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Chem Vocab

Apr 04, 2018

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    absolute zero

    the temperature at which all molecular motion should cease(two words)

    accelerator

    a device that is used to accelerate charged particles to high speeds

    accuracy

    the relationship between the graduations on a measuring device and the actual standard for the quantitybeing measured

    acid

    a substance that produces hydrogen ions in water solution; a proton donor

    acidic anhydride

    a nonmetallic oxide that can react with water to form an acid(two words)

    actinoid series

    fourteen elements beginning with actinium in which the arrow diagram predicts the highest energyelectrons to be in the 5f sublevel(two words)

    activated complex

    an assembly of atoms in an excited state between reactants and products in a chemical reaction(two words)

    activation energy

    the [energy] required to form the activated complex(two words)

    activity

    the effective concentration of a species

    addition polymerization

    the formation of a polymer through addition reactions(two words)

    addition reaction

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    a [reaction]; the combining of two or more molecules through adding on at the double or triple bond of anunsaturated organic compound(two words)

    adiabatic system

    [system] in which heat neither leaves nor enters(two words)

    adsorption

    the process of one substance being attracted and held to the surface of another substance

    alcohol

    one of a class of organic compounds characterized by the presence of the hydroxyl group, -OH

    aldehyde

    one of the class of organic compounds characterized by the presence of the carbonyl group (>C = 0) onthe end of the carbon chain(RCHO)

    aliphatic

    hydrocarbons consisting of chains or nonaromatic rings

    alkali metal

    an element in Group 1(IA)(two words)

    alkaline earth metal

    an element in Group 2(IIA)(three words)

    alkane

    an aliphatic hydrocarbon having only single carbon-carbon bonds

    alkene

    an aliphatic hydrocarbon having one or more double bonds

    alkyne

    an aliphatic hydrocarbon having one or more triple bonds

    allotrope

    form of an element differing in crystal or molecular structure

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    alloy

    a mixture of a metal and one or more other elements, usually metals

    alpha particle

    a helium nucleus(two words)

    amide

    an organic compound containing the -CO-NH2 group; an inorganic compound containing NH2

    amine

    an organic compound derived from ammonia by replacement of one or more hydrogen atoms byhydrocarbon radicals

    amino acid

    an organic compound characterized by the presence of an amino group and a carboxyl group on thesame carbon atom(two words)

    amorphous

    a non-crystalline material that appears solid but without long-range order; supercooled liquid

    ampere

    the unit of electric current equal to one coulomb per second

    amphoteric

    having the ability to act as either an acid or a base

    amplitude

    the maximum value attained by a wave

    anhydrous

    without water

    anion

    a negative ion

    anode

    the positive electrode (general); the electrode at which oxidation occurs (electrochemical)

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    antiparticle

    a particle identical to a second particle in all respects except for opposite charge and magnetic moment

    aromatic compound

    an organic ring [compound] containing one or more benzene rings(two words)

    arrow diagram

    a system for predicting the order of filling energy sublevels with electrons(two words)

    atom

    the smallest particle of an element

    atomic mass

    the [mass] of an atom in atomic mass units; the average mass of the atoms of an element(two words)

    atomic mass unit

    one-twelfth the mass of the carbon-12 atom(three words)

    atomic number

    the [number] of protons in the nucleus of an atom(two words)

    atomic radius

    the distance from the center of an atom to the 90% probability surface of the electron cloud(two words)

    atomic theory

    the body of knowledge concerning the existence of atoms and their characteristic structure(two words)

    Avogadro constant

    the number of objects in a mole; 6.022 136 7 x 10^23(two words)

    Avogadro's principle

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    The [principle] that equal volumes of gases at the same temperature and pressure contain the samenumber of molecules.(two words, possessive)

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    balance

    an instrument used to measure mass

    barometer

    a manometer used to measure atmospheric pressure

    baryon

    a subatomic particle classified as a heavy hadron

    base

    a substance that produces hydroxide ions in water solution; a proton acceptor

    basic anhydride

    a metallic oxide that will react with water to form a base(two words)

    beta particle

    an electron (-) or positron (+)(two words)

    binary acid

    an [acid] containing only hydrogen and one other element(two words)

    binary compound

    a [compound] composed of only two elements(two words)

    binding energy

    the [energy] required to split the nucleus into separate nucleons(two words)

    biochemistry

    the study of the substances and reactions involved in life processes

    body-centered cubic

    having a unit cell with a particle at each vertex of a cube and a particle in the center of the cube(three words, hyphenated)

