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AWS A5_16-A5_16M 2007 Specification

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    AWS A5.16/A5.16M:2007An American National Standard

    Specification forTitanium andTitan ium-AlloyWelding Electrodesand Rods

    IN O T F O R P U B L IC R E L E A S EI

    ~ J > , I II e r ic a n Nat iona,

    A m e r i c a n W e l d i n g S O C i e l y If.Licom)ed to Shawn Younq. /\NSi order X_.52689. Oowntoaced 3/3'1./20084:39 PM. Single "icense only . Copy jn~Jand network ino protdbitecL

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    AWS A5.16/A5.16M:2007An American National Standard

    Approved by theAmerican National Standards Institute

    August 17, 2007

    Specification forTitanium and Titanium-Alloy

    Welding Electrodes and Rods

    [ N O T F O R P U B L IC R E L E A S E J 5th EditionSupersedes AWS A5.16/A5.16M:2004

    Prepared by theAmerican Welding Society (AWS) A5 Committee on Filler Metals and Allied Materials

    Under the Direction of theAWS Technical Activities Committee

    Approved by theAWS Board of Directors

    AbstractAWS A5.16/A5 .16M:2007 is a revision of the titanium welding electrode document last revised in 2004. The compositionsspecified for each classification represent the state of the art. The specification contains testing procedures, standardsizes and forms, and identification and marking practices.This specification makes use of both U.S. Customary Units and the International System of Units (SI). Since these arenot equivalent, each system must be used independently of the other.

    Licensed to Shavvn Younq. ANSl order X_._526S9.Downloaded 3/31/20084:39 PfvL Sinni8 user license only, Copyir,g and netv'%cking

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    AWS A5.16/A5.16M:2007

    [ N O T F O R P U B L IC R E L E A S E J

    International Standard Book Number: 978-0-87171-077-2American Welding Society

    550 NW. Lejeune Road, Miami, FL 33126 2007 by American Welding Society

    All rights reservedPrinted in the United States of America

    Photocopy Rights. No portion of this standard may be reproduced, stored in a retrieval system, or transmitted in anyform, including mechanical, photocopying, recording, or otherwise, without the prior written permission of the copyrightowner.Authorization to photocopy items for internal, personal, or educational classroom use only or the internal, personal, oreducational classroom use only of specific clients is granted by the American Welding Society provided that the appropriatefee is paid to the Copyright Clearance Center, 222 Rosewood Drive, Danvers, MA 01923, tel: (978) 750-8400; Internet:.

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    AWS A5.16/A5.16M:200i

    Statement on the Use of American Welding Society StandardsAll standards (codes, specifications, recommended practices, methods, classifications, and guides) of the AmericarWelding Society (AWS) are voluntary consensus standards that have been developed in accordance with the rules of theAmerican National Standards Institute (ANSI). When AWS American National Standards are either incorporated in, oimade part of, documents that are included in federal or state laws and regulations, or the regulations of other govern-mental bodies, their provisions carry the full legal authority of the statute. In such cases, any changes in those AWSstandards must be approved by the governmental body having statutory jurisdiction before they can become a part olthose laws and regulations. In all cases, these standards carry the full legal authority of the contract or other documemthat invokes the AWS standards. Where this contractual relationship exists, changes in or deviations from requirementsof an AWS standard must be by agreement between the contracting parties.AWS American National Standards are developed through a consensus standards development process that bringstogether volunteers representing varied viewpoints and interests to.achieve consensus, ~~e AWS administers theprocess and establishes rules to.promote fairness in the development of consensus, it d6es net intdependently test, evalu-ate, or verify the accuracy of any information or the soundness of any judgments C('jfuai~itY itz~ dards.AWS disclaims liability for any injury to.persons or to.property, or o.therfi~j3s of any ~t re whatsoever, whetherspecial, indirect, consequential, or compensatory, directly or indirectl~~l]ng f r ' 0 1 : J th2ttblicatio.n, use of, or relianceo.n this standard. AWS also. makes no. guarantee or warran._y /Q#j:h.te aaur~~ "o.mpleteness of any informationpublished herein. / ~ ( ~In issuing and making this standard available, AWS is ~itller ~Me~ng t, ender professional or other services for oron behalf of any person or entity, nor is AWS u~dert dng to::p,etf2.nn~. duty owed by any person or entity to.someoneelse. Anyone using these documents should rel n hi or ~0WXindependent judgment or, as appropriate, seek theadvice of a competent p~o.fessio.nalin d~te9U !~~r~o..f reaso.nabl~ care in ~y given circumstances. It isass~med that the use of this standard and.lt,(""pf(fto.n~ 7~sted to.appropriately qualified and competent pers~~el.ThISstandard may be supersede?Y4uan~~e-w editions, Users should ensure that they have the latest edition.Publication of this standard cl6es.n@~~ri~i1if'ringement of any patent or trade name. Users of this standard acceptany and all liabilities !:7fring~t of aJl~patent or trade name items. AWS disclaims liability for the infringement ofany patent or product t ade 1l~~.Jitlg from the use of this standard.Finally, the AWS does no. ~(ij60.Iice, or enforce compliance with this standard, nor does it have the power to.do.SQ.On occasion, text, tables, or figures are printed incorrectly, constituting errata. Such errata, when discovered, are postedon the AWS web page (www.aws.org).Official interpretations of any of the technical requirements of this standard may only be obtained by sending a request,in writing, to.the appropriate technical committee, Such requests should be addressed to.the American Welding Society,Attention: Managing Director, Technical Services Division, 550 N.W. Lejeune Road, Miami, FL 33126 (see Annex B).With regard to.technical inquiries made concerning AWS standards, oral opinions on AWS standards may be rendered.These opinions are offered solely as a convenience to. users of this standard, and they do. not constitute professionaladvice. Such opinions represent only the personal opinions of the particular individuals giving them. These individualsdo.not speak on behalf of AWS, no.rdo.these oral opinions constitute official or unofficial opinions or interpretations ofAWS. In addition, o.ralopinions are informal and should not be used as a substitute for an official interpretation,This standard is subject to.revision at any time by the AWS A5 Committee on Filler Metals and Allied Materials. Itmustbe reviewed every five years, and if not revised, it must be either reaffirmed or withdrawn. Comments (recommendations,additions, or deletions) and any pertinent data that may be of use in improving this standard are required and should beaddressed to. AWS Headquarters. Such comments will receive careful consideration by the AWS A5 Committee onFiller Metals and Allied Materials and the author of the comments will be informed of the Committee's response to.thecomments. Guests are invited to.attend all meetings of the AWS A5 Committee on Filler Metals and Allied Materials to.express their comments verbally. Procedures for appeal of an adverse decision concerning all such comments areprovided in the Rules of Operation of the Technical Activities Committee, A copy of these Rules can be obtained fromthe American Welding Society, 550 N.W. Lejeune Road, Miami, FL 33126.

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    AWS A5.16/A5.16M:2007

    PersonnelAWS AS Committee on Filler Metals and Allied Materials

    D. A. Fink, ChairJ. S. Lee, 1st Vice Chair

    H. D. Wehr, 2nd Vice ChairR. K. Gupta, Secretary

    J. M. BlackburnR. S. BrownJ. C. Bundy

    R. J. ChristoffelD. D. CrockettJ. J. DeLoach, Jr.D. A. DelSignore

    J. DeVitoH. W.EbertD.M.Fedor

    J. G. FeldsteinS. E. FerreeG. L.FrankeR. D. FuchsC. E. Fuerstenau

    J. A. HenningR. M. HensonM. Q. Johnson

    S. D. KiserP. J. KonkolD. J. KoteckiL. KvidahlA. Y.Lau

    A. S. LaurensonW. A. MarttilaR. Menon

    M. T.MerloD. R. MillerB. Mosier

    A. K. MukherjeeC. L. Null

    M. P. ParekhR. L. Peaslee

    S. D. Reynolds, Jr.P. K.Salvesen

    K. SampathW. S. SeveranceM. J. SullivanR. C. SutherlinR. A. Swain

    R. D. Thomas, Jr.K. P. Thornberry

    L. T. Vernam

    The Lincoln Electric CompanyChevronArcos Alloys CorporationAmerican Welding SocietyDepartment of the NavyRSB Alloy ApplicationsITW Hobart BrothersConsultantThe Lincoln Electric CompanyNaval Surface Waif are CenterConsultantESAB Welding and Cutting ProductsConsultantThe Lincoln Electric CompanyFoster Wheeler Energy CorporationESAB Welding and Cutting ProductsNaval Surface Waifare CenterBohler Thyssen Welding USA, IncorporatedLucas-Milhaupt, IncorporatedNuclear Management CompanyJ. W. Harris CompanyLos Alamos National LaboratorySpecial MetalsConcurrent Technologies CorporationDamian Kotecki Welding ConsultantsNorthrop Grumman Ship SystemsCanadian Welding BureauConsultantDaimler Chrysler CorporationStoody CompanyThe Lincoln Electric CompanyABS AmericasPolymet CorporationSiemens Power Generation, IncorporatedConsultantConsultantWall Colmonoy CorporationConsultantDet Norske Veritas (DNV)ConsultantESAB Welding and Cutting ProductsNASSCOAT! Wah ChangEuroWeld LimitedR. D. Thomas and CompanyCare Medical IncorporatedAlcoTec Wire Company

