International Journal of Basic & Applied Sciences IJBAS-IJENS Vol:12 No:06 109 126206-8585- IJBAS-IJENS @ December 2012 IJENS I J E N S Abstract -- The raw materials, clinker, and cement from the Mass cement factory in Sulaimani City- Kurdistan Region NE- Iraq have been investigated using polarizing microscopy, X-ray diffraction (XRD), Scanning Electron Microscopy SEM and chemical analysis. This study will discuss about the composition and phases mineral variation from different sample type of the factory. Chemical composition analysis using X-ray fluorescence is one of the important quality analyses for examining of cement and widely used in cement industries for a long time as a tool to estimate phase composition. X-ray diffraction is one of the established techniques as a qualitative tool to identify phase existing in the sample. Microscopic invistigation and X-ray diffraction of clinkers from Mass factory indicating the presence of five principle constitutes alite,(C 3 S ), belite (C 2 S), aluminate (C 3 A) , ferrite (C 4 AF), as well as minor isotropic residue (Periclase, and free- lime). The obtained SEM – micrographs show alite with well developed external shape and hexagonal outline and it is larger than the other existing phase while belite is semi rounded and irregular outline phase. The chemical analyses of raw materials used in Mass cement factory indicate that the local raw materials are suitable for cement industry after addition some additive such as iron oxide and sandstone. The chemical and mineralogical analyses for studied clinker samples show that the dominant phases composition are C 3 S and C 2 S while the C 3 A and C 4 AF are less abundant. Transformation of mineral phases is found affected by different temperature during cement production. The different types of mineral phases are observed during the production. Index Term-- Portland cement, Mass Factory, Raw material, Clinker, Phase composition I. INT RODUCT ION Portland cement is a hydraulic material composed primary of calcium silicates, aluminates, and ferrites. In a rotary kiln, at temperature reaching the 1450 ◦ C, clinker nodules are produced from a finely ground, homogenized blend of limestone, shale . and iron ore. The nodules are subsequently ground with gypsum, which serves to control setting, to a fine powder to produce finished Portland cement. The composition and texture (crystal size, abundance, and distribution) of clinker phases result from complex interactions of raw feed chemical and mineralogical composition, particle size distribution, feed homogenization, and the heating and cooling regime [1] and [2]. In order to simplify these phenomena, [3] proposed an approach for the development of the clinker phases. The ferric oxide (Fe 2 O 3 ) reacts with aluminum oxide (Al 2 O 3 ) and lime (CaO) to form the tetracalcium alumino ferrite (Ferrite C 4 AF or Ca 4 Al 2 Fe 2 O 10 ). The remaining aluminum oxide reacts with lime to form the tricalcium aluminates (C 3 A or Ca 3 Al 2 O 6 ). The lime reacts with the silicate oxide (SiO 2 ) to form two calcium silicates phases, the dicalcium silicate (Belite, C 2 S or Ca 2 SiO 4 ) and tricalcium silicate (Alite, C 3 S or Ca 3 SiO 5 ). One of the important quality parameters of Portland cement is its chemical and phase composition. It is necessary to determine a complete mineralogy of clinker cement to correctly understand, interpret and predict the outcome of any plant production process [4], and [5]. Every year a huge amount of Portland cement is produced and used for the construction of building, roads and highways and other local purposes in Kurdistan Region Northeast Iraq. Cement industry of Sulaimani City has been established and expanded very rapidly in the last six years, before that period, two cement companies have been established (Serchinar and Tasluja cement companies). Today, the industry comprises another two production sites (Bazian and Mass cement companies) beside the Tasluja cement company. The Serchinar cement company now stopped production of cement because it is located inside the population area. In order to understand phase transformation of mineral phases in clinker and powdered cement after mixing with gypsum for about 5 %, a feasibility study was carried out for seven samples of clinker and seven samples of powdered cement, from Mass Cement Company. Quantitative and qualitative analyses had done to understand correlation between phase estimation using Bogue calculation and mineral phase existing in the samples. Composition and phase mineral variation of Portland cement in Mass Factory Sulaimani – Kurdistan Region NE- Iraq Tola Ahmed Mirza Mohammed Department of Geology, Faculty of Science and Science Education, School of Science, University of Sulaimnai Email: [email protected]
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Composition and phase mineral variation of Portland cement in Mass Factory Sulaimani
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International Journal of Basic & Applied Sciences IJBAS-IJENS Vol:12 No:06 109
126206-8585- IJBAS-IJENS @ December 2012 IJENS I J E N S
Abstract-- The raw materials, clinker, and cement from the
Mass cement factory in Sulaimani City- Kurdistan Region NE-
Iraq have been investigated using polarizing microscopy, X-ray
diffraction (XRD), Scanning Electron Microscopy SEM and
chemical analysis. This study will discuss about the composition
and phases mineral variation from different sample type of the
factory. Chemical composition analysis using X-ray
fluorescence is one of the important quality analyses for
examining of cement and widely used in cement industries for a
long time as a tool to estimate phase composition. X-ray
diffraction is one of the established techniques as a qualitative
tool to identify phase existing in the sample. Microscopic
invistigation and X-ray diffraction of clinkers from Mass factory
indicating the presence of five principle constitutes alite,(C3S),
belite (C2S), aluminate (C3A) , ferrite (C4AF), as well as minor
isotropic residue (Periclase, and free- lime). The obtained SEM
– micrographs show alite with well developed external shape
and hexagonal outline and it is larger than the other existing
phase while belite is semi rounded and irregular outline phase.