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    Bohr atom

    planetary [atom] model(two words)

    boiling point

    the temperature at which the vapor pressure of a liquid equals the atmospheric pressure(two words)

    bond

    the force holding atoms together in a compound or molecule

    bond angle

    the [angle] between two bond axes extending from the same atom(two words)

    bond axis

    the imaginary line connecting the nuclei of two bonded atoms(two words)

    bond character

    the relative ionic or covalent nature of a chemical bond(two words)

    bond length

    the distance between the nuclei of bonded atoms(two words)

    bond strength

    the energy required to break a bond(two words)

    Boyle's law

    The volume of a specific amount of gas varies inversely as the pressure if the temperature remainsconstant.(two words, possessive)

    branch

    a carbon group, named as a radical, that is attached to the main carbon chain in an organic compound

    Brownian motion

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    the random [motion] of colloidal particles due to their bombardment by the molecules of the dispersingmedium(two words)

    buffer system

    a solution that can receive moderate amounts of either acid or base without significant change in its pH.(two words)

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    calorimeter

    a device for measuring the transfer of heat during a chemical or physical change

    capillary rise

    the tendency of a liquid to [rise] in a tube of small diameter due to the surface tension of the liquid(two words)

    carbide ion

    a carbon atom that has gained four electrons; C^4-(two words)

    carbohydrate

    compounds of carbon, hydrogen, and oxygen that are mostly simple sugars or condensation polymers ofsugars

    carboxylic acid

    the class of organic compounds characterized by the carboxyl group (-COOH)(two words)

    catalysis

    the speeding up of chemical reactions by the presence of a substance that is unchanged after thereaction

    catalyst

    a substance that speeds a chemical reaction without being permanently changed itself

    catenation

    the joining of like atoms in chains.

    cathode

    the negative electrode (general); the electrode at which reduction occurs (electrochemical)

    cathode rays

    the beam of electrons in a gas discharge tube(two words, plural)

    cation

    a positive ion

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    cell potential

    the voltage obtained from a voltaic cell(two words)

    cellulose

    a woody polymer of glucose

    Celsius scale

    the temperature scale based on the boiling point of water as 100 degrees and the freezing point of wateras 0 degrees(two words)

    chain reaction

    a [reaction] in which the product from each step acts as a reactant for the next step

    (two words)

    chalcogen

    an element in Group 16(VIA)

    Charles's law

    The volume of a specific amount of gas varies directly as the absolute temperature if the pressureremains constant.(two words, possessive)

    chemical change

    a [change]; a rearrangement of atoms and/or molecules to produce one or more new substances withnew properties(two words)

    chemical formula

    the notation using symbols and numerals to represent the composition of substances(two words)

    chemical property

    a [property] characteristic of a substance when it is involved in a chemical change(two words)

    chemical reaction

    a [reaction] in which one or more substances are changed into one or more new substances(two words)

    chemical symbol

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    a notation using one to three letters to represent an element(two words)

    chemistry

    the study of the structure and properties of matter

    chromatography

    the separation of a mixture using a technique based upon differential adsorption between a stationaryphase and a mobile phase

    closest packing

    the crystal structure in which space between particles is minimized(two words)

    coefficient

    a numeral, representing the number of formula units of the substance, placed before a formula

    colligative properties

    the [properties] of solutions that depend only on the number of particles present without regard to type(two words, plural)

    colloid

    a dispersion of particles from 1 nm to 100 nm in at least one dimension in a continuous medium

    colloid chemistry

    the study of colloids, especially of surfaces(two words)

    column chromatography

    [chromatography] in which the stationary phase is held in a column(two words)

    combustion

    burning, or reaction with oxygen producing heat and usually light

    common ion effect

    an equilibrium phenomenon in which an ion common to two or more substances in a solution shifts thepoint of equilibrium away from itself(three words)

    complex ion

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    a [catalyst] that functions by adsorbing one of the reactants on its surface; a heterogeneous catalyst(two words)

    containment vessel

    a reinforced concrete and steel structure designed to contain any leakage from a nuclear reactor

    (two words)

    continuous phase

    the dispersing medium in a colloid(two words)

    control rod

    the neutron-absorbing substance used to control the rate of reaction in a nuclear reactor(two words)

    coordinate covalent bond

    a covalent [bond] in which both electrons of the shared pair come from the same atom(three words)

    coordination number

    the [number] of points at which ligands are attached to the central atom or ion in a complex ion orcoordination compound(two words)

    corrosion

    the chemical interaction of a metal with its environment

    coulomb

    the quantity of electrical charge equal to the flow of one ampere for one second

    counting number

    natural [number]; any cardinal number except zero(two words)

    covalent bond

    a [bond] characterized by the sharing of one or more pairs of electrons between two atoms(two words)

    covalent radius

    the [radius] of an atom along the bond axis(two words)

