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Colour Technology (1)

Apr 02, 2018

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    Colour Technology

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    Why use Colours?

    IdentificationBranding

    Convey a Mood or a Style

    Choice

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    Introduction

    Assessment and Measurement of Colour.

    Factors Affecting Colour Matching.

    Methods of Colouring.

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    Colour Assessment

    Eyesight

    Light Source

    Size Background Colour

    Surface Finish

    Metamerism

    observer

    object

    light source

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    Human Visual System

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    The Retina

    Retina uses special cells called rods andcones.

    Rods sees in black, white & shades of grey andtell us the form or shape. (Super-sensitive allowing

    us to see when it's very dark.) Cones senses colour but need more light. Three

    types and each is sensitive to one of three differentcolours - red, green, or blue. Together these can

    sense combinations of light waves. (To see millionsof colours.)

    Rods and cones together process the light to giveyou the total picture.

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    The Rods and Cones

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    The Rods and Cones

    5 million per eye (more L

    and M cones than S cones)100 million per eye

    Responsible for daylight(photopic) vision

    Responsible for low-level (scotopic) vision

    Cone function

    Rod function

    scotopic mesopic photopic

    luminance

    Cones Rods

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    Eyesight

    Individuals perceive colour differently.

    Is Sky Blue the same as Pale

    Blue?

    How many People are Colour-Blind?

    Experts are turned in to Colours.

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    Light source

    A redobject in redlight, appearred- as allthe redlight is reflected.

    A redobject in blue light, appear black - as

    no redlight to reflect back.

    The difference between say daylight and the

    Tungsten Lights used in homes, could besignificant!!

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    Size

    A small area of colour may look very

    different to a large area of the SAME

    colour.

    Hence, it is important when decorating topaint a sufficiently large area.

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    Background colour

    Colours viewed against a strong, vivid coloured

    backgrounds, appears very different against a

    neutral or pastel coloured background.

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    Surface finish

    A high gloss finish always appears darker than a

    matt finish of the same colour.

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    Metamerism

    Change in appearance of a colour underdifferent light source.

    Describe the relative changes in colour between

    two samples, i.e. Good match in day light,different in fluorescent shop lighting.

    Occurs when different colourants are used in

    each sample.

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    Colour Measurement

    Colour Space

    Colour Measuring Devices

    Colorimeters

    Spectrophotometers

    Metamerism

    Light Sources and Illuminates

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    Colour

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    Colour Space

    To measure colour objectively, to communicate

    differences in quantifiable terms.

    Principleis that all colours can be inside a Colour

    Space i.e. this space being a sphere.

    Each colour can then be give a position in the colour

    space.

    Differences between colours can be quantified by

    comparing the values of the co-ordinates.

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    Colour Space

    +a*

    +b*

    -a*

    -b*

    L*=100

    L*=0

    L*

    L*

    -a*

    +a*

    -b*

    +b*

    + L = Lightness - L* = Darkness

    + a* = Redness - a* = Greeness

    + b* =Yellowness - b* = Blueness

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    Colour Space - Delta E

    a*

    b* D C*DH*

    SC

    SH

    222

    ***

    D

    D

    DD

    H

    ab

    C

    ab

    LS

    H

    cS

    C

    lS

    LE

    is the difference between two points in colour

    space, often use to determine a colour

    tolerance or specification.

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    Colour Space

    A different system (Yxy) is used for

    transparent colours.

    Y = percentage of light transmitted

    x = balance between blue and red light

    y = balance between blue and green light

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    More on Metamerism

    Two colours with the same L*,a*,b* values which are

    arrived at by a different route will show metamerism.

    Their colour will be different if the light source ischanged.

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    Colour Measuring Devices

    Colorimeters

    Filters the reflected

    lights into Red, Green

    an blue lights and

    measure the relative

    amounts of each, then

    calculates thenumerical lab value.

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    Colour Measuring Devices

    Spectrophotometers

    Measure the reflectedlights at regular intervals

    across the visiblespectrum, then producesa graph of the spectrumof light reflected by thecolour called the SpectralCurve.

