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    Upstream Sector

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    Introduction

    Source Internet: CPIQ Web Page

    Agradecimientos.

    CPIQ

    El Consejo Profesional de Ingeniera Qumica de Colombia es una entidad

    creada por la Ley 18 de 1976 y su Decreto Reglamentario 371 de 1982,encargada de otorgar las matrculas y expedir las tarjetas profesionales,

    realizar seguimiento y control del adecuado ejercicio de la profesin,

    colaborar con las autoridades universitarias y profesionales y apoyar las

    actividades de las asociaciones gremiales, cientficas y profesionales de la

    Ingeniera Qumica.

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    Hydrocarbon Industry Sectors

    Source Internet Boletin SAO . Association of American Railroads, Bloomber, Ecopetrol

    Upperstream Midstream Downstream

    Exploration and production (E&P)

    Transportation (Crude or Refined)Refinig of Petroleum

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    Petroleum or Crude Oil

    Petroleum comes from Greek Petra-Rock and elaoin-Oil or Latin Oleum-Oil)also Crude Oil, sometimes calledBlack Gold. Petroleumis a HydrocarbonNatural Mixture.

    Source Internet Various

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    Natural Gas

    Natural gasis a hydrocarbon gas mixture consisting primarily ofmethane, but commonly includes varying amounts of alkanes andbutanes and even a lesser percentage of carbon oxide, nitrogenand hydrogen sulfide (sour gas).[

    Source Internet Various

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    Crude Oil and Natural Gas

    Crude Oil(Oil) has Natural Gas. Oil is non renewable resourcesbecause theycannot be replenished on human time frame. They also called fossil fuelbecause they is thought where formed from dinosaurs.

    Source Internet Various

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    Crude Oil and Natural Gas

    Biotic theory: Petroleum is theremains of organic material thatwas deposited, usually in marineenvironments, millions of yearsago.

    Abiotic theory:Deep in the crust or in the mantel ofthe earth, bacteria may make oilabiotically, that is from sources thatwere never alive.

    Hydrogen plus carbon dioxide with thehelp of archaea yield methane pluswater.

    archaea

    Source Theories for The Origen of Oil by Mike Westlund

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    Crude Oil Resources

    OPECs ASB 2013 2012 world reserves

    Salt Mine Emerald Vein

    Reserve

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    Crude Oil Resources

    Source: Internet

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    Crude Oil Resources Native Fluids

    Source: Internet

    Reservoir Rock

    Complex Faulted

    Single Anticlinal

    Reservoir Rock

    Copyright 2010-2014 - San Joaquin Valley Geology

    Porosity

    Permeability

    Saturation

    Grain size

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    Crude Oil Resources

    Exploratory well Exploratory

    And Appraisal Wells

    Source: SPE PRM 2011

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    Crude Oil Resources

    Assessment of Reserves

    Source: SPE PRM 2011

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    Crude Oil Resources

    Source: SPE PRM 2011

    Recoverable reserves is also oftencalled proved reserves.

    A term used in natural resourceindustries to describe the amount of

    resources identified in a reserve thatis technologically or economicallyfeasible to extract. A new reservecan be discovered, but if theresource cannot be extracted by anyknown technological methods, thenit would not be considered part of

    recoverable reserves.

    Recoverable Reserves

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    Crude Oil Resources - Production

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    Crude Oil Resources Year over Year Balance

    2012

    Year EndBalance

    2011

    Year End

    Balance

    Produced

    Discovery

    EOR

    (-)

    (+)

    (+)

    =

    New Proved

    $$$$$$$

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    OPEC Share of World Crude Oil Reserves 2012

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    OPEC Members 2012 Midyear Population

