UNITED STATES ENVIRONMENTAL PROTECTION AGENC' • REGION III CENTRAL REGIONAL LABORATORY 839 BESTGATE ROAD ANNAPOLIS. MARYLAND 21*01 ,(301)286-9180 - DATE: ^—3-^ o SUBJECT: Region HI CLP Data QA Review FROM: Patricia J. Krantz (3ES23) Chief, Quality AssuranceT^Region III TO: QAO, AOB (OS 230) Attached is a Region IIICLP Data Review by reviewers at CH2M HILL. SITE: " Raymark CASE NO: : 13383 " '.-'.. SDGNO: CAW50 LABORATORY: Versar Inc. REVIEWER: Gayle Lytle Attachments —_ _ __ : cc: EPA Site RPM: Mike Towle Edward Kantor, EMSL-LV Regional DPO: Tmn Dciujell,
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CASE NO: : 13383 · The samples collected on December 19, 1989, were designated as Case 13383. Case 13383 consists of Organic Sample Delivery Group (SDG) CAW50 which includes iO soil
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UNITED STATES ENVIRONMENTAL PROTECTION AGENC'• REGION III
CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD
ANNAPOLIS. MARYLAND 21*01,(301)286-9180 -
DATE: ^ — 3-^ o
SUBJECT: Region HI CLP Data QA Review
FROM: Patricia J. Krantz (3ES23)Chief, Quality AssuranceT Region III
TO: QAO, AOB (OS 230)
Attached is a Region III CLP Data Review by reviewers at CH2M HILL.
SITE: " Raymark
CASE NO: : 13383 " '.-'..
SDGNO: CAW50
LABORATORY: Versar Inc.
REVIEWER: Gayle Lytle
Attachments —_ _ __ :
cc: EPA Site RPM: Mike TowleEdward Kantor, EMSL-LVRegional DPO: Tmn Dciujell,
DATA VALIDATION EVALUATION CHECKLIST
Case/SAS Number: l_339__3_____ Site Name: RjGL\fmOf /<-Assignment #:______;___ Revision Number; $ ] G nalysis Type; ______Reviewer; fay/g. LjJ-tf g.______ Contractor; . CHlM lj ILL_____ Sdtfr f: f/JTAnalytical Laboratory; V(s£gj~_______" " ""_____________________Information Informationrequest date: _________ ___ _______ received date:Date submitted to EPA:EPA DPO; Cfru fc. Cayirf.S _________________ Number of hours spentEPA RPMt Mik*. TptVJC on review: H 5
cc: Joe, CUOjry [r.ti 3M HILL _________ Number of_____________________________ samples : 1 3
CRITERIA YES NO COMMENTS
Format according toRegion III protocol
Clarity of report
Qualifiers appliedcorrectly
Consistency betweennarrative, data summaryform(s), and DPO report
Error-free transcription - <&A+J'
EFFICIENCY OF YE5 : NO COMMENTSCONTRACTOR .._ _. , ... -. -.-.....-,— -.,',..-, ... ——.-=..- - - • -----— ~
Approval recommendedfor current submission
Time spent on reviewis reasonable
ESP OVERSIGHT .... , . ... - • - •MONITOR/ ^ /-
DATES AFC/DPO EVALUATOR Jj ~~ ESAT
Received at EPA (j?~~\ I ____Oversight assigned _ . /^^Oversight rec'd by TM JLJN | 3 iy J //ty/.f£Oversight completeFeedback given _-r • 3 • S pMailed to RPM
EVALUATOR SIGNATURE:___________
revised 01/90
MEMORANDUM
TO: Mike Towle/EPA RPM
COPY: Claudia Walters/EPA (3ES23)QA SectionJoe Cleary/CH2M HILL
FROM: Dean R. Charpentier/CH2M HILL OcuGayle Lytle/CH2M HILL JUJ*
DATE: May 15, 1990
RE: Organic Data Validation for RAS Case 13383, SDG CAW50Site: Raymark
OVERVIEW
This data validation report discusses the quality of the data generated from the Raymark site.The samples collected on December 19, 1989, were designated as Case 13383. Case 13383consists of Organic Sample Delivery Group (SDG) CAW50 which includes iO soil samples,1 field duplicate (soil), 1 trip blank (aqueous), and 1 field blank (aqueous) for a total of 13samples. These samples were analyzed through the Contract Laboratory Program (CLP)Routine Analytical Services (RAS) for semivolatiles, volatile organics, and pesticides/PCBs.The requested analyses were performed using approved EPA methodology.
SUMMARY
All the Target Compound List (TCL) organics were successiully analyzed. Areas of concernare listed below under major and minor problems.
MAJOR PROBLEMS
No major problems were encountered during the analyses.
MINOR PROBLEMS
1. -The volatile analysis included five (5) method blanks. The tentatively identifiedcompound (TIC) carbon dioxide (ACN) was found in four (4) of the blanks.This TIC was not found'in any of the samples so no action was taken.
Method blank VBLK89 was contaminated with 3 ug/L methylene chloride. Thisblank affected all samples. All associated results less than ten (10) times the methodblank concentration were qualified possible blank contamination "B".
Acetone was detected in the field blank at 6 ug/L. All associated results less thanten (10) times the method blank concentration were qualified possible blankcontamination "B". _
2. The semivolatile internal standard for CAW57 had an area of 62700 greater than theupper limit of 58800 for perylene-d!2. Since results for all compounds in thissample were non-detect, all compounds associated with perylene-d!2 were qualifiedestimated "UJ".
3. The holding time for several samples was exceeded for volatile analysis. Allaromatic compounds in these samples were qualified biased low "L" or "UL".
4. Extraction holding times were exceeded for soil using the water holding time criteriafor semi-volatiles. All results exceeding 7 day holding time criteria have beenflagged estimated "J" or MUJ".
5. The instrument used for the water sample analysis for volatiles yielded an initialcalibration for acetone (40.6%) that was outside the relative standard deviationcontrol limit (30%). All water sample results for acetone were qualified asestimated "J" or "UJ".
