracture and the heat distortion temperature in accordance with ISO 75-1 shall be determined for the resins to be used.

10.7.6.2.2 The following characteristics shall be determined for samples cut out of the shell. Samples manufactured in parallel may only be used if it is not possible to use cutouts from the shell. Before testing, any liner shall be removed. The tests shall cover the following: a) the thickness of the laminates of the central shell wall and the ends b) the mass content and composition of the glass, and the orientation and arrangement of reinforcement layers c) the tensile strength, elongation at fracture and modulus of elasticity in accordance with ISO 527-1, ISO 527-4 and ISO 527-5 in the direction of stresses. In addition, the elongation at fracture of the resin shall be established by means of ultrasound d) the bending strength and deflection established by the bending creep test in accordance with method A in ISO 14125 for a period of 1 000 h using a sample with a width of at least 50 mm and a support distance of at least 20 times the wall thickness. In addition, the creep factor α and the ageing factor β shall be determined by this test and in accordance with EN 978

10.7.6.2.3 The interlaminate shear strength of the joints shall be measured by testing representative samples in the tensile test in accordance with ISO 527-1, ISO 527-4 and ISO 527-5.

10.7.6.2.4 The chemical compatibility of the shell with the substances being transported shall be demonstrated by at least one of the methods in 10.7.6.2.5 and 10.7.6.2.5. This demonstration shall account for all aspects of the compatibility of the materials of the shell and its equipment with the substances to be transported, including chemical deterioration of the shell, initiation of critical reactions of the contents and dangerous reactions between both.

10.7.6.2.5 In order to establish any deterioration of the shell, representative samples taken from the shell, including any internal liners with welds, shall be subjected to the chemical compatibility test in accordance with EN 977 for a period of 1 000 h at 50 °C. Compared with a virgin sample, the loss of strength and modulus of elasticity measured by the bending test in accordance with EN 978 shall not exceed 25 %. Cracks, bubbles, pitting, separation of the layers and liners, and roughness are not acceptable.

10.7.6.2.6 Certified and documented data shall be provided on positive experiences on the compatibility of the filling substances in question with the materials of the shell with which they come into contact at given temperatures, times and any other relevant service conditions.



10.7.6.3 Type testing

10.7.6.3.1 A representative prototype tank shall be subjected to tests as specified in 10.7.6.3.2 to 10.7.6.3.5 inclusive. For this purpose, service equipment may be replaced by other items if necessary. However, the competent may allow the tests required in 10.7.6.3.5 to be simulated by calculation if impractical to conduct the physical test.

10.7.6.3.2 The prototype shall be inspected for compliance with the design type specification. This shall include an internal and an external visual inspection and measurement of the main dimensions.

10.7.6.3.3 The prototype equipped with strain gauges at all locations where a comparison with the design calculation is required, shall be subjected to the following loads: a) filled with water to the maximum filling degree – the measuring results shall be used to calibrate the design calculation in accordance with 10.7.4 b) filled with water to the maximum filling degree and subjected to acceleration in all three directions by means of driving and braking exercises with the prototype attached to a vehicle; for comparison with the design calculation in accordance with 10.7.4.2, the accelerations and strains recorded shall be extrapolated to correlate with the design case accelerations in 10.4.1.2 c) filled with water and subjected to the specified test pressure. Under this load the shell shall exhibit no visual damage or leakage The strains shall be recorded.

10.7.6.3.4 The prototype shall be subjected to the ball drop test in accordance with EN 976-1. No visible damage inside or outside the tank shall occur.

10.7.6.3.5 The prototype with its service and structural equipment in place, and filled to 80 % of its maximum capacity with water, shall be exposed to a full engulfment in fire for 30 min, caused by an open heating oil pool fire or any type of fire with the same effect. The dimensions of the pool shall exceed those of the tank by at least 50 cm on each side, and the distance between the fuel level and the tank shall be between 50 cm and 80 cm. The rest of the tank below liquid level, including openings and closures, shall remain leakproof.

10.7.7 Type approval

10.7.7.1 The manufacturer shall issue, in respect of each new type of tank, a certificate attesting that the design is suitable for the purpose for which it is intended and that the tank meets the relevant construction and equipment requirements of this part of of this standard and the special provisions applicable to the substances to be transported.

10.7.7.2 The certificate shall be based on the calculation and test report, including all material and prototype test results and the comparison of the test results with the design calculation, and shall refer to the design type specification and the quality assurance programme.

10.7.7.3 The approval shall include the substances or group of substances for which compatibility with the shell is provided. Their shipping names or corresponding collective entry and their class and UN No(s). shall be indicated.

10.7.7.4 In addition, it shall include design and threshold values (such as lifespan, service temperature range, working and test pressures, and material data) specified and all precautions to be taken during the manufacture, testing, type approval, marking and use of any tank manufactured in accordance with the approved design type.



10.7.8 Inspection, including material tests

10.7.8.1 For every tank manufactured in compliance with the prototype, the material tests and the inspections specified in 10.7.8.2 and 10.7.8.3 shall be performed.

10.7.8.2 The material tests in accordance with 10.7.6.2, except for the tensile test, and with the testing time of the creep test reduced to 100 h, shall be performed on samples taken from the shell. Only samples manufactured in parallel shall be used if it is not possible to obtain cut-outs from the shell. The design values of the prototype shall be met.

Shells and their equipment shall either together or separately undergo an initial inspection before being put into service. The inspection shall include: a) check for compliance with the design of the prototype b) check of the design characteristics c) internal and an external examination d) hydraulic pressure test at the test pressure indicated on the tank in accordance with 10.4.8 e) check of operation of the equipment f) leakproofness test, if the shell and its equipment have been pressure tested separately

A certificate shall be issued showing the results of the tests and inspections. This certificate shall refer to the list of substances permitted for transport in the shell in accordance with 10.7.7.

10.7.9 Marking

10.7.9.1 The requirements of 10.4.8 shall apply to the marking of FRP tanks, with the following amendments: a) tank plate may also be laminated to the shell or be made of acceptable plastics materials and; b) design temperature range shall always be indicated.

10.7.9.2 When they are shown on the dangerous goods list, and "M" special provisions shall apply.

10.8 Vacuum-operated waste tanks

10.8.1 General

10.8.1.1 The special requirements in 10.8.2 t0 10.8.4 (inclusive) complete or modify the requirements for tank vehicles and demountable tanks as they apply to vacuum-operated waste tanks. Vacuum-operated waste tanks may be equipped with openable ends, if bottom discharge of the substances to be transported is allowed, as indicated by the letters "A" and "B" in the third part of the tank code. Vacuum-operated waste tanks shall comply with all the requirements in 10.4, except for those in 10.4.4.4 and 10.4.4.5 NOTE A tank that fully complies with all the requirements in clause 10.4 is not considered to be a "vacuum operated waste tank".



10.8.2 Construction

10.8.2.1 Tanks shall be designed for a calculation pressure equal to 1.3 times the filling or discharge pressure, but not less than 400 kPa. For the transport of substances for which a higher calculation pressure is specified, the specified pressure shall apply.

10.8.2.2 Tanks shall be designed to withstand a negative internal pressure of 100 kPa.


10.8.3.1 The items of equipment shall be so arranged as to be protected against the risk of being wrenched off or damaged during transport or handling. This requirement can be complied with by placing the items of equipment in a protected area.

10.8.3.2 The bottom discharge of shells may be achieved by external piping with a stop-valve fitted as close to the shell as is practicable and a second closure, which may be a blank flange or other equivalent device.

10.8.3.3 The position(s) and closing direction(s) of the stop-valve(s) connected to the shell, or to any compartment in the case of compartmented shells, shall be unambiguous, and shall be able to be checked from the ground.

10.8.3.4 In order to avoid any loss of contents in the event of damage to the external filling and discharge fittings (pipes and lateral shut-off devices), the internal stop-valve, or the first external stop-valve, where applicable, and its seatings shall be protected against the danger of being wrenched off by external stresses, or shall be so designed as to withstand these stresses. The filling and discharge devices, including flanges or threaded plugs and protective caps, shall be capable of being secured against any unintended opening.

10.8.3.5 The tanks may be equipped with openable ends. Openable ends shall comply with the following requirements: a) the ends shall be leak-tight when closed b) unintentional opening shall not be possible c) where the opening mechanism is power operated, the end shall remain securely closed in the event of a power failure d) a safety or break-seal device shall be incorporated to ensure that the openable end cannot be opened when there is still residual over-pressure in the tank. This requirement does not apply to openable ends which are power operated, where the movement is positively controlled. In this case, the controls shall be of the "dead-man" type and shall be so positioned that the operator can observe the movement of the openable end at all times and that he is not endangered during opening and closing of the end e) provision shall be made to protect the openable end and to prevent it from being forced open if the vehicle overturns

10.8.3.6 A vacuum-operated waste tank which is fitted with an internal piston to assist in the discharging shall be provided with stop-devices to prevent the piston in every operational position from being ejected from the tank when a force equivalent to the maximum working pressure of the tank is applied to the piston. The maximum working pressure for a tank or compartment with a pneumatically operated piston shall not exceed 100 kPa. The internal piston shall be constructed in a manner and of materials that will not pose a risk of ignition when the piston is moved. The internal piston may be used as a compartment provided that it is securely in position. Where any means by which the internal piston is secured is on the outside of the tank, it shall be placed in a position not liable to accidental damage.

10.8.3.7 A tank may be equipped with a suction boom if the: a) boom is fitted with an internal or an external stop-valve fixed directly to the shell, or directly to the bend that is welded to the shell b) stop-valve in (a) above is so arranged that transport with the valve in an open position is prevented c) boom is constructed in such a way that the tank will not leak as a result of accidental impact on the boom



10.8.3.8 The tanks shall be fitted with additional service equipment which shall comply with the following requirements. a) The outlet of a vacuum pump unit shall be so arranged as to ensure that any flammable or toxic vapours are diverted to a place where they will not pose a danger. b) A device to prevent immediate passage of flame shall be fitted to both the inlet and the outlet of a vacuum pump unit which might create sparks, and shall be fitted to a tank used for the transport of flammable waste. c) Pumps which can deliver a positive pressure shall have fitted in the pipework a safety device which can be pressurized. The safety device shall be set to discharge at a pressure not exceeding the maximum working pressure of the tank. d) A stop-valve shall be fitted between the shell, or the outlet of the overfill prevention device fitted to the shell, and the pipework connecting the shell to the vacuum pump. e) The tank shall be fitted with an acceptable manometer, which shall be mounted in a position where it can easily be read by the person operating the vacuum pump unit. A distinguishing line shall be marked on the scale to indicate the maximum working pressure of the tank. f) The tank, or any compartment of a compartmented tank, shall be equipped with a level-indicating device. Sight glasses may be used as level-indicating devices provided that: 1) they form a part of the tank wall and have a resistance to pressure comparable to that of the tank; or they are fitted on the outside of the tank 2) the top and bottom connections to the tank are equipped with shut-off valves fixed directly to the shell and so arranged that transport with the valves in an open position is prevented 3) they are suitable for operation at the specified maximum working pressure of the tank 4) they are placed in a position where they will not be liable to accidental damage

10.8.3.9 Each shell of a vacuum-operated waste tank shall have a safety valve preceded by a bursting disc.

10.8.3.10 Items of equipment shall comply with the requirements in 10.8.3.1 to 10.8.3.9 (inclusive) and, with the additional relevant reference standards included in this standard.

10.9 Requirements for the construction, equipment, type approval, inspections and tests, and marking of tanks, bulk containers and special compartments for explosives of mobile explosives manufacturing units (MEMU's)

Note 1: For portable tanks, see section 10.10; for fixed tanks (tank-vehicles), demountable tanks, tank- containers and tank swap bodies, with shells made of metallic materials, see section 10.4 to 10.6; for fibre- reinforced plastics tanks see section 10.7; for vacuum operated waste tanks see section 10.8; for bulk containers see section 10.11. Note 2: This section applies to fixed tanks, demountable tanks, tank-containers, tank swap bodies, which do not comply with all requirements of the sections mentioned in Note 1 as well as bulk containers and special compartments for explosives.

10.9.1 Scope

10.9.1.1 The requirements of this section are applicable to tanks, bulk containers and special compartments intended for the carriage of dangerous goods on MEMUs.

10.9.2 General provisions

10.9.2.1 Tanks shall meet the requirements of section 10.4 to 10.6, notwithstanding any minimum capacity defined for fixed tanks, as modified by the special provisions of this section.



10.9.2.2 Bulk containers intended for the carriage of dangerous goods on MEMUs shall comply with the requirements for bulk containers of type BK2.

10.9.2.3 Where a single tank or bulk container contains more than one substance each substance shall be separated by at least two walls with drained air space between.

10.9.3 Tanks

10.9.3.1 Tanks with a capacity of a 1000 litres or more

10.9.3.1.1 These tanks shall meet the requirements of section 10.4 as applicable

10.9.3.1.2 For UN Nos. 1942 and 3375, the tank shall meet the requirements of sections 7.3.2 and 10.4 concerning breather devices and, in addition, shall have bursting discs or other suitable means of emergency pressure relief.

10.9.3.1.3 For shells not of a circular cross-section, for example box-shaped or elliptical shells, which cannot be calculated according to section 10.4 and standards or technical code mentioned therein, the ability to withstand the permissible stress may be demonstrated by a pressure test specified by the competent authority.

The thickness of these shells shall not be less than the values given in the table below:

Material Minimum thickness

Stainless austenitic steels 2,5 mm

Other steels 3 mm

Alluminium alloys 4 mm

Pure aluminium of 99.80% 6 mm

Protection of the tank against damage through lateral impact or overturning shall be provided. Protection shall be provided according to 10.4

10.9.3.1.4 Tanks do not need to be marked with the tank code and the special provisions, as applicable.

10.9.3.2 Tanks with a capacity of less than 1 000 litres

10.9.3.2.1 Tanks will comply with 10.9.3.1.1 to 9.9.3.1.4

10.9.3.2.2 Tanks may have constructional parts that are without a radius of convexity. Alternative supportive measures may be curved walls, corrugated walls or ribs. In at least one direction the distance between parallel supports on each side of the tank shall not be greater than 100 times the wall thickness.

10.9.3.2.3 Welds shall be skilfully made and shall afford the fullest safety. Welding shall be performed by skilled welders using a welding process whose effectiveness (including any heat treatments required) has been demonstrated by test.



10.9.3.2.4 The requirements of 10.4.10 do not apply. However, the initial and periodic inspections of these tanks shall be carried out under the responsibility of the user or owner of the MEMU. Shells and their equipment shall be subject to visual examination of their external and internal condition and a leakproofness test to the satisfaction of the competent authority at least every three years.

10.9.3.2.5 The requirements for type approval (10.4.9) and marking (10.4.8) do not apply.


10.9.4.1 Tanks with bottom discharge for UN 1942 and UN 3375 shall have at least two closures. One of these closures may be the product mixing or discharge pump or auger.

10.9.4.2 Any piping after the first closure shall be of a fusible material (i.e. rubber hose) or have fusible elements.

10.9.4.3 n order to avoid any loss of contents in the event of damage to the external pumps and discharge fittings (pipes), the first closure and its seatings shall be protected against the danger of being wrenched off by external stresses or shall be so designed as to withstand them. The filling and discharge devices (including flanges or threaded plugs) and protective caps (if any) shall be capable of being secured against any unintended opening.

10.9.4.4 Breather devices in accordance with 10.4.7.6.1 on tanks for UN 3375 may be substituted by "goose necks". Such equipment shall be protected against the danger of being wrenched off by external stresses or shall be so designed as to withstand them.

10.9.5 Special compartments for explosives

10.9.5.1 Compartments for packages of explosives containing detonators and/or detonator assemblies and those containing substances or articles of compatibility group D shall be designed to provide effective segregation such that there is no danger of transmission of detonation from the detonators and/or detonator assemblies to the substances or articles of compatibility group D. Segregation shall be achieved by the use of separate compartments or by placing one of the two types of explosive in a special containment system. Either method of segregation shall be approved by the competent authority. If the material used for the compartment is metal, the complete inside of the compartment shall be covered with materials providing suitable fire resistance. The explosives compartments shall be located where they are protected from impact and from damage on rough terrain and dangerous interaction with other dangerous goods on board and from ignition sources on the vehicle e.g. exhausts etc.

10.10 Requirements for portable tanks

Refer to the definition of a "Portable tank".

10.10.1 The requirements of this section apply to portable tanks intended for the carriage of dangerous goods of Classes 2, 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 7, 8 and 9, and to MEGCs intended for the carriage of non-refrigerated gases of Class 2, by all modes of carriage. In addition to the requirements of this section, unless otherwise specified, the applicable requirements of the International Convention for Safe Containers (CSC) 1972, as amended, shall be fulfilled by any multimodal portable tank or MEGC which meets the definition of a "container" within the terms of that Convention. Additional requirements may apply to offshore portable tanks or MEGCs that are handled in open seas. NOTE: The term "Portable tank" refers to tanks that can be handled when filled with product and used for multi-modal transport.



10.10.2 For fixed tanks (tank-vehicles), demountable tanks and tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple element gas containers (MEGCs) other than UN MEGCs, see sections 10.4 to 10.7; for fibre-reinforced plastics tanks, see section 10.7; for vacuum operated waste tanks, see section 10.8 and for MEMU's see section 10.9.

10.10.3 Portable tanks shall comply with the requirements of ADR chapter 6.7 or be ADR certified and plated.

10.11 Requirements for the design, construction, inspection and testing of bulk containers

10.11.1 Application and general requirements

10.11.1.1 Bulk containers and their service and structural equipment shall be designed and constructed to withstand, without loss of contents, the internal pressure of the contents and the stresses of normal handling and carriage.

10.11.1.2 Where a discharge valve is fitted, it shall be capable of being made secure in the closed position and the whole discharge system shall be suitably protected from damage. Valves having lever closures shall be able to be secured against unintended opening and the open or closed position shall be readily apparent.

10.11.1.3 Code for designating types of bulk container The following codes apply to bulk containers: BK1 Sheeted bulk container BK2 Closed bulk container

10.11.1.4 In order to take account of progress in science and technology, the use of alternative arrangements which offer at least equivalent safety as provided by the requirements of this chapter may be considered by the competent authority.

10.11.2 Requirements for the design, construction, inspection and testing of containers conforming to the CSC used as BK1 or BK2 bulk containers


10.11.3 Requirements for the design, construction and approval of BK1 or BK2 bulk containers other than containers conforming to the CSC

10.11.3.1 Bulk containers covered in this section include skips, offshore bulk containers, bulk bins, swap bodies, trough shaped containers, roller containers, and load compartments of vehicles.

10.11.3.2 These bulk containers shall be designed and constructed so as to be strong enough to withstand the shocks and loadings normally encountered during carriage including, as applicable, transhipment between modes of transport.

10.11.3.3 These bulk containers shall be approved by the competent authority and the approval shall include the code for designating types of bulk containers in accordance with this section and the requirements for inspection and testing as appropriate.

10.11.3.4 Bulk containers shall be siftproof. Where a liner is used to make the container siftproof it shall be made of a suitable material. The strength of material used for, and the construction of, the liner shall be appropriate to the capacity of the container and its intended use. Joins and closures of the liner shall withstand pressures



and impacts liable to occur under normal conditions of handling and carriage. For ventilated bulk containers any liner shall not impair the operation of ventilating devices.

10.11.3.5 The operational equipment of bulk containers designed to be emptied by tilting shall be capable of withstanding the total filling mass in the tilted orientation.

10.11.3.6 Any movable roof or side or end wall or roof section shall be fitted with locking devices with securing devices designed to show the locked state to an observer at ground level.

10.11.3.7 Service equipment

10.11.3.7.1

Filling and discharge devices shall be so constructed and arranged as to be protected against the risk of being wrenched off or damaged during carriage and handling. The filling and discharge devices shall be capable of being secured against unintended opening. The open and closed position and direction of closure shall be clearly indicated.

10.11.3.7.2

Seals of openings shall be so arranged as to avoid any damage by the operation, filling and emptying of the bulk container.

10.11.3.7.3

Where ventilation is required bulk containers shall be equipped with means of air exchange, either by natural convection, e.g. by openings, or active elements, e.g. fans. The ventilation shall be designed to prevent negative pressures in the container at all times. Ventilating elements of bulk containers for the carriage of flammable substances or substances emitting flammable gases or vapours shall be designed so as not to be a source of ignition.

10.11.3.8 Marking

Reserved for further use

10.12 Responsibilities of competent authorities

10.12.1 This section serves to outline the duties of competent authorities.

10.12.2 Competent authorities are responsible for the following:

10.12.2.1 Type approval for tanks

10.12.2.2 Type approval for modified tanks

10.12.2.3 Assessment of the in-house quality assurance system of the manufacturer in order to provide approval for the manufacturer to carry out some or all of the required tests and inspections required during the construction process. Compliance with the inspection and testing requirements are considered to be met if EN12972:2007-Tanks for transport of dangerous goods - Testing, inspection and marking of metallic tanks, are complied with.

10.12.2.4 Supervision of manufacture The manufacturing process shall be subject to a survey by the relevant body to ensure the product is produced in conformity with the provisions of the type approval. This verification will include: (a) Conformity with the technical documentation specified in 10.4.9.3.3



(b) That the manufacturing process produces products in conformity with the requirements and the documentation which apply to it; (c) The traceability of materials and check the material certificate(s) against the specifications; (d) As applicable, that the personnel undertaking the permanent joining of parts and the non-destructive tests are qualified or approved; (e) Agreement with the applicant on the location where the examinations and necessary tests are to be carried out; and (f) Recording the results of its survey The following documents will be made available to the competent authority by the manufacturer: i) documents listed in 10.4.9.3.3 ii) copy of the type approval certificate iii) manufacturing procedures including test procedures iv) manufacturing records v) approved qualifications of permanent joining operators vi) approved qualifications of the non destructive test operators vii) reports of the destructive and non destructive tests viii) heat treatment records ix) calibration records

10.12.2.5 Initial inspection and test The competent authority shall: (a Perform the necessary examinations and tests in order to verify that the product is manufactured in accordance with the type approval and the relevant provisions; (b) Check the certificates supplied by the manufacturers of service equipment against the service equipment; (c) Issue an initial inspection and test report to the applicant relating to the detailed tests and verifications carried out and the verified technical documentation; (d) Draw up a written certificate of conformity of the manufacture and affix its registered mark when the manufacture satisfies the provisions; and (e) Check if the type approval remains valid after provisions of this standard (including referenced standards) relevant to the type approval have changed. The certificate in (d) and report in (c) may cover a number of items of the same type (group certificate or report). The manufacturer will provide the following documentation for the initial inspection and test: i) documents listed in 10.4.9.3.3 and 10.4.9.3.4 ii) material certificates of the product and any sub-parts iii) declarations of conformity and material certificates of the service equipment iv) declaration of conformity including the description of the product and all the variations adopted from the type approval



Section 11

Annexures

A Dangerous goods list and exempt quantities "P" provisions "B" provisions "L" provisions "O" provisions Dangerous goods list - To be completed wrt the classification code, hazard ID, tank codes, vehicle types and special tank provisions

B Maintenance inspections and test schedules

C A transport emergency card

D A completed dangerous goods declaration (DGD) and a waste dangerous goods declaration (WDGD)

E Reserved for future use

F Incident report format

G Gasses and gas mixtures To be completed – Reserved for future use

H Equipment standards

I Minimum requirements for non-compliant tanks to remain in operation



Bibliography

To be competed



Annexure A.1 Dangerous goods list Note – This list must be completed by populating columns 4, 13, 14, 15 and 16

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16

Un no Proper shipping name Class Class code

PG Subs risk Exempt qty F Hazard ID

Veh. Type

Tank code Special tank provisions

P B L O

0004 AMMONIUM PICRATE dry or wetted with < 10 % water, by mass

1.1D 20 50

0005 CARTRIGES FOR WEAPONS with bursting charge 1.1F 20 50

0006 CARTRIGES FOR WEAPONS with bursting charge 1.1E 20 50

0007 CARTRIGES FOR WEAPONS with bursting charge 1.2F 20 50

0009 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge

1.2G 20 50

0010 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge

1.3G 20 50

0012 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS

1.4S Unlimited 2 2; 3; 9 1

0014 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK or CARTRIDGES FOR TOOLS, BLANK

1.4S Unlimited 2 2; 3; 9 1

0015 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge

1.2G 20 50

0016 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge

1.3G 20 50

0018 AMMUNITION, TEAR-PRODUCING with burster, expelling charge or propelling charge

1.2G 6.1 8

20 50

0019 AMMUNITION, TEAR-PRODUCING with burster, expelling charge or propelling charge

1.3G 6.1 8

20 50

0020 AMMUNITION, TOXIC with burster, expelling charge or propelling charge

1.2K 6.1

0021 AMMUNITION, TOXIC with burster, expelling charge or propelling charge

1.3K 6.1

0027 BLACK POWDER (GUNPOWDER), granular or as a meal

1.1D 5 20

200 50

2 2; 3; 4; 9

1

0028 BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS

1.1D 20 50

0029 DETONATORS, NON-ELECTRIC for blasting 1.1B 20 50

0030 DETONATORS, ELECTRIC for blasting 1.1B 20 50

0033 BOMBS with bursting charge 1.1F 20 50

0034 BOMBS with bursting charge 1.1D 20 50



0035 BOMBS with bursting charge 1.2D 20 50

0037 BOMB, PHOTO-FLASH 1.1F 20 50

0038 BOMB, PHOTO-FLASH 1.1D 20 50

0039 BOMB, PHOTO-FLASH 1.2G 20 50

0042 BOOSTERS without detonators 1.1D 20 50

0043 BURSTERS, explosive 1.1D 20 50

0044 PRIMERS, CAP TYPE 1.4S Unlimited

0048 CHARGE, DEMOLITION 1.1D 20 50

0049 CARTRIGES, FLASH 1.1D 20 50

0050 CARTRIGES, FLASH 1.3G 20 50

0054 CARTRIGES, SIGNAL 1.3G 20 50

0055 CASES, CARTRIGES, EMPTY, WITH PRIMER 1.4S Unlimited

0056 CHARGES, DEPTH 1.1D 20 50

0059 CHARGES, SHAPED without detonator 1.1D 20 50

0060 CHARGES, SUPPLIMENTARY, EXPLOSIVE 1.1D 20 50

0065 CORD, DETONATING, flexible 1.1D 20 50

0066 CORD, IGNITER 1.4G 100 10

0070 CUTTERS, CABLE, EXPLOSIVE 1.4S Unlimited

0072 CYCLOTRIMETHYLENE- TRINITRAMINE (CYCLONITE; HEXOGEN; RDX), WETTED with not less than 51 % water, by mass

1.1D 20 50

0073 DETONATORS FOR AMMUNITION 1.1B 20 50

0074 DIAZODINITROPHENOL, WETTED with not less than 40 % water, or mixture of alcohol and water, by mass

1.1A 0

0075 DIETHEYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25 % non-volatile, water-insoluble phlegmatizer, by mass

1.1D 20 50

0076 DINITROPHENOL, dry or wetted with less than 15 % water, y mass

1.1D 6.1 20 50

0077 DINITROPHINOLATES, alkali metals, dry or wetted with less than 15 % water, by mass

1.3C 6.1 20 50

0078 DINITRORESORCINOL, dry or wetted with less than 15 % water, by mass

1.1D 20 50

0079 HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL)

1.1D 20 50

0081 EXPLOSIVE, BLASTING, TYPE A 1.1D 20 50

0082 EXPLOSIVE, BLASTING, TYPE B 1.1D 20 50

0083 EXPLOSIVE, BLASTING, TYPE C 1.1D 20 50

0084 EXPLOSIVE, BLASTING, TYPE D 1.1D 20 50

0092 FLARES, SURFACE 1.3G 20 50

0093 FLARES, AERIAL 1.3G 20 50

0094 FLASH POWDER 1.1G 20 50



0099 FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells

1.1D 20 50

0101 FUSE, NON-DETONATING 1.3G 20 50

0102 CORD (FUSE), DETONATING, metal clad 1.2D 20 50

0103 FUSE, IGNITER, tabular, metal clad 1.4G 100 10

0104 CORD (FUSE), DETONATING, MILD EFFECT, metal clad

1.4D 333 2

0105 FUSE, SAFETY 1.4S Unlimited

0106 FUZES, DETONATING 1.1B 20 50

0107 FUZES, DETONATIONG 1.2B 20 50

0110 GRENADES, PRACTICE, hand or rifle 1.4S Unlimited

0113 GUANYL NITROSAMINO-GUANYLIDENE HYDRAZINE, WETTED with not less than 30 % water, by mass

1.1A 0

0114 GUANYL NITROSAMINO-GUANYLETETRAZENE (TETRAZENE), WETTED with not less than 30 % water, or mixture of alcohol and water, by mass

1.1A 0

0118 HEXOLITE (HEXOTOL), dry or wetted with less than 15 % water, by mass

1.1D 20 50

0121 IGNITERS 1.1G 20 50

0124 JET PERFORATING GUNS, CHARGED, oil well, without detonator

1.1D 20 50

0129 LEAD AZIDE, WETTED with not less than 20 % water, or mixture of alcohol and water, by mass

1.1A 0

0130 LEAD STYPHNATE (LEAD TRINITRORESORCINATE) WETTED with not less than 20 % water, mixture of alcohol and water, by mass

1.1A 0

0131 LIGHTER, FUSE 1.4S Unlimited

0132 DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES. N.O.S

1.3C 20 50

0133 MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40 % water, or mixture of alcohol and water, bu mass

1.1D 20 50

0135 MERCURY FULMINATE, WETTED with not less 20 % water, or mixture of alcohol and water, by mass

1.1A 0

0136 MINES with bursting charge 1.1F 20 50

0137 MINES with bursting charge 1.1D 20 50

0138 MINES with bursting charge 1.2D 20 50

0143 NITROGLYCERIN, DESENSITIZED with not less than 40 % non-volatile water-insoluble phlrgmatizer, by mass

1.1D 6.1 20 50

0144 NITROGLYCERIN, DESENSITIZED with not more than 40 % non-volatile water-insoluble phlrgmatizer, by mass

1.1D 20 50



0146 NITROSTARCH, dry or wetted with less than 20 % water, by mass

1.1D 20 50

0147 NITRO UREA 1.1D 20 50

0150 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN); WETTED with not less than 25 % water, by mass, or PENTAERYTHROTOL TETRANITRATE; PETN) DESENSITIZED with not less than 15 % phlematizer, by mass

1.1D 20 50

0151 PENTOLITE, dry or wetted with less than 15 % water, by mass

1.1D 20 50

0153 TRINITROANILINE (PICRAMIDE) 1.1D 20 50

0154 TRINITROPHENOL (PICRIC ACID), dry or wetted with less than 30 % water, by mass

1.1D 20 50

0155 TRINITROCHLOROBENZENE (PICRYL CHRLORIDE)

1.1D 20 50

0159 POWDER CAKE (POWDER PASTE), WETTED with not less than 25 % water, by mass

1.3C 20 50

0160 POWDER, SMOKELESS 1.1C 20 50

0161 POWDER, SMOKELESS 1.3C 10 100

100 10

2 2; 3; 5; 9

1

0167 PROJECTILES with bursting charge 1.1F 20 50

0168 PROJECTILES with bursting charge 1.2D 20 50

0171 AMMONIUM, ILLUMINATING with or without burst, expelling charge or propelling charge

1.2G 20 50

0173 RELEASE DEVICES, EXPLOSIVE 1.4S Unlimited

0174 REVETS, EXPLOSIVE 1.4S unlimited

0180 ROCKETS, with bursting charge 1.1F 20 50

0181 ROCKETS, with bursting charge 1.1E 20 50

0182 ROCKETS, with bursting charge 1.2E 20 50

0183 ROCKETS, with inert head 1.3C 20 50

0186 ROCKET MOTORS 1.3C 20 50

0190 SAMPLES, EXPLOSIVE, other than initiating explosive 0

0191 SIGNAL DEVICES, HAND 1.4G 5 100

200 10

2 2; 3; 6; 9

1

0192 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1.1G 10 units 50 kg

- 20

2 2; 3; 8; 9

1

0193 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1.4S Unlimited 3 2; 3; 8; 9

1

0194 SIGNALS, DISTRESS 1.1G 20 50

0195 SIGNALS, DISTRESS 1.3G 50 20 2 2; 3; 6; 9

1

0196 SIGNALS, SMOKE 1.1G 20 50



0197 SIGNALS, SMOKE 1.4G 100 10 2 2; 3; 6; 9

1

0204 SOUNDING DEVICES, EXPLOSIVE 1.2F 20 50

0207 TETRANITROANILINE 1.1D 20 50

0208 TRINITROPHENYL-METHYLNATRAMINE (TETRYL) 1.1D 20 50

0209 TRINITROTOLUENE (TNT), dry or wetted with less than 30 % water, by mass

1.1D 20 50

0212 TRACERS FOR AMMUNITION 1.3G 20 50

0213 TRINITROANISOLE 1.1D 20 50

0214 TRINITROBENZENE, dry or wetted with less than 30 % water, by mass

1.1D 20 50

0215 TRINITROBENZOIC ACID, dry or wetted with less than 30 % water, by mass

1.1D 20 50

0216 TRINITRO-m-CRESOL 1.1D 20 50

0217 TRINITRONAPHTHALENE 1.1D 20 50

0218 TRINITROPHENETOLE 1.1D 20 50

0219 TRINITRORESORCINOL (STYPHNIC ACID) dry or wetted with less than 20 % water, or mixture of alcohol and water, by mass

1.1D 20 50

0220 UREA NITRATE, dry or wetted with less than 20 % water, by mass

1.1D 20 50

0221 WARHEADS, TORPEDO with bursting charge 1.1D 20 50

0222 AMMONIUM NITRATE with more than 0.2 % combustible substances, including any organic substance calculated as carbon, to the exclusion of any other addedsubstance

