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Chemical Reactions and Quantities Chapter 7
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Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

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Page 1: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chemical Reactions and Quantities

Chapter 7

Page 2: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chemical Reactions occur Everywhere…

• …when fuel burns with oxygen in our cars to make the car move…

• …when we cook our food…

• …when we dye our hair…

• …in our bodies, chemical reactions convert food into molecules that build and move muscle…

• …in leaves of trees and plants, carbon dioxide and water are converted to carbohydrates…

Page 3: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Some chemical reactions are simple, whereas others are quite complex…

• However, they can all be written by chemical equations that chemists use to describe chemical reactions.

• In every chemical reaction, atoms are rearranged to give new substances.

– Just like following a recipe, certain ingredients are combined (and often heated) to form something new.

Page 4: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions

Page 5: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

7.1 Equations for Chemical ReactionsWrite a balanced equation from formulas of the reactants and products for a reaction; determine the number of atoms in the reactants and products.

Page 6: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chemical Change

• A chemical change occurs when a substance is converted into one or more new substances that have different formulas and properties.

• For example, when silver tarnishes, the shiny, silver metal (Ag) reacts with sulfur (S) to become the dull, black substance we call tarnish (Ag2S).

Page 7: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chemical Reaction

• A chemical reaction always involves a chemical change because atoms of the reacting substances form new combinations with new properties.

• For example, a chemical reaction (and chemical change) takes place when a piece of iron (Fe) combines with oxygen (O2) in the air to produce a new substance, rust (Fe2O3), which has a reddish-brown color.

Page 8: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Evidence of a Chemical Reaction

During a chemical change, new properties are often visible, which indicates that a chemical reaction took place.

Page 9: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chemical Equation

When you build a model airplane or prepare a new recipe, you follow a set of direction.

These directions tell you what materials to use and the products you will obtain.

In chemistry, a chemical reaction tells us the materials we need and the products that will form.

Page 10: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Writing a chemical equation

Suppose you work in a bicycle shop assembling wheels and frames into bicycles.

You could represent this by a simple equation:

Page 11: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Writing a chemical equation

Return to the silver example:

When silver tarnishes, the shiny, silver metal (Ag) reacts with sulfur (S) to become the dull, black substance we call tarnish (Ag2S).

* Unbalanced equation

Page 12: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Writing a chemical equation

Return to the iron example:A chemical reaction takes place when a piece of iron (Fe) combines with oxygen (O2) in the air to produce a new substance, rust (Fe2O3), which has a reddish-brown color.

* Unbalanced equation

Generally, each formula is followed by an abbreviation, in parentheses, that gives the physical state of the substance.

solid (s)liquid (l)gas (g)aqueous (aq) dissolved in water

Page 13: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Writing a chemical equation

Some reactions require heat to be added in order for the change to occur.

For example, when you burn charcoal in a grill, the carbon (C) in the charcoal combines with the oxygen (O2) to form carbon dioxide.

* Unbalanced equation

Page 14: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chemical equation symbols

Cu(s) + S(s) → CuS(s)

CaCO3(s) →Δ

CaO(s) + CO2(g)

Na2SO4(aq) + BaCl2(aq) → BaSO4(s) + 2NaCl(aq)

Page 15: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Identifying a balanced chemical equation

When a chemical reaction takes place, the bonds between the atoms of the reactants are broken and new bonds are formed to give the products.

Page 16: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Identifying a balanced chemical equation

All atoms are conserved which means that atoms cannot be gained, lost, or changed into another type of element during the chemical reactions

Every chemical reaction must be written as a balanced reaction, which shows the same number of atoms for each element for the reactants and in the products.

Page 17: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Balanced chemical equation

Consider the following in which hydrogen (H2) reacts with oxygen (O2) to form water:

H2(g) + O2(g) H2O(g) unbalanced

there are the same number of hydrogens on both sides (2) but different numbers of oxygen atoms (2 and 1) so it is unbalanced.