6. Several compounds had values below the Contract Required Quantitation Limit(CRDL) and therefore, were qualified as estimated "J".
7. Several TICs were found in both soil and water semivolatile method blanks. Anyof these TICs found in a sample were crossed off Form IPs. All other TICs wereflagged estimated "J". ...... ...... ..._._. ... _
NOTES
1. The semivolatile MS/MSD recovery for soil was outside of control limits for 4-nitrophenol. The percent recovery for this compound was 121 % and the limit is 114 %.No qualification was made for this reason alone.
2. The semivolatile initial calibration relative standard deviation for benzoic acid (36.2%)was greater than the control limit of 30 %. Since there were no positive results for thiscompound, no flags were applied.
3. The volatile continuing calibration yielded several percent differences greater than thecontrol limit of 25%. Since there were no positive results in the associated samples,it was the reviewer's professional judgment not to apply flags to this data due tocalibration problems.
4. The matrix spike (MS) sample for soil pesticides had percent recoveries below thecontrol limit (75%) for dieldrin (19%), endrin (1956), 4,4'DDT (0%), lindane (17%),and heptachlor (31 %). No action was taken.
5. The matrix spike duplicate (MSD) for soil pesticides also had recoveries outside thecontrol limits for dieldrin (24%), endrin (26%), and 4,4'DDT (0%). The resultantrelative percent difference between MS and MSD results exceeded QA criteria forlindane (117%) and heptachlor (75%). No action was taken.
6. Reproducibility of the aroclor-1260 peaks exceeded the 20% difference QA/QC limit.Percent difference for aroclor-1260 equaled 25 % and 33 % on successive runs. Aroclorwas not detected in any samples. No action was required.
7. In the semivolatile analysis of CAW54, benzo(b)fluoranthene and benzo(k)fluoranthenedid not meet EPA CLP criteria for confirmation. It Was determined after inspection ofthe mass spectra for these two compounds that there was enough agreement among thepeaks to consider the compound present, and no further action was taken.
8. This validation was performed using the Laboratory Data Validation FunctionalGuidelines for Evaluating Qrganics Analyses (February 1988) and the Region IIIModifications (June 1988).'
ATTACHMENTS
Appendix A Glossary of Data Qualifier Codes
Appendix B Data Summary Forms
Appendix C Results as Reported by Laboratory (Form I)
Appendix D Reviewed and Corrected Tentatively Identified Compounds
Appendix E DPO Report
Appendix F Document Support
Sample Cross-Reference TableEPA Case 13383Versar Inc.Raymark
Date Sampled CLP Sample SampleNumber Type
12-19-89 .. CAW50 Water Field Handling Blank
12-19-89 CAW51 Water Trip Blank
12-19-89 CAW52 Soil
12-19-89 CAW53 Soil
12-19-89 - CAW54 Soil
12-19-89 CAW55 Soil
12-19-89 - - CAW56 Soil
12-19-89 CAW57 Soil
12-19-89 - CAW58 Soil
12-19-89 CAW59 Soil
12-19-89 CAW60 Soil
12-19-89 CAW61 Soil
12-19-89 CAW62 Soil Duplicate of CAW55
Appendix A
Glossary of Data Qualifier Codes
GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)
CODES RELATING TO IDENTIFICATION(confidence concerning presence or absence of compounds):
U = Not detected. The associated number indicates approximate sampleconcentration necessary to be detected.
(NO CODE) = Confirmed identification.
B * Not detected substantially above the level reported in laboratory or fieldblanks.
R = Unreliable result. Analyte may or may not be present in the sample.Supporting data necessary to confirm result.
N - Tentative identification. Consider present. Special methods may be neededto confirm its presence or absence in future sampling efforts.
CODES RELATED TO QUANnTATION .(can be used for both positive results and sample quantitation limits):
J = Analyte present. Reported value may not be accurate or precise.
K * Analyte present. Reported value may be biased high. Actual value isexpected lower.
L * Analyte present. Reported value may be biased low. Actual value isexpected to be higher.
UJ « Not detected, quantitation limit may be inaccurate or imprecise.
UL - Not detected, quantitation limit is probably higher.
OTHER CODES
Q - No analytical result.
AR3Q0053
Appendix B
Data Summary Forms
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COMPOUND
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FOR CODE DEFINITIONS
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° 5
Appendix C ;
Results as Reported by_.Laboratory (Form I)
330
1AVOLATILE QRGrtNICS ANALYSIS DATA SHEET ^ SflMPLE
74-87-3——"- -- h loroinethane__________ _ \ 12 IU74-S3-9"--~^————Bromomethane________________ j _ 12 I U75-01-4-——— T VA*! Chloride.___*_________ j 12 I U75-00-3————————Chloroeth&ne '•75-09-2 ———————Methy 1 ene Ch_lorid.e.67-64—i------——Acetone.