    Country 2008 2009 2010 2011 2012

    Algeria 34,591 35,268 35,978 36,717 37,800

    Angola 16,368 16,889 17,430 17,992 18,577

    Ecuador 13,805 14,005 14,307 14,483 15,500

    IR Iran 72,584 73,651 74,733 75,150 76,520

    Iraq 30,578 31,664 32,490 33,339 34,207

    Kuwait 3,442 3,485 3,582 3,697 3,824Libya 6,150 6,263 6,378 6,295 6,411

    Nigeria 151,212 154,727 158,057 162,799 167,683

    Qatar 1,447 1,639 1,715 1,733 1,774

    Saud Arabia 27,787 26,661 27,563 28,376 29,196

    United Arab Emirates 8,074 8,200 8,264 8,328 8,394

    Venezuela 27,732 28,181 28,629 29,072 29,517Total OPEC Members 391,769 400,634 409,127 417,982 429,402

    Source OPECs ASB 2013

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    Oil and Gas Reserves Per Capita

    Source OPECs ASB 2013

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    New World Energy Map - Reserves

    Conventional Reserves Shale GasThousands of Millions of BBL Billions of SCF

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    New World Energy Map

    Source EIA and ARI

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    Country 2008 2009 2010 2011 2012

    1 Venezuela 4,983 5,065 5,525 5,528 5,563

    2 Brasil 380 365 358 417 434

    3 Mxico 359 359 339 349 360

    4 Per 415 415 345 353 3595 Argentina 428 399 379 359 333

    6 Bolivia 750 750 695 281 281

    7 Colombia 114 124 134 153 155

    8 Chile 46 46 45 43 41

    Source OPEPs : Desarrollo Peruano

    Natural Gas Proved Reserves LAR ( Billions of Cubic Meters)

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    Country 2009 2010 2011 2012 2013

    1 Venezuela 99 99 211 211 298(*)

    2 Saudi Arabia 267 262 263 267 268

    3 Canada 178 175 175 174 173

    4 Iran 136 138 137 151 155

    5 Iraq 115 115 115 143 141

    6 Kuwait 104 104 104 104 104

    7 United Arab Emirates 98 98 98 98 98

    8 Russia 60 60 60 60 80

    9 Libya 44 44 46 47 48

    10 Nigeria 36 37 37 37 37

    11 Kazakhstan 30 30 30 30 30

    12 China 16 20 20 20 2613 Qatar 15 25 25 25 25

    Proved Reserves Thousands Millions of Bbl.

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    Country 2008 2009 2010 2011 2012

    1 United States 19,498 18,771 19,180 19,949 18,555

    2 China 7,468 8,540 9,330 8,924 9,324

    3 Japan 4,788 4,406 4,465 4,480 4,720

    4 India 2,864 3,113 3,255 3,426 3,441

    5 Saudi Arabia 1,980 2,195 2,371 2,986 3224

    6 Brazil 2,205 2,481 2,622 2,793 2,933

    7 Russia 2,906 2,950 2,992 2,725 2,725

    8 Germany 2,545 2,453 2,470 2,400 2,338

    9 Canada 2,232 2,153 2,258 2,289 2,327

    10 Korea,South 2,142 2,188 2,268 2,230 2,268

    11 Mexico 2,161 2,071 2,080 2,133 2,147

    12 Iran 1,742 1,766 1,726 2,028 2,08813 France 1,945 1,868 1,881 1,792 1,738

    Oil Demand Thousands of Barrels per Day (k b/d)

    Source US Energy Information Administration

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    World Oil Demand NAR and LAR (1000 b/d)

    Source OPECs ASB 2013

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    World Proven Crude Oil Reserves NAR and LAR (millions barrels)

    Source OPECs ASB 2013

    Lasting time=

    (

    )

    = 6 years

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    Source OPECs ASB 2013

    How much is there?

    World reserves stood at 1,478,211 (*) millions of barrels. Word demand is about 76millions of barrel per day. At this rate, the oil will last about 53 years.

    Lasting time

    )

    = 53 years

    Lasting time

    )

    = 6 years

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    World Crude Oil Production Millions of Barrels Per Day (m b/d)

    (m b/d)

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    USA Crude Oil Production

    Source OPECs ASB 2013

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    World Crude Natural Gas Production (Billions Standard Cubic Meters per Day)

    (b scm/d)

    Source OPECs ASB 2013

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    Crude Oil

    WTI is alight crude oil, with anAPI gravityof around 39.6 andspecific gravityof about 0.827, which

    is lighter thanBrent crude. It contains about 0.24% sulfur thus is rated as a sweet crude oil(havingless than 0.5% sulfur), sweeter than Brent which has 0.37% sulfur.

