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    WATERFLOODING

    By

    William M. Cobb

    James T. Smith

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    05/11

    COPYRIGHT

    By

    William M. Cobb & Associates, Inc.

    12770 Coit Road, Suite 907

    Dallas, TX 75251

    Telephone: (972) 385-0354

    Fax: (972) 788-5165E-Mail: [email protected]

    ALL RIGHTS RESERVED

    This book, or any part thereof, may not be reproduced

    in any form without permission of William M. Cobb & Associates, Inc.

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    iii

    TABLE OF CONTENTS

    PAGE

    I. INTRODUCTION

    The End of Primary Depletion ................................................................. 1-2Factors Controlling Waterflood Recovery .............................................. 1-3

    Waterflooding versus Pressure Maintenance ......................................... 1-5

    Other References ....................................................................................... 1-6

    II. REVIEW OF ROCK PROPERTIES AND FLUID FLOW

    Wettability .................................................................................................. 2-1

    Definition............................................................................................... 2-1

    Importance ............................................................................................ 2-3

    Determination ....................................................................................... 2-4

    Factors Affecting Reservoir Wettability ............................................ 2-5

    Sandstone and Carbonates .................................................................. 2-6

    Native-State, Cleaned, and Restored-State Cores............................. 2-6

    Capillary Pressure ..................................................................................... 2-7

    Definition............................................................................................... 2-7

    Importance ............................................................................................ 2-7

    Sources of Data ..................................................................................... 2-7

    Effect of Reservoir Variables .............................................................. 2-9

    Fluid Saturation ............................................................................... 2-9

    Saturation History ........................................................................... 2-10

    Pore Geometry ................................................................................. 2-11Averaging of Data ................................................................................ 2-11

    J-function ......................................................................................... 2-12

    Correlate with Permeability ........................................................... 2-14

    Relative Permeability ................................................................................ 2-17

    Definition............................................................................................... 2-17

    Air Permeability .............................................................................. 2-18

    Absolute Permeability ..................................................................... 2-18

    Effective Permeability ..................................................................... 2-18

    Relative Permeability ...................................................................... 2-18

    Importance ............................................................................................ 2-19Sources of Data ..................................................................................... 2-19

    Effect of Reservoir Variables .............................................................. 2-20

    Saturation History ........................................................................... 2-20

    Wettability ........................................................................................ 2-21

    End-Point Values ................................................................................. 2-23

    Averaging of Data ................................................................................ 2-24

    PAGE

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    Date Averaging Methods ................................................................ 2-24

    Adjust Average Data to Account for Different Irreducible

    Water Saturations ......................................................................... 2-25

    Default Relative Permeability Relationships ..................................... 2-29

    Problem ...................................................................................................... 2-38

    III. WATERFLOODABLE OIL IN PLACE

    Oil Saturation ............................................................................................. 3-2

    Porosity ....................................................................................................... 3-6

    Net Pay ........................................................................................................ 3-8

    Net Pay Determination Using Air Permeability versus Oil

    Permeability ....................................................................................... 3-12

    Net Pay Determination after Accounting for Data Scatter .............. 3-18

    George and Stiles Fieldwide Net Pay Method .............................. 3-19

    George and Stiles Individual Well Net Pay Method

    (Net to Gross Method) ................................................................... 3-24

    Waterflood Permeability Cutoff Determination Using a

    Water Cut Method ............................................................................ 3-29

    Comparison of Original Oil-In-Place Material Balance Versus

    Volumetric Estimates ........................................................................ 3-40

    Primary Production Net Pay versus Secondary Floodable

    Net Pay ............................................................................................... 3-41

    Summary .................................................................................................... 3-45

    Problems ..................................................................................................... 3-47

    IV. MECHANISM OF IMMISCIBLE FLUID DISPLACEMENT

    Introduction ............................................................................................... 4-1

    Reservoir Response Incompressible vs. Slightly Compressible

    Liquids ..................................................................................................... 4-5

    Fractional Flow Equation ......................................................................... 4-8

    Effect of Wettability ............................................................................. 4-17

    Effect of Formation Dip and Direction of Displacement.................. 4-19

    Effect of Capillary Pressure ................................................................ 4-20

    Effect of Oil and Water Mobilities ..................................................... 4-21Effect of Rate ........................................................................................ 4-22

    Variations of Fractional Flow Equation ............................................ 4-23

    Frontal Advance Equation ....................................................................... 4-24

    Welge Analysis of the Buckley-Leverett Theory in Linear Systems .... 4-26

    Welge Method Saturation at Flood Front ...................................... 4-27

    PAGE

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    Welge Method Average Water Saturation ..................................... 4-30

    Performance at Water Breakthrough ........................................... 4-32

    Performance after Breakthrough .................................................. 4-40

    Application to Radial Flow ................................................................. 4-47

    Effect of Free Gas Saturation ............................................................. 4-48

    Production Performance................................................................. 4-55Displacement Efficiency .................................................................. 4-55

    Conditions for Development of an Oil Bank ................................ 4-56

    Properties Fluid PVT ............................................................................. 4-59

    Reservoir Pressure Distribution ............................................................... 4-64

    Maintain Optimum Reservoir Pressure to Minimize orS ................... 4-74

    Gravity Under-Running ............................................................................ 4-75

    Summary .................................................................................................... 4-76

    Appendix A Development of Frontal Advance Equation ................... 4-79

    Appendix B Buckley-Leverett Theory .................................................. 4-83

    Buckley-Leverett Theory ..................................................................... 4-83Stabilized Zone Concept ...................................................................... 4-85

    Welge Solution to Buckley-Leverett ................................................... 4-89

    Water Saturation at the Front ....................................................... 4-89

    Average Water Saturation ............................................................. 4-92

    Problems ..................................................................................................... 4-98

    V. FLOOD PATTERNS AND AREAL SWEEP EFFICIENCY

    Introduction ............................................................................................... 5-1

    Mobility Ratio ............................................................................................ 5-1Water Displacing Oil ........................................................................... 5-2

    Water-Oil Mobility Ratio after Breakthrough ................................. 5-6

    Oil Displacing Gas ................................................................................ 5-7

    Basic Flood Patterns .................................................................................. 5-9

    Direct Line Drive .................................................................................. 5-10

    Staggered Line Drive ........................................................................... 5-11

    Five-Spot ............................................................................................... 5-12

    Nine-Spot............................................................................................... 5-13

    Seven-Spot............................................................................................. 5-14

    Areal Sweep Efficiency ............................................................................. 5-15

    Causes and Effects ............................................................................... 5-16

    Areal Sweep Efficiency at Breakthrough ................................................ 5-23

    Isolated Pattern ............................................................................... 5-24

    PAGE

    Developed Pattern ........................................................................... 5-24

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    Normal Pattern ................................................................................ 5-24

    Inverted Pattern ................................................................................... 5-24

    Areal Sweep Efficiency after Breakthrough ..................................... 5-29

    Effect of Free Gas Saturation on Areal Sweep .................................. 5-37

    Water Zone ...................................................................................... 5-37

    Oil Zone (Oil Bank) ......................................................................... 5-38Re-Saturation Effects ...................................................................... 5-42

    Other Factors Affecting Areal Sweep Efficiency .............................. 5-43

    Fractures .......................................................................................... 5-43

    Directional Permeability ................................................................. 5-43

    Areal Permeability Variations ....................................................... 5-44

    Formation Dip ................................................................................. 5-44

    Off-Pattern Wells ............................................................................ 5-44

    Sweep Beyond Edge Wells .............................................................. 5-45

    Isolated Patterns .............................................................................. 5-45

    Irregularly Spaced Wells ................................................................ 5-46

    Peripheral and Line Floods ...................................................................... 5-47

    Selection of Waterflood Pattern ............................................................... 5-48

    Summary .................................................................................................... 5-49

    Problems ..................................................................................................... 5-51

    VI. INJECTION RATES AND PRESSURES

    Factors Affecting Water Injection Rate .................................................. 6-1

    Radial System, Unequal Mobilities .......................................................... 6-2

    Regular Patterns ........................................................................................ 6-6

    Unit Mobility Ratio .............................................................................. 6-6Non-Unit Mobility Ratio ...................................................................... 6-10

    Regular Patterns, Unequal Mobilities ................................................ 6-16

    Injectivity in Five-Spot Patterns .............................................................. 6-16

    Prats, et al Method ............................................................................... 6-16

