Page 1
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
25
CHAPTER 3
THE INDUSTRIAL PROCESS,
ENVIRONMENTAL MANAGEMENT SYSTEM
AND GAP ANALYSIS
Discussion on the Industrial Processes
Used by Refineries
Page 2
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
26
It has been confirmed that most of the well recognised refineries in the world, in
accordance with the ISO 9000:2000, make use of several chemical plants in producing the
required product for their consumer’s consumption. Though, most of companies such as
Exxon Mobil’s Fawley refinery are quite efficient in the way they make use this plants for
the production of chemical products like kerosene, fuel oil, and diesel, even bitumen
(which is used for roofing and for road construction as binder), there is the need for oil
industries to embark on the Cleaner Technology by automating all of there plants. This is
really not automatic since it will surely need more funds, time and commitment of the
investors for better production and cleaner environment, the end really justify the need.
The following processes are common in various refineries;
At its simplest, the refining process is all about boiling oil to break it down into its
constituent parts.
Page 3
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
27
The crude oil is heated to about 360°C and pumped into a tower called an Atmospheric
Pipe still, which varies in temperature from top to bottom. Because the different
components of crude oil boil at different temperatures, each can be drawn off separately
and used to make products such as petrol and aviation fuel.
For the heavier oil that is left, this process of heating and distillation is repeated in a
Vacuum Pipe still. This produces feedstock for the manufacture of lubricants, as well as
for the next stage of the refining process.
To remove impurities, the oil is processed at up to 400°C in the Residfiner, using
pressurised hydrogen. The Residfiner makes feedstock for the catalytic cracking unit.
The Catalytic Cracker breaks down the oil (or 'cracks' it) into components that are used
to make additives for plastics and petrol. Other key units - and there are many - include:
1. The Poly Plant, which produces mainly chemical feedstock for plastics
2. The Power former and Isomeric Units, which make LPG and high octane
naphtha for petrol
3. The Lubricating Plant, which produces bases tocks for motor oil.
4. The Bitumen plant is meant for the production of bitumen for roofs and roads.
3.1 Crude Oils, the Hydrocarbon Mixture
Crude oils are complex mixtures containing many different hydrocarbon compounds that
vary in appearance and composition from one oil field to another. Crude oils range in
consistency from liquid to tar-like solids, and in colour from clear to black.
Page 4
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
28
An "average" crude oil contains about 84% carbon, 14% hydrogen, 1%-3% sulphur, and
less than 1% each of nitrogen, oxygen, metals, and salts. Refinery crude base stocks
usually consist of mixtures of two or more different crude oils.
Crude oils are also defined in terms of API (American Petroleum Institute)
gravity. Crude with a high API gravity are usually rich in paraffin’s and have a high
propensity to yield greater proportions of gasoline and light petroleum products. Crude
oils that contain substantial quantities of hydrogen sulphide or other reactive sulphur
compounds are called sour. Those with less sulphur are called sweet.
All crude oils, before refining, need to be evaluated and fully quantified analytically
(quality and quantity analysis) on their potential yield. Crude Oil with low assay numbers
is referred to as Opportunity Crude. This type of oil will be more difficult to process due
to higher levels of contaminants and water. This type of crude will usually give the
desalter plant the most trouble and require the greatest skill of the operators and as such
composition analysis of crude oils before processing makes it possible for industries to
monitor the way such crude is processed to yield even high profit with it high level of
contaminants.
3.2 The Storage Tanks
These are huge tanks that hold all the incoming crude oil of the industry. It is also often
used in mixing several grade of crude oil. Figure 3.1 shows the refinery storage tank farm
[1] used for storing crude oil before they are further processed through other plants.
Storage tanks are quite important in any refinery since they are the ones that hold
the amount of crude required for other plants to operate on. From the picture, the green
Page 5
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
29
part surrounding the tanks is called the bund walls. This is a good practise to avert
spillage when there is overflow from the tank to other plants which can cause fire through
domino effect. The Bund Walls surrounding the tank are important to avert oil spillage
though the walls are too low and there is the need for reconstruction and adequate scaling
to volume of tank. This will be discussed further under the gap analysis of the plants and
areas to develop and breach the gap.
[15]
Figure 3.1 The Storage Tanks used in Holding Crude Oil before Processing
Page 6
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
30
3.3 Desalter Process Plant: The First Chemical Process Plant in Crude Oil
Refining
Crude Oil Pretreatment [16]
(Desalting)
15
Picture is from Fawley refinery : showing storage tanks with bund wall
<http://www.schoolscience.co.uk/content/fawley-tour> 16
Picture Source: Baker Hughes (1999). The Baker petrolite corporation, west airport B1vd. Sugar land,
Texas <http://www.bakerhughes.com/bapt>
Page 7
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
31
3.3.1 Description of the Process
Crude oil often contains water, inorganic salts, suspended solids, and water-soluble trace
metals. As a first step in the refining process, to reduce corrosion, plugging, and fouling of
equipment and to prevent poisoning the catalysts in processing units, these contaminants
must be removed by desalting (dehydration and salting out process). Desalting and
dewatering of crude oil upstream of the crude distillation unit is a key process operation
for the removal of these unwanted components from crude oil before they get to other
major unit operations. The operation of a desalting system can be very challenging due to
changing process variables due to varying crude oil composition- mixture different of
hydrocarbons and other impurities (sulphur (S2-
), nitrogen (N3-
), oxygen (O2-
) and
metallic ions-Ca2+
, Mg2+
etc). At best, it is a process of measuring trade-offs and
compromises.
The two most usual methods of crude oil desalting is the chemical separation and
electrostatic separation. In the two separation techniques, hot water is used as the
extraction agent (withdrawal agent). In chemical desalting, water and chemical surfactant
(demulsifier) are added to the crude, heated so that salts and other impurities dissolve into
the water or fix to the water, and then held in the tank where they settle out. Electrostatic
desalting is the application of high voltage electrostatic charges to concentrate suspended
water globules in the bottom of the settling tank. Surfactants are added only when the
crude has a large amount of suspended solids. Both methods of desalting are continuous
processes. A third and less-common process involves filtering heated crude using
diatomaceous earth.
The feedstock crude oil is heated to between 150° and 350°F (preheated to 66ºC
Page 8
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
32
and 177ºC) to reduce the viscosity and surface tension of the crude oil for easier flow,
mixing and separation of the water. The vapour pressure of the crude-oil feedstock limits
the temperature. In both methods other chemicals may be added. Ammonia solution
(NH4+ OH
-) is often used to reduce corrosion. Caustic acids (H
+) may be added to adjust
the pH of the water wash due to the presence of the alkaline (OH-) from the ammonia
solution. Wastewater and contaminants are discharged from the bottom of the settling tank
to the wastewater treatment plant facility where pre-treated and recycled for further use.
