SAFETY DATA SHEET Calcium chloride pellets/powder 95-98% FUDIX TM page 1 of 34 Date issued: 10.08.2006 Date revised: 02.04.2014 Revision №: 2 SECTION 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING 1.1. Product identifier Calcium chloride pellets / powder 95-98% food grade Trademark: Fudix TM CHEMICAL NAME: calcium chloride, CaCl2 CAS №: 10043-52-4 EC №: 233-140-8 REACH registration number: 01-2119494219-28-0013 Index № CLP Annex VI Regulation (EC) No 1272/2008: 017-013-00-2 1.2. Relevant identified uses of the substance or mixture and uses advised against Food industry uses: pH regulation in brewing industry. Fruits and vegetables processing and preservation. Meat tenderization and freezing point decreasing. Ice cream production. Jelly and jam production. Cheese and curd production for speeding the process of coagulation. 1.3. Details of the supplier of the safety data sheet MANUFACTURER: Zirax LLC ADDRESS: Microrayon 4, 6 Svetly Yar settlement, 404171 Volgograd region, RUSSIA Telephone: +7 8442 494999 Fax: +7 8442 499444 e-mail: [email protected]1.4. Emergency telephone number +7 8442 49-49-99 SECTION 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 of the European Parliament: Hazard statement code: H319: Causes serious eye irritation Hazard Class and category code: Eye Irritation 2 According to Directive 67/548/EEC: Xi; R36 Irritating to eyes 2.2. Label elements According to Regulation (EC) No 1272/2008 EEC HAZARD PICTOGRAM GHS07: exclamation mark SIGNAL WORD: Warning HAZARD STATEMENT: H319: Causes serious eye irritation PRECAUTIONARY STATEMENTS: P 264: Wash hands thoroughly after handling. P 280: Wear protective glasses with splash shields or safety goggles/shield.
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Index № CLP Annex VI Regulation (EC) No 1272/2008: 017-013-00-2
1.2. Relevant identified uses of the substance or mixture and uses advised against
Food industry uses: pH regulation in brewing industry. Fruits and vegetables processing and preservation. Meat tenderization and freezing point decreasing. Ice cream production. Jelly and jam production. Cheese and curd
production for speeding the process of coagulation.
1.3. Details of the supplier of the safety data sheet
EYES: Remove contact lenses, if present and easy to do. Rinse cautiously with water for 15 minutes. Seek medical attention.
SKIN: Remove contaminated clothes; wash off any skin contaminations with soap and water. Launder contaminated clothes before re-use.
INGESTION: Get prompt qualified medical attention. If conscious, give 1-2 glasses of water with absorbent carbon.
INHALATION: Remove to fresh air. Keep in warm and at rest. Give oxygen or artificial aspiration if needed. If symptoms persist seek medical attention.
FIRST AID MEASURES: absorbent carbon, saline purge.
4.2. Most important symptoms and effects, both acute and delayed
EYES: Could cause irritant or burn effects to the eyes. SKIN: Could cause irritant effects to the skin. No delayed symptoms after washing contaminated skin.
INGESTION: May cause nausea. May cause GI tract irritation. INHALATION: Dust may cause irritation to mucous membranes and respiratory system.
4.3. Indication of any immediate medical attention and special treatment needed
No special antidotes. If case of ingestion wash mouth with water and give plenty water to drink. Get medical
attention if needed.
SECTION 5. FIRE FIGHTING MEASURES
5.1. Extinguishing media This product is a nonflammable substance. However, hazardous decomposition and combustion products may be
formed in a fire situation. Cool exposed containers with water spray to prevent overheating. Extinguish fire using
agent suitable for type of surrounding fire and/or chemicals. Do not use water directly on material. Heat is generated when product mixed with water.
5.2. Special hazards arising from the substance or mixture
No special hazards.
5.3. Advice for firefighters
Respiratory and eye protection are required for fire fighting personnel. Avoid breathing corrosive vapors.
6.1. Personal precautions, protective equipment and emergency procedures
Wearing the appropriate personnel protective equipment designated in Section 8, move the container to a containment area or rotate the container so that the opening is above the liquid level.
