Compact and advanced laser spectrometer for water quality analysis Luca Fiorani Luca Fiorani Diagnostics and Metrology Laboratory Diagnostics and Metrology Laboratory ENEA ENEA (Italian National Agency for New (Italian National Agency for New Technologies, Energy and Sustainable Economic Technologies, Energy and Sustainable Economic Development) Development) Transnational Workshop “Efficient Management of Transnational Workshop “Efficient Management of Water Resources” Water Resources” EcoMondo 2010 EcoMondo 2010 Rimini, November 4, 2010 Rimini, November 4, 2010
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Compact and advanced laser spectrometer for water quality analysis
Compact and advanced laser spectrometer for water quality analysis. Luca Fiorani Diagnostics and Metrology Laboratory ENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development). Transnational Workshop “Efficient Management of Water Resources” - PowerPoint PPT Presentation
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Compact and advanced laser spectrometer for water quality analysis
Luca FioraniLuca FioraniDiagnostics and Metrology LaboratoryDiagnostics and Metrology LaboratoryENEA ENEA (Italian National Agency for New Technologies, (Italian National Agency for New Technologies, Energy and Sustainable Economic Development)Energy and Sustainable Economic Development)
Transnational Workshop “Efficient Management of Water Resources”Transnational Workshop “Efficient Management of Water Resources”EcoMondo 2010EcoMondo 2010Rimini, November 4, 2010Rimini, November 4, 2010
CASPERCASPER
• CASPER: Compact and Advanced laser SPEctrometer for Riade (RIADE was an Italian project to combat desertification)
Patent and prizePatent and prize
• CASPER has been patented in 2005• CASPER resulted the first classified project of the
“Research and Innovation Prize 2005” awarded by “BIC Lazio” (Business Innovation Center Latium) and “Regione Lazio” (Latium Regional Government)
PrinciplePrinciple
• Laser induced fluorescence (LIF)– Emission spectrum of Synecochoccus leopoliensis
excited at 355 nm
400 450 500 550 600 650 700 7500
500
1000
1500
2000
Chlorophylls
Phycocyanin
Phycoeritrin
Carotenoids Water Raman
LIF
inte
nsit
y [r
el. u
n.]
Wavelength [nm]
InnovationInnovation
• Double filtration (30 and 0.2 μm)– Discrimination of particulate and dissolved matter
• Double excitation (266 and 405 nm)– Detection of oils, PAH and proteins (266) and CDOM,
chl-a and other algal pigments (405)
HardwareHardware
Spectrometers
Nd:YAGLaser
DiodeLaser
Cuvettes
Filters
Power supplyPumps & valves
USB hub
Water in & out
RS232
Opticalfibers
SoftwareSoftware
• Remote control– Battery, lasers, shutters, pumps and valves are controlled
from the laptop (left)• Data acquisition
– Spectra are acquired from the laptop (right)
Emission spectraEmission spectra
• CDOM– Sensitivity: about 0.1 mg/l
• Chl-a– Sensitivity: about 0.1 μg/l
Excited at 266 nm Excited at 405 nm
The chl-a peak disappears after
ultrafiltration
Data analysisData analysis
• Peak position of spectral bands in the LIF signal
Sicily Campaign 2005Sicily Campaign 2005
• Licata and Siracusa, May 22 – 27, 2005– 81 samplings: GPS, conductivity, temperature, pH, chl-a
and CDOM (CASPER)
Sicily Campaign 2005Sicily Campaign 2005
• Chl-a– Licata, May 22 – 25, 2005
Sicily Campaign 2005Sicily Campaign 2005
• CDOM– Licata, May 22 – 25, 2005
Sicily Campaign 2005Sicily Campaign 2005
• CDOM and conductivity (salinity)
irrigationsea intrusion
Conductivity
CDOM
OceanographyOceanography
• CASPER has been deployed in four oceanographic campaigns (Arctic Ocean and Mediterranean Sea)
CHLCHL retrieved by CASPER retrieved by CASPER during AREX 2006 (black during AREX 2006 (black
• CASPER, an innovative laser spectrofluorometer, has been developed at the ENEA Research Center in Frascati (patent and prize)
• CASPER operated during a field campaign in Sicily (May 22 – 27, 2005) • CASPER data improved our understanding of salinization and desertification• CASPER has also been deployed in oceanographic campaigns• CASPER is now exploited by the Sardinian spin-off “Intrega” (commercial agreement