Page 18: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Balanced chemical equation

H2(g) + O2(g) H2O(g) unbalanced

We use whole numbers called coefficients in front of formulas. Coefficients indicate how many of each molecule are in an equation.

In the balanced equation, there are two H2 molecules and two H2O molecules:

This illustrates the Law of Conservation of Matter which states that matter cannot be created or destroyed during a chemical reaction.

Page 19: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Practice counting atoms

Indicate the number of each type of atom in the following balanced chemical equation:

Fe2S3(s) + 6HCl(aq) 2FeCl3(aq) + 3H2S(g)

reactants products

Fe

S

H

Cl

Page 20: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Practice counting atoms

Indicate the number of each type of atom in the following balanced chemical equation:

2C2H6(g) + 7O2(g) →Δ

4CO2(g) + 6H2O(g)

reactants products

C

H

O

Page 21: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Balancing chemical equations

When silver tarnishes, the shiny, silver metal (Ag) reacts with sulfur (S) to become the dull, black substance we call tarnish (Ag2S). What is the balanced chemical equations describing this reaction?

Page 22: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Balancing chemical equations

A chemical reaction takes place when a piece of iron (Fe) combines with oxygen (O2) in the air to produce a new substance, rust (Fe2O3), which has a reddish-brown color. What is the balanced chemical equation describing this reaction?

Page 23: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Balancing chemical equations

Balance the following chemical reaction:

Na3PO4(aq) + MgCl2(aq) Mg3(PO4)2(s) + NaCl(aq)

Page 24: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions

Page 25: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

7.2 Types of ReactionsIdentify a reaction as a combination, decomposition, single replacement,

double replacement, or combustion.

Page 26: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

A great number of reactions occur in nature, in biological systems, and in the laboratory.

However, there are some general patterns among all reactions that help us classify reactions.

* note – some reactions may fit in morethan one category.

Page 27: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Combination Reactions

• In a combination reaction, two or more elements or compounds bond to form one product.

• For example, sulfur and oxygen combine to form the product sulfur dioxide.

Page 28: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Combination Reactions

2Mg(s) + O2(g) 2MgO(s)

N2(g) + 3H2(g) 2NH3(g)

Cu(s) + S(s) CuS(s)

MgO(s) + CO2(g) MgCO3(s)

Page 29: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Decomposition Reactions

In a decomposition reaction, a reactant splits into two or more simpler products.

For example, when mercury (II) oxide is heated, the compound breaks apart into mercury atoms and oxygen.

2HgO(s) →Δ

2Hg(l) + O2(g)

Page 30: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Decomposition Reactions

CaCO3(s) →Δ

CaO(s) + CO2(g)

Fe2S3(s) 2Fe(s) + 3S(s)

Page 31: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Replacement Reactions

In a replacement reaction, elements in a compound are replaced by other elements.

In a single replacement reaction, one element switches places with another element in the reactants.

*A and B switch places.

Page 32: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Replacement Reactions

Zn(s) + 2HCl(aq) H2(g) + ZnCl2(aq)

Cl2(g) + 2KBr(s) 2KCl(s) + Br2(l)

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Replacement Reactions

In a double replacement reaction, the positive ions in the reacting compounds switch places.

Page 34: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Replacement Reactions

BaCl2(aq) + Na2SO4(aq)

NaOH(aq) + HCl(aq)

Page 35: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Combustion Reactions

The burning of a candle and the burning of fuel in the engine of a car are examples of combustion reactions.

In a combustion reaction, a carbon-containing compound burns in oxygen (O2) to produce carbon dioxide (CO2) and water (H2O) and energy in the form of heat or flame.