    Source : BloomberSource. Association of American Railroads, Bloomber

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    Country 2011 20121 Venezuela 2,881 2,804

    2 Mxico 2,552 2,548

    3 Brazil 2,105 2,061

    4 Colombia 914 914

    5 Argentina 560 5356 Ecuador 500 504

    7 Peru 70 67

    8 Bolivia 44 51

    9 Guatemala 11 11

    10 Chile 4 4

    Oil Production LAR 2012 Thousands of Barrels per Day (1000 b/d)

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    Crude Oil

    How much is there?

    World reserves stood at 1,478,211 (*) millions of barrels. Word demandis about 76 millions of barrel per day. At this rate, the oil will last about53 years.

    Lasting time

    = 53 years

    OPECs ASB 2013 2012 world reserves

    Lasting time

    = 6 years

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    Oil API gravity is one way of expressing density. It is related to the specific gravity (SG) of the fluid asfollows:

    Specific gravity is the ratio of the density of the fluid to the density of water at a referencetemperature and pressure (25C, 101 kPa).

    Is used to a general classification of crudes as extra heavy oil, heavy oil, medium oil and light oil

    Crude Oil API Classification

    The density of a crude of 10 API is equal to the density of fresh water at Standard Conditions

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    Crude Oil Heavy Oil Denominations

    Class Description Viscosity Condition

    (1)

    API range Example

    A Medium Heavy Oil >10 to 25 to 100 to 20 to < 7 Orinoco & Castilla

    C Tar Sands and Bitumen >10000 Non mobile >12 to > 7 Athabasca Sand

    D Oil Shale (2) (2) Non mobile

    Because there is a range variation in viscosity for similar API grades and confusing denominationfor Heavy Oils, Bitumen and Tar Sands there a need for a simple classification based on viscosities

    (1) At cold conditions

    (2)Rock of oil shale is not permeable

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    Crude Oil API Classification

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    Crude Oil

    Petroleum or crude oil isa complex mixture ofhydrocarbons and other chemicals. The

    composition varies widely depending where and

    how the petroleum was formed. In fact, a

    chemical analysis can be used to fingerprint the

    source of the petroleum. However, raw

    petroleum or crude oil has characteristic

    properties and composition.

    1.Carbon 83 to 87%

    2.Hydrogen 10 to 14%

    3.Nitrogen 0.1 to 2%

    4.Oxygen 0.05 to 1.5%

    5.Sulfur 0.05 to 6.0%

    6.Metals < 0.1%

    Elemental Composition

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    Unconventional Resources

    Orinoco Heavy OilSandstone

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    Resource triangle for natural gas (Holditch 2006).

    Unconventional Gas

    Shale Gas

    Source: JPT 2010 BHI/CONNEXUS MAGAZINE

    A depiction of how

    methane hydrate

    found in ice burns.

    The U.S. Department of Energys National EnergyTechnology Laboratory estimates that the global methane

    hydrate resource is 700,000 Tcf (20 000 Tcm). Connexus

    Baker Hughes Inc.

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    Unconventional Gas Vs. Conventional Gas

    Unconventional

    Source: EIA 2010

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    Unconventional Gas

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    Unconventional Gas

    Shale GasFrac JobFrac Job

    Source: EIA / Wikipedia

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    Unconventional Gas - Frac Job

    Water is by far the largest

    component of fracking fluids.

    A Hydraulic fracturing job

    consume from 6,000 to

    600,000 US gallons of

    fracking fluids, but over its

    lifetime an average well may

    require up to an additional 5

    million gallons of water for

    full operation and possible

    restimulation frac jobs.

    Source: source watch organization

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    Portfolio of Electricity Generation USA

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    Preliminary studies suggest significant undiscovered heavy oil potential at shallow depths of less than

    2,000 feet of between 1 billion and 2 billion barrels of oil in place could exist with 100 million to 300million barrels of recoverable reserves. - Hart

    VIM

    VSM

    Colombia - Overview

    Llanos

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    Unconventionals is a very trendy word indeed. But what is so unconventional about unconventional oil and gas resources?