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    Colour Measuring Devices

    Spectrophotometers more accuratethan colorimeters.

    Spectrophotometers better at

    identifying metamerism thancolorimeters.

    Differences between the human eye and

    colour measuring devices > Possible tohave an accurate reading but does not

    visually look right!!!!

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    Light sources and illuminants

    The three most widely used are;

    D65 Simulation of Daylight (ArtificialDaylight).

    A Normal domestic tungsten light.

    TL84 Standard fluorescent tube used inmost shops and showrooms.

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    Colour Matching

    Standard Colour Systems

    The Material

    Colorants

    Legal Restrictions

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    Standard Colour Systems

    Colours presented as printed paper patterns

    books. (RAL and PANTONE system.)

    Building industry has its own set of BS

    colours.

    NCS (Scandinavian) a measuring system

    rather than a fixed set of colours.

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    The Material

    Processing temperatures and chemicalcharacteristics, means a colourant can workin one polymer, but degrade or discolour inanother.

    The more different the standard material isto the match material, the less likely anaccurate match.

    A painted sheet match to Nylon 6.6, thecolourants used in paint will not survive290oC.

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    The colourants-Pigments

    Very fine powdered chemicals dispersed inthe polymers.

    Poor dispersion results in a weaker colour andoften a grainy surface.

    Inorganic pigments are mineral based, i.e.Metal Oxides & Sulphides.

    Organic pigments are chemical compounds,

    less heat stable and more difficult to disperse.Usually give richer and more vivid colours.Less pigment is required.

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    The colourants-Dyes

    Chemical substances that dissolves in thepolymer.

    Chemically interact, as such allows light topass through. When use in transparentmaterials remain transparent.

    A limit how much dye can be added to a

    polymer, the dye can bleed out! Insoluble in Polyolefins.

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    Legal Restrictions

    Food, Medical and Toy - mainly base on purity andinability to extract the colourant from the finishitem.

    Cadmium pigments - base on the premise when

    the Plastic part is incinerated, they can releaseCadmium metals. Applies mainly in the packagingindustry.

    If a colour is required for safety purposes, thenCadmium pigments can be use regardless of the

    Cadmium legislation. Many companies have a Cadmium Free policy

    regardless of the details of the legislation.

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    Methods of colouring

    Dry Colour

    Masterbatch

    Liquid Colour

    Fully Compounded Colour

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    Dry Colour or Dry Blend

    The colourants are mixed with the polymer. Somedispersion aids may be added and often awetting agent to help bind the powder onto the

    surface.

    Advantages : Cheap because the conversioncost is low. Quick to prepare. Very small lot.

    Disadvantages : Can be very Messy, can affectdrying, colour can vary with different machinedue to dispersion.

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    MasterbatchCompounds contains very high levels of colourants (up

    to 80%), then mixed at a fixed ratio to give a specific

    colour.

    Polymer Specific - Carrier is the same material as

    the base material.Universal - Carrier will readily mix with a wide variety

    of polymers.

    Advantages : Better colour control, cleaner and less

    drying problems than Dry-colour. A stock range of

    colours and specific colours can be develop.

    Disadvantages : May not always be compatible with the

    base polymer. Accuracy depends on the Moulder with

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    Liquid colour

    Similar to masterbatches, contains a high level ofcolourants, but the carrier is a liquid.

    Advantages : Better colour control than Dryblend. More even distribution than masterbatch.

    Stock range of colours.

    Disadvantages : Special dosing equipment isrequired. Spillage is messy. Colour can

    depends on processing. Properties can be

    affected by the liquid carrier.

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    Fully compounded colour

    The colourants are added to the basePolymers, then extruded to

    encapsulate the colour into the

    polymer and is fully dispersed.

    Advantages : Specific, accurate and

    controlled colours. The performance

    of the compounds is more

    predictable. Ease of handling.

    Disadvantages : Less flexible than the

    other methods.

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    A Polymer for Every

    Application