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†Electronic Supplementary Information (ESI) available. See DOI: 10.1039/b000000x/ Fig. S1. ATR-FTIR spectra of separators with different treatment conditions. Fig. S2. The ATR-FTIR spectra of hybrid layer coated PP (COI 10.2%) and the separators shaken after 12h, 24h, 48h and 96h, respectively. Electronic Supplementary Material (ESI) for RSC Advances. This journal is © The Royal Society of Chemistry 2014
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DOI: 10.1039/b000000x/ †Electronic Supplementary ...Shaken after 24H 0.0184 0.0127 0.690 Shaken after 48H 0.0241 0.0170 0.705 Shaken after 96H 0.0203 0.0145 0.714 Table S2 The mechanical

Jul 08, 2020

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Page 1: DOI: 10.1039/b000000x/ †Electronic Supplementary ...Shaken after 24H 0.0184 0.0127 0.690 Shaken after 48H 0.0241 0.0170 0.705 Shaken after 96H 0.0203 0.0145 0.714 Table S2 The mechanical

†Electronic Supplementary Information (ESI) available. See DOI: 10.1039/b000000x/

Fig. S1. ATR-FTIR spectra of separators with different treatment conditions.

Fig. S2. The ATR-FTIR spectra of hybrid layer coated PP (COI 10.2%) and the

separators shaken after 12h, 24h, 48h and 96h, respectively.

Electronic Supplementary Material (ESI) for RSC Advances.This journal is © The Royal Society of Chemistry 2014

Page 2: DOI: 10.1039/b000000x/ †Electronic Supplementary ...Shaken after 24H 0.0184 0.0127 0.690 Shaken after 48H 0.0241 0.0170 0.705 Shaken after 96H 0.0203 0.0145 0.714 Table S2 The mechanical

Fig. S3. The cross-section morphologies of the unmodified PP separator and hybrid

layer coated PP (COI: 11.9%) with different magnifications.

Page 3: DOI: 10.1039/b000000x/ †Electronic Supplementary ...Shaken after 24H 0.0184 0.0127 0.690 Shaken after 48H 0.0241 0.0170 0.705 Shaken after 96H 0.0203 0.0145 0.714 Table S2 The mechanical

Fig. S4. Comparison of thermal stability of PP separator, PP-PDA and hybrid layer

coated PP (COI: 11.9%).

Page 4: DOI: 10.1039/b000000x/ †Electronic Supplementary ...Shaken after 24H 0.0184 0.0127 0.690 Shaken after 48H 0.0241 0.0170 0.705 Shaken after 96H 0.0203 0.0145 0.714 Table S2 The mechanical

Fig. S4. The retention ratio of the liquid electrolyte for separators after being kept in

the sample bags for 6 h.

Page 5: DOI: 10.1039/b000000x/ †Electronic Supplementary ...Shaken after 24H 0.0184 0.0127 0.690 Shaken after 48H 0.0241 0.0170 0.705 Shaken after 96H 0.0203 0.0145 0.714 Table S2 The mechanical

Table S1

The absorbance at 1460cm-1 and 1100cm-1 of hybrid layer coated PP (COI 10.2%) and

the separators shaken after 12h, 24h, 48h and 96h, respectively, according to the

corresponding ATR-FTIR spectra

Sample ID PH1460 PH1100 PH1100/PH1460

Hybrid layer coated PP 0.0218 0.0146 0.669

Shaken after 12H 0.0215 0.0146 0.679

Shaken after 24H 0.0184 0.0127 0.690

Shaken after 48H 0.0241 0.0170 0.705

Shaken after 96H 0.0203 0.0145 0.714

Table S2

The mechanical properties of PP separator, hybrid layer coated PP (COI 11.9%) and

plasma treated PP separator

Separator Tensile strength (MPa) Elongation (%)

PP 128.5 76.5

Hybrid layer coated PP 150.1 96.0

Plasma treated PP 110.0 30.6