____________________________________________ AUSTRALIAN VANADIUM PROJECT HYDROGEOLOGICAL ASSESSMENT Prepared for AUSTRALIAN VANADIUM LIMITED March 2021 ____________________________________________ AQ2 Pty Ltd Level 4, 56 William Street Perth 6000 T: 08 9322 9733 www.aq2.com.au
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____________________________________________
AUSTRALIAN VANADIUM PROJECT
HYDROGEOLOGICAL ASSESSMENT
Prepared for
AUSTRALIAN VANADIUM LIMITED
March 2021
____________________________________________
AQ2 Pty Ltd Level 4, 56 William Street Perth 6000 T: 08 9322 9733 www.aq2.com.au
F:\183\3.C&R\048d.docx
Document Status
Version Purpose of Document Author Reviewed By Review Date
A Interim Report EJB DGS Jan 2020
B Updated Report for Referral KLR DGS Nov 2020
C Updated Report KLR DGS Mar 2021
D Final Report KLR DGS Mar 2021
This document has been prepared by AQ2 for the sole use of AQ2 and its client and the document should only be used for the purposes for which it was commissioned and in accordance with the Terms of Engagement for the commission. AQ2 accepts no responsibility for the unauthorised copying or use of this document in any form whatsoever. This document has been prepared using appropriate care, professional expertise and due diligence as requested by the client, or, in the absence of specific requests, in accordance with accepted professional practice. The document is based on information and data generated during this study, provided by the client or other such information available in the public domain that could be reasonably obtained within the scope of this engagement. Unless specified otherwise, AQ2 makes no warranty as to the accuracy of third-party data. The document presents interpretations of geological and hydrogeological conditions based on data that provide only a limited view of the subsurface. Such conditions may vary in space or over time from the conditions indicated by the available data and AQ2 accepts no responsibility for the consequences of such changes where they could not be reasonably foreseen from available data.
4.2 Water Balance .................................................................................................. 22 4.2.1 Water Demand ...................................................................................... 22
4.3 Water Supply ................................................................................................... 22 4.4 Excess Water Management ................................................................................. 23
GRC0180 663630 7015909 467.7 -60 RC, open 11.86 455.86 Micro-pump 1/08/2018 Bores 19AVWM04 and 19AVWM105 were not tested as aquifer parameters at these sites were derived from the test pumping of the adjacent production bores. Bore 19AVWM112 was not tested due to the compromised status of the bore.
Confining Clay - Lake Annean Paleochannel and Tributaries 3 & 4 0.001 0.00001 6 0.00005
Basement 3 0.05 0.005 0.1 0.00001
Orebody 3 & 4 0.005 0.0005 1 0.00005
Basement 4 0.005 0.0005 0.1 0.00001
Deep Aquifer - Lake Annean Paleochannel and Tributaries 5 10 1.0 15 0.00005
Basement 5 to 7 0.0001 0.0001 0.05 0.00001
Orebody 5 & 6 0.005 0.00005 0.1 0.00005
* Modelled aquifers are assumed to be unconfined in the upper most model layer (layer 1). ** Confined storage coefficient specified in layers 2 to 6 only as the fault is modelled as an unconfined aquifer in model layer 1.
F:\183\3.C&R\048d.docx Page 20
4.1.3 Pit Dewatering Requirements
The predicted inflow rates over the 25-year mine life are presented in Figure 5 and summarised by
pit in Table 9. The results of the dewatering assessment can be summarised as follows:
Predicted mine dewatering is initially high as paleochannel sediments are intersected in Pit 2
but decrease as each pit goes into lower permeability bedrock.
o Dewatering for the first year is approximately 8,000 kL/d (92 L/s).
o Dewatering of between 4,000 kL/d (45 L/s) to 5,000 kL/d (60 L/s) between years 2 and 6.
o Dewatering volumes continue to decrease from 3,000 kL/d (35 L/s) at year 7 to 1,500 kL/d (18 L/s) by year 25.
The distribution of permeability within the fractured rock aquifer may be quite variable. In
practice, this means increases in dewatering are likely to be concentrated over permeable
horizons and this level of discretization cannot be included in the model.