    Craig Method........................................................................................ 6-17

    Problem ...................................................................................................... 6-20

    VII. RESERVOIR HETEROGENEITY

    Areal Permeability Variations ................................................................. 7-1Detection of Areal Permeability Variations ...................................... 7-2

    Effect of Areal Permeability Variations ............................................ 7-3

    Vertical Permeability Variations ............................................................. 7-3

    PAGE

    Detection of Stratification ................................................................... 7-4

    Quantitative Evaluation of Permeability Stratification ................... 7-4

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    Single-Value Representation .......................................................... 7-5

    Permeability Variation ................................................................... 7-6

    Stiles Permeability Distribution ..................................................... 7-14

    Lorentz Coefficient .......................................................................... 7-20

    Miller-Lents Permeability Distribution ........................................ 7-21

    Selection of Layers ............................................................................... 7-24Geological Zonation ........................................................................ 7-25

    Natural Barriers .............................................................................. 7-25

    Equal Thickness............................................................................... 7-25

    Equal Flow Capacity ....................................................................... 7-25

    Statistical Zonation ......................................................................... 7-25

    Effect of Crossflow between Layers ................................................... 7-26

    Vertical Sweep Efficiency ......................................................................... 7-26

    Mobility Ratio ....................................................................................... 7-27

    Crossflow............................................................................................... 7-27

    Gravity Forces ...................................................................................... 7-27

    Capillary Forces ................................................................................... 7-27

    Problems ..................................................................................................... 7-29

    VIII. PREDICTION OF WATERFLOOD PERFORMANCE

    Simple Methods ......................................................................................... 8-1

    Analogy ................................................................................................. 8-2

    Rules of Thumb .................................................................................... 8-3

    Empirical Relationships ...................................................................... 8-3

    Reservoir Stratification ............................................................................. 8-3

    Dykstra-Parsons Method ..................................................................... 8-5Stiles Method ........................................................................................ 8-8

    Flow Capacity (C) and Permeability Distribution (k) ................. 8-9

    Vertical Sweep Efficiency (Ev) ........................................................ 8-12

    Water Cut and Water-Oil Ratio .................................................... 8-14

    Oil and Water Producing Rates ..................................................... 8-16

    Cumulative Oil Recovery ............................................................... 8-17

    Procedure for Predicting Performance ......................................... 8-18

    Confined Patterns with Stratification, Areal Sweep, and

    Displacement Methods ............................................................................ 8-18

    Numerical Simulation ............................................................................... 8-20

    PAGE

    CGM CRAIG-GEFFEN-MORSE METHOD

    Introduction .......................................................................................... CGM-1

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    Initial Calculations - Single Layer ...................................................... CGM-3

    Stage 1: Performance Prior To Interference .................................... CGM-7

    Stage 2: Performance from Interference To Fillup ......................... CGM-12

    Stage 3: Performance from Fillup To Breakthrough ...................... CGM-15

    Stage 4: Performance after Water Breakthrough ........................... CGM-18

    Multi-Layer Performance ................................................................... CGM-35Problems ............................................................................................... CGM-40

    IX. WATERFLOOD SURVEILLANCE

    Introduction ............................................................................................... 9-1

    Production and Injection Test Analyses .................................................. 9-2

    Maps ...................................................................................................... 9-2

    Production Well Test Procedures ....................................................... 9-3

    Production and Injection Trend Analysis ......................................... 9-3

    Production Wells ............................................................................. 9-4

    Coordinate Graph ..................................................................... 9-5

    Exponential Decline Curves (and Hyperbolic and

    Harmonic) ............................................................................... 9-6

    Injection Wells ................................................................................. 9-9

    Patterns ............................................................................................ 9-10

    Voidage Replacement Ratio (VRR) (Monthly and

    Cumulative)................................................................................... 9-12

    Spaghetti Graph .............................................................................. 9-14

    Water/Oil Ratio Plot ....................................................................... 9-18

    Oil Cut .............................................................................................. 9-20

    X Plot ................................................................................................ 9-21Oil Cut versus Cumulative Production (Coordinate Graph)...... 9-24

    Recovery Factor versus Hydrocarbon Pore Volumes Injected .. 9-25

    Multiple Trend Forecasting With Field Production

    Constraints .................................................................................... 9-27

    Summary of Production Graphs .................................................... 9-27

    Pressure Transient Testing ....................................................................... 9-28

    Pressure Buildup and Pressure Falloff Testing ................................ 9-29

    Step Rate Test ....................................................................................... 9-30

    Hall Method of Analyzing Injection Well Behavior ......................... 9-37

    PAGE

    Pattern Balancing ...................................................................................... 9-45

    Volumetric Sweep Efficiency .................................................................... 9-58

    Injection Profile Testing ........................................................................... 9-75

    Interval Selection for Waterflood Monitoring ........................................ 9-78

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    Injection Profiles ........................................................................................ 9-80

    Alteration of Injection Profiles ................................................................. 9-84

    Flood Front (Bubble) Maps ...................................................................... 9-85

    Injection Analysis ...................................................................................... 9-91

    Analysis Without Free Gas ( 0Sg ) ................................................... 9-93

    Analysis With Free Gas ( 0Sg ) ........................................................ 9-101Numerical Simulation .......................................................................... 9-114

    Water Testing Program ............................................................................ 9-115

    Dissolved Gases .................................................................................... 9-115

    Microbiological Growth ...................................................................... 9-116

    Minerals ................................................................................................ 9-116

    Total Solids ........................................................................................... 9-116

    Produced Water ................................................................................... 9-117

    Pie Charts ................................................................................................... 9-117

    Integrated Waterflood Monitoring .......................................................... 9-119

    Project Review ........................................................................................... 9-124Problem ...................................................................................................... 9-129

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    INTRODUCTION

    Waterflooding is the most widely used fluid injection process in the world today. It has

    been recognized1 since 1880 that injecting water into an oil-bearing formation has the

    potential to improve oil recovery. However, waterflooding did not experience fieldwide

    application until the 1930s when several injection projects were initiated,2,3

    and it was not

    until the early 1950s that the current boom in waterflooding began. Waterflooding is

    responsible for a significant fraction of the oil currently produced in the world. In fact, in

    the 21st century, most operators begin to investigate the feasibility of water injection

    within a short time following the initial field discovery.

    Many complex and sophisticated enhanced recovery processes have been developed

    through the years in an effort to recover the enormous oil reserves left behind by

    inefficient primary recovery mechanisms. Many of these processes have the potential to

    recover more oil than waterflooding in a particular reservoir. However, no process has

    been discovered which enjoys the widespread applicability of waterflooding. The

    primary reasons why waterflooding is the most successful and most widely used oil

    recovery process are4,5,6

    :

    general availability of water

    low cost relative to other injection fluids

    ease of injecting water into a formation

    high efficiency with which water displaces oil

    The purpose of these notes is to discuss the reservoir engineering aspects of

    waterflooding. It is intended that the reader will gain a better understanding of the

    processes by which water displaces oil from a reservoir and, in particular, will gain the

    ability to calculate the expected recovery performance and to manage the project to

    maximize oil recovery with a minimum number of wellbores and injection volumes.

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    While written materials will be limited to the displacement of oil by water, the

    displacement processes and computational techniques presented have application to other

    oil recovery processes.

    I.

    The End of Primary Depletion.If the cumulative water injection exceeds the cumulative production since the start

    of injection, the reservoir pressure is no longer declining and in most instances

    reservoir pressure begins to increase. For each time period (usually on a monthly

    basis) in which the injection equals or exceeds production, measured at reservoir

    conditions, the average reservoir pressure is maintained or increased. In those

    instances where average pressure is maintained or increased, the primary depletion

    stops. This is due to the fact that the predominate primary drive mechanisms

    including liquid or rock expansion, gas evolving from solution, gas cap expansion,

    or natural water influx are the result of declining reservoir pressure. When pressure

    is being maintained or increased, these primary drive mechanisms no longer

    function.

    During the time of constant or increasing reservoir pressure resulting from water

    injection, oil recovery is the result of a displacementprocess. It should be clear that

    it is possible within localized areas of the field to have situations where injection

    may be greater than production (pressure increasing) and in other areas injection

    may be less than production (pressure declining). In those areas where injection is

    less than production and where average reservoir pressure is only being partially

    maintained, the reservoir is experiencing a combination of pressure depletion and

    fluid displacement. When both recovery processes occur simultaneously, reservoir

    analysis is very complicated and usually must be analyzed using a finely gridded

    numerical simulation model which has been properly history matched with field

    conditions.