The desalted crude is continuously drawn from the top of the settling tanks and sent to the
crude distillation (fractionating) tower. Figure 3.2 shows the desalting plant when drawn in
a systematic way with various part and equipment needed.
Page 9
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
33
Valve
Heater
Pump
Pump
Gravity Settler
P-1
P-2 P-4P-3
P-5
P-6
Electrical
Power
Desalted
Crude
Effluent
Water
Process
water
Unrefined
Crude
Alternative
route
Emulsifier
6/8/2006
Automation of system
AKINLOLU, Akinsola (2006).MSc Project:Semi-automation of Bitumen Plant
From Conventional refinery residue. Coventry University, UK
Figure 3.2 the Electrostatic Desalting Process
Page 10
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
34
A fine equilibrium must be maintained while controlling mixing intensity, wash water
quality, chemical demulsifier feed and other parameters that can provide optimal salt
removal. On one hand the quality of the crude overflow must be within specific standards
and on the other hand the under-carry must not be so potent that it compromises the
system's dehydration abilities or fouls up downstream wastewater treatment. New
legislative demands placed on effluent water quality present the operator with a difficult
challenge. Optimizing the desalting process under constantly varying conditions is a key
ingredient to success of the entire refinery operation.
The main function of the Desalter is to remove salt and water from the crude oil.
However, many other contaminants such as clay, silt, rust, and other debris are also
removed in the plant. These can cause corrosion and fouling of downstream equipment
when deposited on heat transfer surfaces in pipes and other plants. Also, there are metals
that can deactivate catalysts used in the process of refining and as such the desalter is the
bottleneck in most industries because of the multifunction that need to be performed in the
plant and need attention of engineers and operators. Figure 3.3 shows the National Tank
Company (NATCO) desalting plant used for Nigerian crude oil and the various parts of the
plant is shown.
Page 11
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
35
Figure 3.3 The Desalting Process Plant (Zipped and Unzipped)
Source: The NATCO Trigridmax unit Desalter showing all the parts of the Desalter This is the
Trigridmax Desalter for Ashland Oil FPSO <http://www.natcogroup.com/PDFContent/Oil-
Treating/TRIGRID-and-TRIGRIDMAX-Electrostatic-Treater.pdf>
Page 12
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
36
3.4 The Furnace: The Heat Energy Supplying Plant
3.4.1 Heating Operations
Process heaters and heat exchangers preheat feedstock in distillation towers and other
refinery plants that need to be operated at higher temperature. Heat exchangers use either
steam or hot hydrocarbon (like Naphtha) transferred from some other section of the
process for heat input. The heaters are usually designed for specific process operations,
and most are of cylindrical vertical or box-type designs. The major portion of heat
provided to process units comes from fired heaters fuelled by refinery or natural gas,
distillate, and residual oils. Fired heaters can be found in various plants. Types of heaters
include the reformer preheater, Coker heaters, and large-column reboilers.
Page 13
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
37
Figure 3.4 The Furnace Plant
3.4.2 Steam Generation
Heater and Boiler Operations
Steam is generated in main generation plants, and/or at various process units using heat
from outlet gas or other sources. Heaters (furnaces) include burners and a combustion air
system, the boiler enclosure in which heat transfer takes place, a draft or pressure system
to remove flue gas from the furnace, soot blowers, and compressed-air systems that seal
openings to prevent the escape of flue gas. Boilers consist of a number of tubes that carry
the water-steam mixture through the furnace for maximum heat transfer. These tubes run
Page 14
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
38
between steam-distribution drums at the top of the boiler and water-collecting drums at the
bottom of the boiler. Steam flows from the steam drum to the super heater before entering
the steam distribution system.
Heater Fuel
Heaters may use any one or combination of fuels including refinery gas, natural gas,
naphtha, fuel oil, and powdered coal. Refinery off-gas is collected from process units and
combined with natural gas and LPG in a fuel-gas balance drum. The balance drum
provides constant system pressure, fairly stable Btu-content fuel, and automatic separation
of suspended liquids in gas vapours, and it prevents carryover of large slugs of condensate
into the distribution system. Fuel oil is typically a mix of refinery crude oil with straight-
run and cracked residues and other products. The fuel-oil system delivers fuel to process-
unit heaters and steam generators at required temperatures and pressures. The fuel oil is
heated to pumping temperature, sucked through a coarse suction strainer, pumped to a
temperature-control heater, and then pumped through a fine-mesh strainer before being
burned.
The illustration in figure 3.5 shows the use of naphtha as the heating fuel oil gas.
Hot naphtha is passed through an array of pipes while the cold crude oil is pumped in the
other direction over the pipes. Thus while the crude move through one pipe in one
direction, the heater fuel move in the opposite direction in another array of pipes and
thereby heat is transferred from the naphtha to the crude oil. This type of heat energy
transfer is referred as a counter-current flow exchange of heat energy. The diagram
(figure 3.5) shows the crude movement from right to left (arrow turns from blue to green
to brown and the to red after the crude has been heated up)
Page 15
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
39
Figure 3.5 The Inner Structure of Counter Current Heat Exchanger Equipment
Picture Source: <http://www.schoolscience.co.uk/4/>
Page 16
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
40
3.4.3 Steam Distribution System
The distribution system consists of valves, fittings, piping, and connections suitable for the
pressure of the steam transported. Steam leaves the boilers at the highest pressure required
by the process units or electrical generation. The steam pressure is then reduced in turbines
that drive process pumps and compressors. Most steam used in the refinery is condensed to
water in various types of heat exchangers. The condensate is reused as boiler feed water or
discharged to wastewater treatment. When refinery steam is also used to drive steam
turbine generators to produce electricity, the steam must be produced at much higher
pressure than required for process steam. Steam typically is generated by heaters
(furnaces) and boilers combined in one unit. The steam distribution system is further
considered in chapter 11 under the safety used of overriding control system (see this
chapter for more emphasis on the system).
3.4.4 Feed water
Feed water supply is an important part of steam generation. There must always be as many
pounds of water entering the system as there are pounds of steam leaving it. Water used in
steam generation must be free of contaminants including minerals and dissolved impurities
that can damage the system or affect its operation. Suspended materials such as silt,
sewage, and oil, which form scale and sludge, must be coagulated or filtered out of the
water. Dissolved gases, particularly carbon dioxide and oxygen, cause boiler corrosion and
Page 17
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
41
are removed by de-aeration and treatment. Dissolved minerals including metallic salts,
calcium, carbonates, etc., that cause scale, corrosion, and turbine blade deposits are treated
with lime or soda ash to precipitate them from the water. Recirculated cooling water must
also be treated for hydrocarbons and other contaminants.