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    critical pressure

    the [pressure] needed to liquefy a gas at its critical temperature(two words)

    critical temperature

    the highest [temperature] at which the vapor and liquid states of a substance can exist in equilibrium(two words)

    crystal

    a solid in which the particles are arranged in a regular, repeating pattern; a lattice

    crystal defect

    an imperfection in a crystal lattice(two words)

    crystallization

    the forming of crystals by evaporation or cooling

    crystalloid

    a substance that can penetrate a semipermeable membrane

    cubic closest packing

    face-centered cubic

    (three words)

    cyclic

    consisting of atoms bonded in a closed ring

    cycloalkanes

    hydrocarbons in which the carbon atoms are bonded in a ring and all bonds are single bonds(plural)

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    Dalton's law

    In a mixture of gases, the total pressure of the mixture is the sum of the partial pressures of eachcomponent gas.

    (two words, possessive)

    de Broglie's hypothesis

    the [hypothesis] that particles may have the properties of waves.(two words, possessive)

    decomposition

    a reaction in which a compound breaks into two or more simpler substances

    degenerate

    having the same energy

    dehydrating agent

    a substance that can absorb water from other substances(two words)

    deliquescent

    the property of a solid to absorb sufficient water from the air to form a liquid solution

    delocalization

    the concept in which bonding electrons are not confined to the region between two atoms, but may bespread over several atoms or a whole piece of metal

    density

    mass per unit volume

    desiccant

    a drying agent

    didentate

    a ligand that attaches to the central ion in a complex in two places

    diffusion

    the spontaneous spreading of particles throughout a given volume until they are uniformly distributed

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    dilute solution

    a [solution] with a low ratio of solute to solvent(two words)

    dipeptide

    two amino acids joined by an amide link

    dipole

    a polar molecule

    dipole-dipole force

    an attraction between dipoles; component of van der Waals forces(three words, hyphenated)

    dipole-induced dipole force

    an attraction between a dipole and a nonpolar molecule that has been induced to become a dipole;component of van der Waals forces(four words, hyphenated)

    dipole moment

    the strength of a dipole expressed as charge multiplied by distance(two words)

    dislocation

    a crystal defect

    dispersed phase

    colloidal particles distributed throughout the continuous phase(two words)

    dispersion forces

    the [forces] between particles that are not permanent dipoles; component of van der Waals forces(two words, plural)

    dissociation

    the separation of ions in solution

    distillation

    a separation method based on the evaporation of a liquid and the condensation of its vapor

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    electromagnetic energy

    radiant [energy]; energy transferred by electromagnetic waves(two words)

    electron

    an elementary particle with unit negative charge

    electron affinity

    the attraction of an atom for an electron(two words)

    electron cloud

    the space effectively occupied by an electron in an atom(two words)

    electron configuration

    a description of the arrangement of the electrons in an atom(two words)

    electronegativity

    the relative attraction of an atom for a shared pair of electrons

    electronic conduction

    the flow of electrons in a metal(two words)

    electrophoresis

    the migration of colloidal particles in an electric field

    element

    a substance whose atoms all have the same number of protons in the nucleus

    elimination reaction

    an organic [reaction] in which a small molecule is removed from a larger molecule leaving a double bondin the larger molecule(two words)

    empirical formula

    the [formula] giving the simplest ratio between the atoms of the elements present in a compound(two words)

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    endergonic

    a process having an increase in Gibbs free energy

    endothermic

    a change that takes place with the absorption of heat

    endpoint

    the point in a titration where equivalent amounts of reactants are present

    energy

    a property of matter that can be converted to work under the proper circumstances

    energy level

    a specific energy or group of energies that may be possessed by electrons in an atom(two words)

    energy sublevel

    a specific energy that may be possessed by electrons within an energy level in an atom(two words)

    enthalpy

    that part of the energy of a substance that is due to the motion of its particles added to the product of itsvolume and pressure

    enthalpy of formation

    the net amount of energy produced or consumed when a mole of a compound is formed from its elements(three words)

    enthalpy of fusion

    the energy required to change 1 gram of a substance from solid to liquid(three words)

    enthalpy of reaction

    the change in enthalpy accompanying a chemical [reaction](three words)

    enthalpy of solution

    the change in enthalpy when one substance is dissolved in another(three words)