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    AWS A5.16/A5.16M:2007

    Advisors to the AWS AS Committee on Filler Metals and Allied MaterialsR. L. BatemanR. A. Daemen

    J. P. HuntS.Imaoka

    M. A. QuintanaE. R. StevensE. S. Surian

    ElectromanuJacturas, S. A.ConsultantConsultantKobe Steel LimitedThe Lincoln Electric CompanyStevens Welding ConsultingNational University oj Lomas de Zamora

    AWS ASK Subcommittee on Titanium and Zirconium Filler MetalsR. C. Sutherlin, Chair

    J. C. Monsees, Vice ChairS. N. Borrero, Secretary

    D. D. Harwig, Jr.S. KleppenH. KotakiB. Krueger

    S. L. LuckowskiK. T. TranM. E. Wells

    AT! Wah ChangHi- Tech Welding ServicesAmerican Welding SocietyThermadyneCK Worldwide, IncorporatedJapan Titanium SocietyATIWah ChangDepartment oj the ArmyNaval Surface Waif are CenterNaval Surface Waifare Center

    Advisors to the AWS ASK Subcommittee on Titanium and Zirconium Filler MetalsB. Heuer

    R. KellumJ. A. McMasterJ. Richardson

    R. D. Thomas, Jr.

    OpensoWillamette Welding Supply CompanyMC ConsultingNAVSEAR. D. Thomas and Company

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    AWS A5.16/A5.16M:200i

    ForewordThis foreword is not part of AWS AS.16/AS.l6M:2007, Specification for Titanium and Titanium-Alloy

    Welding Electrodes and Rods, but is included for informational purposes only.

    This document is the second of the AS.16 specifications which makes use of both U.S. Customary Units and the Inter-national System of Units (SI). The measurements are not exact equivalents; therefore, each system must be usedindependently of the other, without combining values in any way. In selecting ration . etn\ units, AWS Al.1, MetricPrac~i~eGuidefor ~heW_eldingIn~ustry, and International S~dm_-d ISO S44 , WeldjP: cous~ma'b~s - Technical d~live1}conditions for welding filler materials - Type ofproduct, dimensions, tolerancef, a~fid i{i:/I8s, e used where suitable,Tables and figures make use of both U.S. Customary and SI Units, which,)Y'itCt~ apz~tron .t1he specified tolerances,provides for interchangeability of products in both the U.S. Customy4d SI~Ifi s.The current document is the fourth revision of the initial joint ~41~w.s:~umen. Issued in 1961. The evolution tookplace as follows: The first specification for titanium electrgd6 and weidi~od~as developed more than 40 years agoby a joint committee of the American Welding Societ ~d tfic l~menc~~iety for Testing and Materials. The 1970revision was the first version of this specification t e Ubt~\Se~i .ly by AWS. Three years later, it was recognizedby the American National Standards Institute. ;YThe following new electrode classificatipa were adde ~ERJ;i- 9, ERTi-20, ERTi-21, ERTi-36, and ERTi-38. The currentERTi-9 composition requirements;;ll1fO~h~re~1'iS requirements of ERTi-9ELI. A new requirement (subclauseIS.I) was added requiringzVe im\~each cut length rod.All new requirements W : , O doc en' .. = : : : , DevelopmentAWS AS.16-61T \' Tentative Specificationfor Titanium Alloy Bare Welding Rods and ElectrodesASTM B382-61TAWS AS.16-70ANSI W3.16-1973ANSI/AWS AS.16-90ANSI/AWS AS.16-90R

    Specification for Titanium and Titanium Alloy Bare Welding Rods and Electrodes

    Specification for Titanium and Titanium Alloy Bare Welding Rods and ElectrodesSpecification for Titanium and Titanium Alloy Welding Rods and Electrodes,reaffirmed in 1997

    AWS AS.16/AS.16M:2004 Specificationfor Titanium and Titanium-Alloy Welding Electrodes and RodsComments and suggestions for the improvement of this standard are welcome. They should be sent to the Secretary,AWS AS Committee on Filler Metals and Allied Materials, American Welding Society, SSO N.W. Lejeune Road, Miami,FL 33126.

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    AWS AS.16/AS.16M:200i

    Table of ContentsPage No.

    Personnel vForeword viiList of Tables xList of Figures x1. Scope 12. Normative References 13. Classification 14. Acceptance 45. Certification 46. Rounding-Off Procedure 47. Summary of Tests 48. Retest 49. Chemical Analysis 410. Method ofManufacture 411. Standard Sizes and Lengths 412. Finish and Uniformity 413. Standard Package Forms 514. Winding Requirements 515. FillerMetal Identification 716. Packaging 717. Marking of Packages 7Annex A (Informative)--Guide to AWS Specification for Titanium and Titanium-Alloy Welding Electrodes

    and Rods 9Annex B (Informative)-Guidelines for the Preparation of Technical Inquiries 21AWS Filler Metal Specifications by Material and Welding Process 23American Welding Society (AWS) List of Filler Metal Specifications and Related Documents 25

    ix10 Young. ANS! order onty,

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    AWS A5.16/A5.16M:2007

    List of TablesTable Page No

    Chemical Composition Requirements for Titanium and Titanium-Alloy Electrodes and Rods 22 Standard Sizes and Length 53 Standard Packages, Dimensions, and Weights 5A.I Specification Cross Index-Including Discontinued Titanium Electrodes 10A.2 Guide to Choice of Filler Metal for General Purpose Titanium Welding 14

    List of FiguresFigure PageNo.

    Dimensions of Standard 4 in, 8 in, and 12 in [100 mm, 200 mm, and 300 mm] Diameter Spools 6

    x

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    AWS A5.16/A5.16M:200~

    Specification for Titanium and Titanium-AlloyWelding Electrodes and Rods

    1. Scope1.1 This specification prescribes requirements for the clas-sification of titanium and titanium-alloy electrodes and rodsfor gas tungsten arc, gas metal arc, and plasma arc welding.1.2 Safety and health issues and concerns are beyond thescope of this standard and are therefore not fullyaddressed herein. Some safety and health informationcan be found in the informative annex clauses A5 andAlO. Safety and health information is available fromother sources, including, but not limited to, ANSI Z49.1,Safety in Welding, Cutting, and Allied Processes, andapplicable federal and state regulations.1.3 This specification makes use of both U.S. CustomaryUnits and the International System of Units (SI). Themeasurements are not exact equivalents; therefore, eachsystem must be used independently of the other withoutcombining in any way when referring to filler metalproperties. The specification with the designation A5.16

    ANSI Z49.1, Safety in Welding, Cutting, and AllieaProcesses2.2 American Welding Society (AWS) standard+AWS A5 .01, Filler Metal Procurement Guidelines

    2.3 American Society for Testing and Materials (ASTM)standard:"

    The standards listed below contain\prov.>isi .s, which,through reference in this text, constitUt"-lP datory pro-visions of this AWS standard. For undated references,the latest edition of the referenced standard shall apply.For dated references, subsequent amendments to, or revi-sions of, any of these publications do not apply.2.1 American National Standards Institute (ANSI)standard;'

    1 This ANSI standard is published by the American WeldingSociety, 550 N.W. LeJeune Road, Miami, FL 33126.

    2AWS standards are published by the American WeldingSociety, 550 N.W. Lejeune Road, Miami, FL 33126.3ASTM standards are published by the American Society forTesting and Materials, 100 Barr Harbor Drive, West Consho-hocken, PA 19428-2959.4 ISO standards are published by International Organization ofStandardization, 1 rue de Varembe, Case postale 56, CH-1211Geneva 20, Switzerland.