The dewatering estimates take no account of the impact of cross-cutting dolerite and gabbro
dykes which may be of lower permeability and compartmentalise the orebody.
In low permeability rocks, the area affected by dewatering does not extend far from the
dewatering stress (i.e. far from pit wall into the aquifer) and the hydrostatic pressure behind
the pit walls is expected to be high. This may affect wall stability, particularly where the high
pressure corresponds with geomechanical failure surfaces. Subject to geotechnical analysis,
depressurisation of the pit walls may be required, at least in susceptible areas.
It is anticipated that dewatering discharge may initially be brackish; potentially for the first
two years of mining. However, as the mining depth progresses and / or once the higher
permeability fault zones are intersected, the dewatering production may become saline (or
hyper saline), with the fault zones anticipated to comprise 25 to 40% of groundwater inflow
to the pit.
F:\183\3.C&R\048d.docx Page 21
Table 9: Predicted Dewatering By Pit
Year Pit 1
Dewatering (kL/d)
Pit 2 Dewatering
(kL/d)
Pit 3 Dewatering
(kL/d)
Pit 4 Dewatering
(kL/d)
Total Dewatering
(kL/d) 1 3849 4149 0 0 7998
2 1966 1936 0 0 3902
3 1905 1467 1894 0 5266
4 1706 1256 1273 0 4236 5 1369 1257 1880 0 4505
6 1262 1220 1387 0 3868
7 1180 977 710 0 2866
8 1113 904 618 0 2635
9 1058 847 559 0 2464
10 1014 823 517 0 2354
11 976 0 1002 0 1978 12 1154 0 693 0 1848
13 1023 0 723 0 1746
14 1029 0 598 0 1627
15 1021 0 617 0 1638
16 929 0 555 1310 2794
17 883 0 545 701 2129
18 830 0 531 623 1985 19 783 0 550 728 2061
20 764 0 557 649 1970
21 764 0 537 0 1301
22 804 0 535 0 1338
23 792 0 519 0 1310
24 949 0 500 0 1448
25 832 0 489 0 1321
4.1.4 Open Pit Dewatering Method
Based on the initially high dewatering estimates for the first year of mining and variability of
groundwater inflows to each pit, dewatering of the open pits would be best achieved through a
combination of:
Dewatering bores which can be used to dewater the higher permeability shallow aquifer
sediments associated with the large groundwater inflow volumes at the initiation of mining.
Dewatering bores should also target the permeable structure that is inferred to run along
the footwall of the pit. Bores should be located on the pit crest at either end of the pit with
additional bores along strike and within the pit (if they can be accommodated from mining
logistics).
In-pit sump pumping to remove groundwater inflows from lower permeability units. The
mine plan should therefore allow for the presence of sumps within the pit and temporary
drains across the pit floor to direct groundwater to the sumps.
Sump pumping will not allow any dewatering freeboard which means mining will be affected by:
Rises in groundwater levels following rainfall events that may contribute to inundation of the
lower-benches; and
Wet blasting will be required on lower active benches.
F:\183\3.C&R\048d.docx Page 22
Following the dewatering of the shallow aquifer, sump pumping may continue to be effective for the
life of mine. Although dewatering bores similar to, and including, 19AVWP01 could also be used to
target and dewater the higher permeability fault zone(s). This would offer the advantage of advanced
dewatering and increased dewatered free-board.
Based on test pumping of 19AVWP01, a recommended pumping rate of 8 L/s has been derived (refer
Appendix C). However, it should be noted that the sustainability of pumping from a fractured rock
aquifer and its effectiveness for dewatering is uncertain as it depends on the connectivity and extent
of the fractures / faults. If the orientation of the permeable fault(s) becomes well understood, these
bores could potentially be sited outside the pit areas to avoid the logistical difficulties of in-pit bores
(i.e. mining through and recovering them).
Dewatering infrastructure should be designed to accommodate the likely inflow estimate (presented
in Table 9), with additional capacity for surface water runoff.