6.2. Environmental precautions
WATER SPILL: Use appropriate containment to avoid runoff or release to sewer or waterways.
LAND SPILL: Use appropriate containment to avoid runoff or release to ground.
6.3. Methods and material for containment and cleaning up Construct temporary dikes of dirt, sand, or any appropriate readily available material to prevent spreading of the
material. Wearing the appropriate personal protective equipment designated in Section 8, close or cap valves and/or block or plug hole in leaking container and transfer to another container. Remove containers with disposal
from release area.
6.4. Reference to other sections
For addition information see section 13.
SECTION 7. HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid skin and eye contact and breathing dusts. Use proper protective and respiratory equipment. Not to eat, drink and smoke in work areas. Wash hands thoroughly after handling. Launder contaminated clothing before re-use.
Ventilate area. Sweep or vacuum; do not create dust; place in a dry container for disposal. Clean spill area with water.
7.2. Conditions for safe storage, including any incompatibilities
Store in a cool, dry, well-ventilated place. Keep container closed when not in use. Keep away from incompatible
materials. Protect from atmospheric moisture.
7.3. Specific end use(s) No specific end uses.
SECTION 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
8.1. Control parameters National occupational exposure limit values: maximum allowable concentration in the air of the working zone – 2 mg/m, aerosol, 3 class of hazard 8.2. Exposure controls ENGINEERING CONTROLS: Where environmental controls are lacking or in enclosed spaces use a NIOSH/MSHA approved respirator for dust/fumes. Provide local exhaust ventilation system. Eye wash station and safety shower should be provided within the immediate work area for emergency use. EXPOSURE LIMITS: No occupational exposure limits established by OSHA/ACGIH/NIOSH. PERSONAL PROTECTIVE EQUIPMENT: EYES: Wear safety glasses with splash shields or safety goggles/shield. BODY: Wear appropriate protective (impervious) clothing. Leather work boots and/or leather products will dehydrate with resultant shrinkage and possible destruction. RESPIRATORY: A respirator is not indicated under normal operating conditions. Use of a NIOSH approved respirator should be based upon the presence of nuisance dust. When warranted, use a face mask particulate respirator with particulate respirator with a NIOSH N95 rating. HANDS AND FEET: Wear appropriate rubber gloves and non-leather protective boots. WORK HYGIENIC PRACTICES: Use reasonable care in handling this product. Wash hands after use and before eating.
HEALTH EFFECTS: Moderately toxic by ingestion, slightly toxic by dermal absorption.
CARCINOGENICITY: Not Listed by NTP. Not listed by IARC. Not listed by OSHA.
MUTAGENICITY: Not Available
REPRODUCTIVE TOXICITY REPRODUCTIVE EFFECTS: testing does not appear necessary as calcium chloride will not reach the foetus or the
male and female reproductive organs when exposed orally, dermally orby inhalation, as it does not become
available systemically. TERATOGENIC EFFECTS: Not Available
SENSITIZATION: Not Available
SECTION 12. ECOLOGICAL INFORMATION
12.1. Toxicity
Calcium chloride is not classified as hazardous for the environment. Calcium and chloride are normally occurring ions that don’t have long term negative effect.