    The injection to production ratio on a pattern or fieldwide basis is frequently

    referred to as the voidage replacement ratio (VRR). Reservoir voidage is measured

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    at reservoir conditions and includes oil, water, and free gas production. As a

    reminder, the free gas production should not be assumed negligible. Failure to

    account for free gas in the voidage computation can be a major flaw in computing

    total reservoir voidage.

    II. Factors Controlling Waterflood Recovery

    Oil recovery due to waterflooding can be determined at any time in the life of a

    waterflood project if the following four factors are known.

    A.Oil-in-Place at the Start of Waterflooding-- The oil-in-place at the time of initial

    water injection is a function of the floodable pore volume and the oil saturation.

    Floodable pore volume is highly dependent on the selection and application of net

    pay discriminators such as permeability (and porosity) cutoffs. A successful

    flood requires that sufficient oil be present to form an oil bank as water moves

    through the formation. An accurate prediction of waterflood performance or the

    interpretation of historical waterflood behavior can only be made if a reliable

    estimate of oil-in-place at the start of waterflooding is available. Oil-in-place

    considerations are discussed in Chapter 3.

    B.

    Areal Sweep Efficiency-- This is the fraction of reservoir area that the water willcontact. It depends primarily upon the relative flow properties of oil and water,

    the injection-production well pattern used to flood the reservoir, pressure

    distribution between the injection and production wells, and directional

    permeability. The prediction of areal sweep efficiency will be discussed in

    Chapter 5.

    C.Vertical Sweep Efficiency-- Vertical sweep refers to the fraction of a formation

    in the vertical plane which water will contact. This will depend primarily upon

    the degree of vertical stratification existing in the reservoir and will be discussed

    in Chapter 6.

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    D.Displacement Sweep Efficiency-- This represents the fraction of oil which water

    will displace in that portion of the reservoir invaded by water. Chapter 4 will

    discuss methods of determining the displacement sweep efficiency.

    Methods for predicting oil recovery by waterflooding will be presented in Chapter 8.

    The cumulative displaced waterflood oil can be computed at any time in the life of a

    waterflood project from the following general equation:

    D A V D

    N N E E E (Eq. 1.1)

    where

    N = the oil in place in the floodable pore volume at the start of waterinjection, STBE = the fraction of the floodable pore volume area swept by the injected

    water

    VE = the fraction of the floodable pore volume in the vertical planeswept by the injected water

    DE = the fraction of the oil saturation at the start of water injectionwhich is displaced by water in that portion of the reservoir

    invaded by water

    If at the start of water injection, a free gas saturation has not formed within the oil

    column, it can be assumed that the displaced waterflood oil is approximately equal

    to waterflood oil production. However, if at the start of injection, reservoir

    pressure has declined below the initial bubble point pressure and a free gas

    saturation has been developed, then the displaced oil described in Eq. 1.1 is less

    than the produced waterflood oil. This subject is described in more detail in

    Chapter 4.

    Waterflood recovery is dependent on a number of variables. The variables which

    usuallyhave the greatest impact on waterflood behavior are listed below:

    | Oil saturation at the start of waterflooding, oS

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    Residual oil saturation to waterflooding, ( )or orwS S

    Connate water saturation, wcS

    Free gas saturation at the start of water injection, gS

    Water floodable pore volume, pV , BBLS (This takes into account the

    permeability or porosity net pay discriminator)

    Oil and water viscosity, o and w

    Effective permeability to oil measured at the immobile connate water saturation,

    ( ) Swirok

    Relative permeability to water and oil, rwk and rok

    Reservoir stratification, (Dykstra-Parsons coefficient, V )

    Waterflood pattern (symmetrical or irregular)

    Pressure distribution between injector and producer

    Injection rate, BWPD

    Oil formation volume factor, o

    Economics

    III. Waterflooding versus Pressure Maintenance

    Maximum combined primary and secondary oil recovery occurs when waterflooding

    is initiated at or near the initial bubble point pressure. When water injection

    commences at a time in the life of a reservoir when the reservoir pressure is at a high

    level, the injection is frequently referred to as a pressure maintenance project. On

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    the other hand, if water injection commences at a time when reservoir pressure has

    declined to a low level due to primary depletion, the injection process is usually

    referred to as a waterflood. In both instances, the injected water displaces oil and is

    a dynamic displacement process. Nevertheless, there are important differences in

    the displacement process when water displaces oil at high reservoir pressures

    compared to the displacement process which occurs in depleted low pressure

    reservoirs. The differences in the displacement mechanisms will be discussed in

    Chapters 4 and 5.

    IV. Other References

    In June 2002, a search of the SPE e-library was conducted to obtain a listing of the

    technical papers on the subject of waterflooding which have been presented at SPE

    technical conferences or published in SPE journals. The listing is found at the end

    of this chapter.

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    CHAPTER 1 REFERENCES

    1.Carll, J.F.: The Geology of the Oil Regions of Warren, Venango, Clarion, and Butler

    Counties, Pennsylvania, Second Geological Survey of Pennsylvania (1880) III, pp.

    1875-1879.

    2.History of Petroleum Engineering, API, Dallas, Texas (1961).

    3.Fettke, C.R.: "Bradford Oil Field, Pennsylvania and New York," Pennsylvania

    Geological Survey, 4th Series (1938) M-21.

    4.Craig, F.F., Jr.: The Reservoir Engineering Aspects of Waterflooding, Monograph

    Series, SPE, Dallas, Texas (1971) 3.

    5.

    Willhite, G.P.: Waterflooding, Textbook Series, SPE, Dallas (1986) 3.

    6.Waterflooding, Reprint Series, SPE, Richardson, TX (2003) 56.

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    REVIEW OF ROCK PROPERTIES AND FLUID FLOW

    An understanding of the basic rock and fluid properties which control flow in a porous

    medium is a prerequisite to understanding how a waterflood performs and how a

    waterflood should be designed, implemented, and managed. The purpose of this sectionis not to teach the fundamentals of rock and fluid properties -- a basic knowledge of these

    is assumed. However, certain multiphase flow properties will be discussed as they apply

    to waterflood systems.

    I. Wettability

    A. Definition

    In a rock/oil/brine system, wettabilitycan be defined as the tendency of a fluid topreferentially adhere to, or wet, the surface of a rock in the presence of other

    immiscible fluids. In the case of a waterflood, the wetting phases can be oil or

    water; gas will often be present, but will not wet the rock. When the rock is

    water-wet, water occupies the small pores and contacts the rock surface in the

    large pores. The oil is located in the middle of the large pores. In an oil-wet

    system, the location of the two fluids is partlyreversed from the water-wet case.

    Water usually continues to fill the very small pores but oil contacts the majority of

    the rock surface in the large pores. The water present in the large pores in the oil

    wet rock is located in the middle of the pore, does not contact the large pore throat

    surface, and is usually present in small amounts. Water fills the smallest pores

    even in the oil-wet system because oil never enters the small pore system due to

    capillary forces and consequently, the wettability of the small pores is not

    expected to change.

    Wettability concepts and the location of oil and connate water in the larger pores

    can be illustrated with a simple diagram. Consider the "large" pore in Figure 2-1

    which contains both oil and water.

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    FIGURE 2-1

    PLANE VIEW, CROSS-SECTION VIEW, AND FLUID DISTRIBUTION IN A

    HYPOTHETICAL WATER-WET, OIL-WET, AND FRACTIONAL-WET PORE

    TORTUOUS PORE

    A

    A

    PORE CROSS-SECTION AT POSITION A-A

    WATER-WET OIL-WET FRACTIONAL-WET

    CONNATE WATER

    OIL

    It is important to note, however, that the term wettability is used for the wetting

    preference of the rock and does not necessarily refer to the fluid that is in contact

    with the rock at any given time. For example, consider a cleansandstone core

    that is saturated with a refined oil. Even though the rock surface is coated with

    oil, the sandstone core is still preferentially water-wet. Wettability is not a

    parameter that is used directly in the computation of waterflood performance.

    However, wettability can have a significant impact on such parameters as relative

    permeability, connate water saturation, residual oil saturation, and capillary

    pressure which directly affect waterflood performance. Anderson1-6

    published a

    series of excellent papers which discuss wettability and its impact on rock,

    saturation, and fluid flow behavior.