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    enthalpy of vaporization

    the energy needed to change 1 gram of a substance from liquid to gas(three words)

    entropy

    the degree of disorder in a system

    enzyme

    a biological catalyst

    equation

    a symbolic expression representing a chemical change

    equilibrium

    a state in which no net change takes place in a system

    equilibrium constant

    a mathematical expression giving the ratio of the product of the concentrations of the products to theproduct of the concentrations of reactants in a chemical reaction(two words)

    ester

    an organic compound characterized by the functional group R-CO-O-R'

    esterification

    the production of an ester by the reaction of an alcohol with a carboxylic acid

    ether

    an organic compound characterized by the functional group R-0-R'

    evaporation

    the process by which surface particles of liquids escape into the vapor state

    excess reactant

    reactant remaining when all of some other reactant has been consumed

    exergonic

    a process having a decrease in Gibbs free energy

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    exothermic

    a change that produces heat

    experiment

    a test of a hypothesis under controlled conditions

    extensive property

    a [property] dependent on the amount of matter present(two words)

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    galvanizing

    the coating of iron with a protective layer of zinc

    galvanometer

    an instrument used to detect an electric current

    gamma ray

    a quantum of energy of very high frequency and very short wavelength(two words)

    gas

    the state of matter in which particles are far apart and moving randomly

    gas chromatography

    a chromatographic method in which a carrier gas (inert) distributes the vapor being analyzed in a packedcolumn(two words)

    geometric isomers

    compounds with the same formula but different arrangement of substituents around a double bond(two words, plural)

    Gibbs free energy

    the chemical reaction potential of a substance or system(three words)

    gluon

    a theoretical massless particle exchanged by quarks

    glycogen

    a biological (specifically animal) polymer of glucose

    Graham's law

    The ratio of the relative rates of diffusion of gases is equal to the square root of the inverse ratio of theirmolecular masses.(two words, possessive)

    gray

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    hadrons

    a class of heavy subatomic particles; leptons and _____.(plural)

    half-cell

    the part of an electrochemical cell in which either the oxidation or reduction reaction is taking place; singleelectrode in contact with the solution of an electrolyte(two words, hyphenated)

    half-life

    the length of time necessary for one-half an amount of a radioactive nuclide to disintegrate(two words, hyphenated)

    half-reaction

    either the oxidation or the reduction part of a redox reaction(two words, hyphenated)

    halogen

    an element in Group 17(VIIA)

    heat

    energy transferred due to differences in temperature

    Heisenberg uncertainty principle

    It is impossible to know exactly both the position and momentum of an electron at the same instant.(three words)

    Henry's law

    The mass of gas that will dissolve in a specific amount of a liquid varies directly with the pressure.(two words, possessive)

    hertz

    the unit of frequency equal to one cycle per second

    Hess's law

    The enthalpy change for an overall reaction is equal to the sum of the enthalpy changes for all steps ofthe reaction.(two words, possessive)

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    heterogeneous

    composed of more than one phase

    heterogeneous catalyst

    a [catalyst] in a phase different from that of the reactants(two words)

    heterogeneous mixture

    a combination of two or more substances that are not uniformly dispersed(two words)

    heterogeneous reaction

    a [reaction] in which not all reactants are in the same phase(two words)

    hexagonal closest packing

    having a crystal structure in which space between particles is minimized; found in most metals(three words)

    high performance liquid chromatography

    a type of column chromatography in which the surface area of the particles in the stationary phase isincreased(four words)

    homogeneous

    uniform throughout

    homogeneous catalyst

    a [catalyst] in the same phase as the reactants(two words)

    homogeneous reaction

    a [reaction] in which the reactants are in the same phase(two words)

    homologous series

    compounds that differ from each other by a specific structural unit(two words)

    hybrid orbitals

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    equivalent [orbitals] formed from orbitals of different energies(two words, plural)

    hybridization

    the merging of two or more unlike orbitals to form an equal number of identical orbitals in an atom

    hydrate

    a compound (crystalline) in which the ions are attached to one or more water molecules

    hydrated ion

    complex ion in which the ligands are water molecules(two words)

    hydration

    the adhering of water molecules to dissolved ions

    hydride ion

    a hydrogen atom that has gained an electron; H^-(two words)

    hydrocarbon

    compound containing only the elements hydrogen and carbon

    hydrogen bonding

    a very strong dipole-dipole interaction involving molecules in which hydrogen is bonded to a highlyelectronegative element (N, 0, F)(two words)

    hydrogen ion

    a hydrogen atom that has lost its electron; H^+; a proton(two words)

    hydrolysis

    the reaction of a salt with water to form a weak acid or weak base, or both

    hydronium ion

    H30^+(two words)