Overview of short-term effects on fish
Method Results Remarks Reference
Pimephales promelas freshwater
static
Method: other: EPA/600/4-90/027, EPA/600/6-91/003
LC50 (96 h): 4630 mg/L LC50 (48 h): > 6560 mg/L
LC50 (24 h): > 6660 mg/L
2 (reliable with restrictions) key study
experimental result
Test material (EC name): calcium chloride
Mount, D.R., Gulley, D.D., Hockett, J.R.,
Garrison, T.D. and
Evans, J.M. (1997a)
Lepomis macrochirus freshwater static
Method: other: Doudroff et al., (1951)
(96 h): 9500 — 11300 mg/L 2 (reliable with restrictions)
supporting study experimental result
Test material (EC name): calcium chloride
Cairns, J., Jr. and
Scheier, A. (1959)
Lepomis macrochirus freshwater
static Method: other
LC50 (96 h): 10650 mg/L 2 (reliable with restrictions)
supporting study
Test material (EC name): calcium chloride
Trama, F.B. (1954)
Gambusia affinis freshwater static
Method: other: not mentioned
LC50 (96 h): 13400 mg/L 2 (reliable with restrictions)
supporting study experimental result
Test material (EC name): calcium chloride
Wallen, I.E., Greer,
W.C. and Lasater, R. (1957)
Overview of short-term effects on aquatic invertebrates
Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) (algae)
OECD Guideline 201 (Alga, Growth Inhibition Test)
EC50 (72 h): 2900 mg/L based on: biomass
EC50 (72 h): > 4000 mg/L
based on: growth rate EC50 (72 h): 27000 mg/L
based on: growth rate EC20 (72 h): 1000 mg/L
based on: biomass
1 (reliable without restriction)
key study
experimental result Test material (EC name):
calcium chloride
de Groot, W.A. (1998)
12.2. Persistence and degradability Test not available as product is inorganic.
12.3. Bioaccumulative potential Product is not biodegrade or accumulate.
12.4. Mobility in soil
In accordance with REACH Annex XI, the study does not need to be conducted as in water; calcium chloride is
dissociated into calcium and chloride ions and chloride ions will not adsorb on particulate matter. The calcium ion may bind to particulate matter or may form stable inorganic salts with sulphate and carbonate ions, but calcium is
naturally present in soil. Therefore, exposure of the soil compartment is unlikely.
12.5. Results of PBT and vPvB assessment According to Annex XIII of the REACH Regulation 1907/2006/EC inorganic substances do not need to be subjected
to a PBT assessment.
12.6. Other adverse effects
None identified.
SECTION 13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Observe federal, state, and local regulations when disposing of this substance. DISPOSAL METHOD: Dispose of waste at an appropriate waste disposal facility according to current applicable
laws and regulations. FOR LARGE SPILLS: Contain material according to section 6.
PRODUCT DISPOSAL: Dispose of at a supervised incineration facility or an appropriate waste disposal facility
according to current applicable laws and regulations and product characteristics at time of disposal. EMPTY CONTAINER: Rinse drums with a suitable solvent and steam to remove vapors before disposal or reuse in
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
SECTION 15. REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture General principles of protection EH 44
15.2. Chemical safety assessment
A chemical safety assessment has been performed for calcium chloride according to REACH.
SECTION 16. OTHER INFORMATION
To the best of our knowledge, this Safety Data Sheet conforms to the requirements of:
- Regulation (EC) №1907/2006 of the European Parliament and of the Council of 18 December 2006 - Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008
- Commission Regulation (RU) №453/2010 of 20.05.2010
List of relevant R phrases, hazard statement, safety phrases and precautionary statement:
According to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008: HAZARD STATEMENT: H319: Causes serious eye irritation PRECAUTIONARY STATEMENTS:
P 264: Wash hands thoroughly after handling.
P 280: Wear protective glasses with splash shields or safety goggles/shield. P305 + P351 + P338: IF IN EYES Rinse eyes cautiously with water for 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. P337 + P 313 If irritation continued get prompt qualified medical advice / attention.