Fuel + O2 CO2 + H2O *unbalanced

Fuel often: methane (CH4), propane (C3H8), or similar. Sometimes also has oxygen atoms in the formula: C3H7O

Page 36: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Combustion Reactions

Fuel + O2 CO2 + H2O unbalanced

Methane gas (CH4) aka natural gas undergoes combustion when used to cook food on a gas stove:

CH4(g) + 2O2(g) →Δ

CO2(g) + 2H2O(g) + energy

Combustion of propane (C3H8):

C3H8(g) + 5O2(g) →Δ

3CO2(g) + 4H2O(g) + energy

Page 37: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Summary of Reaction Types

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Practice

Classify as combination, decomposition, single replacement, double replacement, or combustion reaction.

2Fe2O3(s) + 3C(s) 3CO2(g) + 4Fe(s)

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Practice

Classify as combination, decomposition, single replacement, double replacement, or combustion reaction.

2KClO3(s) →Δ

2KCl(s) + 3O2(g)

Page 40: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Practice

Classify as combination, decomposition, single replacement, double replacement, or combustion reaction.

C2H4(g) + 3O2(g) →Δ

2CO2(g) + 2H2O(g) + energy

Page 41: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions

Page 42: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

7.3 Oxidation-Reduction ReactionsDefine the terms oxidation and reduction, identify the

reactants as oxidized and reduced.

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Another type of reaction is the:

oxidation-reduction reaction

This is a continuation of the previous section Types of Reactions. The oxidation-reduction reaction is arguably one of the most important and undeniably the most complicated of the types we will discuss in this chapter.

Because of this, oxidation-reduction reactions has it’s own section in this chapter.

Page 44: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Perhaps you have never heard of an oxidation and reduction reaction. However, this type of reaction has many important applications in your everyday life.

▪ Rusty nail

▪ Tarnish on a silver spoon

▪ Corrosion on metal

▪ When you turn on the lights in your car, an oxidation-reduction reaction within the car battery provides the electricity.

▪ When you light a campfire, as the wood burns, oxygen combines with carbon and hydrogen to produce carbon dioxide, water, and heat.

- In section 7.2 we called this a combustion reaction. It is. It’s also a oxidation-reduction reaction.

▪ When you eat starchy food, the starches break down to give glucose which is oxidized in our cells to give you energy.

Page 45: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Oxidation-Reduction Reactions

In an oxidation-reduction reaction (redox), electrons are transferred from one substance to another.

Page 46: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Oxidation-Reduction Reactions

If one substance loses an electron, another substance must gain the electron.

The substance that lost electrons was oxidized and we define oxidation as the loss of electrons

The substance that gained electrons was reduced and we define reduction as the gain of electrons

Page 47: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Oxidation-Reduction Reactions

The substance that lost electrons was oxidized and we define oxidation as the loss of electrons

The substance that gained electrons was reduced and we define reduction as the gain of electrons

Page 48: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Redox – Example 1

The green color that appears on copper surfaces is due partly to:

2Cu(s) + O2(g) 2CuO(s)

This is a redox reaction, and we can break the equation up to show this.

Page 49: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Redox – Example 1

Break the equation into oxidation and reduction.

2Cu(s) + O2(g) 2CuO(s)

OxidationGoing from charge 0 to +2, Cu lost two electrons and Cu was oxidized.

OILRIG

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Redox – Example 1

Break the equation into oxidation and reduction.

2Cu(s) + O2(g) 2CuO(s)

ReductionGoing from charge 0 to -2, O2 gained four electrons and O2 was reduced.

(Each O went from 0 to -2 and gained 2 electrons. Because there are two oxygen atoms in O2, that’s a total of four electrons.)

OILRIG

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Redox – Example 1

To summarize:

2Cu(s) 2Cu2+(s) + 4e- oxidation

O2(g) + 4e- 2O2-

(s) reduction

In a redox reaction, there’s always two pieces that occur. One substance is oxidized (loses electrons) and another substance is reduced (gains the lost electrons).

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Redox – Example 1

Original equation:2Cu(s) + O2(g) 2CuO(s)

The two half reactions can be added back together to give the original equation.

