•Bonds between atoms are created when electrons are paired up by being transferred or shared . •Atoms tend to form bonds that will allow it to obtain a full valence shell . Chemical Bonds
Jan 19, 2016
•Bonds between atoms are created when electrons are paired up by being transferred or shared.•Atoms tend to form bonds that will allow it to obtain a full valence shell.
Chemical Bonds
Two Types of Chemical Bonds:
Ionic Bonds Covalent Bonds
-Electrons are transferred from one atom to another
-Electrons are shared between atoms.
- Usually occurs between a metal and nonmetal
- Usually occurs between two nonmetals
CompoundsCompounds are formed when two or more kinds of atoms are bound together chemically. Compound can be either ionic or covalent.
Examples:
Why do these bonds occur?Remember: In a neutral atom the number of protons
and neutrons are equal but the atom might be unhappy because it does not have a complete outer shell of electrons(8 electrons). All atoms want to be happy like the Nobel gases!!!!!
How can atoms be happy?-By creating either an ionic or covalent bond.-If they create an ionic bond they either gain or
lose an electron.-Positive ion form by losing an electron-Negative ion form by gaining an
electron
Groups turning Ionic...
Positive Ions (cation)Group 1 Loses 1 electron Ion with a +1
Charge
Group 2 Loses 2 electrons
Ion with a +2 Charge
Group 13 Loses 3 electrons
Ion with a +3 Charge
Negative Ions (anion)Group 15 Gains 3
electronsIon with a -3 charge
Group 16 Gains 2 electrons
Ion with a -2 charge
Group 17 Gains 1 electron Ions with a -1 charge
Prefix number indicated
mono- 1di- 2tri- 3
tetra- 4penta- 5hexa- 6hepta- 7octa- 8nona- 9
deca- 10
Naming Binary Covalent Compounds
Formula Names
N2F6 Dinitrogen Hexafluoride
CO2
SiF4
CBr4
NCl3
P2S3
CO
NO2
SF2
PF5
SO2
NO
CCl4
P2O5
Examples:
Naming Binary Ionic CompoundsRules1. The Cation (positive ion) is named first, the Anion second.2. Monoatomic Cations take the element name Na+ --> Sodium Ca2+ --> Calcium3. Monoatomic Anions take the elements name and ends with "-ide" Cl- --> Chloride NaCl --> Sodium Chloride Li3N --> Lithium Nitride
Note** Greek prefixes are not used to indicate the number of atoms of each element in the formula unit for the compound (e.g., Na2O is named "sodium oxide" not "disodium oxide", or
"disodium monoxide").
Formula Name Formula Name
a. Li2O Lithium Oxide n. K2O
b. CsCl o. RbI
c. MgS p. Mg3N2
d. CaBr2 q. Ca3P2
e. BaI2 r. Al2S3
f. KH s. Ag2O
g. Na2S t. NaH
h. AlN u. CaO
i. AgF v. Na2S
j. ZnO w. LiI
k. CdI2 x. CdS
l. BaS y. ZnCl2
m. LiCl z. CsI
Examples:
Naming Ionic Compounds using Roman Numerals
(The Stock System of Naming)
How do we name compounds when the cation of variable charge is involved?
•Some elements have more then one oxidation number and when naming a compound these must be identified. •Roman numerals are shown after the cation in parenthesis( ) to indicate the oxidation number.•To determine what the oxidation number is, you must use the anion (negative ion) to determine what the positive oxidation number is.
Example- Pb(NO3)4 write the name "lead nitrate".
Since lead has more than one oxidation state we must figure out which lead we have. Since each nitrate (4 of them) has a 1- charge, the Pb must be 4+. So our roman numeral will be (IV).
Pb(NO3)4 is named "lead(IV) nitrate"
Formula Name Formula Name
FeCl2 iron (II) chloride SnCl4
CoBr3 FeP
MnO2 Hg2S
NiBr2 PbO
HgO AuI
CuF2 SnS2
CuI FeBr3
SnBr2 Cr2O3
Au3P CoS
Cr2S3 MnI2
NiBr NiS
FeS PbO2
PbCl4 Mn2O5
II. Nonbinary Ionic compounds
(Use of Polyatomic Ions)
Nonbinary means more than two different elements
Step 1 First give the name of the metal, followed by the memorized polyatomic ion name.