    1

    to

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    Table 1 ~e nr Chemical Composition Requirements for Titanium and Titanium-Alloy Electrodes and Rods ')'~ ~U iCD Weight Percenta,b,c,d ~-o ~0 ~0)ill AWS UNS Other s : :-;::3 Classification Number" C 0 N H Fe Al V Pd Ru Ni Elements Amount N~ 0o 0c; - . . . J.~ ERTi-1 R50100 0,03 0.03-O.l0 0.012 (J.Q05 0.08.>z ERTi-2 R50120 0.03 0.08-0.16 0.015 0.008 0.12rv0a . ERTi-3 R50125 0.03 0.13-0.20 0.02 0.008 0.16~xIG" ERTi-4 R50130 0.03 0.18-0.32 0,025 0.008 0.25NCJ)co 5.5--6.75 3.5-4.5ERTi-5 R56402 0.05 0.12-0.20 0.03 0.015 0.220o:? ERTi-7 R52401 0.03 0.08-0.1.6 0.015 0.008 0.12 0.12-0.25J6m ERTi4 R56321 0.03 0.06-0.12 0.012 0.005 0.20 2.5-3.5 2.0-3.0I)c.~ ERTi-ll R52251 0.03 0.03-0.10 0.012 0.005 0.08 0.12-0.25oN0 ERTi-12 R53401 0.03 0.08-0.1.6 0.015 0.008 0.15 0.6-0.9 Mo 0.2-0.4o tvo: - t : -o> ERTi-13 R53423 0.03 0.03-OJO 0.012 0.005 0.08 0.04-0.06 0.4-0.6n'1J~ ERTi-14 R53424 0.03 0.08-0.1.6 0.015 0.008 0.12 0.04-0.06 0.4-0.6~to ERTi-15A R53416 0.03 0.13-0.20 0.02 0.008 0.16 0.04-0.06 0.4-0.6:])~~

    R52f3 0.03 r . . f : , 16 o 01' O. o s ~ R - S J l 4 . . < l fERTi-16tSCI l R52253 N .Q3 O.gB-O.JO a . o l 2 lb.O(}5 L .08 - L . . . @.io.08ERTi-17CDR563~U:u3--0~OO::U:l2-0~Orz--o~OO.s-'O~20--275-=37S--2~O=3~O-O:Udo80~:::; ERTi-18- ; ? :0c: ERTi-19 R58641 0.03 0.06-0.10 0.015 0.015 0.20 3.0-4.0 7.5-8.5 Mo 3.5-4.50

    '~. Cr 5.5-6.5& 5G. l Zr 3.5-4.5::1Q...' ERTi-20 R58646 0.03 0.06-0.10 0.015 0.015 0.20 3.0-4.0 7.5-8.5 0.04-0.08 Mo 3.5-4.5[)~0 Cr 5.5-6.5~. Zr 3.5-4.5iD

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    r- Table 1 (Continued)?) Chemical Composition Requirements for Titanium and Titanium-Alloy Electrodes and Rods,:0ioo0 Weight Percent- b, c, d0(j)OJ[\ .1 AWS UNS Other:;! Classification Number" C 0 N H Fe Al V Pd Ru Ni Elements Amountdc::J R56408 0.Q3 0.03-0.11 0.012 0.005 0.20 5.5--6.5 3.5-4.5ERTi-23z~ ERTi-24 R56415 0.05 0.12-0.20 0.Q3 O.oI5 0.22 5.5--6.75 3.5-4.5 0.04-0.08~o. ERTi-25 R56413 0.05 0.12-0.20 0.03 0.015 0.22 5.5--6.75 3.5-4.5 0.04-0.08 0.3-0.8:;x, 0" ERTi-26 R52405 0.Q3 0.08-0.16 O.oI5 0.008 0.12 0.08-0.14cco~ ERTi-27 R52255 0.03 0.03-0.10 0.012 0.005 0.08 0.08-0.14c0~ ERTi-28 R56324 0.Q3 0.06-0.12 0.012 0.005 0.20 2.5-3.5 2.0--3.0 0.08-0.14.00; , ; , )Q ERTi-29 R56414 0.03 0.03-0.11 0.012 0.005 0.20 5.5--6.5 3.5-4.5 0.08-0.14'"L52:i ERTi-30 R53531 0.Q3 0.08-0.16 0.015 0.008 0.12 0.04-0.08 Co 0.20-0.80N00 w ERTi-31 R53533 0.03 0.13-0.20 0.02 0.008 0.16 0.04-0.08 Co 0.20-0.80x,w R55112,..-o.03 4.5-5.5 s f ]D ERTi-32 0.05-0.10 0.012 0.008 0.20 0.6-1.4 Mo 0.6-1.2u Si 0.06-0.14:; :' " l Zr 0.6-1.4::; Sn 0.6-1.4:. :ttlc:uo ERTi-33 R53443 0.Q3 0.08-0.16 0.015 0.008 0.12 0.01-0.02 0.02-0.04 0.35-0.55 Cr 0.1-0.2(-)o ERTi-34 R53444 0.Q3 0.13-0.20 0.02 0.008 0.16 0.01-0.02 0.02-0.04 0.35-0.55 Cr 0.1-0.2:JsoC D0 ERTi-36 R58451 0.03 0.06-0.12 0.02 0.0035 0.03 Nb 42.0-47.0:!' : C :S l ERTi-38 R54251 0.05 0.20-0.27 0.02 O.OlD 1.2-1.8 3.5--4.5 2.0-3.0-c :~.~ a Titanium constitutes the remainder of the composition.al b Single values are maximum.s ~C Analysis ofFe and the interstit ia l e lements C, 0, H, and N shall be conducted onsamples off iller metal taken after the f iller metal has been reduced to its f inal diameter and all processing operations have[ been completed. Analysis of the other elements may be conducted on these same samples or it may have been conducted on samples taken from the ingot or the rod stock from which the filler metal is en0 made. In case of dispute, samples from the finished filler metal shall be the referee method. ~s dAny element intentionally added (0, Fe, N, and C) must be measured and reported. Residual e lements, total, shall not exceed 0.20%, with no single element exceeding 0.05%, except for yttrium, which ~tcD shall not exceed 0.005%. Residual e lements need not be reported unless specifically required by the purchaser . A residual e lement isany element present inthe metal in small quantities that is inherent in !? 20 the sponge or scrap additions, but not intentionally added. In titanium these elements include, among others, aluminum, vanadium, tin, chromium, molybdenum, niobium, zirconium, hafnium, bismuth, ~r5~ ruthenium, palladium, yttrium, copper, silicon, and cobalt. ~S 0'>p. e SAE HS-l 086/ASTM DS-56, Metals &Alloys in the Unified Numbering System. s : :

    f ERTi-9 now conforms to the lower interstitial levels of the previous classification ERTi-9ELI (AWSA5.l6/A5.l6M:2004). N00-

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    AWS AS.16/AS.16M:2007

    AS.16 and AS.16M providing it meets the requirementsof both specifications.3.3 The filler metals classified under this specificationare intended for gas tungsten arc, gas metal arc, andplasma arc welding processes, but that is not to prohibittheir use with any other process for which they are foundsuitable.

    4. AcceptanceAcceptance" of the electrode shall be in accordance withthe provisions of AWS AS.Ol.

    5. Certification

    under test shall be considered as not meeting the require-ments of this specification for that classification.In the event that, during preparation or after completionof any test, it is clearly determined that specified OIproper procedures were not followed in preparing the testspecimens or in conducting the test, the test shall be con-sidered invalid, without regard to whether the test wasactually completed, or whether test results met, or failedto meet, the requirement. That test shall be repeated, fol-lowing proper prescribed procedures. In this case, therequirement for doubling the number of test specimensdoes not apply.