2Cu(s) 2Cu2+(s) + 4e- oxidation

O2(g) + 4e- 2O2-

(s) reduction

Page 53: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Redox – Example 2

Zn(s) + CuSO4(aq) ZnSO4(aq) + Cu(s)

Oxidation half-reaction:

Reduction half-reaction:

___________ was oxidized

___________ was reduced

OILRIG

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Redox – Example 3

Zn(s) + Cl2(g) ZnCl2(s)

Oxidation half-reaction:

Reduction half-reaction:

___________ was oxidized

___________ was reduced

OILRIG

Page 55: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions

Page 56: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

7.4 The MoleUse Avogadro’s number to determine the number of

particles in a given number of moles.

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At the grocery store, you buy eggs by the dozen, or soda by the case. At Staples, pencils are ordered by the gross and paper by the ream.

The terms dozen, case, gross, and ream are used to count the number of items present.

Chemists do the samething, and they call itthe mole.

Page 58: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

The mole

In chemistry, particles (such as atoms, molecules, and ions) are counted by the mole which contains 6.02 x 1023 items.

Page 59: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Avogadro’s number

6.02 x 1023 is known

as Avogadro’s number.

602 000 000 000 000 000 000 000 = 6.02 x 1023

It is a very large number and we use it because atoms are so small that it takes an extremely large number of atoms to provide a usable amount to use in chemical reactions in a laboratory.

Page 60: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

The mole and Avogadro’s number

1 mole of any element always contains Avogadro’s number of atoms.

1 mole of carbon atoms contains 6.02 x 1023 carbon atoms.

1 mole of aluminum atoms contains 6.02 x 1023 aluminum atoms.

1 mole of any element = 6.02 x 1023 atoms of that element.

1 mole of any compound = 6.02 x 1023 of that compound

1 mole of CO2 contains 6.02 x 1023 molecules of CO2.

1 mole of NaCl contains 6.02 x 1023 molecules of NaCl.

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Page 62: Chemical Reactions and Quantities - Chemistry …ion.chem.usu.edu/~scheiner/LundellChemistry/lecture...hemical Reactions occur Everywhere… •…when fuel burns with oxygen in our

Converting mole ↔ particles

We use Avogadro’s number as a conversion factor to convert between the moles of a substance and the number of particles it contains.

6.02 x 1023 particles

1 mole

1 mole

6.02 x 1023 particles

The particles can be atoms, molecules, ions, or anything. Replace particles with items if that helps.

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Practice

Convert 4.00 moles of sulfur to atoms of sulfur.

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Practice

Convert 3.01 x 1024 molecules of CO2 to moles of CO2

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moles in chemical formulas

We have seen in past chapters that the subscripts in the chemical formula of a compound indicate the number of atoms of each type of element in the compound.

For example, aspirin, C9H8O4

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moles in chemical formulas

The subscripts also tell us the number of moles of each element in 1 mole of aspirin.

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moles in chemical formulas

And because 1 mole aspirin = 6.02 x 1023 molecules of aspirin

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moles in chemical formulas

We can also use subscripts from the formula, C9H8O4, we can write the conversion factors for each of the elements in 1 mole of aspirin.

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Practice

Propyl acetate, C5H10O2, gives the odor and taste of pears. How many moles of C are present in 1.50 moles of propyl acetate?

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Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions

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7.5 Molar Mass and CalculationsCalculate the molar mass for a substance given its chemical

formula; use molar mass to convert between grams and moles.

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A single atom or molecule is much too small to weigh, even using the best scale.

In fact, it takes a huge number of atoms or molecules to make enough of a substance for you to see.

An amount of water that contains Avogadro’s number of water molecules (6.02 x 1023) is only a few sips!

So in a lab, we use a scale to weigh out substances in moles.

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Molar Mass

For any element, the quantity called molar mass is the quantity in grams that equals the atomic mass of that element.

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Molar Mass

We are counting 6.02 x 1023 atoms of an element when we weigh out the number of grams equal to the molar mass.

