®CBS 20 STANWIX STREET, 10TM FLOOR Pll-I’SBURGH, PENNSYLVANIA 15222 November 23, 2015 To: DISTRIBUTION Dorothy M. Alke ¯ Vice President, Environmental Projects ¯ 412.642.2562 Telephone 412.642.3014 Fax [email protected]Re-" First Quarter 2014 Groundwater.Investigation Plan for Operable Unit 2 Bennett’s Dump, Bloomington, Monroe County, Indiana 1.0 BACKGROUND This report summarizes the results of groundwater, surface water, flow and water level monitoring work completed by CBS Corporation during the first quarter of 2014 at the Bennett’s Dump site. The work was performed for the purpose of assessing the feasibility of capturing PCB-contaminated shallow groundwater and to support the engineering design of an effective capture and treat system. Monitoring activities in accordance with the December 2009 Final Bennett’s Dump Groundwater Investigation Plan for Operable Unit 2 (GWIP) were performed at surface water and groundwater locations including test pits, quarries, piezometers, monitoring wells, springs and streams as¯ summarized in Table 1. The Bennett’s Dump Groundwater Investigation Plan comprises different monitoring schemes for the periods before and after construction of the Passive Quarry Drain. Pre-quarry drain construction monitoring activities were performed until completion of the quarry drain at the beginning of September 2010. The post-quarry drain monitoring program includes all of the locations and monitoring requirements .formerly prescribed by the Long Term Groundwater Monitoring Plan (LTGMP). Therefore, quarterly reporting under the GWIP will replace LTGMP reporting, pending the development and approval of a final LTGMP. In November 2013, an Infiltration Galley for the recovery of shallow groundwater was installed in Bennett’s Dump site grid B13, as shown on Figure 1. A dry-season pilot test was conducted November 5-11, 2013 to evaluate the infiltration gallery’s potential for reducing migration of PCBs from the site into Stout’s Creek in the area downstream from Middle Spring. This was the initial stage of such testing. Results of the November 2013 initial stage pilot test were distributed by email to the parties on January 7, 2014.
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®CBS 20 STANWIX STREET, 10TM FLOOR
Pll-I’SBURGH, PENNSYLVANIA 15222
November 23, 2015
To: DISTRIBUTION
Dorothy M. Alke ¯ Vice President, Environmental Projects
Re-" First Quarter 2014 Groundwater.Investigation Plan for Operable Unit 2 Bennett’s Dump, Bloomington, Monroe County, Indiana
1.0 BACKGROUND
This report summarizes the results of groundwater, surface water, flow and water level monitoring work completed by CBS Corporation during the first quarter of 2014 at the Bennett’s Dump site. The work was performed for the purpose of assessing the feasibility of capturing PCB-contaminated shallow groundwater and to support the engineering design of an effective capture and treat system.
Monitoring activities in accordance with the December 2009 Final Bennett’s Dump Groundwater Investigation Plan for Operable Unit 2 (GWIP) were performed at surface water and groundwater locations including test pits, quarries, piezometers, monitoring wells, springs and streams as¯ summarized in Table 1.
The Bennett’s Dump Groundwater Investigation Plan comprises different monitoring schemes for the periods before and after construction of the Passive Quarry Drain. Pre-quarry drain construction monitoring activities were performed until completion of the quarry drain at the beginning of September 2010. The post-quarry drain monitoring program includes all of the locations and monitoring requirements .formerly prescribed by the Long Term Groundwater Monitoring Plan (LTGMP). Therefore, quarterly reporting under the GWIP will replace LTGMP reporting, pending the development and approval of a final LTGMP.
In November 2013, an Infiltration Galley for the recovery of shallow groundwater was installed in Bennett’s Dump site grid B13, as shown on Figure 1. A dry-season pilot test was conducted November 5-11, 2013 to evaluate the infiltration gallery’s potential for reducing migration of PCBs from the site into Stout’s Creek in the area downstream from Middle Spring. This was the initial stage of such testing. Results of the November 2013 initial stage pilot test were distributed by email to the parties on January 7, 2014.