    9. Chemical AnalysisBy affixing the AWS specification and classification

    For the purpose of determining conformance with thisspecification, an observed or calculated value shall berounded to the "nearest unit" in the last right-hand placeof figures used in expressing the limiting value in accor-dance with the rounding -off method given in ASTM E 29.

    7. Summary of TestsChemical analysis of the filler metal or the rodstock from which the filler metal is made is the onlytest required for classification of a product under thisspecification.

    8. RetestIf the results of any test fail to meet the requirement, thattest shall be repeated twice. The results of both retestsshall meet the requirement. Material for retest may betaken from the original sample or from a new sample.Retest need be only for those specific elements thatfailed to meet the test requirement. If the results of one orboth retests fail to meet the requirement, the materials

    5 See A3 (in Annex A) for further information concerningacceptance, testing of the material shipped, and A5.01.6 See A4 (in Annex A) for further information concerning certi-fication and the testing called for to meet this requirement.

    10. Method of ManufactureThe welding electrodes and rods classified according tothis specification may be manufactured by any methodthat will produce material that meets the requirements ofthis specification.

    11. Standard Sizes and Lengths11.1 Standard sizes and lengths for electrodes and rods inthe different package forms (straight lengths, coils withsupport, coils without support, and spools) are shown inTable 2.

    12. Finish and Uniformity12.1 All electrodes and rods shall have a smooth finishthat is free from slivers, depressions, scratches, scale,seams, laps, and foreign matter that would adverselyaffect the welding characteristics, the operation of thewelding equipment, or the properties of the weld metal.12.2Each continuous length of filler metal shall be froma single heat or lot of material, and welds, when present,shall have been made so as not to interfere with the uni-form, uninterrupted feeding of the filler metal on automaticand semiautomatic equipment.

    4

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    AWS A5.16/A5.16M:2007

    Table 2Standard Sizes and LengthaDiameter Tolerances

    StandardPackageForms in

    StraightLengths"CoilswithoutSupportCoilswith Support 1/85/323/16

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    Spools1116

    +0.01, -0.04+0.01, -0.04

    in mm0.0020.0020.0020.002D.002D.0020.0020.002

    +0.001, -0.002+0.001, -0.002+0.001, -0.002+0.001, -0.002+0.001, -0.002+0.001, -0.002

    0.002

    +0.01, -0.04+0.01, -0.04+0.01, -0.04+0.01, -0.04+0.01, -0.07+0.01, -0.07+0.01, -0.07+0.01, -0.07+0.01, -0.03+0.01, -0.03+0.01, -0.04+0.01, -0.04

    a Dimensions, tolerances, and package forms (for round filler metal) other than those shown shall be as agreed by purchaser and supplier.bDecimal inch are exact conversions with appropriate rounding.C Length shall be 36 in 114in [915 mm 6 mm].dNot shown as standard metric size in ISO 544.

    decimalin" mm0.062 1.60.079 2.00.094 2.40.098 2.50.125 3.20.156 4.00.188 4.8d0.197 5.00.020 0.5d0.030 0.80.D35 0.90.039 1.00.0450.047 1.20.062 1.6

    [ N O T F O R P U B L IC R E L E A S E J13. Standard Package Forms13.1 Standard package forms are straight lengths, coilswith support, coils without support, and spools. Standardpackage dimensions and weights for each form are givenin Table 3. Package forms, sizes, and weights other thanthese shall be as agreed upon between the purchaser andsupplier.13.2 The liners in coils with support shall be designedand constructed to prevent distortion of the coil duringnormal handling and use, and shall be clean and dry inorder to maintain the cleanliness of the filler metal.13.3 Spools (Figure 1) shall be designed and constructedto prevent distortion of the filler metal during normalhandling and use and shall be clean and dry enough inorder to maintain the cleanliness of the filler metal.

    14. Winding Requirements14.1 Filler metal in coils and on spools shall be wound sothat kinks, waves, sharp bends, overlapping, or wedgingare not encountered, leaving the filler metal free tounwind without restriction. The outside end of the elec-trode (the end with which welding is to begin) shall be

    Table 3Standard Packages,Dimensions, and Weights

    PackageForm

    NominalNetWeight

    StraightLengths

    CoilswithoutSupportCoilswith Support

    lb kg5 2.510 525 1050 2525 1050 25

    mm100 1 0.5200 5 2.5300 10--26 5-12340 30 15

    Spools in4812

    Notes:1. Filler metal diameters for all forms and lengths are given in Table 2.2. No more than one classification or size shall be included in eachpackage.3. Dimensions of coils shall be as agreed by purchaser and supplier.4. Dimensions of standard spools are shown in Figure 1.

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    AWS A5.16/A5.16M:2Q07

    "E"

    See Note c

    SECTION A-A

    DIMENSIONS OF STANDARD 8 in AND 12 in [200 mm AND 300 mm] SPOOLS

    4in [100 mm] 8 in [200 mm] 12 in [300 mm]in mm in mm in mm

    A Diameter, max. (Note d) 4.0 102 8.0 203 12 305B Width 1.75 46 2.16 56 4.0 103Tolerance 0.03 +0,-2 0.03 +0,-3 0.06 +0,-3C Diameter 0.63 16 2.03 50.5 2.03 50.5Tolerance +0.01, -0 +1, -0 +0.06, -0 +2.5, -0 +0.06, -0 +2.5, -0D Distance between axes - - 1.75 44.5 1.75 44.5Tolerance - - 0.02 0.5 0.02 0.5E Diameter (Note c) - - 0.44 10 0.44 10Tolerance - - +0,-0.06 +1,-0 +0, -0.06 +1, -0

    a Outside diameter of barrel shall be such as to permit feeding of the filler metals.b Inside diameter of the barrel shall be such that swelling of the barrel or misalignment of the barrel and flanges will not result in the inside

    diameter of the barrel being less than the inside diameter of the flanges.C Holes are provided on each flange, but they need not be aligned. No driving holes required for 4 in [100 mm] spools.d Metric dimensions and tolerances conform to ISO 544 except that "A" specifies tolerances on the nominal diameter, rather than a plus

    tolerance only, which is shown here as a maximum.

    Figure I-Dimensions of Standard 4 in, 8 in, and 12 in[100 mm, 200 mm, and 300 mm] Diameter Spools

    6

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    AWS AS.16/AS.16M:2007

    AnnexAGuide to AWS Specification for Titanium andTitanium-Alloy Welding Electrodes and RodsThis annex is not part of AWS A5.I6/5.I6M:2007, Specification for Titanium and Titanium-Alloy

    Welding Electrodes and Rods, but is included for informational purposes only.

    At. Introduction for corresponding base metals. See Table A.I for crossreference with the earlier designations.The purpose of this guide is to correlate the filler metalclassifications with their intended applications so thespecification can be used effectively. Appropriate basemetal specifications are referred to whenever that can bedone and when it would be helpful. Such references areintended only as examples rather than complete listingsof the materials for which each filler metal is suitable.

    A2.3 Specific alloys are identified by a number similar tothe grade designation used inASTMI ASME8 specifications

    determine whether the new classification or the modifi-cation of an existing classification is more appropriate,and whether either is necessary to satisfy the need.In particular, the request needs to include:(a) All classification requirements as given for exist-

    ing classifications, such as, chemical composition ranges.(b) Information on Description and Intended Use,

    which parallels that for existing classifications, for thatclause of Annex A.

    A2.2 The chemical symbol "Ti" appears after "R" asa means of identifying the filler metals as unalloyedtitanium or a titanium-base alloy. The numeral provides ameans of identifying different variations in the composition.

    8ASME Specifications are available in Boiler and PressureVessel Code, Section IIB, from American Society ofMechanicalEngineers, 345 East 47th Street, New York, New York 10007.

    9Aerospace Material Specifications are available from Societyof Automotive Engineers, 40 Commonwealth Drive, Warrendale,PA 15096-0001.