4.2 Water Balance
4.2.1 Water Demand
The mining and dust suppression (i.e. low-quality) water demand has been estimated by AVL, at
between 0.83 and 0.98 GL/a (2,300 to 2,700 kL/d) with the breakdown of water use as below:
Laterite: Sand - Gravel; angular to sub angular.Trace of silt. Purplish-brown; trace of grey.Ferricrete with the Quartz.
Duricrust: Sand - Gravel; angular to sub angular.Increased silt content. Purplish-brown with blacktraces. Magnetite present; medium - coarsegrained (10%).
Colluvium: Gravel; angular to sub angular. Red-brown. Quartz; medium grained; angular. Minorsilt. Silcrete; medium - large grained. Weatheredclasts; brittle.
Alluvium: Gravel; angular - sub angular. Red -brown - cream. Fined grained quartz. Calcrete 1-10mm grain size, angular (2%).
Sand and Clay: Green - grey, sub angular. Minorsand and gravel. Indurated clay.
Clay: Trace of sand. Brown-red.
Clay: Puggy. Mottled green-light brown.
Clay: Trace of very fine quartz sand. Pale Grey.
Clay: Puggy. Mottled green.
Calcrete: Weathered calcareous clay. Grey-white. Clasts up to 3mm.
Clay: Puggy. Light brown-grey.
Calcrete: Weathered calcareous clay. Grey-white. Clasts up to 3mm.
Clay: Sandy.
Gravel and Sand: Angular to sub angular Quartz(1-4mm). Sub angular to sub rounded Gravel(2-15mm).
Sandy Clay: Yellow/grey. Fine - medium grainedsand. Minor calcrete. Sand content increase at112-114m.
Clayey Sand: 10% clay 90% sand.
Sand and Clay: Coarse Qtz sand 50% andpuggy clay 50%.
Gravel and Clay: Hardened clay, green/grey.Gravel, angular, up to 5mm. Calcrete clasts upto 3mm. Injurated clay. Magnetite <1mm.
Alluvium: Gravel, ang - sub ang 3mm,purple/brown. Calcrete clasts up to 15mm (40-50%). Minor hardened clay (5%).
Gravel and Clay: Hardened clay, green/grey.Gravel, ang, up to 5mm. Calcrete clasts up to8mm. Magnetite <1mm. Minor ultramafic claysup to 10mm. Increased silt. Qtz 1mm sub ang -sub rounded.
Clay: Brown/red, hard. Trace of sand and gravel.
Clay: Puggy clay. Trace of sand. Mottledgreen/light brown. Turns purple at 32-34m.Trace of magnetite.
Gravel and Clay: Hardened clay, green/grey.Gravel, angular, up to 5mm. Calcrete clasts upto 3mm. Injurated clay. Magnetite <1mm.
Alluvium: Gravel, ang - sub ang 3mm,purple/brown. Calcrete clasts up to 15mm (40-50%). Minor hardened clay (5%).
Gravel and Clay: Hardened clay, green/grey.Gravel, ang, up to 5mm. Calcrete clasts up to8mm. Magnetite <1mm. Minor ultramafic claysup to 10mm. Increased silt. Qtz 1mm sub ang -sub rounded.
0-10m Blank 50mmPVC Class 12
4-7m Bentonite Seal
3.6 - 6.4mm GravelPack
10-28m 3mm Slotted50mm PVC Class18
Project:Client:
Logged By:
COMPOSITE WELL LOG
Drilled:
Commenced:S
trat Well Completion
Field NotesDepth GraphicLog(mbgl)
Lithological DescriptionNotesDiagram
Easting:
Northing:
Bore No:
Static Water Level:
Elevation:
Remarks:
Area:
Projection:Australia
Completed:
WA 6005
Aq
uif
er
+61 8 93215594
West Perth
85 Havelock St
Method:
Bit Record:
File Ref: Well No:
0
10
20
30
Australian Vanadium Gabanintha
14/04/2019
16/05/2019
Ausdrill North West
KO
4 mbtoc
458 mRL
654653
7014407
0.83m Stick up
Palaeochannel
GDA94 zone 50J
19AVWM03
DR 0-28m
241mm
F:\183\2.TECH\LogPlot 19AVWM03
FWS
Airlift yield = 4 L/s, EC =4400 uS/cm
Airlift yield = 10 L/s, EC= 8300 uS/cm
Airlift = 7 L/s
No water return
Completed airlift = 8860uS/cm
Alluvium: Gravel; angular to sub angular. Brown.Minor calcrete (2mm) 5%. Minor clay.