November 23, 2015 Page 2
An extended, wet-season pilot test of the Infiltration Gallery was in preparation during March 2014, including baseline sampling at Stout’s Creek segment stations. Those activities are to be reported separately and are not included in this report.
2.0 SURFACE WATER MONITORING
The monitoring work described in this report was performed during January - March, 2014. This three month period constituted the first reporting quarter of 2014 for the Bennett’s Dump site.
Scope of Work
The scope of water sampling for January-MarCh 2014 comprised collecting samples at Stout’s Creek Upstream and Downstream stations, Middle Spring, Rusty Spring and Icebox Quarry. North Spring, Mid-North Spring and Mound Spring were not observed flowing during the first quarter.
Sample Collection and Handling
Samples at the spring and stream locations were collected by carefully filling a new disposable beaker. The water was transferred from the beaker into pre-cleaned amber glass 1-1iter bottles supplied by the analytical laboratory. Routine sampling parameters including temperature and conductivity were measured and recorded.
Samples were analyzed by Pace Analytical Lab of Indianapolis, Indiana. The samples were analyzed to a detection limit of 0.1 parts per billion (ppb) for all PCB parameters by EPA SW-846 method 8082. Beginning in April 2011, Stout’s Creek Downstream samples are analyzed to a detection limit of 0.01 ppb. Samples were also analyzed for total suspended solids (TSS) by method SM2540 D.
Quality Assurance
For quality assurance purposes a duplicate sample and a field blank were collected during each sampling event. All environmental and blank samples were labeled and logged onto a chain of custody form. The samples were stored and transported on ice in insulated coolers. Custody of the water samples was maintained by CBS until shipment to the analytical laboratory.
The field blank sample for 2014 first quarter GWI sampling was BD10770. PCBs were not detected in this sample.
Analgtical Results for Surface Water Samples
Field parameter measurements, PCB analytical results, and QA/QC results for surface water samples collected during this reporting period are reported in Tables 2 through 9. Each table summarizes historical groundwater monitoring data collected since the completion of Passive Quarry Drain in September 2010.
November 23, 2015 Page 3
Copies .of the chain of custody forms are provided in Appendix A. Copies of the certificates of analysis are provided in Appendix B. A validation summary for these samples appears in Appendix C. Copies of the field sampling data sheets are on file at PSARA’s Bloomington Branch Office.
3.0 FLOW AND WATER LEVEL MONITORING
The purpose of flow and water level monitoring is to evaluate site-specific data characterizing site hydrologic response under storm and non-storm conditions, and to evaluate correlations between PCB concentrations, spring flow and groundwater elevations. The goals are to assess the feasibility and support the engineering design of a system to capture and treat Middle Spring flows and nearby shallow groundwater.
Scope of Work
The scope of groundwater level and flow monitoring during this reporting period involved numerous manual measurements and observations, as well as the use of dedicated instrumentation to record water level and other parameters as summarized in Table 10. The instrument at Mound Spring was removed in the third quarter 2012, during an extended dry period, and will be re- installed if adequate .flow resumes.
The approximate locations of the stations are shown on Figure 1.
Flow and Water Level Plots
Middle Spring flowed throughout the first quarter. Mound Spring was not observed to flow during the January-March period. Therefore there are no plots of Mound Spring flow. Manual observations made at Mound Spring during the first quarter were added to the plots of Middle Spring flow.
Flow observations at on-site springs also are presented in Table 11. An Excel spreadsheet file, including water level and flow observation data, accompanies this report as an attached file: BD GWIP Water Level Observations with plots - Q1 2014.xlsx.
Quality Assurance
An instrument maintenance log for the Bennett’s Dump installations is provided in Appendix D. This log details the installation, re-indexing, and maintenance histories of the data logging equipment present at Bennett’s Dump during the reporting quarter.
