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Chapter 7 Electronic Structure of Atoms
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Chapter 7 Electronic Structure of Atoms

Feb 06, 2016

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Chapter 7 Electronic Structure of Atoms. Considering only the n = 1 to n = 5 states in the hydrogen atom, which transition will emit the most energy?. n = 5 to n = 4 n = 5 to n = 2 n = 3 to n = 1 n = 3 to n = 2 n = 4 to n = 2. - PowerPoint PPT Presentation
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Page 1: Chapter 7 Electronic Structure of Atoms

Chapter 7Electronic Structure of Atoms

Page 2: Chapter 7 Electronic Structure of Atoms

Considering only the n = 1 to n = 5 states in the hydrogen atom, which transition will emit the most energy?

1. n = 5 to n = 4

2. n = 5 to n = 2

3. n = 3 to n = 1

4. n = 3 to n = 2

5. n = 4 to n = 2

Page 3: Chapter 7 Electronic Structure of Atoms

1. n = 5 to n = 4

2. n = 5 to n = 2

3. n = 3 to n = 1

4. n = 3 to n = 2

5. n = 4 to n = 2

Considering only the n = 1 to n = 5 states in the hydrogen atom, which transition will emit the most energy?

Page 4: Chapter 7 Electronic Structure of Atoms

Considering only the n = 1 to n = 5 states in the hydrogen atom, which transition will emit the longest wavelength?

1. n = 5 to n = 4

2. n = 5 to n = 2

3. n = 3 to n = 1

4. n = 3 to n = 2

5. n = 4 to n = 2

Page 5: Chapter 7 Electronic Structure of Atoms

1. n = 5 to n = 4

2. n = 5 to n = 2

3. n = 3 to n = 1

4. n = 3 to n = 2

5. n = 4 to n = 2

Considering only the n = 1 to n = 5 states in the hydrogen atom, which transition will emit the longest wavelength?

Page 6: Chapter 7 Electronic Structure of Atoms

What are the valence electrons of vanadium?

1. 4s2

2. 3d3

3. 4s2 3d3

4. 3d5

5. 4d5

Page 7: Chapter 7 Electronic Structure of Atoms

1. 4s2

2. 3d3

3. 4s2 3d3

4. 3d5

5. 4d5

What are the valence electrons of vanadium?

Page 8: Chapter 7 Electronic Structure of Atoms

What are the valence electrons of gallium?

1. 4s2

2. 4p1

3. 4s2 3d10 4p1

4. 4s2 3d10

5. 4s2 4p1

Page 9: Chapter 7 Electronic Structure of Atoms

1. 4s2

2. 4p1

3. 4s2 3d10 4p1

4. 4s2 3d10

5. 4s2 4p1

What are the valence electrons of gallium?

Page 10: Chapter 7 Electronic Structure of Atoms

What is the maximum number of orbitals described by the quantum numbers:

1. 12. 33. 54. 85. 9

n = 3 l = 2

Page 11: Chapter 7 Electronic Structure of Atoms

1. 12. 33. 54. 85. 9

n = 3 l = 2

What is the maximum number of orbitals described by the quantum numbers:

Page 12: Chapter 7 Electronic Structure of Atoms

What is the maximum number of electrons described by the quantum numbers:

1. 72. 143. 164. 325. 48

n = 4

Page 13: Chapter 7 Electronic Structure of Atoms

What is the maximum number of electrons described by the quantum numbers:

1. 72. 143. 164. 325. 48

n = 4

Page 14: Chapter 7 Electronic Structure of Atoms

How many nodal planes does a d orbital have?

1. 02. 13. 24. 35. 4

Page 15: Chapter 7 Electronic Structure of Atoms

1. 02. 13. 24. 35. 4

How many nodal planes does a d orbital have?

Page 16: Chapter 7 Electronic Structure of Atoms

How many unpaired electrons does selenium have?

1. 02. 23. 44. 65. 8

Page 17: Chapter 7 Electronic Structure of Atoms

1. 02. 23. 44. 65. 8

How many unpaired electrons does selenium have?

Page 18: Chapter 7 Electronic Structure of Atoms

How many unpaired electrons does chromium have?

1. 02. 23. 44. 65. 8

Page 19: Chapter 7 Electronic Structure of Atoms

1. 02. 23. 44. 65. 8

How many unpaired electrons does chromium have?