Alluvium: Gravel; angular to sub angular. Browncream with minor black. Calcrete clasts up to40mm, increasing content at 6m. Minorultramafic clasts upto 10mm. Becomes purplebrown at 12m, increase magnetite.
Gravel: Rock clasts and gravel up to 40mm, subrounded to angluar. Calcrete clasts upto 40mm.Minor magnetite. Minor Quartz; angular to subangular. High yielding (10 L/s). Increased siltcontent at 22m.
Gravel and Clay: Gravel 70%; angular, minorcalcrete. Clay 30%.
Clay: Gravelly clay with hardened clay clasts upto 50mm. Brown.
Soil: Surficial soil with rock fragments. Redbrown, angluar caprock and silty soils.
Gravel: Sandy. Tan/khaki clay, silt and rockfragments 10-40mm.
Calcrete: Ivory calcrete with brown coarse sandand gravel 1-8mm. CaCO3 80%.
Gravel and Sand: Brown sandy gravel and clay(30%). Rock fragments 10-25mm.
Clay: Red brown clay with sandy gravel. Clay80%.
2-4m Bentonite Seal
0-22m Blank 50mmND PVC Class 18
3.6-6.4mm GravelPack
22-28m 3mm Slotted50mm ND PVCClass 18
Project:Client:
Logged By:
COMPOSITE WELL LOG
Drilled:
Commenced:S
trat Well Completion
Field NotesDepth GraphicLog(mbgl)
Lithological DescriptionNotesDiagram
Easting:
Northing:
Bore No:
Static Water Level:
Elevation:
Remarks:
Area:
Projection:Australia
Completed:
WA 6005
Aq
uif
er
+61 8 93215594
West Perth
85 Havelock St
Method:
Bit Record:
File Ref: Well No:
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
Australian Vanadium Gabanintha
23/05/2019
29/05/2019
Ausdrill North West
KO
13.96 mbtoc
469.50 mRL
663778
7015448
0.84m Stick up
Orebody
GDA94 zone 50J
19AVWM104
DR 0-60m
DDH 60-175m
241mm(0-60m)/191mm(60-175m)
F:\183\2.TECH\LogPlot 19AVWM104
FWS
Airlft yield = <1 L/s
Airlift yield = 1.2 L/s, EC= 15000 uS/cm
Airlfit yield = <1 L/s
Airlift yield = <1 L/s
Airlift yield = 1 L/s
Airlift yield = 2.5 L/s, EC= 60000 uS/cm
Airlift yield = 3.5 L/s, EC= 121000 uS/cm
Airlift yield = 3 L/s, EC =156000 uS/cm
Airlift yield = 5 L/s, EC =176000 uS/cm
Airlift yield = 10 L/s, EC> 240000 uS/cm
Airlift yield = 6 L/s, EC >240000 uS/cm
Airlift yield = 5 L/s, EC =190000 uS/cm
Airlift yield = 5.0 L/s
Airlift yield = 5.0 L/s
Airlift yield = 10 L/s, EC= 226000 uS/cm
Duricrust: Red - brown, silty. Gravel; anguar tosub angular, clasts upto 20mm. Trace ofmagnetite. Trace of Calcrete.
Calcrete: Weathered calcrete, purple - cream,clasts upto 20mm. Gravel; angular to subangular. High silt content. Minor clay.
Saprock: Weathered igneous rock sub roundedto angular. Clasts of ultra mafic upto 20mm. 50%clay; purple brown.
Saprock: Gravelly. Grey - brown, puggy clay(weathered bedrock). Minor gravel.
Saprock: Clayey (weathered bedrock). Red -brown - purple. Gravel; angular to sub angular.Clay 30%, decreasing with depth. Gravelbecoming fine grained at 38m.
