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Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology
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Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Dec 23, 2015

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Page 1: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Dr. Kamal K. TahaAssociate Professor of Physical

ChemistryDean CAIS

U of B

Introduction to Nanotechnology

Page 2: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

DefinitionNanotechnology, shortened to “nanotech”, is the study of the controlling of matter on an atomic and molecular scale. Generally nanotechnology deals with structures sized between 1 to 100 nanometer in at least one dimension and involve developing materials or devices within that size.

Page 3: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

How small is Nano - small?

Units in nanometers (µm)

Page 4: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Compared to Human Hair

A Human Hair is about 100,000µm wide

Page 5: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

At small size physical observation simply changes. It is no longer governed by the classical picture.

Page 6: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Nano-structures & SensitivityAs objects are scaled down the ratio of the surface to volume increases sharply. This makes surface effects more pronounced.

Isolated small size electrode will possesses high sensitivity due to non-linearity effects.

Page 7: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.
Page 8: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Chemical Synthesis

Page 9: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

LOW temperature methods Hydrothermal chemical growth of ZnO

Page 10: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Different Nano-structrures Obtained by controlling the reaction parameters

Page 11: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.
Page 12: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.
Page 13: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Nanotechnology spans many Areas

NANOTECHNOLOGY

Information

Technology

Mechanical Eng. &

Robotics

Biotechnology

Transportation

NationalSecurity &Defense

Food andAgriculture

Energy &Environment

Aerospace

AdvanceMaterials & Textiles

Medicine /

Health

NANOTECHNOLOGY

Information

Technology

Mechanical Eng. &

Robotics

Biotechnology

Food andAgricultureAerospac

e

AdvanceMaterials & Textiles

Medicine /

Health

Energy &Environment

NANOTECHNOLOGY

Information

Technology

Mechanical Eng. &

Robotics

Biotechnology

Food andAgricultureAerospac

e

AdvanceMaterials & Textiles

Medicine /

Health

NANOTECHNOLOGY NationalSecurity &Defense

Food andAgriculture

Energy &Environment

Aerospace

AdvanceMaterials & Textiles

Medicine /

Health

NANOTECHNOLOGY

Food andAgricultureAerospac

e

AdvanceMaterials & Textiles

Medicine /

Health

Energy &Environment

NANOTECHNOLOGY

Information

Technology

Food andAgricultureAerospac

eMedicin

e /Health

Mechanical Eng. &

Robotics

NANOTECHNOLOGY NationalSecurity &Defense

Food andAgriculture

Energy &Environment

Aerospace

Medicine /

Health

NANOTECHNOLOGY

Food andAgricultureAerospac

eMedicin

e /Health

Energy &Environment

NANOTECHNOLOGY

Information

Technology

Food andAgricultureAerospac

eMedicin

e /Health

Biotechnology

Mechanical Eng. &

Robotics

NANOTECHNOLOGY NationalSecurity &Defense

Food andAgriculture

Energy &Environment

Aerospace

Medicine /

Health

NANOTECHNOLOGY

Food andAgricultureAerospac

eMedicin

e /Health

Energy &Environment

NANOTECHNOLOGY

Information

Technology

Food andAgricultureAerospac

eMedicin

e /Health

Transportation

Biotechnology

Mechanical Eng. &

Robotics

NANOTECHNOLOGY NationalSecurity &Defense

Food andAgriculture

Energy &Environment

Aerospace

Medicine /

Health

NANOTECHNOLOGY

Food andAgricultureAerospac

eMedicin

e /Health

Information

Technology

Food andAgricultureAerospac

eMedicin

e /Health

Information

Technology

Mechanical Eng. &

Robotics

Information

Technology

Biotechnology

Mechanical Eng. &

Robotics

Information

Technology

Transportation

Biotechnology

Mechanical Eng. &

Robotics

Information

Technology

NationalSecurity &Defense

Transportation

Biotechnology

Mechanical Engineering

/Robotics

Information

Technology

Page 14: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Nanosized Iron for Groundwater Remediation:Smaller sized iron particles More complete reduction of chlorinated hydrocarbons

Page 15: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Absorbents for selective removal of pollutants • Teabag catalysts for de-stenching• Use high surface area Cu-ZnO catalysts to absorb S - compounds

Page 16: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

End-of-pipe management and cleanup of pollution

Treatment & Remediation

Iron Treatment Walls…

Used in groundwater treatment for many years. Iron chemically reduces organic and inorganic environmental contaminants. Currently involves granular or “microscale” iron ( 50 m or 50,000 nm).

and Nanotechnology

Nanosized iron enhances the reaction. Enhanced further by coupling with other metals (Fe/Pd)* on the nanoscale. Nano Fe0 is more reactive and effective than the microscale. Smaller size makes it more flexible -- penetrates difficult to access areas. * Elliot and Zhang ES&T 2001, 35, 4922-4926

Page 17: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.
Page 18: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Kamat, P.V, et al. J.Phys.Chem. B 2002, 106,788-794.

Nanosized zinc oxide (ZnO) “senses” organic pollutants indicated by change in visible emission signal.

Sensing capability means that the energy-consuming oxidation stage only occurs when the pollutants present.

“Sense and Shoot” Approach to Pollution

Treatment

“Sense and Shoot” Approach to Pollution

Treatment

The ZnO “shoots” the pollutants via photocatalytic oxidation to form more environmentally benign compounds.

Multifunctionality and “smartness” is highly desirable for environmental applications.

Dual role of ZnO semicondouctor film as a sensor and photocatalyst

>300 nm

UV

Page 19: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.
Page 20: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.
Page 21: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Drug Delivery

Page 22: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Targeting Ligands

Page 23: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Liposome's

Page 24: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

Governments Expenditure in Nanotech.

Western Europe : USD 669 Million

Japan : USD 810 Million

U. S. A. : USD 774 Million

Asia : USD 800 Million

Page 25: Dr. Kamal K. Taha Associate Professor of Physical Chemistry Dean CAIS U of B Introduction to Nanotechnology.

AcknowledgementsTOKTEN-Sudan;Dr. Omer Nor;Institute for Technical Research –NCR Omdurman Ahlia University Future university University of Elneelain