Depending on the characteristics of raw boiler feed water, some or all of the
following six stages of treatment will be applicable:
Clarification;
Sedimentation;
Filtration;
Ion exchange;
Deaeration; and
Internal treatment
3.5 Health and Safety Considerations
3.5.1 Fire Protection and Prevention
The most potentially hazardous operation in steam generation is heater start up. A
flammable mixture of gas and air can build up as a result of loss of flame at one or more
burners during light-off. Each type of unit requires specific start up and emergency
procedures including purging before light off and in the event of misfire or loss of burner
flame (see chapter 8 and 11).
Page 18
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
42
3.5.2 Safety
If feed water runs low and boilers are dry, the tubes will overheat and fail. Conversely,
excess water will be carried over into the steam distribution system and damage the
turbines. Feed water must be free of contaminants that could affect operations. Boilers
should have continuous or intermittent blow down systems to remove water from steam
drums and limit build up of scale on turbine blades and super heater tubes. Care must be
taken not to overheat the super heater during start up and shut-down. Alternate fuel sources
should be provided in the event of loss of gas due to refinery unit shutdown or emergency
(detail in chapter 11 under the use of HSS-High Selective Switches). Knockout pots
provided at process units remove liquids from fuel gas before burning.
3.5.3 Health
Safe work practices and/or appropriate personal protective equipment may be needed for
potential exposures to feed water chemicals, steam, hot water, radiant heat, and noise, and
during process sampling, inspection, maintenance and turnaround activities.
Page 19
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
43
3.6 The Fractional Distillation Process Plant
Fractional distillation splits the crude oil into simpler mixtures called fractions. The
different fractions are taken out of the still at different levels of the distillation column.
For the splitting of the crude to various fractions to take place, the desalted crude is heated
in a furnace to about 370°C to 400ºC and pumped into the column with the required
pressure at the bottom of a distillation tower. Most of the hydrocarbons (mixture of
compounds with chemical formula CxHy [ 17]
) are gaseous, though the very thick ones are
still a liquid even at this temperature.
A distillation tower is often called a still Tower. This can be seen in figure 3.6. The
crude oil is heated in the furnace and this generate the heated oil fumes and semi-solid and
partial semi-liquid phases that is transferred to the still plant hoping to separate due the
difference in the boiling point of the oil mixture.
The different fractions come out at different levels. The residue from the
atmospheric still is passed to the vacuum still (the left of the zipped diagram of figure
3.6). Here, it splits into more fractions. The tower is akin to a huge heat exchanger - it
removes heat from the gases as they rise up it. The temperature of the heated mixture
decreases progressively from 370ºC to 20°C by the time the vapours reach the top.
_______________________________________________________________________________________ 17
CXHY is the general formula given to hydrocarbons either they are saturated, unsaturated, aromatic
(cyclic) or aliphatic hydrocarbons.
Page 20
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
____________________________________________________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
44
Figure 3.6 Showing The Fractional Distillation the Real Life One and The Unzipped (Opened) Showing What is Going on Inside The Column
Source: Fawley refinery <http://www.exxonmobil.co.uk>, <http://www.schoolscience.co.uk/contenet/4/chemistry/knowl/4/distilling.html
Each column trays has holes for gas/fumes
Oil fractions to move to upper trays of the
column and separates out.
The columns is hot at the bottom and
cool at the upper part
Hot vapours of Oil rises and split into
there fractions with different boiling
point. Lighter fractions-Petroleum gas,
petrol -rises higher in the tower and get
collected.
Heavier fractions with higher boiling
point settle at the bottom trays and
get collected-Lubrication oil, bitumen
etc.
The Desalted crude oil inlet
Page 21
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
45
The vapours condense as they rise up the tower. The heavier ones (with higher boiling
points) condense first. The thinner, runny ones, with lower boiling point get further up the
tower before they condense. And the ones that are naturally gases pass out of the top. This
are called the Natural gases (NG). When they are liquefied by equipment they are called
Liquefied Natural Gas (LNG).
Thus, hot mixture is pumped into the bottom of the tower from the heater called
the furnace, the tower acts as a heat exchanger, removing heat from the vapours as they
rise. Some of them condense back into liquids and fall back down the column. So the
temperature gradually decreases as you go up the column. Different groups of
hydrocarbons condense at different heights. The heaviest fractions are at the bottom,
while the lightest at the top. Figure 3.6 illustrate how the fractional distillation looks like.
It also shows the zipped and the unzipped part (the real life and the inner part of the
tower).
3.6.1 Crude Oil Distillation (Fractionation) Process
Process Description
The first step in the refining process is the separation of crude oil into various fractions or
straight-run cuts by distillation in atmospheric and vacuum towers. The main fractions or
"cuts" obtained have specific boiling-point ranges and can be classified in order of
decreasing volatility into gases, light distillates, middle distillates, gas oils, and residuum
(unzipped part of figure 3.6).
Page 22
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
46
Atmospheric Distillation Tower
At the refinery, the desalted crude feedstock is preheated using recovered process heat.
The feedstock then flows to a direct-fired crude charge heater where it is fed into the
vertical distillation column just above the bottom, at pressures slightly above atmospheric
and at temperatures ranging from 650° to 700°F (344ºC to 372ºC heating crude oil above
these temperatures may cause undesirable thermal cracking). All but the heaviest
fractions flash into vapour. As the hot vapour rises in the tower, its temperature is reduced.
Heavy fuel oil or asphalt residue is taken from the bottom. At successively higher points
on the tower, the various major products including lubricating oil, heating oil, kerosene,
gasoline, and uncondensed gases (which condense at lower temperatures) are drawn off (
see the table 3.1 on the fractions that can be obtained).