1.1D 20 50

0224 BARIUM AZIDE, dry or wetted with less than 50 % water, bu mass

1.1A 0

0225 BOOSTERS WITH DETONATOR 1.1B 20 50

0226 CYCLOTETRAMETHY-LENETETRANITRAMINE (HMX; OCTOGEN), WETTED with not less than 15 % water, by mass

1.1D 20 50

0234 SODIUM DINITRO-o-CRESOLATE, dry or wetted with less than 15 % water, by mass

1.3C 20 50

0235 SODIUM PICRAMATE, dry or wetted with less than 20 % water, by mass

1.3C 20 50

0236 ZIRCONIUM PICRAMATE, dry or wetted with less than 20 % water, by mass

1.3C 20 50

0237 CHARGES, SHAPED, FLEXIBLE, LINEAR 1.4D 500 2

0238 ROCKETS, LINE-THROWING 1.2G 20 50

0240 ROCKETS, LINE-THROWING 1.3G 20 50

0241 EXPLOSIVE, BLASTING, TRYPE E 1.1D 20 50

0242 CHARGES, PROPELLING, FOR CANNON 1.3C 20 50



0243 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge

1.2H 20 50

0244 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge

1.3H 20 50

0245 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge

1.2H 20 50

0246 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge

1.3H 20 50

0247 AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge

1.3J 20 50

0248 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge

1.2L 0

0249 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge

1.3L 0

0250 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge

1.3L 0

0254 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge

1.3G 20 50

0255 DETONATORS, ELECTRIC for blasting 1.4B 500 2

0257 FUZES, DETONATING 1.4B 500 2

0266 OCTOLITE (OCTOL), dry or wetted with less than 15 % water, by mass

1.1D 20 50

0267 DETONATORS, NON-ELECTRIC for blasting 1.4B 20 50

0268 BOOSTERS WITH DETONATOR 1.2B 0

0271 CHARGES, PROPELLING 1.1C 20 50

0272 CHARGES, PROPELLING 1.3C 20 50

0275 CARTRIDGES, POWER DEVICE 1.3C 20 50

0276 CARTRIDGES, POWER DEVICE 1.4C 500 2

0277 CARTRIDGES, OIL WELL 1.3C 20 50

0278 CARTRIDGES, OIL WELL 1.4C 500 2

0279 CHARGES, PROPELLING FOR CANNON 1.1C 20 50



0282 NITROGUANIDINE (PICRITE), dry or wetted with less than 20 % water, by mass

1.1D 20 50

0283 BOOSTERS without detonator 1.2D 20 50

0284 GREMADES, hand or rifle, with bursting charge 1.1D 20 50

0285 GREMADES, hand or rifle, with bursting charge 1.2D 20 50

0286 WARHEADS, ROCKETS with bursting charge 1.1D 20 50

0287 WARHEADS, ROCKETS with bursting charge 1.2D 20 50

0288 CHARGES, SHAPED, FLEXIBLE, LINEAR† 1.1D 20 50

0289 CORD, DETONATING, flexible† 1.4D 500 2

0290 CORD (FUSE), DETONATING, metal clad† 1.1D 20 50



0291 BOMBS with bursting charge† 1.2F 20 50

0292 GRENADES, hand or rifle, with bursting charge† 1.1F 20 50

0293 GRENADES, hand or rifle, with bursting charge† 1.2F 20 50

0294 MINES with bursting charge† 1.2F 20 50

0295 ROCKETS with bursting charge† 1.2F 20 50

0296 SOUNDING DEVICES, EXPLOSIVE† 1.1F 20 50

0297 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge†

1.4G 500 2

0299 BOMBS, PHOTO-FLASH† 1.3G 20 50

0300 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge†

1.4G 500 2

0301 AMMUNITION, TEAR-PRODUCING with burster, expelling charge or propelling charge†

1.4G 500 2

0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge†

1.4G 500 2

0305 FLASH POWDER† 1.3G 20 50

0306 TRACERS FOR AMMUNITION† 1.4G 500 2 2 2; 3; 6; 9

1

0312 CARTRIDGES, SIGNAL† 1.4G 500 2

0313 SIGNALS, SMOKE† 1.2G 20 50

0314 IGNITERS† 1.2G 20 50

0315 IGNITERS† 1.3G 20 50

0316 FUZES, IGNITING† 1.3G 20 50

0317 FUZES, IGNITING† 1.4G 500 2

0318 GRENADES, PRACTICE, hand or rifle† 1.3G 20 50

0319 PRIMERS, TUBULAR† 1.3G 20 50

0320 PRIMERS, TUBULAR† 1.4G 500 2

0321 CARTRIDGES FOR WEAPONS with bursting charge† 1.2E 20 50

0322 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge†

1.2L 0

0323 CARTRIDGES, POWER DEVICE 1.4S Unlimited 2 2; 3; 9 1

0324 PROJECTILES with bursting charge† 1.2F 20 50

0325 IGNITERS† 1.4G 500 2

0326 CARTRIDGES FOR WEAPONS, BLANK† 1.1C 20 50

0327 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK†

1.3C 20 50

0328 CARTRIDGES FOR WEAPONS, INERT PROJECTILE†

1.2C 20 50

0329 TORPEDOES with bursting charge† 1.1E 20 50

0330 TORPEDOES with bursting charge† 1.1F 20 50

0331 EXPLOSIVE, BLASTING, TYPE B† (AGENT, BLASTING, TYPE B)

1.5D 20 50



0332 EXPLOSIVE, BLASTING, TYPE E† (AGENT, BLASTING, TYPE E)

1.5D 20 50

0333 FIREWORKS† 1.1G 20 50

0334 FIREWORKS† 1.2G 20 50

0335 FIREWORKS 1.3G 20 50 2 2; 3; 7; 9

1

0336 FIREWORKS 1.4G 5 10 100

200 100 10

2 2; 3; 7; 9

1

0337 FIREWORKS 1.4S Unlimited 2 2; 3; 7; 9

1

0338 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK†

1.4C 500 2

0339 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS†

1.4C 500 2

0340 NITROCELLULOSE, dry or wetted with less than 25 % water (or alcohol), by mass†

1.1D 20 50

0341 NITROCELLULOSE, unmodified or plasticized with less than 18 % plasticizing substance, by mass†

1.1D 20 50

0342 NITROCELLULOSE, WETTED with not less than 25 % alcohol, by mass†

1.3C 20 50

0343 NITROCELLULOSE, PLASTICIZED with not less than 18 % plasticizing substance, by mass†

1.3C 20 50

0344 PROJECTILES with bursting charge† 1.4D 500 2

0345 PROJECTILES, inert with tracer† 1.4S Unlimited

0346 PROJECTILES with burster or expelling charge† 1.2D 20 50

0347 PROJECTILES with burster or expelling charge† 1.4D 500 20

0348 CARTRIDGES FOR WEAPONS with bursting charge† 1.4F 500 2

0349 ARTICLES, EXPLOSIVE, N.O.S. 1.4S Unlimited

0350 ARTICLES, EXPLOSIVE, N.O.S. 1.4B 500 2

0351 ARTICLES, EXPLOSIVE, N.O.S. 1.4C 500 2

0352 ARTICLES, EXPLOSIVE, N.O.S. 1.4D 500 2

0353 ARTICLES, EXPLOSIVE, N.O.S. 1.4G 500 2

0354 ARTICLES, EXPLOSIVE, N.O.S. 1.1L 0



0357 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1L 0



0360 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting†

1.1B 20 50


1.4B 500 2



0362 AMMUNITION, PRACTICE† 1.4G 500 2

0363 AMMUNITION, PROOF† 1.4G 500 2

0364 DETONATORS FOR AMMUNITION† 1.2B 20 50

0365 DETONATORS FOR AMMUNITION† 1.4B 500 2

0366 DETONATORS FOR AMMUNITION† 1.4S Unlimited

0367 FUZES, DETONATING† 1.4S Unlimited

0368 FUZES, IGNITING† 1.4S Unlimited

0369 WARHEADS, ROCKET with bursting charge† 1.1F 20 50

0370 WARHEADS, ROCKET with burster or expelling charge†

1.4D 500 2

0371 WARHEADS, ROCKET with burster or expelling charge†

1.4F 500 2


0373 SIGNAL DEVICES, HAND 1.4S Unlimited 3 2; 3; 6; 9

1

0374 SOUNDING DEVICES, EXPLOSIVE† 1.1D 20 50

0375 SOUNDING DEVICES, EXPLOSIVE† 1.2D 20 50

0376 PRIMERS, TUBULAR† 1.4S Unlimited

0377 PRIMERS, CAP TYPE† 1.1B 20 50

0378 PRIMERS, CAP TYPE† 1.4B 500 2

0379 CASES, CARTRIDGE, EMPTY, WITH PRIMER† 1.4C 500 2

0380 ARTICLES, PYROPHORIC† 1.2L 0

0381 CARTRIDGES, POWER DEVICE† 1.2C 20 50

0382 COMPONENTS, EXPLOSIVE TRAIN, N.O.S.† 1.2B 20 50


0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S.† 1.4S Unlimited

0385 5-NITROBENZOTRIAZOL† 1.1D 20 50

0386 TRINITROBENZENE-SULFONIC ACID† 1.1D 20 50

0387 TRINITROFLUORENONE† 1.1D 20 50

0388 TRINITROTOLUENE (TNT) AND TRINITRO-BENZENE MIXTURE or TRINITROTOLUENE (TNT) AND HEXANITRO-STILBENE MIXTURE†

1.1D 20 50

0389 TRINITROTOLUENE (TNT) MIXTURE CONTAINING TRINITRO-BENZENE AND HEXA-NITROSTILBENE†

1.1D 20 50

0390 TRITONAL† 1.1D 20 50

0391 CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLO-NITE; HEXO-GEN; RDX) AND CYCLOTETRA-METHYLENETETRA-NITRAMINE (HMX; OCTOGEN) MIXTURE, WETTED with not less than 15 % water, by mass or CYCLOTRI-METHYLENE-TRINI-TRAMINE (CYCLO-NITE; HEXOGEN; RDX) AND CYCLOTETRA-METHYLENETETRANI-TRAMINE

1.1D 20 50



(HMX; OCTO-GEN) MIXTURE, DESEN-SITIZED with not less than 10 % phlegmatizer, by mass†

0392 HEXANITROSTILBENE† 1.1D 20 50

0393 HEXOTONAL† 1.1D 20 50

0394 TRINITRORESORCINOL (STYPHNIC ACID), WETTED with not less than 20 % water, or mixture of alcohol and water, by mass†

1.1D 20 50

0395 ROCKET MOTORS, LIQUID FUELLED† 1.2J 20 50

0396 ROCKET MOTORS, LIQUID FUELLED† 1.3J 20 50

0397 ROCKETS, LIQUID FUELLED with bursting charge† 1.1J 20 50

0398 ROCKETS, LIQUID FUELLED with bursting charge† 1.2J 20 50

0399 BOMBS WITH FLAMMABLE LIQUID with bursting charge†

1.1J 20 50

0400 BOMBS WITH FLAMMABLE LIQUID with bursting charge†

1.2J 20 50

0401 DIPICRYL SULFIDE, dry or wetted with less than 10 % water, by mass†

1.1D 20 50

0402 AMMONIUM PERCHLORATE† 1.1D 20 50

0403 FLARES, AERIAL 1.4G 250 4 2 2; 3; 6; 9

1

0404 FLARES, AERIAL 1.4S Unlimited 3 2; 3; 6; 9

1

0405 CARTRIDGES, SIGNAL 1.4S Unlimited 3 2; 3; 6; 9

0406 DINITROSOBENZENE† 1.3C 20 50

0407 TETRAZOL-1-ACETIC ACID† 1.4C 500 2

0408 FUZES, DETONATING with protective features† 1.1D 20 50



0411 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) with not less than 7 % wax, by mass†

1.1D 20 50

0412 CARTRIDGES FOR WEAPONS with bursting charge† 1.4E 500 2

0413 CARTRIDGES FOR WEAPONS, BLANK† 1.2C 20 50

0414 CHARGES, PROPELLING, FOR CANNON† 1.2C 20 50

0415 CHARGES, PROPELLING† 1.2C 20 50

0417 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS†

1.3C 20 50

0418 FLARES, SURFACE† 1.1G 20 50

0419 FLARES, SURFACE† 1.2G 20 50

0420 FLARES, AERIAL† 1.1G 20 50

0421 FLARES, AERIAL† 1.2G 20 50

0424 PROJECTILES, inert with tracer† 1.3G 20 50



0425 PROJECTILES, inert with tracer† 1.4G 500 2

0426 PROJECTILES with burster or expelling charge† 1.2F 20 50

0427 PROJECTILES with burster or expelling charge† 1.4F 500 2

0428 ARTICLES, PYROTECHNIC for technical purposes† 1.1G 20 50

0429 ARTICLES, PYROTECHNIC for technical purposes† 1.2G 20 50

0430 ARTICLES, PYROTECHNIC 1.3G 50 20 2 2; 3; 6; 9

1

0431 ARTICLES, PYROTECHNIC 1.4G 100 10 2 2; 3; 6; 9

1

0432 ARTICLES, PYROTECHNIC 1.4S Unlimited 2 2; 3; 6; 9

1

0433 POWDER CAKE (POWDER PASTE), WETTED with not less than 17 % alcohol, by mass†

1.1C 20 50

0434 PROJECTILES with burster or expelling charge† 1.2G 20 50

0435 PROJECTILES with burster or expelling charge† 1.4G 500 2

0436 ROCKETS with expelling charge† 1.2C 20 50



0439 CHARGES, SHAPED, without detonator† 1.2D 20 50

0440 CHARGES, SHAPED, without detonator† 1.4D 500 2

0441 CHARGES, SHAPED, without detonator† 1.4S Unlimited

0442 CHARGES, EXPLOSIVE, COMMERCIAL without detonator†

1.1D 20 50


1.2D 20 50


1.4D 500 2


1.4S Unlimited

0446 CASES, COMBUSTIBLE, EMPTY, without primer† 1.4C 500 2

0447 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER†

1.3C 20 50

0448 5-MERCAPTOTETRAZOL-1-ACETIC ACID† 1.4C 500 2

0449 TORPEDOES, LIQUID FUELLED with or without bursting charge†

1.1J 20 50

0450 TORPEDOES, LIQUID FUELLED with inert head† 1.3J 20 50

0451 TORPEDOES with bursting charge† 1.1D 20 50


0453 ROCKETS, LINE-THROWING 1.4G 250 4 2 2; 3; 6; 9

0454 IGNITERS 1.4S Unlimited 2 2; 3; 9 1

0455 DETONATORS, NON-ELECTRIC for blasting† 1.4S Unlimited

0456 DETONATORS, ELECTRIC for blasting† 1.4S Unlimited



0457 CHARGES, BURSTING, PLASTICS BONDED 1.1D 20 50



0460 CHARGES, BURSTING, PLASTICS BONDED 1.4S Unlimited




0464 ARTICLES, EXPLOSIVE, N.O.S. 1.1E 20 50

0465 ARTICLES, EXPLOSIVE, N.O.S. 1.1F 20 50








0473 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1A 0

0474 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1C 20 50

0475 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1D 20 50

0476 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1G 20 50




0480 SUBSTANCES, EXPLOSIVE, N.O.S. 1.4D 500 2

0481 SUBSTANCES, EXPLOSIVE, N.O.S. 1.4S Unlimited

0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI), N.O.S.†

1.5D 20 50

0483 CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLONITE; HEXOGEN; RDX), DESENSITIZED

1.1D 20 50

0484 CYCLOTETRA-METHYLENETETRA-NITRAMINE (HMX; OCTOGEN), DESENSITIZED

1.1D 20 50


0486 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI)†

1.6N 500 2

0487 SIGNALS, SMOKE 1.3G 50 20 2 2; 3; 6; 9

1

0488 AMMUNITION, PRACTICE† 1.3G 20 50

0489 DINITROGLYCOLURIL (DINGU)† 1.1D 20 50

0490 NITROTRIAZOLONE (NTO)† 1.1D 20 50

0491 CHARGES, PROPELLING† 1.4C 500 2

0492 SIGNALS, RAILWAY TRACK, EXPLOSIVE† 1.3G 20 50



0493 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1.4G 30 x units 2 x plastic boxes

2 2; 3; 8; 9

1

0494 JET PERFORATING GUNS, CHARGED, oil well, without detonator†

1.4D 0494 500 2

0495 PROPELLANT, LIQUID† 1.3C 0495 20 50

0496 OCTONAL 1.1D 0496 20 50

0497 PROPELLANT, LIQUID† 1.1C 0497 20 50

0498 PROPELLANT, SOLID† 1.1C 0498 20 50



1.4S 0500 Unlimited


0502 ROCKETS with inert head† 1.2C 0502 20 50

0503 AIR BAG INFLATORS, or AIR BAG MODULES, or SEAT-BELT PRETENSIONERS†

1.4G 0503 500 2

0504 1H-TETRAZOLE 1.1D 0504 20 50

0505 SIGNALS, DISTRESS, ship 1.4G 250 4 2 2; 3; 6; 9

1

0506 SIGNALS, DISTRESS, ship 1.4S Unlimited 3 2; 3; 6; 9

1

0507 SIGNALS, SMOKE 1.4S Unlimited 3 2; 3; 6; 9

1

0508 1-HYDROXYBENZO-TRIAZOLE, ANHYDROUS, dry or wetted with less than 20 % water, by mass

1.3C 20 50

0509 O\POWDER, SMOKELESS 1.4C 500 2

1001 ACETYLENE, DISSOLVED 2.1 100 10 9; 10; 36

2

1002 AIR, COMPRESSED 2.2 500 2 9; 10

1003 AIR, REFRIGERATED LIQUID 2.2 5.1 200 5 5 9; 11; 36

20

1005 AMMONIA, ANHYDROUS 2.3 8 100 10 9; 10; 36

7; 17

1006 ARGON, COMPRESSED 2.2 500 2 9; 10; 36

1008 BORON TRIFLUORIDE 2.3 8 10 100 9; 10; 36

7; 17

1009 BROMOTRIFLUORO-METHANE (REFRIGERANT GAS R 13B1)

2.2 500 2 9; 10; 36

1010 1,2-BUTADIENE, STABILIZED or 1,3-BUTA-DIENE STABILIZED or MIXTURES OF 1,3-BUTA-DIENE AND HYDRO-CARBONS, STABILIZED, having a vapour pressure at 70 °C < 1,1 MPa (11 bar) and a density at 50°C > 0,525 kg/L

2.1 100 10 9; 10; 36

2; 20



1011 BUTANE 2.1 100 10 9; 10; 36

2; 20

1012 BUTYLENES MIXTURE or 1-BUTYLENE or CIS- 2-BUTYLENE or TRANS-2-BUTYLENE

2.1 100 10 9; 10; 36

2; 20

1013 CARBON DIOXIDE 2.2 500 2 9; 10; 36

1014 CARBON DIOXIDE AND OXYGEN MIXTURE, COMPRESSED

2.2 5.1 200 5 9; 10; 36

1015 CARBON DIOXIDE AND NITROUS OXIDE MIXTURE 2.2 500 2 9; 10; 36

1016 CARBON MONOXIDE, COMPRESSED 2.3 2.1 50 20 9; 10; 36

2; 7; 17

1017 CHLORINE 2.3 8 10 100 9; 10; 36

7; 17

1018 CHLORODIFLUORO-METHANE (REFRIGERANT GAS R 22)

2.2 500 2 9; 10; 36

1020 CHLOROPENTA-FLUOROETHANE (REFRIGERANT GAS R 115)

2.2 500 2 9; 10; 36

1021 1-CHLORO-1,2,2,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 124)

2.2 500 2 9; 10; 36

1022 CHLOROTRIFLUORO-METHANE (REFRIGERANT GAS R 13)

2.2 500 2 9; 10; 36

1023 COAL GAS, COMPRESSED 2.3 2.1 10 100 9; 10; 36

2; 7; 17

1026 CYANOGEN 2.3 2.1 10 100 9; 10; 36

2; 7; 17

1027 CYCLOPROPANE 2.1 100 10 9; 10; 36

2; 20

1028 DICHLORODIFLUORO-METHANE (REFRI-GERANT GAS R 12)

2.2 500 2 9; 10; 36

1029 DICHLOROFLUORO-METHANE (REFRI-GERANT GAS R 21)

2.2 500 2 9; 10; 36

1030 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a)

2.1 100 10 9; 10; 36

2; 20

1032 DIMETHYLAMINE, ANHYDROUS 2.1 100 10 9; 10; 36

2; 20

1033 DIMETHYL ETHER 2.1 100 10 9; 10; 36

2; 20

1035 ETHANE 2.1 100 10 9; 10; 36

2; 20

1036 ETHYLAMINE 2.1 100 10 9; 10; 36

2; 20



1037 ETHYL CHLORIDE 2.1 100 10 9; 10; 36

2; 20

1038 ETHYLENE, REFRIGERATED LIQUID 2.1 100 10 5 9; 11; 36

2,17

1039 ETHYL METHYL ETHER 2.1 100 10 9; 10; 36

2; 20

1040 ETHYLENE OXIDE 2.3 2.1 10 100 9; 10; 36

2; 7; 17

1040 ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50 °C

2.3 2.1 10 100 9; 10; 36

2; 7; 17

1041 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with > 9 % but < 87 % ethylene oxide

2.1 100 10 9; 10; 36

2; 20

1043 FERTILIZER AMMO-NIATING SOLUTION with free ammonia

2.2 500 2

1044 FIRE EXTINGUISHERS with compressed or liquefied gas

2.2 500 2 9

1045 FLUORINE, COMPRESSED 2.3 5.1 8

10 100 9; 10; 36

7; 17

1046 HELIUM, COMPRESSED 2.2 500 2 9; 10; 36

1048 HYDROGEN BROMIDE, ANHYDROUS 2.3 8 10 100 9; 10; 36

7; 17

1049 HYDROGEN, COMPRESSED 2.1 100 10 9; 10; 36

2

1050 HYDROGEN CHLORIDE, ANHYDROUS 2.3 8 10 100 9; 10; 36

7; 17

1051 HYDROGEN CYANIDE, STABILIZED containing < 3 % water

6.1 I 3 5 200 1; 13; 28

2; 9; 10; 17

1052 HYDROGEN FLUORIDE, ANHYDROUS 8 I 6.1 5 200 13; 28; 34

17

1053 HYDROGEN SULFIDE 2.3 2.1 10 100 9; 10; 36

2; 7; 17

1055 ISOBUTYLENE 2.1 100 10 9; 10; 36

2; 20

1056 KRYPTON, COMPRESSED 2.2 500 2 9; 10; 36

1057 LIGHTERS or LIGHTER REFILLS containing flammable gas

2.1 100 10 9 2

1058 LIQUEFIED GASES, non-flammable, charged with nitrogen, carbon dioxide or air

2.2 500 2 9; 10; 36

1060 METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED

2.1 100 10 9; 10; 36

2; 20

1061 METHYLAMINE, ANHYDROUS 2.1 100 10 9; 10; 36

2; 20

1062 METHYL BROMIDE with < 2 % chloropicrin 2.3 10 100 9; 10; 36

7; 17



1063 METHYL CHLORIDE (REFRIGERANT GAS R 40)

2.1 100 10 9; 10; 36

2; 20

1064 METHYL MERCAPTAN 2.3 2.1 10 100 9; 10; 36

2; 7; 17

1065 NEON, COMPRESSED 2.2 500 2 9; 10; 36

1066 NITROGEN, COMPRESSED 2.2 500 2 9; 10; 36

1067 DINITROGEN TETROXIDE (NITROGEN DIOXIDE) 2.3 5.1 8

10 100 9; 10; 36

7; 17

1069 NITROSYL CHLORIDE 2.3 8 10 100 9; 10; 36

7; 17

1070 NITROUS OXIDE 2.2 5.1 200 5 9; 10; 36

1071 OIL GAS, COMPRESSED 2.3 2.1 10 100 9; 10; 36

2; 7; 17

1072 OXYGEN, COMPRESSED 2.2 5.1 200 5 9; 10; 36

1073 OXYGEN, REFRIGERATED LIQUID 2.2 5.1 200 5 5 9; 11; 36

20

1075 PETROLEUM GASES, LIQUEFIED 2.1 100 10 9; 10; 36

2; 20

1076 PHOSGENE 2.3 8 10 100 9; 10; 36

7; 17

1077 PROPYLENE 2.1 100 10 9; 10; 36

2; 20

1078 REFRIGERANT GAS, N.O.S 2.2 500 2 9; 10; 36

1079 SULFUR DIOXIDE 2.3 8 50 20 9; 10; 36

7; 17

1080 SULFUR HEXAFLUORIDE 2.2 500 2 9; 10; 36

1081 TETRAFLUORO-ETHYLENE, STABILIZED 2.1 100 10 9; 10; 36

2; 20

1082 TRIFLUOROCHLORO-ETHYLENE, STABILIZED 2.3 2.1 10 100 9; 10; 36

2; 7; 17

1083 TRIMETHYLAMINE, ANHYDROUS 2.1 100 10 9; 10; 36

2; 20

1085 VINYL BROMIDE, STABILIZED 2.1 100 10 9; 10; 36

2; 20

1086 VINYL CHLORIDE, STABILIZED 2.1 100 10 9; 10; 36

2; 20

1087 VINYL METHYL ETHER, STABILIZED 2.1 100 10 9; 10; 36

2; 20

1088 ACETAL 3 II 500 2 2; 20

1089 ACETALDEHYDE 3 I 100 10 2; 20



1090 ACETONE 3 II 500 2 2; 20

1091 ACETONE OILS 3 II 500 2 2; 20

1092 ACROLEIN, STABILIZED 6.1 I 3 5 200 1; 13; 28

2; 9; 17

1093 ACRYLONITRILE, STABILIZED 3 I 6.1 50 20 13; 28 2; 19

1098 ALLYL ALCOHOL 6.1 I 3 5 200 1; 13; 28

2; 9; 17

1099 ALLYL BROMIDE 3 I 6.1 50 20 13; 28 2; 19

1100 ALLYL CHLORIDE 3 I 6.1 50 20 13; 28 2; 19

1104 AMYL ACETATES 3 III 1 000 1 2

1105 PENTANOLS 3 II 500 2 2; 20

1105 PENTANOLS 3 III 1000 1 2

1106 AMYLAMINE 3 II 8 200 5 2; 20

1106 AMYLAMINE 3 III 8 500 2 2

1107 AMYL CHLORIDE 3 II 500 2 2; 20

1108 1-PENTENE (n-AMYLENE) 3 I 100 10 2; 20

1109 AMYL FORMATES 3 III 1 000 1 2

1110 n-AMYL METHYL KETONE 3 III 1 000 1 2

1111 AMYL MERCAPTAN 3 II 500 2 2; 20

1112 AMYL NITRATE 3 III 1 000 1 2

1113 AMYL NITRITE 3 II 500 2 2; 20

1114 BENZENE 3 II 500 2 2; 20

1120 BUTANOLS 3 II 500 2 2; 20

1120 BUTANOLS 3 III 1000 1 2

1123 BUTYL ACETATES 3 II 500 2 2; 20 2; 20

1123 BUTYL ACETATES 3 III 1000 1 2

1125 n-BUTYLAMINE 3 II 8 200 5 2; 20

1126 1-BROMOBUTANE 3 II 500 2 2; 20

1127 CHLOROBUTANES 3 II 500 2 2; 20

1128 n-BUTYL FORMATE 3 II 500 2 2; 20

1129 BUTYRALDEHYDE 3 II 500 2 2; 20

1130 CAMPHOR OIL 3 III 1 000 1 2

1131 CARBON DISULFIDE 3 I 6.1 50 20 13; 28 2; 19

1133 ADHESIVES containing flammable liquid 3 I 100 10 2; 20

1133 ADHESIVES containing flammable liquid 3 II 500 2 2; 20

1133 ADHESIVES containing flammable liquid 3 III 1000 1 2

1134 CHLOROBENZENE 3 III 1 000 1 2

1135 ETHYLENE CHLOROHYDRIN 6.1 I 3 5 200 1; 13; 28

2; 9; 17

1136 COAL TAR DISTILLATES, FLAMMABLE 3 II 500 2 2; 20



1136 COAL TAR DISTILLATES, FLAMMABLE 3 III 1000 1 2

1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining)

3 I 100 10 2; 20


3 II 500 2 2; 20


3 III 1000 1 2

1143 CROTONALDEHYDE, STABILIZED 6.1 I 3 5 200 1; 13; 28

2; 9; 17

1144 CROTONYLENE 3 I 100 10 2; 20

1145 CYCLOHEXANE 3 II 500 2 2; 20

1146 CYCLOPENTANE 3 II 500 2 2; 20

1147 DECAHYDRO-NAPHTHALENE 3 III 1 000 1 2

1148 DIACETONE ALCOHOL 3 II 500 2 2; 20

1148 DIACETONE ALCOHOL 3 III 1000 1 2

1149 DIBUTYL ETHERS 3 III 1 000 1 2

1150 1,2-DICHLORO-ETHYLENE 3 II 500 2 2; 20

1152 DICHLOROPENTANES 3 III 1 000 1 2

1153 ETHYLENE GLYCOL DIETHYL ETHER 3 II 500 2 2; 20

1153 ETHYLENE GLYCOL DIETHYL ETHER 3 III 1000 1 2

1154 DIETHYLAMINE 3 II 8 200 5 2; 20

1155 DIETHYL ETHER (ETHYL ETHER) 3 I 100 10 2; 20

1156 DIETHYL KETONE 3 II 500 2 2; 20

1157 DIISOBUTYL KETONE 3 III 1 000 1 2

1158 DIISOPROPYLAMINE 3 II 8 200 5 2; 20

1159 DIISOPROPYL ETHER 3 II 500 2 2; 20

1160 DIMETHYLAMINE AQUEOUS SOLUTION 3 II 8 200 5 2; 20

1161 DIMETHYL CARBONATE 3 II 500 2 2; 20

1162 DIMETHYLDICHLORO-SILANE 3 II 8 200 5 2; 20

1163 DIMETHYLHYDRAZINE, UNSYMMETRICAL 6.1 I 3; 8 5 200 1; 13; 28

2; 9; 17

1164 DIMETHYL SULFIDE 3 II 500 2 2; 20

1165 DIOXANE 3 II 500 2 2; 20

1166 DIOXOLANE 3 II 500 2 2; 20

1167 DIVINYL ETHER, STABILIZED 3 I 100 10 2; 20

1169 EXTRACTS, AROMATIC, LIQUID 3 I 100 10 2; 20

1169 EXTRACTS, AROMATIC, LIQUID 3 II 500 2 2; 20

1169 EXTRACTS, AROMATIC, LIQUID 3 III 1000 1 2



1170 ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

3 II 500 2 2; 20

1170 ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

3 III 1000 1 2

1171 ETHYLENE GLYCOL MONOETHYL ETHER 3 III 1 000 1 2

1172 ETHYLENE GLYCOL MONOETHYL ETHER ACETATE

3 III 1 000 1 2

1173 ETHYL ACETATE 3 II 500 2 2; 20

1175 ETHYLBENZENE 3 II 500 2 2; 20

1176 ETHYL BORATE 3 II 500 2 2; 20

1177 2-ETHYLBUTYL ACETATE 3 III 1 000 1 2

1178 2-ETHYL-BUTYRALDEHYDE 3 II 500 2 2; 20

1179 ETHYL BUTYL ETHER 3 II 500 2 2; 20

1180 ETHYL BUTYRATE 3 III 1 000 1 2

1181 ETHYL CHLORO-ACETATE 6.1 II 3 5 200 13; 28 2; 9; 19

1182 ETHYL CHLORO-FORMATE 6.1 I 3; 8 5 200 1; 13; 28

2; 9; 17

1183 ETHYLDICHLORO-SILANE 4.3 I 3; 8 0 1 23 2; 20

1184 ETHYLENE DICHLORIDE 3 II 6.1 200 5 13; 28 2; 19

1185 ETHYLENEIMINE, STABILIZED 6.1 I 3 5 200 1; 13; 28

2; 9; 17

1188 ETHYLENE GLYCOL MONOMETHYL ETHER 3 III 1 000 1 2

1189 ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE

3 III 1 000 1 2

1190 ETHYL FORMATE 3 II 500 2 2; 20

1191 OCTYL ALDEHYDES 3 III 1 000 1 2

1192 ETHYL LACTATE 3 III 1 000 1 2

1193 ETHYL METHYL KETONE 3 II 500 2 2; 20

1194 ETHYL NITRITE SOLUTION 3 I 6.1 50 20 13; 28 2; 19

1195 ETHYL PROPIONATE 3 II 500 2 2; 20

1196 ETHYLTRICHLORO-SILANE 3 II 8 200 5 2; 20

1197 EXTRACTS, FLAVOURING, LIQUID 3 I 100 10 2; 20

1197 EXTRACTS, FLAVOURING, LIQUID 3 II 500 2 2; 20

1197 EXTRACTS, FLAVOURING, LIQUID 3 III 1000 1 2

1198 FORMALDEHYDE SOLUTION, FLAMMABLE 3 III 8 500 2 2

1199 FURALDEHYDES 6.1 II 3 5 200 13; 28 2; 9; 19

1201 FUSEL OIL 3 II 500 2 2; 20

1201 FUSEL OIL 3 III 1000 1 2

1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT, flash point < 60,5 °C c.c.

3 III 1 000 1 2

1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT, flash point > 60,5 °C c.c.

3 III 1 000 1



1202 DIESEL FUEL complying with standard EN 590:1993 or GAS OIL or HEATING OIL, LIGHT with a flash point as specified in EN 590:1993

3 III 1 000 1 2

1203 MOTOR SPIRIT or GASOLINE or PETROL 3 II 500 2 2; 20

1204 NITROGLYCERIN SOLUTION IN ALCOHOL with < 1 % nitroglycerin

3 II 500 2

1206 HEPTANES 3 II 500 2 2; 20

1207 HEXALDEHYDE 3 III 1 000 1 2; 20

1208 HEXANES 3 II 500 2 2

1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound)

3 I 100 10 2; 20


3 II 500 2 2; 20


3 III 1000 1 2

1212 ISOBUTANOL (ISOBUTYL ALCOHOL) 3 III 1 000 1 2

1213 ISOBUTYL ACETATE 3 II 500 2 2; 20

1214 ISOBUTYLAMINE 3 II 8 200 5 2; 20

1216 ISOOCTENES 3 II 500 2 2; 20

1218 ISOPRENE, STABILIZED 3 I 100 10 2; 20

1219 ISOPROPYL ALCOHOL (ISOPROPANOL) 3 II 500 2 2; 20

1220 ISOPROPYL ACETATE 3 II 500 2 2; 20

1221 ISOPROPYLAMINE 3 I 8 50 20 2; 20

1222 ISOPROPYL NITRATE 3 II 500 2 2; 20

1223 KEROSENE 3 III 1 000 1 2

1224 KETONES, LIQUID, N.O.S. 3 II 500 2 2; 20

1224 KETONES, LIQUID, N.O.S. 3 III 1000 1 2

1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN, MIXTURE LIQUID, FLAMMABLE, TOXIC, N.O.S.

3 II 6.1 200 5 13; 28 2; 19

1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN, MIXTURE LIQUID, FLAMMABLE, TOXIC, N.O.S.

3 III 6.1 500 2 13; 28 2

1229 MESITYL OXIDE 3 III 1 000 1 2

1230 METHANOL 3 II 6.1 200 5 13; 28 2; 19

1231 METHYL ACETATE 3 II 500 2 2; 20

1233 METHYLAMYL ACETATE 3 III 1 000 1 2

1234 METHYLAL 3 II 500 2 2; 20

1235 METHYLAMINE, AQUEOUS SOLUTION 3 II 8 200 5 2; 20

1237 METHYL BUTYRATE 3 II 500 2 2; 20



1238 METHYL CHLORO-FORMATE 6.1 I 3; 8 5 200 1; 13; 28

2; 9; 17

1239 METHYL CHLORO-METHYL ETHER 6.1 I 3 5 200 1; 13; 28

2; 9; 17

1242 METHYLDICHLORO-SILANE 4.3 I 3; 8 0 1 23 2; 20

1243 METHYL FORMATE 3 I 100 10 2; 20

1244 METHYLHYDRAZINE 6.1 I 3; 8 5 200 1; 13; 28

2; 9; 17

1245 METHYL ISOBUTYL KETONE 3 II 500 2 2; 20

1246 METHYL ISOPROPENYL KETONE, STABILIZED 3 II 500 2 2; 20

1247 METHYL METHA-CRYLATE MONOMER, STABILIZED

3 II 500 2 2; 20

1248 METHYL PROPIONATE 3 II 500 2 2; 20

1249 METHYL PROPYL KETONE 3 II 500 2 2; 20

1250 METHYLTRICHLORO-SILANE 3 I 8 50 20 2; 20

1251 METHYL VINYL KETONE, STABILIZED 6.1 I 3; 8 5 200 1; 13; 28

2; 9; 17

1259 NICKEL CARBONYL 6.1 I 3 5 200 1; 13; 28

2; 9; 17

1261 NITROMETHANE 3 II 500 2 2; 20

1262 OCTANES 3 II 500 2 2; 20

1263 PAINT or PAINT RELATED MATERIAL 3 I 100 10 2; 20

1263 PAINT or PAINT RELATED MATERIAL 3 II 500 2 2; 20

1263 PAINT or PAINT RELATED MATERIAL 3 III 1000 1 2

1264 PARALDEHYDE 3 III 1 000 1 2

1265 PENTANES, liquid 3 I 100 10 2; 20

1265 PENTANES, liquid 3 II 500 2 2; 20

1266 PERFUMERY PRODUCTS with flammable solvents 3 I 100 10 2; 20

1266 PERFUMERY PRODUCTS with flammable solvents 3 II 500 2 2; 20

1266 PERFUMERY PRODUCTS with flammable solvents 3 III 1000 1 2

1267 PETROLEUM CRUDE OIL 3 I 100 10 2; 20

1267 PETROLEUM CRUDE OIL 3 II 500 2 2; 20

1267 PETROLEUM CRUDE OIL 3 III 1000 1 2

1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S.