    hygroscopic

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    absorbing water from the air

    hypothesize

    to propose an explanation based on observations

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    ideal gas

    a model in which [gas] particles are mass points and exert no attraction for each other(two words)

    ideal gas equation

    PV = nRT(three words)

    ideal solution

    a [solution] in which all intermolecular forces are roughly equal(two words)

    immiscible

    a property of two liquids that will not dissolve in each other at all

    indicator

    a weak organic acid whose color differs from that of its conjugate; used to indicate the pH of a solution

    induced dipole

    a nonpolar molecule that is transformed into a [dipole] by an electric field(two words)

    inductive effect

    the influence of one functional group on another(two words)

    inertia

    the tendency of an object to resist any change in its velocity

    infrared spectroscopy

    the study of the behavior of matter when it is exposed to infrared radiation

    (two words)

    inhibitor

    a substance that stops or retards a chemical reaction by forming a complex with a reactant

    inner transition elements

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    isomer

    a substance that has the same molecular formula as another substance, but differs in structure; asubstance that exhibits isomerism with another substance

    isomerism

    the property of having more than one structure for the same formula

    isomorphism

    condition of two or more compounds having the same crystalline structure

    isothermal process

    a [process] taking place at constant temperature(two words)

    isotope

    one of two or more atoms having the same number of protons but different numbers of neutrons

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    joule

    the SI unit of energy; 1 kg-m^2/s^2

    Joule-Thomson effect

    the cooling [effect] observed when a compressed gas is allowed to expand rapidly through a smallopening(three words, hyphenated)

    kelvin

    the SI unit of temperature; 1/273.16 of the interval between absolute zero and the triple point of water

    Kelvin scale

    the temperature [scale] with 0 equal to absolute zero and 273.16 equal to the triple point of water(two words)

    ketone

    an organic compound characterized by the functional group R-CO-R'

    kilogram

    the SI unit of mass

    kinetic energy

    the [energy] of an object due to its motion(two words)

    kinetic theory

    the group of ideas explaining the interaction of matter and energy due to particle motion(two words)

    kinetically stable

    property of a compound for which the activation energy for decomposition is so high that reaction

    proceeds too slowly for a change to be detected(two words)

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    light subatomic particles(plural)

    Lewis electron dot diagram

    the representation of an atom, ion, or molecule in which an element symbol stands for the nucleus and all

    inner level electrons while dots stand for outer level electrons(four words)

    ligand

    a negative ion or polar molecule attached to a central ion in a complex

    limiting reactant

    the [reactant] that is consumed completely in a chemical reaction(two words)

    linear accelerator

    a device for accelerating particles in a straight line(two words)

    lipid

    a biological molecule that is soluble in nonpolar solvents

    liquefaction

    condensing a gas to a liquid

    liquid

    the state of matter characterized by its constituent particles appearing to vibrate about moving points

    liquid crystal

    a substance that has order in the arrangement of its particles in only one or two dimensions(two words)

    liter

    one cubic decimeter

    London forces

    another name for dispersion [forces](two words, plural)

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    macromolecule

    a crystal composed of a single molecule with all atoms covalently bonded in a network fashion

    magnetohydrodynamics

    the study of the behavior of plasmas in magnetic fields

    malleability

    noun--the property of a substance that allows it to be beaten into thin sheets

    manometer

    a device for measuring gas pressure

    mass

    measure of the amount of matter

    mass defect

    the difference between the mass of an atom and the sum of the masses of the particles composing it(two words)

    mass-energy stoichiometry

    a problem in which the amount of energy absorbed or released during a reaction can be calculated fromthe mass of materials(three words, hyphenated)

    mass-mass stoichiometry

    a problem in which the mass of one substance is provided and the mass of another substance must becalculated(three words, hyphenated)

    mass number

    the total [number] of protons and neutrons in an atom(two words)

    mass spectrometry

    an analysis of substances on the basis of the behavior of their ionized forms in magnetic and electricfields(two words)

    material

    a specific kind of matter

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    a material consisting of two or more substances

    mobile phase

    the fluid containing the mixture to be fractionated in chromatography(two words)

    model

    an arrangement analogous to, and useful for, understanding a system in nature, but existing only in one'smind

    moderator

    a substance used to slow neutrons in a nuclear reactor

    molal boiling point constant

    the change of the boiling point of a solvent in a one-molal solution(four words)

    molal freezing point constant

    the change of the freezing point of a solvent in a one-molal solution(four words)

    molality

    a unit of concentration equal to the number of moles of solute per kilogram of solvent