For example, carbon has an atomic mass of 12.01 on the periodic table. This means 1 mole of carbon atoms has the mass of 12.01g.

Then to obtain 1 mole of carbon atoms, we would weigh out 12.01g of carbon.

Atomic mass of Carbon: 12.01 amuMolar mass of Carbon: 12.01 g/mol

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Using Molar Mass

The molar mass of an element is useful to convert moles of an element to grams (or grams to moles).

For example, 1 mole of sulfur as a mass of 32.066g

1 mole S = 32.066g of S

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Molar Mass of a Compound

We can calculate the molar mass of a compound by adding up the molar mass of each atom.

Example: Calculate the molar mass of lithium carbonate (Li2CO3)

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Practice

Calculate the molar mass for salicyclic acid, C7H6O3.

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Examples of 1 mole

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Calculations using Molar Mass

We can now change from moles to grams (or grams to moles) using the molar mass as a conversion factor.

Example: Convert 0.750 moles of silver to grams of silver.

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Calculations using Molar Mass

We can change moles to grams (or vice versa) for a compound using the compound’s molar mass.

Example: A box of salt contains 737 g of NaCl. How many moles of NaClare present?

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Summary

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Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions

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7.6 Mole Relationships in Chemical Equations

Give a quantity in moles of reactant or product, use a mole-mole factorfrom the balanced chemical equation to calculate the number of moles

of another substance in the reaction.

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Law of Conservation of Mass

In any chemical reaction, the total amount of matter in the reactants is equal to the total amount of matter in the products.

- an application of the Law of Conservation of Mass

Thus no material is lost or gained as original substances are changed into new substances.

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For example, tarnish (Ag2S), forms when silver reacts with sulfur to form silver sulfide:

2Ag(s) + S(s) Ag2S(s)

For every 2 silver atoms, 1 sulfur atom is required

Or

For every 2 moles of silver atoms, 1 mole of sulfur atoms is required.

Because the molar mass can be determined, the moles of Ag, S, and Ag2S can also be stated in terms of mass (grams) of each…

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Thus 215.8 g of Ag and 32.1 g of S reacts to form 247.9 g of Ag2S.

215.8g + 32.1g = 249.9g

The total mass of reactants (249.9 g) equals the total mass of the products (249.9 g).

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Info in a balanced equation

The various ways in which a chemical equation can be interpreted:

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Mole-mole factors

When iron reacts with sulfur, the product is iron(III) sulfide:

2Fe(s) + 3S(s) Fe2S3(s)

From the balanced equation, we see that 2 moles of iron reacts with 3 moles of sulfur to form mole of iron(II) sulfide.

(Actually, any amount of iron or sulfur may be used, but the ratio of iron reacting with sulfur will always be the same.)

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Mole-mole factors

From the coefficients, we can write mole-mole factors between any two compounds in an equation.

2Fe(s) + 3S(s) Fe2S3(s)

Fe and S:

Fe and Fe2S:

S and Fe2S:

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Mole-mole factors in calculations

Whenever you prepare a recipe, you need to know the proper amounts of ingredients and how much the recipe will make.

The same is true for chemistry.

Now that we have written all the possible mole-mole factors for

2Fe(s) + 3S(s) Fe2S3(s)

we will use those mole-mole factors in a chemical calculation.

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Practice #1

How many moles of sulfur are needed to react with 1.42 moles of iron?

2Fe(s) + 3S(s) Fe2S3(s)

2 moles Fe

3 moles S

2 moles Fe

1 mole Fe2S3

3 moles S

1 moleFe2S3

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Practice #2

How many moles of iron are needed to react with 2.75 moles of sulfur?

2Fe(s) + 3S(s) Fe2S3(s)

2 moles Fe

3 moles S

2 moles Fe

1 mole Fe2S3

3 moles S

1 moleFe2S3

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Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions

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7.7 Mass Calculations for Reactions

Given the mass in grams of a substance in a reaction, calculate the mass in grams of another substance in the reaction.