3 I 10 10 2; 20


3 II 500 2 2; 20


3 III 1000 1 2

1272 PINE OIL 3 III 1 000 1 2

1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) 3 II 500 2 2; 20

1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) 3 III 1000 1 2



1275 PROPIONALDEHYDE 3 II 500 2 2; 20

1276 n-PROPYL ACETATE 3 II 500 2 2; 20

1277 PROPYLAMINE 3 II 8 200 5 2; 20

1278 1-CHLOROPROPANE 3 II 500 2 2; 20

1279 1,2-DICHLOROPROPANE 3 II 500 2 2; 20

1280 PROPYLENE OXIDE 3 I 100 10 2; 20

1281 PROPYL FORMATES 3 II 500 2 2; 20

1282 PYRIDINE 3 II 500 2 2; 20

1286 ROSIN OIL 3 I 100 10 2; 20

1286 ROSIN OIL 3 II 500 2 2; 20

1286 ROSIN OIL 3 III 1000 1 2

1287 RUBBER SOLUTION 3 I 100 10 2; 20

1287 RUBBER SOLUTION 3 II 500 2 2; 20

1287 RUBBER SOLUTION 3 III 1000 1 2

1288 SHALE OIL 3 II 500 2 2; 20

1288 SHALE OIL 3 III 1000 1 2

1289 SODIUM METHYLATE SOLUTION in alcohol 3 II 8 200 5 2; 20

1289 SODIUM METHYLATE SOLUTION in alcohol 3 III 8 500 2 2

1292 TETRAETHYL SILICATE 3 III 1 000 1 2

1293 TINCTURES, MEDICINAL 3 II 500 2 2; 20

1293 TINCTURES, MEDICINAL 3 III 1000 1 2

1294 TOLUENE 3 II 500 2 2; 20

1295 TRICHLOROSILANE 4.3 I 3; 8 0 1 23 2; 20

1296 TRIETHYLAMINE 3 II 8 200 5 2; 20

1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, < 50 % trimethylamine, by mass

3 I 8 50 20 2; 20


3 II 8 200 5 2; 20


3 III 8 500 2 2

1298 TRIMETHYLCHLORO-SILANE 3 II 8 200 5 2; 20

1299 TURPENTINE 3 III 1 000 1 2

1300 TURPENTINE SUBSTITUTE 3 II 500 2 2; 20

1300 TURPENTINE SUBSTITUTE 3 III 1000 1 2

1301 VINYL ACETATE, STABILIZED 3 II 500 2 2; 20

1302 VINYL ETHYL ETHER, STABILIZED 3 I 100 10 2; 20

1303 VINYLIDENE CHLORIDE, STABILIZED 3 I 100 10 2; 20

1304 VINYL ISOBUTYL ETHER, STABILIZED 3 II 500 2 2; 20

1305 VINYLTRICHLORO-SILANE 3 I 8 50 20 2; 20

1306 WOOD PRESERVATIVES, LIQUID 3 II 500 2 2; 20



1306 WOOD PRESERVATIVES, LIQUID 3 III 1000 1 2

1307 XYLENES 3 II 500 2 2; 20

1307 XYLENES 3 III 1000 1 2

1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID 3 I 100 10 2; 20

1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID 3 II 500 2 2; 20

1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID 3 III 1000 1 2

1309 ALUMINIUM POWDER, COATED 4.1 II 50 20 11

1309 ALUMINIUM POWDER, COATED 4.1 III 500 2 1

1310 AMMONIUM PICRATE, WETTED with > 10 % water, by mass

4.1 I 0 17

1312 BORNEOL 4.1 III 500 2 1

1313 CALCIUM RESINATE 4.1 III 500 2 12 1

1314 CALCIUM RESINATE, FUSED 4.1 III 500 2 1

1318 COBALT RESINATE, PRECIPITATED 4.1 III 500 2 12 1

1320 DINITROPHENOL, WETTED with > 15 % water, by mass

4.1 I 6.1 0 28 17

1321 DINITROPHENOLATES, WETTED with > 15 % water, by mass

4.1 I 6.1 0 28 17

1322 DINITRORESORCINOL, WETTED with > 15 % water, by mass

4.1 I 0 17

1323 FERROCERIUM 4.1 II 50 20 11

1324 FILMS, NITROCEL-LULOSE BASE, gelatin coated, except scrap

4.1 III 500 2

1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 4.1 II 50 20 11

1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 4.1 III 500 2 1

1326 HAFNIUM POWDER, WETTED with > 25 % water 4.1 II 50 20 11; 12

1327 Hay, Straw, or Bhusa 4.1 Not dangerous for road transport

1328 HEXAMETHYLENE-TETRAMINE 4.1 III 500 2 1

1330 MANGANESE RESINATE 4.1 III 500 2 12 1

1331 MATCHES, 'STRIKE ANYWHERE' 4.1 III 500 2

1332 METALDEHYDE 4.1 III 500 2 1

1333 CERIUM, slabs, ingots or rods 4.1 II 50 20 11

1334 NAPHTHALENE, CRUDE or NAPHTHALENE, REFINED

4.1 III 500 2 2

1336 NITROGUANIDINE (PICRITE), WETTED with > 20 % water, by mass

4.1 I 0 17

1337 NITROSTARCH, WETTED with > 20 % water, by mass

4.1 I 0 17

1338 PHOSPHORUS, AMORPHOUS 4.1 III 500 2 1

1339 PHOSPHORUS HEPTA-SULFIDE, free from yellow and white phosphorus

4.1 II 50 20



1340 PHOSPHORUS PENTA-SULFIDE, free from yellow and white phosphorus

4.3 II 4.1 20 50 1 23

1341 PHOSPHORUS SESQUI-SULFIDE, free from yellow and white phosphorus

4.1 II 50 20

1343 PHOSPHORUS TRI-SULFIDE, free from yellow and white phosphorus

4.1 II 50 20

1341 PHOSPHORUS SESQUI-SULFIDE, free from yellow and white phosphorus

4.1 II 50 20

1343 PHOSPHORUS TRI-SULFIDE, free from yellow and white phosphorus

4.1 II 50 20

1344 TRINITROPHENOL, WETTED with > 30 % water, by mass

4.1 I 0 17

1345 RUBBER SCRAP or RUBBER SHODDY, powdered or granulated

4.1 II 50 20 11

1346 SILICON POWDER, AMORPHOUS 4.1 III 500 2 1

1347 SILVER PICRATE, WETTED with > 30 % water, by mass

4.1 I 0 17

1348 SODIUM DINITRO-ortho-CRESOLATE, WETTED with > 15 % water, by mass

4.1 I 6.1 0 28 17

1349 SODIUM PICRAMATE, WETTED with > 20 % water, by mass

4.1 I 0 17

1350 SULFUR 4.1 III 500 2 1

1352 TITANIUM POWDER, WETTED with > 25 % water 4.1 II 50 20 11; 12

1353 FABRICS or FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S.

4.1 III 500 2

1354 TRINITROBENZENE, WETTED with > 30 % water, by mass

4.1 I 0 17

1355 TRINITROBENZOIC ACID, WETTED with > 30 % water, by mass

4.1 I 0 17

1356 TRINITROTOLUENE (TNT), WETTED with > 30 % water, by mass

4.1 I 0 17

1357 UREA NITRATE, WETTED with > 20 % water, by mass

4.1 I 0 17

1358 ZIRCONIUM POWDER, WETTED with > 25 % water 4.1 II 50 20 11; 12

1360 CALCIUM PHOSPHIDE 4.3 I 6.1 0 1 23; 28 20

1361 CARBON, animal or vegetable origin 4.2 II 100 10 1; 12; 13

1361 CARBON, animal or vegetable origin 4.2 III 200 5 1; 13 4

1362 CARBON, ACTIVATED 4.2 III 200 5 1 4

1363 COPRA 4.2 III 200 5 1 4

1364 COTTON WASTE, OILY 4.2 III 200 5 1 4

1365 COTTON, WET 4.2 III 200 5 1 4

1366 DIETHYLZINC 4.2 I 4.3 0 1 20

1369 p-NITROSODIMETHYL-ANILINE 4.2 II 100 10 1; 12

1370 DIMETHYLZINC 4.2 I 4.3 0 1 20



1372 Fibres, animal or fibres, vegetable burnt, wet or damp 4.2 Not dangerous for road transport

1373 FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S., with oil

4.2 III 200 5 1 4

1374 FISH MEAL (FISH SCRAP), UNSTABILIZED 4.2 II 100 10 1

1376 IRON OXIDE, SPENT or IRON SPONGE, SPENT obtained from coal gas purification

4.2 III 200 5 1 4

1378 METAL CATALYST, WETTED with a visible excess of liquid

4.2 II 100 10 1

1379 PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper)

4.2 III 200 5 1 4

1380 PENTABORANE 4.2 I 6.1 0 1 28 20

1381 PHOSPHORUS WHITE or YELLOW, UNDER WATER or IN SOLUTION

4.2 I 6.1 0 1 28 20

PHOSPHORUS WHITE or YELLOW, DRY 4.2 I 6.1 0 1 28 20

1382 POTASSIUM SULFIDE, ANHYDROUS or POTASSIUM SULFIDE with < 30 % water of crystallization

4.2 II 100 10 1; 12

1383 PYROPHORIC METAL, N.O.S or PYROPHORIC ALLOY, N.O.S.

4.2 I 0 1 20

1384 SODIUM DITHIONITE (SODIUM HYDRO-SULFITE) 4.2 II 100 10 1; 12

1385 SODIUM SULFIDE, ANHYDROUS or SODIUM SULFIDE with < 30 % water of crystallization

4.2 II 100 10 1; 12

1386 SEED CAKE with > 1,5 % oil and < 11 % moisture 4.2 III 200 5 1 4

1387 Wool waste, wet 4.2 Not dangerous for road transport

1389 ALKALI METAL AMALGAM, LIQUID 4.3 I 0 1 23 20

1389 ALKALI METAL AMALGAM, LIQUID 4.3 I 0 1 23 20

1390 ALKALI METAL AMIDES 4.3 II 100 10 1; 12 23

1391 ALKALINE METAL DISPERSION or ALKALINE EARTH METAL DISPERSION

4.3 I 0 1 23 20

1392 ALKALINE EARTH METAL AMALGAM, LIQUID 4.3 I 0 1 23 20

1393 ALKALINE EARTH METAL ALLOY, N.O.S. 4.3 II 100 10 1; 12 23

1394 ALUMINIUM CARBIDE 4.3 II 100 10 1; 12 5 23

1395 ALUMINIUM FERRO-SILICON POWDER 4.3 II 6.1 20 50 1 23; 28

1396 ALUMINIUM POWDER, UNCOATED 4.3 II 100 10 1; 12 23

1396 ALUMINIUM POWDER, UNCOATED 4.3 III 500 2 1 5 23

1397 ALUMINIUM PHOSPHIDE 4.3 I 6.1 0 1 23; 28 20

1398 ALUMINIUM SILICON POWDER, UNCOATED 4.3 III 500 2 1 5 23

1400 BARIUM 4.3 II 100 10 1; 12 23

1401 CALCIUM 4.3 II 100 10 1; 12 23

1402 CALCIUM CARBIDE 4.3 I 0 1 23 20

1402 CALCIUM CARBIDE 4.3 II 100 10 1 5 23

1403 CALCIUM CYANAMIDE with >0,1% calcium carbide 4.3 III 500 2 1 23



1404 CALCIUM HYDRIDE 4.3 I 0 1 23 20

1405 CALCIUM SILICIDE 4.3 II 100 10 1; 12 7 23

1405 CALCIUM SILICIDE 423.3 III 500 2 1 5; 7 23

1407 CAESIUM 4.3 I 0 1 23 20

1408 FERROSILICON with > 30 % but < 90 % silicon 4.3 III 6.1 100 10 1 1 23; 28

1409 METAL HYDRIDES, WATER-REACTIVE, N.O.S. 4.3 I 0 1 23 20

1409 METAL HYDRIDES, WATER-REACTIVE, N.O.S. 4.3 II 100 10 1 23

1410 LITHIUM ALUMINIUM HYDRIDE 4.3 I 0 1 23 20

1411 LITHIUM ALUMINIUM HYDRIDE, ETHEREAL 4.3 I 3 0 1 23 2; 20

1413 LITHIUM BOROHYDRIDE 4.3 I 0 1 23 20

1414 LITHIUM HYDRIDE 4.3 I 0 1 23 20

1415 LITHIUM 4.3 I 0 1 23 20

1417 LITHIUM SILICON 4.3 II 100 10 1; 12 23

1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER

4.3 I 4.2 0 1 23 20


4.3 II 4.2 20 50 1 23


4.3 III 4.2 100 10 1 5 23

1419 MAGNESIUM ALUMINIUM PHOSPHIDE 4.3 I 6.1 0 1 23; 28 20

1420 POTASSIUM METAL ALLOYS, LIQUID 4.3 I 0 1 23 20

1421 ALKALI METAL ALLOY, LIQUID, N.O.S 4.3 I 0 1 23 20

1422 POTASSIUM SODIUM ALLOYS, LIQUID 4.3 I 0 1 23 20

1423 RUBIDIUM 4.3 I 0 1 23 20

1426 SODIUM BOROHYDRIDE 4.3 I 0 1 23 20

1427 SODIUM HYDRIDE 4.3 I 0 1 23 20

1428 SODIUM 4.3 I 0 1 23 20

1431 SODIUM METHYLATE 4.2 II 8 20 50 1

1432 SODIUM PHOSPHIDE 4.3 I 6.1 0 1 23; 28 20

1433 STANNIC PHOSPHIDES 4.3 I 6.1 0 1 23; 28 20

1435 ZINC ASHES 4.3 III 500 2 1 5 23

1436 ZINC POWDER or ZINC DUST 4.3 I 4.2 0 1 23 20

1436 ZINC POWDER or ZINC DUST 4.3 II 4.2 20 50 1; 12 23

1436 ZINC POWDER or ZINC DUST 4.3 III 4.2 100 10 1 5 23

1437 ZIRCONIUM HYDRIDE 4.1 II 50 20

1438 ALUMINIUM NITRATE 5.1 III 200 5 8 24

1439 AMMONIUM DICHROMATE 5.1 II 50 20 11 24

1442 AMMONIUM PERCHLORATE 5.1 II 50 20 6; 11; 12 8 24

1444 AMMONIUM PERSULFATE 5.1 III 200 5 8 24

1445 BARIUM CHLORATE, SOLID 5.1 II 6.1 20 50 11; 12 24; 28



1446 BARIUM NITRATE 5.1 II 6.1 20 50 11 24; 28

1447 BARIUM PERCHLORATE, SOLID 5.1 II 6.1 20 50 11; 12 24; 28

1448 BARIUM PERMAN-GANATE 5.1 II 6.1 20 50 11; 12 24; 28

1449 BARIUM PEROXIDE 5.1 II 6.1 20 50 11; 12 24; 28

1450 BROMATES, INORGANIC, N.O.S. 5.1 II 50 20 11 8 24

1451 CAESIUM NITRATE 5.1 III 200 5 8 24

1452 CALCIUM CHLORATE 5.1 II 50 20 11 8 24

1453 CALCIUM CHLORITE 5.1 II 50 20 11 24

1454 CALCIUM NITRATE 5.1 III 200 5 8 24

1455 CALCIUM PER-CHLORATE 5.1 II 50 20 11; 12 8 24

1456 CALCIUM PERMAN-GANATE 5.1 II 50 20 11; 12 24

1457 CALCIUM PEROXIDE 5.1 II 50 20 11; 12 24

1458 CHLORATE AND BORATE MIXTURE 5.1 II 50 20 11 8 24

1458 CHLORATE AND BORATE MIXTURE 5.1 III 200 5 8 24

1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID

5.1 II 50 20 11 8 24

1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID

5.1 III 200 5 8 24

1461 CHLORATES, INORGANIC, N.O.S. 5.1 II 50 20 11; 12 8 24

1462 CHLORITES, INORGANIC, N.O.S. 5.1 II 50 20 11; 12 24

1463 CHROMIUM TRIOXIDE, ANHYDROUS 5.1 II 8 20 50 24

1465 DIDYMIUM NITRATE 5.1 III 200 5 8 24

1466 FERRIC NITRATE 5.1 III 200 5 8 24

1467 GUANIDINE NITRATE 5.1 III 200 5 8 24

1469 LEAD NITRATE 5.1 II 6.1 20 50 11 24; 28

1470 LEAD PERCHLORATE, SOLID 5.1 II 6.1 20 50 11; 12 24; 28

1471 LITHIUM HYPO-CHLORITE, DRY or LITHIUM HYPO-CHLORITE MIXTURE

5.1 II 50 20 11 24

1472 LITHIUM PEROXIDE 5.1 II 50 20 11; 12 24

1473 MAGNESIUM BROMATE 5.1 II 50 20 8 24

1474 MAGNESIUM NITRATE 5.1 III 200 5 8 24

1475 MAGNESIUM PER-CHLORATE 5.1 II 50 20 11; 12 8 24

1476 MAGNESIUM PEROXIDE 5.1 II 50 20 11; 12 24

1477 NITRATES, INORGANIC, N.O.S. 5.1 II 50 20 11 24

1477 NITRATES, INORGANIC, N.O.S. 5.1 III 200 5 8 24

1479 OXIDIZING SOLID, N.O.S. 5.1 I 20 50 10 24 20

1479 OXIDIZING SOLID, N.O.S. 5.1 II 50 20 11 24

1479 OXIDIZING SOLID, N.O.S. 5.1 III 200 5 24

1481 PERCHLORATES, INORGANIC, N.O.S. 5.1 II 50 20 11; 12 8 24

1481 PERCHLORATES, INORGANIC, N.O.S. 5.1 III 200 5 8 24



1482 PERMANGANATES, INORGANIC, N.O.S. 5.1 II 50 20 11; 12 24

1482 PERMANGANATES, INORGANIC, N.O.S. 5.1 III 200 5 24

1483 PEROXIDES, INORGANIC, N.O.S. 5.1 II 50 20 11; 12 24

1483 PEROXIDES, INORGANIC, N.O.S. 5.1 III 200 5 24

1484 POTASSIUM BROMATE 5.1 II 50 20 8 24

1485 POTASSIUM CHLORATE 5.1 II 50 20 8 24

1486 POTASSIUM NITRATE 5.1 III 200 5 8 24

1487 POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE

5.1 II 50 20 8 24

1488 POTASSIUM NITRITE 5.1 II 50 20 8 24

1489 POTASSIUM PER-CHLORATE 5.1 II 50 20 11; 12 8 24

1490 POTASSIUM PERMAN-GANATE 5.1 II 50 20 24

1491 POTASSIUM PEROXIDE 5.1 I 20 50 10; 12 24 20

1492 POTASSIUM PER-SULFATE 5.1 III 200 5 8 24

1493 SILVER NITRATE 5.1 II 50 20 8 24

1494 SODIUM BROMATE 5.1 II 50 20 8 24

1495 SODIUM CHLORATE 5.1 II 50 20 8 24

1496 SODIUM CHLORITE 5.1 II 50 20 11 24

1498 SODIUM NITRATE 5.1 III 200 5 8 24

1499 SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE

5.1 III 200 5 8 24

1500 SODIUM NITRITE 5.1 III 6.1 100 10 24; 28

1502 SODIUM PERCHLORATE 5.1 II 50 20 11; 12 8 24

1503 SODIUM PERMAN-GANATE 5.1 II 50 20 11; 12 24

1504 SODIUM PEROXIDE 5.1 I 20 50 10 24 20

1505 SODIUM PERSULFATE 5.1 III 200 5 8 24

1506 STRONTIUM CHLORATE 5.1 II 50 20 11 8 24

1507 STRONTIUM NITRATE 5.1 III 200 5 8 24

1508 STRONTIUM PER-CHLORATE 5.1 II 50 20 11; 12 8 24

1509 STRONTIUM PEROXIDE 5.1 II 50 20 11; 12 24

1510 TETRANITROMETHANE 5.1 I 6.1 0 5 24; 28 20

1511 UREA HYDROGEN PEROXIDE 5.1 III 8 100 10 24

1512 ZINC AMMONIUM NITRITE 5.1 II 50 20 24

1513 ZINC CHLORATE 5.1 II 50 20 11 8 24

1514 ZINC NITRATE 5.1 II 50 20 24

1515 ZINC PERMANGANATE 5.1 II 50 20 11; 12 24

1516 ZINC PEROXIDE 5.1 II 50 20 11; 12 24

1517 ZIRCONIUM PICRAMATE, WETTED with > 20 % water, by mass

4.1 I 0 17

1541 ACETONE CYANO-HYDRIN, STABILIZED 6.1 I 5 200 1; 13; 28 9; 17



1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S.

6.1 I 5 200 10; 12 1; 13; 28 9; 17


6.1 II 50 20 11 13; 28 9; 19


6.1 III 100 10 9b 13; 28 9

1545 ALLYL ISOTHIO-CYANATE, STABILIZED 6.1 II 3 5 200 13; 28 2; 9; 19

1546 AMMONIUM ARSENATE 6.1 II 50 20 11 13; 28 9; 19

1547 ANILINE 6.1 II 50 20 13; 28 9; 19

1548 ANILINE HYDRO-CHLORIDE 6.1 III 100 10 9b 13; 28 9

1549 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S.

6.1 III 100 10 9b 13; 28 9

1550 ANTIMONY LACTATE 6.1 III 100 10 9b 13; 28 9

1551 ANTIMONY POTASSIUM TARTRATE 6.1 III 100 10 9b 13; 28 9

1553 ARSENIC ACID, LIQUID 6.1 I 5 200 1; 13; 28 9; 17

1554 ARSENIC ACID, SOLID 6.1 II 50 20 11 13; 28 9; 19

1555 ARSENIC BROMIDE 6.1 II 50 20 11 13; 28 9; 19

1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s. and Arsenic sulfides, n.o.s

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13; 28 9; 19


6.1 III 100 10 13; 28 9

1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s. and Arsenic sulfides, n.o.s.

6.1 I 5 200 10; 12 1; 13; 28 9; 17


6.1 II 50 20 11 13; 28 9; 19


6.1 III 100 10 9b 13; 28 9

1558 ARSENIC 6.1 II 50 20 11 13; 28 9; 19

1559 ARSENIC PENTOXIDE 6.1 II 50 20 11 13; 28 9; 19

1560 ARSENIC TRICHLORIDE 6.1 I 5 200 1; 13; 28 9; 17

1561 ARSENIC TRIOXIDE 6.1 II 50 20 11 13; 28 9; 19

1562 ARSENICAL DUST 6.1 II 50 20 11 13; 28 9; 19

1564 BARIUM COMPOUND, N.O.S. 6.1 II 50 20 11 13; 28 9; 19

1564 BARIUM COMPOUND, N.O.S. 6.1 III 100 10 9a 13; 28 9

1565 BARIUM CYANIDE 6.1 I 5 200 10; 12 1; 13; 28 9; 17

1566 BERYLLIUM COMPOUND, N.O.S. 6.1 II 50 20 11 13; 28 9; 19



1566 BERYLLIUM COMPOUND, N.O.S. 6.1 III 100 10 9b 13; 28 9

1567 BERYLLIUM POWDER 6.1 II 4.1 5 200 11 13; 28 9; 19

1569 BROMOACETONE 6.1 II 3 5 200 13; 28 2; 9; 19

1570 BRUCINE 6.1 I 5 200 10; 12 1; 13; 28 9; 17

1571 BARIUM AZIDE, WETTED with > 50 % water, by mass 4.1 I 6.1 0 28 17

1572 CACODYLIC ACID 6.1 II 50 20 11 13; 28 9; 19

1573 CALCIUM ARSENATE 6.1 II 50 20 11 13; 28 9; 19

1574 CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID

6.1 II 50 20 11 13; 28 9; 19

1575 CALCIUM CYANIDE 6.1 I 5 200 10; 12 1; 13; 28 9; 17

1577 CHLORODINITRO-BENZENES, LIQUID 6.1 II 50 20 13; 28 9; 19

1578 CHLORONITRO-BENZENES, SOLID 6.1 II 50 20 11 13; 28 9; 19

1579 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLID 6.1 III 100 10 9b 13; 28 9

1580 CHLOROPICRIN 6.1 I 5 200 1; 13; 28 9; 17

1581 CHLOROPICRIN AND METHYL BROMIDE MIXTURE with > 2 % chloropicrin

2.3 10 100 9; 10: 36 7; 17

1582 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE

2.3 10 100 9; 10; 36 7; 17

1583 CHLOROPICRIN MIXTURE, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

1583 CHLOROPICRIN MIXTURE, N.O.S. 6.1 II 50 20 13; 28 9; 19

1583 CHLOROPICRIN MIXTURE, N.O.S. 6.1 III 100 10 13; 28 9

1585 COPPER ACETO-ARSENITE 6.1 II 50 20 11 13; 28 9; 19

1586 COPPER ARSENITE 6.1 II 50 20 11 13; 28 9; 19

1587 COPPER CYANIDE 6.1 II 50 20 11 13; 28 9; 19

1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 II 50 20 11 13; 28 9; 19

1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 III 100 10 9b 13; 28 9

1589 CYANOGEN CHLORIDE, STABILIZED 2.3 8 10 100 9; 10; 36 7; 17

1590 DICHLOROANILINES, LIQUID 6.1 II 50 20 13; 28 9; 19

1591 o-DICHLOROBENZENE 6.1 III 100 10 13; 28 9

1593 DICHLOROMETHANE 6.1 III 100 10 13; 28 9

1594 DIETHYL SULFATE 6.1 II 50 20 13; 28 9; 19

1595 DIMETHYL SULFATE 6.1 I 8 5 200 1; 13; 28 9; 17

1596 DINITROANILINES 6.1 II 50 20 11 13; 28 9; 19

1597 DINITROBENZENES, LIQUID 6.1 II 50 20 13; 28; 31 9; 19

1597 DINITROBENZENES, LIQUID 6.1 III 100 10 13; 28; 31 9

1598 DINITRO-o-CRESOL 6.1 II 50 20 11 13; 28 9; 19

1599 DINITROPHENOL SOLUTION 6.1 II 50 20 13; 28 9; 19

1599 DINITROPHENOL SOLUTION 6.1 III 100 10 13; 28 9

1600 DINITROTOLUENES, MOLTEN 6.1 II 50 20 13 9; 19



1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S.

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13; 28 9; 19


6.1 III 100 10 13; 28 9

1603 ETHYL BROMOACETATE 6.1 II 3 5 200 13; 28 2; 9; 19

1604 ETHYLENEDIAMINE 8 II 3 10 100 2

1605 ETHYLENE DIBROMIDE 6.1 I 5 200 1; 13; 28 9; 17

1606 FERRIC ARSENATE 6.1 II 50 20 11 13; 28 9; 19

1607 FERRIC ARSENITE 6.1 II 50 20 11 13; 28 9; 19

1608 FERROUS ARSENATE 6.1 II 50 20 11 13; 28 9; 19

1611 HEXAETHYL TETRA-PHOSPHATE 6.1 II 50 20 13; 28 9; 19

1612 HEXAETHYL TETRA-PHOSPHATE AND COMPRESSED GAS MIXTURE

2.3 10 100 9; 10; 36 7; 17

1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION) with < 20 % hydrogen cyanide

6.1 I 3 5 200 1; 13; 28 2; 9; 17

1614 HYDROGEN CYANIDE, STABILIZED, containing < 3 % water and absorbed in a porous inert material

6.1 I 3 5 200 1; 13; 28 2; 9; 10; 17

1616 LEAD ACETATE 6.1 III 100 10 9b 13; 28 9

1617 LEAD ARSENATES 6.1 II 50 20 11 13; 28 9; 19

1618 LEAD ARSENITES 6.1 II 50 20 11 13; 28 9; 19

1620 LEAD CYANIDE 6.1 II 50 20 11 13; 28 9; 19

1621 LONDON PURPLE 6.1 II 50 20 11 13; 28 9; 19

1622 MAGNESIUM ARSENATE 6.1 II 50 20 11 13; 28 9; 19

1623 MERCURIC ARSENATE 6.1 II 50 20 11 13; 28 9; 19

1624 MERCURIC CHLORIDE 6.1 II 50 20 11 13; 28 9; 19

1625 MERCURIC NITRATE 6.1 II 50 20 11 13; 28 9; 19

1626 MERCURIC POTASSIUM CYANIDE 6.1 I 5 200 10; 12 1; 13; 28 9; 17

1627 MERCUROUS NITRATE 6.1 II 50 20 11 13; 28 9; 19

1629 MERCURY ACETATE 6.1 II 50 20 11 13; 28 9; 19

1630 MERCURY AMMONIUM CHLORIDE 6.1 II 50 20 11 13; 28 9; 19

1631 MERCURY BENZOATE 6.1 II 50 20 11 13; 28 9; 19

1634 MERCURY BROMIDES 6.1 II 50 20 11 13; 28 9; 19

1636 MERCURY CYANIDE 6.1 II 50 20 11 13; 28

1637 MERCURY GLUCONATE 6.1 II 50 20 11 13; 28

1638 MERCURY IODIDE 6.1 II 50 20 11 13; 28

1639 MERCURY NUCLEATE 6.1 II 50 20 11 13; 28

1640 MERCURY OLEATE 6.1 II 50 20 11 13; 28

1641 MERCURY OXIDE 6.1 II 50 20 11 13; 28



1642 MERCURY OXY-CYANIDE, DESENSITIZED 6.1 II 50 20 11 13; 28

1643 MERCURY POTASSIUM IODIDE 6.1 II 50 20 11 13; 28

1644 MERCURY SALICYLATE 6.1 II 50 20 11 13; 28

1645 MERCURY SULFATE 6.1 II 50 20 11 13; 28 9; 19

1646 MERCURY THIO-CYANATE 6.1 II 50 20 11 13; 28 9; 19

1647 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID

6.1 I 5 200 1; 13; 28 9; 19

1648 ACETONITRILE 3 II 500 2 9; 19

1649 MOTOR FUEL ANTI-KNOCK MIXTURE 6.1 I 5 200 1; 13; 28 9; 19

1650 beta-NAPHTHYLAMINE, SOLID 6.1 II 50 20 11 13; 28 9; 19

1651 NAPHTHYLTHIOUREA 6.1 II 50 20 11 13; 28 9; 19

1652 NAPHTHYLUREA 6.1 II 50 20 11 13; 28 9; 19

1653 NICKEL CYANIDE 6.1 II 50 20 11 13; 28 9; 19

1654 NICOTINE 6.1 II 50 20 13; 28 9; 19

1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S.

6.1 I 5 200 10; 12 1; 13; 28 9; 17


6.1 II 50 20 11 13; 28 9; 19


6.1 III 100 10 9b 13; 28 9

1656 NICOTINE HYDRO-CHLORIDE, LIQUID or SOLUTION

6.1 II 50 20 13; 28; 31 9; 19

1656 NICOTINE HYDRO-CHLORIDE, LIQUID or SOLUTION

6.1 III 100 10 9b 13; 28 9

1657 NICOTINE SALICYLATE 6.1 II 50 20 11 13; 28 9; 19

1658 NICOTINE SULFATE, SOLUTION 6.1 II 50 20 13; 28; 31 9; 19

1658 NICOTINE SULFATE, SOLUTION 6.1 III 100 10 9b 13; 28; 31 9

1659 NICOTINE TARTRATE 6.1 II 50 20 11 13; 28 9; 19

1660 NITRIC OXIDE, COMPRESSED 2.3 5.1; 8 10 100 9; 10; 36 7; 17

1661 NITROANILINES (o-, m-, p-) 6.1 II 50 20 11 13; 28 9; 19

1662 NITROBENZENE 6.1 II 50 20 13; 28 9; 19

1663 NITROPHENOLS (o-, m-, p-) 6.1 III 100 10 9b 13; 28 9

1664 NITROTOLUENES, LIQUID 6.1 II 50 20 13; 28 9; 19

1665 NITROXYLENES, LIQUID 6.1 II 50 20 13; 28 9; 19

1669 PENTACHLOROETHANE 6.1 II 50 20 13; 28 9; 19

1670 PERCHLOROMETHYL MERCAPTAN 6.1 I 5 200 1; 13; 28 9; 17

1671 PHENOL, SOLID 6.1 II 50 20 11 13; 28 9; 19

1672 PHENYLCARBYLAMINE CHLORIDE 6.1 I 5 200 1; 13; 28 9; 17

1673 PHENYLENEDIAMINES (o-, m-, p-) 6.1 III 100 10 9b 13; 28 9

1674 PHENYLMERCURIC ACETATE 6.1 II 50 20 11 13; 28 9; 19

1677 POTASSIUM ARSENATE 6.1 II 50 20 11 13; 28 9; 19



1678 POTASSIUM ARSENITE 6.1 II 50 20 11 13; 28 9; 19

1679 POTASSIUM CUPRO-CYANIDE 6.1 II 50 20 11 13; 28 9; 19

1680 POTASSIUM CYANIDE, SOLID 6.1 I 5 200 10; 12 1; 13; 28 9; 17

1683 SILVER ARSENITE 6.1 II 50 20 11 13; 28 9; 19

1684 SILVER CYANIDE 6.1 II 50 20 11 13; 28 9; 19

1685 SODIUM ARSENATE 6.1 II 50 20 11 13; 28 9; 19

1686 SODIUM ARSENITE, AQUEOUS SOLUTION 6.1 II 50 20 13; 28 9; 19

1686 SODIUM ARSENITE, AQUEOUS SOLUTION 6.1 III 100 10 13; 28 9

1687 SODIUM AZIDE 6.1 II 50 20 11 13; 28 9; 19

1688 SODIUM CACODYLATE 6.1 II 50 20 11 13; 28 9; 19

1689 SODIUM CYANIDE, SOLID 6.1 I 5 200 10; 12 1; 13; 28 9; 17

1690 SODIUM FLUORIDE, SOLID 6.1 III 100 10 9b 13; 28 9

1691 STRONTIUM ARSENITE 6.1 II 50 20 11 13; 28 9; 19

1692 STRYCHNINE or STRYCHNINE SALTS 6.1 I 5 200 10; 12 1; 13; 28 9; 17

1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 6.1 II 50 20 13; 28 9; 19

1694 BROMOBENZYL CYANIDES, LIQUID 6.1 I 5 200 1; 13; 28 9; 17

1695 CHLOROACETONE, STABILIZED 6.1 I 3; 8 5 200 1; 13; 28 2; 9; 17

1697 CHLOROACETO-PHENONE, SOLID 6.1 II 50 20 11 13; 28 9; 19

1698 DIPHENYLAMINE CHLOROARSINE 6.1 I 5 200 1; 13; 28 9; 17

1699 DIPHENYLCHLORO-ARSINE, LIQUID 6.1 1 5 200 1; 13; 28 9; 17

1700 TEAR GAS CANDLES 6.1 II 4.1 5 200 13; 28 9; 19

1701 XYLYL BROMIDE, LIQUID 6.1 II 50 20 13; 28 9; 19

1702 1,1,2,2-TETRACHLORO-ETHANE 6.1 II 50 20 13; 28 9; 19

1704 TETRAETHYL DITHIO-PYROPHOSPHATE 6.1 II 50 20 11 13; 28 9; 19

1707 THALLIUM COMPOUND, N.O.S. 6.1 II 50 20 11 13; 28 9; 19

1708 TOLUIDINES, LIQUID 6.1 II 50 20 13; 28 9; 19

1709 2,4-TOLUYLENE-DIAMINE, SOLID 6.1 III 100 10 9b 13; 28 9

1710 TRICHLOROETHYLENE 6.1 III 100 10 13; 28 9

1711 XYLIDINES, LIQUID 6.1 II 50 20 13; 28 9; 19

1712 ZINC ARSENATE, ZINC ARSENITE or ZINC ARSENATE AND ZINC ARSENITE MIXTURE

6.1 II 50 20 11 13; 28 9; 19

1713 ZINC CYANIDE 6.1 I 5 200 10; 12 1; 13; 28 9; 17

1714 ZINC PHOSPHIDE 4.3 I 6.1 0 1 23; 28 20

1715 ACETIC ANHYDRIDE 8 II 3 10 100 2

1716 ACETYL BROMIDE 8 II 50 20

1717 ACETYL CHLORIDE 3 II 8 200 5 2; 20

1718 BUTYL ACID PHOSPHATE 8 III 200 5

1719 CAUSTIC ALKALI LIQUID, N.O.S. 8 II 50 20

1719 CAUSTIC ALKALI LIQUID, N.O.S. 8 III 200 5



1722 ALLYL CHLORO-FORMATE 6.1 I 3;8 5 200 1; 13; 28 2; 9; 17

1723 ALLYL IODIDE 3 II 8 200 5 2; 20

1724 ALLYLTRICHLORO-SILANE, STABILIZED 8 II 3 10 100 2

1725 ALUMINIUM BROMIDE, ANHYDROUS 8 II 50 20 11

1726 ALUMINIUM CHLORIDE, ANHYDROUS 8 II 50 20 11

1727 AMMONIUM HYDROGEN-DIFLUORIDE, SOLID 8 II 50 20 11

1728 AMYLTRICHLORO-SILANE 8 II 50 20

1729 ANISOYL CHLORIDE 8 II 50 20 11

1730 ANTIMONY PENTA-CHLORIDE, LIQUID 8 II 50 20

1731 ANTIMONY PENTA-CHLORIDE SOLUTION 8 II 50 20

1731 ANTIMONY PENTA-CHLORIDE SOLUTION 8 III 200 5

1732 ANTIMONY PENTA-FLUORIDE 8 II 6.1 10 100 13; 28

1733 ANTIMONY TRI-CHLORIDE 8 II 50 20 11

1736 BENZOYL CHLORIDE 8 II 50 20

1737 BENZYL BROMIDE 6.1 II 8 5 200 13; 28 9; 19

1738 BENZYL CHLORIDE 6.1 II 8 5 200 13; 28 9; 19

1739 BENZYL CHLORO-FORMATE 8 I 20 50 20

1740 HYDROGEN-DIFLUORIDES, N.O.S. 8 II 50 20 11

1740 HYDROGEN-DIFLUORIDES, N.O.S. 8 III 200 5 9b

1741 BORON TRICHLORIDE 2.3 8 10 100 9; 10; 36 7; 17

1742 BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID

8 II 50 20

1743 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID

8 II 50 20

1744 BROMINE or BROMINE SOLUTION 8 I 6.1 5 200 13; 28 17

1745 BROMINE PENTA-FLUORIDE 5.1 I 6.1;8 0 24; 28 20

1746 BROMINE TRIFLUORIDE 5.1 I 6.1;8 0 24; 28 20

1747 BUTYLTRICHLORO-SILANE 8 II 3 10 100 2

1748 CALCIUM HYPO-CHLORITE, DRY or CALCIUM HYPO-CHLORITE MIXTURE, DRY with > 39 % available chlorine (8,8 % available oxygen)

5.1 II 50 20 11 24; 35

1748 CALCIUM HYPO-CHLORITE, DRY or CALCIUM HYPO-CHLORITE MIXTURE, DRY with > 39 % available chlorine (8,8 % available oxygen)