Step 2 If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.
Examples
NaOH Fe(NO3)3
Fe(SO4)2Zn(C2H3O2)2
Formula Name Formula Name
NH4+ Ammonium O2
2- Peroxide
C2H3O2- Acetate NO3
- Nitrate
CO32- Carbonate NO2
- Nitrite
HCO31- Hydorgen
carbonateSO4
2- Sulfate
ClO4- Perchlorate SO3
2- Sulfite
ClO3- Chlorate PO4
3- Phosphate
ClO2- Chlorite PO3
3- Phosphite
ClO- Hypochlorite CrO42- Chromate
CN- Cyanide Cr2O72- Dichromate
OH- Hydroxide MnO41- Permanganate
Memorized Polyatomic Ion List
II. Nonbinary Ionic compoundsNonbinary means more than two different elements
Step 1
First give the name of the metal, followed by the memorized polyatomic ion name.
Step 2
If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.
Examples
NaOH Fe(NO3)3
Fe(SO4)2Zn(C2H3O2)2
Sodium hydroxide
CO
II. Nonbinary Ionic compoundsNonbinary means more than two different elements
Step 1
First give the name of the metal, followed by the memorized polyatomic ion name.
Step 2
If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.
Examples
NaOH Fe(NO3)3
Fe(SO4)2Zn(C2H3O2)2
Sodium hydroxide
Iron(III) nitrate
II. Nonbinary Ionic compoundsNonbinary means more than two different elements
Step 1
First give the name of the metal, followed by the memorized polyatomic ion name.
Step 2
If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.
Examples
NaOH Fe(NO3)3
Fe(SO4)2Zn(C2H3O2)2
Sodium hydroxide
Iron(III) nitrate
Iron(II) sulfate
II. Nonbinary Ionic compoundsNonbinary means more than two different elements
Step 1
First give the name of the metal, followed by the memorized polyatomic ion name.
Step 2
If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.
Examples
NaOH Fe(NO3)3
Fe(SO4)2Zn(C2H3O2)2
Sodium hydroxide
Iron(III) nitrate
Iron(II) sulfate Zinc acetate
NOMENCLATURE
COVALENT BONDS(non-metal with non-
metal)
IONIC BONDS(metal with non-metal)
POLYATOMIC ION(more than 2 elements in
the compound)
Rules:• Use pre-fixes (mono-, di-, tri-, tetra-, penta-, etc…)• Second element ends
with the suffix “-ide)
Rules:• Find polyatomic ion
on the cheat sheet.• If the polyatomic ion
is listed first, then the second element ends with the suffix “-ide)
• If the polyatomic ion is listed last, then simply name the first element.
Rules:• No pre-fixes!• Second element ends
with the suffix “-ide)
If there is a TRANSITION METAL (groups 3-12) present, then use roman numerals (I, II, III, IV, V)
Balancing Chemical Equations
Recall: •The law of Conservation of Matter (mass). Matter can not be created or destroyed only changed.•A chemical equation is a way to show matter being changed from one compound to another.
For example:H + O ------> H O
•This equations show when hydrogen and oxygen combine it makes water. But look closer.... In the first half of the equation you have one hydrogen and one oxygen and in the second you have two hydrogen and one oxygen. You must balance this equation due to the law of conservation of matter. With the equation the way it is, you are saying that you created another hydrogen and you can not create matter.
2H + O-----> H ONow it is Balanced!!! Two hydrogen on each side and one oxygen on each side.
2
2
PRACTICE:
PRACTICE:
4 Types of Chemical Reactions
1. Single Replacement Reaction- Occurs when one element replaces another element in a
compound.A + BC -----> B +AC
2. Double Replacement Reaction- Occurs when cations of two compounds switch places.
AB + CD ----> CB + AD3. Decomposition Reaction
-Occurs when a single compound breaks down into simpler compounds.
AB -----> A + B4. Synthesis Reaction
-Occurs when two of more substances combine to form a single substance.
A + B ----> AB