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    AWS A5.16/A5.16M:2007

    Table A.1Specification Cross Index-Including Discontinued Titanium ElectrodesBaseFiller Metal Metal

    AWS Classification Aerospace Japan ASTMIUNS Materials ISO ITS ASME2007 2004 1990 1970 Numbers Specification Classification" Z3331b GradesERTi-l ERTi-l ERTi-l ERTi-l R50l00 4951 STi-OlOO YTx28ERTi-2 ERTi-2 ERTi-2 ERTi-2 R50120 STi-0120 YTx-35 2ERTi-3 ERTi-3 ERTi-3 ERTi-3 R50l25 STi-0l25 YTx49 3ERTi-4 ERTi-4 ERTi-4 ERTi-4 R50l30 STi-0l30 4ERTi-5 ERTi-5 ERTi-5 ERTi-6AI-4V R56402 4954 STi-6402c YTAx640 5ERTi-7 ERTi-7 ERTi-7 ERTi-0.2Pd R52401 STi-2401 YTx49Pd 7ERTi-ge ERTi-9ELld ERTi-9ELl ERTi-3AI-2.5V-l R56321 STi-6321 N/AERTi-ll ERTi-ll R52251 STi-2251 Ytx 28Pd, 11YTx35PdERTi-12 ERTi-12 ERTi-12 R53401 STi-3401 12ERTi-13 ERTi-13 R53423 STi-3423 13ERTi-14 14ERTi-15A 15ERTI-16 16ERTi-17 17ERTi-18 ERTi-18 R56326 STi-6326 18ERTi-19 R58641 STi-8641c 19ERTi-20 R58646 STi-8646c 20ERTi-21 R58211 STi-8211c 21ERTi-23 ERTi-23 ERTi-5ELl ERTi-6AI-4V-l R56408 4956 STi-6408 YTAx640E 23ERTi-24 ERTi-24 R56415 STi-6415 24ERTi-25 ERTi-25 R56413 STi-6413 25ERTi-26 ERTi-26 R52405 STi-2405 26ERTi-27 ERTi-27 R52255 STi-2255 27ERTi-28 ERTi-28 R56324 STi-6324 28ERTi-29 ERTi-29 R56414 STi-6414 29ERTi-30 ERTi-30 R53531 STi-3531 30ERTi-31 ERTi-31 R53533 STi-3533 31ERTi-32 ERTi-32 R55112 STi-5112 32ERTi-33 ERTi-33 R53443 STi-3443 33ERTi-34 ERTi-34 R53444 STi-3444 34ERTi-36 R58451 STi-4841c 36ERTi-38 R54251 STi-5451c 38

    Discontinued ERTi-6 ERTi-5AI-2.5Sn R54522 4953 STi-5631 YTAx525Discontinued ERTi-6ELl ERTi-5AI-2.5Sn-l R54523 STi-5631Discontinued ERTi-9 ERTi-3AI-2.5V R56320 STi-6320 YTAx325 9Discontinued ERTi-15 ERTi-6Al-2Cb-l Ta-lMo R56210 STi-5621Discontinued ERTi-8Al-IMo-l VDiscontinued ERTi-13V-IICr-3AI

    a The Internationalsystemfor Ti filler metal specificationshas been publishedas ISO 24034:2005, Welding Consumables - Solid wires and rodsfor fusion welding of titanium and titanium alloys- Classification. The four-digitnumbersin most instancesare truncatedfrom the five-digitUNSR-seriesnumbers.b The"x" designatesthe fillermetalform,B = rods,W = wire.C Thesedesignationnumbershavebeenproposedfor additionto ISO 24034:2005.dRenamedERTi-9 inthis edition.c The 2007 ERTi-9compositionhasbeenspecificallydesignedforweldingGrade9. It replacesthe lowerinterstitiallevelsof the previousERTi-9ELI.

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    The act of placing the AWS specification and classifica-tion designation on the packaging enclosing the productor the classification on the product itself, constitutes thesupplier's (manufacturer's) certification that the productmeets all of the requirements of the specification. Theonly testing requirement implicit in this certification isthat the manufacturer has actually conducted the testsrequired by the specification on material that is represen-tative of that being shipped and that the material met therequirements of the specification. Representative mate-rial, in this case, is any production run of that classifica-tion using the same formulation. Certification is not to beconstrued to mean that tests of any kind were necessarilyconducted on samples of the specific material shipped.Tests on such material mayor may not have been con-?:..===::":""O~=~=::....:;.:::....::==.:..=="'----;'Iuct~~. ~~asls for tfi~ cen_ifiC(jfl~ required by ~e

    s~ I lcat .n n k (lIaS's,.~-anon ~st @frepresentatlveL " W te ial C i : \ t f 15v~6mll t~ManufJlcturer's QualityAssurance ftrogram;ffl~ HoT . _

    A request for a new classification without the above infor-mation will be considered incomplete. The Secretary willreturn the request to the requestor for further information.

    (3) The request should be sent to the Secretary of theAS Committee on Filler Metals and Allied Materials atAWS Headquarters. Upon receipt of the request, theSecretary will:

    (a) Assign an identifying number to the request.This number shall include the date the request wasreceived.

    (b) Confirm receipt of the request and give theidentification number to the person who made therequest.

    (c) Send a copy of the request to the Chair of theAS Committee on Filler Metals and Allied Materials andthe Chair of the particular Subcommittee involved.

    (d) File the original request.(e) Add the request to the log of outstanding

    requests.

    AWS AS.16/AS.16M:2007

    specified in Schedule F, Table 1, of AWS AS.O!. Testingin accordance with any other Schedule in that Table shallbe specifically required by the purchase order. In suchcases, acceptance of the material shipped shall be inaccordance with those requirements.

    A4. Certification

    in a "timely manner" and the Secretary shall report theseto the Chair of the AS Committee on Filler Metals andAllied Materials, for action.

    (S ) The Secretary shall include a copy of the log ofall requests pending and those completed during the pre-ceding year with the agenda for each AS Committee onFiller Metals and Allied Materials meeting. Any otherpublication of requests that have been completed will beat the option of the American Welding Society, asdeemed appropriate.

    A3. AcceptanceAcceptance of all welding materials classified under thisspecification is in accordance with AWS AS.OI, FillerMetal Procurement Guidelines, as the specification states.Any testing a purchaser requires of the supplier, formaterial shipped in accordance with this specification,needs to be clearly stated in the purchase order, accord-ing to the provisions of AWS AS.O!. In the absence ofany such statement in the purchase order, the suppliermay ship the material with whatever testing the suppliernormally conducts on material of that classification, as

    AS. Ventilation During WeldingAS.1 Five major factors govern the quantity of fumes towhich welders and welding operators are exposed duringwelding. They are:

    (l) Dimensions of the space in which welding is done(with special regard to the height of the ceiling);(2) Number of welders and welding operators work-

    ing in that space;(3) Rate of evolution of fumes, gases, or dust, accord-

    ing to the materials and processes used;(4) The proximity of the welders or welding opera-

    tors to the fumes as the fumes issue from the weldingzone, and to the gases and dusts in the space in whichthey are working; and

    (S ) The ventilation provided to the space in which thewelding is done.AS.2 American National Standard Z49.I, Safety in Weld-ing, Cutting, and Allied Processes (published by theAmerican Welding Society), discusses the ventilation

    11

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    A6.1 Titanium and titanium alloys can be welded by gastungsten arc, gas metal arc, plasma arc, and electronbeam welding processes. Titanium is a reactive metaland is sensitive to embrittlement by oxygen, nitrogen,and hydrogen, at elCvat temperatures. Consequently,the metal must b~rotecte rom atmospheric contami-natio~. This can~e~CD'.i.ded by ~ieldi~g the metal withweldmg grade Illl(lt gt'sO_8eclled mAWS A5.321A5.32M, specificatron..JWe{d~d~l4ing Gases, forclasses SG-A or SG-H~,l)y hav~1trres of thesesingle shielding gas classes Sbrroun~~~oltenor solidified hot weld metal. ~l