    molar heat capacity

    the energy necessary to raise the temperature of one mole of a substance by one Celsius degree(three words)

    molar mass

    the [mass] in grams of one mole of a substance(two words)

    molar volume

    the [volume] occupied by one mole of a substance; equal to 22.414 10 dm^3 for a gas at standardtemperature and standard atmospheric pressure(two words)

    molarity

    a unit of concentration equal to the number of moles of solute in a cubic decimeter of solution

    mole

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    the Avogadro constant number of objects

    mole fraction

    a unit of concentration equal to the number of moles of component per mole of solution(two words)

    molecular formula

    a [formula] indicating the actual number of atoms of each element making up a molecule(two words)

    molecular mass

    the [mass] found by adding the atomic masses of the atoms comprising the molecule(two words)

    molecule

    a neutral group of atoms held together by covalent bonds

    momentum

    the product of mass and velocity

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    nematic substance

    a [substance] that is a liquid crystal with one dimension of order(two words)

    net ionic equation

    a chemical [equation] with spectator ions eliminated(three words)

    network crystal

    a [crystal] in which each atom is covalently bonded to all its nearest neighbors, so that the entire crystal isone molecule(two words)

    neutral

    neither acidic nor basic (electrolytes); neither positive nor negative (electricity)

    neutralization

    combining equivalent amounts of acid and base

    neutralization reaction

    the double displacement [reaction] between an acid and a base to produce salt and water(two words)

    neutrino

    a neutral particle associated with leptons

    neutron

    a neutral subatomic particle; a hadron

    Newtonian mechanics

    the laws of [mechanics] applicable in the macroscopic world

    (two words)

    nitrile

    an organic compound characterized by the functional group -CN

    nitro

    the functional group -N02

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    a substance containing a nitrogenous base, a sugar, and a phosphate group

    nuclide

    an atom of a specific energy with a specified number of protons and a specified number of neutrons in itsnucleus

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    observe

    to note with the senses, aided or unaided

    octahedral

    the shape in which six objects are equally spaced about a central object

    octane rating

    a system of [rating] gasoline based upon the proportions of heptane and 2,2,4-trimethylpentane in themixture(two words)

    octet

    an especially stable arrangement of four pairs of electrons in the outer energy level of an atom

    octet rule

    the tendency of atoms to gain or lose electrons so that they acquire eight electrons in their outer level(two words)

    ohm

    the SI unit of electrical resistance; one volt per ampere

    olefin

    an alkene; any hydrocarbon that contains one double bond per molecule; used to manufacture fibers inwhich the _____ is polermized into a long-chain synthetic polymer; ethylene or propylene are especiallyused as synethic units

    optimum conditions

    the [conditions] maximizing the product of an equilibrium reaction(two words, plural)

    orbital

    the space that can be occupied by 0, 1, or 2 electrons with the same energy level, energy sublevel, andspacial orientation

    organic

    pertaining to carbon compounds

    organic chemistry

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    packing

    the adsorbent in a chromatographic column

    pair repulsion

    a model used to predict molecular shape based on the mutual repulsion of electron clouds(two words)

    paper chromatography

    a chromatographic method that uses paper as the stationary phase; the mobile phase moves by capillaryaction(two words)

    parent chain

    the longest continuous [chain] of carbon atoms in an organic compound(two words)

    partially miscible

    property of two liquids that dissolve in each other to some extent, but not completely(two words)

    pascal

    the SI unit of pressure; 1 N/m^2

    Pauli exclusion principle

    No two electrons in an atom can have the same set of quantum numbers.(three words)

    peptide bond

    an amide link; -CO-NH-(two words)

    percent of ionization

    the amount ionized divided by the original amount, multiplied by 100(three words)

    percent composition

    the mass of an element in a compound divided by the mass of the compound, multiplied by 100(two words)

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    a graphical representation of the equilibrium relationships of the phases of a substance(two words)

    phenol

    C6H5OH; any compound having a hydroxyl group attached to a benzene ring

    photoelectric effect

    ejection of electrons from a surface exposed to light(two words)

    photon

    quantum of visible radiant energy

    physical change

    a [change] in which the same substance is present before and after the change(two words)

    physical property

    a [property] that can be observed without a change of substance(two words)

    pi bond

    a [bond] formed by the sideways overlap of p orbitals(two words)

    planetary model

    the [model] of the atom in which the sun represents the nucleus and the planets represent the electrons(two words)

    plasma

    a state composed of electrons and positive ions that have been knocked apart by collisions at very hightemperatures

    pOH

    -log[OH^-]

