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Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed further. It is not readily understood without
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Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Dec 22, 2015

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Page 1: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Chem 125 Lecture 110/25/02

Projected material

This material is for the exclusive use of Chem 125 students at Yale and may not

be copied or distributed further.

It is not readily understood without reference to notes from the lecture.

Page 2: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

WeradRadix

Latin

Licorice(glukos + rhiza)

Greek

RutabegaSwedish

WortOld English

Mathematics (16th Cent)

Race?RazzaItalian

Eradicate

WurzelGerman

Chemistry (18th Cent - France)

Politics (18th Cent - England)

Radish Radical: Going to the root or origin

= Root

Page 3: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

1787: Radical Introduced as a Political Term

"The necessity of a substantial and radical reform in the representation..."

J. Jebb

Page 4: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

September 17, 1787

Page 5: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

byLouis Bernard

Guyton de MORVEAU(1737-1816)

"Radical"Introduced as aChemical Term

1787

age 50

Page 6: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Méthode de Nomenclature Chimique1787

Antoine François de FOURCROY

(1755-1809) age 32Claude Louis BERTHOLLET

(1748-1822) age 39

Page 7: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

AntoineLaurent

Lavoisier(1743-1794)

age 45

7,000 pounds (~$300,000)

Page 8: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Clarity:

Facts Ideas

Words

“impressions of the same seal”

Page 9: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Facts: Analysis

Page 10: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Analysis

Page 11: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

TraitéÉlémentairede Chimie

(1789)

?WORD

FACT

THEORY

Oxy-gen+

Base or Radical

Acid

Page 12: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Lavoisier'sCompound

Radicals

Page 13: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Elemental Analysis by Oil Combustion

Air Supply

LampOil

Supply

H2OCollector

CO2

Collector

Page 14: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Silliman Crystal

Page 15: Chem 125 Lecture 1 10/25/02 Projected material This material is for the exclusive use of Chem 125 students at Yale and may not be copied or distributed.

Silliman Crystal