12 JU7 !
_____________________, 12 IU! 75-15-0—-—~——darboV'DisLiff id&___;_Z___— ' 6 I UI 75-35-4—~ --~—1, 1 -Dich 1 oroeth^ne JT^__;__ZZ_ I 6 I UI 75-35-3————————-1, l-Dichloroe:thane__________ I 6 I UJ 54O-53-0———---"i,S-D.ichloroeth,ene.l,i-fcDt^l^ __ I 6 I Uf 67-66-3—- - R nlorof orm____'___________3—' -& ' uI 107-06-2—-—-'- —i, 2-l).ichloroethane_______!_ I S 1 UI 78-93-3——i-——- -p-ftM*!1 - - - :..._ ____________________, . 12 IUI 71-55-6—————-_^1", 1, l-TrichipTop^hane______^_ I, 6 I UI 56-23-5——•-——————Carbon Tetrachlpride___^___;— I 6 I UI 108-03-4—————-V_inyl" Acetate___u._,__~______^' 12 I Ui 7 5 —E'7—4 •—- —-^—- —— B r o.m o d i c h 1 or onie t h a n e.___. _ ____ J 6 I U7S-S7-5—-^—=^=^i=*i . p-n'i r-h i r*.^«n.K«-« — ~ - . . . . u___ __^ _ _,___1QO610-1-5— —— -~cis^l,3-DichlorppropeneI__ _ _l 6 IU79-01 -6----^----Trichloroethene_____._.__^_-_._ ___ J IS I
— ^ ™-—™.,.. J 6 ! U. ^ _ _ l l 6 I U
71-43~2--~::-~ -:-lSe"nzerte __ __" _ '_ __ __ ___ " ___ " I 6 I U10061-02-6— —^-—brans-1, 3-Dich lor opropene ___ ! 6 I U
i , j--cl/™-*t-»--*"-=-=—~——i<roi'rto'dich lproiii(i?than.e_^_^_,I 78 - S 7 •-• 5 -----1- —- - 1, 2 - D i c h 1 o •/- o p T d p a n e? _v_^-___^_,I 1 f\S\'£ "I ^ '•• "=•" " - - - - . . ^_- - : - - - -
CONCENTRATION UNITS:CflS NO. COMPOUND <ug/L or ug/Kg) UG/KG Q
1 .______. . . . . . . I II 74-S7~3--~™----~-CI-iloromethane_^i_____________ I 13 I U
I 75-01-4—--————^Vinyl""ChloTidelZZZZZZZZZZZZZZi 13 I U\ 75-00-3-----~~™~-C"hlDroethane____™__~_____ I 13 " I UI 75-09-2—-—————Hletbylene ChlorideZ___:_____I . 16 IBI 67-64-1———————Acetone____._______________ I 7 ! JI 75-15-0——————-—Carbon bisulfide____~______1 7 IUI 75-35-4————————-'l, 1-Dichloroethene______~_ I 7 I UI 75-35-3————-———1, 1-Dichlorpethane_________~l _ 7 IU1 540-59-0 ——————— l,E-Dichloroethene Xtotal) __ I 7 !UI £7~66-3---~-r---^-:-Chiofoform____J______'_________ i 7 I U
I 78-93-3——^—-^-2^Buj:anpne_'__*~_____________ I 13 I UI 71-55-6------~-~i7T, f'-frichlorpethane_^___ I 7 I UI 56-23-5—-———-—Carbon Tetrachlora.de_____^__ i 7 I US 108-05-4———————VinyT "Acetate________.__.,__"^J 13 I U
! 7S-fl7-5—-"— -r- —T, 2--DichlprppT:PpanE>____-____ I 7 i UI 100610-1-5—————cis~l, 3-Dichiorppropene_____,1 7 I UI 79-01-6—~————-Trich'l oroeth ene_____________J 7 IUI I24~4fi-i—•-—————Dibromochlorometbane________ I /" I UI 79-00-5———'—?-" "•. '-1, 1, H-Trichloroethavie^^^^^^^^^l 7 I UI 71-43—2——••———--^JSenzene_______\_______^^___ I 7 I Ut 10061-02-6—————-trans-1, 3-DichlpTopropene____I 7 !UI 7i3~* 25~ 2—'—————:—" "Br onto f or ni __ , J 7 I UI 108-10-1-——=————/*"iv(e'*'t"'>'1-2-Pentanone3ZZZZZZZZl 13 1U! 591-78-6————-.—-2-Hexanone._________12______ I 13 IUI 127-18-4———————Tetrachlo-rpethene__.?=_____2_Z-' -, 7 f'ui 79-34—5———•—•-—™i, 1, S, S-Te^trachlorpethanc___l_ . 7 JUI 108-88-3—-~-——--ToTuene__"___I______________I . 7 IUI 108-90-7———————Chlorobenzene_______________! 7 IUI 1 i^ri_Ji 1 ~A____ — — __™Cf'"'[""K v/1 f". /i •/•. -r r~.n ci " I "7 I I Ii .L \j\j -*i .i. ~*t——————— t. tfi t y j. LJt?iiz e j '£?_.__ _ l / i ui 100-42-5—>——»~-Styrene____._Z»_Z™_________;__ I 7 I UI 1330-20-7-——————Total Xylenes_ __ ~ ]
% Moistures not dec. 32 :. - Bate Analyzed: 12/H8/S9
Column: '<pack/cap) PACK Dilution Factor: 1.0
CONCENTRATION UNITS:CAS NO. "COMPOUND '• (ug/L or ug/Kg) UG/KG Q
I 74-37-3—-—-•^——-'CTilp-ronie thane.i 74-83-9—-----———Bromomethane__I 75-01-4 —————~^V i n yl C hl'o r±d <I * >j—OO—3"~'——*——••?••——\_,n l proetn ane_ _ II 75-09-S——T——-—Methylene Chiprid'e^_________Z_ JI 67-64-1—=-—==-*——Acetone _"... "_...._,....:_______________ II 75-is-o———————-Carbon Disulfide________.___ II 75—35-4———•————1, l~D,i-chloroethene__________ II 75-35-3-——-———-1, 1-Dichl oroeth ane_,_____:___ II 54O-59-0———————1, 2-Di ch 1 orpethene C total > "„ II 67-66-3r--—-T-~~~rCh 1 orof orm.___^^_________^^____ I
I 56-23-5——:—'—-——^Carbon f etrachloride___;____ ii 1 f\a_.A _A_____.......---...11•; •n'.j 'ii j. vc> w*j—"i———————v u. ny J.• 7S--£'7-'4.----- -.—-—Brombcl I
