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Colour Technology
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Why use Colours?
IdentificationBranding
Convey a Mood or a Style
Choice
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Introduction
Assessment and Measurement of Colour.
Factors Affecting Colour Matching.
Methods of Colouring.
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Colour Assessment
Eyesight
Light Source
Size Background Colour
Surface Finish
Metamerism
observer
object
light source
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Human Visual System
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The Retina
Retina uses special cells called rods andcones.
Rods sees in black, white & shades of grey andtell us the form or shape. (Super-sensitive allowing
us to see when it's very dark.) Cones senses colour but need more light. Three
types and each is sensitive to one of three differentcolours - red, green, or blue. Together these can
sense combinations of light waves. (To see millionsof colours.)
Rods and cones together process the light to giveyou the total picture.
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The Rods and Cones
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The Rods and Cones
5 million per eye (more L
and M cones than S cones)100 million per eye
Responsible for daylight(photopic) vision
Responsible for low-level (scotopic) vision
Cone function
Rod function
scotopic mesopic photopic
luminance
Cones Rods
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Eyesight
Individuals perceive colour differently.
Is Sky Blue the same as Pale
Blue?
How many People are Colour-Blind?
Experts are turned in to Colours.
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Light source
A redobject in redlight, appearred- as allthe redlight is reflected.
A redobject in blue light, appear black - as
no redlight to reflect back.
The difference between say daylight and the
Tungsten Lights used in homes, could besignificant!!
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Size
A small area of colour may look very
different to a large area of the SAME
colour.
Hence, it is important when decorating topaint a sufficiently large area.
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Background colour
Colours viewed against a strong, vivid coloured
backgrounds, appears very different against a
neutral or pastel coloured background.
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Surface finish
A high gloss finish always appears darker than a
matt finish of the same colour.
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Metamerism
Change in appearance of a colour underdifferent light source.
Describe the relative changes in colour between
two samples, i.e. Good match in day light,different in fluorescent shop lighting.
Occurs when different colourants are used in
each sample.
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Colour Measurement
Colour Space
Colour Measuring Devices
Colorimeters
Spectrophotometers
Metamerism
Light Sources and Illuminates
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Colour
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Colour Space
To measure colour objectively, to communicate
differences in quantifiable terms.
Principleis that all colours can be inside a Colour
Space i.e. this space being a sphere.
Each colour can then be give a position in the colour
space.
Differences between colours can be quantified by
comparing the values of the co-ordinates.
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Colour Space
+a*
+b*
-a*
-b*
L*=100
L*=0
L*
L*
-a*
+a*
-b*
+b*
+ L = Lightness - L* = Darkness
+ a* = Redness - a* = Greeness
+ b* =Yellowness - b* = Blueness
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Colour Space - Delta E
a*
b* D C*DH*
SC
SH
222
***
D
D
DD
H
ab
C
ab
LS
H
cS
C
lS
LE
is the difference between two points in colour
space, often use to determine a colour
tolerance or specification.
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Colour Space
A different system (Yxy) is used for
transparent colours.
Y = percentage of light transmitted
x = balance between blue and red light
y = balance between blue and green light
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More on Metamerism
Two colours with the same L*,a*,b* values which are
arrived at by a different route will show metamerism.
Their colour will be different if the light source ischanged.
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Colour Measuring Devices
Colorimeters
Filters the reflected
lights into Red, Green
an blue lights and
measure the relative
amounts of each, then
calculates thenumerical lab value.
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Colour Measuring Devices
Spectrophotometers
Measure the reflectedlights at regular intervals
across the visiblespectrum, then producesa graph of the spectrumof light reflected by thecolour called the SpectralCurve.
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Colour Measuring Devices
Spectrophotometers more accuratethan colorimeters.
Spectrophotometers better at
identifying metamerism thancolorimeters.
Differences between the human eye and
colour measuring devices > Possible tohave an accurate reading but does not
visually look right!!!!
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Light sources and illuminants
The three most widely used are;
D65 Simulation of Daylight (ArtificialDaylight).
A Normal domestic tungsten light.
TL84 Standard fluorescent tube used inmost shops and showrooms.
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Colour Matching
Standard Colour Systems
The Material
Colorants
Legal Restrictions
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Standard Colour Systems
Colours presented as printed paper patterns
books. (RAL and PANTONE system.)
Building industry has its own set of BS
colours.
NCS (Scandinavian) a measuring system
rather than a fixed set of colours.
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The Material
Processing temperatures and chemicalcharacteristics, means a colourant can workin one polymer, but degrade or discolour inanother.
The more different the standard material isto the match material, the less likely anaccurate match.
A painted sheet match to Nylon 6.6, thecolourants used in paint will not survive290oC.
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The colourants-Pigments
Very fine powdered chemicals dispersed inthe polymers.
Poor dispersion results in a weaker colour andoften a grainy surface.
Inorganic pigments are mineral based, i.e.Metal Oxides & Sulphides.
Organic pigments are chemical compounds,
less heat stable and more difficult to disperse.Usually give richer and more vivid colours.Less pigment is required.
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The colourants-Dyes
Chemical substances that dissolves in thepolymer.
Chemically interact, as such allows light topass through. When use in transparentmaterials remain transparent.
A limit how much dye can be added to a
polymer, the dye can bleed out! Insoluble in Polyolefins.
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Legal Restrictions
Food, Medical and Toy - mainly base on purity andinability to extract the colourant from the finishitem.
Cadmium pigments - base on the premise when
the Plastic part is incinerated, they can releaseCadmium metals. Applies mainly in the packagingindustry.
If a colour is required for safety purposes, thenCadmium pigments can be use regardless of the
Cadmium legislation. Many companies have a Cadmium Free policy
regardless of the details of the legislation.
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Methods of colouring
Dry Colour
Masterbatch
Liquid Colour
Fully Compounded Colour
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Dry Colour or Dry Blend
The colourants are mixed with the polymer. Somedispersion aids may be added and often awetting agent to help bind the powder onto the
surface.
Advantages : Cheap because the conversioncost is low. Quick to prepare. Very small lot.
Disadvantages : Can be very Messy, can affectdrying, colour can vary with different machinedue to dispersion.
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MasterbatchCompounds contains very high levels of colourants (up
to 80%), then mixed at a fixed ratio to give a specific
colour.
Polymer Specific - Carrier is the same material as
the base material.Universal - Carrier will readily mix with a wide variety
of polymers.
Advantages : Better colour control, cleaner and less
drying problems than Dry-colour. A stock range of
colours and specific colours can be develop.
Disadvantages : May not always be compatible with the
base polymer. Accuracy depends on the Moulder with
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Liquid colour
Similar to masterbatches, contains a high level ofcolourants, but the carrier is a liquid.
Advantages : Better colour control than Dryblend. More even distribution than masterbatch.
Stock range of colours.
Disadvantages : Special dosing equipment isrequired. Spillage is messy. Colour can
depends on processing. Properties can be
affected by the liquid carrier.
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Fully compounded colour
The colourants are added to the basePolymers, then extruded to
encapsulate the colour into the
polymer and is fully dispersed.
Advantages : Specific, accurate and
controlled colours. The performance
of the compounds is more
predictable. Ease of handling.
Disadvantages : Less flexible than the
other methods.
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A Polymer for Every
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