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    B. Importance

    The performance of a waterflood is controlled to a large extent by wettability.

    Reasons for this are:

    1.The wettability of the rock/fluid system is important because it is a major factor

    controlling the location, flow, and distribution of fluids in a reservoir. In

    general, one of the fluids in a porous medium of uniform wettability that

    contains at least two immiscible fluids will be the wetting fluid. When the

    system is in equilibrium, the wetting fluid will completely occupy the smallest

    pores and be in contact with a majority of the rock surface (assuming, of

    course, that the saturation of the wetting fluid is sufficiently high). The

    nonwetting fluid will occupy the centers of the larger pores and form globulesthat extend over several pores. Since wettability controls the relative position

    of fluids within the rock matrix, it controls their relative ability to flow. The

    wetting fluid, because of its attraction to the rock surface, is in an unfavorable

    position to flow. Furthermore, the saturation of the wetting fluid cannot be

    reduced below some irreducible value when flooded with another immiscible

    fluid. With all other things equal, a waterflood in a water-wet reservoir will

    yield a higher oil recovery at a lower water-oil ratio (WOR) than an oil-wet

    reservoir. Chapter 4 presents information that allows an engineer to quantify

    the effects of wettability on flood performance.

    2.Wettability affects the capillary pressure and relative permeability data used to

    describe a particular waterflood system. It is found, in measuring multiphase

    flow properties, that the direction of saturation change (saturation history)

    affects the measured properties. If measurements are made on a core while

    increasing the saturation of the wetting phase, this is referred to as the

    imbibition direction. Conversely, when the wetting phase saturation is

    decreased during a test, it is referred to as the drainage direction. Different

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    capillary pressure and relative permeability curves are obtained depending upon

    the direction of saturation change used in the laboratory to make measurements.

    The direction of saturation change used to determine multiphase flow properties

    should correspond to the saturation history of the waterflood. Thus, it is

    necessary to know the wettability of the reservoir. For example, a waterflood

    in a water-wet reservoir is an imbibition process; whereas in an oil-wet

    reservoir, it would be a drainage process. Different data would apply to these

    two situations.

    C. Determination

    Historically, all petroleum reservoirs were believed to be strongly water-wet. This

    was based on two major facts. First, most clean sedimentary rocks are strongly

    water-wet. Second, most reservoirs were deposited in aqueous environments into

    which oil later migrated. It was assumed that the connate water would prevent the

    oil from touching the rock surfaces.

    Reservoir rock can change from its original, strongly water-wet condition by

    adsorption of polar compounds and/or the deposition of organic matter originally

    in the crude oil. Some crude oils make a rock oil-wet by depositing a thick

    organic film on the mineral surfaces. Other crude oils contain polar compounds

    that can be adsorbed to make the rock more oil-wet. Some of these compounds

    are sufficiently water soluble to pass through the aqueous phase to the rock.

    The realization that rock wettability can be altered by absorbable crude oil

    components led to the idea that heterogeneous forms of wettability exist in

    reservoir rock. Generally, the internal surface of reservoir rock is composed of

    many minerals with different surface chemistry and adsorption properties, which

    may lead to variations in wettability. Fractional wettability is also called

    heterogeneous, spotted, or Dalmation wettability. In fractional wettability, crude

    oil components are strongly adsorbed in certain areas of the rock, so a portion of

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    the rock is strongly oil-wet, while the rest is strongly water-wet. Note that this is

    conceptually different from intermediate wettability which assumes all portions of

    the rock surface have a slight but equal preference to being wetted by water or oil.

    Several methods are available to determine the wettability of a reservoir rock.

    These methods have been detailed in the literature2,7,8

    and will not be discussed

    here. They are:

    Contact Angle

    Imbibition -- Displacement Core Tests

    Capillary Pressure Tests

    Relative Permeability Tests

    Others

    D. Factors Affecting Reservoir Wettability

    The original strong water-wetness of most reservoir minerals can be altered by the

    adsorption of polar compounds and/or the deposition of organic matter that was

    originally in the crude oil. The surface-active agents in the oil are generally

    believed to be polar compounds that contain oxygen, nitrogen, and/or sulfur.

    These compounds contain both a polar and a hydrocarbon end. The polar end

    adsorbs on the rock surface, exposing the hydrocarbon end and making the surface

    more oil-wet. Experiments have shown that some of these natural surfactants are

    sufficiently soluble in water to adsorb onto the rock surface after passing through

    a thin layer of water. In addition to the oil composition, the degree to which the

    wettability is altered by these surfactants is also determined by the pressure,

    temperature, mineral surface and brine chemistry, including ionic composition and

    pH.

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    E. Sandstone and Carbonates

    The types of mineral surfaces in a reservoir are also important in determining

    wettability. Studies1 show that carbonate reservoirs are typically more oil-wet

    than sandstone reservoirs. Laboratory experiments show that the mineral surface

    interacts with the crude oil composition to determine wettability.

    F. Native-State, Cleaned, and Restored-State Cores

    Cores in three different states of preservation are used in core analysis: native

    state, cleaned, and restored state. Anderson1 indicates the best results for

    multiphase-type flow analyses are obtained with native-state cores, where

    alterations to the wettability of the undisturbed reservoir rock are minimized.

    Anderson's1-6

    work defines the term native-state as being any core that was

    obtained and stored by methods that preserve the wettability of the reservoir. No

    distinction is made between cores taken with oil- or water-based fluids, as long as

    the native wettability is maintained. Be aware, however, that some papers

    distinguish on the basis of drilling fluid. Anderson further defined native-state to

    be cores taken with a suitable oil-filtrate-type drilling mud, which maintains the

    original connate water saturation. Fresh-state refers to a core with unaltered

    wettability that was taken with a water-base drilling mud that contains no

    compounds that can alter core wettability.

    The second type of core is the cleanedcore, where an attempt is made to remove

    all the fluids and adsorbed organic material by flowing solvents through the cores.

    Cleaned cores are usually strongly water-wet and should be used only for such

    measurements as porosity and air permeability where the wettability will not

    affect the results.

    The third type of core is the restored-statecore in which the native wettability is

    restored by a three-step process. The core is cleaned and then saturated with brine

    followed by reservoir crude oil. Finally, the core is aged in reservoir crude at

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    reservoir temperature for about 1,000 hours. The methods used to obtain the three

    different types of cores are discussed in more detail in References 1 through 6.

    II. Capillary Pressure

    A. Definition

    Capillary pressure can be qualitatively expressed as the difference in pressure

    existing across the interface separating two immiscible fluids. Conceptually, it is

    perhaps easier to think of it as the suction capacity of a rock for a fluid that wets

    the rock, or the capacity of a rock to repel a non-wetting fluid. Quantitatively,

    capillary pressure will be defined in this text as the difference between pressure in

    the oil phase and pressure in the water phase. For example:

    c o wP P (Eq. 2.1)

    B. Importance

    1. Capillary forces, along with gravity forces, control the vertical distribution of

    fluids in a reservoir. Capillary pressure data can be used to predict the vertical

    connate water distribution in a water-wet system.

    2. Capillary pressure data are needed to describe waterflood behavior in more

    complex prediction models and in naturally fractured reservoirs.

    3. Capillary forces influence the movement of a waterflood front and,

    consequently, the ultimate displacement efficiency.

    4. Capillary pressure data are used to determine irreducible (immobile) water

    saturation.

    5. Capillary pressure data provide an indication of the pore size distribution in a

    reservoir.

    C.

    Sources of Data

    Unfortunately, capillary pressure data are not available for most reservoirs,

    especially older reservoirs developed with no thought of subsequent enhanced

    recovery projects. The only reliable sources of data are laboratory measurements

    made on reservoir core samples. These measurements are seldom made due to the

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    time and expense of obtaining unaltered core samples and conducting necessary

    tests. The laboratory tests4most commonly used are:

    Restored State (porous diaphragm) Method

    Centrifuge Method

    Mercury Injection Methods

    Most laboratory measurements are made using either air-brine or air-mercury

    systems. Consequently, the resulting data must be converted to actual reservoir

    conditions, taking into account the difference between interfacial tensions of

    laboratory and reservoir fluids and the difference in wettability effects of the fluids.