    Heavy-oil exploitation is widely commercialized; whether by mining of the oil sands and oil shales or by in-situ steaming or combusting

    processes that bring extra-heavy oil to the surface. Yet we say that such oil is unconventional.

    Research and pilot operations continue in an effort to increase recovery and decrease costs. When cheap and easy oil becomes scarce,

    should we then refer to these recovery techniques as advanced, complex, or difficult recovery rather than the exploitation of

    unconventional oil?

    The same could be said for shale gas. A few years ago, such gas was said to be unconventional. However, continued research and recent

    exploitation with multifracs from horizontal wells have led us to think differently. Already, shale gas appears to be more conventional

    than coalbed methane. With the ever-increasing need for natural gas as a clean fuel, the importance of producing more gas is growing.Not all unconventional gas is equal: Each type is at a different stage of exploitation. While waiting to find out about the effect of

    renewable energies on our society, gas remains the leading fuel of choice, whether it is natural or a product of gasification of coal or

    biomass.

    So, where do we look next? Previous centuries all favored a particular source of energy: The 19th century focused on coal because it had

    no other alternative, and the 20th century was mainly oil-centered. In the 21st century, we must turn wisely to the resources we have.

    There is no doubt that we will have to use a diversity of energy sources adapted to our needs: oil, gas, nuclear,

    and renewable energies will all find their share. Marcel Polikar

    Source: JPT JULY 2010

    Marcel Polikar, SPE, is a Senior Reservoir Engineer with Shell International E&P in Rijswijk, The Netherlands, in the Thermal and UnconventionalEnhanced-Oil-Recovery R&D group.

    Unconventional - Insight

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    Operation and Services

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    Real Time Remote Services

    Digital USA Summit: Baker Hughes Inc.

    Digital Oil Field/Engineer

    Real Time/Remote Control Advanced Control System

    Data Base Management

    Real Time Decision

    Globalized Teamwork's

    Production Enhancement

    Reservoir Optimization

    The Future Belongs to DigitalProfessionals

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    Exploration

    Seismic Operations

    Source Internet Various

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    Exploration Prospection

    Source Internet Various

    Seismic Operations

    Vibroseis

    Seismic lab Crew

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    Exploration and Development- Rig Types

    Source Internet Various

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    Rig Systems Main Components

    1. Crown3. Drill Line

    4. Monkey board

    5. Traveling Block

    6. Top Drive

    7. Derick

    8. Drill Pipe

    9. Dog House10. Blow Out Preventer

    13. Generators

    16. Mud Pumps

    18. Mud Pits

    19. Reservoir Pit

    21. Shale Shaker

    22. Choke Manifold23. Pipe Ramp

    Toolpusher:

    Driller

    Derrickhand

    Motorman

    Boilerman

    Roughneck Jobs

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    Rig Systems - Hoisting

    Source Internet Various

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    Rig Systems - Rotating

    Source Internet Various

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    Rig Systems - Pipes

    Drill Collars

    HWDPBits

    Subs & Stabilizers

    Drill String

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    Rig Systems - BITS

    Cones

    Inserts PDC

    Reamer

    Core Bit

    Hybrid

    Source: Baker Hughes Inc and others

    Jets

    Eccentric

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    Rig Systems Rotating

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    Rig Systems Circulation

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    Rig Systems Safety

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    Drilling a well

    Drilling and connections.

    TheDrillstringis run into the holewith aBit. The drillstring is rotatedand the bit drills the hole.

    Pipe is run into the hole asJoints(30)

    orStands(90), a stand being threejoints of pipe.

    After a joint or stand has been drilleddown, aConnectionis made to addanother joint or stand to the stringand drilling continues.

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    Drilling a well

    Drilling and tripping.When a bit is worn out, or the plannedhole section has been finished thedrillstring will be pulled or tripped.

    Stands of pipe are pulled and racked in the

    derrick.The bit will be changed and the pipetripped back into the hole.