    point mass

    an ideal gas particle with [mass] but no dimensions(two words)

    polar covalent

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    a bond formed by a shared pair of electrons that are more strongly attracted to one atom than to the other(two words)

    polarity

    property of a molecule caused by an unsymmetrical charge distribution

    polyatomic ion

    a group of atoms covalently bonded but possessing an overall charge(two words)

    polymer

    a very large molecule made from the same simple units repeated many times

    polymerization

    the formation of a polymer from monomers

    polymorphism

    the property of a substance whereby it exists in more than one crystalline form

    polyprotic acid

    an [acid] with more than one ionizable hydrogen atom(two words)

    positional isomers

    two or more molecules having the same formula but having a functional group in different positions on theparent chain(two words, plural)

    positron

    the antiparticle of the electron

    potential difference

    the [difference] in electric potential

    (two words)

    potential energy

    the [energy] of an object due to its position(two words)

    precipitate

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    a solid, produced by a reaction, that separates from a solution

    precision

    the measure of the reproducibility of measurements within a set

    pressure

    force per unit area

    principal quantum number

    the [quantum number] designating energy level and electron cloud size(three words)

    probability

    mathematical expression of "chance" or "odds"

    product

    a substance produced as the result of a chemical change

    protein

    a biological polymer of amino acids linked by amide groups

    proton

    positive nucleon

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    qualitative

    adj.--concerning the kinds of matter present

    quantitative

    adj.--concerning the amounts of matter present

    quantum

    a discrete "packet" of energy

    quantum mechanics

    the laws of [mechanics] concerning the interaction of matter and radiation at the atomic and subatomiclevel

    (two words)

    quantum number

    a [number] describing a property of an electron in an atom(two words)

    quantum theory

    the [theory] that energy is transferred in discrete units(two words)

    quark

    a theoretical particle believed to be elementary and a constituent of a hadron

    rad

    0.01 gray

    radiant energy

    [energy] being transferred between objects by electromagnetic waves(two words)

    radical

    a fragment of a molecule; neutral, yet at least one atom lacking its octet of electrons

    radioactivity

    spontaneous nuclear decay

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    0.01 sievert

    reversible change

    a [change] that can also go in the opposite direction(two words)

    reversible reaction

    a [reaction] in which the products may react to produce the original reactants(two words)

    reversible thermodynamic change

    an ideal [change] in which the difference in pressure is infinitesimal(three words)

    Rutherford-Bohr atom

    the planetary [atom] model(three words, hyphenated)

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    salt

    a compound formed from a positive ion other than hydrogen and a negative ion other than hydroxide

    salt bridge

    an ionic solution used to complete an electric circuit in a voltaic cell(two words)

    saponification

    the reaction of an ester with a strong aqueous base to form a soap and glycerol

    saturated

    the gaseous phase of a system with equilibrium between a substance and its vapor

    saturated compound

    a [compound] having only single bonds between carbon atoms(two words)

    saturated hydrocarbon

    a [hydrocarbon] in which all carbon-carbon bonds are single bonds(two words)

    saturated solution

    a [solution] in which undissolved solute is in equilibrium with dissolved solute

    (two words)

    science

    the systematic investigation of nature

    screw dislocation

    a crystal defect due to improperly aligned unit cells(two words)

    second

    the SI unit of time

    semiconductor

    a substance that conducts electricity, but poorly

    semipermeable membrane

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    a barrier allowing the passage of small ions and molecules but blocking passage of large particles(two words)

    shared pair

    a [pair] of electrons bonding two atoms together by being shared by the two atoms

    (two words)

    shielding effect

    the decrease in the attraction between outer electrons and the nucleus due to the presence of otherelectrons between them; electron _____.(two words)

    SI units

    the internationally accepted set of standards for measurements(two words, plural)

    side chain

    a branch on the parent [chain] of an organic molecule(two words)

    sievert

    the SI unit used to measure the absorbed dose of radiation; ionizing radiation equal to 100 rem

    sigma bond

    a [bond] formed by the direct or end-to-end overlap of atomic orbitals(two words)

    significant digits

    the reliable [digits] in a measurement based on the accuracy of the measuring instrument(two words, plural)

    silicates

    compounds containing silicon and oxygen(plural)

    simple cubic

    having a unit cell with one particle centered on each vertex of a cube(two words)

    single displacement

    a reaction in which one element replaces another in a compound(two words)

