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Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Dec 26, 2015

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Page 1: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,
Page 2: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Dmitri Mendeleev

A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8

groups, but he understood that many elements were still missing. He placed gaps in his periodic table where he thought these

elements belonged, and he correctly predicted these elements properties which validated his ordering of the elements.

Photo by Jurii

Page 3: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Elements are arranged and identified on the periodic table by the number of protons they

have in their nucleus.

The ATOMIC NUMBER is equal to the number of protons in an element. In its uncharged

atomic state, it is also equal to the number of electrons.

Page 4: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Elements also has an atomic mass listed. Remember atomic mass of an element is

different than the mass number of an isotope.

The ATOMIC MASS is equal to the number of grams in 1 mole of an element. Atomic mass is

sometimes referred to as atomic weight.

28.1 grams of siliconApproximately 1 mole of Si

Page 5: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

It is very important that you can use the periodic table to distinguish metals from nonmetals.

Find the dark jagged line on the Periodic Table

On the left side of this line are all of the metals

On the right side of this line are

all of the nonmetals

Page 6: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Sodium

Beryllium

+ 2

+ 1

This gives metals a positive charge.

Positively charged ions are called cations.

When elements lose electrons and increase

their charge, we say that they have been oxidized.

Page 7: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

This gives nonmetals a negative charge.

Negatively charged ions are called anions.

When elements gain electrons and lower

their charge, we say that they have been reduced.

Oxygen

Chlorine

- 2

- 1

Page 8: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Metals lose/donate electrons and nonmetals gain/accept electrons

This is whyMETALS react with

NONMETALS!

sodium chlorinesodium chloride

+1 -1

Page 9: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

You need to understand the pattern of elements gaining and donating electrons on the periodic table.

Think about counting from the outside to the inside!

Page 10: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

The metals in the middle of the periodic table are known as the transition metals.

Transition Metals

Page 11: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

The elements that lay on either side of the dark, jagged have rather unique properties. Sometimes they behave like metals, and sometimes they behave like nonmetals.

Because of this, they are called Metalloids

Page 12: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

You also need to know that Iron, Cobalt, and Nickel have special properties such as the ability to be made into magnets. Together, these three elements are known as the .Iron Triad

Iron Triad

Page 13: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

s p

The elements whose valence electrons are in the s and p sublevels are known as the representative

elements. The number of valence electrons of these elements is followed by an A.

Page 14: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

d

f

The elements whose valence electrons are in the d and f sublevels are known as the transition

elements. The number of valence electrons of these elements is followed by a B.

Page 15: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

There are several groups/families on the periodic table whose name you should have memorized.

Group 1 = Alkali MetalsGroup 2 = Alkaline Earth MetalsGroup 17 = HalogensGroup 18 = Noble Gases

Page 16: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Elements in the same group/family have similar

physical and chemical properties because they all have the same number of

valence electrons!

All of the elements in group 16 have 6 valence electrons

Columns on the periodic table are known as groups

or families.

Page 17: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

How many valence electrons do the elements of group 2 have?

2A = 2

How many valence electrons do the elements of group 6 have?

6B = 6

Page 18: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

How many valence electrons do the elements of group 17 have?

7A = 7

How many valence electrons does sulfur have?

6A = 6

Page 19: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Which group on the periodic table undergoes the fewest chemical reactions?

They are inert gases. This is because they have 8 valence electrons and their s and p sublevels are full.

Inert means they resist chemical reactions!

Page 20: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

The Periodic Table can be used to determine the charge of the representative elements when they become ions!

+1

+2 +3+4or-4 -3 -2 -1

0

Page 21: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Determine the charge of each of the elements on your notes.

+1 -1 +2-2 -3 -1-2 +1 +2+2 -1 0

Noble Gases do not become ions. This is why we say they have a charge of zero (0)

Page 22: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

The transition metals are the d-block elements. Because of this, the number of electrons they will lose is less predictable.

You will know the charge of a transition metal by the ROMAN NUMERAL in its name!

Iron (III) has a ____ charge.Iron (II) has a ____ charge.

copper (I) has a ____ charge.copper (II) has a ____ charge.

+3+2

+1+2

Page 23: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Determine the charge of each of the transition metals on your notes.

+2 +4 +3+4 +2 +3

Page 24: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Why is the charge of a transition metal always positive?

Metals ______________ electrons.This gives them a ____ charge.

Positively charged ions are called ________.

lose/donate+

Remember:

Since all of the transition elements are metals, they will all be cations!

Metals

cations

Page 25: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Ionic compounds are ALWAYS between a metal and a nonmetal.

On the left side of this line are all of the metals

On the right side of this line are

all of the nonmetals

Page 26: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

Covalent compounds are ALWAYS between nonmetals.

On the right side of this line are

all of the nonmetals

Page 27: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

The formula above shows the ratio of an unidentified element, X, to sodium in an ionic salt. In which group on the periodic table does Element X most likely belong?

A Group 1 B Group 2 C Group 17 D Group 18

Since it is an ionic salt, it has to be a nonmetal since sodium is a metal. It cannot be group 18 since group 18 is the inert noble gases that would not react with sodium.

Understanding the previous facts at a conceptual level is critical to your success in chemistry. Using this knowledge, determine the identity of each of the following unknown elements.

Page 28: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

The formula above shows the ratio of an unidentified element, X, to fluorine in an ionic salt. Which group below is most likely the identity of Element X?

A sulfur B lithium C arsenic D krypton

Since it is an ionic salt, it has to be a metal since fluorine is a nonmetal. Ionic compounds have both a metal and a nonmetal.

Page 29: Dmitri Mendeleev A Russian chemist named Dmitri Mendeleev created the first widely accepted periodic table. He still relied on this idea of 8 groups,

The formula above shows the ratio of an unidentified element, X, to chlorine in a covalent molecule. Which element below is most likely the identity of Element X?

A sodium B neon C phosphorous D copper

Since it is a covalent molecule, it has to be a nonmetal. It cannot be neon since neon is an inert noble gas that would not react with chlorine.