Cristina Grosso, John Ross, Don Yee, Sarah Lowe Amy Franz, Pedrag Stevanovic, Jennifer Hunt Upload RMP analytical results from laboratories into the relational.

RMP 2004 Status and Trends Program. CCSF Sediment Trace Metals analyses. Contract #4981 2 3 4 5 6 7 8 9 10 11 12 13 14 15 17 18 19 20 21 22 23 24 25 26 27

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1 498 RMP 04S - 77 BC11 SedChem 7/30/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw2 498 RMP 04S - 170 SB020S SedChem 8/2/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw3 498 RMP 04S - 85 BD31 SedChem 7/29/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw4 498 RMP 04S - 207 SPB017S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw5 498 RMP 04S - 222 SPB019S SedChem 7/29/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw6 498 RMP 04S - 200 SPB016S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw7 498 RMP 04S - 162 SB019S SedChem 8/2/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw8 498 RMP 04S - 192 SPB015S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw9 498 RMP 04S - 185 SPB002S SedChem 7/29/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw10 498 RMP 04S - 61 BA10 SedChem 8/3/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw11 498 RMP 04S - 69 BA41 SedChem 8/2/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw12 498 RMP 04S - 177 SPB001S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw13 498 RMP 04S - 342 SU019S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw14 498 RMP 04S - 215 SPB018S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw15 498 RMP 04S - 312 SU015S SedChem 7/27/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw16 498 RMP 04S - 31 LSB017S SedChem 8/3/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw17 498 RMP 04S - 305 SU002S SedChem 7/27/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw18 498 RMP 04S - 260 CB016S SedChem 7/30/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw19 498 RMP 04S - 24 LSB016S SedChem 8/3/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw

Cristina Grosso, John Ross, Don Yee, Sarah Lowe

Amy Franz, Pedrag Stevanovic, Jennifer Hunt

• Upload RMP analytical results from laboratories into the relational database

format and continue to QA/QC these data

• Completed phase I of getting the labs to submit data in new standardized reporting formats.

2005: RMP Data Management

Sediment

Site Code Cruise # Qual Result MDL Unit Qual Result MDL Unit Qual Result MDL Unit

BD15 2000-02 0.200 0.020 mg/kg 0.411 0.090 mg/kg b 57.848 0.090 mg/kgBD22 2000-02 0.194 0.020 mg/kg 0.285 0.090 mg/kg b 52.760 0.090 mg/kgBD41 2000-02 0.041 0.020 mg/kg 0.184 0.090 mg/kg b 16.546 0.090 mg/kgBD15 2000-07 0.195 0.020 mg/kg 0.363 0.100 mg/kg 49.194 0.100 mg/kgBD22 2000-07 0.190 0.020 mg/kg 0.331 0.090 mg/kg 52.325 0.090 mg/kgBD31 2000-07 0.182 0.020 mg/kg 0.423 0.090 mg/kg 54.733 0.090 mg/kgBD41 2000-07 0.081 0.020 mg/kg 0.175 0.100 mg/kg 23.710 0.100 mg/kgBD15 2001-02 ND 0.147 mg/kg 0.333 0.074 mg/kg b 54.081 0.074 mg/kgBD22 2001-02 ND 0.173 mg/kg 0.225 0.087 mg/kg b 51.361 0.087 mg/kgBD41 2001-02 ND 0.080 mg/kg 0.069 0.040 mg/kg b 16.696 0.040 mg/kgBD15 2001-08 0.204 0.010 mg/kg 0.220 0.070 mg/kg 58.920 0.070 mg/kgBD22 2001-08 0.176 0.010 mg/kg 0.240 0.070 mg/kg 53.100 0.070 mg/kgBD31 2001-08 0.189 0.020 mg/kg 0.220 0.080 mg/kg 56.730 0.080 mg/kgBD41 2001-08 0.055 0.010 mg/kg 0.130 0.060 mg/kg 24.570 0.060 mg/kgBD31 2002-07 ND 0.090 mg/kg 0.340 0.090 mg/kg 50.920 0.090 mg/kgSPB001S 2002-07 0.180 0.090 mg/kg 0.270 0.090 mg/kg 42.100 0.090 mg/kgSPB002S 2002-07 0.090 0.090 mg/kg 0.300 0.090 mg/kg 45.970 0.090 mg/kgSPB003S 2002-07 0.160 0.100 mg/kg 0.250 0.100 mg/kg 53.660 0.100 mg/kgSPB004S 2002-07 0.210 0.100 mg/kg 0.380 0.100 mg/kg 49.160 0.100 mg/kgSPB005S 2002-07 ND 0.080 mg/kg 0.300 0.080 mg/kg 41.230 0.080 mg/kgSPB006S 2002-07 0.110 0.090 mg/kg 0.270 0.090 mg/kg 34.990 0.090 mg/kgSPB007S 2002-07 0.140 0.090 mg/kg 0.290 0.090 mg/kg 52.980 0.090 mg/kgSPB008S 2002-07 0.110 0.090 mg/kg 0.350 0.090 mg/kg 55.520 0.090 mg/kg

Ag Cd Cu

Maintain public access of RMP data

through our Web Query Tool

2006: Data Management

Upload RMP analytical results from laboratories into the SWAMP comparable relational database and continue to QA/QC these data;

Redesign the web-based data access tool to interface with the new relational database format.