Page 20: Chapter 7 Electronic Structure of Atoms

What is the wavelength for radiation transmitted by WGR, 550 AM (550 kHz)?

1. 0.545 m2. 5.45 m3. 545 m4. 0.0018 m5. 1.8 m

Page 21: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. 0.545 m2. 5.45 m3. 545 m4. 0.0018 m5. 1.8 m

)s10(5.5

)ms10(3.015

18

c

545

Page 22: Chapter 7 Electronic Structure of Atoms

Predict which of the following electronic transitions will produce the longest wavelengthspectral line.

1. n = 4 to n = 22. n = 5 to n = 23. n = 5 to n = 34. n = 6 to n = 4

Page 23: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. n = 4 to n = 22. n = 5 to n = 23. n = 5 to n = 34. n = 6 to n = 4

The wavelength increases as frequency decreases. The lowest frequency (longest wavelength) is associated with the lowest energy, and the smallest energy difference here is between n = 6 and n = 4.

Page 24: Chapter 7 Electronic Structure of Atoms

What is the wavelength of a helium4 ion moving in a cyclotron at 1.0% the speed of light? Mass of helium 4 ion = 6.6 1027 g.

1. 3.3 106 m

2. 3.3 108 m

3. 3.3 1011 m

4. 3.3 1014 m

Page 25: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. 3.3 106 m

2. 3.3 108 m

3. 3.3 1011 m

4. 3.3 1014 m

)ms10kg)(3.010(6.6

Js)10(6.631630

34

mv

h

11103.3

Page 26: Chapter 7 Electronic Structure of Atoms

Which of the following is not an allowed set of quantum numbers?

1. n = 3, l = 1, ml = 1

2. n = 3, l = 3, ml =23. n = 4, l = 0, ml = 0

4. n = 3, l = 1, ml =1

Page 27: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. n = 3, l = 1, ml = 1

2. n = 3, l = 3, ml =23. n = 4, l = 0, ml = 0

4. n = 3, l = 1, ml =1

The value of l can be no larger than n 1.

Page 28: Chapter 7 Electronic Structure of Atoms

How many electrons maximum can exist in the 4d orbital?

1. 2 2. 63. 104. 14

Page 29: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. 2 2. 63. 104. 14

There are five 4d orbitals, each of which can contain up to 2 electrons each for a total of 10 maximum.

Page 30: Chapter 7 Electronic Structure of Atoms

The electron subshell 3p represents the principal quantum number n = ___ and azimuthal quantum number l = ___.

1. 3; 2 2. 2; 33. 3; 14. 1; 3

Page 31: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. 3; 2 2. 2; 33. 3; 14. 1; 3

The principal quantum number n is 3, and a p orbital indicates l = 1.

Page 32: Chapter 7 Electronic Structure of Atoms

The maximum number of electrons in an atom that can exist in the 4f subshell and have ml = 1 is

1. 2 2. 73. 144. 32

Page 33: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. 2 2. 73. 144. 32

For any value of ml, the maximum number of electrons is 2.

Page 34: Chapter 7 Electronic Structure of Atoms

The following orbital diagram represents the electron configuration of which element?

1. Carbon2. Nitrogen3. Oxygen4. Neon

1s 2s 2p

Page 35: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. Carbon2. Nitrogen3. Oxygen4. Neon

1s 2s 2p

Page 36: Chapter 7 Electronic Structure of Atoms

The element with the electronic configuration [Ar]4s13d5 is:

1. Manganese2. Chromium3. Magnesium4. Iron

Page 37: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. Manganese2. Chromium3. Magnesium4. Iron

Page 38: Chapter 7 Electronic Structure of Atoms

What is the characteristic outer shell electron configuration of the noble gases?

1. s2p6

2. s2p5

3. s2p4

4. s2p3

Page 39: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1. s2p6

2. s2p5

3. s2p4

4. s2p3

Noble gases have completely filled s and p orbitals, hence their lack of reactivity.

Page 40: Chapter 7 Electronic Structure of Atoms

Which of the following orbital diagrams obeys Hund’s rule for a ground-state atom?1.

2.

3.

3s 3d

3s 3d

3s 3d

Page 41: Chapter 7 Electronic Structure of Atoms

Correct Answer:

1.

2.

3.

3s 3d

3s 3d

3s 3d