Page 23
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
47
Table 3.1 The Main Fractions and Levels
Fraction Carbons BP °C Uses
Gases 1 to 4 < 40 • Fuel in refinery
• Bottled and sold as LPG
Naphtha’s 5 to 10 25 – 175 • Blended into petrol’s
• Feedstock for making
chemicals
Kerosene’s 10 to 16 150 – 260 • Aviation fuel
Light gas oils 14 to 50 235 – 360 • Diesel fuel production
Heavy gas oils 20 to 70 330 – 380 • Feedstock for catalytic
cracker
Lubricants > 60 340 – 575 • Grease for lubrication
• Fuel additives
• Feedstock for catalytic
cracker
Fuel oil > 70 > 490 • Fuel oil (power stations and
ships)
Bitumen > 80 >580 • Road and roof surfaces
Page 24
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
48
3.7 The Bitumen [18]
Plant: The Plant for the Bituminous Fraction
3.7.1 Bitumen Process
Bitumen can be produced by the oxidation of oil residues from the distillation tower. It can
also be produced by the oxidation reaction on tar sand or heavy oil derived from the semi-
solid bituminous deposits. The Tar or the vacuum gas oil is first heated to 250-270ºC at 2
atmospheres in a continuous oxidation reaction by oxygen as it circulates in a reactor
Page 25
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
49
where the reaction is taking place (such as the Biturox reactors [19]
figure 3.7). The
bitumen reactor plant that is newly commissioned in Ukraine is called Biturox Plant. Air
utilization is kept just below 100 per cent in the reactor, resulting in short processing times
and low operating costs. Due to gentle and efficient oxygen introduction, thermo-cracking
is limited to a minimum. The valuable resin components in the product are saved (no
coking as in conventional blowers).
This short residence time, guarantee the uniform character of the reaction and
homogeneity of the product, which guarantee high quality. This is the key characteristic
attribute of the bitumen produced in Lisichansk in Ukraine.
The final product is cooled in the heat exchangers to 180-200ºC, and then sent to
the bitumen product tanks and from their pumped to the loading facilities (figure 3.7). Off
gases from the reactors are sent to the thermal treatment furnace where they are burnt. Due
to an optimum air/feed ratio, Biturox Plants yield considerably less off gas than traditional
units, which minimizes atmospheric emissions.
In addition, the resulting residual product, so-called black solar oil, is used as
heating fuel. The loading facilities provide for filling in two rail tank car sand two road
trucks simultaneously. Loading operations are controlled automatically from the pump
station control room.
18
Picture source: the Lisichansk bitumen Plant. Commissioned, July 2004
<http://www.google.com/bitumen_eng[1].PDF> 19
Biturox reactor is the plant built for the production of multi grade of bitumen. (Biturox®
composition controlled bitumen process). <http://www.biturox.com/200.0.html>
Page 26
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
____________________________________________________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
50
Figure 3.7 The Bitumen Process Flow Diagram
Source: <http://www.biturox.com/lisichansk.pdf>The Biturox Process plant in Lisichansk bitumen Process plant, Ukraine.
Page 27
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
51
Roads need to be cost-efficient in construction and maintenance and durable over a long
lifetime. Bitumen (binders) of the highest quality which performs well under any climatic
condition and which will withstand the heaviest traffic load is the key to these
requirements.
As such there is the need for the adoption of semi-automation not only in the
loading facilities but also in the whole of the process involved in the production for more
cost-effective, higher quality of road binders (bitumen) and for more intrinsic
environmentally friendly production. These areas are discussed under the arising issues
and the adoption hybridization of Lean techniques, Automation and Chemical processes
control (Chapter 5) after detecting the gaps in all of the industrial processes used.
Page 28
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
52
3.8 Environmental Management System
Air pollution occurs when some certain composition in the air are exceeded. There is a
concentration and time effects which are factors affecting air pollution and this is known
as the Time-Concentration effect. Of course, air is not the only part that the industrial
processes are affecting, the Water pollution and Land pollution are also occurring in a
great alarming rate most especially in African countries. Most of the chemical industries
meet the standards like the Clean-air acts regulations in UK and as such converts there
wastes from air pollution waste to land or water pollution. This is diagrammatically
represented in figure 3.8 in which most industry will incorporate some controls that will
convert there by-product or waste from being a gas by-product to solid or liquid product
and vive versa, and if such by-product is not needed, will be disposed off as waste.
This brings about the establishment of the International Standard Organisation
(ISO) that look into management and quality control systems. This was first articulated in
the ISO 9002 certified series.
This is carried out by an external supervisor and if they are satisfied with the
system in place, a certificate will be issued as been certified as an environmentally
friendly system. This regulatory system started with the BS 7750 (1992, 1994) and
contains, the Environmental policy, which is a statement policy of the company as regards
the environmental concern.
It also contains the Objectives and Targets –action, programme, manual and
documents to follow by the personnel. The Operational Controls are also stipulated and
Page 29
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
53
must be in place. The Environmental management records, environmental audit of the
plant periods and the environmental management reviews are all part of the document.
Figure 3.8 Illustrates the Conversion of Waste Materials/Pollution from one form to
another (Solid, liquid or gas)
Page 30
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
54
3.8.1 Implication of Industrial Processes to the Environmental
The question is, “is it possible to produce these products (ranging from the LPG, petrol,
diesel, kerosene to the Bitumen) with Zero discharge or without polluting the
environment?”
“The answer at this level, even to great Engineers who has been
working with industry for many years will say “NO”…”
But the one fact is certain that there is nothing that is a waste. The waste of one industry
may be the raw material for another industry or plant.
“To a farmer who planted cassava and saw some ground nut
growing within the cassava will say that the ground nut is a weed.
But is the ground nut crops useless?”
This shows that what is a waste in one process can surely be a raw material for another
process. And as such if waste can be treated in that way, it would be amazing that the so
called waste material (solid, liquid or gas-Water spillage, land pollution, air pollution,
greenhouse gas emissions etc) are always useful.
The focus of this write-up is to look at the positive effect of the use of semi-
automation for the production of bitumen and this if possible applied to the on going
development of the Nigeria “Olokola” bitumen/heavy oil.
This really poses some major concern and cost (production with zero discharge to the
environment) for most well organised establishment (and view it as an impossible task),
Page 31
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
55
yet the combination of the Lean technique, Chemical processes control and Automation
system (LeChAs) can proves to be the way out and the best solution to this problem.
It is also important to disclose, as it has been discussed in the literature review, that
the world level of crude oil is decreasing and as such the write focus on the use of use of
the combination of techniques mentioned earlier (LeChAs) for effective use of the
decreasing crude oil deposit. Bitumen/heavy oil deposit, (which may be a long term
substitute) which can be used for production of some fractions derived from refining the
crude oil such as the asphalt from bitumen, and also as a source of energy is also looked
into in the course of the write-up. Of course, the use of bituminous deposits can be a long-
term solution; the short-term solution is the use of the hybrid between the lean
manufacturing technique, knowledge of chemical engineering processes and the
automation system (LeChAs).
To deliberate on LeChAs, the point is what is the Gap between the ways industries
are producing bitumen in the conventional process and the advantage that can/will be
derived from the use LeChAs. This statement suggest that there is the need for a Gap
analysis of a refinery first to examine the gap in the industrial continuous flow process, if
any, and as such creates a way forward for the solution to the problem. The write-up may
not be able to solve the problem totally but it really gives rise to a prospect/topic for
discussion to the desired solution.