    This conversion can be made using the relationship:

    L

    RcLcR PP

    cos

    cos (Eq. 2.2)

    where:

    cRP = capillary pressure at reservoir conditions, psi

    cL = capillary pressure measured in the laboratory, psi

    = interfacial tension

    = contact angle

    Capillary pressure data from another reservoir having similar rock-fluid

    characteristics can also be used but is not generally recommended. When this is

    necessary, a correlating function such as the "J-function" (to be discussed later) is

    generally used.

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    D. Effect of Reservoir Variables

    1. Fluid Saturation

    Capillary pressure varies with the fluid saturation of a rock, increasing as the

    wetting phase saturation decreases. Accordingly, capillary pressure data are

    generally presented as a function of wetting phase saturation.4 A typical

    capillary pressure curve for a water-wet system is illustrated in Figure 2-2.

    FIGURE 2-2

    EFFECT OF SATURATION HISTORY ON OIL-WATER

    CAPILLARY PRESSURE CURVES FOR A WATER-WET ROCK

    0

    5

    10

    15

    20

    0 20 40 60 80 100

    CapillaryPressure,psia

    Water Saturation, percent

    Imbibition

    Drainage

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    2. Saturation History

    As noted previously, the direction in which the fluid saturation of a rock is

    changed during measurement of multiphase flow properties has a significant

    affect on measured properties. This hysteresis effect is obvious in Figure 2-2.

    The direction of saturation change used in the laboratory, or in other models,

    must match the direction of saturation change in the reservoir to which the data

    will be applied.

    3. Pore Geometry

    Other factors being equal, capillary pressure is inversely proportional to the

    radius of the pores containing the fluids.9

    If all pores were the same size in a

    rock, the capillary pressure curve would ideally be described by Curve 1 in

    Figure 2-3. However, all rocks exhibit a range of pore sizes which causes a

    variation in capillary pressure with fluid saturation. In general, the slope of the

    capillary pressure curve will increase with increasing pore size heterogeneity.

    This is illustrated by Curves 2, 3, and 4 on Figure 2-3 which represent a

    homogeneous, moderately heterogeneous, and very heterogeneous reservoir,

    respectively.

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    FIGURE 2-3

    EFFECT OF RESERVOIR HETEROGENEITY ON

    CAPILLARY PRESSURE CURVES

    0

    5

    10

    15

    20

    0 20 40 60 80 100

    CapillaryPressure,psia

    Water Saturation, percent

    Curve 1

    Curve 2

    Curve 3

    Curve 4

    E. Averaging of Data

    Even when good capillary pressure data are available, it is generally found that

    each core sample tested from a reservoir gives a different capillary pressure curve

    than every other core sample. Thus, an obvious question arises. How do we

    determine which curve represents the average behavior of the reservoir to be

    waterflooded? Two methods are commonly used to resolve this problem: (1) the

    J-function and (2) correlation with permeability.

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    1. J-function

    This function was developed by M. C. Leverett10

    in an attempt to develop a

    universal capillary pressure curve. The dimensionless J-function relates

    capillary pressure to reservoir rock and fluid properties according to the

    relationship.

    2

    1

    cw

    k

    f

    PSJ

    (Eq. 2.3)

    where:

    wSJ = J-function at a particular water saturation, dimensionless

    cP = capillary pressure, dynes/cm2

    = interfacial tension, dynes/cm

    k = permeability, cm2 (1.0 cm2= 1.013 x 108D)

    = porosity, fraction

    f = wettability function, dimensionless

    This equation was developed with the idea that, at a given saturation, the value

    of wSJ would be the same for all rocks regardless of their individual

    characteristics. For example, suppose the capillary pressure is measured for a

    rock with permeability 1k , porosity 1 , using fluids with interfacial

    tension 1 , and the wettability function is 1.0cosf . The

    capillary pressure for the rock will be some value c1P at *wS . Now suppose

    we measure the capillary pressure in a second rock with properties 2k , 2 ,

    2 and 0.1f . At saturation*wS (same as for Core 1), a value of

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    capillary pressure c2P will be obtained. If the J-function correlation works,

    the J-function for Cores 1 and 2, at saturation*wS , will be equal even though

    the values of capillary pressure are different. For example:

    2

    1

    2

    2

    2

    22

    1

    1

    1

    1

    1*2

    *1

    0.10.1

    kPkP

    SJSJ ccww (Eq. 2.4)

    Further, this relationship would be true at all saturations so a plot of Jversus

    wS should be the same for all rocks, as depicted by Figure 2-4.

    FIGURE 2-4

    J-FUNCTION VS WATER SATURATION

    0

    1

    2

    3

    4

    0 20 40 60 80 100

    Water Saturation, percent

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    Ideally then, it would only be necessary to know the interfacial tension, average

    porosity, and average permeability of the reservoir to be flooded to obtain the

    proper capillary pressure curve for any reservoir.

    Unfortunately, the method does not work universally, i.e., capillary pressure for

    all cores, or reservoirs, will not plot on a common curve. This is due primarily

    to the difference in pore size distributions and rock wettability between cores.

    Rock samples of different permeability and porosity characteristics generally

    would not be expected to have equivalent pore size distributions. Further,

    because of handling, cleaning, and in situ variation in wettability, it is simply

    not adequate to assume in Eq. 2.4 that 0.1f . However, for a given

    reservoir, or for a group of reservoirs with similar lithology, this plotting

    technique is often satisfactory for smoothing capillary pressure data and

    determining the capillary pressure curve that applies at average reservoir

    conditions. Consequently, this method is probably used more commonly than

    other techniques for averaging data.

    2. Correlate with Permeability

    This method is based on the following empirical observation. If capillary

    pressure is determined for several cores from the same reservoir (so that and

    f remain relatively constant) and the logarithm of permeability is plottedas a function of water saturation for fixed values of capillary pressure, then

    straight lines or smooth curves result. This is illustrated by Figure 2-5. If the

    average effective permeability of the reservoir is known, the correct average

    capillary pressure curve can be obtained by simply entering the subject graph

    with the average permeability to read values of capillary pressure as a function

    of saturation.

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    FIGURE 2-5

    CORRELATION OF CAPILLARY PRESSURE WITH

    PERMEABILITY

    1

    10

    100

    1,000

    0 20 40 60 80 100

    Permeabilit

    y,md

    Water Saturation, percent

    k

    c1Pc2Pc3Pc4Pc5P

    _________________________________________________________

    EXAMPLE 2:1

    Capillary pressure data measured on five cores from a sandstone reservoir are

    presented below.

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    Water Saturations for Constant Capillary Pressure, percent

    k, md 75 psi 50 psi 25 psi 10 psi 5 psi

    470.0 18.5 22.0 29.0 39.0 49.5

    300.0 22.5 25.5 34.0 45.5 56.0

    115.0 30.0 34.0 41.0 53.5 65.0

    50.0 36.0 40.5 51.0 64.0 77.0

    27.0 41.0 44.0 55.0 69.0 81.5

    The geometric mean permeability of the reservoir, based on 43 core samples, is

    155 md. The interfacial tension, L of the air-brine system used to measure

    capillary pressure, is 71 dynes/cm. The reservoir oil-water system has an

    interfacial tension, , equal to 33 dynes/cm. Find a capillary pressure curve

    that will apply to average reservoir conditions, i.e., the geometric mean

    permeability.

    SOLUTION

    Figure 2-6 shows that capillary pressure data can be correlated with

    permeability. The laboratory values of capillary pressure versus saturation,

    corresponding to k = 155 md, are shown in the following table. The values of

    capillary pressure, converted to reservoir conditions, are also tabulated.

    percentSw , psicL, ,RcR cLL

    P P psi

    27.2 75 34.931.5 50 23.2

    39.2 25 11.6

    51.0 10 4.6

    62.8 5 2.3

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    10

    100

    1,000

    0 20 40 60 80 100

    Water Saturation, percent

    Permeability,md

    75 psi 50 psi 25 psi 10 psi 5 psi

    FIGURE 2-6

    CORRELATION OF CAPILLARY PRESSURE, SATURATION,

    AND PERMEABILITY FOR EXAMPLE 2.1

    k = 155 md

    III. Relative Permeability

    A. Definition

    Before engaging in a discussion of relative permeability, a brief review of the

    different permeability terms which frequently appear in technical reports or as part

    of technical conversations is in order. The different permeability terms are:

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    air permeability, md

    absolute permeability, md

    effective permeability, md

    relative permeability, dimensionless

    1. Air Permeability- the routinepermeability measured on a core sample. This

    measurement is conducted using a gas, such as nitrogen or natural gas, and does

    not usually take into account the Klinkenberg effect.9 Air permeabilities are

    frequently used as estimates of absolute permeability, However, unless the

    Klinkenberg correction is performed, air permeability can overstate the absolute

    permeability by a factor of 1.5 or more.