November 23, 2015 Page 4
Crest Gauges
The purpose of the crest gauges at Middle Spring and Mound Spring is to provide an indication of maximum flow during each reporting period. Maximum recorded water levels and flows estimated from these data are presented in the instrument maintenance log in Appendix D. Manual observations during the First quarter are presented in Table 11. Mound Spring observations are :included on the Middle Spring flow plots.
Potentiometric Data
Potentiometric contours shown on Figure 1 were developed based on water level measurements taken on March 18, 2014. The specific water level measurement locations are listed in the table :insert on Figure 1.
If you have questions regarding the sampling and flow/water level monitoring activities or findings for this reporting period, please call Neill Vaughan at (812) 335-0424.
BP:15-(
Attachments
DISTRIBUTION Tom Alcamo, USEPA Region 5 Douglas Petroff, IDEM Simeon Baker, MCHD
CC:
John Langley, CBU Jeff Lifka, Tetra Tech John Bassett, AECOM Russ Cepko, CBS Mike Hessling, PSARA Patrick Kneip, PSARA Neill Vaughan, PSARA BP Files
List of Tables
1. Groundwater Investigation Plan Monitoring Requirements and Recommended Interim Plan
3.
4.
5.
6.
7.
8.
o
10.
11.
12.
Requirements
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Icebox Quarry Water Samples
Stout’s Creek Upstream
Stout’s Creek Downstream
Mound Spring
Rusty Spring
Middle Spring
Mid-North Spring
Post-Quarry Drain PCB Results, North Spring
Flow and Water Level Monitoring, GWIP Stations
Flow Observations, On-Site Springs
Instrument Maintenance Log (Appendix D)
List of Figures and Plots
Figure 1 - Site Map with Monitoring and Sampling Locations, Potentiometric Surface Contours
Continuous Monitoring Plots Middle Spring Continuous Flow and Mound Spring Flow Observations, January 2014 Middle Spring Continuous Flow and Mound Spring Flow Observations, February 2014 Middle Spring Continuous Flow and Mound Spring Flow Observations, March 2014
Manual Monitoring Plots Bennett’s Dump On-Site Springs Flow and Rain, January 1 to March 31, 2014
Stout’s Creek Downstream Flow and Rain, January 1 to March 31, 2014 Bennett’s Dump Quarries and Pits, Observed Water Levels Bennett’s Dump Monitoring Wells, Observed Water Levels Bennett’s Dump Piezometers, Observed Water Levels
TABLES
Table 1. Groundwater Investigation Plan Monitoring Requirements
and Recommended Interim Plan Requirements
Bennett’s Dump, Bloomington, Monroe County, Indiana
Station
Middle Spring
Mound Spring
Middle Spring
Mound Spring
Rusty Spdng
Stout’s Creek Downstream
Stout’s Creek Upstream
North Spring
Mid-North Spring
Wedge Quan’y
Wedge South Quar~
Test Pit A
Test Pits 1,2,3,and 4
Downstream Quarry Drain
Outlet
Wedge Quarry
Icebox Quarry
Wedge Quarry
Wedge South Quan’y
Icebox Quarry
Test Pit A
Test Pit 4
PZ-H7
PZ-K9SW
PZ-I 11
PZ-LM5
MW-BC-10
MW-B 13
MW-C5
MW-C4A
MW-C3A
MW-I
MW-3
1VF~-6I
MW-6D
1 Frequency
2 weeks prior to drain construction
12 months after drain construction
Monthly after drain construction
or episodic so 12 samples collected
Every 2 weeks after drain construction"
Monthly after drain construction
Pre-drain construction - every rain event
Pnst-Drain construction - 5 rain events
Post-drain construction - 5 rain events
Once pre-drain c~nstruction.