5.1 III 200 5 24; 35

1749 CHLORINE TRIFLUORIDE 2.3 5.1; 8 10 100 9; 10; 36 7; 17

1750 CHLOROACETIC ACID SOLUTION 6.1 II 8 5 200 13; 28 9; 19

1751 CHLOROACETIC ACID, SOLID 6.1 II 8 5 200 13; 28 9; 19

1752 CHLOROACETYL CHLORIDE 6.1 I 8 5 200 1; 13; 28 9; 17

1753 CHLOROPHENYL-TRICHLOROSILANE 8 II 50 20

1754 CHLOROSULFONIC ACID (with or without sulfur trioxide)

8 I 20 50 20



1755 CHROMIC ACID SOLUTION 8 II 50 20

1755 CHROMIC ACID SOLUTION 8 III 200 5

1756 CHROMIC FLUORIDE, SOLID 8 II 50 20 11

1757 CHROMIC FLUORIDE SOLUTION 8 I 50 20

1757 CHROMIC FLUORIDE SOLUTION 8 III 200 5

1758 CHROMIUM OXY-CHLORIDE 8 I 20 50 20

1759 CORROSIVE SOLID, N.O.S. 8 I 20 50 10; 12 20

1759 CORROSIVE SOLID, N.O.S. 8 II 50 20 11

1759 CORROSIVE SOLID, N.O.S. 8 III 200 10 9b

1760 CORROSIVE LIQUID, N.O.S. 8 I 20 50 20

1760 CORROSIVE LIQUID, N.O.S. 8 II 50 20

1760 CORROSIVE LIQUID, N.O.S. 8 III 200 5

1761 CUPRIETHYLENE-DIAMINE SOLUTION 8 II 6.1 10 100 13; 28

1761 CUPRIETHYLENE-DIAMINE SOLUTION 8 III 6.1 50 20 13;28

1762 CYCLOHEXENYLTRI-CHLOROSILANE 8 II 50 20

1763 CYCLOHEXYLTRI-CHLOROSILANE 8 II 50 20

1764 DICHLOROACETIC ACID 8 II 50 20

1765 DICHLOROACETYL CHLORIDE 8 II 50 20

1766 DICHLOROPHENYL-TRICHLOROSILANE 8 II 50 20

1767 DIETHYLDICHLORO-SILANE 8 II 3 10 100 2

1768 DIFLUOROPHOSPHORIC ACID, ANHYDROUS 8 II 50 20

1769 DIPHENYLDICHLORO-SILANE 8 II 50 20

1770 DIPHENYLMETHYL BROMIDE 8 II 50 20 11

1771 DODECYLTRICHLORO-SILANE 8 II 50 20

1773 FERRIC CHLORIDE, ANHYDROUS 8 III 200 5 9b

1774 FIRE EXTINGUISHER CHARGES, corrosive liquid 8 II 50 20

1775 FLUOROBORIC ACID 8 II 50 20

1776 FLUOROPHOSPHORIC ACID, ANHYDROUS 8 II 50 20

1777 FLUOROSULFONIC ACID 8 I 20 50 20

1778 FLUOROSILICIC ACID 8 II 50 20

1779 FORMIC ACID 8 II 50 20

1780 FUMARYL CHLORIDE 8 II 50 20

1781 HEXADECYLTRICHLOROSILANE 8 II 50 20

1782 HEXAFLUOROPHOS-PHORIC ACID 8 II 50 20

1783 HEXAMETHYLENE-DIAMINE SOLUTION 8 II 50 20

1783 HEXAMETHYLENE-DIAMINE SOLUTION 8 III 200 5

1784 HEXYLTRICHLORO-SILANE 8 II 50 20

1786 HYDROFLUORIC ACID AND SULFURIC ACID MIXTURE

8 I 6.1 5 200 13; 28 20

1787 HYDRIODIC ACID 8 II 50 20



1787 HYDRIODIC ACID 8 III 200 5

1788 HYDROBROMIC ACID 8 II 50 20

1788 HYDROBROMIC ACID 8 III 200 5

1789 HYDROCHLORIC ACID 8 II 50 20

1789 HYDROCHLORIC ACID 8 III 200 5

1790 HYDROFLUORIC ACID with > 60 % hydrogen fluoride 8 I 6.1 5 200 13; 28 17

1790 HYDROFLUORIC ACID with < 60 % hydrogen fluoride 8 II 6.1 10 100 13; 28

1791 HYPOCHLORITE SOLUTION 8 II 50 20

1791 HYPOCHLORITE SOLUTION 8 III 200 5

1792 IODINE MONO-CHLORIDE 8 II 50 20 11

1793 ISOPROPYL ACID PHOSPHATE 8 III 200 5

1794 LEAD SULFATE with > 3 % free acid 8 II 50 20 11 9a

1796 NITRATING ACID MIXTURE with > 50 % nitric acid 8 I 5.1 5 200 24 20

1796 NITRATING ACID MIXTURE with < 50 % nitric acid 8 II 50 20

1798 NITROHYDROCHLORIC ACID 8 I Carriage prohibited

1799 NONYLTRICHLORO-SILANE 8 II 50 20

1800 OCTADECYLTRI-CHLOROSILANE 8 II 50 20

1801 OCTYLTRICHLORO-SILANE 8 II 50 20

1802 PERCHLORIC ACID with < 50 % acid, by mass 8 II 5.1 10 100 24

1803 PHENOLSULFONIC ACID, LIQUID 8 II 50 20

1804 PHENYLTRICHLORO-SILANE 8 II 50 20

1805 PHOSPHORIC ACID, SOLUTION 8 III 200 5

1806 PHOSPHORUS PENTACHLORIDE 8 II 50 20 11

1807 PHOSPHORUS PENTOXIDE 8 II 50 20 11

1808 PHOSPHORUS TRIBROMIDE 8 II 50 20

1809 PHOSPHORUS TRICHLORIDE 6.1 I 8 5 200 1; 13; 28 9; 17

1810 PHOSPHORUS OXYCHLORIDE 8 II 50 20

1811 POTASSIUM HYDRO-GENDIFLUORIDE, SOLID 8 II 6.1 10 100 11 13; 28

1812 POTASSIUM FLUORIDE, SOLID 6.1 III 100 10 9b 13; 28 9

1813 POTASSIUM HYDROXIDE, SOLID 8 II 50 20 11

1814 POTASSIUM HYDROXIDE SOLUTION 8 II 50 20

1814 POTASSIUM HYDROXIDE SOLUTION 8 III 200 5

1815 PROPIONYL CHLORIDE 3 II 8 200 5 2; 20

1816 PROPYLTRICHLORO-SILANE 8 II 3 10 100 2

1817 PYROSULFURYL CHLORIDE 8 II 50 20

1818 SILICON TETRA-CHLORIDE 8 II 50 20

1819 SODIUM ALUMINATE SOLUTION 8 II 50 20

1819 SODIUM ALUMINATE SOLUTION 8 III 200 5

1823 SODIUM HYDROXIDE, SOLID 8 II 50 20 11



1824 SODIUM HYDROXIDE SOLUTION 8 II 50 20

1824 SODIUM HYDROXIDE SOLUTION 8 III 200 5

1825 SODIUM MONOXIDE 8 II 50 20 11

1826

NITRATING ACID MIXTURE, SPENT with > 50 % nitric acid

8 I 5.1 5 200 24 20

1826 NITRATING ACID MIXTURE, SPENT with < 50 % nitric acid

8 II 5.1 50 20

1827 STANNIC CHLORIDE, ANHYDROUS 8 II 50 20

1828 SULFUR CHLORIDES 8 I 20 50 20

1829 SULFUR TRIOXIDE, STABILIZED 8 I 20 50 20

1830 SULFURIC ACID with > 51 % acid

8 II 50 20

1831 SULFURIC ACID, FUMING 8 I 6.1 5 200 13; 28 20

1832 SULFURIC ACID, SPENT 8 II 50 20

1833 SULFUROUS ACID 8 II 50 20

1834 SULFURYL CHLORIDE 8 I 20 50 20

1835 TETRAMETHYL-AMMONIUM HYDROXIDE, SOLUTION

8 II 50 20

1835 TETRAMETHYL-AMMONIUM HYDROXIDE, SOLUTION

8 III 200 5

1836 THIONYL CHLORIDE 8 I 20 50 20

1837 THIOPHOSPHORYL CHLORIDE 8 II 50 20

1838 TITANIUM TETRA-CHLORIDE 8 II 50 20

1839 TRICHLOROACETIC ACID 8 II 50 20 11

1840 ZINC CHLORIDE SOLUTION 8 III 200 5

1841 ACETALDEHYDE AMMONIA 9 III 500 2 3

1843 AMMONIUM DINITRO-o-CRESOLATE 6.1 II 50 20 11 13; 28 9; 19

1845 Carbon dioxide, solid (Dry ice) 9 Non-dangerous for road transport

1846 CARBON TETRA-CHLORIDE 6.1 II 50 20 13; 28 9; 19

1847 POTASSIUM SULFIDE, HYDRATED with > 30 % water of crystallization

8 II 50 20 11

1848 PROPIONIC ACID 8 III 200 5

1849 SODIUM SULFIDE, HYDRATED with > 30 % water 8 II 50 20 11

1851 MEDICINE, LIQUID, TOXIC, N.O.S. 6.1 II 50 20 13; 28 9; 19

1851 MEDICINE, LIQUID, TOXIC, N.O.S. 6.1 III 100 10 13;28 9

1854 BARIUM ALLOYS, PYROPHORIC 4.2 I 0 1 20

1855 CALCIUM, PYROPHORIC or CALCIUM ALLOYS, PYROPHORIC

4.2 I 0 1 20

1856 Rags, oily 4.2 Non-dangerous for road transport

1857 Textile waste, wet 4.2 Non-dangerous for road transport

1858 HEXAFLUOROPRO-PYLENE (REFRIGERANT GAS R 1216)

2.2 500 2 9; 10; 36



1859 SILICON TETRA-FLUORIDE 2.3 8 10 100 9; 10; 36 7; 17

1860 VINYL FLUORIDE, STABILIZED 2.1 100 10 9; 10; 36 2; 20

1862 ETHYL CROTONATE 3 II 500 2 2; 20

1863 FUEL, AVIATION, TURBINE ENGINE 3 I 100 10 2; 20

1863 FUEL, AVIATION, TURBINE ENGINE 3 II 500 2 2;20

1863 FUEL, AVIATION, TURBINE ENGINE 3 III 1000 1 2

1865 n-PROPYL NITRATE 3 II 500 2 2; 20

1866 RESIN SOLUTION, flammable 3 I 100 10 2; 20

1866 RESIN SOLUTION, flammable 3 II 500 2 2;20

1866 RESIN SOLUTION, flammable 3 III 1000 1 2

1868 DECABORANE 4.1 II 6.1 10 100 11; 12 28

1869 MAGNESIUM or MAGNESIUM ALLOYS with > 50 % magnesium in pellets, turnings or ribbons

4.1 III 500 2 1

1870 POTASSIUM BOROHYDRIDE 4.3 I 0 1 23 20

1871 TITANIUM HYDRIDE 4.1 II 50 20

1872 LEAD DIOXIDE 5.1 III 6.1 100 10 24; 28

1873 PERCHLORIC ACID with > 50 % but < 72 % acid, by mass

5.1 I 8 0 24 20

1884 BARIUM OXIDE 6.1 III 100 10 9a 13; 28 9

1885 BENZIDINE 6.1 II 50 20 11 13; 28 9; 19

1886 BENZYLIDENE CHLORIDE 6.1 II 50 20 13; 28 9; 19

1887 BROMOCHLORO-METHANE 6.1 III 100 10 13; 28 9

1888 CHLOROFORM 6.1 III 100 10 13; 28 9

1889 CYANOGEN BROMIDE 6.1 I 8 5 200 1; 13; 28 9; 17

1891 ETHYL BROMIDE 6.1 II 50 20 13; 28 9; 19

1892 ETHYLDICHLORO-ARSINE 6.1 I 5 200 1; 13; 28 9; 17

1894 PHENYLMERCURIC HYDROXIDE 6.1 II 50 20 11 13; 28 9; 19

1895 PHENYLMERCURIC NITRATE 6.1 II 50 20 11 13; 28 9; 19

1897 TETRACHLORO-ETHYLENE 6.1 III 100 10 13; 28 9

1898 ACETYL IODIDE 8 II 50 20

1902 DIISOOCTYL ACID PHOSPHATE 8 III 200 5

1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8 I 20 50 20

1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8 II 50 20

1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8 III 200 5

1905 SELENIC ACID 8 I 20 50 10; 12 20

1906 SLUDGE ACID 8 II 50 20

1907 SODA LIME with > 4 % sodium hydroxide 8 III 200 5 9b

1908 CHLORITE SOLUTION 8 II 50 20

1908 CHLORITE SOLUTION 8 III 200 5

1910 Calcium oxide 8 III Non-dangerous for road transport



1911 DIBORANE 2.3 2.1 10 100 9; 10; 36 2; 7; 17

1912 METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE

2.1 100 10 9; 10; 36 2; 20

1913 NEON, REFRIGERATED LIQUID 2.2 500 2 5 9; 11; 36 20

1914 BUTYL PROPIONATES 3 III 1 000 1 2

1915 CYCLOHEXANONE 3 III 1 000 1 2

1916 2,2'-DICHLORODIETHYL ETHER 6.1 II 3 5 200 13; 28 2; 9; 19

1917 ETHYL ACRYLATE, STABILIZED 3 II 500 2 2; 20

1918 ISOPROPYLBENZENE 3 III 1 000 1 2

1919 METHYL ACRYLATE, STABILIZED 3 II 500 2 2; 20

1920 NONANES 3 III 1 000 1 2

1921 PROPYLENEIMINE, STABILIZED 3 I 6.1 50 20 13; 28 2; 19

1922 PYRROLIDINE 3 II 8 200 5 2; 20

1923 CALCIUM DITHIONITE (CALCIUM HYDRO-SULFITE) 4.2 II 100 10 1; 12

1928 METHYL MAGNESIUM BROMIDE IN ETHYL ETHER 4.3 I 3 0 1 23 2; 20

1929 POTASSIUM DITHIONITE (POTASSIUM HYDRO-SULFITE)

4.2 II 100 10 1; 12

1931 ZINC DITHIONITE (ZINC HYDROSULFITE) 9 III 500 2 3

1932 ZIRCONIUM SCRAP 4.2 III 200 5 1 4

1935 CYANIDE, SOLUTION, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

1935 CYANIDE, SOLUTION, N.O.S. 6.1 II 50 20 13;28 9;19

1935 CYANIDE, SOLUTION, N.O.S. 6.1 III 100 10 13;28 9

1938 BROMOACETIC ACID, SOLUTION 8 II 50 20

1938 BROMOACETIC ACID, SOLUTION 8 III 200 5

1939 PHOSPHORUS OXYBROMIDE 8 II 50 20 11

1940 THIOGLYCOLIC ACID 8 II 50 20

1941 DIBROMODIFLUORO-METHANE 9 III 500 2

1942 AMMONIUM NITRATE with < 0,2 % total combustible material, including any organic substance calculated as carbon, to the exclusion of any other added substance

5.1 III 200 5 8 24

1944 MATCHES, SAFETY (book, card or strike on box) 4.1 III 500 2

1945 MATCHES, WAX 'VESTA' 4.1 III 500 2

1950 AEROSOLS, asphyxiant 2.2 500 2 9; 12

1950 AEROSOLS, toxic, corrosive 2.2 6.1; 8 200 5 9; 12; 28 7

1950 AEROSOLS, flammable 2.1 100 10 9; 12 2

1950 AEROSOLS, toxic, oxidizing 2.2 5.1; 6.1 200 5 9; 12; 28 7

1950 AEROSOLS, toxic, flammable 2.1 6.1 20 50 9; 12; 28 2; 7

1950 AEROSOLS, corrosive, oxidizing 2.2 8 5.1

200 5 9; 12

1950 AEROSOLS, toxic, oxidizing, corrosive 2.2 6.1 200 5 9; 12; 28 7



5.1 8

1950 AEROSOLS, flammable, corrosive 2.1 8 20 50 9; 12 2

1950 AEROSOLS, oxidizing 2.2 5.1 200 5 9; 12

1950 AEROSOLS, toxic, flammable, corrosive 2.1 6.1 8

20 50 9; 12; 28 2; 7

1950 AEROSOLS, toxic 2.2 6.1 200 5 9; 12; 28 7

1950 AEROSOLS, corrosive 2.2 8 200 5 9; 12

1951 ARGON, REFRIGERATED LIQUID 2.2 500 2 5 9; 11; 36 20

1952 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with < 9 % ethylene oxide

2.2 500 2 9; 10; 36

1953 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 2.1 10 100 9; 10; 36 2; 7; 17

1954 COMPRESSED GAS, FLAMMABLE, N.O.S. 2.1 100 10 9; 10; 36 2

1955 COMPRESSED GAS, TOXIC, N.O.S. 2.3 10 100 9; 10; 36 7; 17

1956 COMPRESSED GAS, N.O.S. 2.2 500 2 9; 10; 36

1957 DEUTERIUM, COMPRESSED 2.1 100 10 9; 10; 36 2

1958 1,2-DICHLORO-1,1,2,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 114)

2.2 500 2 9; 10; 36

1959 1,1-DIFLUORO-ETHYLENE (REFRI-GERANT GAS R 1132a)

2.1 100 10 9; 10; 36 2; 20

1961 ETHANE, REFRIGE-RATED LIQUID 2.1 100 10 5 9; 11; 36 2; 17

1962 ETHYLENE 2.1 100 10 9; 10; 36 2

1963 HELIUM, REFRIGE-RATED LIQUID 2.2 500 2 5 9; 11; 36 20

1964 HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S.

2.1 100 10 9; 10; 36 2

1965 HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S 2.1 100 10 9; 10; 36 2; 20

1966 HYDROGEN, REFRIGE-RATED LIQUID 2.1 100 10 5 9; 11; 36 2; 17

1967 INSECTICIDE GAS, TOXIC, N.O.S. 2.3 10 100 9; 10; 36 2; 17

1968 INSECTICIDE GAS, N.O.S. 2.2 500 2 9; 10; 36

1969 ISOBUTANE 2.1 100 10 9; 10; 36 2; 20

1970 KRYPTON, REFRIGE-RATED LIQUID 2.2 500 2 5 9; 11; 36 20

1971 METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content

2.1 100 10 9; 10; 36 2

1972 METHANE, REFRIGE-RATED LIQUID or NATURAL GAS, REFRIGERATED LIQUID with high methane content

2.1 100 10 5 9; 11; 36 2; 17

1973 CHLORODIFLUORO-METHANE AND CHLOROPENTA-FLUOROETHANE MIXTURE with fixed boiling point, with ca 49% chlorodifluoro-methane (REFRIGERANT GAS R 502)

2.2 500 2 9; 10; 36

1974 CHLORODIFLUORO-BROMOMETHANE (REFRIGERANT GAS R 12B1)

2.2 500 2 9; 10; 36



1975 NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE

2.3 5.1 8

10 100 9; 10; 36 7; 17

1976 OCTAFLUOROCYCLO-BUTANE (REFRIGERANT GAS RC 318)

2.2 500 2 9; 10; 36

1977 NITROGEN, REFRIGE-RATED LIQUID 2.2 500 2 5 9; 11; 36 20

1978 PROPANE 2.1 100 10 9; 10; 36 2; 20

1979 RARE GASES MIXTURE, COMPRESSED (e.g. Argon; Helium; Krypton; Neon; Xenon)

2.2 500 2 9; 10; 36

1980 RARE GASES AND OXYGEN MIXTURE, COMPRESSED

2.2 500 2 9; 10; 36

1981 RARE GASES AND NITROGEN MIXTURE, COMPRESSED

2.2 500 2 9; 10; 36

1982 TETRAFLUORO-METHANE (REFRIGE-RANT GAS R 14)

2.2 500 2 9; 10; 36

1983 1-CHLORO-2,2,2-TRI-FLUOROETHANE (REFRIGERANT GAS R 133a)

2.2 500 2 9; 10; 36

1984 TRIFLUOROMETHANE (REFRIGERANT GAS R 23)

2.2 500 2 9; 10; 36

1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 I 6.1 50 20 13; 28 2; 19

1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 I 6.1 200 5 13;28 2;19

1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 III 6.1 500 2 13;28 2

1987 ALCOHOLS, N.O.S. 3 II 25 40 2; 20

1987 ALCOHOLS, N.O.S. 3 III 25 40 2

1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3 I 6.1 50 20 13; 28 2; 19

1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3 II 6.1 200 5 13;28 2;19

1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3 III 6.1 500 2 13;28 2

1989 ALDEHYDES, N.O.S. 3 I 100 10 2; 20

1989 ALDEHYDES, N.O.S. 3 II 500 2 2;20

1989 ALDEHYDES, N.O.S. 3 III 1000 1 2

1990 BENZALDEHYDE 9 III 500 2

1991 CHLOROPRENE, STABILIZED 3 I 6.1 50 20 13; 28 2; 19

1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3 I 6.1 50 20 13; 28 2; 19

1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3 II 6.1 200 5 13;28 2;19

1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3 III 6.1 500 2 13;28 2

1993 FLAMMABLE LIQUID, N.O.S. 3 I 100 10 2; 20

1993 FLAMMABLE LIQUID, N.O.S. 3 II 500 2 2;20

1993 FLAMMABLE LIQUID, N.O.S. 3 III 1000 1 2

1994 IRON PENTACARBONYL 6.1 I 3 5 200 1; 13; 28 2; 9; 17

1999 TARS, LIQUID, including road asphalt and oils, bitumen and cut backs

3 II 500 2 2; 20

1999 TARS, LIQUID, including road asphalt and oils, bitumen and cut backs

3 III 1000 1 2



2000 CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap

4.1 III 500 2

2001 COBALT NAPHTHENATES, POWDER 4.1 III 500 2 1

2002 CELLULOID, SCRAP 4.2 III 200 5 1

2004 MAGNESIUM DIAMIDE 4.2 II 100 10 1; 12

2005 MAGNESIUM DIPHENYL 4.2 I 4.3 0 1 20

2006 PLASTICS, NITROCEL-LULOSE-BASED, SELF-HEATING, N.O.S.

4.2 III 200 5 1

2008 ZIRCONIUM POWDER, DRY 4.2 I 0 1 20

2008 ZIRCONIUM POWDER, DRY 4.2 II 100 10 1;12

2008 ZIRCONIUM POWDER, DRY 4.2 III 200 5 1 4

2009 ZIRCONIUM, DRY, finished sheets, strip or coiled wire 4.2 III 200 5 1 4

2010 MAGNESIUM HYDRIDE 4.3 I 0 1 23 20

2011 MAGNESIUM PHOSPHIDE 4.3 I 6.1 0 1 23; 28 20

2012 POTASSIUM PHOSPHIDE 4.3 I 6.1 0 1 23; 28 20

2013 STRONTIUM PHOSPHIDE 4.3 I 6.1 0 1 23; 28 20

2014 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with > 20 % and < 60 % hydrogen peroxide (stabilized as necessary)

5.1 II 8 20 50 24

2015 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with > 60 % hydrogen peroxide

5.1 I 8 0 5 24 20

2016 AMMUNITION, TOXIC, NON-EXPLOSIVE without burster or expelling charge, non-fuzed

6.1 II 50 20 13; 28 9; 19

2017 AMMUNITION, TEAR-PRODUCING, NON-EXPLOSIVE without burster or expelling charge, non-fuzed

6.1 II 8 5 200 13; 28 9; 19

2018 CHLOROANILINES, SOLID 6.1 II 50 20 11 13; 28 9; 19

2019 CHLOROANILINES, LIQUID 6.1 II 50 20 13; 28 9; 19

2020 CHLOROPHENOLS, SOLID 6.1 III 100 10 9b 13; 28 9

2021 CHLOROPHENOLS, LIQUID 6.1 III 100 10 13; 28 9

2022 CRESYLIC ACID 6.1 II 8 5 200 13; 28 9; 19

2023 EPICHLOROHYDRIN 6.1 II 3 5 200 13; 28 2; 9; 19

2024 MERCURY COMPOUND, LIQUID, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

2024 MERCURY COMPOUND, LIQUID, N.O.S. 6.1 II 50 20 13;28 9;19

2024 MERCURY COMPOUND, LIQUID, N.O.S. 6.1 III 100 10 13;28 9

2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 II 50 20 11 13;28 9;19

2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 III 100 10 9b 13;28 9

2026 PHENYLMERCURIC COMPOUND, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 II 50 20 11 13;28 9;19

2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 III 100 10 9b 13;28 9

2027 SODIUM ARSENITE, SOLID 6.1 II 50 20 11 13; 28 9; 19



2028 BOMBS, SMOKE, NON-EXPLOSIVE with corrosive liquid, without initiating device

8 II 50 20

2029 HYDRAZINE, ANHYDROUS 8 I 3 6.1

5 200 13; 28 2; 20

2030 HYDRAZINE AQUEOUS SOLUTION, with > 37 % hydrazine, by mass

8 I 6.1 5 200 13; 28


8 II 6.1 10 100 13;28


8 III 6.1 50 20 13;28

2031 NITRIC ACID, other than red fuming, with > 70 % nitric acid

8 I 5.1 5 200 24 20

NITRIC ACID, other than red fuming, with < 70 % nitric acid

8 II 50 20

2032 NITRIC ACID, RED FUMING 8 I 5.1 6.1

5 200 13; 24; 28 20

2033 POTASSIUM MONOXIDE 8 II 50 20 11

2034 HYDROGEN AND METHANE MIXTURE, COMPRESSED

2.1 100 10 9; 10; 36 2

2035 1,1,1-TRIFLUORO-ETHANE (REFRIGERANT GAS R 143a)

2.1 100 10 9; 10; 36 2; 20

2036 XENON 2.2 500 2 9; 10; 36

2037 RECEPTACLES, SMALL, CONTAINING GAS (flammable) without a release device, non-refillable

2.1 100 10 9; 12 2

RECEPTACLES, SMALL, CONTAINING GAS (toxic, flammable and corrosive) without a release device, non-refillable

2.3 2.1 8

10 100 9; 12 2; 7

2037 RECEPTACLES, SMALL, CONTAINING GAS (toxic and oxidizing) without a release device, non-refillable

2.3 5.1 10 100 9; 12 7

2037 RECEPTACLES, SMALL, CONTAINING GAS (toxic, oxidizing and corrosive) without a release device, non-refillable

2.3 5.1 8

10 100 9; 12 7

2037 RECEPTACLES, SMALL, CONTAINING GAS (oxidizing) without a release device, non-refillable

2.2 5.1 200 5 9; 12

2037 RECEPTACLES, SMALL, CONTAINING GAS (toxic) without a release device, non-refillable

2.3 10 100 9; 12 7

2037 RECEPTACLES, SMALL, CONTAINING GAS (toxic and corrosive) without a release device, non-refillable

2.3 8 10 100 9; 12 7

2037 RECEPTACLES, SMALL, CONTAINING GAS (non-flammable) without a release device, non-refillable

2.2 500 2 9; 12

2037 RECEPTACLES, SMALL, CONTAINING GAS (toxic and flammable) without a release device, non-refillable

2.3 2.1 10 100 9; 12 2; 7

2038 DINITROTOLUENES, LIQUID 6.1 II 50 20 13; 28 9; 19

2044 2,2-DIMETHYLPROPANE 2.1 100 10 9; 10; 36 2; 20

2045 ISOBUTYRALDEHYDE (ISOBUTYL ALDEHYDE) 3 II 500 2 2; 20

2046 CYMENES 3 III 1 000 1 2



2047 DICHLOROPROPENES 3 II 500 2 2; 20

2047 DICHLOROPROPENES 3 III 1000 1 2

2048 DICYCLOPENTADIENE 3 III 1 000 1 2

2049 DIETHYLBENZENE 3 III 1 000 1 2

2050 DIISOBUTYLENE, ISOMERIC COMPOUNDS 3 II 500 2 2; 20

2051 2-DIMETHYLAMINO-ETHANOL 8 II 3 10 100 2

2052 DIPENTENE 3 III 1 000 1 2

2053 METHYL ISOBUTYL CARBINOL 3 III 1 000 1 2

2054 MORPHOLINE 8 I 3 5 200 2; 20

2055 STYRENE MONOMER, STABILIZED 3 III 1 000 1 2

2056 TETRAHYDROFURAN 3 II 500 2 2; 20

2057 TRIPROPYLENE 3 II 500 2 2; 20

2057 TRIPROPYLENE 3 II 1000 1 2

2058 VALERALDEHYDE 3 II 500 2 2; 20

2059 NITROCELLULOSE SOLUTION, FLAMMABLE with < 12,6 % nitrogen, by dry mass, and < 55 % nitrocellulose

3 I 100 10 2; 20


3 II 500 2 2;20


3 III 1000 1 2

2067 AMMONIUM NITRATE BASED FERTILIZER 5.1 III 200 5 8 24

2071 Ammonium nitrate based fertilizer, uniform mixtures of the nitrogen/phosphate, nitrogen/potash or nitrogen/phosphate/potash type, containing < 70 % ammonium nitrate and < 0,4% total combus-tible/organic material calculated as carbon or with < 45 % ammonium nitrate and unrestricted combustible material

9 III Non-dangerous for road transport

2073 AMMONIA SOLUTION, relative density < 0,880 at 15 °C in water, with > 35 % < 50 % ammonia

2.2 500 2 9; 10

2074 ACRYLAMIDE, SOLID 6.1 III 100 10 9b 13; 28 9

2075 CHLORAL, ANHYDROUS, STABILIZED 6.1 II 50 20 13; 28 9; 19

2076 CRESOLS, LIQUID 6.1 II 8 5 200 13; 28 9; 19

2077 alpha-NAPHTHYLAMINE 6.1 III 100 10 9b 13; 28 9

2078 TOLUENE DIISO-CYANATE 6.1 II 50 20 13; 28 9; 19

2079 DIETHYLENETRIAMINE 8 II 50 20

2186 HYDROGEN CHLORIDE, REFRIGERATED LIQUID 2.3 CARRIAGE PROHIBITED

2187 CARBON DIOXIDE, REFRIGERATED LIQUID 2.2 500 2 5 9; 11; 36 20

2188 ARSINE 2.3 2.1 10 100 9; 10; 36 2; 7; 17

2189 DICHLOROSILANE 2.3 2.1 10 100 9; 10; 36 2; 7; 17



8

2190 OXYGEN DIFLUORIDE, COMPRESSED 2.3 5.1 8

10 100 9; 10; 36 7; 17

2191 SULFURYL FLUORIDE 2.3 10 100 9; 10; 36 7; 17

2192 GERMANE 2.3 2.1 10 100 9; 10; 36 2; 7; 17

2193 HEXAFLUOROETHANE (REFRIGERANT GAS R 116)

2.2 500 2 9; 10; 36

2194 SELENIUM HEXA-FLUORIDE 2.3 8 10 100 9; 10; 36 7; 17

2195 TELLURIUM HEXA-FLUORIDE 2.3 8 10 100 9; 10; 36 7; 17

2196 TUNGSTEN HEXA-FLUORIDE 2.3 8 10 100 9; 10; 36 7; 17

2197 HYDROGEN IODIDE, ANHYDROUS 2.3 8 10 100 9; 10; 36 7; 17

2198 PHOSPHORUS PENTA-FLUORIDE 2.3 8 10 100 9; 10; 36 7; 17

2199 PHOSPHINE 2.3 2.1 10 100 9; 10; 36 2; 7; 17

2200 PROPADIENE, STABILIZED 2.1 100 10 9; 10; 36 2; 20

2201 NITROUS OXIDE, REFRIGERATED LIQUID 2.2 5.1 200 5 5 9; 11; 36 20

2202 HYDROGEN SELENIDE, ANHYDROUS 2.3 2.1 10 100 9; 10; 36 2; 7; 17

2203 SILANE 2.1 100 10 9; 10; 36 2

2204 CARBONYL SULFIDE 2.3 2.1 10 100 9; 10; 36 2; 7; 17

2205 ADIPONITRILE 6.1 III 100 10 13; 28 9

2206 ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE, SOLUTION, TOXIC, N.O.S.

6.1 II 50 20 13; 28 9; 19

2206 ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE, SOLUTION, TOXIC, N.O.S.

6.1 III 100 10 13;28 9

2208 CALCIUM HYPO-CHLORITE MIXTURE, DRY with > 10 % but < 39 % available chlorine

5.1 III 200 5 24; 35

2209 FORMALDEHYDE SOLUTION with > 25 % formaldehyde

8 III 200 5

2210 MANEB or MANEB PREPARATION with > 60 % maneb

4.2 III 4.3 50 20 1; 12 4

2211 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour

9 III 1 000 1 3

2212 BROWN ASBESTOS (amosite; mysorite) or (BLUE ASBESTOS (crocidolite)

9 II 20 50 1; 13; 28 19

2213 PARAFORMALDEHYDE 4.1 III 500 2 13 1

2214 PHTHALIC ANHYDRIDE with > 0,05 % maleic anhydride

8 III 200 5 9b

2215

MALEIC ANHYDRIDE MOLTEN 8 III 200 5

MALEIC ANHYDRIDE 8 III 200 5 9b

2216 Fish meal (Fish scrap), stabilized Non-dangerous for road transport

2217 SEED CAKE with < 1,5 % oil and < 11 % moisture 4.2 III 200 5 1 4

2218 ACRYLIC ACID, STABILIZED 8 II 3 10 100 2

2219 ALLYL GLYCIDYL ETHER 3 III 1 000 1 2



2222 ANISOLE 3 III 1 000 1 2

2224 BENZONITRILE 6.1 II 50 20 13; 28 9; 19

2225 BENZENESULFONYL CHLORIDE 8 III 200 5

2226 BENZOTRICHLORIDE 8 II 50 20

2227 n-BUTYL METHA-CRYLATE, STABILIZED 3 III 1 000 1 2

2232 2-CHLOROETHANAL 6.1 I 5 200 1; 13; 28 9; 17

2233 CHLOROANISIDINES 6.1 III 100 10 9b 13; 28 9

2234 CHLOROBENZOTRI-FLUORIDES 3 III 1 000 1 2

2235 CHLOROBENZYL CHLORIDES, LIQUID 6.1 III 100 10 13; 28 9

2236 3-CHLORO-4-METHYL-PHENYL ISOCYANATE, LIQUID

6.1 II 50 20 13; 28 9; 19

2237 CHLORONITROANILINES 6.1 III 100 10 9b 13; 28 9

2238 CHLOROTOLUENES 3 III 1 000 1 2

2239 CHLOROTOLUIDINES, SOLID 6.1 III 100 10 9b 13; 28 9

2240 CHROMOSULFURIC ACID 8 I 20 50 20

2241 CYCLOHEPTANE 3 II 500 2 2; 20

2242 CYCLOHEPTENE 3 II 500 2 2; 20

2243 CYCLOHEXYL ACETATE 3 III 1 000 1 2

2244 CYCLOPENTANOL 3 III 1 000 1 2

2245 CYCLOPENTANONE 3 III 1 000 1 2

2246 CYCLOPENTENE 3 II 500 2 2; 20

2247 n-DECANE 3 III 1 000 1 2

2248 DI-n-BUTYLAMINE 8 II 3 10 100 2

2249 DICHLORODIMETHYL ETHER, SYMMETRICAL 6.1 I CARRIAGE PROHIBITED

2250 DICHLOROPHENYL ISOCYANATES 6.1 II 50 20 11 13; 28 9; 19

2251 BICYCLO[2.2.1]HEPTA-2,5-DIENE, STABILIZED (2,5-NORBORNADIENE, STABILIZED)

3 II 500 2 2; 20

2252 1,2-DIMETHOXYETHANE 3 II 500 2 2; 20

2253 N,N-DIMETHYLANILINE 6.1 II 50 20 13; 28 9; 19

2254 MATCHES, FUSEE 4.1 III 500 2

2256 CYCLOHEXENE 3 II 500 2 2; 20

2257 POTASSIUM 4.3 I 0 1 23 20

2258 1,2-PROPYLENE-DIAMINE 8 II 3 10 100 2

2259 TRIETHYLENE-TETRAMINE 8 II 50 20

2260 TRIPROPYLAMINE 3 III 8 500 2 2

2261 XYLENOLS, SOLID 6.1 II 50 20 11 13; 28 9; 19

2262 DIMETHYLCARBAMOYL CHLORIDE 8 II 50 20

2263 DIMETHYLCYCLO-HEXANES 3 II 500 2 2; 20

2264 N,N-DIMETHYLCYCLO-HEXYLAMINE 8 II 3 10 100 2

2265 N,N-DIMETHYL-FORMAMIDE 3 III 1 000 1 2



2266 DIMETHYL-N-PROPYL-AMINE 3 II 8 200 5 2; 20

2267 DIMETHYL THIOPHOS-PHORYL CHLORIDE 6.1 II 8 5 200 13; 28 9; 19

2269 3,3'-IMINODIPROPYL-AMINE 8 III 200 5

2270 ETHYLAMINE, AQUEOUS SOLUTION with > 50 % and < 70 % ethylamine

3 II 8 200 5 2; 20

2271 ETHYL AMYL KETONE 3 III 1 000 1 2

2272 N-ETHYLANILINE 6.1 III 100 10 13; 28 9

2273 2-ETHYLANILINE 6.1 III 100 10 13; 28 9

2274 N-ETHYL-N-BENZYL-ANILINE 6.1 III 100 10 13; 28 9

2275 2-ETHYLBUTANOL 3 III 1 000 1 2

2276 2-ETHYLHEXYLAMINE 3 III 8 500 2 2

2277 ETHYL METHACRYLATE, STABILIZED 3 II 500 2 2; 20

2278 n-HEPTENE 3 II 500 2 2; 20

2279 HEXACHLORO-BUTADIENE 6.1 III 100 10 13; 28 9

2280 HEXAMETHYLENE-DIAMINE, SOLID 8 III 200 5 9b

2281 HEXAMETHYLENE DIISOCYANATE 6.1 II 50 20 13; 28 9; 19

2282 HEXANOLS 3 III 1 000 1 2

2283 ISOBUTYL METHA-CRYLATE, STABILIZED 3 III 1 000 1 2

2284 ISOBUTYRONITRILE 3 II 6.1 200 5 13; 28 2; 19

2285 ISOCYANATOBENZO-TRIFLUORIDES 6.1 II 3 5 200 13; 28 2; 9; 19

2286 PENTAMETHYLHEPTANE 3 III 1 000 1 2

2287 ISOHEPTENE 3 II 500 2 2; 20

2288 ISOHEXENE 3 II 500 2 2; 20

2289 ISOPHORONEDIAMINE 8 III 200 5

2290 ISOPHORONE DIISOCYANATE 6.1 III 100 10 13; 28 9

2291 LEAD COMPOUND, SOLUBLE, N.O.S. 6.1 III 100 10 9b 13; 28 9

2293 4-METHOXY-4-METHYL-PENTAN-2-ONE 3 III 1 000 1 2

2294 N-METHYLANILINE 6.1 III 100 10 13; 28 9

2295 METHYL CHLORO-ACETATE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2296 METHYLCYCLOHEXANE 3 II 500 2 2; 20

2297 METHYLCYCLO-HEXANONE 3 III 1 000 1 2

2298 METHYLCYCLO-PENTANE 3 II 500 2 2; 20

2299 METHYL DICHLORO-ACETATE 6.1 III 100 10 13; 28 9

2300 2-METHYL-5-ETHYL-PYRIDINE 6.1 III 100 10 13; 28 9

2301 2-METHYLFURAN 3 II 500 2 2; 20

2302 5-METHYLHEXAN-2-ONE 3 III 1 000 1 2

2303 ISOPROPENYLBENZENE 3 III 1 000 1 2

2304 NAPHTHALENE, MOLTEN 4.1 III 500 2

2305 NITROBENZENE-SULFONIC ACID 8 II 50 20 11

2306 NITROBENZOTRI-FLUORIDES, LIQUID 6.1 II 50 20 13; 28 9; 19



2307 3-NITRO-4-CHLORO-BENZOTRIFLUORIDE 6.1 II 50 20 13; 28 9; 19

2308 NITROSYLSULFURIC ACID, LIQUID 8 II 50 20

2309 OCTADIENES 3 II 500 2 2; 20

2310 PENTANE-2,4-DIONE 3 III 6.1 500 2 13; 28 2

2311 PHENETIDINES 6.1 III 100 10 13; 28 9

2312 PHENOL, MOLTEN 6.1 II 50 20 13 9; 19

2313 PICOLINES 3 III 1 000 1 2

2315 POLYCHLORINATED BIPHENYLS, LIQUID 9 II 0 1 1; 13; 28 19

2316 SODIUM CUPRO-CYANIDE, SOLID 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2317 SODIUM CUPRO-CYANIDE SOLUTION 6.1 I 5 200 1; 13; 28 9; 17

