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iscovery of Natural Organic Metals for el Cells, Transistors and Supercapacito Nikhil S. Malvankar 1,2 , Madeline Vargas 2 , Mark T. Tuominen 1 and Derek R. Lovley 2 Departments of 1 Physics and 2 Microbiology, University of Massachusetts, Amherst. Bacteria-produced proteins behave as if they are metal Geobacter sprouts a web of microbial nanowires with metallic-like conductivity Geobacter Email: [email protected] Cell Phone: 413-313-3179
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Discovery of Natural Organic Metals for Fuel Cells, Transistors and Supercapacitors

Feb 25, 2016

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Discovery of Natural Organic Metals for Fuel Cells, Transistors and Supercapacitors. Nikhil S. Malvankar 1,2 , Madeline Vargas 2 , Mark T. Tuominen 1 and Derek R. Lovley 2 Departments of 1 Physics and 2 Microbiology, University of Massachusetts, Amherst. . Email: [email protected] - PowerPoint PPT Presentation
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Page 1: Discovery of Natural Organic Metals for  Fuel Cells, Transistors and  Supercapacitors

Discovery of Natural Organic Metals for Fuel Cells, Transistors and SupercapacitorsNikhil S. Malvankar1,2, Madeline Vargas2, Mark T. Tuominen1 and Derek R. Lovley2

Departments of 1Physics and 2Microbiology, University of Massachusetts, Amherst.

Bacteria-produced proteins behave as if they are metals

Geobacter sproutsa web of microbial nanowires with metallic-like conductivity

Geobacter

Email: [email protected] Cell Phone: 413-313-3179

Page 2: Discovery of Natural Organic Metals for  Fuel Cells, Transistors and  Supercapacitors

Geobacter uses electrodes as we use oxygen

Nanowires show structural features

similar to synthetic organic metalsX-ray diffractionrevealed highlyordered structure

Peak corresponds to pi stacking distance (3.5 Å)

Metal-like conductivity of microbial nanowires

Conductivity increased upon cooling

Temperature (K)

Con

duct

ivity

(µS

/cm

)

Nanowires

Biofilm

Nanowire networks carry electrons over

10,000 times the size of a single microbe

Equivalent to humans using oxygen 10 km away

Pi stacking givesmetallic conductivity

Page 3: Discovery of Natural Organic Metals for  Fuel Cells, Transistors and  Supercapacitors

Microbial Nanowires: A new paradigm for biological electron transfer and bioelectronics

Protein-based nanomaterials are inexpensive and environmentally-sustainableThey can work under unusual aqueous and acidic environments

Microbial Fuel Cells with improved

current and power density

Applications of Microbial Nanowires

Transistors with 100-fold ON-OFF ratio

Con

duct

ivity

S/c

m)

Gate voltage (Volts)

ON

OFF

High-performance Supercapacitors

Email: [email protected] Cell Phone: 413-313-3179