I 100610-1-5-—-_——ci.s-1, 3-DichlorpprPpene_____ Ii 79-0I--D"---—?——=—-Trichloroethent?___________;___ Ii 124-48-1-—————^jOil^rpmj^chlp-rp^methant?^__^^_=._^.-l.I 79-00-5-—*- -~> =l, 1, -lTrJ.chlprpethane,_ ^ , __ If 71 -43-2——™-——™-B'e'nz e'he_ 'f___^___________"____ lI 10061-OE-6—————trans~l , 3-Dich'lprpprppene___ I1 75-H5-S.—:—--—-~Bromoform_________;_________ IIOW —* 'I ») -" 1 ~™ •*——•-•**" — -i-. —•-*—- li i |V| j^i " r> •.* T —* «J — L"*11X1 v^ *fr* "» v% J^i i.' 1J' *^ *-* J* w j* 7 j i tr L- *« > J. £*• r t. II w til 11U j I ti l
I 591-73-6—-——---2-Hexanone_____;____ZHIIZZZZ'1 127-18-4——•———™Tetracnlcjroethene___________ II 79-34-5--—-*-*- —'~-~-i,1,2, 2-fetrachioroethane___ 1j ios-88-3———————Toluene__^__________________I' 108-90-7———'——""Chlorobenzene_^_____________ I: lot) ;-41-~4™——————^Ethyl benzene__________________ iI 100-42-5——-——-Sbyrerie „__..". ;.._"_ _„ _____Z'i 1330~£C)~7—^———-totar'Xyleines,
FORM I VOA
ift ' EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET
I CAU61uab Name: VERSAR INC Contract: Ga-01-7471 I
uab Code: VERSAR Case No.: 133S3 SAS No.s" SDG HP.: CAW50
Matrix: (soil/water) SOIL. Lab Sample ID: 93396A
Sample wt/vols 5-0 Cg/mLi G Lab File IBs R3011
Level: Clow/med) LOU Bate Received: 12/20/89
% Moisture: not dec. 41 Bate Analyzed: 12/23/39
Column: (pack/cap) PACK Dilution"Factor: 1.0
CONCENTRATION UNITS:CAS NO. COMPOUND <ug/L or ug/Kg) UG/KG R
CAS NO. COMPOUND ' CONCENTRATION UNITS:uum uuwo Cug/L ar ug/Kg) UG/KG Q
I
I ^4~S^~3~~"r^~~~^^c'ilorome'bhane _, ----- I ,J /jt — D > ft ^, - - — —J -«— —**«*i,: -M.___._ t r •( 1 I I t^ tiJ-,J——-.————±*rpmoTffethAne . ' ——————, il M,' ^™^~4——————'^iny ilh 1 oridi~———————————— f ! ni 75-00-3—— -—-rTVfrv r«4-V-:;;_" ~!—————————'- 13 i u i
_ ___________________ i iLf I U II 75-09-S-——~^~-^-Tiethx,i^ne_Chloride_Z_Z_Z__ ] - 6 I U II 67-64-1——"-—————Acetone_____________________ I . 13 I U II 75-15-0——~———-Carbon7Bij5W.lf.ideZ___^Z_Z_Z_Z_f. 6 IU 1I 75-35-4————~-~T,_i-Dic_hlprQe_then5___^__»„_ ' 6 I U II 75-35-3————————-1, l"-Dichloroethane_.____^_.____^.:_-_.,l 6 IU II 540-59-0——^-—— 1, E~Dichloroethene Ctotal) __ I 6 IU J
- — ' • ' - • ' - 6 1 U I
6 IU I13 IU 1
_ ________, 6 I U I-^-CaTbo^'tetrachlOTide . " i 6 IU 1
__ j n':: ; """ " "" 'f
I '/"l •—A i"i_*% " " _"" " - - - - j - - i ' ., _ _ , —™_.__—,,___,__ • .-j i .j- i - 2 = *~™"1'.-i-r2™Trichlprpethc(ne I n
I /!--*3-£————-"——-Benzene.. _ ___;_____~———————f P I
! i3!eiZpS"fi"" f*-:n"S 3-5Ichld °P op 5Zir"l ' 6 lu' o c-o e - ——"-^-^Bromoform . , ...
'«______ i 6 I Unene—_;__:________ I 4 j jX.emetha
I 1591— 7A—ft-___i___ o itOVA /o t. ——————2—Hexanone
J 79~34~ ---- - ~~r? i, a,2~Tetrachlproethane
431330---SO-7—
n
"
U
1/87 Rev
B IB _ EPA SAMPLE NO.SEMIVOLATILE QRGANICS ANALYSIS DATA SHEET ' _______________
95—46—7—————————2—Met hy 1 ph eno 1 _____________.3963S-3£-9—————bis<£-Chloroisopropyl)Ether,106—44-5————————4-Methy 1 pheno 1 ________.__. .r;r.6£ 1-S4-7———————^N-N i troso-D i —n-Propy 1 ami ne_.67—7£-l;——————^—^Hexaohloroethane__________.96—95-3——:——— - N i t robenzene______________.76—5S-1————-^^-—~lsophorone_.________________.68—75—5—————————^N11 rophenol ______________,105-67—9——————"fr, 4-D i met h y 1 pheno 1 _______._.
65-id—————————Benzoic Acid_______________.111-91-1———————ibis(£—Chloroethoxy) Methane__ i1 £0-83-2——-——— £, 4-Dichlorophenol_______.__.11 £0—62-1————=—-^1, £, 4—Trichlorobensene_____._ I91-£0-3—*-*—————Naphthalene________________t106—47-8———————'4—Ch loroani 1 ine__________p__1S7—S6-3——:——:— Hexach 1 orobut ad i ene______\__ I59-50-7————————4-Chloro-3-Methylphenol____._ I91 -57-6*————"•*—£-Met h y 1 napht h a 1 ene______:__ I77—47-4—-=-«————Hexach 1 orocyc 1 opent sd i ene,_ __„_. i88—06-£——:—— ^ £, 4, 6—Trichlorophenol_______I95-95—4————————£, 4, 5—Trichlorophenol_______I91-58—7————————£-Chloronaphthalene_________ I86—74—4—————————£—Nitroani 1 ine_ ,_____________ I131-11 -3—————=—*D i met hyl Ph thai at e__________ I£08—96—8————:—^^^^Aceriaphthylene____________._ i
—. — Pent acn 1 oropheno 1—— Phenanthrene~ — Anthracene—— D i -n— But y 1 pht ha 1 at e _________—— Fl uoranthene—— Pyrene—— Butvlbenzvlohthalate—— 3, 3' -Dichiorobenzidine ______- — Benzo < a Tflnt hracene—— —Chrysene-: — bis<£-Ethylhexyl)Phthalate __—— D i -n-Oc t y 1 Ph t h a 1 at e ________— •— "Benzo (b) Fl uoranthene
£07-06-9 —————— —Benzo < k) Fl uoranthene
193-39-5-----53-70-3 —————
1 ) — Cannot De
!JiLjri£. f \ d / ffyr L/ r i LJ _ _ _..