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    A7.7 ERTi-S. Grade 5 (Ti 6AI-4V), commonly callec"6-4," is the most common and widely used alloy gradedue to its relatively low cost and good availability. It hasa UTS of 130,000 : H i [895 MPa] minimum, good weld-ability, and can~at treated to a higher strength 01toughness. Gfade1Jjs u ed in aircraft components sudas landi~ear wing>sp'Jrs, and compressor blades. ItsA7.2 Use of a filler metal of the same strength and com- corro~0n resistance io/'{enerally comparable to Grade 2

    position except enhanced with palladium or ruthenium ano/it i~~.. use~n corrosion service where higher(e.g. substituting ERTi-7 for ERTi-2) could be consid- st'ength i I,e'll;~,particularly in shafts, high strengthered where preferential weld metal corrosion is antici- 01 Illg-,an k'Ys.pated and will generally produce satisfactory results. If it ~is desired to weld other combinations of dissimil A 'S:~~'F1-7.Grade 7 has the same mechanical proper-grades, welds should be evaluated as to suitability for. e" ,\'s .7 Grade ~. The 0.12 wt % palla~ium addit~onpurpose intended for both mechanical and covfosioll . ~ Im9l'0ves corrosron performance under mildly reducingproperties. Caution should be exercised Wh~nZoni:a1r~-- .Ifnditions or where. crevice or unde.r-deposit corros~oning welding alloys with unalloyed filler me61s .12~cau~ IS a problem. ERTl-7 can be consI~ered for weldl~gdifferences in hydrogen solubility 1!an /ad @ (fe}~ye Gr~de 2 or 16 where improved corrosion performance ISc.racking probl~ms. ~n the absenc~ 0 pe~ific. ihlo1)Pa- desired,non, consulta~I?n wI~h the m.ateml' S}T-ft~lS r:eom- A7.9 ERTi-9. Grade 9 (Ti 3AI-2.5V) is a "half' alloy~en~ed. Additional mformatIor/~~~~l ' III the version of Grade 5 and is used for applications wheretitanium ~hapter o~ ~e A~TS!Weldb'

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    AWS AS.16/ AS.16M:2007

    ASTMBase Recommended AlternateMetal UTS (min.) YS (min.) Nominal Filler FillerGrade ksi [MPa] ksi [MPa] Composition Metal Metals Comments35 [240] 20 [138] Ti (unalloyed) ERTi-l

    2 50 [345] 40 [275] Ti (unalloyed) ERTi-2 ERTi-l is no longerrecommended for Grade 2in structural applications2H 58 [400] 40 [275] Ti (unalloyed) ERTi-2 Identical to Grade 2 exceptfor higher tensile strength3 65 [450] 55 [380] Ti (unalloyed) ERTi-3 ERTi-2 is no longerrecommended for Grade 3in structural applications4 80 [550] 70 [483] Ti (unalloyed) ERTi-45 130 [895] 120 [828] Ti 6A1-4V ERTi-56 NAa7 50 [345] 40 [275] Ti 0.15Pd ERTi-77H 58 [400] 40 [275] Ti 0.15Pd ERTi-7 Identical to Grade 7 exceptfor higher tensile strength

    NAa9 90 [620] 70 [483] Ti 3Al-2.5V ERTi-9

    NAa11 35 [240] 20 [138] TiO.15Pd ERTi-1112 70 [483] 50 [345] Ti 0.8Ni-0.3Mo ERTi-1213 40 [275] 25 [170] Ti 0.5Ni-0.05Ru ERTi-1314 60 [410] 40 [275] Ti 0.5Ni-0.05Ru ERTi-1415 70 [483] 55 [380] Ti 0.5Ni-0.05Ru ERTi-15A "A" suffix used to distinguishfrom obsolete ERTi-15composition16 50 [345] 40 [275] Ti 0.05Pd ERTi-16 ERTi-7 ERTi-7 provides comparablemechanical properties andequal or better corrosionresistance16H 58 [400] 40 [275] Ti 0.05Pd ERTi-16 Identical to Grade 16 exceptfor higher tensile strength17 35 [240] 20 [138] Ti 0.05Pd ERTi-17 ERTi-11 ERTi-11 providescomparable mechanicalproperties and equal or bettercorrosion resistance18 90 [620] 70 [483] Ti 3Al-2.5V ELI-0.05Pd ERTi-1819 115 [793] 110 [759] Ti 3Al-8V-6Cr-4Zr-4Mo ERTi-19

    (Continued)

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    AWS A5.16/ A5.16M:2007

    ASTM Base MetalBase Recommended AlternateMetal UTS (min.) YS (min.) Nominal Filler FillerGrade ksi [MPa] ksi [MPa] Composition Metal Metals Comments20 115 [793] 110 [759] Ti 3AI-8V -6Cr-4Zr-4Mo-0.05Pd ERTi-2021 115 [793] 110 [759] Ti 3AI-15Mo-2.5Nb-0.2Si ERTi-21

    NAa23 120 [828] 110 [759] Ti 6AI-4V ELI ERTi-2324 130 [895] 120 [828] Ti 6AI-4V -0.05Pd ERTi-2425 130 [895] 120 [828] Ti 6AI-4V-0.5Ni-0.5Pd ERTi-2526 50 [345] 40 [275] TiO.lORu ERTi-26 ERTi-7 ERTi-7 provides comparablemechanical properties andequal or better corrosionresistance26H 58 [400] 40 [275] TiO.lORu ERTi-26 ERTi-7 Identical to Grade 26 exceptfor higher tensile strength27 35 [240] 20 [138] TiO.lORu ERTi-27 ERTi-1 ERTi-11 providescomparable mechanicalproperties and equal or bettercorrosion resistance28 90 [620] 70 [483] Ti 3AI-2.5V ELI-O.lORu ERTi-28 ERTi-18 ERTi-18 providescomparable mechanicalproperties and comparablecorrosion resistance29 120 [828] 110 [759] Ti 6AI-4VELI-0.lORu ERTi-2930 50 [345] 40 [275] Ti 0.3Co-0.05Pd ERTi-3031 65 [450] 55 [380] Ti 0.3Co-0.05Pd ERTi-3132 100 [689] 85 [586] Ti 5AI-1Sn-1Zr-1V-0.8Mo ERTi-3233 50 [345] 40 [275] Ti OANi-0.015Pd-0.015Ru-0.14Cr ERTi-3334 65 [450] 55 [380] Ti OANi-0.015Pd-0.015Ru-0.14Cr ERTi-3435 NAa36 65 [450] 60 [410] Ti45Nb ERTi-3637 NAa38 130 [895] 115 [794] Ti 4AI-2.5V -1.5Fe ERTi-38

    a Either there is no current ASTM Grade or no corresponding AWS Filler Metal Grade.Note: Properties in solution treated condition. Material is normally purchased in this condition and heat treated as required.

    [ N O T F O R P U B L IC R E L E A S E J15

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    AWS A5.16/ A5.16 :2007

    addition ;mpro~B':!S!!~ -O.5Pd) is romreducing conditions or where crevice or under-deposit parable in mechanical and metalworking properties t ccorrosion is a problem. Grade 13 has a lower alloy cost Grades 9 and 28. The palladium addition improves th(than Grades 11, 17, and 27 due to lower ruthenium con- alloy corrosion resistance. Grade 18 was developed origtent. This alloy was developed and is primarily used in inally for energy industry applications like hypersalineJapan. brine tubulars, including coiled tubing,

    A7.16 ERTi-17. Grade 17 has the same mechanicalproperties as Grades 1, 11, and 26. It is often referred toas a "lean palladium grade." The minimum 0.04 wt %palladium addition improves corrosion performanceunder mildly reducing conditions or where crevice orunder-deposit corrosion is a problem. Grade 17 has a A7.22 ERTi-24. Grade 24 (Ti 6AI-4V-O.5Pd) is compa-lower alloy cost than Grade 11 and comparable perfor- rable in mechanical and metalworking properties tomance except under the most aggressive corrosion condi- Grade 5. The palladium addition improves the alloytions. _W-eldingWitllER'IT-TI overco~es sligh~o_wer corrosion re~lstance. Ilie .an~y~as. d~floped ~rigina.llycorrosion res~stanC'e)f eltt m