    2. Absolute Permeability- the permeability of a core sample when filled with a

    single liquid such as water or oil. Absolute permeability is independent of the

    fluid but is dependent on the pore throat sizes. Absolute permeability is most

    applicable in aquifer studies because the aquifer usually contains a single fluid,

    water.

    3.

    Effective Permeability- the permeability to water, oil, or gas ( gow kkk ,, )

    when more than one phase is present. Effective permeability of a phase is

    dependent on fluid saturation. Application of Darcy's Law for determination of

    production ( oq or wq ) or injection ( wi ) rates utilize effective permeability.

    Effective permeability to oil and water are most commonly used in waterflood

    analysis.

    4. Relative Permeability - the ratio of effective permeability to some base

    permeability, usually the effective permeability to oil measured at the immobile

    (irreducible) connate water saturation, ( ) , /( )wir S wiro S ro o ok k k k

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    /( ) wirrw w o S k k k . Since the effective permeability of a rock dependson the fluid saturation, it follows that relative permeability is also a function of

    fluid saturation. When the base permeability is ( )wiro S

    k , then the relative

    permeability to oil at the immobile connate water saturation, ( )wirro S

    k , is

    1.0. In relative permeability measurements prepared prior to about 1975,

    laboratories frequently used the uncorrected air permeability as the base

    permeability. The net effect is to cause the ( )wirro S

    k value to be less

    than 1.0, usually in the range of 0.6 to 0.8.

    B. Importance

    As the name implies, relative permeability data indicate the relative ability of oil

    and water to flow simultaneously in a porous medium. These data express the

    effects of wettability, fluid saturation, saturation history, pore geometry, and fluid

    distribution on the behavior of a reservoir system.5,6,7

    Accordingly, this is

    probably the single, most important flow property which affects the behavior of a

    waterflood. When using ( )wiro S

    k as the base permeability, the relative

    permeability to oil and water ranges between 0.0 and 1.0 when plotted versus

    water saturation. This scale allows for easy comparison of one set of relative

    permeability versus another set from a different core sample. The comparison is

    made by a simple overlay.

    C.

    Sources of Data

    1. Laboratory measurement on representative core samples possessing appropriate

    reservoir wettability

    a. Steady-state method

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    b. Unsteady-state method

    2. Use data from similar reservoir

    3. Mathematical models

    4.

    History matching

    5. Calculate from capillary pressure data

    D. Effect of Reservoir Variables

    1. Saturation History

    Figure 2-7 shows the effect of saturation history on a set of relative

    permeability data. It is noted that the direction of flow has no effect on the

    flow behavior of the wetting phase. However, a significant difference exists

    between the drainage and imbibition curves for the non-wetting phase. This

    again points out the need for knowing wettability. For a water-wet system, we

    would choose the imbibition data; whereas, drainage data would be needed to

    correctly predict the performance of an oil-wet reservoir.

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    0

    20

    40

    60

    80

    100

    0 20 40 60 80 100

    RelativePermeab

    ility,percent

    Wetting Phase Saturation, percent

    Wetting Phase

    FIGURE 2-7EFFECT OF SATURATION HISTORY ON RELATIVE

    PERMEABILITY DATA

    2. Wettability

    Wettability affects the fluid distribution within a rock and, consequently, has a

    very important effect on relative permeability data. This is indicated on Figure

    2-8 which compares data for water-wet and oil-wet systems.

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    0

    20

    40

    60

    80

    100

    0 20 40 60 80 100

    RelativePermeabilty,percent

    Water Saturation, percent

    Oil Wet

    WaterWet

    FIGURE 2-8

    EFFECT OF WETTABILITY

    ON RELATIVE PERMEABILITY DATA

    Several important differences between oil-wet curves and water-wet curves are

    generallynoted.

    a. The water saturation at which oil and water permeabilities are equal

    (intersection point of curves) will generally be greater than 50 percent for

    water-wet systems and less than 50 percent for oil-wet systems.

    b. The connate water saturation for a water-wet system will generally be

    greater than 20 percent; whereas, for oil-wet systems, it will normally be

    less than 15 percent

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    c. The relative permeability to water at maximum water saturation (residual oil

    saturation) will be less than about 0.3 for water-wet systems but will be

    greater than 0.5 for oil-wet systems.

    These observations may not hold true for intermediate wettability rocks.

    Further, for high permeability values 100 mdwir

    o Sk these findings

    may not be true7. For example, water-wet rocks with large pore throats (high

    permeability) sometimes exhibit immobile connate water saturation of less than

    10 to 15 percent. Nevertheless, Figure 2-8 indicates the shape and magnitude

    of relative permeability curves can give an indication of the wettability

    preference of a reservoir for moderate to low levels of permeability; i.e.,( ) 100 md

    wiro Sk .

    E. End-Point Values

    Summary water-oil relative permeability tests are frequently conducted on core

    samples. These summary tests are often referred to as "end-point" tests because

    they reflect

    wirS ,

    orS , ( )

    Swirok , and( )

    Sorwk . Results of these tests are

    less expensive than normal relative permeability tests, but they can provide useful

    information on reservoir characteristics. Listed below are end-point test data for

    three sandstone cores.

    Water-Oil End-Point Relative Permeability Tests*

    Initial Conditions Terminal Conditions

    mdk , %, %wirS , mdok , %orS , mdwk , rok rwk

    9.4 14.5 27.5 6.4 35.4 1.8 1.0 0.28

    3.7 15.8 37.6 2.4 34.2 0.8 1.0 0.33

    18.0 13.8 24.7 13.0 38.3 4.6 1.0 0.35

    *Tests conducted at confining overburden pressure

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    F. Averaging of Data

    1. Data Averaging Methods

    Again, we often face the problem of having several permeability curves for a

    particular formation, all of which are different. It is desirable to select one set

    of curves which will apply at average reservoir conditions, i.e., at the average

    formation permeability. Methods to accomplish this are:

    a. Determine the saturation at different values of rok or rorw kk / for each

    of the different sets of data (use same values of permeability or permeability

    ratio in obtaining saturations from the different permeability curves). This

    is probably done most often using rorw kk / . The saturations obtained at

    equal values of permeability are arithmetically averaged to define the

    average set of permeability data.

    b. In some cases, a plot of rorw kk / versus water saturation for each core

    will yield a correlation with permeability as shown in Figure 2-9. However,

    smooth curves rather than straight lines will often result. If the effective

    average permeability is known, an average permeability curve can be

    determined from the correlation.

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    0.1

    1

    10

    100

    0 20 40 60 80 100

    Water Satuaration, percent

    FIGURE 2-9CORRELATION OF RELATIVE PERMEABILITY

    DATA WITH ABSOLUTE PERMEABILITY

    k1 k2 k3

    2. Adjust Average Data to Account for Different Irreducible Water

    Saturations

    This is not necessary for oil-wet systems, but in the case of water-wet systems,

    the situation often occurs where the accepted value of irreducible water

    saturation does not agree with the average relative permeability data chosen to

    represent the reservoir. The procedure for converting the data to a different

    irreducible water saturation is:

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    a.From the average relative permeability curves, read values of rok and

    rwk at different values of oil saturation.

    b.Multiply each of the saturations from Step (a) by 1.0o

    wir

    S

    S

    c.Using the normalized curve obtained from Step (b), the permeability data

    can be placed back on a total pore volume basis, using any desired value of

    initial water saturation, by multiplying the normalized saturations by

    wirS0.1 .

    It is also possible to normalize the relative permeability data before the data are

    averaged.

    _______________________________________________________________

    EXAMPLE 2:2

    Relative permeability curves measured on three cores from the Levelland Field,

    San Andres formation, in West Texas are shown in Figure 2-10. The averageinitial water saturation of this reservoir is believed to be 15 percent. Find the

    average oil and water relative permeability curves for this reservoir and adjust

    the curves to the average connate water saturation.

