Damla Koylu, Syena Sarrafpour, Jingjing Zhang, Sanya ... Electronic Supplementary Information for Acene-Doped Polymer Films: Singlet Oxygen Dosimetry and Protein Sensing Damla Koylu,
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Electronic Supplementary Information for
Acene-Doped Polymer Films: Singlet Oxygen Dosimetry and Protein Sensing
Damla Koylu, Syena Sarrafpour, Jingjing Zhang, Sanya Ramjattan, Matthew J. Panzer,
and Samuel W. Thomas III*
Department of Chemistry and Department of Chemical and Biological Engineering
Figure S3. 1H NMR spectra (in CDCl3) of two separated endoperoxides of dianisyl tetracene (TET) made by photo-oxidation. These spectra account for all signals in the crude photolysis mixture (Fig. S2).
Figure S2. 1H NMR spectra (in CDCl3) of dianisyl tetracene TET (top), and the mixture of two endoperoxides generated by direct photolysis (bottom).
Figure S1. 1H NMR spectra (in C6D6) of rubrene endoperoxide generated by direct photo-oxidation.
Figure S7. Dependence of ratiometric fluorescent response of 2.5% TET/PF films to 546 nm irradiation of 100 nM RB on film thickness.
Figure S8. TET/PF films (2.5% w/w) do not respond to irradiation (35 min) of 100 nM RB at 546 nm when the solution of RB is deoxygenated by bubbling with argon for 30 minutes. Heights of the bars represent the mean ratiometric signal from three films; error bars represent one standard deviation.
1. T. A. Singh-Rachford, F. N. Castellano, J. Phys. Chem. A, 2008, 112, 3550–3556. 2. J. Zhang, S. Sarrafpour, R. H. Pawle and S. W. Thomas III, Chem. Commun., 2011,