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    AWS AS.16/AS.16M:2007

    A7.2S ERTi-27. Grade 27 has the same mechanicalproperties as Grades 1, 11 and 17. The minimum 0.08 wt %ruthenium addition improves corrosion performanceunder mildly reducing conditions or where crevice orunder-deposit corrosion is a problem in a manner similarto the 0.04 wt % palladium addition in Grade 17. Grade26 has a lower alloy cost than Grade 11 or 27. Corrosionperformance is comparable to Grade 17, and also toGrade 7 except under the most aggressive corrosion con-ditions. Welding with ERTi-11 overcomes slightly lowercorrosion resistance of welds made with matching fillermetal.A7.26 ERTi-28. Grade 28 (Ti 3 AI-2.5V-0.IRu) is com-parable in mechanical properties and fabricability toGrades 9 and 18. The minimum 0.08 wt % rutheniumaddition improves corrosion performance under mildlyreducing conditions or where crevice or under-depositcorrosion is a problem in a manner similar to the0.04 wt % palladium addition in Grade 18. Grade 28 hasa lower alloy cost than Grade 18 and its corrosion perfor-mance is comparable to Grade 18. Itwas developed orig-inally for energy industry applications like hypersalinebrine tubulars where better formability and weldabilityare needed.A7.27 ERTi-29. Grade 29 (Ti 6AI-4V-0.IRu) is com-parable in mechanical and fabricability properties toGrade 23. The minimum 0.08 wt % ruthenium additionimproves corrosion performance under mildly reducingconditions or where crevice or under-deposit corrosion isa problem. It was originally developed and widely usedfor energy industry applications like tubulars for down-hole oil and gas production and hypersaline geothermalbrine applications.A7.28 ERTi-30. Grade 30 has the same mechanical

    A7.29 ERTi-31. Grade 31 has the same mechanical

    A7.31 ERTi-33. Grade 33 has the same mechanicalproperties as Grade 2. The ruthenium and palladiumadditions improve corrosion performance under mildlyreducing conditions or where crevice or under-depositcorrosion is a problem. This alloy was developed and isprimarily used in Japan.A7.32 ERTi-34. Grade 34 has the same mechanicalproperties as Grade 3. The ruthenium and palladiumadditions improve corrosion performance under mildlyreducing conditions or where crevice or under-depositcorrosion is a problem. This alloy was developed and isprimarily used in Japan.A7.33 ERTi-36. Grade 36 (Ti-45Nb) is matched toASTM Grade 36 (UNS R58450). Except for oxygen, allother intentional alloy additions are similar to the basemetal. This alloy can be used in welded applications andprovides improved corrosion resistance compared toGrades 7, 16, and 26 in some environments. This alloymay provide improved ignition resistance compared toother titanium grades in high oxygen, partial pressureenvironments.A7.34 ERTi-38. Grade 38 (Ti 4AI-2.5V-1.5Fe) ismatched to ASTM Grade 38 and ASME Code Case 2532(UNS R54250). Except for oxygen, all other intentionalalloy additions are similar to the base metal. This is ahigh strength alloy intended for welded applications attemperatures somewhat higher than other titaniumgrades. ERTi-38 is the highest strength titanium alloyaccepted for ASME Code construction.

    AS. Special Testsproperties as Grade 2. The ruthenium addition improves It is recognized that supplementary tests may be requiredcorrosion performance under mildly reducing conditions for certain applications. Insuch cases, tests to determineor where crevice or under-deposit corrosion is a problem. specific properties, such as corrosion-resistance, scale-This allo: was developed and is primarily used in Japan. resistance, or strength at elevate emperatures may belO T F O R P U B L !C R E L E A S E

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    AWS A5.16/A5.16M:2007

    Some classifications have been discontinued, from onerevision of this specification to another. This results 10ANSI ZA9.1 is publishedby theAmericanWeldingSociety,either from changes in commercial practice or changes in 550N.W.LeJeuneRoad,Miami, FL 33126.the classificafi0n-syst~m-us{ll.-in-th@-&p{lGifi(;[email protected]'f=h 11AW,s-standards-are-puhlished-hcy_theAmerican Weldingd"'ifio,"'"" that'Offer d are list d in L l c t y R E I E A ~ E n l l FL 33126

    AS.I Corrosion or Scaling Tests. Although welds madewith fillers in this specification are commonly used incorrosion and heat-resisting applications, tests for thoseproperties are not included in the specification. Whenrequired for a particular application, tests can be con-ducted on specimens taken from either a weld pad or awelded joint. Specimens from a joint are suitable forqualifying the welding procedure (for a specific applica-tion involving corrosion or oxidation resistance) but notfor qualifying the electrode. Tests on specimens from ajoint have the disadvantage of being a combined test ofthe properties of the weld metal, the heat-affected zone(HAZ), and the unaffected base metal. With them, it ismore difficult to obtain reproducible data (when a differ-ence exists in the properties of the metal in the variousparts of the specimen). Specimens taken from a jointhave the advantage of being able to duplicate the jointdesign and the welding sequence planned for fabrication.AS.I.I Specimens for testing the corrosion or oxida-

    tion resistance of the weld metal alone are prepared byfollowing the procedure outlined in A8.1.2 of the specifi-cation. The pad size should be at least 3/4 in [19 mm] inheight, 2-112 in [65 mm] in width, and 1 + 5 /8 n(in) [25 +16 n{mm}] in length, where n represents the number ofspecimens required from the pad. Specimens measuring112x 2 x 114 in [13 x 50 x 6.4 mm] are machined fromthe top of the pad in a manner such that the 2 in [50 mm]dimension of the specimen is parallel with the 2-112 in[65 mm] dimension of the pad and the 11 2 in [13 mm]dimension is parallel with the length of the pad.AS.I.2 The heat treatment, surface finish, and mark-

    ing of the specimens prior to testing should be in accor-dance with standard practices for tests of similar alloys inthe wrought or cast forms. The testing procedures shouldcorrespond to those of ASTM G 4, Standard Guide forConducting Corrosion Tests in Field Applications, orASTM G 31, Standard Practice for Laboratory Immer-sion Corrosion Testing of Metals, as the case may be.

    A9. Discontinued Classifications

    AIO. General Safety ConsiderationsAIO.I Safety and health issues and concerns are beyondthe scope of this standard and, therefore, are not fully ad-dressed herein. Some safety and health information canbe found in annex clause AS. Safety and health informa-tion is available from other sources, including, but notlimited to Safety and Health Fact Sheets listed in AlO.3,ANSI Z49.1, Safety in Welding, Cutting, and Allied Pro-cesses,lO and applicable federal and state regulations.AIO.2 Safety and Health Fact Sheets. The Safety andHealth Fact Sheets listed below are published by theAmerican Welding Society (AWS). They may be down-loaded and printed directly from the AWS website athttp://www.aws.org. The Safety and Health Fact Sheetsare revised and additional sheets are added periodically.AIO.3 AWS Safety and Health Fact Sheets Index(SHF) 11No. Title

    23456789

    1011121314

    Fumes and GasesRadiationNoiseChromium and Nickel in Welding FumeElectrical HazardsFire and Explosion PreventionBum ProtectionMechanical HazardsTripping and FallingFalling ObjectsConfined SpacesContact Lens WearErgonomics in the Welding EnvironmentGraphic Symbols for Precautionary Labels

    15 Style Guidelines for Safety and Health Documents16 Pacemakers and Welding17 Electric and Magnetic Fields (EMF)

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    No. Title No. Title18 LockoutlTagout 25 Metal Fume Fever19 Laser Welding and Cutting Safety 26 Arc Viewing Distance20 Thermal Spraying Safety 27 Thoriated Tungsten Electrodes21 28 Oxyfuel Safety: Check Valve and FlashbackResistance Spot Welding Arrestors22 Cadmium Exposure from Welding & Allied 29 Grounding of Portable and Vehicle MountedProcesses Welding Generators23 California Proposition 65 30 Cylinders: Safe Storage, Handling, and Use24 Fluxes for Arc Welding and Brazing: Safe 31 Eye and Face Protectionfor Welding and Cutting

    Handling and Use Operations

    [ N O T F O R P U B L IC R E L E A S E J

    19

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    Annex BGuidelines for the Preparation of Technical Inquiries

    This annex is not part of AWS AS.16/S.16M:2007, Specificationfor Titanium and Titanium-AlloyWelding Electrodes and Rods, but is included for informational purposes only.