After drain construction, if PCBs found
in downstream drain outlet then
individual components monthly
Monthly after drain construction
Every 2 weeks after drain construction
After one storm >I"
Quarterly after drain construction
Every 2 weeks before drain construction,
Monthly after drain construction
Every 2 weeks before drain construction,
Monthly after drain construction
Water Level or Flow
Measurement
¯ Hourly logging of flow, at V-notch weir
V-notch or visual flow estimate
Flow by velocity probe
Flow by velocity probe
Visual tlow estimate
V-notch or visual flow estimate
Water level
Weir, velocity probe or visual flow
estimation, depending upon
conditions
Hourly water level
Water level
Water level
Water level
Sample2
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
Frequency of monitoring and sampling is quarterly, unless amended by approved Scopes of Work for other GWIP activities.
At time of PCB sample collection, also measure field parameters of conductivity and temperature. 3 Previous Interim recommendations anticipated the March 2012 pumping test and a follow-up pumping test, performed in March-April 2013.
Note: All monitoring requirements subject to change when a final revised LTGMP is developed.
TOTAL sUSPENDED sOLIDS DRIED AT 103~105 DEGREES CSM2540 O 19TH ED i. " : NELAC:Y
Parameter Result Det. Limit Units
SUSPENDED SOLIDS I1 I 1 I mg/L
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace Analytical
Pace Analytica! Services,
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Lab ID
AA1175O
Report To
RUSS CEPKO CBS CORP - NATIONAL CITY CENTER
20 STANWIX STREET
10TH FLOOR PITTSBURG, PA 15222-1384
CLIENT ID: BD10768 MATRIX TYPE: NON-SPECIFIC WATER
SUBMITTER: 2226 - CBS CORPORATION DATA PACKAGE #: 66021 MATRIX: WT
LOCATION: BENNETT’S DUMP
26-MAR-14
Printed
27-MAR-14
Bill To
BETH STEIGERWALD
CBS CORPORATION
Completed PO Number
BL-0396
Sampled
18-MAR-14 10:00
20 STANWlX STREET 10TH FLOOR PITTSBURGH, PA 15222
Sample Description
PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C i :
. ~nalyst:.CiHIPSKiND ~ ii i i : ~ A~’~iysis Datei21’MAR~i4 ~ instrUme~i PREP’ ~::
Parameter Result Det. Limit
INITIAL WEIGHT OR VOLUME 2000
FINAL VOLUME 1
~ PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846;8082A ......... ¯
: Prep: POB SEPARAToRY FUnnEL. LIQUID:LIQ0iD:EXTRA~i0~:S~846:3516~ P230.ii~ :
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221
PCB AROCLOR 1232
PCB AROCLOR 1242
PCB AROCLOR 1248
PCB AROCLOR 1254
PCB AROCLOR 1260
PCB AROCLOR 1262
SURROGATE RECOVERY
DECACHLOROBIPHENYL(DCB)
SUMMATION OF AROCLORS
Result
BDL
BDL
0.086
BDL
BDL
BDL
52.0
Det. Limit
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
% Rec
0.086 0.01 ug/L
Aroclor pattern is degraded
Page 1 of 2
~ace Analytical~
Pace Analytical Services, Inc.
Sample lD: AAl1750 BD10768
TOTAL SUSPENDED SOLIDS DRIED AT 103’105. DEGREES C SM2540 DI:i9TH ED ’~’ i NE[_AC:Y :
Parameter Result Det. Limit Units
SUSPENDED SOLIDS I1 I 1 I mg/L
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace AnalyticaF Pace Analytical Services, Inc.
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11751
PO Number
BL-0396
Sampled
18-MAR-14 10:15
Report To
RUSS CEPKO CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET 10TH FLOOR PITTSBURG, PA 15222-1384
CLIENT ID: BD10769
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
DATA PACKAGE #: 66021
MATRIX: WT
LOCATION: BENNETT’S DUMP
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWlX STREET 10TH FLOOR PITTSBURGH, PA 15222
Sample Description
Parameter
1Result i Det. Limit Urn~i~s ,,
INITIAL WEIGHT OR VOLUME 2000 mL
FINAL VOLUME ~ i i~: ’ .....