-^ — ^I ndeno (1 , £, 3-cd ) Pyrene ______—— Dibenz (a, h) Anthracene _______"—:— -^Benzo < p , h , i ) Pery 1 ene ________
———— bis (£— Chloroisopropy 1 ) Ether _————— 4— Methyl phenol— = — N— N i t roso— D i — n-Propy 1 am i ne, __———— Hexachlorbetharie———— N i t roben zene————— .isophorone .—— : —— -4_ NitroDhenol— , —— ,-4— Dimethvlphenoi— -— — Benzoic Acid———— bis(£-Chloroethoxy) Methane _
———— 1, £, 4-Trichlorobenzene———— Naphthalene———— 4— Chloroani 1 ine '.——— -Hexacnlorobut ad iene———— -4— Chloro-3-Methyl phenol——— -— £— Met hy 1 na ph t h a 1 ene ;———— -Hexach 1 orocyc 1 opent ad i ene__. __———— S, 4, 6-Trichlorophenol——— — £, 4, 5— Trichlorophenol———— S— Chl oronaph thai ene————— £— N i t roan i 1 i ne———— D i met hy 1 Ph t h a 1 at e———— Acenaph thy Iene _ :———— £, 6— Dinitrotol uene _ . _____ ; _ _
CONCENTRATION UNITS:CftS NO. COMPOUND Cuo/L or ug/Kg) UG/KG G
1 06-46-7 ———I 100-51-6 ———
&£ 1-64-7 ———£7-7£- 1 ————
/ O W :3 1
ti 6 *~ 7 j — D — — "—
111-91-1 ——
31 C.*tl ^— — — —
1(36-47-6 ——
77—47—4 ———
95-95-4 ———3 1 iJO / • •»—
tio f *r •"+
131-11-3 ——
———— Phenol———— bis <£-Ch loroethyl ) Ether ___ ; _ _———— £^Ch loroohenoi L———— 1. 3— Di Chlorobenzene———— i , 4-D i ch 1 or o bens ene '.————— genzyl Alcohol———— 1, £— Di Chlorobenzene————— 2-Met hy 1 ph eno 1———— bis(£-Chloroisopropyl ) Ether _———— 4-Met h y 1 pheno 1————— N— N i t romo— D i — n— Pr opy 1 am i ne_, _————— :He"x ach 1 oroet h ane———— N i t robenz ene
———— £-N i t rooh eno 1 - -———— £, 4— Dimethyl phenol
—— ——Naphthalene— — — — 4-Chloroani 1 ine—— -— —Hex ach 1 or o but ad i ene———— 4-Ch loro— 3-^Met hy 1 pheno 1———— £— Met hy 1 naph t h a 1 ene—— - —— Hexachlorocyclopentadiene ___———— £, 4, 6— Trichlorophenol———— £, 4, 5— Trichlorophenol———— £— Chloronaphthalene _________———— £-N i t r o an i 1 i ne
f 9S-09-£————-——3~Ni t roani 1 i ne______________ I . 4100 I Ut 63-3£-S-—:——-=^=ftcenap"hth"ene_____.______„.„_i _ £30 I JI 51^36-5————————£,"4-f>init"rophenoV___________ \ ..„ 4100 I U\ 100-0£-7———----T 4-N i t roph eno 1 ________________ t 4100 I Ul 13£-64-9———————Di benzof uran___,________________ I 160 I Ji i £ i -.14-£———————^£, 4-D in i t rot o 1 uene____.___.___ I 860 I UI S4_££_2-———_—H3iethylphthalate_^______"' I .,_ 660 IUI 7005-7£-3--- ——---4-Ch 1 oropheny 1 -pheny 1 ether__ t 860 IUI aS-73-7——:-——•——-Fl uorene____________________I 860 t Uj 100-10-6———————4-N i t roan i"l i ne__i__________ 1 4100 1 Ui 534-52-1—————~-4, 6-Dinitro-£-Methyl phenol__,1 4100 IUl 86-30-6————-——=—N-Nitrosodi pheny lam ine (1)__I. 860 IUi 101 -55—5———•—--r-—-^4V—Bronic-bnenyf—pheny let her___ I 660 I Ut 116-74-1————————MexachlbrobenzeneJ____t_______i 860 i Ui , 67-66-5———---——Pent ach 1 oropheno 1J______-___ I 4100 I U
"~" "" " 3000 i\ 85—01—e-————————Phenanthrene_______t 1S0-12-7———————Anthracene_-________i s4-74-£-———-———D i -n-But y 1 ph tha 1 ate.I £06-44-0———:———FI uorant hene________________t 1 £9-00-0———————Pyrene_____________________i 65-68-7——————•——But y 1 benzy 1 pht ha 1 at e________i 91 -94-1——1—™—3, 3' -Dich lorobenz i d ine______* 56-55-3————-———Benzo (a'i Anthracene__________i 218-01 -9———————Chrysene___________________i 117-61-7—————•-~bis~<£-Ethylhexyl )Phthalate__I 117-64-0———————Di-n-Qctyl Phthalate_________l 205-99-2———•——Benzo (b)Fl uorant hene________I £07-06-9————•—-Benzo <k)Fl uorantheneI 50-32-6————————Benzo (a)i 193-39-5———————IndenoTi, £, 3-cd) Pyrene____.I 53-70-3——————-—Diben"z"<a, h> Anthracene______