2318 SODIUM HYDRO-SULFIDE with < 25 % water of crystallization

4.2 II 100 10 1; 12

2319 TERPENE HYDRO-CARBONS, N.O.S. 3 III 1 000 1 2

2320 TETRAETHYLENE-PENTAMINE 8 III 200 5

2321 TRICHLOROBENZENES, LIQUID 6.1 III 100 10 13; 28 9

2322 TRICHLOROBUTENE 6.1 II 50 20 13; 28 9; 19

2323 TRIETHYL PHOSPHITE 3 III 1 000 1 2

2324 TRIISOBUTYLENE 3 III 1 000 1 2

2325 1,3,5-TRIMETHYL-BENZENE 3 III 1 000 1 2

2326 TRIMETHYLCYCLO-HEXYLAMINE 8 III 200 5

2327 TRIMETHYLHEXA-METHYLENEDIAMINES 8 III 200 5

2328 TRIMETHYLHEXA-METHYLENE DIISOCYANATE 6.1 III 100 10 13; 28 9

2329 TRIMETHYL PHOSPHITE 3 III 1 000 1 2

2330 UNDECANE 3 III 1 000 1 2

2331 ZINC CHLORIDE, ANHYDROUS 8 III 200 5 9b

2332 ACETALDEHYDE OXIME 3 III 1 000 1 2

2333 ALLYL ACETATE 3 II 6.1 200 5 13; 28 2; 19

2334 ALLYLAMINE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2335 ALLYL ETHYL ETHER 3 II 6.1 200 5 13; 28 2; 19

2336 ALLYL FORMATE 3 I 6.1 50 20 13; 28 2; 19

2337 PHENYL MERCAPTAN 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2338 BENZOTRIFLUORIDE 3 II 500 2 2; 20

2339 2-BROMOBUTANE 3 II 500 2 2; 20

2340 2-BROMOETHYL ETHYL ETHER 3 II 500 2 2; 20

2341 1-BROMO-3-METHYL-BUTANE 3 III 1 000 1 2

2342 BROMOMETHYL-PROPANES 3 II 500 2 2; 20

2343 2-BROMOPENTANE 3 II 500 2 2; 20

2344 BROMOPROPANES 3 II 500 2 2; 20

2344 BROMOPROPANES 3 III 1000 1 2

2345 3-BROMOPROPYNE 3 II 500 2 2; 20



2346 BUTANEDIONE 3 II 500 2 2; 20

2347 BUTYL MERCAPTAN 3 II 500 2 2; 20

2348 BUTYL ACRYLATES, STABILIZED 3 III 1 000 1 2

2350 BUTYL METHYL ETHER 3 II 500 2 2; 20

2351 BUTYL NITRITES 3 II 500 2 2; 20

2351 BUTYL NITRITES 3 III 1000 1 2

2352 BUTYL VINYL ETHER, STABILIZED 3 II 500 2 2; 20

2353 BUTYRYL CHLORIDE 3 II 8 200 5 2; 20

2354 CHLOROMETHYL ETHYL ETHER 3 II 6.1 200 5 13; 28 2; 19

2356 2-CHLOROPROPANE 3 I 100 10 2; 20

2357 CYCLOHEXYLAMINE 8 II 3 10 100 2

2358 CYCLOOCTATETRAENE 3 II 500 2 2; 20

2359 DIALLYLAMINE 3 II 6.1 8

200 5 13; 28 2; 19

2360 DIALLYL ETHER 3 II 6.1 200 5 13; 28 2; 19

2361 DIISOBUTYLAMINE 3 III 8 500 2 2

2362 1,1-DICHLOROETHANE 3 II 500 2 2; 20

2363 ETHYL MERCAPTAN 3 I 100 10 2; 20

2364 n-PROPYLBENZENE 3 III 1 000 1 2

2366 DIETHYL CARBONATE 3 III 1 000 1 2

2367 alpha-METHYL-VALERALDEHYDE 3 II 500 2 2; 20

2368 alpha-PINENE 3 III 1 000 1 2

2370 1-HEXENE 3 II 500 2 2; 20

2371 ISOPENTENES 3 I 100 10 2; 20

2372 1,2-DI-(DIMETHYLAMINO) ETHANE 3 II 500 2 2; 20

2373 DIETHOXYMETHANE 3 II 500 2 2; 20

2374 3,3-DIETHOXYPROPENE 3 II 500 2 2; 20

2375 DIETHYL SULFIDE 3 II 500 2 2; 20

2376 2,3-DIHYDROPYRAN 3 II 500 2 2; 20

2377 1,1-DIMETHOXYETHANE 3 II 500 2 2; 20

2378 2-DIMETHYLAMINO-ACETONITRILE 3 II 6.1 200 5 13; 28 2; 19

2379 1,3-DIMETHYLBUTYL-AMINE 3 II 8 200 5 2; 20

2380 DIMETHYLDIETHOXY-SILANE 3 II 500 2 2; 20

2381 DIMETHYL DISULFIDE 3 II 500 2 2; 20

2382 DIMETHYLHYDRAZINE, SYMMETRICAL 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2383 DIPROPYLAMINE 3 II 8 200 5 2; 20

2384 DI-n-PROPYL ETHER 3 II 500 2 2; 20

2385 ETHYL ISOBUTYRATE 3 II 500 2 2; 20

2386 1-ETHYLPIPERIDINE 3 II 8 200 5 2; 20

2387 FLUOROBENZENE 3 II 500 2 2; 20



2388 FLUOROTOLUENES 3 II 500 2 2; 20

2389 FURAN 3 I 100 10 2; 20

2390 2-IODOBUTANE 3 II 500 2 2; 20

2391 IODOMETHYLPRO-PANES 3 II 500 2 2; 20

2392 IODOPROPANES 3 III 1 000 1 2

2393 ISOBUTYL FORMATE 3 II 500 2 2; 20

2394 ISOBUTYL PROPIONATE 3 III 1 000 1 2

2395 ISOBUTYRYL CHLORIDE 3 II 8 200 5 2; 20

2396 METHACRYLALDEHYDE, STABILIZED 3 II 6.1 200 5 13; 28 2; 19

2397 3-METHYLBUTAN-2-ONE 3 II 500 2 2; 20

2398 METHYL tert-BUTYL ETHER 3 II 500 2 2; 20

2399 1-METHYLPIPERIDINE 3 II 8 200 5 2; 20

2400 METHYL ISOVALERATE 3 II 500 2 2; 20

2401 PIPERIDINE 8 I 3 5 200 2; 20

2402 PROPANETHIOLS 3 II 500 2 2; 20

2403 ISOPROPENYL ACETATE 3 II 500 2 2; 20

2404 PROPIONITRILE 3 II 6.1 200 5 13; 28 2; 19

2405 ISOPROPYL BUTYRATE 3 III 1 000 1 2

2406 ISOPROPYL ISOBUTYRATE 3 II 500 2 2; 20

2407 ISOPROPYL CHLORO-FORMATE 6.1 I 3; 8 5 200 1; 13; 28 2; 9; 17

2409 ISOPROPYL PROPIONATE 3 II 500 2 2; 20

2410 1,2,3,6-TETRAHYDRO-PYRIDINE 3 II 500 2 2; 20

2411 BUTYRONITRILE 3 II 6.1 200 5 13; 28 2; 19

2412 TETRAHYDRO-THIOPHENE 3 II 500 2 2; 20

2413 TETRAPROPYL ORTHO-TITANATE 3 III 1 000 1 2

2414 THIOPHENE 3 II 500 2 2; 20

2416 TRIMETHYL BORATE 3 II 500 2 2; 20

2417 CARBONYL FLUORIDE 2.3 8 10 100 9; 10; 36 7; 17

2418 SULFUR TETRA-FLUORIDE 2.3 8 10 100 9; 10; 36 7; 17

2419 BROMOTRIFLUORO-ETHYLENE 2.1 100 10 9; 10; 36 2; 20

2420 HEXAFLUOROACETONE 2.3 8 10 100 9; 10; 36 7; 17

2421 NITROGEN TRIOXIDE 2.3 CARRIAGE PROHIBITED

2422 OCTAFLUOROBUT-2-ENE (REFRIGERANT GAS R 1318)

2.2 500 2 9; 10; 36

2424 OCTAFLUOROPROPANE (REFRIGERANT GAS R 218)

2.2 500 2 9; 10; 36

2426 AMMONIUM NITRATE, LIQUID, hot concentrated solution, in a concentration of > 80 % and < 93 %

5.1 200 5

2427 POTASSIUM CHLORATE, AQUEOUS SOLUTION 5.1 II 50 20 6 24

2427 POTASSIUM CHLORATE, AQUEOUS SOLUTION 5.1 III 200 5 6 24



2428 SODIUM CHLORATE, AQUEOUS SOLUTION 5.1 II 50 20 24

2428 SODIUM CHLORATE, AQUEOUS SOLUTION 5.1 III 200 5 24

2429 CALCIUM CHLORATE, AQUEOUS SOLUTION 5.1 II 50 20 24

2429 CALCIUM CHLORATE, AQUEOUS SOLUTION 5.1 III 200 5 24

2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues)

8 I 20 50 10; 12 20


8 II 50 20 11


8 III 200 5 9b

2431 ANISIDINES 6.1 III 100 10 13; 28 9

2432 N,N-DIETHYLANILINE 6.1 III 100 10 13; 28 9

2433 CHLORONITRO-TOLUENES, LIQUID 6.1 III 100 10 13; 28 9

2434 DIBENZYLDICHLORO-SILANE 8 II 50 20

2435 ETHYLPHENYLDI-CHLOROSILANE 8 II 50 20

2436 THIOACETIC ACID 3 II 500 2 2; 20

2437 METHYLPHENYLDI-CHLOROSILANE 8 II 50 20

2438 TRIMETHYLACETYL CHLORIDE 6.1 I 3 8

5 200 1; 13; 28 2; 9; 17

2439 SODIUM HYDROGEN-DIFLUORIDE 8 II 50 20 11

2440 STANNIC CHLORIDE PENTAHYDRATE 8 III 200 5 9b

2441 TITANIUM TRICHLORIDE, PYROPHORIC or TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC

4.2 I 8 0 1 20

2442 TRICHLOROACETYL CHLORIDE 8 II 50 20

2443 VANADIUM OXY-TRICHLORIDE 8 II 50 20

2444 VANADIUM TETRA-CHLORIDE 8 I 20 50 20

2445 LITHIUM ALKYLS, LIQUID 4.2 I 4.3 0 1 20

2446 NITROCRESOLS, SOLID 6.1 III 100 10 9b 13; 28 9

2447 PHOSPHORUS, WHITE, MOLTEN 4.2 I 6.1 0 20

2448 SULFUR, MOLTEN 4.1 III 500 2

2451 NITROGEN TRI-FLUORIDE 2.2 5.1 200 5 9; 10; 36

2452 ETHYLACETYLENE, STABILIZED 2.1 100 10 9; 10; 36 2; 20

2453 ETHYL FLUORIDE (REFRIGERANT GAS R 161)

2.1 100 10 9; 10; 36 2; 20

2454 METHYL FLUORIDE (REFRIGERANT GAS R 41)

2.1 100 10 9; 10; 36 2; 20

2455 METHYL NITRITE 2.2 CARRIAGE PROHIBITED

2456 2-CHLOROPROPENE 3 I 100 10 2; 20

2457 2,3-DIMETHYLBUTANE 3 II 500 2 2; 20

2458 HEXADIENES 3 II 500 2 2; 20

2459 2-METHYL-1-BUTENE 3 I 100 10 2; 20



2460 2-METHYL-2-BUTENE 3 II 500 2 2; 20

2461 METHYLPENTADIENE 3 II 500 2 2; 20

2463 ALUMINIUM HYDRIDE 4.3 I 0 1 23 20

2464 BERYLLIUM NITRATE 5.1 II 6.1 20 50 11 24; 28

2465 DICHLOROISO-CYANURIC ACID, DRY or DICHLOROISO-CYANURIC ACID SALTS

5.1 II 50 20 24

2466 POTASSIUM SUPEROXIDE 5.1 I 20 50 10; 12 24 20

2468 TRICHLOROISO-CYANURIC ACID, DRY 5.1 II 50 20 24

2469 ZINC BROMATE 5.1 III 200 5 8 24

2470 PHENYLACETONITRILE, LIQUID 6.1 III 100 10 13; 28 9

2471 OSMIUM TETROXIDE 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2473 SODIUM ARSANILATE 6.1 III 100 10 9b 13; 28 9

2474 THIOPHOSGENE 6.1 II 50 20 13; 28 9; 19

2475 VANADIUM TRICHLORIDE 8 III 200 5 9b

2477 METHYL ISOTHIO-CYANATE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE, SOLUTION, FLAMMABLE, TOXIC, N.O.S.

3 II 6.1 200 5 13; 28 2; 19

2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE, SOLUTION, FLAMMABLE, TOXIC, N.O.S.

3 III 6.1 500 2 13;28 2

2480 METHYL ISOCYANATE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2481 ETHYL ISOCYANATE 3 I 6.1 50 20 13; 28 2; 19

2482 n-PROPYL ISOCYANATE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2483 ISOPROPYL ISO-CYANATE 3 I 6.1 50 20 13; 28 2; 19

2484 tert-BUTYL ISOCYANATE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2485 n-BUTYL ISOCYANATE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2486 ISOBUTYL ISOCYANATE 3 II 6.1 200 5 13; 28 2; 19

2487 PHENYL ISOCYANATE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2488 CYCLOHEXYL ISO-CYANATE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2490 DICHLOROISOPROPYL ETHER 6.1 II 50 20 13; 28 9; 19

2491 ETHANOLAMINE or ETHANOLAMINE SOLUTION 8 III 200 5

2493 HEXAMETHYLENEIMINE 3 II 8 200 5 2; 20

2495 IODINE PENTAFLUORIDE 5.1 I 6.1; 8 0 24; 28 20

2496 PROPIONIC ANHYDRIDE 8 III 200 5

2498 1,2,3,6-TETRAHYDRO-BENZALDEHYDE 3 III 1 000 1 2

2501 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION

6.1 II 50 20 13; 28 9; 19

2501 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION

6.1 III 100 10 13;28 9

2502 VALERYL CHLORIDE 8 II 3 10 100 2



2503 ZIRCONIUM TETRA-CHLORIDE 8 III 200 5 9b

2504 TETRABROMOETHANE 6.1 III 100 10 13; 28 9

2505 AMMONIUM FLUORIDE 6.1 III 100 10 9b 13; 28 9

2506 AMMONIUM HYDROGEN SULFATE 8 II 50 20 11 9a

2507 CHLOROPLATINIC ACID, SOLID 8 III 200 5 9b

2508 MOLYBDENUM PENTA-CHLORIDE 8 III 200 5 9b

2509 POTASSIUM HYDROGEN SULFATE 8 II 50 20 11 9a

2511 2-CHLOROPROPIONIC ACID 8 III 200 5

2512 AMINOPHENOLS (o-, m-, p-)

6.1 III 100 10 9b 13; 28 9

2513 BROMOACETYL BROMIDE 8 II 50 20

2514 BROMOBENZENE 3 III 1 000 1 2

2515 BROMOFORM 6.1 III 100 10 13; 28 9

2516 CARBON TETRA-BROMIDE 6.1 III 100 10 9b 13; 28 9

2517 1-CHLORO-1,1-DI-FLUOROETHANE (REFRIGERANT GAS R 142b)

2.1 100 10 9; 10; 36 2; 20

2518 1,5,9-CYCLODODECA-TRIENE 6.1 III 100 10 13; 28 9

2520 CYCLOOCTADIENES 3 III 1 000 1 2

2521 DIKETENE, STABILIZED 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2522 2-DIMETHYLAMINO-ETHYL METHACRYLATE 6.1 II 50 20 13; 28 9; 19

2524 ETHYL ORTHO-FORMATE 3 III 1 000 1 2

2525 ETHYL OXALATE 6.1 III 100 10 13; 28 9

2526 FURFURYLAMINE 3 III 8 500 2 2

2527 ISOBUTYL ACRYLATE, STABILIZED 3 III 1 000 1 2

2528 ISOBUTYL ISO-BUTYRATE 3 III 1 000 1 2

2529 ISOBUTYRIC ACID 3 III 8 500 2 2

2531 METHACRYLIC ACID, STABILIZED 8 II 50 20

2533 METHYL TRICHLORO-ACETATE 6.1 III 100 10 13; 28 9

2534 METHYLCHLOROSILANE 2.3 2.1; 8 10 100 9; 10; 36 2; 7; 17

2535 4-METHYLMORPHOLINE (N-METHYL-MORPHOLINE)

3 II 8 200 5 2; 20

2536 METHYLTETRA-HYDROFURAN 3 II 500 2 2; 20

2538 NITRONAPHTHALENE 4.1 III 500 2 1

2541 TERPINOLENE 3 III 1 000 1 2

2542 TRIBUTYLAMINE 6.1 II 50 20 13; 28 9; 19

2545 HAFNIUM POWDER, DRY 4.2 I 0 20

2545 HAFNIUM POWDER, DRY 4.2 II 100 10 1;12

2545 HAFNIUM POWDER, DRY 4.2 III 200 5 1 4

2546 TITANIUM POWDER, DRY 4.2 I 0 1 20

2546 TITANIUM POWDER, DRY 4.2 II 100 10 1;12



2546 TITANIUM POWDER, DRY 4.2 III 200 5 1 4

2547 SODIUM SUPEROXIDE 5.1 I 20 50 10; 12 24 20

2548 CHLORINE PENTA-FLUORIDE 2.3 5.1; 8 10 100 9; 10; 36 7; 17

2552 HEXAFLUOROACETONE HYDRATE, LIQUID 6.1 II 50 20 13; 28 9; 19

2554 METHYLALLYL CHLORIDE 3 II 500 2 2; 20

2555 NITROCELLULOSE WITH WATER with > 25 % water, by mass

4.1 II 50 20 17

2556 NITROCELLULOSE WITH ALCOHOL with > 25 % alcohol, by mass, and < 12,6 % nitrogen, by dry mass

4.1 II 50 20 17

2557 NITROCELLULOSE, with < 12,6 % nitrogen, by dry mass, MIXTURE WITH or WITHOUT PLASTICIZER, WITH or WITHOUT PIGMENT

4.1 II 50 20 17

2558 EPIBROMOHYDRIN 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2560 2-METHYLPENTAN-2-OL 3 III 1 000 1 2

2561 3-METHYL-1-BUTENE 3 I 100 10 2; 20

2564 TRICHLOROACETIC ACID SOLUTION 8 II 50 20

2564 TRICHLOROACETIC ACID SOLUTION 8 III 200 5

2565 DICYCLOHEXYLAMINE 8 III 200 5

2567 SODIUM PENTA-CHLOROPHENATE 6.1 II 50 20 11 13; 28 9; 19

2570 CADMIUM COMPOUND 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2570 CADMIUM COMPOUND 6.1 II 50 20 11 13;28 9;19

2570 CADMIUM COMPOUND 6.1 III 100 10 9b 13;28 9

2571 ALKYLSULFURIC ACIDS 8 II 50 20

2572 PHENYLHYDRAZINE 6.1 II 50 20 13; 28 9; 19

2573 THALLIUM CHLORATE 5.1 II 6.1 20 50 11; 12 24; 28

2574 TRICRESYL PHOSPHATE with > 3 % ortho isomer 6.1 II 50 20 13; 28 9; 19

2576 PHOSPHORUS OXY-BROMIDE, MOLTEN 8 II 50 20

2577 PHENYLACETYL CHLORIDE 8 II 50 20

2578 PHOSPHORUS TRIOXIDE 8 III 200 5 9b

2579 PIPERAZINE 8 III 200 5 9b

2580 ALUMINIUM BROMIDE SOLUTION 8 III 200 5

2581 ALUMINIUM CHLORIDE SOLUTION 8 III 200 5

2582 FERRIC CHLORIDE SOLUTION 8 III 200 5

2583 ALKYLSULFONIC ACIDS, SOLID or ARYL-SULFONIC ACIDS, SOLID with > 5 % free sulfuric acid

8 II 50 20 11

2584 ALKYLSULFONIC ACIDS, LIQUID or ARYLSUL-FONIC ACIDS, LIQUID with > 5 % free sulfuric acid

8 II 50 20

2585 ALKYLSULFONIC ACIDS, SOLID or ARYL-SULFONIC ACIDS, SOLID with < 5 % free sulfuric acid

8 III 200 5 9b

2586 ALKYLSULFONIC ACIDS, LIQUID or ARYLSUL-FONIC ACIDS, LIQUID with < 5 % free sulfuric acid

8 III 200 5

2587 BENZOQUINONE 6.1 II 50 20 11 13; 28 9; 19



2588 PESTICIDE, SOLID, TOXIC, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

2588 PESTICIDE, SOLID, TOXIC, N.O.S. 6.1 II 50 20 11 13;28 9;19

2588 PESTICIDE, SOLID, TOXIC, N.O.S. 6.1 III 100 10 9b 13;28 9

2589 VINYL CHLOROACETATE 6.1 II 3 5 200 13; 28 2; 9; 19

2590 WHITE ASBESTOS (chrysotile, actinolite, anthophyllite, tremolite)

9 III 20 50 1 13; 28

2591 XENON, REFRIGERATED LIQUID 2.2 500 2 5 9; 11; 36 20

2599 CHLOROTRIFLUORO-METHANE AND TRI-FLUOROMETHANE AZEOTROPIC MIXTURE with ca 60 % chlorotrifluoro-methane (REFRIGERANT GAS R 503)

2.2 500 2 9; 10; 36

2600 CARBON MONOXIDE AND HYDROGEN MIXTURE, COMPRESSED

2.3 2.1 10 100 9; 10; 36 2; 7; 17

2601 CYCLOBUTANE 2.1 100 10 9; 10; 36 2; 20

2602 DICHLORODIFLUORO-METHANE AND 1,1-DI-FLUOROETHANE AZEOTROPIC MIXTURE with ca 74 % dichlorodi-fluoromethane (REFRIGERANT GAS R 500)

2.2 500 2 9; 10; 36

2603 CYCLOHEPTATRIENE 3 II 6.1 200 5 13; 28 2; 19

2604 BORON TRIFLUORIDE DIETHYL ETHERATE 8 I 3 5 200 2; 20

2605 METHOXYMETHYL ISOCYANATE 3 I 6.1 50 20 13; 28 2; 19

2606 METHYL ORTHO-SILICATE 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2607 ACROLEIN DIMER, STABILIZED 3 III 1 000 1 2

2608 NITROPROPANES 3 III 1 000 1 2

2609 TRIALLYL BORATE 6.1 III 100 10 13; 28 9

2610 TRIALLYLAMINE 3 III 8 500 2 2

2611 PROPYLENE CHLORO-HYDRIN 6.1 II 3 5 200 13; 28 2; 9; 19

2612 METHYL PROPYL ETHER 3 II 500 2 2; 20

2614 METHALLYL ALCOHOL 3 III 1 000 1 2

2615 ETHYL PROPYL ETHER 3 II 500 2 2; 20

2616 TRIISOPROPYL BORATE 3 II 500 2 2; 20

2616 TRIISOPROPYL BORATE 3 III 1000 1 2

2617 METHYLCYCLO-HEXANOLS, flammable 3 III 1 000 1 2

2618 VINYLTOLUENES, STABILIZED 3 III 1 000 1 2

2619 BENZYLDIMETHYLAMINE 8 II 3 10 100 2

2620 AMYL BUTYRATES 3 III 1 000 1 2

2621 ACETYL METHYL CARBINOL 3 III 1 000 1 2

2622 GLYCIDALDEHYDE 3 II 6.1 200 5 13; 28 2; 19

2623 FIRELIGHTERS, SOLID with flammable liquid 4.1 III 500 2

2624 MAGNESIUM SILICIDE 4.3 II 100 10 1; 12 23

2626 CHLORIC ACID, AQUEOUS SOLUTION with < 10 % chloric acid

5.1 II 50 20 24



2627 NITRITES, INORGANIC, N.O.S. 5.1 II 50 20 24

2628 POTASSIUM FLUORO-ACETATE 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2629 SODIUM FLUORO-ACETATE 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2630 SELENATES and SELENITES 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2642 FLUOROACETIC ACID 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2643 METHYL BROMO-ACETATE 6.1 II 50 20 13; 28 9; 19

2644 METHYL IODIDE 6.1 I 5 200 1; 13; 28 9; 17

2645 PHENACYL BROMIDE 6.1 II 50 20 11 13; 28 9; 19

2646 HEXACHLOROCYCLO-PENTADIENE 6.1 I 5 200 1; 13; 28 9; 17

2647 MALONONITRILE 6.1 II 50 20 11 13; 28 9; 19

2648 1,2-DIBROMOBUTAN-3-ONE 6.1 II 50 20 13; 28 9; 19

2649 1,3-DICHLOROACETONE 6.1 II 50 20 11 13; 28 9; 19

2650 1,1-DICHLORO-1-NITRO-ETHANE 6.1 II 50 20 13; 28 9; 19

2651 4,4'-DIAMINODIPHENYL-METHANE 6.1 III 100 10 9b 13; 28 9

2653 BENZYL IODIDE 6.1 II 50 20 13; 28 9; 19

2655 POTASSIUM FLUORO-SILICATE 6.1 III 100 10 9b 13; 28 9

2656 QUINOLINE 6.1 III 100 10 13; 28 9

2657 SELENIUM DISULFIDE 6.1 II 50 20 11 13; 28 9; 19

2659 SODIUM CHLORO-ACETATE 6.1 III 100 10 9b 13; 28 9

2660 NITROTOLUIDINES (MONO) 6.1 III 100 10 9b 13; 28 9

2661 HEXACHLOROACETONE 6.1 III 100 10 13; 28 9

2662 HYDROQUINONE, SOLID 6.1 III 100 10 9b 13; 28 9

2664 DIBROMOMETHANE 6.1 III 100 10 13; 28 9

2667 BUTYLTOLUENES 6.1 III 100 10 13; 28 9

2668 CHLOROACETONITRILE 6.1 II 3 5 200 13; 28 2; 9; 19

2669 CHLOROCRESOLS, SOLUTION 6.1 II 50 20 13; 28 9; 19

2669 CHLOROCRESOLS, SOLUTION 6.1 III 100 10 13;28 9

2670 CYANURIC CHLORIDE 8 II 50 20 11

2671 AMINOPYRIDINES (o-, m-, p-)

6.1 II 50 20 11 13; 28 9; 19

2672 AMMONIA SOLUTION, relative density >0,880 < 0,957 at 15 °C in water, with > 10 % < 35 % ammonia

8 III 200 5

2673 2-AMINO-4-CHLORO-PHENOL 6.1 II 50 20 11 13; 28 9; 19

2674 SODIUM FLUORO-SILICATE 6.1 III 100 10 9b 13; 28 9

2676 STIBINE 2.3 2.1 10 100 9; 10; 36 2; 7; 17

2677 RUBIDIUM HYDROXIDE SOLUTION 8 II 50 20

2677 RUBIDIUM HYDROXIDE SOLUTION 8 III 200 5

2678 RUBIDIUM HYDROXIDE 8 II 50 20 11

2679 LITHIUM HYDROXIDE SOLUTION 8 II 50 20

2679 LITHIUM HYDROXIDE SOLUTION 8 III 200 5



2680 LITHIUM HYDROXIDE 8 II 50 20 11

2681 CAESIUM HYDROXIDE SOLUTION 8 II 50 20

2681 CAESIUM HYDROXIDE SOLUTION 8 III 200 5

2682 CAESIUM HYDROXIDE 8 II 50 20 11

2683 AMMONIUM SULFIDE SOLUTION 8 II 3 6.1

10 100 13; 28 2

2684 3-DIETHYLAMINO-PROPYLAMINE 3 III 8 500 2 2

2685 N,N-DIETHYLETHYLENE-DIAMINE 8 II 3 10 100 2

2686 2-DIETHYLAMINO-ETHANOL 8 II 3 10 100 2

2687 DICYCLOHEXYL-AMMONIUM NITRITE 4.1 III 500 2 1

2688 1-BROMO-3-CHLORO-PROPANE 6.1 III 100 10 13; 28 9

2689 GLYCEROL alpha-MONO-CHLOROHYDRIN 6.1 III 100 10 13; 28 9

2690 N,n-BUTYLIMIDAZOLE 6.1 II 50 20 13; 28 9; 19

2691 PHOSPHORUS PENTA-BROMIDE 8 II 50 20 11

2692 BORON TRIBROMIDE 8 I 20 50 20

2693 BISULFITES, AQUEOUS SOLUTION, N.O.S. 8 III 200 5

2698 TETRAHYDROPHTHALIC ANHYDRIDES with > 0,05 % of maleic anhydride

8 III 200 5 9b

2699 TRIFLUOROACETIC ACID 8 I 20 50 20

2705 1-PENTOL 8 II 50 20

2707 DIMETHYLDIOXANES 3 II 500 2 2; 20

2707 DIMETHYLDIOXANES 3 III 1000 1 2

2709 BUTYLBENZENES 3 III 1 000 1 2

2710 DIPROPYL KETONE 3 III 1 000 1 2

2713 ACRIDINE 6.1 III 100 10 9b 13; 28 9

2714 ZINC RESINATE 4.1 III 500 2 12 1

2715 ALUMINIUM RESINATE 4.1 III 500 2 12 1

2716 1,4-BUTYNEDIOL 6.1 III 100 10 9b 13; 28 9

2717 CAMPHOR, synthetic 4.1 III 500 2 1

2719 BARIUM BROMATE 5.1 II 6.1 20 50 11 24; 28

2720 CHROMIUM NITRATE 5.1 III 200 5 8 24

2721 COPPER CHLORATE 5.1 II 50 20 11 8 24

2722 LITHIUM NITRATE 5.1 III 200 5 8 24

2723 MAGNESIUM CHLORATE 5.1 II 50 20 11 8 24

2724 MANGANESE NITRATE 5.1 III 200 5 8 24

2725 NICKEL NITRATE 5.1 III 200 5 8 24

2726 NICKEL NITRITE 5.1 III 200 5 8 24

2727 THALLIUM NITRATE 6.1 II 5.1 5 200 11; 12 13; 28 9; 19

2728 ZIRCONIUM NITRATE 5.1 III 200 5 8 24

2729 HEXACHLOROBENZENE 6.1 III 100 10 9b 13; 28 9



2730 NITROANISOLES, LIQUID 6.1 III 100 10 13; 28 9

2732 NITROBROMO-BENZENES, LIQUID 6.1 III 100 10 13; 28 9

2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLY AMINES, FLAMMABLE, CORROSIVE, N.O.S.

3 I 8 50 20 2; 20


3 II 8 200 5 2;20


3 III 8 500 2 2

2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.

8 I 3 5 200 2; 20

2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.

8 II 3 10 100 2

2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S.

8 I 20 50 20


8 II 50 20


8 III 200 5

2738 N-BUTYLANILINE 6.1 II 50 20 13; 28 9; 19

2739 BUTYRIC ANHYDRIDE 8 III 200 5

2740 n-PROPYL CHLORO-FORMATE 6.1 I 3; 8 5 200 1; 13; 28 2; 9; 17

2741 BARIUM HYPOCHLORITE with > 22 % available chlorine

5.1 II 6.1 20 50 11 24; 28

2742 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S.

6.1 II 3; 8 5 200 13; 28 2; 9; 19

2743 n-BUTYL CHLORO-FORMATE 6.1 II 3; 8 5 200 13; 28 2; 9; 19

2744 CYCLOBUTYL CHLORO-FORMATE 6.1 II 3; 8 5 200 13; 28 2; 9; 19

2745 CHLOROMETHYL CHLOROFORMATE 6.1 II 8 5 200 13; 28 9; 19

2746 PHENYL CHLORO-FORMATE 6.1 II 8 5 200 13; 28 9; 19

2747 tert-BUTYLCYCLOHEXYL CHLOROFORMATE 6.1 III 100 10 13; 28 9

2748 2-ETHYLHEXYL CHLOROFORMATE 6.1 II 8 5 200 13; 28 9; 19

2749 TETRAMETHYLSILANE 3 I 100 10 2; 20

2750 1,3-DICHLORO-PROPANOL-2 6.1 II 50 20 13; 28 9; 19

2751 DIETHYLTHIOPHOS-PHORYL CHLORIDE 8 II 50 20

2752 1,2-EPOXY-3-ETHOXY-PROPANE 3 III 1 000 1 2

2753 N-ETHYLBENZYL-TOLUIDINES, LIQUID 6.1 III 100 10 13; 28 9

2754 N-ETHYLTOLUIDINES 6.1 II 50 20 13; 28 9; 19

2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 III 100 10 9b 13;28 9



2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 18 2; 19

2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2759 ARSENICAL PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2759 ARSENICAL PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2759 ARSENICAL PESTICIDE, SOLID, TOXIC 6.1 III 100 10 9b 13;28 9

2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6.1 III 100 10 11 9b 13;28 9

2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 III 100 10 9b 13;28 9

2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6.1 III 100 10 9b 13;28 9

2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2775 COPPER BASED PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2775 COPPER BASED PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2775 COPPER BASED PESTICIDE, SOLID, TOXIC 6,1 III 100 10 9b 13;28 9

2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 6.1 II 100 10 9b 13;28 9



2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC flash point < 23 °Cc.c.

3 I 6.1 50 20 13; 28 2; 19

2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC flash point < 23 °Cc.c.

3 II 6.1 200 5 13;28 2;19

2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC

6.1 I 5 200 10; 12 1; 13; 28 9; 17


6.1 II 50 20 11 13;28 9;19


6.1 III 100 10 9b 13;28 9

2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6.1 III 100 10 9b 13;28 9

2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 6.1 III 100 10 9b 13;28 9

2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2785 4-THIAPENTANAL 6.1 III 100 10 13; 28 9

2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 III 100 10 9b 13;28 9

2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6.1 II 50 20 13;28 9;19

2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6.1 III 100 10 13;28 9

2789 ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, > 80 % ACID, by mass

8 II 3 10 100 2

2790 ACETIC ACID, SOLUTION, > 50 % < 80 % acid, by mass

8 II 50 20



2790 ACETIC ACID, SOLUTION, > 10 % < 50 % acid, by mass

8 III 200 5

2793 FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to self-heating

4.2 III 200 5 1 4

2794 BATTERIES, WET, FILLED WITH ACID, electric storage

8 200 5 14

2795 BATTERIES, WET, FILLED WITH ALKALI, electric storage

8 200 5 14

2796 SULFURIC ACID with < 51 % acid or BATTERY FLUID, ACID

8 II 50 20

2797 BATTERY FLUID, ALKALI 8 II 50 20

2798 PHENYLPHOSPHORUS DICHLORIDE 8 II 50 20

2799 PHENYLPHOSPHORUS THIODICHLORIDE 8 II 50 20

2800 BATTERIES, WET, NON-SPILLABLE, electric storage 8 200 5 14

2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE, INTERMEDIATE, LIQUID, CORROSIVE, N.O.S

8 I 20 50 20


8 II 50 20


8 III 200 5

2802 COPPER CHLORIDE 8 III 200 5 9b

2803 GALLIUM 8 III 200 5 9b

2805 LITHIUM HYDRIDE, FUSED SOLID 4.3 II 100 10 1 23

2806 LITHIUM NITRIDE 4.3 I 0 1 23 20

2807 Magnetized material 9 III Non-dangerous for road transport

2809 MERCURY 8 III 200 5

2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 II 50 20 13;28 9;19

2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 III 100 10 13;28 9

2811 TOXIC SOLID, ORGANIC, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

2811 TOXIC SOLID, ORGANIC, N.O.S. 6.1 II 50 20 11 13;28 9;19

2811 TOXIC SOLID, ORGANIC, N.O.S. 6.1 III 100 10 9b 13;28 9

2812 Sodium aluminate, solid 8 III Non-dangerous for road transport

2813 WATER-REACTIVE SOLID, N.O.S. 4.3 I 0 1 23 20

2813 WATER-REACTIVE SOLID, N.O.S. 4.3 II 100 10 1;12 23

2813 WATER-REACTIVE SOLID, N.O.S. 4.3 III 500 2 1 5 23

2814 INFECTIOUS SUB-STANCE, AFFECTING HUMANS 6.2 II 0 13; 25; 26; 28

3; 9; 15

2815 N-AMINOETHYL-PIPERAZINE 8 III 200 5

2817 AMMONIUM HYDROGEN-DIFLUORIDE SOLUTION 8 II 6.1 10 100 13; 28

2817 AMMONIUM HYDROGEN-DIFLUORIDE SOLUTION 8 III 6.1 50 20 13;28



2818 AMMONIUM POLY-SULFIDE SOLUTION 8 II 6.1 10 100 13; 28

2818 AMMONIUM POLY-SULFIDE SOLUTION 8 III 6.1 50 20 13;28

2819 AMYL ACID PHOSPHATE 8 III 200 5

2820 BUTYRIC ACID 8 III 200 5

2821 PHENOL SOLUTION 6.1 II 50 20 13; 28 9; 19

2821 PHENOL SOLUTION 6.1 III 100 10 13;28 9

2822 2-CHLOROPYRIDINE 6.1 II 50 20 13; 28 9; 19

2823 CROTONIC ACID 8 III 200 5 9b

2826 ETHYL CHLOROTHIO-FORMATE 8 II 3 10 100 2

2829 CAPROIC ACID 8 III 200 5

2830 LITHIUM FERROSILICON 4.3 II 100 10 1; 12 23

2831 1,1,1-TRICHLORO-ETHANE 6.1 III 100 10 13; 28 9

2834 PHOSPHOROUS ACID 8 III 200 5 9b

2835 SODIUM ALUMINIUM HYDRIDE 4.3 II 100 10 1 23

2837 BISULFATES, AQUEOUS SOLUTION 8 II 50 20

2837 BISULFATES, AQUEOUS SOLUTION 8 III 200 5

2838 VINYL BUTYRATE, STABILIZED 3 II 500 2 2; 20

2839 ALDOL 6.1 II 50 20 13; 28 9; 19

2840 BUTYRALDOXIME 3 III 1 000 1 2

2841 DI-n-AMYLAMINE 3 III 6.1 500 2 13; 28 2

2842 NITROETHANE 3 III 1 000 1 2

2844 CALCIUM MANGANESE SILICON 4.3 III 500 2 1 5; 7 23

2845 PYROPHORIC LIQUID, ORGANIC, N.O.S. 4.2 I 0 1 20

2846 PYROPHORIC SOLID, ORGANIC, N.O.S. 4.2 I 0 1 20

2849 3-CHLOROPROPANOL-1 6.1 III 100 10 13; 28 9

2850 PROPYLENE TETRAMER 3 III 1 000 1 2

2851 BORON TRIFLUORIDE DIHYDRATE 8 II 50 20

2852 DIPICRYL SULFIDE, WETTED with > 10 % water, by mass

4.1 I 0 17

2853 MAGNESIUM FLUORO-SILICATE 6.1 III 100 10 9b 13; 28 9

2854 AMMONIUM FLUORO-SILICATE 6.1 III 100 10 9b 13; 28 9

2855 ZINC FLUOROSILICATE 6.1 III 100 10 9b 13; 28 9

2856 FLUOROSILICATES, N.O.S. 6.1 III 100 10 9b 13; 28 9

2857 REFRIGERATING MACHINES containing non-flammable, non-toxic gases or ammonia solutions (UN 2672)

2.2 500 2 9

2858 ZIRCONIUM, DRY, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns)

4.1 III 500 2 1

2859 AMMONIUM META-VANADATE 6.1 II 50 20 11 13; 28 9; 19

2861 AMMONIUM POLY-VANADATE 6.1 II 50 20 11 13; 28 9; 19



2862 VANADIUM PENTOXIDE, non-fused form 6.1 III 100 10 9b 13; 28 9

2863 SODIUM AMMONIUM VANADATE 6.1 II 50 20 11 13; 28 9; 19

2864 POTASSIUM META-VANADATE 6.1 II 50 20 11 13; 28 9; 19

2865 HYDROXYLAMINE SULFATE 8 III 200 5 9b

2869 TITANIUM TRICHLORIDE MIXTURE 8 II 50 20 11

2869 TITANIUM TRICHLORIDE MIXTURE 8 III 200 5 9b

2870 ALUMINIUM BORO-HYDRIDE 4.2 I 4.3 0 1 20

2870 ALUMINIUM BORO-HYDRIDE IN DEVICES 4.2 I 4.3 0 1 20

2871 ANTIMONY POWDER 6.1 III 100 10 9b 13; 28 9

2872 DIBROMOCHLORO-PROPANES 6.1 II 50 20 13; 28 9; 19

2872 DIBROMOCHLORO-PROPANES 6.1 III 100 10 13;28 9

2873 DIBUTYLAMINO-ETHANOL 6.1 III 100 10 13; 28 9

2874 FURFURYL ALCOHOL 6.1 III 100 10 13; 28 9

2875 HEXACHLOROPHENE 6.1 III 100 10 9b 13; 28 9

2876 RESORCINOL 6.1 III 100 10 9b 13; 28 9

2878 TITANIUM SPONGE POWDERS or TITANIUM SPONGE GRANULES

4.1 III 500 2 1

2879 SELENIUM OXY-CHLORIDE 8 I 6.1 5 200 13; 28 20

2880 CALCIUM HYPO-CHLORITE, HYDRATED, or CALCIUM HYPO-CHLORITE, HYDRATED MIXTURE with > 5,5 % < 16 % water

5.1 II 50 20 10

11 24; 35

2880 CALCIUM HYPO-CHLORITE, HYDRATED, or CALCIUM HYPO-CHLORITE, HYDRATED MIXTURE with > 5,5 % < 16 % water

5.1 III 100 10 8 24;35

2881 METAL CATALYST, DRY 4.2 I 0 1 20

2881 METAL CATALYST, DRY 4.2 II 100 10 1;12

2881 METAL CATALYST, DRY 4.2 III 200 5 1 4

2900 INFECTIOUS SUB-STANCE, AFFECTING ANIMALS only

6.2 0 13; 25; 26; 28

3; 9; 15

2901 BROMINE CHLORIDE 2.3 5.1 8

10 100 9; 10; 36 7; 17

2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 II 50 20 13;28 9;19

2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 III 100 10 13;28 9

2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

2904 CHLOROPHENOLATES, LIQUID or PHENOLATES, LIQUID

8 III 200 5



2905 CHLOROPHENOLATES, SOLID or PHENOLATES, SOLID

8 III 200 5 9b

2907 ISOSORBIDE DINITRATE MIXTURE with > 60 % lactose, mannose, starch or calcium hydrogen phosphate

4.1 II 50 20 11; 12 17

2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 8 I 3 5 200 2; 20

2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 8 II 3 10 100 2

2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. 8 I 4.1 5 200 20

2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. 8 II 4.1 10 100 11

2922 CORROSIVE LIQUID, TOXIC, N.O.S. 8 I 6.1 5 200 13; 28 20

2922 CORROSIVE LIQUID, TOXIC, N.O.S. 8 II 6.1 10 100 13;28

2922 CORROSIVE LIQUID, TOXIC, N.O.S. 8 III 6.1 50 20 13;28

2923 CORROSIVE SOLID, TOXIC, N.O.S. 8 I 6.1 5 200 13; 28 20

2923 CORROSIVE SOLID, TOXIC, N.O.S. 8 II 6.1 10 100 11 13;28

2923 CORROSIVE SOLID, TOXIC, N.O.S. 8 III 6.1 50 20 9b 13;28

2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 3 I 8 5 200 2; 20

2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 3 II 8 10 100 2;20

2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 3 III 8 50 20 2

2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S.