Page 32
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
____________________________________________________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
56
Figure 3.9 The Industrial Refining Process
Source: http://www.exxonmobil.co.uk/welcome-fawley.pdf Picture by: Paul Carter, August 2005
Page 33
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
57
3.9 The GAP Analysis
3.9.1 Case Study on Refineries and Chemical Plants in UK
This is a Gap analysis on petroleum refineries and petrochemical companies. Example of this
refinery in United Kingdom is the ExxonMobil Fawley refinery [20]
. It was formed in 1999,
from the merger of Exxon (Esso's parent company) and Mobil. However, the Fawley site has
played an important role in the water side area of Hampshire for over 50 years.
Information was also gathered from several industries websites to carry out the gap
analysis. One of the company is called the National Tank Company [21]
(NATCO). Founded
in 1926 in Tulsa, Oklahoma as the National Tank Company, NATCO has always been at the
forefront of oil industry production processing. Starting with a single location and selling
only simple storage tanks, NATCO evolved as the industry evolved. NATCO/Axsia offers a
comprehensive range of technology to the refining industry. These technologies, supported by
decades of experience, range from hydrocyclone packages through skid-mounted topping
units to Lump Sum Turnkey (LSTK) hydrogen plant installations.
Other industries used include the Baker Petrolite industry [22]
, the Lisichansk industry
in Ukraine [23]
, The PÖrner group [Biturox.com] [24]
.
_______________________________________________________________________________________ 20
Source: The Fawley Refinery community Report of 2004, Esso Petroleum Company Limited, Esso
Refinery Fawley, Southampton < http://www.exxonmobil.co.uk. > 21
Source: The National Tank Company (NATCO) website,< www.natcogroup.com/ > 22
Source: Baker Hughes (1999). The Baker petrolite corporation, west airport B1vd. Sugar land, Texas
<http://www.bakerhughes.com/bapt> 23
Source: The Lisichansk Bitumen Plant.Commissioned, July 2004
http://www.google.com/bitumen_eng[1].pdf>
Page 34
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
58
Gap analysis technique is a set of techniques used to examine and describe the gap
between current performances and desired future goals. The gaps can include:
The difference between the current operation of an activity and the activity vision, sometimes
referred to as "C delta V" (current gap vision);
The difference between actual and theoretical targets, sometimes referred to as
"A delta T" (actual gap target); or the difference between actual
performance measures and world class benchmarks.
In addition to an overall enterprise vision, visions can be expressed for individual and core
sets of activities, such as logistics, procurement, and the plant’s performance from the
information gathered from the shop floor, product development, or customer
engagement/requirement. The "C delta V" technique is useful to summarize the results of a
gap analysis. The vision statements for a set of activities should conform generally to the
criteria for the enterprise vision as a whole, but, more importantly, should be as specific as
possible with respect to targets and measures.
The "A delta T" technique is useful to summarize the results of either a benchmarking
study or the results of activity simulations where actual can be compared to various targets.
For example, during a flow rate of an activity, it may be theoretically possible to fulfil a
customer order in four hours, using a variety of methods. Tests of the new methods may only
show a fulfilment time of five hours. One or both of these measures can be compared against
the current cycle time of one business day.
24
Source: The PÖrner Groups <www.poerner.at/>, Biturox reactor is the plant build for the production
of multi grade of bitumen. (Biturox® composition controlled bitumen process).
<http://www.biturox.com/200.0.html>
Page 35
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
59
Purpose
The purpose of gap analysis technique is to compare the current actual performance of an
activity to either its theoretical target or its vision.
Benefits
The benefit of gap analysis technique [25]
is that it provides an objective basis for
comparison of actual performance of an activity to either its theoretical target or its vision.
Gap analysis consists of defining the present state, the desired or `target' state and hence the
gap between them. In the later stages of problem solving the aim is to look at ways to bridge
the gap defined and this may often be accomplished by backward-chaining logical sequences
of actions or intermediate states from the desired state to the present state.
In other words, what is the current state of the company (a), what is the future (b)
and what is the Gap between the current and the future state envisioned (c), and
Thus,
"What (c) must be done/put in place, or must have happened to current state
(a) in order that this desired state (b) can exist?"
Page 36
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
60
3.9.2 ISO 9000:2000 Standard and the Gap Analysis
One of the first steps in the Quality Management System (QMS) transition or implementation
project is to compare the current QMS to the requirements of the ISO 9000:2000 standard.
This is most commonly called a Gap Analysis.
Gap Analysis Checklist
The most important tool for the Gap Analysis is the Gap Analysis Checklist [26]
. This is a list
of the requirements in the standard, written in question format. It is a best practice to use this
list to compare the QMS that is in place with the requirements of the ISO 9001:2000
Standard. The checklist provides adequate recommendations of what documents to look for;
examples of what will meet the requirements and other guidance on auditing to the standard.
The checklist also gives specific place to documentation that did or did not meet the standard.
It is vital to comment, at this stage, that because of the little information gathered from
the ExxonMobil website, a complete gap analysis is not feasible but the little one found
proves quite helpful in embarking on the analysis and as such further analysis need to be
carried out for more practical implementation of the areas discussed in the report.
25
Source: <http://www.gantthead.com/process> 26
Source: The 9000 Store by Vinca, LLC. ( 2001) ISO 9001:2000 and AS9100 Resource Centre
Page 37
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
61
Scheduling and Performing the Gap Analysis
Schedule and perform the audit. Enough time is required to do an in-depth audit. The more
information for the analysis, the more task lists and project plan, the more efficient and
effective the project will be.
When the audit has been completed, need for meeting with other auditors to
summarize the results is required. These results can be transferred to task lists for the
implementation. This meeting should be held shortly after the audit, so that information is
fresh in the auditors' memory.
Scheduling and Conducting the ISO 9001 Gap Analysis
A. Schedule the Gap
1. Review the project plan:
2. Identification of auditors to carry out the gap analysis
3. The Gap Analysis is Scheduled, and communicated to all employees on
what is being done, and why. There is the need to be able to make the
employees comfortable with answering the auditor's questions.
4. There may be the need to consider sending out a newsletter to inform
employees that the Gap will be performed, by whom, when and why the Gap is
<http://www.the9000store.com/Gap-Analysis-checklist.aspx>
Page 38
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
62
being performed. The Employee Newsletter is included in the Gap Analysis
Checklist Toolkit.
5. The audit schedule
6. It is determined if the audit is carried out by process/procedure or by area of
the facility. The approach used for the report is audit by area of the facility
and the performance of the facilities based on the information gathered
online.
7. The facilities are divided into manageable plants.
8. Time need to be scheduled to audit each section of the standard that applies
to the area.