——— :— Ben zy 1 A 1 coh o 1———— 1, £-Dichlorobenzene———— £— Met h y 1 pheno 1———— bis <£— Chloroimopropyl ) Ether _———— 4— Met hy 1 pheno 1— -. —— if\j_ jxj j roso— D i — n— Propy 1 am i ne __———— Hexachloroethane——— —Nitrobenzene———— tsoohorone————— £— N i t ropneno 1 _ _______ _____ _————— c_, 4— Dimethylphenol———— Benz o i c Ac i d———— b i s < £— Ch 1 oroet hox y ) Met h ane __— - — :— 2, 4— Dichlorophenol———— 1, 2, 4— Tri Chlorobenzene———— Naphthalene——— :_ 4— chloroani 1 ine—— — -^Hexachlorofautadiene————— 4— Chl oro—j— Methyl phenol———— £-Met hy 1 na ph t h a 1 ene———— Hexach 1 orocyc lopent ad i ene ___
ci, 4, 6 Trichlorophenol———— £, 4, 5— Trichlorophenol———— £— Ch 1 orona ph t ha 1 ene _________———— £— IM it roan i 1 ine———— D i met hy 1 Pht ha 1 at e———— Acenaph thy Iene———— 2, fc»-Diriitrotoluene
————— bis(£-Chloroethyl )Ether 1————— £— Chlorophenol 1————— 1, 3— Di Chlorobenzene 1————— 1, 4— Dicnlorobenzerie 1——— --Benzyl Alcohol 1————— 1, 2— Dichlorobenzene 1—— r —— £-Methy 1 pheno 1 1————— bis<2-Chloroisopropyl) Ether _ J————— 4— Met h y 1 pheno 1 1————— N— N i t r omo— D i — n— Propy 1 am i ne __ 1—————— Hexach loroettnane 1-- ——— -— NitroPenzene 1————— Isoonorone 1——— _. — ci^Nitropnenol 1————— 2, 4-Dimethylphenol 1————— Benzoic Acid 1————— bis <£— Chloroethoxy) Methane _ __ 1— • ———— £, 4— Dichlorophenol 1————— i. £, 4— Trichlorobenzene 1————— Napnthalene 1————— 4-Chloroanil ine 1————— Hex ach 1 orob ut ad i ene 1————— 4— Ch 1 oro-3-Met hy 1 pheno 1 _____ 1————— 2-Methyl naphthalene 1— ———— -Hexach 1 orocycl opent ad a ene _ _ _ 1-; ———— £•- 4^ 6-Trichlorophenol 1—————— £i 4, 5-Trichlorophenol 1————— 2-Ch 1 oronapht ha 1 ene 1————— 2— N i t roan i 1 i ne 1————— Dimethyl Phthalate " " 1————— Acenaph t h y 1 ene )——— — — ;i= ~6— Dinitrotoluene f
S 3 —"3£ -9—--—•——-™?ft c ena "ph't'hene^__________„__51— 28-S————————-^^-4— DI nitrc< phenol_________100-02-7-——---~4-Ni t ropnenp 1 _!_„_ "• -:--132-64-9——;—•-—- Dibenzof u'ran_____^--~____121-14—£-——.————,__, !4-D i n i t rot o 1 uene_______64-66—2-———--——-Diethylphthaiate_________7005-72-5—--———4-Chlorophenyl-phenylether_SS-75-7-^—"—————-F 1 uoren'e______.___100-10-6————--—-A-NTt roan i"l i ne534-52-1-——--"-"-"4, 6-D-initro-£-Methyl phenol__86-50—6—————————N—Nitrosodiphenylamine <1)__101 -55-3———•"—"—4-~0rorn6pheny 1 -pheny 1 et her___
I 116—74— 1 —————:—Hexach 1 orobenzene,l 67-66-5——————-—PentfacnToropheno-.i 85-01 —6————~r~—Phenant hrene___________t 1 £0— 1 £-7——-—-"——Ant hrace;ne_____.______i 64-74-£—--——^----Di-n-Butylphthalate___I £06-44-0———————F1 uorant hene_~________J 1 £9-00-0———————Pyrene_______]________t 85-68-7—:——•———B"utyl benzyl phthal ate__i 91 -94- i ———-———5, 3'~—D i ch 1 orobenz i d i ne.I 56-55-3-——------Benzo <a)Anthracene£18-01-9————-——Chrysene___________________117-61-7———————b is (2-Ethylhexyl) Phthal ate__117-64-0———————D i -n-Oct y 1 Ph t h a 1 at e______£05—99-£————-——BenzoTb) Fl uoranthene________£07-08-9———————Benzo (k) Fluor ant hene_^.______50-5£-8-——•———•—Benzo <a) Pyrene______________193—39—5———•———Indeho < 1 f £, 3—cd) Pyrene_^___53-70-3-———————Dibenz (a, h ) Anthracene,
t 191-24-2——————-Benzo (gIh,i)Perylene^___II__ I 9 ?R3I8Q II _____ •-_______________ ___________________________ I ___________^ -_-! _-____ "" ..<1) — Cannot be "separatee)" from Dipheriyiamine
FORM I 5V-£ " ^'---la7 ftev
IB EPA SAMPLE NO.SEMI VOLATILE ORGANICS ANALYSIS DATA SHEET
I CAW573 Name: VgRSAR INC __________ Contract:. 66-01-7471 I _
Code: VERSAR Came No. : 13565 SAS No. : ____ ' SDG No. : C.AW50
j 95_4£_7 ————OzroiiiQ *ic. s1 06— 44— 5 ———A -_' j T r ^j
621-64-7 ———67-72-1 ————np j— r- --— '-J -mSlmJ O
^- ^-_r J^l ^ 1 J ]_
- ___ .___£.. .___
w _<} r *_P •bJ
105-67—9 ———
111-S1-1 ———
120-82-1 ———9 1 -20-3 ————
l?t ~ A — Q.