Mafic: Fresh igneous rock, highly magnetic,minor gravels. 30% clay. Quartz up to 2mm.
Mafic: Purple weathered igneous rock. Highlymagnetic, fine grained.
Ore: Dark green - black- metallic. Highlymagnetic. Minor gravel. Ore content increasingat 92m. Fine grained with clasts up to 15mm.
Ore: Green fractured mafic igneous rock.Plagioclase & Pyroxene present. Highlymagnetic. Minor Sulphides.
Basement: Competent rock dark green - purple,fractured igneous rock. Minor ore/magnetite.Large quartz; angular to sub angluar up to20mm, weathered. High sulphide content.
2-4m Bentonite Seal
0-7m Blank 50mmPVC Class 12
7-19m 1mm Slotted50mm PVC Class 12
19-31m Blank 50mmPVC Class 12
1.2-3.6mm GravelPack
31-175m 3mmSlotted 50mm PVCClass 12
Project:Client:
Logged By:
COMPOSITE WELL LOG
Drilled:
Commenced:S
trat Well Completion
Field NotesDepth GraphicLog(mbgl)
Lithological DescriptionNotesDiagram
Easting:
Northing:
Bore No:
Static Water Level:
Elevation:
Remarks:
Area:
Projection:Australia
Completed:
WA 6005
Aq
uif
er
+61 8 93215594
West Perth
85 Havelock St
Method:
Bit Record:
File Ref: Well No:
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
Australian Vanadium Gabanintha
29/05/2019
2/06/2019
Ausdrill North West
KO
12.49 mbtoc
469 mRL
663421
7016066
0.82m Stick up
Orebody
GDA94 zone 50J
19AVWM105
DR 0-84m
DDH 84-178m
241mm(0-84m)/191mm(84-178)
F:\183\2.TECH\LogPlot 19AVWM105
FWS
Airlft yield = <1 L/s
Airlfit yield = <1 L/s
Airlfit yield = <1 L/s
Airlift yield = <1 L/s
Airlift yield = <1 L/s
Airlift yield = 1 L/s, EC =135000 uS/cm
Airlift yield = 1.5 L/s
Airlift yield = 5.5 L/s, EC= 193000 uS/cm
Airlift yield = 9 L/s, EC =225000 uS/cm
Airlift yield = 9 L/s
Airlift yield = 10 L/s, EC= 322000 uS/cm
Airlift yield = 12 L/s
Airlift yield = 6 L/s, EC =232000 uS/cm
Airlift yield = 9 L/s, EC =280000 uS/cm
Duricrust: Red brown, silty sand and gravel.Sand; fine grained. Gravek; ang to sub angclasts up to 30mm. High magnetite content.Large clasts of ultra mafics.
Gravel: Red - brown, silty. Gravel; ang to subang. 20% clay.
Clay: With minor gravel (20%).
Gravel and Clay: 50% gravel; red brown, ang tosub ang. 50% clay.
Saprolite: Red - brown, silty. Puggy clay withgravel. High magnetite content.
Saprock: Weathered igneous rock with minorgravels. Clasts up to 50mm; ang to sub ang.Clay 30%.
Saprock: Red black medium - coarse grained;sub rounded - sub ang. 50% ore 50% gravel.
Saprock: Weathered ignenous rock with minorgravels. Clasts upto 10mm. High magnetitecontent. 40% clay - becoming hard andgreen/yellow @ 70m.
Saprock: Yellow - green- grey stiff mottled clay(70%). Weathered igneous rock/gravel ang - subang. High magnetite content.
Ultra Mafic: Weathered igneous rock (basalt?)purple - dark green. Minor clay increasing @96m. High magentite content. Minor Quartz -ang to sub ang, weathered.
Ore: Black metallic magnetite; ang to sub angfine grained with large clasts upto 30mm (80%).Weathered igneous rock (20%).Limitted Quartzand high sulphide content (pyrite).
Basement: Grey grren weathered ignenous rock.Quartz; ang to sub ang. Minor gravel. Minor clay- stiff. Minor fine grained magnetite.