According to Directive 67/548/EEC: Xi Irritant
R36 Irritating to eyes
S-phrases:
(S2) - keep out of the reach of children S22 - do not breathe dust
S24 - avoid contact with skin
Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. It is the users' responsibility to satisfy themselves as to the suitability and completeness
of such information for their own particular use. We do not accept liability for any loss or damage that may occur
from the use of this information nor do we offer warranty against patent infringement. ZIRAX LLC reserves the right to refuse shipment of this product to any customer who fails to demonstrate the
ability to consistently handle and use it safely and in compliance with all applicable laws, rules and regulations. Such demonstration may require on-site inspection of any or all storage, processing, packaging and other handling
The overview of exposure scenarios of Calcium Chloride
Short description of
Identified Use
Product Category
(PC)
Life Cycle Stage(s) covered by the
IU
Sector of use
(SU)
Process Category
(Proc)
Article Category
(AC)
Environmental
Release
Category (ERC)
Ma
nu
factu
re
Fo
rmu
lati
on
End Use
Se
rvic
e
Lif
e
(fo
r
art
icle
)
Ind
ustr
ial
Pro
fessio
na
l
Co
nsu
me
r
ES1: Production of
calcium chloride
Not applicable X SU8 (SU3) PROC1, PROC2, PROC3,
PROC4, PROC6, PROC8a,
PROC8b, PROC9, PROC15, PROC26
Not
applicable
ERC1
ES2: Use of calcium
chloride as chemical intermediate
Not applicable X SU8, SU9, SU14
(SU1, SU3, SU4, SU5, SU6b)
PROC1, PROC2, PROC3,
PROC4, PROC6, PROC8a, PROC8b, PROC9,
PROC15, PROC22a, PROC22b, PROC22c,
PROC23a, PROC23b, PROC23c, PROC261,
PROC27a2, PROC27b3
Not
applicable
ERC6a
1 No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 26 (handling of solid inorganic substances at abient temperature) are covered within this scenario. 2 No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC27a (Production of metal powders (hot processes)) are covered within this scenario by PROC22 and PROC23. 3 No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 27b (Production of metal powders (wet processes)) are covered within this scenario.
Title Production of calcium chloride; CAS: 10043-52-4
Use Descriptor Sector of Use: Industrial SU8, (SU3)
Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6,
PROC8a, PROC8b, PROC9, PROC15,PROC26
Environmental Release Categories: ERC1
Processes, tasks,
activities covered
Manufacturing of Calcium Chloride, includes recycling/ recovery,
material transfers, storage, maintenance and loading (including marine vessel/barge, road/rail car and bulk container), sampling and
associated laboratory activities.
Section 2 Operational conditions and risk management measures
Field for additional statements to explain scenario if required.
Section 2.1 Control of worker exposure
Product characteristics
Physical form of
product
Solid, medium dustiness [OC2]
Concentration of
substance in product
Covers percentage substance in the product up to 100 % (unless
stated differently) [G13].
Amounts used Not applicable
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently) [G2]
Human factors not
influenced by risk management
Not applicable
Other Operational Conditions affecting
worker exposure
Assumes use at not more than 20°C above ambient temperature, unless stated differently [G15].;
Assumes a good basic standard of occupational hygiene is
implemented [G1].
Contributing Scenarios
Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection.
Justification
General measures
(irritants) [G19].
Avoid all skin contact with product, clean up contamination/spills as
soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately.
Provide basic employee training to prevent / minimise exposures and
to report any skin problems that may develop [E3].Use suitable eye protection [PPE26].
General exposures
[CS1]. With sample collection [CS56].
Provide a good standard of general ventilation. Natural ventilation is
from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1].
measured
data, see 9.1.2 (PROC1)
General exposures [CS1]. Continuous
process [CS54]. ;
Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied
Processes, tasks, activities covered Use of Calcium Chloride as chemical intermediate. Use as an intermediate. Includes recycling/ recovery, material transfers,
storage, maintenance and loading (including marine vessel/barge,
road/rail car and bulk container), sampling and associated laboratory activities.
Section 2 Operational conditions and risk management measures
Field for additional statements to explain scenario if required.
Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Solid, medium dustiness [OC2]
Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated differently) [G13].
Amounts used Not applicable
Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently)
[G2]
Human factors not influenced by risk
management
Not applicable
Other Operational Conditions affecting
worker exposure Assumes use at not more than 20°C above ambient temperature,
unless stated differently [G15].; Assumes a good basic standard of occupational hygiene is
implemented [G1].
Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures , 4. Personal protection.
General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as
soon as they occur. Wear gloves (tested to EN374) if hand
contamination likely, wash off any skin contamination immediately. Provide basic employee training to prevent / minimise exposures
and to report any skin problems that may develop [E3].Use suitable eye protection [PPE26].
General exposures [CS1]. With sample collection [CS56].
No specific measures identified [EI18].
General exposures [CS1].
Continuous process [CS54]. With sample collection [CS56].