4.1 II 8 10 100 11; 12

2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S.

4.1 III 8 20 50 12

2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 4.1 II 6.1 10 100 11; 12 28

2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 4.1 III 6.1 20 50 12 28

2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 6.1 I 8 5 200 1; 13; 28 9; 17

2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 6.1 II 8 5 200 13;28 9;19

2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 6.1 I 8 5 200 1; 13; 28 9; 17

2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 6.1 II 8 5 200 11;12 13;28 9;19

2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 6.1 I 3 5 200 1; 13; 28 2; 9; 17

2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 6.1 II 3 5 200 13;28 2;9;19

2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 6.1 I 4.1 5 200 1; 13; 28 9; 17

2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 6.1 II 4.1 5 200 11 13;28 9;19

2931 VANADYL SULFATE 6.1 II 50 20 11 13; 28 9; 19

2933 METHYL-2-CHLORO-PROPIONATE 3 III 1 000 1 2

2934 ISOPROPYL 2-CHLORO-PROPIONATE 3 III 1 000 1 2

2935 ETHYL-2-CHLORO-PROPIONATE 3 III 1 000 1 2

2936 THIOLACTIC ACID 6.1 II 50 20 13; 28 9; 19

2937 alpha-METHYLBENZYL ALCOHOL, LIQUID 6.1 III 100 10 13; 28 9

2940 9-PHOSPHABICYCLO-NONANES (CYCLO-OCTADIENE PHOSPHINES)

4.2 II 100 10 1; 12

2941 FLUOROANILINES 6.1 III 100 10 13; 28 9



2942 2-TRIFLUOROMETHYL-ANILINE 6.1 III 100 10 13; 28 9

2943 TETRAHYDRO-FURFURYLAMINE 3 III 1 000 1 2

2945 N-METHYLBUTYLAMINE 3 II 8 200 5 2; 20

2946 2-AMINO-5-DIETHYL-AMINOPENTANE 6.1 III 100 10 13; 28 9

2947 ISOPROPYL CHLORO-ACETATE 3 III 1 000 1 2

2948 3-TRIFLUOROMETHYL-ANILINE 6.1 II 50 20 13; 28 9; 19

2949 SODIUM HYDRO-SULFIDE with > 25 % water of crystallization

8 II 50 20 11

2950 MAGNESIUM GRANULES, COATED, particle size > 149 microns

4.3 III 500 2 1 5 23

2956 5-tert-BUTYL-2,4,6-TRI-NITRO-m-XYLENE (MUSK XYLENE)

4.1 III 500 2 14 14

2965 BORON TRIFLUORIDE DIMETHYL ETHERATE 4.3 I 3 8

0 1 23 2; 20

2966 THIOGLYCOL 6.1 II 50 20 13; 28 9; 19

2967 SULFAMIC ACID 8 III 200 5 9b

2968 MANEB, STABILIZED or MANEB PREPARATION, STABILIZED against self-heating

4.3 III 500 2 1 5 23

2969 CASTOR BEANS or CASTOR POMACE or CASTOR FLAKE or CASTOR MEAL

9 II 1 000 1 3

2983 ETHYLENE OXIDE AND PROPYLENE OXIDE MIXTURE, with < 30 % ethylene oxide

3 I 6.1 50 20 13; 28 2; 19

2984 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with > 8 % and < 20 % hydrogen peroxide (stabilized as necessary)

5.1 III 200 5 24

2985 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S.

3 II 8 200 5 2; 20

2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S.

8 II 3 10 100 2

2987 CHLOROSILANES, CORROSIVE, N.O.S. 8 II 50 20

2988 CHLOROSILANES, WATER-REACTIVE, FLAMMABLE, CORROSIVE, N.O.S.

4.3 I 3 8

0 1 23 2; 20

2989 LEAD PHOSPHITE, DIBASIC 4.1 II 50 20 11

2989 LEAD PHOSPHITE, DIBASIC 4.1 III 500 2 1

2990 LIFE-SAVING APPLIANCES, SELF-INFLATING 9 1 000 1

2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19

2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9



2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19

2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9

2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 5 20 13;28 2;9

2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19

2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9

2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19

2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9

3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19

3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9

3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19



3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9

3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19

3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9

3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13;28 9;19


6.1 III 100 10 13;28 9

3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19

3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9

3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 1;9;19


6.1 III 3 50 20 13;28 2.9

3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13;28 9;19


6.1 III 100 10 13;28 9

3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17




6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19

3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9

3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

3022 1,2-BUTYLENE OXIDE, STABILIZED 3 II 500 2 2; 20

3023 2-METHYL-2-HEPTANE-THIOL 6.1 I 3 5 200 1; 13; 28 2; 9; 17

3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19


6.1 III 3 50 20 13;28 2;9

3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13;28 9;19


6.1 III 100 10 13;28 9

3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 II 50 20 11 13;28 9;19

3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 III 100 10 9b 13;28 9

3028 BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE SOLID, electric storage

8 200 5 14

3048 ALUMINIUM PHOSPHIDE PESTICIDE 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3051 ALUMINIUM ALKYLS 4.2 I 4.3 0 1 20

3052 ALUMINIUM ALKYL HALIDES, LIQUID 4.2 I 4.3 0 1 20

3053 MAGNESIUM ALKYLS 4.2 I 4.3 0 1 20

3054 CYCLOHEXYL MERCAPTAN 3 III 1 000 1 2

3055 2-(2-AMINOETHOXY)-ETHANOL 8 III 200 5

3056 n-HEPTALDEHYDE 3 III 1 000 1 2

3057 TRIFLUOROACETYL CHLORIDE 2.3 8 10 100 9; 10; 36 7; 17



3064 NITROGLYCERIN, SOLUTION IN ALCOHOL with > 1 % < 5 % nitroglycerin

3 II 500 2 2; 19

3065 ALCOHOLIC BEVERAGES, with > 70 % alcohol by volume

3 II 500 2 2; 20

3065 ALCOHOLIC BEVERAGES, with > 24 % < 70 % alcohol by volume

3 III 1 000 1 2

3066 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound)

8 II 50 20

3066 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound)

8 III 200 5

3070 ETHYLENE OXIDE AND DICHLORODIFLUORO-METHANE MIXTURE with < 12,5 % ethylene oxide

2.2 500 2 9; 10; 36

3071 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S.

6.1 II 3 5 200 13; 28 2; 9; 19

3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment

9 1 000 1

3073 VINYLPYRIDINES, STABILIZED 6.1 II 3 8

5 200 13; 28 2; 9; 19

3076 ALUMINIUM ALKYL HYDRIDES 4.2 I 4.3 0 1 20

3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

9 III 1 000 1 13 3 13

3078 CERIUM, turnings or gritty powder 4.3 II 100 10 1; 12 23

3079 METHACRYLONITRILE, STABILIZED 3 I 6.1 50 20 13; 28 2; 19

3080 ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE, SOLUTION, TOXIC, FLAMMABLE, N.O.S.

6.1 II 3 5 200 13; 28 2; 9; 19

3082 ENVIRONMENTALLY HAZARDOUS SUB-STANCE, LIQUID, N.O.S.

9 III 1 000 1 13

3083 PERCHLORYL FLUORIDE 2.3 5.1 10 100 9; 10; 36 7; 17

3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 8 I 5.1 5 200 24 20

3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 8 II 5.1 10 100 11;12 24

3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 5.1 I 8 0 24 20

3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 5.1 II 8 20 50 11;12 24

3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 5.1 III 8 100 10 24

3086 TOXIC SOLID, OXIDIZING, N.O.S. 6.1 I 5.1 5 200 1; 13; 28 9; 17

3086 TOXIC SOLID, OXIDIZING, N.O.S. 6.1 II 5.1 5 200 11;12 13;28 9;19

3087 OXIDIZING SOLID, TOXIC, N.O.S. 5.1 I 6.1 0 24; 28 20

3087 OXIDIZING SOLID, TOXIC, N.O.S. 5.1 II 6.1 20 50 11;12 24;28

3087 OXIDIZING SOLID, TOXIC, N.O.S. 5.1 III 6.1 100 10 24;28

3088 SELF-HEATING SOLID, ORGANIC, N.O.S. 4.2 II 100 10 1; 12



3088 SELF-HEATING SOLID, ORGANIC, N.O.S. 4.2 III 200 5 1

3089 METAL POWDER, FLAMMABLE, N.O.S. 4.1 II 50 20 11

3089 METAL POWDER, FLAMMABLE, N.O.S. 4.1 III 500 2 12 1

3090 LITHIUM METAL BATTERIES (including lithium alloy batteries)

9 II 20 50

3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIP-MENT or LITHIUM BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries)

9 II 20 50

3092 1-METHOXY-2-PRO-PANOL 3 III 1 000 1 2

3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. 8 I 5.1 5 200 24 20

3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. 8 II 5.1 10 100 24

3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. 8 I 4.3 5 200 20

3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. 8 II 4.3 10 100

3095 CORROSIVE SOLID, SELF-HEATING, N.O.S. 8 I 4.2 5 200 20

3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. 8 II 4.2 10 100 11;12

3096 CORROSIVE SOLID, WATER-REACTIVE, N.O.S. 8 I 4.3 5 200 20

3096 CORROSIVE SOLID, WATER-REACTIVE, N.O.S. 8 II 4.3 10 100 11;12

3097 FLAMMABLE SOLID, OXIDIZING, N.O.S. 4.1 CARRIAGE PROHIBITED

3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 5.1 I 8 0 24 20

3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 5.1 II 8 20 50 24

3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 5.1 III 8 100 10 24

3099 OXIDIZING LIQUID, TOXIC, N.O.S. 5.1 I 6.1 0 24; 28 20

3099 OXIDIZING LIQUID, TOXIC, N.O.S. 5.1 II 6.1 20 50 24;28

3099 OXIDIZING LIQUID, TOXIC, N.O.S. 5.1 III 6.1 100 10 24;28

3100 OXIDIZING SOLID, SELF-HEATING, N.O.S. 5.1 CARRIAGE PROHIBITED

3101 ORGANIC PEROXIDE TYPE B, LIQUID 5.2 1 0 1; 5 15; 20; 22; 24

9; 17

3102 ORGANIC PEROXIDE TYPE B, SOLID 5.2 1 0 1; 5 15; 20; 22; 24

9; 17

3103 ORGANIC PEROXIDE TYPE C, LIQUID 5.2 10 100 1 15; 20; 22; 24

8; 18

3104 ORGANIC PEROXIDE TYPE C, SOLID 5.2 10 100 1 15; 20; 22; 24

8; 18

3105 ORGANIC PEROXIDE TYPE D, LIQUID 5.2 10 100 1 15; 22; 24 19

3106 ORGANIC PEROXIDE TYPE D, SOLID 5.2 10 100 1 15; 22; 24 19

3107 ORGANIC PEROXIDE TYPE E, LIQUID 5.2 20 50 1 15; 22; 24

3108 ORGANIC PEROXIDE TYPE E, SOLID 5.2 20 50 1 15; 22; 24

3109 ORGANIC PEROXIDE TYPE F, LIQUID 5.2 20 50 1 15; 22; 24

3110 ORGANIC PEROXIDE TYPE F, SOLID 5.2 20 50 1 15; 22; 24

3111 ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED

5.2 1 0 8 15; 20; 21; 22; 24

4; 9; 16



3112 ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED

5.2 1 0 8 15; 20; 21; 22; 24

4; 9; 16

3113 ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED

5.2 0 8 15; 20; 21; 22; 24

4; 8; 17

3114 ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED

5.2 0 8 15; 20; 21; 22; 24

4; 8; 17

3115 ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

5.2 0 8 15; 21; 22; 24

4; 18

3116 ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED

5.2 0 8 15; 21; 22; 24

4; 18

3117 ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED

5.2 0 8 15; 21; 22; 24

4; 19

3118 ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED

5.2 0 8 15; 21; 22; 24

4; 19

3119 ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED

5.2 0 8 15; 21; 22; 24

4

3120 ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED

5.2 0 8 15; 21; 22; 24

4

3121 OXIDIZING SOLID, WATER-REACTIVE, N.O.S. 5.1 CARRIAGE PROHIBITED

3122 TOXIC LIQUID, OXIDIZING, N.O.S. 6.1 I 5.1 5 200 1; 13; 28 9; 17

3122 TOXIC LIQUID, OXIDIZING, N.O.S. 6.1 II 5.1 5 200 13;28 9;19

3123 TOXIC LIQUID, WATER-REACTIVE, N.O.S. 6.1 I 4.3 5 200 1; 13; 28 9; 17

3123 TOXIC LIQUID, WATER-REACTIVE, N.O.S. 6.1 II 4.3 5 200 13;28 9;19

3124 TOXIC SOLID, SELF-HEATING, N.O.S. 6.1 I 4.2 5 200 1; 13; 28 9; 17

3124 TOXIC SOLID, SELF-HEATING, N.O.S. 6.1 II 4.2 5 200 11;12 13;28 9;19

3125 TOXIC SOLID, WATER-REACTIVE, N.O.S. 6.1 I 4.3 5 200 1; 13; 28 9; 17

3125 TOXIC SOLID, WATER-REACTIVE, N.O.S. 6.1 II 4.3 5 200 11;12 13;28 9;19

3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S.

4.2 II 8 20 50 1

3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S.

4.2 III 8 50 20 1

3127 SELF-HEATING SOLID, OXIDIZING, N.O.S. 4.2 CARRIAGE PROHIBITED

3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 4.2 II 6.1 20 50 1 28

3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 4.2 III 6.1 50 20 1 28

3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 4.3 I 8 0 1 23 20

3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 4.3 II 8 20 50 1 23

3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 4.3 III 8 100 10 1 23

3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 4.3 I 6.1 0 1 23; 28 20

3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 4.3 II 6.1 20 50 1 23;28

3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 4.3 III 6.1 100 10 1 23;28

3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4.3 I 8 0 1 23 20

3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4.3 II 8 20 50 1;12 23

3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4.3 II 8 20 50 1 23



3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 4.3 CARRIAGE PROHIBITED

3133 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. 4.3 CARRIAGE PROHIBITED

3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 4.3 I 6.1 0 1 23; 28 20

3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 4.3 II 6.1 20 50 1 23;28

3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 4.3 III 6.1 100 10 1 23;28

3135 WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. 4.3 CARRIAGE PROHIBITED

3136 TRIFLUOROMETHANE, REFRIGERATED LIQUID 2.2 500 2 5 9; 11; 36 20

3137 OXIDIZING SOLID, FLAMMABLE, N.O.S. 5.1 CARRIAGE PROHIBITED

3138 ETHYLENE, ACETYLENE AND PROPYLENE MIXTURE, REFRIGE-RATED LIQUID, containing at least 71,5 % ethylene with < 22,5 % acetylene and < 6 % propylene

2.1 100 10 5 9; 11; 36 2; 17

3139 OXIDIZING LIQUID, N.O.S. 5.1 I 20 50 24 20

3139 OXIDIZING LIQUID, N.O.S. 5.1 II 50 20 24

3139 OXIDIZING LIQUID, N.O.S. 5.1 III 200 5 24

3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S.

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13;28 9;19


6.1 III 100 10 13;28 9

3141 ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S.

6.1 III 100 10 13; 28 9

3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 6.1 I 5 200

1; 13; 28 9; 17

3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 6.1 II 50 20 13;28 9;19

3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 6.1 III 100 10 13;28 9

3143 DYE, SOLID, TOXIC, N.O.S. or DYE, INTERMEDIATE, SOLID, TOXIC, N.O.S.

6.1 I 5 200 10; 12 1; 13; 28 9; 17


6.1 II 50 20 11 13;28 9;19


6.1 III 100 10 9b 13;28 9

3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S.

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13;28 9;19


6.1 III 100 10 13;28 9

3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues)

8 I 20 50 20


8 II 50 20




8 III 200 5

3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 6.1 II 50 20 11 13;28 9;19

3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 6.1 III 100 10 9b 13;28 9

3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE, INTERMEDIATE, SOLID, CORROSIVE, N.O.S.

8 I 20 50 10; 12 20


8 II 50 20 11


8 III 200 5 9b

3148 WATER-REACTIVE LIQUID, N.O.S. 4.3 I 0 1 23 20

3148 WATER-REACTIVE LIQUID, N.O.S. 4.3 II 100 10 1 23

3148 WATER-REACTIVE LIQUID, N.O.S. 4.3 III 500 2 1 23

3149 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid(s), water and < 5 % peroxyacetic acid, STABILIZED

5.1 II 8 20 50 24

3150 DEVICES, SMALL, HYDROCARBON GAS POWERED or HYDRO-CARBON GAS REFILLS FOR SMALL DEVICES with release device

2.1 100 10 9 2

3151 POLYHALOGENATED BIPHENYLS, LIQUID or POLYHALOGENATED TERPHENYLS, LIQUID

9 II 1 000 1 15 1; 13; 28 19

3152 POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID

9 II 1 000 1 15 1; 13; 28 19

3153 PERFLUORO(METHYL VINYL ETHER) 2.1 100 10 9; 10; 36 2; 20

3154 PERFLUORO(ETHYL VINYL ETHER) 2.1 100 10 9; 10; 36 2; 20

3155 PENTACHLOROPHENOL 6.1 II 50 20 11 13; 28 9; 19

3156 COMPRESSED GAS, OXIDIZING, N.O.S. 2.2 5.1 200 5 9; 10; 36

3157 LIQUEFIED GAS, OXIDIZING, N.O.S. 2.2 5.1 200 5 9; 10; 36

3158 GAS, REFRIGERATED LIQUID, N.O.S. 2.2 500 2 5 9; 11; 36 20

3159 1,1,1,2-TETRAFLUORO-ETHANE (REFRIGERANT GAS R 134a)

2.2 500 2 9; 10; 36

3160 LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 2.1 10 100 9; 10; 36 2; 7; 17

3161 LIQUEFIED GAS, FLAMMABLE, N.O.S. 2.1 100 10 9; 10; 36 2; 20

3162 LIQUEFIED GAS, TOXIC, N.O.S. 2.3 10 100 9; 10; 36 7; 17

3163 LIQUEFIED GAS, N.O.S. 2.2 500 2 9; 10; 36

3164 ARTICLES, PRES-SURIZED, HYDRAULIC or PNEUMATIC (containing non-flammable gas)

2.2 500 2 9

3165 AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methyl-hydrazine) (M86 fuel)

3 I 6.1 8

50 20 13; 28 2; 19

3166 Engine, internal combustion or vehicle, flammable gas, powered or vehicle, flammable liquid powered

9 Non-dangerous for road transport



3167 GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid

2.1 100 10 9 2

3168 GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid

2.3 2.1 10 100 9 2; 7

3169 GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated liquid

2.3 10 100 9 7

3170 ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS

4.3 4.3

II III

100 500

10 2

1; 12 1

3 1; 5

23 23

3171 Battery-powered vehicle or battery-powered equipment 9 Non-dangerous for road transport

3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S.

6.1 II 5 200 1; 13; 28 9; 17


6.1 II 50 20 13;28 9;19


6.1 III 100 10 13;28 9

3174 TITANIUM DISULFIDE 4.2 III 200 5 1

3175 SOLIDS or mixtures of solids (such as prepara-tions and wastes) CONTAINING FLAMMABLE LIQUID, N.O.S. having a flash point < 60,5 °C c.c.

4.1 II 50 20 11; 12 3

3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 4.1 II 50 20

3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 4.1 III 500 2

3178 FLAMMABLE SOLID, INORGANIC, N.O.S. 4.1 II 50 20 11

3178 FLAMMABLE SOLID, INORGANIC, N.O.S. 4.1 III 500 2 1

3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 4.1 II 6.1 10 100 11; 12 28

3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 4.1 III 6.1 20 50 12 28

3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S.

4.1 II 8 10 100 11; 12

3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S.

4.1 III 8 20 50 12

3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.

4.1 II 50 20 11

3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.

4.1 III 500 2 1

3182 METAL HYDRIDES, FLAMMABLE, N.O.S. 4.1 II 50 20

3183 SELF-HEATING LIQUID, ORGANIC, N.O.S. 4.1 III 500 2 1

3183 SELF-HEATING LIQUID, ORGANIC, N.O.S. 4.2 II 100 10 1

3183 SELF-HEATING LIQUID, ORGANIC, N.O.S. 4.2 III 200 5 1

3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 4.2 II 6.1 20 50 1 28

3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 4.2 III 6.1 50 20 1 28

3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S.

4.2 II 8 20 50 1



3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S.

4.2 III 8 50 20 1

3186 SELF-HEATING LIQUID, INORGANIC, N.O.S. 4.2 II 100 10 1

3186 SELF-HEATING LIQUID, INORGANIC, N.O.S. 4.2 III 200 5 1

3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 4.2 II 6.1 20 50 1 28

3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 4.2 III 6.1 50 20 1 28

3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S.

4.2 II 8 20 50 1

3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S.

4.2 III 8 50 20 1

3189 METAL POWDER, SELF-HEATING, N.O.S. 4.2 II 1000 10 1; 12

3189 METAL POWDER, SELF-HEATING, N.O.S. 4.2 III 200 5 1 4

3190 SELF-HEATING SOLID, INORGANIC, N.O.S. 4.2 II 100 10 1; 12

3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. 4.2 III 200 5 1 4

3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. 4.2 II 6.1 20 50 1 28

3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. 4.2 III 6.1 50 20 1 28

3192 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S.

4.2 II 8 20 50 1

3192 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S.

4.2 III 8 50 20 1

3194 PYROPHORIC LIQUID, INORGANIC, N.O.S. 4.2 I 0 1 20

3200 PYROPHORIC SOLID, INORGANIC, N.O.S. 4.2 I 0 1 20

3205 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 4.22 II 100 10 1; 12

3205 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 4.2 III 200 5 1

3206 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S.

4.2 II 8 20 50 1

3206 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S.

4.2 III 8 50 20 1

3208 METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. 4.3 I 0 1 23 20

3208 METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. 4.3 II 100 10 1;12 23

3208 METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. 4.3 III 500 2 1 5 23

3209 METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S.

4.3 I 4.2 0 1 23 20


4.3 II 4.2 20 50 1 23


4.3 III 4.2 100 10 1 5 23

3210 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 II 50 20 24

3210 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 III 200 5 24

3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 II 50 20 6 24



3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 III 200 5 6 24

3212 HYPOCHLORITES, INORGANIC, N.O.S. 5.1 II 50 20 11 24

3213 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 II 50 20 6 24

3213 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 III 200 5 24

3214 PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 II 50 20 24

3215 PERSULFATES INORGANIC, N.O.S. 5.1 III 200 5 8 24

3216 PERSULFATES INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 III 200 5 24

3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 II 50 20 24

3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 III 200 5 24

3219 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 II 50 20 24

3219 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

5.1 III 200 5 24

3220 PENTAFLUOROETHANE (REFRIGERANT GAS R 125)

2.2 500 2 9; 10; 36

3221 SELF-REACTIVE LIQUID, TYPE B 4.1 1 0 1 15; 20; 22 9; 17

3222 SELF-REACTIVE SOLID, TYPE B 4.1 1 0 1 15; 20; 22 9; 17

3223 SELF-REACTIVE LIQUID, TYPE C 4.1 10 100 1 15; 20; 22 8; 18

3224 SELF-REACTIVE SOLID, TYPE C 4.1 10 100 1 15; 20; 22 8; 18

3225 SELF-REACTIVE LIQUID, TYPE D 4.1 10 100 1 15; 22 19

3226 SELF-REACTIVE SOLID, TYPE D 4.1 10 100 1 15; 22 19

3227 SELF-REACTIVE LIQUID, TYPE E 4.1 20 50 1 15; 22

3228 SELF-REACTIVE SOLID, TYPE E 4.1 20 50 1 15; 22

3229 SELF-REACTIVE LIQUID, TYPE F 4.1 20 50 1 15; 22

3230 SELF-REACTIVE SOLID, TYPE F 4.1 20 50 1 15; 22

3231 SELF-REACTIVE LIQUID, TYPE B, TEMPERATURE CONTROLLED

4.1 1 0 8 15; 20; 21; 22

4; 9; 16

3232 SELF-REACTIVE SOLID, TYPE B, TEMPERATURE CONTROLLED

4.1 1 0 8 15; 20; 21; 22

4; 9; 16

3233 SELF-REACTIVE LIQUID, TYPE C, TEMPERATURE CONTROLLED

4.1 0 8 15; 20; 21; 22

4; 8; 17

3234 SELF-REACTIVE SOLID, TYPE C, TEMPERATURE CONTROLLED

4.1 0 8 15; 20; 21; 22

4; 8; 17

3235 SELF-REACTIVE LIQUID, TYPE D, TEMPERATURE CONTROLLED

4.1 0 8 15; 21; 22 4; 18

3236 SELF-REACTIVE SOLID, TYPE D, TEMPERATURE CONTROLLED

4.1 0 8 15; 21; 22 4; 18



3237 SELF-REACTIVE LIQUID, TYPE E, TEMPERATURE CONTROLLED

4.1 0 8 15; 21; 22 4; 19

3238 SELF-REACTIVE SOLID, TYPE E, TEMPERATURE CONTROLLED

4.1 0 8 15; 21; 22 4; 19

3239 SELF-REACTIVE LIQUID, TYPE F, TEMPERATURE CONTROLLED

4.1 0 8 15; 21; 22 4

3240 SELF-REACTIVE SOLID, TYPE F, TEMPERATURE CONTROLLED

4.1 0 8 15; 21; 22 4

3241 2-BROMO-2-NITRO-PROPANE-1,3-DIOL 4.1 III 500 2 14 14

3242 AZODICARBONAMIDE 4.1 II 50 20 14 14

3243 SOLIDS CONTAINING TOXIC LIQUID, N.O.S. 6.1 II 50 20 10 13; 28 9; 19

3244 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. 8 II 50 20 10

3245 GENETICALLY MODIFIED MICRO-ORGANISMS 9 50 20 1; 13; 26; 27; 28

17

3246 METHANESULFONYL CHLORIDE 6.1 I 8 5 200 1; 13; 28 9; 17

3247 SODIUM PEROXY-BORATE, ANHYDROUS 5.1 II 50 20 24

3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 II 6.1 200 5 13; 28 2; 19

3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 III 6.1 500 2 13;28 2

3249 MEDICINE, SOLID, TOXIC, N.O.S. 6.1 II 50 20 13; 28 9; 19

3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S.

6.1 III 100 10 9b 13;28 9

3250 CHLOROACETIC ACID, MOLTEN 6.1 II 8 5 200 13 9; 19

3251 ISOSORBIDE-5-MONO-NITRATE 4.1 III 500 2 14 14

3252 DIFLUOROMETHANE (REFRIGERANT GAS R 32)

2.1 100 10 9; 10; 36 2; 20

3253 DISODIUM TRIOXO-SILICATE 8 III 200 5 9b

3254 TRIBUTYLPHOSPHANE 4.2 I 0 1

3255 tert-BUTYL HYPO-CHLORITE 4.2 CARRIAGE PROHIBITED

3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S., with flash point > 60,5 °C c.c., at or above its flash point

3 III 1 000 1 2

3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100°C and below its flash point (including molten metals, molten salts, etc.)

9 III 1 000 1 12

3258 ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 °C

9 III 1 000 1 13


8 I 20 50 10; 12 20


8 II 50 20 11


8 III 200 5 9b

3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 8 I 20 50 10; 12 20

3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 8 II 50 20 11



3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 8 III 200 5 9b

3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 8 I 20 50 10; 12 20

3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 8 II 50 20 11

3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 8 III 200 5 9b

3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 8 I 20 50 10; 12 20

3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 8 II 50 20 11

3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 8 III 200 5 9b

3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 8 I 20 50 10; 12 20

3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 8 II 50 20 11

3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 8 III 200 5 9b

3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 8 I 20 50 20

3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 8 II 50 20

3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 8 III 200 5

3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 I 20 50 20

3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 II 50 20

3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 III 200 5

3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 8 I 20 50 20

3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 8 II 50 20

3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 8 III 200 5

3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 8 I 20 50 20

3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 8 II 50 20

3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 8 III 200 5

3268 AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT PRETEN-SIONERS

9 III 50 20

3269 POLYESTER RESIN KIT 3 II 500 2 2; 20

3269 POLYESTER RESIN KIT 3 III 100 1 2

3270 NITROCELLULOSE MEMBRANE FILTERS, with < 12,6 % nitrogen, by dry mass

4.1 II 50 20

3271 ETHERS, N.O.S. 3 I 500 2 2; 20

3271 ETHERS, N.O.S. 3 III 1000 1 2

3272 ESTERS, N.O.S. 3 II 500 2 2; 20

3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3 III 1000 1 2

3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3 I 6.1 50 20 13; 28 2; 19

3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3 II 6.1 200 5 13;28 2;19

3274 ALCOHOLATES SOLUTION, N.O.S., in alcohol 3 II 8 200 5 2; 20

3275 NITRILES, TOXIC, FLAMMABLE, N.O.S. 6.1 I 3 5 200 1; 13; 28 2; 9; 17

3275 NITRILES, TOXIC, FLAMMABLE, N.O.S. 6.1 II 3 5 200 13;28 2;9;19

3276 NITRILES, TOXIC, LIQUID, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

3276 NITRILES, TOXIC, LIQUID, N.O.S. 6.1 II 50 20 13;28 9;19

3276 NITRILES, TOXIC, LIQUID, N.O.S. 6.1 III 100 10 13;28 9



3277 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. 6.1 II 8 5 200 13; 28 9; 19

3278 ORGANOPHOSPHORUS COMPOUND, TOXIC, LIQUID, N.O.S.

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13;28 9;19


6.1 III 100 10 13;28 9

3279 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S.

6.1 I 3 5 200 1; 13; 28 2; 9; 17

3279 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S.

6.1 II 3 5 200 13;28 1;9;19

3280 ORGANOARSENIC COMPOUND, LIQUID N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

3280 ORGANOARSENIC COMPOUND, LIQUID N.O.S. 6.1 II 50 20 13;28 9;19

3280 ORGANOARSENIC COMPOUND, LIQUID N.O.S. 6.1 III 100 10 13;28 9

3281 METAL CARBONYL, LIQUID N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

3281 METAL CARBONYL, LIQUID N.O.S. 6.1 II 50 20 13;28 9;19

3281 METAL CARBONYL, LIQUID N.O.S. 6.1 III 100 10 13;28 9

3282 ORGANOMETALLIC COMPOUND, TOXIC, LIQUID N.O.S.

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13;28 9;19


6.1 III 100 10 13;28 9

3283 SELENIUM COMPOUND, SOLID, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3283 SELENIUM COMPOUND, SOLID, N.O.S. 6.1 II 50 20 11 13;28 9;19

3283 SELENIUM COMPOUND, SOLID, N.O.S. 6.1 III 100 10 9b 13;28 9

3284 TELLURIUM COMPOUND, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3284 TELLURIUM COMPOUND, N.O.S. 6.1 II 50 20 11 13;28 9;19

3284 TELLURIUM COMPOUND, N.O.S. 6.1 III 100 10 9b 13;28 9

3285 VANADIUM COMPOUND, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3285 VANADIUM COMPOUND, N.O.S. 6.1 II 50 20 11 13;28 9;19

3285 VANADIUM COMPOUND, N.O.S. 6.1 III 100 10 9b 13;28 9

3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. 3 I 6.1 8

50 20 13; 28 2; 19

3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. 3 II 6.1 8

200 5 13;28 2;19

3287 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

3287 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 II 50 20 13;28 9;19

3287 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 III 100 10 13;28 9

3288 TOXIC SOLID, INORGANIC, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

3288 TOXIC SOLID, INORGANIC, N.O.S. 6.1 II 50 20 11 13;28 9;19

3288 TOXIC SOLID, INORGANIC, N.O.S. 6.1 III 100 10 9b 13;28 9



3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 6.1 I 8 5 200 1; 13; 28 9; 17

3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 6.1 II 8 5 200 13;28 9;19

3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 6.1 I 8 5 200 1; 13; 28 9; 17

3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 6.1 II 8 5 200 11;12 13;28 9;19

3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S.

6.2 II 0 1 11 13; 25; 28 3

3292 BATTERIES, CON-TAINING SODIUM or CELLS, CONTAINING SODIUM

4.3 II 100 10 1 23

3293 HYDRAZINE, AQUEOUS SOLUTION with < 37 % hydrazine, by mass

6.1 III 100 10 13; 28 9

3294 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with < 45 % hydrogen cyanide

6.1 I 3 5 200 1; 13; 28 2; 9; 17

3295 HYDROCARBONS, LIQUID, N.O.S. 3 I 100 10 2; 20

3295 HYDROCARBONS, LIQUID, N.O.S. 3 II 500 2 2;20

3295 HYDROCARBONS, LIQUID, N.O.S. 3 III 1000 1 2

3296 HEPTAFLUOROPRO-PANE (REFRIGERANT GAS R 227)

2.2 500 2 9; 10; 36

3297 ETHYLENE OXIDE AND CHLOROTETRA-FLUOROETHANE MIXTURE with < 8,8 % ethylene oxide

2.2 500 2 9; 10; 36

3298 ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with <7,9% ethylene oxide

2.2 500 2 9; 10; 36

3299 ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with < 5,6 % ethylene oxide

2.2 500 2 9; 10; 36

3300 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with > 87 % ethylene oxide

2.3 2.1 10 100 9; 10; 36 2; 7; 17

3301 CORROSIVE LIQUID, SELF-HEATING, N.O.S. 8 I 4.2 5 200 20

3301 CORROSIVE LIQUID, SELF-HEATING, N.O.S. 8 II 4.2 10 100

3302 2-DIMETHYLAMINO-ETHYL ACRYLATE 6.1 II 50 20 13; 28 9; 19

3303 COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. 2.3 5.1 10 100 9; 10; 36 7; 17

3304 COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. 2.3 8 10 100 9; 10; 36 7; 17

3305 COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S.

2.3 2.1 8

10 100 9; 10; 36 2; 7; 17

3306 COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S.

2.3 5.1 8

10 100 9; 10; 36 7; 17

3307 LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. 2.3 5.1 10 100 9; 10; 36 7; 17

3308 LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. 2.3 8 10 100 9; 10; 36 7; 17

3309 LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S.

2.3 2.1 8

10 100 9; 10; 36 2; 7; 17

3310 LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S.

2.3 5.1 8

10 100 9; 10; 36 7; 17

3311 GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. 2.2 5.1 200 5 5 9; 11; 36 20

3312 GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. 2.1 100 10 5 9; 11; 36 2; 17



3313 ORGANIC PIGMENTS, SELF-HEATING 4.2 II 100 10 1

3313 ORGANIC PIGMENTS, SELF-HEATING 4.2 III 200 5 1

3314 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour

9 III 500 2 3

3315 CHEMICAL SAMPLE, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

3316 CHEMICAL KIT or FIRST AID KIT 9 II 500 2

3316 CHEMICAL KIT or FIRST AID KIT 9 III 1000 1

3317 2-AMINO-4,6-DINITRO-PHENOL, WETTED with > 20 % water, by mass

4.1 I 0 17

3318 AMMONIA SOLUTION, relative density <0,880 at 15°C in water, with >50% ammonia

2.3 8 10 100 9; 10 7

3319 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S., with >2 % but < 10 % nitroglycerin, by mass

4.1 II 50 20 17

3320 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION, with < 12 % sodium borohydride and < 40 % sodium hydroxide by mass

8 II 50 20

3320 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION, with < 12 % sodium borohydride and < 40 % sodium hydroxide by mass

8 III 200 5

3334 Aviation regulated liquid, n.o.s. 9 Non-dangerous for road transport

3335 Aviation regulated solid, n.o.s. 9 Non-dangerous for road transport

3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S.