    Trips must be monitored to assure thecorrect fluid is being returned to the hole.

    Source Internet Various

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    Drilling a well Drilling Fluids Muds

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    Drilling a well

    Directional drilling To avoid collision with other wells.

    To allow intersection by a reliefwell in the event of a blow-out.

    To hit the geological target areas

    To provide a better definition ofgeological and reservoir data.

    For equity determination.

    To fulfil local and governmentregulations.

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    Completing a well

    CASING

    Casing is steel pipe that protects the holefrom collapse and the formation fromdamage.

    Casing is run from the wellhead, eachcasing being run inside the other.

    Surface Casing (30 & 20)

    Intermediate Casing (13 3/8 & 9 5/8)

    Liner (7 & 5)Hung inside the previously

    run casing

    CONDUCTOR (26 20)

    SUPERFICIE (20 13-3/8)

    INTERMEDIO (13-3/8 7)

    LINER (9-5/8 5)

    TIE-BACK LINER (9-5/8 5)

    TYPICAL

    DEPTHS

    40-1500FT

    100-3000 FT

    4000-16000 FT

    GREATER THAN

    20000 FT

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    Cementing a well

    Once casing is run, it will be cemented into place.Cementing helps:

    Bond the casing to the formation

    Protect any producing formations

    In the control of blowouts

    Seal off troublesome zones

    Provide support for the casing

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    Well Logging and Testing

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    Well Logging and Testing

    Orinoco Extra heavy Ol

    Source Internet Various,Also Baker Hughes Inc.

    Can be produced on cold?

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    Well Logging and Testing

    Well Head

    X masstree

    Skid Unit

    Flares

    Separators

    How much fluids

    Gas

    Ol Water

    What quality

    What pressure

    How much fluids

    Gas

    Ol Water

    What quality

    What pressure

    Shaped Charges

    Pay Zone

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    Fluid Sampling Analysis

    Chromatographic

    Phase Diagram

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    Reservoir Characterization

    Static Model

    Dynamic Model

    Volumetric OIP

    Well Planning

    Updated Reserves

    Production Optimization

    Source Internet

    Geophysicist

    Geologist Geochemist

    Reservoir Engineer

    Production Engineer

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    Completion and Production

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    Environmental Management

    Fluid Environmental Services

    Control Control deSlidos

    de Slidos

    Control de

    Slidos

    Procesamiento de

    Cortes

    Procesamiento

    de Lquidos

    Re-inyeccin de

    cortes y

    Transporte

    Disposicinde

    Desechos

    Central de

    Procesamiento

    Limpiezade

    Tanques

    Control of solids in MudCentrifuge

    Selective Flocculation

    Mud dehydrationDecantation

    Flocculation

    Chemical mixing

    Centrifugation

    Dilution

    Solids disposalLiquid Treatment

    Mud Dehydration

    Water treatment

    Chemical mixing

    Fluids Transfer

    Disposal

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    Problems while drilling

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    Deep Water Horizon Safety

    Deepwater Horizonexplosion and blowout

    An explosion on the drilling rig

    Deepwater Horizonoccurred on April 20,

    2010, killing 11 workers.

    TheDeepwater Horizonsank on April 22,2010, in water approximately 5,000 feet

    (1,500 m) deep, and was located resting

    on theseafloorapproximately 1,300 feet

    (400 m) (about a quarter of a mile)

    northwest of the well.

    Source Internet Various

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    Chemical Industry Safety -Bhopal

    1984

    Eldesastre de Bhopal, ocurrido en1984en

    la regin deBhopal(India), se origin al

    producirse una fuga deisocianato de metilo

    en una fbrica de pesticidas.

    Se estima que entre 6.000 y 8.000 personas

    murieron en la primera semana tras el

    escape txico y al menos otras 12.000

    fallecieron posteriormente como

    consecuencia directa de la catstrofe,

    que afect a ms de 600.000 personas,

    150.000 de las cuales sufrieron graves

    secuelas..

    De Wikipedia, la enciclopedia libre

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    Colombia - Overview