59-50-7 ———
86—06-2 ————95-95-4 ————
86-74-4 ———
4,*ld*u (LI w
—— ---Phenol———— bis <£-Ch loroethyl ) Ether——— -H-Chloropnenol—— - — 1 . 3-D i ch 1 orobenz ene———— 1 , 4-Di Chlorobenzene———— Ben zy 1 A 1 coho 1———— 1, £— Di Chlorobenzene———— £-Methyl phenol— - —— bis <£— Chloroisopropyl ) Ether _———— 4— Met hy 1 pheno 1———— N-N i t roso-D i -n-Propy 1 am i ne_ __———— Hexach loroethane———— Nitrobenzene———— Isoohorone———— £— Nitroonenol '.— - —— 2, 4-Dirnethylphenol———— Benzoic Acid—— - — bis (2-Chloroethoxy) Methane __———— £, 4— Dichlorophenol———— 1, £, 4— Trichlorobenzene———— Naphthalene———— 4— Chloroani line_, _________ _____———— Hexach lorobut ad iene———— -4— Chloro-3— Methyl phenol— — • = -* £— Me t hylnaphthal ene ______ __—
J )l_.k ^ JI J J^^>l 'L. j' L- ± U LJ w i 1 v l LU L.T rrUT
———— £, 4, 6— Trichlorophenol _______———— £, 4, 5-Trichlorophenol———— £-Chlorona phthal ene ______ __— - —— £— Nitroani 1 ine———— D i m et h y 1 Ph t h a 1 at e _________——— —fiTcenaph thy Iene _____________ _———— £, 6-Dinitrotoluene
CONCENTRATION UNITS:COS NO. COMPOUND (ug/L or ug/Kq) UG/KG U
I 99—129-2—————————3-N i t roan i I i ne___.I 65-5£-9————>———Acenaphthene_"_"_._.I 51—23-5———-.-=—*.£ 4-i_ Dinitrophenol__,i 100-02-7————————4-N i t ro ph eno 1 _____.I 132-64-9-——— ---D i ben z o f ur an______I l £ 1 -14-£——————£, 4—D i n i t ro t o 1 uene,I 64-66-2——-----Diethylp~hthalate_J7005-7£-3————--4-Chloropheny1-phenylether.86-73-7————————F1 uorene
I 100-10-6——————4-N i t roan i 1 i neI 534-52-1 ——-—--4, 6-D i n i t ro-2-Met h y 1 pheno 1 _.i 86-30-6——•—"——N—Nitrosbdiphen"yl^ami"ne Q ) _.I 101-55-5— ^^^—*•%—Brornophenyl-Qheny let her___I ilb-74—l—————r—Hex"acm'brobenzene'67—66-5———-———'-—P^nt~ach'16rophenoi^__85—0 1 -6-———rr—r-T-Phenanthrene__:_;__:_120-1 £-7———————Anthracene________S4—74-2———- r—:—D i —n—But y 1 ph t h a 1 at e.£06-44-0————————Fl uoranthene
t 1 £9-00-065-68-7—————•—-Butyl benzyl phthal ateSi—54-1——————————37-3' —Dich lorobenzidine____m56—55—3—————-——Benso (a) Anthracene_______.218-01-9———————Chrysene_________________117-61 -7———————b i s (£-Et hy 1 hexy 1) Pht halat e.117-64-0———————Di-n-Octyl Phthalate
1 £05—99-£—•——:———Benzo (b) Fl uoranthene.I 207-06-9———————Benzo <k)Fl uorant hene_.I 50-3£-8—:——————Benzo (a) Pyrene_______.I 193—39-5—————Indeno(l,2, 3—cd) Pyrene.I 53-70-3————————Dibenz <a, h) Anthracene_.I 191-24-2———-——Benzo < g, h, i ) Per y Iene_.
5400 i U1100 IU5400 )U5400 IU1100 IU1100 IU1100 I U1100 )U1100 IU5400 IU5400 t U1100 IU1100 IU
•A Moisture: not dec. SE dec. ___ Bate Extracted: l£/£9/89
Extraction:" (SepF/Cont/Sonc) SQNC Date Analysed: 0l/£4/30
GPC Cleanup: (Y/N> Y__ pH: 6. 9 pi lut ion _Factor: 1. 053
CONCEN TRATI ON.UNIT5:CAS NO. COMPOUND (uo/L or ua/Ko) OG/KG Q
c
1111.1
11I
111I111t1t1\It1,
1f1f1JIJ11
111-44-4 ——95-57-8 ———E? J • ^~- 1lJ-4- 1 /W 1
106-46-7 ——100-51-6 ——j*j tajw j.9s! 4A 7
106-44-5 —6£ 1-64-7 —O / / 1± 1
98-95-3 ——7S-53-1 ——S6-75-5 ——
65-85-0 ——111-91-1 —
91-20-3 ———10S-47-6 —87-68-3 ———1= t T— - — -•53—50—7 ———
77-47-4 ——86-06-2——95-95-4 ——O 1 ^O "7
88-74-4 ——131-1 1—3 —
606-20-2—
i———— —Pheno 1 (————— bis(£-Chloroethyl ) Ether _____ 1————— £— Ch 1 oropheno 1 !————— 1, 3— Dichlorobenzene 1————— 1, 4— Dichlorobenzene I————— Ben zy 1 A 1 coho 1 ______________ 1—————— 1, £— Dichl orocenz ene l——— . — £— Me t h y 1 ph eno 1 ______________ 1————— bis <£— Chloroisopropy 1 ) Et her _ i———— ;==2p viet h y 1 ph eno 1 ___________ , __ __ 1————— N— N 1 1 roso— D i — n— Propy I am i ne __ 1—————— Hexach loroethane _______ .._____ '————— N i t robenzene I————— I soph or one i————— .-2-NitroDhenol 1——— ^ 2_- 4-D i rnet n y 1 pheno 1 I——— : — Benzole Acid I————— bis<£~Chloroethoxy) Metnane_ _ 1—————— £, 4— Dichlorophenol ' 1
- l.i-, 4 Trichlorobenzene 1—————— Naphthalene 1—————— 4-Chloroani 1 ine !————— Hexach 1 orobut ad i ene 1————— 4-Ch 1 oro-3-Met hy 1 ph eno 1 _ ; ___ 1——— — £— Methyl naphtha Iene _________ 1