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221’
PCB AROCLOR 1232
PCB AROCLOR 1242
PCB AROCLOR 1248
PCB AROCLOR 1254
PCB AROCLOR 1260
,PCB AROCLOR 1262
SURROGATE .:RECOVERY
DECACHLOROBIPHENYL; (DCB)
SUMMATION OF AROCLORS
Result
BDL
BDL :: :: : ::
BDL
BDL
BDL
BDL
BDL
BDL
66.0
BDL
Det. Limit
0.01
’ : O~Ol
0.01
0.01
Units
ug/L
ug/L’
ug~L ug/E
0.01 ug/L
0.01 ug/_L
0.01 ug~L
% Rec
0.01 ug/L.
Page 1 of 2
~ace Analytical °
Sample ID: AAl1751 BD10769
TOTAL SUSPENDEDISOLIDS IDRIED AT103.4 05 ~DEGR EE~ ~i SM2540 D 19THED ’ ~ :: :~’ i: NELAC:Y i
Parameter Result Det. Umit Units
SUSPENDED SOLIDS
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25~MAR-14
Page 2 of 2
~ace Analytical Pace Analytlc~l Services, Inc.
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11752
PO Number
BL-0396
Sampled
18-MAR-14 10:20
Report To
RUSS CEPKO
CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET
10TH FLOOR
PITTSBURG, PA 15222-1384
CLIENT ID: BD10770
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
DATA PACKAGE #: 66021
MATRIX: BD
LOCATION: BENNETT’S DUMP
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWlX STREET 10TH FLOOR
PITTSBURGH, PA 15222
Sample Description
Parameter
FINAL VOLUME
Units
m L
mk
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221
PCB AROCLOR 1232
PCB AROCLOR 1242
PCB AROCLOR 1248
PCB AROCLOR 1254
PCB AROCLOR 1260
PCB AROCLOR 1262
SURROGATERECOVER¥:
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
62.0
BDL
Det. Limit
DECAGHLOROBIPHENYL (DCB)
SUMMATION OF AROCLORS
Units
0.10 ug/L
0.10 :ug/L
0.10 ug/L
0.10 Ug/L
0.10 ug/L
0,10: ugiL
0.10 ug/L
0.10 ug/L
% Rec
0.10 ug/L
Page 1 of 2
, . ~ace Analytical~
Sample lD: AAl1752 BD10770
TOTAL: SUSPENDED SOLIDS DRIED AT 103’105 DEGREESiC SM2540 D 19~HED . :i, ~::, i~;~:, N ELAC:¥1 ~
Parameter Result Det. Limit Units / SUSPENDED SOLIDS L BDL [ 1 ~ rng/L /
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace Analytical°
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11753
PO Number
BL-0396
Sampled
18-MAR-14 10:25
Report To
RUSS CEPKO
CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET
10TH FLOOR
PITTSBURG, PA 15222-1384
CLIENT ID: BD10771
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
DATA PACKAGE #: 66021 MATRIX: BD
LOCATION: BENNETT’S DUMP
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWIX STREET 10TH FLOOR PITTSBURGH, PA 15222
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace Analytical~
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11754
PO Number
BL-0396
Sampled
18-MAR-14 10:45
Report To
RUSS CEPKO CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET 10TH FLOOR PITTSBURG, PA 15222-1384
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWIX STREET 10TH FLOOR PITTSBURGH, PA 15222
Sample Description
CLIENT ID: BD10772
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace Analytical
Pace Analytical
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST.
INDIANAPOLIS, IN 46231
(317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11755
PO Number
BL-0396
Sampled
18-MAR-14 10:30
Report To
RUSS CEPKO
CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET
10TH FLOOR
PITTSBURG, PA 15222-1384
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWlX STREET 10TH FLOOR
PITTSBURGH, PA 15222
Sample Description
CLIENT ID: BD10773
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
DATA PACKAGE #: 66021 MATRIX: BD,
LOCATION: BENNETT’S DUMP
Parameter
INITIAL WEIGHT OR VOLUME
FINAL VOLUME
Result
1000
5
Det. Limit Units
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221
PCB AROCLOR 1232
PCB AROCLOR 1242 ’
PCB AROCLOR 1248
PCB AROCLOR t 254 ....