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When we have the balanced chemical equation for a reaction, we can use the mass of one of the substances (A) to calculate the mass of a second (B).

However, the calculations require us to convert the mass of A to the moles of A (using A’s molar mass). Then we use the mole-mole factor to convert moles A to moles B. Then finally use B’s molar mass to convert moles B to grams B.

grams A moles A mole B grams B

molarmass A

molarmass B

mole-molefactor

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Practice

How many grams of CO2 are produced when 54.6g of C2H2 is burned?

2C2H2(g) + 5O2(g) →Δ

4CO2(g) + 2H2O(g)

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Practice

Calculate grams CO2 produced when 25 g of O2 reacts.

2C2H2(g) + 5O2(g) →Δ

4CO2(g) + 2H2O(g)

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Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions

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7.8 Limiting Reactants and Percent Yield

Identify the limiting reactant and calculate the amount of product formed from the limiting reactant. Given the actual quantity of product,

determine the percent yield for a reaction.

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When you make peanut butter sandwiches for lunch, you need 2 slices of bread and 1 tablespoon of peanut butter for each sandwich.

+

If you have 8 slices of bread and a full jar of peanut butter, you will run out of bread after you make 4 peanut butter sandwiches once the bread is used up, even though there is a lot of peanut butter left in the jar. The number of slices of bread has limited the number of sandwiches you can make.

Limiting Reactant

1 peanut buttersandwich

1 Tbl. peanutbutter

2 slicesbread

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On a different day, you might have 8 slices of bread but only a tablespoon ofpeanut butter left in the peanut butter jar. You will run out of peanut butterafter you make just 1 sandwich and have 6 slices of bread left over. The smaller amount of peanut butter available has the limited the number of sandwiches you can make.

Limiting Reactant

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Limiting Reactant

The reactant that is completely used up is the limiting reactant.

The reactant that does not completely react and is left over iscalled the excess reactant.

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In the same way, the reactants in a chemical reactions do not always combine in quantities that allow each to be used up at exactly the same time.

In many reactions, there is a limiting reactant that determines the amount of product that can be formed.

Moles from Limiting Reactant

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When we know the quantities of the reactants of a chemical reaction we calculate the amount of product that is possible from each reactant if it were completely consumed. The limiting reactant is the one that runs out first and produces the smaller amount of product.

Identifying Limiting Reactant

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If 3.00 moles of CO and 5.00 moles of H2 are the initial reactants, what is the limiting reactant? And how many moles of CH3OH can be produced.

CO(g) + 2H2(g) CH3OH(g)

Practice #1

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If 4.00 moles of CO and 4.00 moles of H2 are the initial reactants, what is the limiting reactant? And how many moles of CH3OH can be produced.

CO(g) + 2H2(g) CH3OH(g)

Practice #2

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The quantities of the reactants can also be given in grams. We combine knowledge from sections 7 and 8 to find the limiting reactant.

The calculation to find the limiting reactant is the same as the last two Practice slides. But before we can do it, we must convert grams to moles.

- Subscripts in chemical equations are not grams!!- You need to use moles to compare subscripts!!

Mass from Limiting Reactant

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How many grams of CO are formed from 70.0 g of SiO2 and 50.0 g of C?

SiO2(s) + 3C(s) →Δ

SiC(s) + 2CO(g)

Practice

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In our reactions so far we have assumed 100% efficiency, meaning all of the reactants changed completely to products.

While this is ideal, it’s hardly reality. Often, reactant is lost when moving from container to container, chemicals aren’t 100% pure, and unwanted side reactions use up reactant making unwanted products. Thus 100% of the desired product is not actually obtained.

When we do a chemical reaction in the lab, we measure out specific quantities ofthe reactants. We then calculate the theoretical yield for the reaction. Which is the amount of product (100%) we would expect if all the reactants were converted to the desired products.