9. If audit team are used, the team are assign to cover the various areas of the
facility.
10. Arrangement of the Gap Analysis checklists is done so that each auditor will
have the sections of the standard that are applicable in the areas they will
cover.
B. Conducting the Audit
Following the schedule that have been prepared, each area of the facility are then monitored
to evaluate the current state and quality of the system.
Focus is on what is in place, and what is not in place. The focus is not on compliance or non
compliance to the current system, but on the design of the current system, and how it
matches the ISO 9001:2000 requirements.
Note is on what is in place, and what will need to be developed and changed.
Complete notes, references and documents are taken.
Page 39
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
63
C. Reporting
Summary of the audit findings in the form of a task list is then drafted. Usually, several
categories of tasks are identified.
Processes that comply with the standard and are documented.
Processes that comply with the standard and must be documented.
Processes that do not comply with the standard and must be redesigned.
Processes required by the standard that are not currently in place.
For each requirement (or set of requirements) of the standard, the status of the current
system is identified. The ISO 9001:2000 Steering Team will use this information as they
assign responsibility and timelines to Teams. Task Teams will be assigned responsibility for
development of a procedure.
Gap analysis alone however is not adequate for all problem situations as goals may
evolve and emerge during the course of problem solving, "what ought to be" can be a highly
variable target. Also, some problems have many alternative solutions, in which case
backward-chaining search strategies will have little practical use.
The CDAC (the Centre for Distributed Automation and Control [27]
) (formerly
the Manufacturing Automation and Control Group) was formed in 1995 with the
intention of helping to bridge the gap between academic and industrial activities in the
manufacturing automation and control field. The main business focus of CDAC's work is
in understanding and improving the ability of manufacturing production to respond in the face
of unpredictable disturbances and increasing change. Traditionally production
performance has been assessed in terms of output under steady-state operation conditions.
Page 40
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
64
However, greater product variety, smaller batch sizes and frequent new product introductions,
coupled with tighter delivery requirements, demand operations that are capable of performing
consistently under continually changing conditions.
The technological focus of the group involves the development of adaptable, robust
algorithms and reconfigurable control system architectures to support distributed, intelligent
(holonic) manufacturing systems and devices. An important aspect of these systems is that
decisions made within a production control system are tightly coupled to the physical
devices that execute them.
The emerging focus of the groups’ activities lies in the internet based application of
these distributed intelligent technologies to develop support for agile, product-driven supply
chains.
27
Source(s):<http://www.eng.cam.ac.uk/automation/>
Page 41
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
65
Figure 3.10 The Link between the Future State and the Present
Situation
The objective of this step is to identify areas of the current and target system for which
provision has not been made in the Oil/Bitumen Production. This is required in order to
identify areas for the project to be undertaken as part of the implementation of the target
system Approach.
A key step in validating architecture is to consider what may have been forgotten. The
architecture must support all of the essential information processing needs of the
organization, as driven by the required applications. The most critical source of gaps that
should be considered is stakeholder concerns that have not been addressed in subsequent
Page 42
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
66
architectural work. Stakeholders are quite important aspect of gap analysis though this is not
considered in the report and as such literatures need to be considered for the aspect.
Gap analysis highlights services and/or functions that have been accidentally left out,
deliberately eliminated, or is yet to be developed or procured:
A matrix with all the business functions of the current state on the vertical axis is drawn up,
and all the business functions of the target Technology on the horizontal axis. In creating the
matrix it is imperative to use terminology that is accurate and consistent.
The Current state axis is added to a final row labelled 'New Services/technology', and
to the Target technology axis a final column labelled 'Eliminated services / technology'.
Where a function is available in both the current and target technology, this is recorded as
'Included' at the intersecting cell.
Where a function from the current state is missing in the target technology, each must
be reviewed. If it was correctly eliminated, it is marked as such in the appropriate 'Eliminated
Services/technology' cell. If it is not, an accidental omission has been uncovered in the new
target that must be addressed by reinstating the function in the next iteration of the design -
mark it as such in the appropriate 'Eliminated Services' cell.
Where a function from the target architecture cannot be found in the current state, it is
marked as the intersection with the 'New' row, as a gap that needs to be filled, either by
developing or procuring the function.
When the exercise is completed, anything under 'Eliminated Services/Technology' or 'New
Services/Technology' is a gap, which should either be explained as correctly eliminated, or
marked as to be addressed by reinstating or developing/procuring the function.
Page 43
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
67
3.10 The Gap analysis of Oil Refinery
3.10.1 Fawley Refinery
The Brief history and Processes
In 1921, the Site was developed by the Atlantic Gulf and West Indies Petroleum Company
(AGWI). In 1925, the site was purchased by Standard Oil - whose initials gave Esso its
name: So spells Esso. 1951 The new refinery opened by Prime Minister Clement Attlee. Esso
Petroleum formed. In 1958 the first chemicals project began. 1966 Esso Chemical (later to
become Exxon Chemical, then ExxonMobil Chemical) began operations. In 1969, the Marine
Terminal was extended - to one mile in length. Almost exactly 17 years in 1986, Esso became
the first UK Company to introduce unleaded petrol and 2years after that in 1988
Computerisation of all control rooms was initiated.
1999 marked the year when Exxon and Mobil merged to form ExxonMobil. In 2001,
50th anniversary of the "new" refinery was celebrated.
Oil was first refined at Fawley in 1921, when the Atlantic Gulf and West Indies
Company processed Crude oil from Mexico into heavy fuel oil for ships.
Today, Fawley turns crude oil from the North Sea, Europe and the Middle East into
products such as Petrol, diesel, aviation fuel and petrochemicals.
The site has a workforce of some 1,300 employees and up to 2,000 contractors.
Page 44
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
68
Mission, Goals and Objectives
2004 was an exceptional year. The site achieved its best ever safety performance, the refinery
established new records for reliability and throughput, and the chemicals plant enjoyed a year
of high production and improved efficiency.
The goal of the company is to have a workplace where ‘Nobody gets Hurt’ and, this
was almost achieved that year with the help and efforts of everyone on site.
Throughout the whole of 2004, it recorded just one injury – to a chemicals plant employee –
that required more than first aid treatment.
According to the Fawley refinery community report of 2004;
“…When you consider that our workforce averaged…
Some 2,400 people last year, this is a remarkable achievement…”
(www.exxonmobil.org: Fawley refinery community report, 2004)
A flawless safety performance has been initiated in 2005 which includes observing and
understanding the at-risk behaviours that lead to injuries, and then intervening to change
those behaviours. 2004 was another year in which the company also recorded no oil spillages
from ships at Fawley Marine Terminal due to company operations, and the site’s oil in
effluent water performance was the second best ever.