Processes, tasks, activities covered Formulation and distribution , packing and re-packing (including drums and small packs) of the Calcium Chloride and its mixtures in batch or
continuous operations, including storage, materials transfers, mixing, large and small scale packing, loading (including marine vessel/barge,
rail/road car and IBC loading), maintenance and associated laboratory
activities. e.g. production of adsorbents, cosmetics, metals, fertilizers, plant protection, cement, haemodialysis solution and general
distributor activities with Calcium Chloride
Section 2 Operational conditions and risk management measures
Field for additional statements to explain scenario if required.
Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Solid, medium dustiness [OC2]
Concentration of substance in product Covers percentage substance in the product up to 100 % (unless
stated differently) [G13].
Amounts used Not applicable
Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently) [G2]
Human factors not influenced by risk
management
Not applicable
Other Operational Conditions affecting
worker exposure Assumes use at not more than 20°C above ambient temperature,
unless stated differently [G15]. Assumes a good basic standard of occupational hygiene is
implemented [G1].
Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures , 4. Personal protection.
General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as
soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately.
Processes, tasks, activities covered Use of Calcium Chloride as processing aid. Use as a process chemical or extraction agent. Includes recycling/ recovery, material transfers,
storage, maintenance and loading (including marine vessel/barge, road/rail car and bulk container), sampling and associated laboratory
activities. E.g. functions as adsorbent, coagulant, emulsion breaker,
alginates, extraction agent, completion fluid, heat transfer fluid, water treatment chemical or use within the paper industry for example as
antistatic
Section 2 Operational conditions and risk management measures
Field for additional statements to explain scenario if required.
Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Solid, medium dustiness [OC2].
Concentration of substance in product Covers percentage substance in the product up to 100 % (unless
stated differently) [G13].
Amounts used Not applicable
Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently) [G2]
Human factors not influenced by risk
management
Not applicable
Other Operational Conditions affecting
worker exposure Assumes use at not more than 20°C above ambient temperature,
unless stated differently [G15].; Assumes a good basic standard of occupational hygiene is
implemented [G1].
Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection.
General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as
soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately.
Provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop [E3]. Use suitable eye
protection [PPE26].
General exposures [CS1]. Continuous process [CS54].
worker exposure Assumes use at not more than 20°C above ambient temperature,
unless stated differently [G15]. Assumes a good basic standard of occupational hygiene is
implemented [G1].
Outdoor [OC9].
Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection.
General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as
soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately.
Provide basic employee training to prevent / minimise exposures and
to report any skin problems that may develop [E3]. Use suitable eye protection [PPE26].
Mixing operations (open systems)
[CS30].
No specific measures identified [EI18].
Bulk open loading and unloading [CS503].
Non-dedicated facility [CS82]
No specific measures identified [EI18].
Bulk closed loading and unloading [CS501].
Dedicated facility [CS81]
No specific measures identified [EI18].
Drum/batch transfers [CS8]. Transport [CS58].
No specific measures identified [EI18].
Spraying [CS10]. Minimise exposure by partial enclosure of the operation or equipment
and provide extract ventilation at openings [E60]. or: Wear a respirator conforming to EN140 with Type A/P2 filter or better
[PPE29]
Spraying [CS10].
Avoid carrying out operation for more than 1 hour [OC11], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better
[PPE29]
Spreading Large surfaces [CS46].
No specific measures identified [EI18].
Mixing operations (open systems)
[CS30]. Manual [CS34].
No specific measures identified [EI18].
Spreading Manual [CS34]. No specific measures identified [EI18].
Equipment cleaning and maintenance
[CS39].
Non-dedicated facility [CS82]
No specific measures identified [EI18].
Storage [CS67].
General exposures (closed systems)
[CS15].
No specific measures identified [EI18].
Storage [CS67].
General exposures (closed systems) [CS15].
With sample collection [CS56].
No specific measures identified [EI18].
Section 2.2 Control of environmental exposure
Product characteristics Substance is a unique structure [PrC1].
Physical form of product Solid, medium dustiness [OC2].
Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated
differently) [G13].