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    FIGURE 2-10RELATIVE PERMEABILITY DATA FOR EXAMPLE 2.2

    0

    20

    40

    60

    80

    100

    0 20 40 60 80 100

    Water Saturation, percent

    RelativePermeability

    1 2 3

    1 2 3

    SOLUTION

    The calculations necessary to average, normalize, and adjust the curves to a

    new saturation basis are presented in the following tables for the oil and water

    data. The average permeability curves, adjusted to 15 percent irreducible water

    saturation, are presented in Figure 2-11.

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    Conversion of Oil Permeability Data

    (All Values in Percent)

    (1) (2) (3) (4) (5) (6) (7) (8)

    kro Sw1 Sw2 Sw3 SwAVG

    wi

    o

    S

    S

    0.1

    (6) * (1.0-0.15) (Sw)NEW

    1.00 8.0 25.0 37.0 23.3 100.0 85.0 15.0

    0.90 11.0 27.5 39.0 25.8 96.7 82.2 17.8

    0.80 13.5 30.0 41.0 28.2 93.6 79.6 20.4

    0.70 16.5 32.5 44.0 31.0 90.0 76.5 23.5

    0.60 20.0 35.0 46.0 33.7 86.4 73.4 26.6

    0.50 23.0 37.5 48.5 36.3 83.1 70.6 29.4

    0.40 26.5 40.5 51.0 39.3 79.1 67.2 32.8

    0.30 30.5 44.0 54.5 43.0 74.3 63.2 36.8

    0.20 35.0 47.2 58.0 46.7 69.5 59.0 41.00.10 41.1 51.0 63.2 51.8 62.8 53.4 46.6

    0.05 46.0 54.0 67.0 55.7 57.8 49.1 50.9

    0.01 52.5 58.0 72.5 61.0 50.8 43.2 56.8

    0.00 56.0 60.5 76.0 64.2 46.7 39.7 60.3

    Conversion of Water Permeability Data(All Values in Percent)

    (1) (2) (3) (4) (5) (6) (7) (8)

    krw Sw1 Sw2 Sw3 SwAVGwi

    o

    S

    S

    0.1

    (6) * (1.0 - 0.15) (Sw)NEW

    0.50 62.0 73.0 86.5 73.8 34.2 29.1 70.9

    0.40 59.0 70.0 83.5 70.8 38.1 32.4 67.6

    0.30 56.0 67.0 80.5 67.8 42.0 35.7 64.3

    0.20 52.0 63.5 76.5 64.0 46.9 39.9 60.1

    0.10 46.5 58.5 71.0 58.7 53.8 45.7 54.3

    0.05 42.5 55.0 67.0 54.8 58.9 50.1 49.90.01 36.0 48.0 62.0 48.7 66.9 56.9 43.1

    0.00 8.0 25.0 37.0 23.3 100.0 85.0 15.0

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    FIGURE 2-11

    NORMALIZED AND ADJUSTED

    RELATIVE PERMEABILITY CURVES FOR EXAMPLE 2.2

    0

    20

    40

    60

    80

    100

    0 20 40 60 80 100

    Water Saturation, percent

    RelativePe

    rmeability

    _______________________________________________________________

    G. Default Relative Permeability Relationships

    The most reliable source of relative permeability data is from laboratory

    measurements performed on cores obtained from the reservoir of interest. For the

    measurements to be meaningful, considerable care and effort must be expended to

    ensure that the in situ reservoir wettability is preserved during coring, surfacing,

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    storage, and measurement operations. Failure to preserve native wettability will

    cause the measured relative permeability values to be of little use for reservoir

    analysis.

    Unfortunately, many reservoirs considered for waterflooding are characterized by

    the absence of relative permeability or, at best, by unreliable data. In these

    situations, it may be necessary to use certain "default" relative permeability

    models for data.

    Several authors have presented mathematical models which can be used to

    describe relative permeability relationships for the simultaneous flow of oil and

    water. The relationships are restricted to reservoirs in which flow is through the

    matrix. Consequently, those results are not applicable for flow through reservoirs

    possessing significant vugs or natural fractures.

    Corey11

    has suggested that for a drainageprocess (waterflood of an oil-wet rock):

    4werw Sk (Eq. 2.5)

    where:

    wir

    wirwwe

    S

    SSS

    0.1

    (Eq. 2.6)

    with:

    wS = water saturation, fraction

    wirS = irreducible water saturation, fraction

    and:

    22 0.1)0.1( wewero SSk (Eq. 2.7)

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    Where there is simultaneous flow of oil and water in a water-wet system during an

    imbibitionprocess, Smith12

    suggests that:

    2

    1

    4

    0.1

    wirwirw

    wrw S

    SS

    Sk (Eq. 2.8)

    and:

    2

    0.10.1

    orwir

    wirwro

    SS

    SSk (Eq. 2.9)

    where:

    orS = residual oil saturation, fraction

    More recently, Hirasaki13

    summarized certain relative data compiled by the 1984

    National Petroleum Council14

    (NPC). As part of a national enhanced oil recovery

    study, it was necessary to forecast remaining waterflood recovery in many

    reservoirs throughout the United States. In many instances, reservoir data such as

    rock wettability and relative permeability were not available. Consequently, an

    NPC technical committee recommended default relative permeability relation-

    ships similar to those presented by Molina15

    . These relationships are listed below.

    EXW

    wiror

    wirwSrwrw SS

    SSkk

    or

    0.1 (Eq. 2.10)

    and:

    1.0

    1.0wir

    EXO

    w orro ro S

    or wir

    S Sk k

    S S

    (Eq. 2.11)

    where:

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    EXW = water relative permeability exponent

    EXO = oil relative permeability exponent

    ( )Swir

    rok = relative permeability to oil at the irreducible water saturation

    (usually 1.0)

    ( )Sor

    rwk = relative permeability to water at the waterflood residual oil

    saturation (usually about 0.25 to 0.4 depending on

    wettability)

    orS = residual waterflood oil saturation, fraction

    wS = water saturation, fraction

    wirS = irreducible water saturation, fraction

    In addition to Eq. 2.10 and Eq. 2.11, the NPC also provided certain other default

    data which are listed below.

    Parameter Sandstone Carbonate

    Oil relative permeability end-point 1.0 1.0

    Water relative permeability end-point 0.25 0.40Oil relative permeability exponent 2 2

    Water relative permeability exponent 2 2

    Residual oil saturation, percent 25 37

    A comparison of these default end-point values with the statements listed on page

    20 of Craig8suggests a possible conclusion that carbonate reservoirs behave as if

    they are oil-wet. This observation should not be interpreted as an indication of

    rock wettability but the result of attempting to "average" a large amount of data.

    Finally, Honapour16

    provides a thorough review of the empirical equations used to

    compute two phase (oil/water or gas/oil) and three phase (gas/oil/water) relative

    permeability.

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    __________________________________________________________________

    EXAMPLE 2:3

    A carbonate oil reservoir is being considered for waterflooding. At the present

    time, the immobile (irreducible) water saturation is estimated to be 25 percent.

    Compute a pair of oil and water relative permeability curves that could be used in

    the evaluation of the waterflood.

    SOLUTION

    In the absence of specific data, the default relative permeability relationships

    described by Eq. 2.10 and Eq. 2.11 will be utilized. The following data are

    estimated from analog fields or from the NPC default values.

    orwS = 35 percent (analog field)

    ( )Swir

    rok = 1.0 (based on ( ) Swirbase ok k )

    ( )Sor

    rwk = 0.35 (assumes intermediate wettability)

    EXO = 2.0 (1984 NPC)

    EXW = 2.0 (1984 NPC)

    EXW

    wiror

    wirw

    orSrwrw SS

    SSkk

    0.1

    1.01.0wir

    XO

    w orro ro S

    or wir

    S Sk kS S

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    Substituting:

    0.2

    25.035.00.1

    25.0)35.0(

    wrwS

    k

    and:

    0.2

    25.035.00.1

    35.00.10.1

    wroS

    k

    Finally, rwk and rok can be computed and plotted as a function of water

    saturation.

    %w

    S , r w

    kro

    k

    25 0.000 1.000

    30 0.001 0.766

    35 0.022 0.562

    40 0.049 0.391

    45 0.088 0.250

    50 0.137 0.14155 0.197 0.062

    60 0.268 0.016

    65 0.350 0.000

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    FIGURE 2-12

    OIL/WATER RELATIVE PERMEABILITY

    0

    0.2

    0.4

    0.6

    0.8

    1

    0 20 40 60 80 100Water Saturation, percent

    RelativePermeability

    kro

    krw

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    CHAPTER 2 REFERENCES

    1.Anderson, W.G.: "Wettability Literature Survey - Part l: Rock/Oil/Brime Inter-

    actions and the Effects of Core Handling on Wettability," JPT(Oct. 1986) pp. 1125-

    44.

