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Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no mixing with environment. Pressure inside = pressure outside
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Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Dec 21, 2015

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Page 1: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2011 R. R. Dickerson & Z.Q. Li

1

Continuing to build a cloud model:Consider a wet air parcel

Parcel boundary

As the parcel moves assume no mixing with environment.

Pressure inside = pressure outside

Page 2: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

2

We have already considered a dry parcel, now consider a parcel just prior to saturation (the book leaves out several steps):

mass of parcel = md + mv = mp

Suppose we expand the parcel reversibly and adiabatically and condense out some mass of liquid = mL, keeping total mass constant.

mp = md + mv’ + mL

or mL + mv‘= mv

Where mv’ is the new mass of vapor in the parcel.

Page 3: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

3

mL = mv - mv’

Let the mass ratio of liquid to dry air be .

example. for this Let wwmm

d

L

Since for this small change, w is the sum of water vapor and liquid; at w’, the parcel is saturated.

sww

Consider the initial state to be just saturated:

sdwd This is Eq. 2.37 in Rogers and Yau.

Page 4: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

4

Define to be the adiabatic liquid water content, and dis the increase in adiabatic liquid water mixing ratio. increases from the LCL where it is zero to….

= ws(Tc,pc) - ws(T,p) at any other level.

Define the parcel total water mixing ratio QT:

QT = ws +

QT is conserved in a closed system (the book uses just Q).

Page 5: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

5

Consider an adiabatic displacement of a saturated parcel. Assume a reversible process with total mass conserved. The specific (per kg) entropy of cloudy air and vapor will be:

T

wLdwdd

T

wLw

T

L

w

svwsd

svwsd

vwv

wvd

)(

)(

Page 6: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

6

The system is closed so we can consider an isentropic process:

PdP

RTdT

T

swvL

TdT

pd

wTd

www

cd

ddQd

ccd

d

'

where

airdry for Remember

0

liquid ofheat specific

0

Page 7: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

7

T

swvL

T

swvL

T

swvL

T

swvL

dPTd

dPBdTAd

dPRdTdcQc

dPRdTdQcTdc

Bd

A

d

dwTp

dTwp

)ln(ln0

lnln0

lnln)(0

lnlnln0

Adding together the entropy changes with temperature for dry and wet air with the entropy of evaporation, setting total entropy change to zero:

Page 8: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

8

With further rearrangement:

constant exp

0expln

0ln)(ln

)(

)/('

wcQcT

wL

Tp

svcQcRd

d

svdA

B

wTp

AB

TP

TPd

AT

wLdPdTd

ATswvL

Page 9: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

9

Wet, Equivalent Potential Temperature, q

and Equivalent Potential Temperature, e.

θq is the temperature a parcel of air would reach if all of the latent heat were converted to sensible heat by a reversible adiabatic expansion to w = 0 followed by a dry adiabatic compression to 1000 hPa.

Page 10: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

10

Because the previously derived quantity is a constant, we may define

)(

1000

)(

exp

exp1000

)/(

)/(/

wcQcT

wL

dPso

wcQcT

wL

Tp

sv

wcTQpcR

q

Tp

svcQcRd

ARq

T

TP wTp

Page 11: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

11

Equivalent Potential Temperature e

If one assumes the latent heat goes only to heat dry air and not H2O, this is called a pseudo adiabatic process. Set QT = 0, then one obtains the equation for the equivalent potential temperature.

Page 12: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

12

Pseudoadiabatic Process

Consider a saturated parcel of air. Expand parcel from T, p, wo …

…to T+dT, p+dp, wo+dwo

(note: dT, dp, dwo are all negative)

This releases latent heat = - Lvdwo

Assume this all goes to heating dry air, and not into the water vapor, liquid, or solid (rainout) .

Page 13: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

13

AssumeAssume all condensation products fall out of parcel immediately.

op

v

p

pov

d

sd

ddpov

dwTc

L

p

dp

c

R

T

dT

p

dpRTdTcdwL

dpepddp

dpdTcqddwL

or

p

RT

)(

Page 14: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

14

process. baticpseudoadia afor get we

' using

)/'(

lnlnlnln

1000;hat Remember t/'

op

v

op

v

p

p

o

o

cR

o

dwTc

Ld

dwTc

L

p

dp

c

R

T

dT

cRkp

dpk

d

T

dTor

pkpkT

hPapp

pTp

Since dw0 < 0, increases for a pseudoadiabatic process.

Page 15: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

15

T

wd

c

Ld

T

wd

T

dw

o

p

v

oo

Hess) (see

Integrate from the condensation level

where T = Tc, original o

to a level where ws ~ 0

Page 16: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

16

Use of Equivalent Potential Temperaturee

e is the temperature that a parcel of air would have if all of its latent heat were converted to sensible heat in a pseudoadiabatic expansion to low pressure, followed by a dry adiabatic compression to 1000 hPa. e is conserved in both adiabatic and pseudoadiabatic processes. See Poulida et al., JGR, 1996.

cp

sve Tc

wLexp

Page 17: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

17

Adiabatic Equivalent Temperature Tea

Adiabatic equivalent temperature (also known as pseudoequivalent temperature): The temperature that an air parcel would have after undergoing the following process: dry-adiabatic expansion until saturated; pseudoadiabatic expansion until all moisture is precipitated out; dry- adiabatic compression to the initial pressure. Glossary of Met., 2000.

Page 18: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

18

Adiabatic Equivalent Temperature Tea

Instead of compressing to 1000 hPa, we go instead to the initial pressure.

k

pTwhile

k

pT

Tc

wLTT

eae

cp

svea

1000

1000 i.e.,

exp

Page 19: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

19

Note:

J/kg 10x5.2~L

KJ/kg 10~6

v

3 pc

Kc

L

p

v 310x5.2~

Since T is in the range of 200-300 K and wo is generally < 20 x 10-3

epp

ovea

op

ov

Tc

wLTTThus

lessorwTc

wL

~,

.2.0~10~

Generally Tea and Tep (equivalent potential

temp) are within 5o C.

Page 20: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

20

Additional Temperature Definitions

Wet Bulb Potential Temperature w

Defined graphically by following pseudo/saturated adiabats to 1000 hPa from Pe, Tc.

This temp is conserved in most atmos. processes.

Adiabatic Wet Bulb Temperature Twa (or Tsw)Follow pseudo/saturated adiabats from Pe, Tc to initial pressure.

|Tw- Twa| ~ 0.5o or less.

Page 21: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

21

Conservative Properties of Air Parcels

C NC

e C C

w C C

Td NC NC

Tw NC NC

w C NC

T* NC NC

Te NC NC

Tc C NC

f NC C

q C C

Variable dry adiabatic saturated/pseudo adiabatic

Page 22: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

22

Remember Thermodynamic Diagrams (lecture 4)

A true thermodynamic diagram has Area Energy

T

RlnP

isotherms

isobars

Emagram

T

lnP

Dry adiabats

T-gram

Page 23: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

23

In the U.S. a popular meteorological thermodynamic diagram is the Skew T – LogPSkew T – LogP diagram:

y = -RlnPx = T + klnP

k is adjusted to make the angle between isotherms and dry adiabats nearly 90o.

See Hess for more complete information.

Page 24: Copyright © 2011 R. R. Dickerson & Z.Q. Li 1 Continuing to build a cloud model: Consider a wet air parcel Parcel boundary As the parcel moves assume no.

Copyright © 2010 R. R. Dickerson & Z.Q. Li

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