Amounts used Not applicable
Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently) [G2]
Human factors not influenced by risk
management
Not applicable
Other Operational Conditions affecting worker exposure
Assumes use at not more than 20°C above ambient temperature, unless stated differently [G15].;
Assumes a good basic standard of occupational hygiene is implemented
[G1].
Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection.
General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as soon as they occur. Wear gloves (tested to EN374) if hand contamination
likely, wash off any skin contamination immediately. Provide basic
employee training to prevent / minimise exposures and to report any skin problems that may develop [E3].
Use suitable eye protection [PPE26].
General exposures (open systems) [CS16].
Batch process [CS55]. With sample collection [CS56].
Filling / preparation of equipment from drums or containers [CS45].
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11], or:
Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]
Application of cleaning products in
closed systems [CS101] With sample collection [CS56].
Filling / preparation of equipment from
drums or containers. [CS45].
Provide a good standard of general ventilation (not less than 3 to 5 air
changes per hour) [E11]. or: Wear a respirator conforming to EN140 with Type A/P2 filter or better
[PPE29]
Mixing operations (open systems)
[CS30].
Provide a good standard of general ventilation (not less than 3 to 5 air
changes per hour) [E11], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better
[PPE29]
Bulk open loading and unloading [CS503].
Non-dedicated facility [CS82].
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11], or:
Wear a respirator conforming to EN140 with Type A/P2 filter or better
[PPE29]
Bulk closed loading and unloading
[CS501]. Dedicated facility [CS81].
Provide a good standard of general ventilation (not less than 3 to 5 air
changes per hour) [E11], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better
[PPE29].
Pouring from small containers [CS9]. Transport [CS58].
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11], or:
Wear a respirator conforming to EN140 with Type A/P2 filter or better
Field for additional statements to explain scenario if required.
Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Solid, medium dustiness [OC2].
Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated differently) [G13].
Amounts used Not applicable
Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently) [G2]
Human factors not influenced by risk
management
Not applicable
Other Operational Conditions affecting worker exposure
Assumes use at not more than 20°C above ambient temperature, unless stated differently [G15].
Assumes a good basic standard of occupational hygiene is implemented
[G1]. Outdoor [OC9].
Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measure, 4. Personal protection.
General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as soon
as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately. Provide basic
employee training to prevent / minimise exposures and to report any skin problems that may develop [E3].
Use suitable eye protection [PPE26].
Mixing operations (open systems)
[CS30].
No specific measures identified [EI18].
Bulk open loading and unloading
[CS503].
Non-dedicated facility [CS82].
No specific measures identified [EI18].
Filling / preparation of equipment from
drums or containers. [CS45]. Non-dedicated facility [CS82].
No specific measures identified [EI18].
Bulk closed loading and unloading
[CS501]. Dedicated facility [CS81].
No specific measures identified [EI18].
Drum/batch transfers [CS8].
Transport [CS58].
No specific measures identified [EI18].
Pouring from small containers [CS9]. No specific measures identified [EI18].
Rolling, Brushing [CS51]. No specific measures identified [EI18].
Spraying [CS10]. Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]. or:
Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]
Spraying [CS10]. Avoid carrying out operation for more than 1 hour [OC11], or:
Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]
Dipping, immersion and pouring No specific measures identified [EI18].
Processes, tasks, activities covered Handling of Calcium Chloride pellets, flakes or other Calcium Chloride with low dustiness or preparations of these.
Section 2 Operational conditions and risk management measures
Field for additional statements to explain scenario if required.
Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Solid, low dustiness [OC1].
Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated
differently) [G13].
Amounts used Not applicable
Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently) [G2]
Human factors not influenced by risk management
Not applicable
Other Operational Conditions affecting
worker exposure Assumes use at not more than 20°C above ambient temperature,
unless stated differently [G15]. Assumes a good basic standard of occupational hygiene is implemented
[G1].
Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection.
General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as soon as they occur. Wear gloves (tested to EN374) if hand
contamination likely, wash off any skin contamination immediately. Provide basic employee training to prevent / minimise exposure.
Use suitable eye protection [PPE26].
General measures applicable to all activities [CS135].