When the reaction ends, we collect and measure the mass of the product that was actually made. This is called the actual yield.

Because the reaction is hardly ever 100% efficient the actual yield is less than the theoretical yield.

Percent Yield

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We can represent the ratio of actual yield to theoretical yield in one number called percent yield.

% yield =actual yield

theoretical yieldx 100

Percent Yield

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What is the % yield of LiHCO3 for the reaction if 50.0 g of LiOH gives 72.8 g LiHCO3.

LiOH(s) + CO2(g) LiHCO3(s)

Practice

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Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions

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7.9 Energy in Chemical Reactions

Given the heat of reaction, calculate the loss or gain of heat for an exothermic or endothermic reaction.

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Almost every chemical reaction involves a loss or gain of energy.

To discuss energy change for a reaction, we look at the energy of the reactants before the reaction and the energy of the products after the reaction.

The SI unit for energy is the joule (J)

1 kilojoule (kJ) = 1000 joules (J)

Energy in Chemical Reactions

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Energy is often present as heat.

The heat of reaction is the amount of heat absorbed or releasedduring a reaction that takes place at constant pressure.

A change of energy occurs as reactants interact, bonds break apart, and products form.

Another name for heat of reaction is enthalpy change.

ΔH = Hproducts - Hreactants

Heat of Reaction

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In an exothermic reaction the energy of the products is lower than that of the reactants.

- Heat is released along with the products that form.

For example when 1 mole of H2 and 1 mole of Cl2 react, 2 mole HCl form. Theenergy of the HCl is 185kJ less than the H2 and Cl2

Exothermic Reactions

Because products are lower energy, thatenergy difference is released as heat.

We write ΔH with a negative sign to indicate exothermic.

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Hot packs are used in medicine, camping gear, emergency kits, etc.Inside the hot pack are two pouches. One pouch has water, the other has CaCl2 When the boundary is broken between pouches an exothermic reaction takes place and releases heat.

CaCl2(s)

𝐻2𝑂CaCl2(aq)

Temperatures can increase as much as 66C

Exo example: Hot Packs

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In an endothermic reaction, the energy of the products is higher than that of the reactants.

- Heat is required to begin the reaction and convert reactants to products.

For example: 1 mole N2 and 1 mole O2 react to form 2 moles NO only when at least 180 kJ of heat is added.

Endothermic Reactions

We write ΔH with a positive sign to indicate endothermic.

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Cold packs work the same way with two pouches. One pouch as water, the other has NH4NO3. The temperature can drop to 4-5C.

NH4NO3(s) + 26kJ𝐻2𝑂

NH4NO3(aq)

Endo example: Cold Packs

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The value of ΔH refers to the heat change for each substance in the balanced equation.

2H2O(l) 2H2(g) + O2(g) Δ H = +572 kJ

means that for this reaction, +572 kJ are absorbed by 2 moles of H2O to produce 2 moles of H2 an 1 mole of O2.

We can use ΔH to write conversion factors just like the mole-mole factors from section 7.6.

Calculations of Heat in Reactions

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Suppose that 9.00 g H2O undergoes the reaction. Calculate the heat absorbed.

2H2O(l) 2H2(g) + O2(g) Δ H = +572 kJ

Calculations of Heat in Reactions

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How much heat, in kJ, is released when nitrogen and hydrogen react to form 50.0g of ammonia (NH3)?

N2(g) + 3H2(g) 2NH3(g) Δ H = -92.2 kJ

Practice

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Chapter Seven

7.1 – Equations for Chemical Reactions

7.2 – Types of Reactions

7.3 – Oxidation-Reduction Reactions

7.4 – The Mole

7.5 – Molar Mass and Calculations

7.6 – Mole Relationships in Chemical Equations

7.7 – Mass Calculations for Reactions

7.8 – Limiting Reactants and Percent Yield

7.9 – Energy in Chemical Reactions