The chemical analyses of raw materials used in Mass cement
factory indicate that the local raw materials are suitable for
cement industry after addition some additive such as iron oxide
and sandstone. The chemical and mineralogical analyses for
studied clinker samples show that the dominant phases
composition are C3S and C2S while the C3A and C4AF are less
abundant. Transformation of mineral phases is found affected
by different temperature during cement production. The
different types of mineral phases are observed during the
production.
Index Term-- Portland cement, Mass Factory, Raw material,
Clinker, Phase composition
I. INTRODUCTION
Portland cement is a hydraulic material composed primary of
calcium silicates, aluminates, and ferrites. In a rotary kiln, at
temperature reaching the 1450◦C, clinker nodules are produced
from a finely ground, homogenized blend of limestone, shale
.
and iron ore. The nodules are subsequently ground with
gypsum, which serves to control setting, to a fine powder to
produce finished Portland cement. The composition and
texture (crystal size, abundance, and distribution) of clinker
phases result from complex interactions of raw feed chemical
and mineralogical composition, particle size distribution, feed
homogenization, and the heating and cooling regime [1] and
[2]. In order to simplify these phenomena, [3] proposed an
approach for the development of the clinker phases. The ferric
oxide (Fe2O3) reacts with aluminum oxide (Al2O3) and lime
(CaO) to form the tetracalcium alumino ferrite (Ferrite C4AF or
Ca4Al2Fe2O10). The remaining aluminum oxide reacts with lime
to form the tricalcium aluminates (C3A or Ca3Al2O6). The lime
reacts with the silicate oxide (SiO2) to form two calcium silicates
phases, the dicalcium silicate (Belite, C2S or Ca2SiO4) and
tricalcium silicate (Alite, C3S or Ca3SiO5).
One of the important quality parameters of Portland cement is
its chemical and phase composition. It is necessary to
determine a complete mineralogy of clinker cement to correctly
understand, interpret and predict the outcome of any plant
production process [4], and [5]. Every year a huge amount of
Portland cement is produced and used for the construction of
building, roads and highways and other local purposes in
Kurdistan Region Northeast Iraq. Cement industry of
Sulaimani City has been established and expanded very rapidly
in the last six years, before that period, two cement companies
have been established (Serchinar and Tasluja cement
companies). Today, the industry comprises another two
production sites (Bazian and Mass cement companies) beside
the Tasluja cement company. The Serchinar cement company
now stopped production of cement because it is located inside
the population area.
In order to understand phase transformation of mineral phases
in clinker and powdered cement after mixing with gypsum for
about 5 %, a feasibility study was carried out for seven
samples of clinker and seven samples of powdered cement,
from Mass Cement Company. Quantitative and qualitative
analyses had done to understand correlation between phase
estimation using Bogue calculation and mineral phase existing
in the samples.
Composition and phase mineral variation of
Portland cement in Mass Factory Sulaimani –
Kurdistan Region NE- Iraq
Tola Ahmed Mirza Mohammed Department of Geology, Faculty of Science and Science Education, School of Science, University of Sulaimnai