    2.Anderson, W.G.: "Wettability Literature Survey - Part 2: Wettability Measurement,"

    JPT(Nov. 1986) pp. 1246-62.

    3.Anderson, W.G.: "Wettability Literature Survey - Part 3: The Effects of Wettability

    on the Electrical Properties of Porous Media,"JPT(Dec. 1986) pp. 1371-78.

    4.Anderson, W.G.: "Wettability Literature Survey - Part 4: The Effects of Wettability

    on Capillary Pressure,"JPT(Oct. 1987) pp. 1283-1300.

    5.Anderson, W.G.: "Wettability Literature Survey - Part 5: The Effects of Wettability

    on Relative Permeability on Relative Permeability,"JPT(Nov. 1987) pp. 1453-68.

    6.Anderson, W.G.: "Wettability Literature Survey - Part 6: The Effects of Wettability

    on Waterflooding,"JPT(Dec. 1987) pp. 1605-20.

    7.Willhite, G.P.: Waterflooding, Textbook Series, SPE, Dallas (1986) 3.

    8.Craig, F.F., Jr.: The Reservoir Engineering Aspects of Waterflooding, Monograph

    Series, SPE, Dallas, Texas (1971) 3.

    9.Amyx, J.W., Bass, D.M. Jr., and Whiting, R.L.: Petroleum Reservoir Engineering,

    McGraw-Hill Book Company (1960).

    10.Leverett, M.C.: "Capillary Behavior in Porous Solids," Trans., AIME (1941).

    11.Corey, A.T.: "The Interrelation Between Gas and Oil Relative Permeabilities,"

    Producers Monthly,(November 1954).

    12.Smith, C.R.: Mechanics of Secondary Oil Recovery, Reinhold Publishing

    Corporation, New York (1966).

    13.Hirasaki, G.J., Morrow, F., Willhite, G.P.: "Estimation of Reservoir Heterogeneity

    From Waterflood Performance," SPE Paper 13415, Unsolicited technical papersubmitted for publication during Fall 1984.

    14.National Petroleum Council:Enhanced Oil Recovery, (June 21, 1984).

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    15.Molina, N.N.: "A Systematic Approach to the Relative Permeability in Reservoir

    Simulation," SPE Paper 9234 presented at the 1980 SPE Annual Technical

    Conference and Exhibition, Dallas.

    16.Honarpour, M., Koederitz, L., and Harvey, A.H.: Relative Permeability of Petroleum

    Reservoirs, CRC Press, Boca Raton , FL (1986).

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    PROBLEM 2:1

    REVIEW OF ROCK AND FLUID PROPERTIES

    A series of laboratory studies resulted in the following average relative permeability data

    for an oil reservoir. (Note that the base permeability is the air permeability -- it is old

    data.)

    %w

    S , rwk rok

    25 0.000 0.565

    30 0.002 0.418

    35 0.015 0.300

    40 0.025 0.218

    45 0.040 0.14450 0.060 0.092

    55 0.082 0.052

    60 0.118 0.027

    65 0.153 0.009

    70 0.200 0.000

    These data indicate the irreducible water saturation in the reservoir is 25 percent. Well

    logs and core analysis suggest, however, that the true irreducible saturation isapproximately 15 percent. Adjustthe permeability data so they represent an irreducible

    water saturation of 15 percent and present the data in normalizedform on a scale of 0.0

    to 1.0.

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    WATERFLOODABLE OIL-IN-PLACE

    To accurately predict and effectively manage waterflood operations, it is necessary to

    estimate the reservoir oil-in- place within the floodable portion of the reservoir at the start

    of water injection. As indicated earlier, the basic oil recovery evaluation equation used to

    compute displaced oil by waterflooding can be summarized as:

    D A V DN N E E E (Eq. 3.1)

    where:

    D

    N = oil displaced by water injection, STB

    (It will be shown in later chapters that, in many instances, significant

    amounts of displaced oil may not be produced due to gas resaturation

    effects.)

    N = oil-in-place at start of waterflooding within thefloodablezones, STB

    E = areal sweep efficiency, fraction

    V

    E = vertical sweep efficiency, fraction

    DE = unit displacement efficiency, fraction

    The oil-in-place at the start of waterflooding is given by:

    o

    o

    7758Ah SN

    B

    (Eq. 3.2)

    where:

    = floodable area, acres

    h = floodable pay, feet

    = porosity, fraction

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    oS = oil saturation at start of the flood, fraction

    oB = oil formation volume factor at start of the flood, RB/STB

    Three major difficulties encountered in using Eq. 3.2 are the determination of

    waterfloodable net pay, porosity, and oil saturation. SinceNrepresents the oil in place at

    the start of water injection, it would appear that this value could be obtained by simply

    taking the differences in the original oil-in-place and the primary production up to the start

    of injection. This simple approach can be misleading due to the fact that the net pay for

    primary production is assumed to be the net pay for water injection. As will be shown

    later in this chapter, the net pay cutoffs and subsequent net pay for water injection is much

    different than for primary depletion. Another deficiency in computing Nby taking thedifference in the original oil-in-place and primary production is that such a simple

    calculation does not indicate how the gas saturation has increased and the oil saturation has

    decreased if reservoir pressure is below the initial bubble point pressure.

    I. Oil Saturation

    Most waterfloods are implemented late in the life of the reservoir after significant

    primary production has occurred and at a time when the reservoir pressure is below the

    bubble-point pressure. As primary production occurs, reservoir pressure declines

    below the bubble-point, solution gas evolves from the oil in the reservoir, and a free

    gas saturation forms within the oil zone. The development of a free gas saturation is

    characterized by the production of a portion of the gas and an increase in the gas-oil

    ratio. Despite production of the free gas, a large portion of it remains in the reservoir.

    Consequently, the oil saturation at the start of waterflooding can be substantially less

    than the oil saturation at the discovery of the field.

    The oil saturation in the reservoir is constant at (1 wcS ) during those times when

    average reservoir pressure is at or above the initial bubble point pressure. However,

    the oil saturation begins to decrease and the free gas saturation begins to increase as

    the average reservoir pressure declines below the initial bubble point pressure. To

    compute the average oil saturation, let the initial bubble point pressure be the

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    beginning reference point. Consider the following equation at any time when the

    reservoir pressure is below the bubble point pressure.

    Reservoir Oil Volume

    Reservoir Pore VolumeoS (Eq. 3.3)

    The reservoir oil volume consists of the number of barrels of oil in the reservoir at the

    time of interest and can be estimated as:

    Stock Tank Oil Volume = OOIP at bubble-point pressure - Primary Oil

    Produced below bubble-point pressure (Eq. 3.4)

    or:

    Reservoir Oil Volume=ob pp o

    ( N N )B (Eq. 3.5)

    where:

    obN = original oil-in-place at the bubble-point pressure, STB

    pN = primary oil production between the bubble-point and current

    reservoir pressure, STB

    oB = oil formation volume factor at prevailing pressure, RB/STB

    The reservoir pore volume can be estimated using a volumetric material balance

    where:

    wc

    obob

    V (1.0 S )

    N B

    (Eq. 3.6)

    Solving for pore volume gives:

    ob obp

    wc

    N BV

    ( 1.0 S )

    (Eq. 3.7)

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    where:

    obB = oil formation volume factor at the bubble-point pressure, RB/STB

    wc

    S = connate water saturation at the time of discovery, fraction

    Substituting Eq. 3.5 and Eq. 3.7 into Eq. 3.3 leads to:

    ob pp oo

    ob ob

    wc

    N N BS

    N B

    1.0 S

    (Eq. 3.8)

    Rearranging results in the average oil saturation equation.

    pp oo wcob ob

    N BS 1.0 1.0 S

    N B

    (Eq. 3.9)

    This equation plays a very important role in estimating waterflood potential.

    ____________________________________________________________________

    EXAMPLE 3:1

    A reservoir is a candidate for waterflooding. The primary oil recovery factor below

    the bubble-point pressure is 12 percent. The connate water saturation is 36 percent,

    and the oil formation volume factors oB at the bubble-point and current pressureare estimated fro