Continue with developing a tool for Status & Trends laboratories to submit electronic data via the web;

Develop tools to increase the efficiency of data review; Upload select datasets from RMP Pilot & Special Studies (or other

studies) into the RMP SWAMP comparable relational database so that the data could be downloaded using the data access tool.

2005: RMP Website

2005: RMP Website – Program information

2005: RMP Website - Data Access

SITE_CODE CRUISE_TYPE SITE_NAME Lat in DD long in DD DatumBA10 WATER Coyote Creek 37.46868 -122.06320 NAD-83BA20 WATER South Bay 37.49315 -122.08792 NAD-83BA30 WATER Dumbarton Bridge 37.51375 -122.13462 NAD-83BA40 WATER Redwood Creek 37.55878 -122.20912 NAD-83BB15 WATER San Bruno Shoal 37.61477 -122.28205 NAD-83BB30 WATER Oyster Point 37.66910 -122.32862 NAD-83BB70 WATER Alameda 37.74225 -122.32207 NAD-83BC10 WATER Yerba Buena Island 37.82158 -122.34950 NAD-83BC20 WATER Golden Gate 37.86350 -122.67333 NAD-83BC30 WATER Richardson Bay 37.86210 -122.47868 NAD-83BC41 WATER Point Isabel 37.88690 -122.34272 NAD-83BC60 WATER Red Rock 37.91765 -122.43573 NAD-83BD15 WATER Petaluma River 38.11148 -122.48655 NAD-83BD20 WATER San Pablo Bay 38.04823 -122.42185 NAD-83BD30 WATER Pinole Point 38.02423 -122.36262 NAD-83BD40 WATER Davis Point 38.05072 -122.27768 NAD-83BD50 WATER Napa River 38.09672 -122.26068 NAD-83BF10 WATER Pacheco Creek 38.05110 -122.09898 NAD-83BF20 WATER Grizzly Bay 38.11588 -122.03952 NAD-83BF40 WATER Honker Bay 38.06702 -121.93437 NAD-83BG20 WATER Sacramento River 38.05978 -121.81020 NAD-83BG30 WATER San Joaquin River 38.02062 -121.80522 NAD-83BW10 WATER Standish Dam 37.45167 -121.92150 NAD-83BW15 WATER Guadalupe River 37.42600 -121.98000 NAD-83C-1-3 WATER Sunnyvale 37.43425 -122.01010 NAD-83C-3-0 WATER San Jose 37.46023 -121.97560 NAD-83

Download data

Get maps

Get site locations

2006: RMP Website - Plans

Website maintenance and updates in 2006

2005: Status and Trends Monitoring

Successful sampling season

Contracts came in on budget

W=4S=8

W=6S=8

W=4S=8

W=10S=8

W=4S=8

Rivers

SuisunSan PabloBay

CentralBay

SouthBay

Lower SouthBay

Number of SAMPLES

Water: 31 totalSediment:47 total

= Historical fixed stationW=4S=8

W=6S=8

W=4S=8

W=10S=8

W=4S=8

Rivers

SuisunSan PabloBay

CentralBay

SouthBay

Lower SouthBay

Number of SAMPLES

Water: 31 totalSediment:47 total

W=4S=8

W=5S=8

W=4S=8

W=9S=8

W=4S=8

Rivers

SuisunSan PabloBay

CentralBay

SouthBay

Lower SouthBay

Rivers

SuisunSan PabloBay

CentralBay

SouthBay

Lower SouthBay

Number of SAMPLES

Water: 31 totalSediment:47 total

= Historical fixed station = Historical fixed station

2005: Status and Trends Monitoring

WATER SAMPLING

July 2005

31 sites (5 historic RMP)Backup site

Target site

2005: Status and Trends Monitoring

SEDIMENT SAMPLING

July/August 2005

47 sites (7 historic RMP)

Sediment organics analyses by High Resolution Mass Spectrometer

Backup site

Target site

2005: Status and Trends Monitoring

BIVALVE BIOACCUMULATION SAMPLING

June - Sept 2005

11 sites (all historical RMP)

Deployed Mytilus (9 sites)

Trawled for Corbicula Analyzed for organics

(including PBDEs)

2006: Status and Trends Monitoring

Water, Sediment, and Bivalve Bioaccumulation sampling

(same effort as in 2005)

NewWATER Chemistry

Drop Dissolved Organic Contaminants in Water (this year)

WATER Toxicity

Scheduled Every 5-years

Estuary Tributaries

Suisun Creek

Napa River

Petaluma River

San Lorenzo Creek

Coyote Creek

Note: Site locations are not accurately placed on this map.