Page 45
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
69
For many years now the company have worked hard to reduce the amount of energy it
takes to produce our products, and without these efforts this it would be consuming some 60
per cent more fuel than it does today. Not only does greater energy efficiency make good
business sense but it also reduces greenhouse gas emissions. The new EU Emissions
Trading Scheme is intended to reduce carbon dioxide (CO2) emissions and meeting the CO2
caps brings a new impetus to energy efficiency.
Refining Operations
The "new" Esso refinery at Fawley was opened in 1951. It is the largest refinery in the UK:
one car in six in the UK runs on Fawley fuel. Most of the refinery's output leaves the site by
underground pipeline.
Chemical Operations
ExxonMobil Chemical is supplied with feedstock by its sister company, Esso (see figure
3.11). Its products are used to make plastics, textiles, toiletries, detergents, asphalt for roof
and boats and many other everyday items. Most European tyres contain butyl rubber
produced at Fawley.
Page 46
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
70
Figure 3.11 The Fawley Refinery: The control panel, Reactor Vessel and the Overview
of the plant
Source: Esso Petroleum Company and ExxonMobil (Fawley Refinery and Chemical Plant)
http://www.fawleyonline.org.uk
Picture by: Paul Carter, Ian Jackson, and Chris Pearsall (2005)
Page 47
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
71
Safety Matters
ExxonMobil is committed to the very highest safety, health and environmental standards.
But they are never complacent, and are always exploring ways of further improving the safety
and integrity of various operations.
Safety is first priority in all their activities, and our safety performance across the site is
excellent. The concern for safety, health and more cleanly environmental standard forms the
basic goal and mission of the company in Fawley;
“Nobody gets Hurt” (ExxonMobil Community report, Fawley refinery and Chemical
Plant, 2004)
Safety awards recently won at Fawley include a top award from the Royal
Society for the Prevention of Accidents (RoSPA), the chemical industry's
prestigious Diamond Safety Award, and the British Safety Council's top
Five Star awards.
One third of the employees' time is spent on safety-related matters. [ 28]
Page 48
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
72
Safeguarding the Environment
The thriving salt marsh that borders the site is a testament to Fawley's environmental
performance. It forms a Site of Special Scientific Interest (SSSI) [21]
, which is home to some
22 species of birds. The rest of the site is surrounded by a tree screen containing some 50,000
mature trees and shrubs, originally planted 50 years ago. Fawley continues to set new records
in its environmental performance. For instance:
Esso pioneered the introduction of environmentally friendly fuels in the UK.
The site's emissions to atmosphere have been falling steadily each year.
The water that returns to Southampton Water is often cleaner than when it
was extracted.
28
Source(s): Fawley Refinery and Chemical Plant (ExxonMobil community Report), 2004.
http://www.exxonmobil.co.uk Fawley, Southampton UK.
Page 49
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
73
Figure 3.12 The Diagram is some of the Pictures taken when the Refinery Perform a
“Site of Special Scientific analysis”
Page 50
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
74
Recordable Injuries and Total Recordable Injury Rate (RITIR)
The total number of employee and contractor recordable injuries –any injury requiring more
than first aid treatment – fell to one in 2004, compared to 23 in 2003 [29]
and 18 in 2002. The
total recordable injury rate (TRIR) per 200,000 work hours for employees was 0.08
compared with 0.23 in 2003, and was zero for contractors compared with 1.42 in 2003.
Employees are encouraged to take safety awareness home to share with their families and
local neighbourhood. One initiative in 2004 promoted cycling safety. Four hundred pupils at
Hardley School were given a talk about the dangers of not wearing a helmet, and ExxonMobil
donated £1,000 for the purchase of cycle helmets and lights. There was also a children’s
painting competition. The whole chart on the recordable injuries for 10 years can be seen in
Appendix 1.
The Greenhouse Gas Emissions (GhG)
The refinery and chemical plant are both in the EU Emissions Trading Scheme, which places
caps on CO2 emissions [30]
. It monitors its CO2 emissions to meet the scheme’s requirements
and an independent audit company carried out verification of these emissions.
“Oil refineries and petrochemical plants are large consumers of energy
and always are constantly looking for ways to reduce the energy
_______________________________________________________________________________________ 29
Source: http://www.exxonmobil.co.uk Esso Petroleum Company Limited and ExxonMobil Chemical ,
August 2005<www.fawleyonline.org.uk> 30
Source: http://www.exxonmobil.co.uk Esso Petroleum Company Limited and ExxonMobil Chemical,
Page 51
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
75
consumption by increasing the efficiency of there operations.”
Improving energy efficiency reduces GhG emissions. As a result of continuous
improvements, energy efficiency improvements, GhG emissions on a total and a throughput
basis continue to decrease. However, even with the focus on energy efficiency, meeting the
caps on CO2 emissions in the future will be challenging. (Diagram for the GhG in Appendix
II)
Emission to the Air
Emissions to air mainly fall into two categories: products of combustion and volatile
organic compounds (VOCs).
Products of Combustion – oxides of nitrogen (NOX) and sulphur (SOX), and carbon dioxide
(CO2) – are generated when fuel oil and gas are burned to provide heat and power. NOX and
SOX are the principal emissions that have a bearing on air quality, and are shown on the chart.
There were occasions in 2004 when the refinery processed crude oils with higher sulphur
content and burnt more fuel oil than usual. This resulted in slightly increased SOX and NOX
levels, although they were within consent limits. In 2004 emitted 7,039 tonnes of NOX,
20,382 tonnes of SOX and 3,499,000 tonnes of CO2 (see Appendix III).
VOCs - are carbon-based compounds, similar to those in paint and petrol, which evaporate
readily into the air. They are emitted from storage tanks, during the operation of equipment
and when loading ships. In 2004 company recorded 5,772 tonnes of VOCs.
August 2005<www.fawleyonline.org.uk>
Page 52
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
76
Emission to Water
The site draws water from Southampton Water to use for cooling purposes and returns it
after treatment. During the refining and chemical manufacturing processes, the water can pick
up small quantities of oil. This process water, together with rainwater that falls on the site, is
treated to a very high standard prior to its discharge.
The oil-in-water performance continues to be well within the strict consent limits due
to the significant efforts made to minimise the amount of oil present in effluent water. Nearly
150 million tonnes of water were used in 2004 for cooling. It discharges 55.4 tonnes of oil in
effluent water (average of 0.4 parts per million). Total Organic Carbon (a measure of the
amount of dissolved and non-dissolved organic carbon-containing substances present in
water) was 377.9 tonnes (average of 2.5 parts per million). Appendix III and IV gives the
statistical data for the GhG, NOX and SOX, VOCs and the emission to water for up to 10 years
of operation.