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    smectic substance

    a [substance] that is a liquid crystal having two dimensions of order(two words)

    solid

    the state of matter characterized by particles that appear to vibrate about fixed points

    solubility

    the quantity of solute that will dissolve in a specified amount of solvent at a specific temperature

    solubility product constant

    the equilibrium [constant] for the dissolving of a slightly soluble salt(three words)

    solute

    the substance present in lesser quantity in a solution

    solution

    a homogeneous mixture composed of solute and solvent

    solution equilibrium

    the state in which solute is dissolving at the same rate that solute is coming out of solution(two words)

    solvation

    the attaching of solvent particles to solute particles

    solvent

    the substance present in the greater amount in a solution

    space lattice

    the arrangement pattern of the unit cells in a crystal

    (two words)

    specific heat

    the amount of energy required to raise the temperature of one gram of a substance by one Celsiusdegree(two words)

    specific rate constant

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    a [constant] relating the rate of a reaction to reactant concentrations(three words)

    spectator ion

    an [ion] present in a solution but not taking part in a chemical reaction

    (two words)

    spectroscopy

    the study of the interaction of matter and radiant energy

    spectrum

    a unique set of wavelengths absorbed or emitted by a substance

    spin

    a property of subatomic particles corresponding to rotation on an axis

    spontaneous

    occurring without outside influence

    square planar

    the arrangement in which four objects are at the corners of a square around a fifth object in the center(two words)

    stability

    the ability of a substance to remain undecomposed

    standard atmospheric pressure

    101.325 kPa(three words)

    standard solution

    a [solution] whose concentration is known with a high degree of accuracy(two words)

    standard state

    thermodynamic reference conditions, 25.0 C, 101.3 kPa, 1M(two words)

    standard temperature

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    0 degrees C for gases; 25 degrees C for thermodynamics(two words)

    starch

    a biological (specifically plants) polymer of glucose

    state

    the particle arrangement in a phase as solid, liquid, gas, or plasma

    state function

    a thermodynamic quantity that is determined solely by the conditions, not the method of arriving at thoseconditions(two words)

    stationary phase

    the adsorbent in chromatography(two words)

    stoichiometry

    mass and volume relationships in chemical changes

    STP

    standard temperature and atmospheric pressure (273 K and 101.325 kPa)

    strong acid

    a completely ionized acidic electrolyte(two words)

    strong base

    a completely ionized basic electrolyte(two words)

    structural isomers

    two or more compounds with the same formula but differing arrangements of the parent carbon chain(two words, plural)

    subatomic particle

    a [particle] smaller than an atom(two words)

    sublevel

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    an [element] not occurring in nature(two words)

    system

    that part of the universe under consideration

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    technology

    the practical applications of scientific discoveries

    temperature

    a measure of the average kinetic energy of the particles composing a material

    temporary dipole

    a [dipole] formed from a nonpolar molecule for a brief period due to the presence of an electric field(two words)

    ternary

    composed of three elements

    ternary acid

    an [acid] containing hydrogen, usually oxygen, and one other element(two words)

    tetradentate

    describing a ligand that attaches to the central ion in four locations

    tetrahedral

    adj.--four objects equally spaced in three dimensions around a fifth object

    theory

    an explanation of a phenomenon

    thermodynamic stability

    the [stability] of a substance due to a positive change in the Gibbs free energy for the decomposition ofthe substance(two words)

    thermodynamics

    the study of the flow of energy in systems

    thermometer

    a device for measuring temperature

    thin layer chromatography

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    the temperature and pressure at which all three states of a substance are in equilibrium(two words)

    Tyndall effect

    the scattering of light by colloidal or suspended particles

    (two words)

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    vapor pressure

    the [pressure] exerted by a vapor in equilibrium with its liquid(two words)

    velocity

    the speed and direction of motion

    viscosity

    the resistance of a liquid to flow

    visible spectroscopy

    the study of the interaction of matter with visible radiation(two words)

    vitamin

    a group of biochemicals that are necessary for some enzymatic reactions to take place

    volatile

    an easily evaporated liquid

    volt

    the SI unit of electric potential difference

    voltaic cell

    a [cell] in which a chemical reaction generates an electric current(two words)

    wave

    a periodic disturbance in a medium

    wave equation

    the [equation] describing the behavior of the electron as a wave

    (two words)

    wavelength

    the distance between two successive crests of a wave

    wave-particle duality of nature

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    All particles have wave properties and all waves have particle properties.(five words, hyphenated)

    weak acid

    a slightly ionized acidic electrolyte

    (two words)

    weak base

    a slightly ionized basic electrolyte(two words)

    weak forces

    an attraction of molecules for each other through the action of dipoles(two words, plural)

    weight

    the gravitational attraction of Earth or a celestial body for matter

    work

    a force moving through a distance

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