San Mateo Creek

REVIEW

SEDIMENT INVESTIGATION

IN THE TRIBUTARIES

Nov & April (2004-2005)

Six Tributaries, two locations ea.,

two sampling events. Sediment Toxicity-two amphipods

(Hyalella (FW) + Eohaustorius (Est.)) Sediment chemistry at upstream sites

and toxic downstream sites (RMP analyte list + pyrethroids)

Water Toxicity Sampling (April only)

Five Tributaries

Ceriodaphnia, Americamysis, Menidia

Diazinon & Chlorpyrifos

2005 S&T: Episodic Toxicity Monitoring & PRISM

November Sampling (Nov. 1st – 4th)

April Sampling (Apr. 18th – 20th)

Sampled Tributaries

Suisun Creek

Napa River

Petaluma River

San Lorenzo Creek

Coyote Creek

Note: Site locations are not accurately placed on this map.

San Mateo Creek

November - 2004

Preliminary Results – Sediment Toxicity

Sampled Tributaries

Suisun Creek

Napa River

Petaluma River

San Lorenzo Creek

Coyote Creek

Note: Site locations are not accurately placed on this map.

San Mateo Creek

April - 2005

Preliminary Results – Sediment Chemistry

MIN MAX MIN MAX% Fines (<63 um) 15 67 24 100TOC (%) 0.5 2.7Bifenthrin 1.9 10.3 0 2.4Cyfluthrin 0 8.62 0 0Cypermethrin 0 4.17 0 0Esfenvalerate 0 0 0 0Lambda-cyhalothrin 0 0 0 0Permethrin 0 20.5 0 0

Nov Apr

NA

Preliminary Results – Sediment Chemistry

NBay SBayERM MIN MAX MIN MAX AVG AVG

% Fines (<63 um) 15 67 24 100 64 86TOC (%) 0.5 2.7 1.1 1.4Sum of DDTs (SFEI) 46.1 6.7 122.3 2.3 44.6 3.5 4.8Sum of Chlordanes (SFEI) 6 0 58.2 0 45.8 0.5 1.4Aldrin 0 0.5 0 0.6 0.8 0.9Dieldrin 8 0 6.7 0 3.58 0.3 0.5Endrin 0 0 0 0 0.3 1.4Sum of PBDEs (SFEI) 0 8 0 23 3 34Sum of PCBs (SFEI) 180 4 36 7 35 3 15

Nov Apr

NA

Preliminary Results – Sediment Chemistry

NBay SBayERM MIN MAX MIN MAX AVG AVG

% Fines (<63 um) 15 67 24 100 64 86Ag 3.7 0.2 0.7 0.2 0.3Al 36175 56700 33584 36543As 70 2.5 8.0 10.1 8.5Cd 9.6 0.1 0.4 0.2 0.2Cu 270 20 57 42 40Fe 9313 32695 39065 39174Hg 0.71 0.05 0.70 0.03 1.53 0.22 0.32Mn 364 1134 989 1323Ni 51.6 9 125 90 88Pb 218 18 63 17 24Se 0.1 0.7 0.3 0.3Zn 410 62 198 108 125

NA

NA

NA

NA

NA

NA

NA

NA

Nov Apr

NA

NA

NA

2006 Proposal: Episodic Toxicity Monitoring

Water Board priority to investigate the causes of the persistent sediment toxicity observed in the Estuary

Focus on locations which have been shown to be toxic and work to investigate the potential causes.

A workgroup will convene in the spring of 2006 to begin planning the detailed workplan

Sampling will occur in the wet season of next year (Nov 06 – Apr 07)

timing will allow for coordination with other RMP projects (EEPS).

• Sample Water and Sediment twice & archive sediments

• Test for toxicity and water/sediment quality

if toxic sediments

if really toxic sediments then add

Resample to investigate duration of toxicityPerform sediment chemistry (RMP list + pyrethroids)

Resample to perform sediment TIEs

2006 Proposal: Episodic Toxicity Monitoring

Focus on a couple tributaries known to be toxic