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Chemical Reactions and Collision Theory Chemistry I 2007
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Page 1: Chemical Reactions and Collision Theory Chemistry I 2007.

Chemical Reactions and Collision Theory

Chemistry I 2007

Page 2: Chemical Reactions and Collision Theory Chemistry I 2007.

Chemical reaction Format

Generic Format

A + B C + D

Reactants Products

Substances being mixed

LHS of arrow

Substance being made

RHS of arrow

“Yield” = reaction taking place

Page 3: Chemical Reactions and Collision Theory Chemistry I 2007.

Types of Chemical Reactions

5 main types of Chemical Reactions

1) Synthesis

2) Decomposition

3) Single Displacement

4) Double Displacement

5) Combustion

Page 4: Chemical Reactions and Collision Theory Chemistry I 2007.

Synthesis

Synthesis means “to make”

Generic RXN

A + B C

Always

makes

1 product

Real Life reaction

Fe

Iron main component in steel

Oxygen

Iron (III) Oxide

AKA RUST

Fe2O3+ O2

Page 5: Chemical Reactions and Collision Theory Chemistry I 2007.

DecompositionDecomposing video

Generic Reaction

A B + C

Only 1 Reactant

Real Life Reaction

H2O2 H2 + O2

Hydrogen Peroxide

Page 6: Chemical Reactions and Collision Theory Chemistry I 2007.

Single Displacement

Generic Reaction

A + XY X + AY

OR

A + XY Y + XA

Metal for a metal

Non-metal for a Non-metal

Page 7: Chemical Reactions and Collision Theory Chemistry I 2007.

Single Displacement

A + XY X + AY

Always a Single Element

Always a Compound (2 or more elements)

Page 8: Chemical Reactions and Collision Theory Chemistry I 2007.

Single Displacement

Al + HCl H2 + AlCl3

Single Element

Compound (2 or more elements)

Page 9: Chemical Reactions and Collision Theory Chemistry I 2007.

Double Displacement

Generic Reaction

AB + XY XB + AY

2 Compounds

(2 or more elements bonded together)

Page 10: Chemical Reactions and Collision Theory Chemistry I 2007.

Double displacement

KI + Pb(NO3)2

Compound 1 Compound 2

PbI2 + KNO3

K and Pb switch

Page 11: Chemical Reactions and Collision Theory Chemistry I 2007.

CombustionGeneric reaction

CxHy + O2 CO2 + H2O

ALWAYSHydrocarbon

Burning a substance in the presence of oxygen (O2)

Page 12: Chemical Reactions and Collision Theory Chemistry I 2007.

Combustion

C8H18 + O2 CO2 + H2O

Octane

Gasoline

CH3OH + O2 CO2 + H2O

Methanol

Page 13: Chemical Reactions and Collision Theory Chemistry I 2007.

Chemical Reaction Review

Generic Format of reaction

5 different types of chemical reactions

A + B C + D

Reactants Products

A + B C + D

Products

1) Synthesis

2) Decomposition

3) Single Displacement

4) Double Displacement

5) Combustion

Page 14: Chemical Reactions and Collision Theory Chemistry I 2007.

How do reactions occur?

Collision Theory Collision TheoryCollision Theory

In order for a chemical reaction to take place, the reactants must collide.

The collision transfers kinetic energy needed to break the necessary bonds so that new bonds can be formed.

Page 15: Chemical Reactions and Collision Theory Chemistry I 2007.

Collision requirements

Requirement 1Must have the proper orientation. 2HCl + Mg MgCl2 + H2

H---ClMgWrong Orientation

H-Cl MgH Cl-Mg Correct Orientation

Page 16: Chemical Reactions and Collision Theory Chemistry I 2007.

Collision requirements

Requirement 2

Mg

Must have enough kinetic energy to reach a threshold of energy called activation energy

H---Cl H---Cl MgH Cl--Mg

Page 17: Chemical Reactions and Collision Theory Chemistry I 2007.

Energy of Activation

Page 18: Chemical Reactions and Collision Theory Chemistry I 2007.

Energy of Activation

Page 19: Chemical Reactions and Collision Theory Chemistry I 2007.

Increasing the Rate of Reactions

What needs to happen in order for the rate of the chemical reaction to increase (go faster)?

More collisions = Faster reaction rate

Page 20: Chemical Reactions and Collision Theory Chemistry I 2007.

4 Factors that cause more collisions

1) ____________

2) ____________

3) ____________

4) ____________

Page 21: Chemical Reactions and Collision Theory Chemistry I 2007.

5th way in increase Rxn Rate

Add a Catalyst = Speeds up a reaction but is not used in the reaction

Lowers the activation energy

Page 22: Chemical Reactions and Collision Theory Chemistry I 2007.

Summary• Molecules must collide with the correct

orientation and enough energy in order to react.

More collisions Faster the reaction rate.

Increase Temperature, Concentration, Pressure, and surface area results in more collisions therefore faster reactions.

Adding a catalysts lowers the energy of activation thus faster reaction rate.