Mexachlorocyclopentaaiene ___ i— . ——— 2 4, 6-Trichlorophenol ___ _ _ _ 1————— £, 4, 5— Trichlorophenol 1—————— 2— Chloronaphthalene __________ 1————— 2— N i t r oan Hi ne J————— Dimethyl Phthalate ' i——— — ftcenaphthy Iene i— 2,6 Dinitrotoluene ___________ 1
l. _3 N it roan i i ine I_ - = - _ . • • - ; , . - - - - - • '
J-tcenapntriSKiS 1—— £, 4— Dinitrophenol 1—— 4-Nitrophenol _______________ 1—— Dibensofuran 1——2^ 4-D i n i t rot o 1 uene __________ i— —DiethVlphthaiate 1——— 4— ChlorOpiheny 1— pheny letner__ _ 1— Fluorene " i— — 4— Nit roar, i i me - - i— —4, Q-Dinitro-^-Methylpnenoi^ _ i—— N-Nitrosod i pheny 1 am me < 1 ) _ __ l .,- — 4-Bromophenyl -pheny let her ___ i— — — riexach lorooenzene ___________ i— ——Pent ach lorophenoi 1— '— T-Phenanthrene '. 1— - •Ar.thracene " ' 1— -D i -n-eU t y 1 ph t h a 1 a t e 1—— -F 1 uorant hene 1—— Pyrene 1—— Butyl benzyl phthal ate 1—— 3, 3' -Dichlorobensidine ______ i—— Benzo (a) Anthracene 1
———— N— N 1 1 roso— D i — n— Pr opy 1 am i ne _ _ i———— H^xachloroethane I—— •— -N i t robenzene i—— -— Isophorone t—— ^ — 2— Nitropnenol -- - i———— c , 4-D i met h y i ph eno 1 ______ ! __ _ i———— Benzoic Acid 1••*»"»» ™ *fr T 1 **•*—— 1^^ 1 i"hlV i£5 rt fc*™! —f \.f \ rrt al" fr"l 3 Xi CA \u A. ? \ LI t^i i ± "— ' r v c? v l J i—1 f\ y / l* )CT v i > d ' > " J
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg> UG/KG Q
•**«r * ^ -/
100-02-7 ————1 32-64-9 —— -121-14-2 ——— "
1 7005-72-3 ——DC. "7 ~ffOD / O /
100-10-6 —————534-52-1 ————Oo J1O u
87-66-5 —————
1 120-1 £-7 ————
£06-44-0 ————129-00-0 ———
56-55-3 — ———218-01-9 ————117-81-7 ————
WW / *+ W
!9l-£4-£ ———
( 1 ) - Cannot b
1- —— 3-N i t roan i 1 i ne i
Ml»LJrJ<_i^Ji)vJJl-rriLJ 1
— -— — S, 4— D i n i t ropheno 1 ___________ I——— 4-N i t ropheno 1 i— —— Dibenzofuran 1~ —— -2y ~D i n i t ro t o 1 uene - 1- —— Diethvlphthalate' " 1— : — - 4-Ch 1 orb phenyl— pheny let her __ i—'• —— FTuorene • j
•*v S-'Qi'^iir.'li1 _ . _^ _ __ _ _ _ _ _ t
——— 4, 6— Dinitro— £— Me't'hy 1 phenol __ 1——— N-Ni trosodi pheny 1 am ine ( 1 ) __ _ i—— — 4-Brorridphenyl — pheny let her ___ i———— Hexach lorobenzene l—— -Pent ach lorophenoi 1
O « Data had no problems/or qualified dueQ * Data qualified due to major problems.U » Data unacceptable.X * Problems, but do not affect data.
ACTION ITEMS:
VOA BNA PEST - OTHER "
0 q 0 KAo o oX K riA ,0 P .___0
0 0 0
X X X
o o oO 'O ' Q
o o OG O O
o o oto minor problems.
-
AREAS OF CONCERN:' 5(\veft?J icr uer*. hard fa rtzd <) d *nrtn more.cli-ff>i':J/r
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NOTABLE PERFORMANCE: ft DOAf. * C 1
APPENDIX FSUPPORT DOCUMENTATION
62
Calibration Outliers for Volatile Analysis
Compound Sample %Diff DateMatrix
2-Butanone Soil -32.5 12/22/89Total Xylenes Soil -28.3 12/22/89Bromoform Soil -27.2 12/22/89Acetone Soil 27.2 12/28/89Total Xylenes Soil -27.3 12/28/89Bromomethane Water -36.8 12/28/89Carbon Disulfide Water -33.8 12/28/891,1-Dichloroethane Water -37 12/28/891,2-Dichloroethene Water -28.8 12/28/89Chloroform Water -41.8 12/28/891,2-Dichloroethane Water -58.3 12/28/892-Butanone Water -32 12/28/891,1,1-Trichloroethane Water -38.9 12/28/89Bromodichloromethane Water -34.8 12/28/89cis-l,3-Dichloropropene Water 31.4 12/28/891,1,2-Trichloroethane . Water -33 12/28/89trans-l,3-Dichloropropene Water -42.6 12/28/89.4-Methyl-2-Pentanone Water -41.4 12/28/892-Hexanone Water -51.5 12/28/891,1,2,2-Tetrachloroethane Water -40.1 12/28/89Toluene Water -25.3 12/28/89
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; I
Lab Name: VERSAR IMC Contracts 63-01-7471 I
i-ab Code: VERSAR Case No.s 13383 SAS Mo-: DDG No. s CAW50
.**fixs <iiOil/waUer> SOIL Lal* G^mpls 12= V£LK£
Sample wt/vols D.O <g/mL> G Lab File'lDs R3709_._._*-,• •