Page 53
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
77
3.10.2 Waste Management [31]
The chart below shows off-site waste disposal and includes hazardous and non-hazardous
waste [32]
resulting from routine operations, and hazardous waste from activities such as tank
cleaning or which is incident related. Much of the waste from the chemicals plant is recycled.
This includes spent sulphuric acid (H2SO4 used on site and late reused for Oleum formation
H2S2O7) which is sent off-site to be recycled to form fresh sulphuric acid for use in the plant’s
processes (see chapter 4, 8 and 11 for more information on waste management which can be
adopted by the industry). In 2005 [33]
biopiling was reintroduced in Fawley refinery, which is
a practice of oily sludge on site as an environmentally friendly means of waste disposal (the
statistics can be viewed in Appendix V).
It had been using biopiling – using ‘bugs’ to break down contaminants in waste
biologically – for some time but, in 2002, the Environment Agency required the site to be
licensed for this activity. As a result, material intended for biopiling has had to be sent off-
site, resulting in an increase in landfill waste disposal. In 2004, waste from routine operations
amounted to 4,400 tonnes of hazardous waste, 4,600 tonnes of acid to recycling (classed as
hazardous waste) and 2,070 tonnes of non-hazardous waste.
Non-routine operations produced 7,100 tonnes of hazardous waste.
_______________________________________________________________________________________ 31
Source(s): The Fawley Refinery Southampton UK. The 2005 waste management statistical data not
included. 32
Source(s): The Statistics on TRIR, GHG emission , NOX and SOX emissions COX, emission to air
and Oil in Water were all retrieved from the company’s community report and statistical data
(Fawley refinery- http://www.fawleyonline.co.uk). All statistics can be seen in the Appendix 33
Statistical data is from the website,< http://www.fawleyonline.org.uk/waste-management.pdf>
Page 54
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
78
3.10.3 Refinery to the Customer
In the everyday supply to the world market, over 45 million litres of clean petrol, diesel jet
fuel and gas oils, bitumen and chemical products are always in distribution through
underground pipelines and oil tanks.
Fawley refinery operates nearly 1,200km of pipelines in a network that connects to six
distribution terminals at key locations around the UK and airports-Heathrow, Gatwick and
Birmingham airport.
The Fawley different products are fed one after another into pipelines in a
predetermined sequence. These pipelines are controlled using sophisticated computer and
information collection system that keeps track of the interface between products so that they
can be separated on arrival at the terminal.
Most of the company’s orders are processed by the European Customer Service Centre
(ECSC) based in the UK.
According to the information gathered from the company’s website, experienced
customer service staff, computer-aided route planning and other initiatives such as the night-
shift deliveries, all ensures high level of efficiency and customer services.
The final link in the delivery system, by road from distribution terminal to customer is carried
out by a contractor company that has a fleet of around 135 Esso-branded tracks.
It is quite obvious that the company has in place quite highly well organised and
sophisticated customer to supplier and delivery system. And as such the company supplies
almost one in six cars in UK through its 950 service stations.
Page 55
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
79
3.10.4 Some of the Company’s Best Practices
The following are the few among the best practices that the company has adopted (More will
be discovered at the company’s shop floor)
It monitors its CO2 emissions to meet the scheme’s requirements and
verification of these emissions was carried out by an independent audit
company.
In 2005 biopiling was reintroduced in Fawley refinery, which is a practice of
oily sludge on site as an environmentally friendly means of waste disposal.
The total number of employee and contractor recordable injuries –any injury
requiring more than first aid treatment.
Employees are encouraged to take safety awareness home to share with their
families and local neighbourhood.
Fawley refinery operates nearly 1,200km of pipelines in a network that
connects to six distribution terminals at key locations around the UK and
airports-Heathrow, Gatwick and Birmingham airport.
According to the information gathered from the company’s website,
experienced customer service staff, computer-aided route planning and other
initiatives such as the night-shift deliveries, all ensures high level of
efficiency and customer services.
The different products are fed one after another into pipelines in a
predetermined sequence. These pipelines are controlled using sophisticated
Page 56
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
80
computer and information collection system that keeps track of the interface
between products so that they can be separated on arrival at the terminal.
The refinery performs a “Special Scientific analysis” on organism yearly to
see the effect of industry to the natural habitat and how to improve it
processes.
3.11 The Result of Gap analysis
3.11.1 Gaps/Areas to be Implemented from LeChAs
It is important to state at this stage that a full gap analysis can only be carried out at the shop
floor of any industry and as such some of the conclusions that will later be reached may not
be fully applicable to some industry but surely this report is a step ahead for a better and
intrinsic environmental friendly oil refinery. The gap analysis also has highlighted several
areas in which most of industries are failing to work on and what need to be done. This
section is determined to stress these areas and chapter 5 will fully discuss the hybridization
of Lean techniques, Chemical processes and the Automation systems for moving the oil
refinery from the current state to the new/future state expected of any oil refinery.
Page 57
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
81
3.11.2 The Dramatic Shift from End-of Pipe to Cleaner Technology
The End-of Pipe Technology
Most of industries engage in what is called End-of pipe production. This is a process in which
a process does not envisage pollution before it occurs. And as such when the pollution is
created then the industry embark on how to either abate the effect of the pollution or
containment/mitigation measures to keep to the standard stipulated in there ISO certified
agreement.
This can occur due to a little change in the raw materials used in there production.
There are varying types of crude oils used in many refineries and as such if the process used
does not take into account this phenomenon, there is high probability of pollution or failure in
the control units in place.
Cleaner Technology
There is a dramatic shift from the end-of pipe technology to the Cleaner technology. This is a
process of changing the raw materials used for production to a less or less pollution
susceptible raw material. This aspect will be discussed more fully under the use of
bituminous deposit as a substitute to crude oil as a source of energy and other necessary
product like asphalt for road construction.
Page 58
MSc Project by AKINLOLU, Akinsola O
_______________________________________________________________________________________
_________________________________________________________________________ Semi-automation in Oil Refinery and Bitumen Plant
82
There are some processes in which the raw material can not be substituted and as such
there is the need to incorporate an automation system that first deals with the analysis of the
raw material (incoming crude oil) and this will govern the way the process is going to handle
the material to avert any pollution. This is the basis, the report looks into, and the use of
LeChAs in automation of conventional refinery and the automation of the bitumen plant.
This will be discussed fully in chapter 5 and 10 under the future state/automation of oil
production and bitumen plant.
In effect implementation/application of Cleaner technology with the hybridisation
process (LeChAs development) can be the way to pollution free industrial production (zero
discharge process).