PCB AROCLOR 1260
PCB AROCLOR 1262
SURROGATE RECOV:ERY, .....
DECACHLOROBIPH ENYL (DCB)
SUMMATION OF AROCLORS ...... :
Aroclor pattern is degraded
Result
BDL
BDL
2.9
BDL
BDL
BDL
BDL
92.0
2.9
Det. Limit Units
0.10. ug/L
.0.10: U~/L .....
0.10 ug/L
0.10 uglL
0.10 ug/L
0.10 ug/L 0.10 ug/L
’% Rec
0:i:0i’ug/L :
Page 1 of 2
,~ace Analytical ° Pace Analytical Services, Inc.
Sample lD: AAl1755 BD10773
Parameter Result Det. Limit Units I
SUSPENDED SOLIDS ~ 2 t 1 ~ mg/L J
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
APPENDIX C
Data Validation
Validation Results March 18, 2014
Bennett’s Dump SDG #66021
Groundwater Monitoring Samples
1. Validation of the following samples has been completed:
BD10767 to BD10773
Validation was performed per the requirements forlevel 4 data in the project QAPjP. This includes a check for; Holding Time, Calibration, Blank Contamination, Precision, Accuracy, and Accuracy of Nominal Reporting Limits against method requirements.
Based on this review no data qualifications are recommended.
The QAPjP requires an assessment of the overall data quality with respect to Precision, Accuracy, Representativeness, Completeness and Comparability (PARCC).
o Precision and accuracy: Precision and accuracy were accessed by reviewing the lab performance on lab spiked samples, lab spike duplicates and field duplicates. All requirements were met.
o Representativeness: The representativeness requirement involves an assessment of the field sampling and lab analytical techniques. The field sampling locations and techniques as well as lab procedures were in accordance with the approved sampling plan and QAPjP. Therefore the representativeness requirements were met.
o Completeness: The completeness goal for the project was for all project data to be 90% accepted. Completeness is calculated by dividing the total number of acceptable analyses by the total performed. An acceptable analysis is defined as one that conformed to QC protocols and is not rejected. All these analyses were accepted. The project completeness goal has been met to date.
O Comparability: All the samples taken, analyzed and validated by CBS were ¯ taken by CBS or it’s contractors sampling crews using the same procedures as previous samples at this location. These samples were analyzed by Heritage Labs. Care should be taken when attempting to trend Heritage sample results with other labs using slightly different procedures. Overall these results should be directly comparable to other Heritage lab results from these locations.
Overall, the main objective of the sampling event was to determine if PCBs are present at a concentration of. 1 ppb or more (!).0] ppb for Stout’s Creek ])ownstream, SCD and Upstream, SCIJ-).. This data is of sufficient quality to satisfy this goal.
O:~LEA~EnvironmentalkBloomington\SHAREDIRkBP validation~reports\validation report -BD Mar 18, 2014.doc 9/2/14
APPENDIX D
Instrument Maintenance Log
Bennett’s Dump InStrument Maintenance Log First Quarter 2014
Office Rain Gauge: Instrument
HOBO
#9928483
Mound Sp.: Instrument
Crest gauge
Middle Spring: Instrument
In-Situ LevelTROLL #303381
Crest gauge
Date
1/1/2014 to
3/31/2014
1/1/2014 to 3/31/2014
2/18/2014 2/21/2014 3/26/2014
1/13/2014 2/4/2014 2/18/2014 3/5/2014 3/19/2014
2/18/2014 2/21/2014 3/26/2014
Action
Normal function.
Not instrumented, Manually observed due to infrequent and short-duration flow.
0.33 feet 0.32 feet 0 feet
No re-indexing needed. Re-indexed by 0.001 ft. Re-indexed by 0.019 ft. Re-indexed by 0.003 ft. Re-indexed by 0.004 ft.