3 I 100 10 2; 20


3 II 500 2 2;20


3 III 1000 1 2

3337 REFRIGERANT GAS R 404A (Pentafluoro-ethane, 1,1,1-trifluoro-ethane and 1,1,1,2-tetra-fluoroethane zeotropic mixture with ca 44 % pentafluoroethane and 52 % trifluoroethane)

2.2 500 2 9; 10; 36

3338 REFRIGERANT GAS R 407A (Difluoromethane, pentafluoroethane and 1,1,1,2-tetrafluoroethane zeotropic mixture with ca 20 % difluoromethane and 40 % pentafluoroethane)

2.2 500 2 9; 10; 36

3339 REFRIGERANT GAS R 407B (Difluoromethane, pentafluoroethane and 1,1,1,2-tetrafluoroethane zeotropic mixture with ca 10 % difluoromethane and 70 % pentafluoroethane)

2.2 500 2 9; 10; 36

3340 REFRIGERANT GAS R 407C (Difluoromethane, pentafluoroethane and 1,1,1,2-tetrafluoroethane zeotropic mixture with ca 23 % difluoromethane and 25 % pentafluoroethane)

2.2 500 2 9; 10; 36



3341 THIOUREA DIOXIDE 4.2 II 100 10 1; 12

3341 THIOUREA DIOXIDE 4.2 III 200 5 1

3342 XANTHATES 4.2 II 100 10 1; 12

3342 XANTHATES 4.2 III 200 5 1

3343 NITROGLYCERIN MIXTURE, DESEN-SITIZED, LIQUID, FLAMMABLE, N.O.S., with < 30 % nitroglycerin, by mass

3 100 10 2; 17

3344 PENTAERYTHRITE TETRANITRATE MIXTURE, DESEN-SITIZED, SOLID, N.O.S., with > 10 % < 20 % PETN, by mass

4.1 II 50 20 17

3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC

6.1 I 5 200 10; 12 1; 13; 28 9; 17


6.1 II 50 20 11 13;28 9;19


6.1 III 100 10 9b 13;28 9

3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 I 6.1 50 20 13; 28 2; 19

3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

3 II 6.1 200 5 13;28 2;19

3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 1;9;19


6.1 III 3 50 20 13;28 2;9

3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC

6.1 I 5 200 1; 13; 28 9; 17


6.1 II 50 20 13;28 9;19


6.1 III 100 10 13;28 9

3349 PYRETHROID PESTICIDE, SOLID, TOXIC 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point < 23 °C c.c.

6.1 II 50 20 11 13;28 9;19


6.1 III 100 10 9b 13;28 9


3 I 6.1 50 20 13; 28 2; 19


3 II 6.1 200 5 13;28 2;19

3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point > 23 °C c.c.

6.1 I 3 5 200 1; 13; 28 2; 9; 17


6.1 II 3 5 200 13;28 2;9;19




6.1 III 3 50 20 13;28 2;9

3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 I 5 200 1; 13; 28 9; 17

3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 II 50 20 13;28 9;19

3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 III 100 10 13;28 9

3354 INSECTICIDE GAS, FLAMMABLE, N.O.S. 2.1 100 10 9; 10; 36 2; 20

3355 INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 2.1 10 100 9; 10; 36 2; 7; 17

3356 OXYGEN GENERATOR, CHEMICAL 5.1 II 50 20 24

3357 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S., with < 30 % nitroglycerin, by mass

3 II 500 2 2; 17

3358 REFRIGERATING MACHINES containing flammable, non-toxic, liquefied gas

2.1 100 10 9 2

3359 FUMIGATED UNIT 9 1 000 1

3360 Fibres, vegetable, dry 4.1 Non-dangerous for road transport

3361 CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 6.1 II 8 5 200 13; 28 9; 19

3362 CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S.

6.1 II 8 3

5 200 13; 28 2; 9; 19

3363 Dangerous goods in machinery or dangerous goods in apparatus

9 Non-dangerous for road transport

3364 TRINITROPHENOL (PICRIC ACID), WETTED, with > 10 % water, by mass

4.1 I 0 17

3365 TRINITROCHLORO-BENZENE (PICRYL CHLORIDE) wetted with > 10 % water, by mass

4.1 I 0 17

3366 TRINITROTOLUENE (TNT), wetted with > 10 % water, by mass

4.1 I 0 17

3367 TRINITROBENZENE, wetted with > 10 % water, by mass

4.1 I 0 17

3368 TRINITROBENZOIC ACID, wetted with > 10 % water, by mass

4.1 I 0 17

3369 SODIUM DINITRO-ortho-CRESOLATE, WETTED with > 10 % water, by mass

4.1 I 6.1 0 13; 28 17

3370 UREA NITRATE, wetted with > 10 % water, by mass 4.1 I 0 17

3371 2-METHYLBUTANAL 3 II 500 2 2; 20

3373 DIAGNOSTIC SPECIMENS or CLINICAL SPECIMENS

6.2 0 3

3374 ACETYLENE, SOLVENT FREE 2.1 100 10 9; 10; 36 2

3375 AMMONIUM NITRATE EMULSION or SUSPEN-SION or GEL, intermediate for blasting explosives, liquid or solid

5.1 II 50 20 24 9; 14

3376 4-NITROPHENYL-HYDRAZINE, with > 30 % water, by mass

4.1 I 0 1 17

3377 SODIUM PERBORATE MONOHYDRATE 5.1 III 200 5 8 24

3378 SODIUM CARBONATE PEROXYHYDRATE 5.1 II 50 20 11 8 24

3378 SODIUM CARBONATE PEROXYHYDRATE 5.1 III 200 5 8 24



3379 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. 3 I 100 10 2; 20

3380 DESENSITIZED EXPLOSIVE, SOLID, N.O.S. 4.1 I 0 17

3381 TOXIC BY INHALATION, LIQUID, N.O.S. with an inhalation toxicity < 200 mL/m3 and saturated vapour concentration > 500 LC50

6.1 I 5 200 1; 13; 28 9; 17

3382 TOXIC BY INHALATION, LIQUID, N.O.S. with an inhalation toxicity <1 000 mL/m3 and saturated vapour concentration > 10 LC50

6.1 I 5 200 1; 13; 28 9; 17

3383 TOXIC BY INHALATION, LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity < 200 mL/m3 and saturated vapour concentration > 500 LC50

6.1 I 3 5 200 1; 13; 28 2; 9; 17

3384 TOXIC BY INHALATION, LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity < 1000 mL/m3 and saturated vapour concentration >10 LC50

6.1 I 3 5 200 1; 13; 28 2; 9; 17

3385 TOXIC BY INHALATION, LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxicity < 200 mL/m3 and saturated vapour concentration > 500 LC50

6.1 I 4.3 5 200 1; 13; 28 9; 17

3386 TOXIC BY INHALATION, LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxicity < 1 000 mL/m3 and saturated vapour concentration > 10 LC50

6.1 I 4.3 5 200 1; 13; 28 9; 17

3387 TOXIC BY INHALATION, LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity < 200 mL/m3 and saturated vapour concentration > 500 LC50

6.1 I 5.1 5 200 1; 13; 28 9; 17

3388 TOXIC BY INHALATION, LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity < 1000 mL/m3 and saturated vapour concentration > 10 LC50

6.1 I 5.1 5 200 1; 13; 28 9; 17

3389 TOXIC BY INHALATION, LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity < 200 mL/m3 and saturated vapour concentration > 500 LC50

6.1 I 8 5 200 1; 13; 28 9; 17

3390 TOXIC BY INHALATION, LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity < 1000 mL/m3 and saturated vapour concentration > 10 LC50

6.1 I 8 5 200 1; 13; 28 9; 17

3391 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC

4.2 I 0 1 20

3392 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC

4.2 I 0 1 20

3393 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATER-REACTIVE

4.2 I 4.3 0 1 20

3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE

4.2 1 4.3 0 1 20

3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE

4.3 I 0 1 23 20


4.3 II 100 10 1 23


4.3 III 500 2 1 23

3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE

4.3 I 4.1 0 1 23




4.3 II 4.1 20 50 1 23


4.3 III 4.1 100 10 1 23

3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELF-HEATING

4.3 I 4.2 0 1 23 20


4.3 II 4.2 20 50 1 23


4.3 III 4.2 100 10 1 23

3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE

4.3 I 0 1 23 20


4.3 II 100 10 1 23


4.3 III 500 2 1 23

3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

4.3 I 3 0 1 23 2; 20


4.3 II 3 20 50 1 23 2


4.3 III 3 100 10 1 23 2

3400 ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING

4.2 II 100 10 1; 12

3400 ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING

4.2 III 200 5 1

3401 ALKALI METAL AMALGAM, SOLID 4.3 I 0 1 23 20

3402 ALKALINE EARTH METAL AMALGAM, SOLID 4.3 I 0 1 23 20

3403 POTASSIUM METAL ALLOYS, SOLID 4.3 I 0 1 23 20

3404 POTASSIUM SODIUM ALLOYS, SOLID 4.3 I 0 1 23 20

3405 BARIUM CHLORATE SOLUTION 5.1 II 6.1 20 50 24; 28

3405 BARIUM CHLORATE SOLUTION 5.1 III 6.1 100 10 24;28

3406 BARIUM PERCHLORATE SOLUTION 5.1 II 6.1 20 50 24; 28

3406 BARIUM PERCHLORATE SOLUTION 5.1 III 6.1 100 10 24;28

3407 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION

5.1 II 50 20 24

3407 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION

5.1 III 200 5 24

3408 LEAD PERCHLORATE SOLUTION 5.1 II 6.1 20 50 24; 28

3408 LEAD PERCHLORATE SOLUTION 5.1 III 6.1 100 10 24;28

3409 CHLORONITRO-BENZENES, LIQUID 6.1 II 50 20 13; 28 9; 19

3410 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE SOLUTION

6.1 III 100 10 13; 28 9

3411 beta-NAPHTHYLAMINE SOLUTION 6.1 II 50 20 13; 28 9; 19



3411 beta-NAPHTHYLAMINE SOLUTION 6.1 III 100 10 13;28 9

3413 POTASSIUM CYANIDE SOLUTION 6.1 I 5 200 1; 13; 28 9; 17

3413 POTASSIUM CYANIDE SOLUTION 6.1 II 50 20 13;28 9;19

3413 POTASSIUM CYANIDE SOLUTION 6.1 III 100 10 13;28 9

3414 SODIUM CYANIDE SOLUTION 6.1 I 5 200 1; 13; 28 9; 17

3414 SODIUM CYANIDE SOLUTION 6.1 II 50 20 13;28 9;19

3414 SODIUM CYANIDE SOLUTION 6.1 III 100 10 13;28 9

3415 SODIUM FLUORIDE SOLUTION 6.1 III 100 10 13; 28 9

3416 CHLOROACETO-PHENONE, LIQUID 6.1 II 50 20 13; 28 9; 19

3417 XYLYL BROMIDE, SOLID 6.1 II 50 20 11 13; 28 9; 19

3418 2,4-TOLUYLENE-DIAMINE SOLUTION 6.1 III 100 10 13; 28 9

3419 BORON TRIFLUORIDE ACETIC ACID COMPLEX, SOLID

8 II 50 20 11

3420 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID

8 II 50 20 11

3421 POTASSIUM HYDROGEN DIFLUORIDE SOLUTION 8 II 6.1 10 100 13; 28

3421 POTASSIUM HYDROGEN DIFLUORIDE SOLUTION 8 III 6.1 50 20 13;28

3422 POTASSIUM FLUORIDE SOLUTION 6.1 III 100 10 13; 28

9

3423 TETRAMETHYL-AMMONIUM HYDROXIDE, SOLID 8 II 50 20 11

3424 AMMONIUM DINITRO-o-CRESOLATE SOLUTION 6.1 II 50 20 13; 28 9; 19

3424 AMMONIUM DINITRO-o-CRESOLATE SOLUTION 6.1 III 100 10 13;28 9

3425 BROMOACETIC ACID, SOLID 8 II 50 20 11

3426 ACRYLAMIDE SOLUTION 6.1 III 100 10 13; 28 9

3427 CHLOROBENZYL CHLORIDES, SOLID 6.1 III 100 10 9b 13; 28 9

3428 3-CHLORO-4-METHYL-PHENYL ISOCYANATE, SOLID

6.1 II 50 20 11 13; 28 9; 19

3429 CHLOROTOLUIDINES, LIQUID 6.1 III 100 10 13; 28 9

3430 XYLENOLS, LIQUID 6.1 II 50 20 13; 28 9; 19

3431 NITROBENZO-TRIFLUORIDES, SOLID 6.1 II 50 20 11 13; 28 9; 19

3432 POLYCHLORINATED BIPHENYLS, SOLID 9 II 500 2 15 1; 13; 28 19

3433 LITHIUM ALKYLS, SOLID 4.2 I 4.3 0 1 20

3434 NITROCRESOLS, LIQUID 6.1 III 100 10 13; 28 9

3435 HYDROQUINONE SOLUTION 6.1 III 100 10 13; 28 9

3436 HEXAFLUOROACETONE HYDRATE, SOLID 6.1 II 50 20 11 13; 28 9; 19

3437 CHLOROCRESOLS, SOLID 6.1 II 50 20 11 13; 28 9; 19

3438 alpha-METHYLBENZYL ALCOHOL, SOLID 6.1 III 100 10 9b 13; 28 9

3439 NITRILES, TOXIC, SOLID, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

6.1 NITRILES, TOXIC, SOLID, N.O.S. 6.1 II 50 20 11 13;28 9;19

3439 NITRILES, TOXIC, SOLID, N.O.S. 6.1 III 100 10 9b 13;28 9

3440 SELENIUM COMPOUND, LIQUID, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17



3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 6.1 II 50 20 13;28 9;19

3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 6.1 III 100 10 13;28 9

3441 CHLORODINITRO-BENZENES, SOLID 6.1 II 50 20 11 13; 28 9; 19

3442 DICHLOROANILINES, SOLID 6.1 II 50 20 11 13; 28 9; 19

3443 DINITROBENZENES, SOLID 6.1 II 50 20 11 13; 28 9; 19

3444 NICOTINE HYDRO-CHLORIDE, SOLID 6.1 II 50 20 13; 28 9; 19

3445 NICOTINE SULFATE, SOLID 6.1 II 50 20 11 13; 28 9; 19

3446 NITROTOLUENES, SOLID 6.1 II 50 20 11 13; 28 9; 19

3447 NITROXYLENES, SOLID (ortho-/ meta-/ para-) 6.1 II 50 20 11 13; 28 9; 19

3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 6.1 I 5 200 1; 13; 28 9; 17

3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 6.1 II 50 20 11 13;28 9;19

3449 BROMOBENZYL CYANIDES, SOLID 6.1 I 5 200 1; 13; 28 9; 17

3450 DIPHENYLCHLORO-ARSINE, SOLID 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3451 TOLUIDINES, SOLID 6.1 II 50 20 11 13; 28 9; 19

3452 XYLIDINES, SOLID 6.1 II 50 20 11 13; 28 9; 19

3453 PHOSPHORIC ACID, SOLID 8 III 200 5 9b

3454 DINITROTOLUENES, SOLID 6.1 II 50 20 11 13; 28 9; 19

3455 CRESOLS, SOLID 6.1 II 8 5 200 11 13; 28 9; 19

3456 NITROSYLSULFURIC ACID, SOLID 8 II 50 20 11

3457 CHLORONITRO-TOLUENES, SOLID 6.1 III 100 10 9b 13; 28 9

3458 NITROANISOLES, SOLID 6.1 III 100 10 9b 13; 28 9

3459 NITROBROMO-BENZENES, SOLID 6.1 III 100 10 9b 13; 28 9

3460 N-ETHYLBENZYL-TOLUIDINES, SOLID 6.1 III 100 10 9b 13; 28 9

3461 ALUMINIUM ALKYL HALIDES, SOLID 4.2 I 4.3 0 1 20

3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S.,

6.1 I 5 200 10; 12 1; 13; 28 9; 17


6.1 II 50 20 11 13;28 9;19


6.1 III 100 10 9b 13;28 9

3464 ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S.

6.1 I 5 200 10; 12 1; 13; 28 9; 17


6.1 II 50 20 11 13;28 9;19


6.1 III 100 10 9b 13;28 9

3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 6.1 II 50 20 11 13;28 9;19

3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 6.1 III 100 10 9b 13;28 9

3466 METAL CARBONYLS, SOLID, N.O.S. 6.1 I 5 200 10; 12 1; 13; 28 9; 17

3466 METAL CARBONYLS, SOLID, N.O.S. 6.1 II 50 20 11 13;28 9;19



3466 METAL CARBONYLS, SOLID, N.O.S. 6.1 III 100 10 9b 13;28 9

3467 ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S.

6.1 I 5 200 10; 12 1; 13; 28 9; 17


6.1 II 50 20 11 13;28 9;19


6.1 III 100 10 9b 13;28 9

3468 HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM

2.1 100 10 9; 10; 36 2; 20

3468 HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT

2.1 100 10 9; 10; 36

2; 20

3469 PAINT,FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound)

3 I 8 50 20 2; 20

3469 PAINT,FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound)

3 II 8 200 5 2; 20

3469 PAINT,FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) paint thinning or reducing compound)

3 III 8 500 2 12 2

3470 PAINT,CORROSIVE, FLAMMABLE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE (including paint thinning or reducing compound) paint thinning or reducing compound)

8 II 3 10 100 2

3471 HYDROGENDIFLUORIDES SOLUTION, N.O.S 8 II 6.1 10 100 13; 28

3471 HYDROGENDIFLUORIDES SOLUTION, N.O.S 8 III 6.1 50 20 12 13; 28

3472 CROTONIC ACID, LIQUID 8 lll 200 5 12

3473 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing flammable liquids

3 1000 1 2

3474 1-HYDROXYBENZO-TRIAZOLE, ANYDROUS, WETTED with not less than 20 % water, by mass

4.1 I 0 17

3475 ETHANOL AND GASOLINE MIXTURE or ETHANOL AND MOTOR SPIRIT MIXTURE or ETHANOL AND PETROL MIXTURE, with more than 10 % ethanol

3 II 500 2 2; 20



3476 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing water-reactive substances

4.3 1000 1 1 23

3477 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing corrosive substances

8 1000 1

3478 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing liquefied flammable gas

2.1 100 10 9; 12 2

3479 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing hydrogen in metal hydride

2.1 100 10 9; 12 2

3480 LITHIUM ION BATTERIES (including lithium ion polymer batteries

9 II 500 2

3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT or LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries)

9 II 500 2

3482 ALKALI METAL DISPENSION, FLAMMABLE or ALKALINE EARTH METAL DISPENSION, FLAMMABLE

4.3 I 3 0 1 23 2; 20

3483 MOTOR FUEL ANTIKNOCK MIXTURE, FLAMMABLE 6.1 I 3 5 200 1; 13; 28 2; 9; 14

3484 HYDRAZINE AQUEOUS SOLUTION, FLAMMABLE wit more than 37 % hydrazine, by mass

8 l 3 6.1

0 13; 28 2; 14

3485 CALCIUM HYPOCHLORITE, CORROSIVE or CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE, with more than 39 % available chlorine (8,8 % available oxygen)

5.1 II 8 20 50 11 24; 35

3486 CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 10 % but not more than 39 % available chlorine

5.1 III 8 100 10 24; 35

3487 CALCIUM HYPOCHLORITE, CORROSIVE or CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE, with not less than 5,5 % but not more than 16 % water

5.1 II 8 20 50 11 24; 35

3488 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S with an inhalation toxicity lower, than or equal to 200 mL/m3 and saturated vapour concentration > 500 LC50

6.1 I 3 8

5 200 1; 13; 28 2; 9; 14

3489 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S with an inhalation toxicity lower, than or equal to 1000 mL/m3 and saturated vapour concentration > 10 LC50

6.1 I 3 8

5 200 1; 13; 28 2; 9; 14

3490 TOXIC BY INHALATION LIQUID, WATER-REACTIVE; FLAMMABLE, N.O.S with an inhalation toxicity lower,

6.1 I 4.3 3

20 50 1; 13; 28 2; 9; 14



than or equal to 200 mL/m3 and saturated vapour concentration > 500 LC50

3491 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, CORROSIVE, N.O.S with an inhalation toxicity lower, than or equal to 200 mL/m3 and saturated vapour concentration > 500 LC50

6.1 I 4.3 3

20 50 1; 13; 28 2; 9; 14

3492 TOXIC BY INHALATION LIQUID, CORROSIVE, FLAMMABLE, N.O.S with an inhalation toxicity lower, than or equal to 200 mL/m3 and saturated vapour concentration > 500 LC50

6.1 I 3 8

5 200 1; 13; 28 2; 9; 14

3493 TOXIC BY INHALATION LIQUID, CORROSIVE, FLAMMABLE, N.O.S with an inhalation toxicity lower, than or equal to 1000 mL/m3 and saturated vapour concentration > 10 LC50

6.1 I 3 8

5 200 1; 13; 28 2; 9; 14

3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC

3 I 6.1 50 20 13; 28 2; 22


3 Il 6.1 200 5 13; 28 2; 19


3 Ill 6.1 500 2 12 13; 28 2

3495 IODINE 8 lll 6.1 50 20 9a; 9b 13; 28

3496 BATTERIES, NICKEL-METAL HYDRIDE 9 50 20 1; 13; 26; 27; 28

17

3497 KRILL MEAL 4.2 II 100 10 1

3497 KRILL MEAL 4.2 III 200 5 1 4

3498 IODINE MONOCHLORIDE, LIQUID 8 II 50 20

3499 CAPACITOR, electric double layer (with an energy storage capacity greater than 0.3 Wh)

9 50 20 1; 13; 26; 27; 28

17

3500 CHEMICAL UNDER PRESURE, N.O.S. 2.2 500 2 9; 10; 12; 36

3501 CHEMICAL UNDER PRESURE, FLAMMABLE, N.O.S. 2.1 100 10 9; 10; 12; 36

2

3502 CHEMICAL UNDER PRESURE, TOXIC, N.O.S. 2.2 6.1 20 50 9; 10; 12; 28; 36

3503 CHEMICAL UNDER PRESURE, CORROSIVE, N.O.S. 2.2 8 200 5 9; 10; 12; 36

3504 CHEMICAL UNDER PRESURE, FLAMMABLE, TOXIC, N.O.S.

2.1 6.1 20 50 9; 10; 12; 28; 36

2

3505 CHEMICAL UNDER PRESSURE, FLAMMABLE, CORROSIVE, N.O.S.

2.1 8 20 50 9; 10; 12; 36

2

3506 MERCURY CONTAINED IN MANUFACTURED ARTICLES

8 III 6.1 50 20 13; 28



Annexure A.2 Special provisions for the carriage of packaged dangerous goods These provisions are shown in column 8 under the column heading "P". Table A.2 below details the requirements associated with the provisions. Table A.2

"P" provision Requirements

P1 Packages shall be loaded onto closed or sheeted vehicles or into closed or sheeted containers.

P2 Less than full packages may only be transported in transport receptacles approved by the competent authority.

P3 May only be transported in the original manufacturer supplied packaging as authorized by the competent authority.

P4 Reserved.

P5 Packages may not be carried in small containers.

P6 Flexible IBCs shall be carried in closed vehicles or in closed containment units, in sheeted vehicles or in sheeted containment units. The sheet shall be of an impermeable and non-combustible material.

P7 Reserved

P8 The following provisions shall apply: a) Organic peroxides and self-reactive substances shall be forwarded in such a manner that control temperatures are never exceeded. b) The means of temperature control chosen for the transport operation depend on a number of factors such as 1) the control temperature(s) of the substance(s) to be carried, 2) the difference between the control temperature and the expected ambient temperature, 3) the effectiveness of the thermal insulation, 4) the duration of the transport operation, 5) the safety margin to be allowed for delays en route. c) Suitable methods to prevent the control temperature from being exceeded are listed below, in ascending order of effectiveness:

M1 Thermal insulation, provided that the initial temperature of the substance is sufficiently below the control temperature.

M2 Thermal insulation and coolant system, provided that

1) an adequate quantity of non-flammable coolant (for example liquid nitrogen or solid carbon dioxide), allowing a reasonable margin for possible delay, is carried or a means of replenishment is assured, 2) there is a uniform cooling effect even when most of the coolant has been consumed, 3) the need to ventilate the transport unit before entering is clearly indicated by a warning on the door(s).

M3 Thermal insulation and single mechanical refrigeration, provided that for substances with a flash point lower than the sum of the emergency temperature plus 5 °C, explosion-proof electrical fittings are used within the cooling compartment to prevent ignition of flammable vapours from the substances.

M4 Thermal insulation and combined mechanical refrigeration system and coolant system, provided that

1) an adequate quantity of non-flammable coolant (for example liquid nitrogen or solid carbon dioxide), allowing a reasonable margin for possible delay, is carried or a means of replenishment is assured, 2) the requirements of methods M2 and M3 are complied with.



M5 Thermal insulation and dual mechanical refrigeration system, provided that

1) apart from the integral power supply unit, the two systems are independent of each other, 2) each system alone is capable of maintaining adequate temperature control, 3) for substances with a flashpoint lower than the sum of the emergency temperature plus 5 °C, explosion-proof electrical fittings are used within the cooling compartment to prevent ignition of flammable vapours from the substances. d) Methods M4 and M5 may be used for all organic peroxides and self-reactive substances.

Method M3 may be used for organic peroxides and self-reactive substances of types C, D, E and F and, when the maximum ambient temperature to be expected during carriage does not exceed the control temperature by more than 10 °C, for organic peroxides and self-reactive substances of type B.

Method M2 may be used for organic peroxides and self-reactive substances of types C, D, E and F when the maximum ambient temperature to be expected during carriage does not exceed the control temperature by more than 30 °C.

Method M1 may be used for organic peroxides and self-reactive substances of types C, D, E, and F when the maximum ambient temperature to be expected during carriage is at least 10 °C below the control temperature. e) Where substances are required to be carried in insulated, refrigerated or mechanically refrigerated vehicles or containers, these vehicles or containers shall comply with the requirements of SANS 1518. f) If substances are contained in protective packagings filled with a coolant, they shall be loaded in closed or sheeted vehicles or closed or sheeted containment units. These closed containment units shall be adequately ventilated. The sheets of these vehicles and containment units shall be of an impermeable and non-combustible material. g) Any control and temperature sensing device in the refrigeration system shall be readily accessible and all the electrical connections shall be weatherproof. The temperature of the air inside the transport unit shall be measured by two independent sensors and the output shall be recorded so that any change in temperature is readily detectable. When substances that have a control temperature of less than 25 °C are carried, the transport unit shall be equipped with visible and audible alarms, powered independently of the refrigeration system and set to operate at or below the control temperature. h) A back-up refrigeration system shall be available

P9 Reserved

P10 IBCs shall be carried in closed or sheeted vehicles or closed or sheeted containers

P11 IBCs other than metal or rigid plastics IBCs shall be carried in closed or sheeted vehicles or closed or sheeted containers.

P12 IBCs of type 31HZ2 (see SANS 10233) shall be carried in closed vehicles or containers.

P13 When packed in 5H1, 5L1 or 5 M1 bags (see SANS 10229-1), goods shall be carried in closed vehicles or containers.



Annexure A.3 Special provisions for the carriage of dangerous goods transported in bulk These provisions are shown in column 9 under the column heading "B". Table A.3 below details the requirements associated with the provisions. Table A.3

"B" provision Requirements

BK1 Carriage in bulk in closed or sheeted vehicles, in closed containers or in large sheeted containers is permitted.

BK2 Carriage in bulk is permitted in closed vehicles with a metal body, in closed metal containers and in sheeted vehicles and sheeted large containers covered with a non-combustible sheet and having a metal body or having floor and walls protected from the load.

B3 Carriage in bulk is permitted in sheeted vehicles and sheeted large containers with adequate ventilation.

B4 Carriage in bulk is permitted in closed or sheeted vehicles with a metal body, and in closed metal containers or in sheeted large metal containers. For UN No. 2008, 2009, 2210, 2545, 2546, 2881, 3189 and 3190, only carriage in bulk of solid waste is permitted.

B5 Carriage in bulk is permitted in specially equipped vehicles and containers. The openings used for loading and unloading shall be capable of being closed hermetically.

B6 Reserved

B7 Carriage in bulk in closed or sheeted vehicles, in closed containers or in large sheeted containers is permitted only if the substance is in pieces.

B8 Carriage in bulk is permitted as a full load, in closed vehicles, in closed containers or in sheeted vehicles or in large containers covered with an impermeable, non-combustible sheet. Vehicles and containers shall be so constructed that either the substances contained cannot come into contact with wood or any combustible material, or the entire surface of floor and walls, if made of wood or other combustible material, shall be provided with an impermeable surface resistant to combustion, or coated with sodium silicate or a similar substance.

B9a Carriage in bulk is permitted, as a full load, in sheeted vehicles, in closed containers or in sheeted containers with complete walls. For substances of class 8, the body of the vehicle or container shall be equipped with a suitable and sufficiently stout inner lining.

B9b Carriage in bulk of full loads (if class 8, only for wastes) is permitted in closed containers or in sheeted large containers with complete walls. For wastes of class 8, containers shall be equipped with a suitable and sufficiently stout inner lining.

B10 Carriage in bulk is permitted as a full load in sheeted vehicles, in closed containers or in sheeted large containers with complete walls. The bodies of vehicles or containers shall be leakproof or rendered leakproof, for example by means of a suitable and sufficiently stout inner lining.

B11 Carriage in bulk is permitted in specially equipped vehicles and containers in a manner which shall avoid risks to humans, animals and the environment, for example by loading the waste into bags through airtight connections.

B12 Substances for which carriage in tank vehicles, portable tanks or in tank containers is unsuitable because of the high temperature and density of the substance may be carried in special vehicles or containers in accordance with standards specified by the competent authority of the member state of origin.

B13 Carriage in bulk is permitted in specially equipped vehicles or containers in accordance with standards specified by the competent authority of the member state of origin.



B14 The following provisions shall apply: a) Used batteries may be carried in bulk in specially equipped vehicles or containers. Large plastics containers are not permitted. Small plastics containers, when fully loaded and at −18 °C, shall be capable of withstanding a drop test from a height of 0,8 m onto a hard surface, without breakage. b) The load compartments of vehicles or containers shall be of material resistant to the corrosive substances contained in the batteries. Less resistant steels may be used when there is a sufficient wall thickness or plastics lining/layer resistant to the corrosive substances. The design of the load compartments of vehicles or containers shall take account of any residual currents and impact from the batteries. c) Constructional precaution measures shall be taken to ensure that there will be no leakage of corrosive substances from the load compartments of vehicles or containers during carriage. Open load compartments shall be covered. The cover shall be resistant to corrosive substances.d) Before loading, the compartments of vehicles or containers, including their equipment, shall be inspected for damage. Vehicles or containers with damaged load compartments shall not be loaded. The load compartments of vehicles or containers shall not be loaded above the top of their walls. e) No batteries that contain different substances and no other goods liable to react dangerously with each other shall be present in the load compartments of vehicles or containers. During carriage no dangerous residue of the corrosive substances contained in the batteries shall adhere to the outer surface of the load compartments of vehicles or containers.

B15 Carriage in bulk is permitted in closed or sheeted vehicles, closed containers or sheeted large containers with complete walls for substances or mixtures (such as preparations or wastes) containing not more than 1 000 mg/kg of substance to which this UN No. is assigned.

B16 For radio-active material-Inclusion to be verified

B17 For radio-active material-Inclusion to be verified



Annexure A.4 Special provisions for the loading operation during the carriage of dangerous goods These provisions are shown in column 10 under the column heading "L". Table A.4 below details the requirements associated with the provisions. Table A.4

"L" provision Requirements

L1 The following operations are prohibited: a) loading or unloading in a public place in a built-up area without special permission from the local competent authority; and b) loading or unloading of goods in a public place elsewhere than in a built-up area unless prior notice thereof has been given to the local competent authority, and unless these operations are urgently necessary for reasons of safety.

L2 Before loading, the loading surface of the vehicle or container shall be thoroughly cleaned.

L3 Explosives shall not be transported with other dangerous goods on the same vehicle. Explosives shall not be conveyed by public transport, except in terms of provision L7(a) and L8(a)

L4 A maximum of 25 kg black powder may be transported in the cargo containment area of a light delivery vehicle or other commercial delivery vehicle when a licensed black powder dealer obtains black powder from a supplier for resale.

L5 A maximum of 250 kg of smokeless powder may be transported by a person to whom a firearm transporter's permit has been issued in terms of the relevant national legislation (see foreword) or by a licensed smokeless powder dealer in the cargo containment area of a light delivery vehicle or other commercial delivery vehicle.

L6 a) Pyrotechnic signals such as flares and smoke devices may be transported under the following circumstances: 1) bona fide users for emergency signalling, such as boat owners, mountaineers and hikers in any motor vehicle, except public transport, in quantities not exceeding 5 kg; or 2) licensed dealers in pyrotechnics, in the cargo containment area of a light delivery vehicle or other commercial delivery vehicle in quantities not exceeding 50 kg for class 1.3G articles, and 100 kg for class 1.4G articles. b) Pyrotechnic articles for technical purposes, such as rock breaking cartridges, may be transported by or on behalf of persons or companies authorized by the competent authority, in the cargo containment area of a light delivery vehicle or other commercial delivery vehicle in quantities not exceeding 50 kg for class 1.3G articles, and 100 kg for class 1.4G articles.

L7 Fireworks may be transported under the following circumstances: a) maximum of 5 kg of class 1.4G or 1.4S consumer fireworks may be conveyed by public transport on condition that it is under the direct control of the owner; b maximum of 10 kg of class 1.4G or 1.4S consumer fireworks in any motor vehicle for personal use; c) maximum of 50 kg of class 1.3G fireworks in the cargo containment area of a light delivery vehicle or other commercial delivery vehicle, for professional use; and d) maximum of 500 kg of class 1.4G consumer fireworks in the cargo containment area of a light delivery vehicle or other commercial vehicle from a supplier to a licensed fireworks dealer

L8 Railway track signals may be transported under the following circumstances: a) maximum of 10 units in a container is received from the manufacturer by a train driver, rail track worker, or other person authorized in writing by a railway operator, in any vehicle, including



public transport, on condition that it remains under the direct control of such authorized person; and b maximum of 50 kg in the cargo containment area of a light delivery vehicle or other commercial delivery vehicle, for distribution between suppliers and distribution depots.

L9 Packages shall not be thrown or subjected to impact. Receptacles shall be so stowed in the vehicle or container that they cannot overturn or fall.

L10 Cylinders shall be laid parallel to or at right angles to the longitudinal axis of the vehicle or container; however, those situated near the forward transverse wall shall be laid at right angles to the said axis. Short cylinders of large diameter (about 30 cm and over) may be stowed longitudinally with their valve-protecting devices directed towards the middle of the vehicle or container. Cylinders which are sufficiently stable or are carried in suitable devices effectively preventing them from overturning may be placed upright. Cylinders which are laid flat shall be securely and appropriately wedged, attached or secured so that they cannot shift.

L11 Packages shall always be orientated in the manner for which they were designed and be protected against any possibility of being damaged by other packages.

L12 When pallets loaded with articles are stacked, each tier of pallets shall be evenly distributed over the lower tier, if necessary, by the interposition of a material of adequate strength.

L13 If any substance has leaked and spilt in a vehicle or container, the vehicle or container may not be re-used until after it has been thoroughly cleaned and, if necessary, disinfected or decontaminated. Any other goods and articles carried in the same vehicle or container shall be examined for possible contamination.

L14 Goods shall be shielded from direct sunlight and heat during carriage. Packages shall be stored only in cool, well-ventilated places away from heat sources.

L15 The quantity of organic peroxides and self-reactive substances that may be carried in a vehicle or combination of vehicles shall be in accordance with table C.5.

L16 Reserved

L17 Reserved

L18 Reserved

L19 Reserved

L20 Reserved

L21 The transport unit shall be thoroughly inspected before loading. Before carriage the operator shall be informed about: a) the operation of the refrigeration system, including a list of suppliers of coolant available en route, and b) procedures to be followed in the event of loss of temperature control. In the case of temperature control in accordance with methods M2 or M4 of provision P8 (see C.2), a sufficient quantity of non-flammable refrigerant (for example liquid nitrogen or dry ice), including a reasonable margin for possible delays shall be carried, unless a means of replenishment is assured. Packages shall be so stowed as to be readily accessible. The specified control temperature shall be maintained during the whole transport operation, including loading and unloading, as well as any intermediate stops.

L22 Packages shall be loaded so that a free circulation of air within the loading space provides a uniform temperature of the load. If the contents of one vehicle or large container exceed 5 000 kg of flammable solids or organic peroxides (or both), the load shall be divided into stacks of not more than 5 000 kg separated by air spaces of at least 0.05 m.



L23 When handling packages, special measures shall be taken to ensure that they do not come into contact with water.

L24 Before loading, vehicles and containers shall be thoroughly cleaned and in particular be free of any combustible debris (such as, straw, hay and paper).

