Chemistry 12 Solubility Equilibrium III Name: Date: Block: 1. One Source vs. Two Source Solubility Problems 2. Challenging Solubility Problems 3. Prediction of Forming a Precipitate One Source vs. Two Source Solubility Problems One Source Two Source • Both ions come from the same salt (source) Mg(OH)2(s) ⇋ Mg 2+ (aq) + 2 OH - (aq) • Both ions come from a different salt (source) MgS(s) ⇋ Mg 2+ (aq) +S 2- (aq) NaOH(s) ⇋ Na + (aq) + OH - (aq) Mg(OH)2(s) ⇋ Mg 2+ (aq) + 2 OH - (aq) • Ion concentrations are related through mole ratio v 1:1 ratio = v 1:2 ratio = v 1:3 ratio = v 2:3 ratio = • Related through Ksp • Ex: Find the [OH - ] if [Mg 2+ ] = 4.5 x 10 -3 M. Challenging Solubility Problems A solution has a concentration of calcium ions equal to 2.5 x 10 -2 M. What is the maximum concentration of sulphate ions allowed without causing precipitation? s s 25 X Y ksp Mg2t COH 72 5 as 2 453 X y Ksp _Cmg't foH 32 4 y S2 Mglothes Mgitag t 20 Tag 453 Ksp CMgztTCoH 72 5.6 10 12 2754 A 10855 OH gantry 4 5 10 3 saturated he Casoyes Calctag t 50472g 2.5 10 2M soup 7 7.1 15 Ksp Catcsai 7 2.5 10 2 7 1 10 5 2.5 10 2 Soy I 42.8 10 32
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