    Bl. Introdu t19~\. provision(s) the inquirer is addressing.The American Weldil1lt~o~JC6~S) oard of Directors . . .has adopted a policy wh~yal (ij1c>iai"lht~pretations B2.2 Purpose ~fth~ Inq~lry. The p~rpo.seof the mquiryof AWS standards are hanQ.!e~rformal'manner. shall be stated in this portion of the mquiry. The purposeUnder this policy, all interpreta49ns~de ~the can be to obtain an interpretation of a standard's require-committee that is responsible for ili:~t~. ~fi~~. ent or to request the revision of a particular provisioncommunication concerning an interprelatipn' is :i.ected Inthe standard.through the AWS staff member who WOtKS~ith~a~ B Content of the Inquiry. The inquiry should becommittee. The policy requires that all request: o~ con~~et complete, to enable the committee to under-interpretation be sub~~tted in writing: Such requests'l ~. a1!t;PQj,_nt of the inquiry. Sketches should be usedbe handl~d as expeditiously as possible, but due to the ~~~ppr~iate, and all paragraphs, figures, andcomplexity of t~e work ~d the procedw:es that ~ust be '

    that revisIon~ ~,_}B2. Procedure B2.4 Proposed ~pIY. Hie inquirer should, as aproposed reply, stat~nferpretation of the provisionthat is the point of the inquiry or provide the wording fora proposed revision, if this is what the inquirer seeks.

    All inquiries shall be directed to:Managing DirectorTechnical Services DivisionAmerican Welding SocietySSON.W. Lejeune RoadMiami, FL 33126

    All inquiries shall contain the name, address, and affilia-tion of the inquirer, and they shall provide enough infor-mation for the committee to understand the point ofconcern in the inquiry. When the point is not clearlydefined, the inquiry will be returned for clarification. Forefficient handling, all inquiries should be typewritten andin the format specified below.B2.1 Scope. Each inquiry shall address one single provi-sion of the standard unless the point of the inquiryinvolves two or more interrelated provisions. The provi-sion(s) shall be identified in the scope of the inquiry

    along with the edition of the standard that contains the

    B3. Interpretation of Provisions ofthe StandardInterpretations of provisions of the standard are made bythe relevant AWS technical committee. The secretary ofthe committee refers all inquiries to the chair of the par-ticular subcommittee that has jurisdiction over the por-tion of the standard addressed by the inquiry. Thesubcommittee reviews the inquiry and the proposed replyto determine what the response to the inquiry shouldbe. Following the subcommittee's development of theresponse, the inquiry and the response are presented tothe entire committee for review and approval. Uponapproval by the committee, the interpretation is an official

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    interpretation of the Society, and the secretary transmitsthe response to the inquirer and to the Welding Journalfor publication.

    B4. Publication of InterpretationsAll official interpretations will appear in the WeldingJournal and will be posted on the AWS web site.

    B5. Telephone InquiriesTelephone inquiries to AWS Headquarters concerningAWS standards should be limited to questions of a gen-eral nature or to matters directly related to the use of thestandard. The AWS Board Policy Manual requires thatall AWS staff members respond to a telephone requestfor an official interpretation of any AWS standard withthe information that such an interpretation can be

    obtained only through a written request. Headquartersstaff cannot provide consulting services. However, thestaff can refer a caller to any of those consultants whosenames are on file at AWS Headquarters.

    B6. AWS Technical CommitteesThe activities of AWS technical committees regardinginterpretations are limited strictly to the interpretation ofprovisions of standards prepared by the committees or toconsideration of revisions to existing provisions on thebasis of new data or technology. Neither AWS staff northe committees are in a position to offer interpretive orconsulting services on (1) specific engineering problems,(2) requirements of standards applied to fabricationsoutside the scope of the document, or (3) points notspecifically covered by the standard. In such cases, theinquirer should seek assistance from a competent engi-neer experienced in the particular field of interest.

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    AWS Filler Metal Specifications by Material and Welding Process

    Carbon Steel

    GTAWGMAWOFW SMAW PAW FCAW SAW ESW EGW BrazingA5.2 A5.1 A5.18 A5.20 A5.17 A5.25 A5.26 A5.8, A5.31A5.2 A5.5 A5.28 A5.29 A5.23 A5.25 A5.26 A5.8, A5.31

    A5.4 A5.9, A5.22 A5.22 A5.9 A5.9 A5.9 A5.8, A5.31A5.15 A5.15 A5.15A5.1l A5.14A5.3 A5.10

    Low-Alloy Steel

    Shielding Gases

    Stainless SteelCast IronNickel AlloysAluminum Alloys

    Copper AlloysTitanium AlloysZirconium AlloysMagnesium AlloysTungsten ElectrodesBrazing Alloys and FluxesSurfacing AlloysConsumable Inserts

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    AWS A5.16/A5.16M:200j

    AWS Filler Metal Specifications and Related DocumentsDesignation TitleFMC Filler Metal Comparison ChartslFS International Index of Welding Filler Metal ClassificationsUGFM User's Guide to Filler MetalsA4.2M (ISO 8249: Standard Procedures for Calibrating Magnetic Instruments to Measure the Delta Ferrite Content Austenitic ana2000 MOD) Duplex Ferritic-Austenitic Stainless Steel Weld MetalA4.3 Standard Methodsfor Determination of the Diffusible Hydrogen Content ofMartensitic, Bainitic, and Ferritic Steel

    Weld Metal Produced by Arc WeldingA4.4M Standard Proceduresfor Determination of Moisture Content of Welding Fluxes and Welding Electrode Flux Covering!AS.Ol Filler Metal Procurement GuidelinesAS.02/AS.02M Specification for Filler Metal Standard Sizes, Packaging, and Physical AttributesAS.l/ AS.1M Specification for Carbon Steel Electrodes for Shielded Metal Arc WeldingAS.21AS.2M Specification for Carbon and Low-Alloy Steel Rods for Oxyfuel Gas WeldingAS.3/AS.3M Specification for Aluminum and Aluminum-Alloy Electrodes for Shielded Metal Arc WeldingAS.41AS.4M Specification for Stainless Steel Electrodes for Shielded Metal Arc WeldingAS.S/AS.5M

    AS.9/AS.9M Specification for Bare Stainless Steel Welding Electrodes and RodsAS.lO/AS.lOM Specification for Bare Aluminum and Aluminum-Alloy Welding Electrodes and RodsAS .111AS.11M Specification for Nickel and Nickel-Alloy Welding Electrodes for Shielded Metal Arc WeldingAS.I21AS.12M Specification for Tungsten and Tungsten-Alloy Electrodes for Arc Welding and CuttingAS.13 Specification for SUrfacing Electrodes for Shielded Metal Arc WeldingAS.14/AS.14M Specificationfor Nickel and Nickel-Alloy Bare Welding Electrodes and RodsAS.lS Specification for Welding Electrodes and Rods for Cast IronAS.16/AS.16M Specification for Titanium and Titanium-Alloy Welding Electrodes and RodsAS .171AS.17M Specification for Carbon Steel Electrodes and Fluxes for Submerged Arc WeldingAS.18/AS.18M Specification for Carbon Steel Electrodes and Rods for Gas Shielded Arc WeldingAS.19 Specification for Magnesium Alloy Welding Electrodes and RodsAS.201AS.20M Specification for Carbon Steel Electrodes for Flux Cored Arc WeldingAS.21 Specification for Bare Electrodes and Rods for SurfacingAS.22 Specification for Stainless Steel Electrodes for Flux Cored Arc Welding and Stainless Steel Flux Cored Rods for

    Gas Tungsten Arc WeldingAS.231AS.23M Specification for Low-Alloy Steel Electrodes and Fluxes for Submerged Arc WeldingAS.241AS.24M Specification for Zirconium and Zirconium Alloy Welding Electrodes and RodsAS.2S1AS.2SM Specification for Carbon and Low-Alloy Steel Electrodes and Fluxes for Electroslag WeldingAS.26/AS.26M Specification for Carbon and Low-Alloy Steel Electrodes for EZectrogas WeldingAS.281AS.28M Specification for Low-Alloy Steel Electrodes and Rods for Gas Shielded Arc WeldingAS.29/AS.29M Specification for Low-Alloy Steel Electrodesfor Flux Cored Arc WeldingAS.30/AS.30M Specification for Consumable InsertsAS.31 Specification for Fluxes for Brazing and Braze WeldingAS.32/AS.32M Specification for Welding Shielding GasesAS.34/AS.34M Specification for Nickel-Alloy Electrodesfor Flux Cored Arc Welding