L25 Packages shall be so stowed that they are readily accessible. When packages are required to be carried at an ambient temperature of not more than 15 °C or be refrigerated, the temperature shall be maintained when unloading or during storage. Packages shall be stowed only in cool places away from sources of heat.

L26 The wooden parts of a vehicle or container that have come into contact with these substances shall be removed and burnt.

L27 Packages shall be so stowed that they are readily accessible. When packages are to be carried refrigerated, the functioning of the cooling chain shall be ensured when unloading or during storage. Packages shall only be stowed in cool places away from sources of heat.

L28 Packages shall not be loaded together with packages known to contain foodstuffs, other articles of consumption or animal feeds.

L29 Reserved

L30 Reserved

L31 Reserved

L32 Reserved

L33 For radioactive materials-Inclusion to be verified

L34 Prior to carriage of pressure receptacles it shall be ensured that the pressure has not risen due to potential hydrogen generation.

L35 If bags are used as single packagings, they shall be adequately separated to allow for the dissipation of heat.

L36 Packages shall preferably be loaded in open or ventilated vehicles or open or ventilated containers. If this is not feasible and packages are carried in other closed vehicles or containers, the cargo doors of the vehicles or containers shall be marked with the following in letters not less than 25 mm high:

"WARNING NO VENTILATION

OPEN WITH CAUTION" This shall be in a language considered appropriate by the consignor.

The following load limits as indicated in Table A.4.1 below shall apply to organic peroxides or self-reactive substances Table A.4.1

Type of Organic peroxide or self-reactive substance

Type B without

temperature control

Type C without

temperature control

Type D, E or F without

temperature control

Type B with temperature

control

Type C with temperature

control

Type D, E, or F with

temperature control

Maximum quantity in kg

1 000a 10 000 20 000 1 000b 5 000c 20 000

a 5 000 kg if the loading space is ventilated at the top and if the transport unit is insulated with heat resistant material.

b 5 000 kg if the transport unit is insulated with a heat-resistant material.

c 10 000 kg if the transport unit is insulated with a heat-resistant material.



Annexure A.5 Special provisions for the transport operation These provisions are shown in column 11 under the column heading "O". Table A.5 below details the requirements associated with the provisions. Table A.5

"O" provision Requirements

O1 Explosives shall be transported with all due precautions against theft or accident.

O2 Closed vehicles that carry liquids with a flash point of not more than 60.5 °C or flammable substances or articles of class 2, shall not be entered by persons who carry lighting apparatus other than portable lamps so designed and constructed that they cannot ignite any flammable vapours or gases which may have penetrated into the interior of the vehicle. In the case of vehicles of type Fl, a good electrical connection from the vehicle chassis to earth shall be established before tanks are filled or emptied. In addition, the rate of filling shall be limited.

O3 For transport units that carry substances of class 6.2, the requirements with regard to fire extinguishers shall not apply.

O4 For the carriage of substances under controlled temperature, maintenance of the prescribed temperature is essential for safe carriage. In general, there shall be: a) a thorough inspection of the transport unit before loading, b) an instruction to the operator about the operation of the refrigeration system, including a list of suppliers of coolant available en route, c) procedures to be followed in the event of loss of control, d) regular monitoring of the operating temperature, and e) availability of a back-up refrigeration system or spare parts. The temperature of the air space within the transport unit shall be measured by two independent sensors and the output shall be so recorded that temperature changes are readily detectable. The temperature shall be logged every four to six hours. If the control temperature is exceeded during carriage, an alert procedure shall be initiated involving any necessary repairs to the refrigeration equipment or an increase in the cooling capacity (e.g. by adding liquid or solid coolant). There shall also be frequent checking of the temperature and preparations for implementation of the emergency procedures. If the emergency temperature is reached, the emergency procedures shall be set in operation.

O5 For radioactive material-Inclusion to be verified


O7 Each member of the vehicle crew shall be provided with a respiratory protective device enabling the crew member to escape when carrying gases or articles classified as toxic, or with a toxic subsidiary risk.

O8 When a transport unit is loaded with more than 2 000 kg of these substances, stops for service requirements shall be as far as possible from inhabited or frequented places. A longer stop near such places is permissible only with the consent of the local emergency services.

O9 During the carriage of these substances, stops for service requirements shall be as far as possible from inhabited or frequented places. A longer stop near such places is permissible only with the consent of the local emergency services

O10 When the vehicle is stationary, the packages shall be effectively protected against the action of the sun, for example by means of sheets placed not less than 20 cm above the load.





O13 When a consignment cannot be delivered, it shall be placed in a safe place. The emergency services shall be informed as soon as possible and requested for instructions on how to proceed.

O14 The provisions in 5.3.4 concerning the supervision of vehicles shall apply when the total mass of these substances in the vehicle exceeds 100 kg.

O15 The provisions in 5.3.4 concerning the supervision of vehicles shall apply to class 4 whatever the mass and to substances of class 3 when the total mass of these substances in the vehicle exceeds 100 kg.

O16 The provisions in 5.3.4 concerning the supervision of vehicles shall apply when the total mass of these substances in the vehicle exceeds 500 kg. In addition, vehicles carrying more than 500 kg of these substances shall be subject at all times to supervision for the prevention of any malicious act and to alert the driver and the emergency services in the event of loss or fire.

O17 The provisions in 5.3.4 concerning the supervision of vehicles shall apply when the total mass of these substances in the vehicle exceeds 1 000 kg

O18 The provisions in 5.3.4 concerning the supervision of vehicles shall apply when the total mass of these substances in the vehicle exceeds 2 000 kg.






Annexure B – (Normative)

Maintenance, inspection and test schedules

his annex contains the inspection schedules to be applied to vehicles and all types of tanks and applicable product containment structures carried by vehicles subsequent to the initial inspections and tests which are done as part of the construction. These inspections and tests are contained in Section 10 of this standard

B.1 General

B.1.1 The various inspection types are categorized as in table B.1.1

Table B.1.1

Category Description

Operational inspections Normal inspections that would be done as part of the in-operation and maintenance inspections and apply to the vehicle and tank/product containment structure.

Intermediate periodic inspection This term is in keeping with the term used in the European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR) and is a subsequent inspection related to the initial inspection and applies to the tank/product containment structure only. It occurs every 2,5 years to 3 years, depending on the tank type.

Major periodic inspection This term is in keeping with the ADR and is a subsequent inspection related to the initial inspection and applies to the tank/product containment structure only. It occurs every 5 years to 6 years.

Exceptional inspections Additional inspections required during major structural repair work that would involve all of the elements of an intermediate or periodic inspection or when a previously owned vehicle is procured and deployed in an operation.

B.1.2 Cognisance needs to be taken of the relevant requirements of other applicable statutory requirements that could influence the required inspection schedule.

B.1.3 The schedules and requirements state the minimum requirements.

B.1.4 Intermediate periodic and major periodic inspections may be performed within a period of three months before or after the due date. However, should the inspection take place more than three months before the due date, the next due periodic inspections will be performed at the required intervals after the date of the actual periodic inspection being carried out.

B.1.5 If an exceptional inspection, covering structural repair or modification of tanks and cargo containment areas that will require verification of adherence to design, construction and material requirements as stated in the applicable standard of construction is carried out, and it includes all the elements of an intermediate periodic inspection or a major periodic inspection, the next periodic inspections will be performed at the required intervals after the date of the actual exceptional inspection being carried out.

B.1.6 The intermediate periodic inspection is applicable to all tanks. Specific requirements of national legislation in participant member states could require that pressure vessels undergo inspections and tests at shorter



intervals than those required by this standard. In such cases, the requirements of such legislation will take precedence over the requirements of this standard in the member state of operation.10

B.1.7 Inspection categories, intervals and applicability of such inspections are given in Table B.1.2

Table B.1.2

1 2 3 4 5

Inspection type Interval Clause Vehicle/tank type Performed by

Operational Daily B.2.1 All Vehicle driver

Monthly1 B.2.2 All Competent person

12-monthly B.2.3 All Competent person

Intermediate periodic 30-monthly B.3.1 Tank containers, swap bodies, Portable tanks and Multi-element Gas Containers (MEGCs)

Competent person

36-monthly B.3.2 Fixed tanks, demountable tanks and battery vehicles

Competent person

Major periodic 60-monthly B.4.1 Tank containers, swap bodies, Portable tanks and Multi-element Gas Containers (MEGCs)

Competent authority

72-monthly B.4.2 Fixed tanks, demountable tanks and battery vehicles

Competent authority

Exceptional As required B.5 All tanks and product containment structures

Competent authority

1. The term "monthly" means a maximum interval of 6 weeks.

B.2 Daily inspection requirements

B.2.1 This section contains the requirements that shall be included in a typical daily or pre-shift inspection done by the vehicle driver.

B.2.2 The inspection covering the listed items shall be performed, at a 4 to 6 week interval.

B.2.3 Table B.2.1 gives the applicable focus area as well as specific items that shall be. Any defects found shall be reported and attended to as required before proceeding on the journey. The items requiring inspection will depend on the vehicle type, application and the equipment fitted. It is thus obvious that not all items listed will be found on every vehicle and tank.

B.2.4 The inspection requirements given in table B.2 are not intended to explain how to do the inspection, but to detail the items and areas that need to be inspected. The manner of inspection shall be addressed by means of the appropriate training.

10 Consideration must be given to specifying a consistent interval of inspection of pressure vessels on a regional basis. For example, in South Africa all pressure vessels have to undergo a major periodic inspection at 36-month intervals.



Table B.2

1 2

Focus area Inspection item

General roadworthiness All headlights, tail lights, brake lights, indicators, side marker lamps and number plate lamp Windscreen, and wipers Rear-view mirrors Number plates Front white and rear red retro-reflectors, reflective marking tape and chevron Coolant, oil, fuel and other leaks Coolant, oil and fuel levels and security of all caps and closures Driver's seat Starting of vehicle and condition Operation of gauges, in-cab warning devices, clutch and brake pedals, horn and steering play Body damage and loose equipment and fittings that would render the vehicle unsafe Mudguards, spray suppression and side under-run protection Vehicle suspension and axles Tyres, wheel nuts and tyre pressure Service and park brake operation trailer brake and electrical connections Trailer hitches and couplers such as 5th wheels, A-frames, automatic trailer couplers ball-type hitches, A-frames and tow eyes and drawbar turntables Electrical wiring and junctions Truck battery and enclosure

Documentation and legal License and operator discs Dangerous goods designated space and correct documentation Dangerous goods transportation permit Dangerous goods placards correct Prohibition signs in place as required Specific local requirements met (for example, 80 km/h sign for Botswana, yellow triangle for Mozambique)

Product and cargo containment

Product tank and pipelines for leaks Packaged goods cargo area for signs of leakage Tank and cargo containment structure supports and frames Valve positions and condition Hose stowage and condition Manhole covers Access ladders Tank top spill containment area and drains Loading and discharge adaptors and dustcaps Security of metering and pumping equipment and leaks Control enclosures closed and control valves and mechanisms in the correct position Electrical bonding systems Emergency release systems Load body sides Compressed gas stowage Container locks Cargo doors and locks

Loose equipment Fire extinguishers and stowage (pressure, seals, expiry) Wheel chocks and stowage Warning triangles Spill and first aid kits Personal protection equipment



B.3 Monthly inspection requirements

B.3.1 This section contains the requirements that shall be included in a typical monthly time-driven inspection done during the operational preventive maintenance schedule applied to the vehicle or equipment.

B.3.2 The inspection covering the listed items shall be performed, at a maximum interval of 6 weeks.

B.3.3 Table B.3. provides the applicable focus area as well as specific items that shall be checked during the monthly inspection, for presence or availability, operability, condition, security and validity, as applicable. Any defects or issues of non-compliance found shall be reported and attended to as required before the vehicle or equipment is made available for operation.

B.3.4 The inspection requirements given in table B.3.1 are not intended to explain how to do the inspection, but to detail the items and areas that need to be inspected. The manner of inspection shall be addressed by means of the appropriate training.

Table B.3

1 2


General roadworthiness All headlights, tail lights, brake lights, indicators, side marker lamps and number plate lamp Windscreen, and wipers Rear-view mirrors Number plates Front white and rear red retro-reflectors, reflective marking tape and chevron Coolant, oil, fuel and other leaks Coolant, oil and fuel levels and security of all caps and closures Driver's seat Starting of vehicle and condition Operation of gauges, in-cab warning devices, clutch and brake pedals, horn and steering play Body damage and loose equipment and fittings that would render the vehicle unsafe Mudguards, spray suppression and side under-run protection Vehicle suspension and axles Tyres, wheel nuts and tyre pressure Service and park brake operation trailer brake and electrical connections Trailer hitches and couplers such as 5th wheels, A-frames, automatic trailer couplers ball-type hitches, A-frames and tow eyes and drawbar turntables Electrical wiring and junctions Truck battery and enclosure

Documentation and legal License and operator discs Dangerous goods designated space and correct documentation Dangerous goods transportation permit Dangerous goods placards correct Prohibition signs in place as required Specific local requirements met (for example, 80 km/h sign for Botswana, yellow triangle for Mozambique)


Product tank and pipelines for leaks Packaged goods cargo area for signs of leakage Tank and cargo containment structure supports and frames Valve positions and condition Hose stowage and condition Manhole covers



Access ladders Tank top spill containment area and drains Loading and discharge adaptors and dustcaps Security of metering and pumping equipment and leaks Control enclosures closed and control valves and mechanisms in the correct position Electrical bonding systems Emergency release systems Load body sides Compressed gas stowage Container locks Cargo doors and locks

Loose equipment Fire extinguishers and stowage (pressure, seals, expiry) Wheel chocks and stowage Warning triangles Spill and first aid kits Personal protection equipment

Tests Overfill prevention systems Hose continuity Electrical bonding system continuity Measurement of wear tolerances on trailer coupling systems including 5th wheels, kingpins, automatic trailer couplers, ball type couplers, A-frames and tow eyes and drawbar trailer turntables Road test of vehicle and brake system Tests and inspections required by vehicle applicable manufacturer Tests and inspections required by applicable equipment manufacturers

B.4 Annual inspection requirements

B.4.1 This section contains the requirements that shall be included in an annual, time-driven inspection done during the operational preventive maintenance schedule applied to the vehicle or equipment. In addition it includes the annual statutory roadworthiness inspection and certification and inspections applicable, in specific, to tanks carrying corrosive products.

B.4.2 The inspection is could be done one month prior to the due date or one month after the due date, but the following inspection due date remains at a 12-month interval relevant to the current inspection.

B.4.3 Table B.4.1 provides the annual inspection requirements. The list of requirements is not intended to explain how to do the inspection, but to detail the items and areas that need to be inspected. The manner of inspection shall be addressed by means of the appropriate training.

B.4.4 Table B.4 provides the applicable focus area as well as specific items that shall be checked during daily inspection, for presence or availability, operability, condition, security and validity, as applicable. Any defects found shall be reported and attended to as appropriate before making the vehicle or equipment available for operation.

Table B.4

1 2


General roadworthiness As in Table B.3

Documentation and legal As in Table B.3




As in Table B.3

Loose equipment As in Table B.3

Tests As in Table B.3

Statutory roadworthiness test

In accordance with the relevant national legislation of the member state where the vehicle is registered.

Material thickness inspection on corrosive products tanks (Class 8 or class 8 subsidiary risk)

Perform internal inspection. Perform random material thickness tests on tank shell and ends. Perform pressure test on tank to maximum operating pressure. Certify for continued use in accordance with applicable design and construction standards.

B.5 Intermediate periodic inspection and test requirements

B.5.1 This section contains the requirements for the inspections and tests applicable to the tank and associated equipment conducted on a periodic basis after the initial inspection and test.

B.5.2 The inspection shall be performed in accordance with the intervals specified in B.1

B.5.3 Actual tests conducted shall take cognisance of the actual original construction date and relevant standard of construction at the time of construction. Tests shall be carried out in accordance with the requirements stated in the construction standard applicable to the specific tank or cargo containment area, or equipment being inspected and tested, in accordance with the intervals as stated in this standard

B.5.4 The inspection and test requirements are contained in table B.5

Table B.5

1 2

Tank type Inspection item

Fixed tanks, demountable tanks and battery vehicles tank containers, swap bodies, portable tanks and multiple-element gas containers (MEGCs)

Perform an external visual inspection Perform a leakproof test at an internal pressure at least equal to the maximum working pressure. For tanks intended for the carriage of liquids or solids in a granular or powdery state, and when a gas is used to perform the leakproof test, it shall be carried out at a pressure at least equal to 25 % of the maximum working pressure. In all cases, the test pressure shall not be less than 20 kPa. For tanks equipped with venting systems and a safety device to prevent product spilling out if the tank overturns, the test pressure shall be equal to the static pressure of the product carried at the maximum fill level. The leakproof test shall be carried out separately on each compartment of a compartmented shell. The pressure tests on the tank shall be performed with all equipment in place. Only vents and pressure relief systems may be blocked off to ensure that the appropriate test pressures are attained. Visually inspect all tank related equipment and ensure correct operation thereof.

FRP fixed tanks, demountable tanks and battery vehicles tank containers, swap bodies and portable tanks vacuum operated waste tanks

Perform and external and internal visual inspection. Perform a leakproof test at an internal pressure at least equal to the maximum working pressure. For tanks intended for the carriage of liquids or solids in a granular or powdery state, and when a gas is used to perform the leakproof test, it shall be carried out at a pressure at least equal to 25 % of the maximum working pressure. In all cases, the test pressure shall not be less than 20 kPa.



For tanks equipped with venting systems and a safety device to prevent product spilling out if the tank overturns, the test pressure shall be equal to the static pressure of the product carried at the maximum fill level. The leakproof test shall be carried out separately on each compartment of a compartmented shell. The pressure tests on the tank shall be performed with all equipment in place. Only vents and pressure relief systems may be blocked off to ensure that the appropriate test pressures are attained. Visually inspect all tank related equipment and ensure correct operation thereof.

Bulk containers Testing and maintenance performed in accordance with the International Convention for Safe Containers (CSC).

B.6 Major periodic inspection and test requirements

B.6.1 This section contains the requirements for the inspections and tests applicable to the tank and associated equipment conducted on a periodic basis after the initial inspection and test.

B.6.2 The inspection is performed in accordance with the intervals specified in B.1

B.6.3 Actual tests conducted need to take cognisance of the actual original construction date and relevant standard of construction at the time of construction. Therefore tests shall be carried out in accordance with the requirements stated in the construction standard applicable to the specific tank or cargo containment area, or equipment being inspected and tested, in accordance with the intervals as stated in this standard.

Table B.6

1 2

Tank type Inspection item

Fixed tanks, demountable tanks and battery vehicles tank containers, swap bodies, portable tanks and multiple-element gas containers (MEGCs)

Perform an external and internal visual inspection. Sheathing for thermal or other insulation shall be removed only to the extent required for reliable appraisal of the characteristics of the shell. Perform a hydraulic pressure test at the test pressure indicated on the tank. The hydraulic pressure test shall be carried out separately on each compartment of a compartmented shell. The pressure tests on the tank shall be performed with all equipment in place. Only vents and pressure relief systems may be blocked off to ensure that the appropriate test pressures are attained. Visually inspect all tank related equipment and ensure correct operation thereof.

FRP fixed tanks, demountable tanks and battery vehicles tank containers, swap bodies and portable tanks vacuum operated waste tanks

Perform an external and internal visual inspection. Sheathing for thermal or other insulation shall be removed only to the extent required for reliable appraisal of the characteristics of the shell. Perform a hydraulic pressure test at the test pressure indicated on the tank. The hydraulic pressure test shall be carried out separately on each compartment of a compartmented shell. The pressure tests on the tank shall be performed with all equipment in place. Only vents and pressure relief systems may be blocked off to ensure that the appropriate test pressures are attained. Visually inspect all tank related equipment and ensure correct operation thereof.

Bulk containers Testing and maintenance performed in accordance with the International Convention for Safe Containers (CSC)



B.7 Exceptional inspection and test requirements

B.7.1 The requirements for additional inspections and tests are as follows: a) During major structural repair or modification work that would involve all of the elements of an intermediate or periodic inspection, or when a previously owned vehicle is procured and deployed in an operation. b) Actual tests conducted need to take cognisance of the actual original construction date and relevant standard of construction at the time of construction (Tests shall be carried out in accordance with the requirements stated in the construction standard applicable to the specific tank or cargo containment area, or equipment being inspected and tested.

Table B.7

1 2 3

Activity Inspection and test requirements Responsibility

Structural repair or modification of tanks and cargo containment areas that will require verification of adherence to design, construction and material requirements as stated in the applicable standard of construction.

Perform an external and internal visual inspection in the affected areas. Sheathing for thermal or other insulation shall be removed only to the extent required for reliable appraisal of the characteristics of the shell. Perform a hydraulic pressure test for the affected areas at the test pressure indicated on the tank. The hydraulic pressure test shall be carried out separately on each compartment of a compartmented shell. The pressure tests on the tank shall be performed with all equipment in place. Only vents and pressure relief systems may be blocked off to ensure that the appropriate test pressures are attained. Inspect the quality management system documentation of the organization responsible for the work to ensure compliance with material, design and construction requirements. This will include areas such as: - Material certification - Non-destructive testing - Welding qualification - Design approval Inspect service equipment repaired, replaced or added during the work done for compliance with the requirements of the applicable standard of construction and compliance with the individual equipment standards. This will include: - Inspection of manhole covers, vapour vents, bottom outlet valves, loading adaptors, hoses, emergency pressure vents, pressure relief equipment and pressure and vacuum vents. - Ensuring correct installation and operation of such equipment. - Ensuring that all necessary equipment compliance documentation such as test certificates are available

Competent authority



Inspect general vehicle constructional compliance in relation to the areas repaired or modified in terms of the applicable standard of construction. This will include items such as: Electrical installations Mudguards Spray suppression Under-run protection devices Drive away interlocks Ladders and steps Pipelines Vapour recovery systems Overfill prevention systems Fire extinguishers Spill containment areas Electrical bonding Tank plating

Placing of a previously owned fixed tank vehicles, demountable tanks and battery vehicles tank containers, swap bodies, portable tanks, multiple-element gas containers (MEGCs) and vacuum operated tanks in operation

Inspect service equipment fitted for compliance with the requirements of the applicable standard of construction and compliance with the individual equipment standards. This will include: - Inspection of manhole covers, vapour vents, bottom outlet valves, loading adaptors, hoses, emergency pressure vents, pressure relief equipment and pressure and vacuum vents. - Inspection of such service equipment for correct installation and operation of such equipment. Inspect for general vehicle constructional compliance in terms of the applicable standard of construction. This will include items such as: Electrical installations Mudguards Spray suppression Under-run protection devices Drive away interlocks Ladders and steps Pipelines Vapour recovery systems Overfill prevention systems Fire extinguishers Spill containment areas Electrical bonding Tank plating Inspection of documentation to ensure that the following documentation is in place: Initial construction manufacturer's certificate and third party approvals. Intermediate periodic inspection, major periodic inspection and exceptional inspection documentation.

Competent authority



Annexure C Transport emergency card - issued in the format as indicated below

TRANSPORT EMERGENCY CARD

In accordance with SADCSTAN [insert number]

PROPER SHIPPING NAME UN number

Insert proper shipping name

Class

Subsidiary risk

APPEARANCE Packing group

Insert appearance

ERG number

DANGER

Insert the appropriate danger phrase

PERSONAL PROTECTIVE EQUIPMENT

Insert the appropriate protective equipment phrase

EMERGENCY RESPONSE EQUIPMENT

Insert the appropriate emergency response phrase

DRIVER FIRST ACTIONS – Only if it can be carried out without personal risks

Insert driver first action phrase

DRIVER SPECIAL/ADDITIONAL ACTIONS – Only if it can be carried out without personal risks

Insert driver special/additional actions phrase

DRIVER FIRST ACTIONS – Only if it can be carried out without personal risks

Insert driver first action phrase

DRIVER ACTION IN CASE OF FIRE – Only if it can be carried out without personal risks

Insert driver action in case of fire phrase

FIRST AID

Insert first aid phrase

SPECIAL INFORMATION FOR EMERGENCY SERVICES

Insert first aid phrase

ADDITIONAL INFORMATION

EMERGENCY TELEPHONE NUMBERS

PREPARED BY:

Preparation date: MM/YY Reference/Serial no If any

Expiry date MM/YY



Annexure D.1 (Normative in terms of the required contents as relevant – The format is not Normative) Refer Section 8 of this standard

Example of Dangerous Goods Declaration (DGD) Note: The example provides a hypothetical situation with packaged goods and bulk product on one vehicle purely for

illustrative purposes)

Dangerous goods declaration

Consignment note: XYZ2314 Company logo (Optional) Consignor: Anfos Warehousing 3 Straight street Uptown Tel. no: +245312451234

Operator: ABC Carriers 12 Factory bend Downtown Tel no: +245411234567 Vehicle: Truck tractor: ABC0102 Trailer: ABC0345

Product manufacturer: C-Chemicals Unit 5 Uptown Tel no: +245319876542

Consignee: Chemical Distributors Shop 26 Nextown Tel no: +245611357890

Product owner: (If required) Additional information on handling/transport/ storage

1 Product UN XXXX to be kept out of direct sunlight 2 Product not be be transported in same cargo space as flammable products

Product Custodian: (If required)

Party contracting the operator: Anfos Warehousing 3 Straight street Uptown Tel. no: +245312451234

Shipping name UN no Class PG Quantity and type of packaging Volume (l) Gross mass

(kg)

Net mass (kg)

Sodium hydroxide solution 1824 8 II 2 x 10l plastic containers 50 kg 40 kg

Cresylic acid 2022 6.1 (8) II Bulk 20 000 n/a

Declarations

Consignor I hereby declare that the content of this consignment is fully and accurately described above by the proper shipping name, and is classified, packaged, marked and labelled/placarded, and is in all respects in proper condition for transport in accordance with SADCSTAN XXX Section 8 Where the consignor is not the manufacturer, the declaration is based on information received.

The consignor is (Tick as relevant Product

manufacturer

Product custodian

Product owner Part that contracts

the operator

Signed: AN Other Date: 20/01/2018

Driver The consignment described above has been received into my vehicle. My vehicle is correctly placarded and I am in possession of all necessary transport documentation pertaining to the transport of dangerous goods, including information to be followed in case of an emergency.

Signed: John Johnson Date: 20/01/2018



Annexure D.2 (Normative in terms of the required contents as relevant – The format is not Normative) Refer Section 8 of this standard

Example of Waste Dangerous Goods Declaration (WDGD)

Waste dangerous goods declaration

Consignment note: XYZ2314 Company logo (Optional) Consignor/Waste generator

Consignor: Anfos Warehousing Physical address: 3 Straight Street Uptown Tel. no: +245312451234 Postal address PO Box 222 Uptown Emergency tel no +245312451234 e-mail [email protected] WIS number WM1234-X

Origin/Source of waste Product spilt during road accident Classification of waste Oxidize solid, Carcinogen 1A, Mutagen 1B Reprod tox 2, Acute tox 2 (inhalation) Acute tox 3 (dermal), Acute tox 3 (oral) Skin corr 1A

Site where waste was generated Anfos Warehousing 3 Straight Street Uptown Date of collection: 20/01/2018

Quantity of waste 20000 kg

Declaration by consignor/waste generator

I hereby declare that the contents of this consignment is fully and accurately described, classified, marked and labelled/placarded and in all respects in proper condition for transport in accordance with the applicable laws and regulations.

Signed: AN Other Date: 20/01/2018

Operator/Waste transporter

ABC Carriers 12 Factory Bend Downtown Tel no: +245411234567 Vehicle: Truck tractor: ABC0102 Trailer: ABC0345

Declaration by operator/waste transporter

The consignment described above has been received into my vehicle. My vehicle is correctly placarded and I am in possession of all necessary transport documentation pertaining to the transport of dangerous goods, including information to be followed in case of an emergency.

Signed: John Johnson Date: 20/01/2018



Annexure D.2 Waste Dangerous Gods Declaration – Concluded

Consignee/Waste Manager

Consignee/waste manager P Person Waste Incorporated Dumpsite City Receiving address 24 Dump Street Dumpsite City Postal address PO Box 300 Dumpsite City Waste management facility license number WP-3334-P Telephone number +245711234567

Details of waste received by consignee/waste manager Type of waste management applied Re-use/ recycling/ recovery/ treatment/disposal Reporting description and code in terms of national waste information regulations Inorganic waste – solid. HW05 – 02 Details of waste diverted No waste diverted Details of diverting facility (where applicable) Nil Discrepancies in information: No discrepancies Quantity 20000kg

Declaration by consignee/waste manager

I hereby confirm that the hazardous waste described above has been received at the waste site and the waste has been treated and disposed of as indicated.

Signed: P Person Date: 20/01/2018

Shipping name UN no Class PG Quantity and type of packaging

Volume (L) Gross mass (kg)

Net mass (kg)

Chromium (VI) oxide 1463 5.1 II Bulk n/a 20 000 kg

Additional information on the handling/transport/storage – applicable P, B, L, O provisions: The transportation of UN 1463 is subject to special provision L24 of annexure A



Annexure E Reserved for future use



Annexure F (Normative) Incident report An incident involving the transport of dangerous goods by road shall be reported in the following format (see 7.1.2.6).



Annexure G (Normative)

Gasses and gas mixtures




Annexure H (Normative)

Equipment standards

Unless specific requirements are contained in section 10 of this standard, the following equipment standards apply to vehicles designed and constructed in accordance with Section 10 of this standard, as relevant:

For all tanks

EN 14025-2013 Tanks for the transport of dangerous goods – Metallic pressure tanks – Design and construction

EN 14432-2006 Tanks for the transport of dangerous goods – Tank equipment for the transport of liquid chemicals – Product discharge and air inlet valves

EN 14433-2006 Tanks for the transport of dangerous goods - Tank equipment for the transport of liquid chemicals – Foot valves

For testing and inspection

EN 12972-2007 Tanks for the transport of dangerous goods – Testing, inspection and marking of metallic tanks

For tanks with a maximum working pressure not exceeding 50 kPa and intended for the carriage of substances for which a letter "G" is given as the second character of the 4-character tank code (annexure A)

EN 13094-2008

Tanks for the transport of dangerous goods - Metallic tanks with a working pressure not exceeding 0.5 bar – Design and construction

For tanks for gases of Class 2

EN 12493-2013 LPG equipment and accessories – Welded steel tanks for Liquefied Petroleum Gas (LPG) – Road tankers – Design and manufacture. Note: Road tankers to be understood in the meaning of "fixed tanks" and "demountable tanks".

EN 12252: 2014 LPG equipment and accessories – Equipping of LPG road tankers. Note: Road tankers to be understood in the meaning of "fixed tanks" and "demountable tanks".

EN 13175:2014

LPG equipment and accessories-Specification and testing for Liquefied Petroleum Gas (LPG) – pressure vessel valves and fittings

EN13530-2-2002 -A1-2004

Cryogenic vessels – Large transportable vacuum insulated vessels – Part 2: Design, fabrication, inspection and testing

EN 14398-2-2003 +A2:2008

Cryogenic vessels – Large transportable non-vacuum insulated vessels – Part 2: Design, fabrication, inspection and testing

EN 14129:2014 LPG equipment and accessories – Pressure relief valves for LPG pressure vessels

EN 1626:2008 (except valve category B)

Cryogenic vessels – Valves for cryogenic service

EN 13807-2003 Transportable gas cylinders − Battery vehicles − Design, manufacture, identification and testing

For tanks intended for the carriage of liquid petroleum products and other dangerous substances ofClass 3 which have a vapour pressure not exceeding 110 kPa at 50 °C and petrol and which have no toxic or corrosive subsidiary hazard

EN 13094- 2008+AC:2008

Tanks for the transport of dangerous goods – Metallic tanks with a working pressure not exceeding 0.5 bar – Design and construction



EN 13082- 2008+A1:2012

Tanks for the transport of dangerous goods – Service equipment for tanks – Vapour transfer valve

EN 13083-2008+A1:2013 Tanks for transport of dangerous goods. Service equipment for tanks. Adaptor for bottom loading and unloading

EN 13308-2002 Tanks for the transport of dangerous goods – Service equipment for tanks – Non-pressure balanced foot valve

EN 13314-2002 Tanks for the transport of dangerous goods – Service equipment for tanks – Fill hole cover

EN 13315-2002 Tanks for transport of dangerous goods. Service equipment for tanks. Gravity discharge coupler

EN 13316-2002 Tanks for the transport of dangerous goods – Service equipment for tanks – Pressure balanced foot valve

EN 13317-2002 -A1-2006

Tanks for the transport of dangerous goods – Service equipment for tanks – Manhole cover assembly

EN14595-2005 Tanks for the transport of dangerous goods – Service equipment for tanks – Pressure and vacuum breathing vent

EN14956:2005 Tanks for the transport of dangerous goods – Service equipment for tanks – Emergency pressure relief valve

EN16257-2012 Tanks for the transport of dangerous goods – Service equipment for tanks – Footvalve-Sizes other than 100 mm (nom)



Annexure I (Normative)

Minimum requirements for continued use of non-compliant tanks and vehicles

With reference to section 7.3.1.8 of this standard Note: The items will be applied as relevant to the type of tank, product being carried, the type of loading operation and the type of vehicle. The term "All tanks" and "All vehicles" must thus be viewed in relation to this.

I.1 Tanks in operation will comply with the following minimum standards

Item Requirement References Tank type

Tank standard Minimum standard of compliance: ADR 2005 or later, or US DOT 2005 or later, or SABS1398, or SABS1518, or SANS1518:2004 or later or Relevant to pressure vessels only if not compliant with the above: ASME VIII BS5500 AD Merkblatter

10.4 All tanks

Tank code 4-character tank code in accordance with this standard

7.3.2 7.3.3

All tanks

Tank marking Tank to be fitted with a durable plate in accordance with the applicable tank standard indicating at least: The tank standard The tank code The name of the manufacturer The date of manufacture The test pressure The gross capacity of each compartment

All tanks

Tank load plates Compliance with the requirements of this standard. 10.3.16 All tanks

Manhole covers Manhole covers will be a minimum of 400mm in diameter to allow entry into the tank. Manhole covers will provide a liquid-tight seal when closed. Latches for openable covers will preferably be of a self-latching type Compliance with: EN13317 EN13314 or US DOT 178.345

10.4.7.5 All tanks

Bottom loading/outlet closures

Number of closures in accordance with the tank code allocated to the tank

10.3.3 10.4.7.3

All tanks

Bottom loading adaptors-API

EN13083 All tanks

Bottom valves Compliance with the requirements of this standard. Bottom valves will comply with (as relevant) EN13308 (pressure balanced) or En13316 (Non-pressure balanced) or

10.3.8 All tanks



US DOT 178.345

Bottom valve operators Compliance with the requirements of this standard 10.3.13 All tanks

Pressure relief Compliance with the requirements of this standard Pressure and vacuum vents will comply with EN14595

10.4.7.6 10.4.7.7

All tanks

Vapour venting Compliance with the requirements of this standard 10.3.7 All tanks

Emergency pressure relief Compliance with the requirements of this standard Emergency pressure relief will comply with: EN14596

10.3.2 All tanks

Pneumatic overfill systems Compliance with the requirements of this standard 10.3.1 All tanks

Electronic overfill systems Compliance with EN13922 10.3.1 All tanks

Vapour recovery system Compliance with the requirements of this standard 10.3.6 All tanks

Tank overturn protection Effective overturn protection Top of overturn protection to be at least 25mm above tank top equipment If no overturn protection is fitted, the tank top fittings will be of adequate strength or protected in such a manner that it loss of product will not occur during a roll-over

10.4.7.2.2 All tanks

Tank top spill containment area

Compliance with the requirements of this standard 10.3.4 All tanks

Permanently enclosed areas of entrapment

Compliance with the requirements of this standard 10.3.5 All tanks

Internal bonding Compliance with the requirements of this standard 10.3.9 FL and EX

Electrical continuity Compliance with the requirements of this standard 10.2.10 10.3.26.5

FL and EX

Product hoses Compliance with the requirements of this standard 10.3.20 All tanks

Gravity discharge couplers (API)

EN13315 All tanks

Pumps Compliance with the requirements of this standard 10.3.15 FL and EX

Drive-away prevention Not applicable 10.2.14 n/a

Labelling Compliance with the requirements of this standard 10.3.16 All tanks

Tank condition Tank to be in generally acceptable condition with no leaks evident and no deformation of tank shell material that could result in thinning of the material or reduced reliability.

All tanks

Tank mountings Attachment of the tank to the vehicle must be sound and without defects

All tanks

I.2 Vehicles in operation will comply with the following minimum standards:

Item Requirement References Vehicle type

Battery isolator switch Compliance with the requirements of this standard 10.2.2.5 FL and EX

Electrical wiring Compliance with the requirements of this standard 10.2.2.1 10.2.2.2

All vehicles

Location of electrical equipment

Compliance with the requirements of this standard 10.2.2.8 FL and EX

Electrical continuity Compliance with the requirements of this standard 10.2.2.7

Trailer electrical sockets Compliance with the requirements of this standard 10.2.10 All vehicles

Permanent electrical supplies

Compliance with the requirements of this standard 10.2.2.5 FL and EX



Brake systems Compliance with the requirements of this standard 10.2.8 All vehicles

Endurance brake system Compliance with the requirements of this standard 10.2.9 All vehicles

Front air charge line Compliance with the requirements of this standard 10.2.5 All vehicles

Rear under-run device Compliance with the requirements of this standard 10.3.26.3 All vehicles

Wheel chocks Compliance with the requirements of this standard 10.2.11 All vehicles

Cab Compliance with the requirements of this standard 10.2.4.1 FL and EX

Cab roof Compliance with the requirements of this standard 10.2.4.2 All vehicles

Mudguards Not applicable 10.2.12 n/a

Side under-run protection Not applicable 10.2.13 n/a

Ground clearance Compliance with the requirements of this standard 10.2.14 All vehicles

Cab rear wall Compliance with the requirements of this standard 10.2.4.3 All vehicles

Engine compartment splash guard

Compliance with the requirements of this standard 10.2.4.4 All vehicles

Vehicle Engine Compliance with the requirements of this standard 10.2.7 All vehicles

Exhaust system Compliance with the requirements of this standard 10.2.3 FL and EX

Battery enclosure Compliance with the requirements of this standard 10.2.2.4 All vehicles

Fuel tank Compliance with the requirements of this standard 10.2.6 All vehicles

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