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S1 5-Azadibenzo[a,g]corannulene V. M. Tsefrikas, A. K. Greene and L. T. Scott* Electronic Supplementary Information NMR spectra of compounds 6, 9, 10, 11, 12, 13a, 13b, 14a, 14b, 15, 18, 20, and 22 pages S2-S27 Figure ESI 1. UV-VIS spectra of 5-azadibenzo[a,g]corannulene (6) before and after acid addition page S28 Figure ESI 2. UV-VIS spectra of 5-azadibenzo[a,g]corannulene (6) plus acid plus base page S28 Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is © the Partner Organisations 2017
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Dibenzo[g,m]azacorannulene ESI 170108Dibenzo[g,m]azacorannulene ESI 170108 Author: LTScott Created Date: 20170108155930Z ...

Jul 03, 2020

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Page 1: Dibenzo[g,m]azacorannulene ESI 170108Dibenzo[g,m]azacorannulene ESI 170108 Author: LTScott Created Date: 20170108155930Z ...

S1

5-Azadibenzo[a,g]corannuleneV.M.Tsefrikas,A.K.GreeneandL.T.Scott*

ElectronicSupplementaryInformation

NMRspectraofcompounds6,9,10,11,12,13a,13b,14a,14b,15,18,20,and22 pagesS2-S27

FigureESI1.UV-VISspectraof5-azadibenzo[a,g]corannulene(6)beforeandafteracidaddition pageS28

FigureESI2.UV-VISspectraof5-azadibenzo[a,g]corannulene(6)plusacidplusbase pageS28

Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers.This journal is © the Partner Organisations 2017

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0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

10.0

8.00

8.50

9.00

N

TMS

1 H N

MR

(500

MH

z, C

DC

l 3)

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050

100

150

200

N

TMS

13C

NM

R (1

25 M

Hz,

CD

Cl 3)

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S6

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

7.50

8.00

8.50

9.00 1 H

NM

R (5

00 M

Hz,

CD

Cl 3)

N

H

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1 H N

MR

(500

MH

z, C

DC

l 3)

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

10.0

8.00

8.50

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Figure ESI 1. UV-VIS spectra (CH2Cl2) of 5-azadibenzo[a,g]corannulene (6) before and after addition oftrifluoroaceticacid.

FigureESI2.UV-VISspectra(CH2Cl2)of5-azadibenzo[a,g]corannulene(6),neutralizedwithtriethylamineafteradditionoftrifluoroaceticacid.