2-4m Bentonite Seal
0-10m Blank 50mmPVC Class 12
10-16m 1mm Slotted50mm PVC Class12
16-28m Blank 50mmPVC Class 12
1.2-3.6mm GravelPack
28-178m 3mmSlotted 50mm PVCClass 12
Project:Client:
Logged By:
COMPOSITE WELL LOG
Drilled:
Commenced:S
trat Well Completion
Field NotesDepth GraphicLog(mbgl)
Lithological DescriptionNotesDiagram
Easting:
Northing:
Bore No:
Static Water Level:
Elevation:
Remarks:
Area:
Projection:Australia
Completed:
WA 6005
Aq
uif
er
+61 8 93215594
West Perth
85 Havelock St
Method:
Bit Record:
File Ref: Well No:
0
10
20
30
40
50
60
70
80
90
100
110
Australian Vanadium Gabanintha
19/05/2019
23/05/2019
Ausdrill North West
KO
12.30 mbtoc
470.00 mRL
663916
7015608
0.8m Stick up
Orebody
GDA94 zone 50J
19AVWM108
DR 0-34m
DDH 34-100m
241mm(0-34m)/191mm(34-100m)
F:\183\2.TECH\LogPlot 19AVWM108
FWS
Seepage only
Airlfit yield = 2 L/sEC = 12520 uS/cmpH = 7.72
Airlfit yield = 3 L/s
Completed Airlift = 0.6 -0.7 L/sEC = 28800 uS/cm
Duricrust: Red brown silty coarse sand andangular to sub angular gravel rock fragments 2-10 mm
Calcrete: Pinkish brown weathered calcrete andsilty gravels comprised of rock fragments 4-8mmdiameter.
Calcrete: Purplish ivory calcrete with weatheredrock fragments and pebbles.
Ore: Purple brown highly weathered ore bodybasalt, ~50% remnant clay.
Ore: Purple weathered ore body basalt, clay~30%, highly fractured.
Ore: Green grey highly weathered ore body hostrock, friable cuttings in fracture zone.
Ore: Whitish grey fractured and weathered hostcountry rock, highly weathered
Mafic: Grey green competent host country rock,minor fracturing
0-28m Blank 50mmPVC Class 12
23-25m BentoniteSeal
1.2-3.6mm GravelPack
28-100m 1mmSlotted 50mm PVCClass 12
Project:Client:
Logged By:
COMPOSITE WELL LOG
Drilled:
Commenced:S
trat Well Completion
Field NotesDepth GraphicLog(mbgl)
Lithological DescriptionNotesDiagram
Easting:
Northing:
Bore No:
Static Water Level:
Elevation:
Remarks:
Area:
Projection:Australia
Completed:
WA 6005
Aq
uif
er
+61 8 93215594
West Perth
85 Havelock St
Method:
Bit Record:
File Ref: Well No:
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
Australian Vanadium Gabanintha
3/06/2019
9/06/2019
Ausdrill North West
KO
8.32 mbtoc
468 mRL
664733
7014236
0.8m Stick up
Orebody
GDA94 zone 50J
19AVWM112
DR 0-88m
DDH 88-151m
241mm(0-88m)/191(88-151m)
F:\183\2.TECH\LogPlot 19AVWM112
FWS
Airlft yield = <1 L/s, EC= 4300 uS/cm
Airlfit yield = 9 L/s, EC =3420 uS/cm
Airlfit yield = 18 L/s, EC= 2950 uS/cm
Airlift yield = 12 L/s, EC= 2990 uS/cm
No fluid return
Airlift yield = 10 L/s
Airlift yield = 15 L/s, EC= 2810 uS/cm
Airlift yield = 15 L/s, EC= 2560 uS/cm
Airlift yield = 20 L/s
Airlift yield = 4 L/s, EC =250000 uS/cm
Airlift yield = 4 L/s, EC =250000 uS/cm
Airlift yield = 4 L/s, EC =250000 uS/cm
Airlift yield = 4 L/s, EC =255000 uS/cm
Airlift yield = 4 L/s, EC =255000 uS/cm
Duricrust: Red brown silty angular to sub-angular gravels, with minor calcrete clasts up to10mm.
Calcrete: Red brown and cream weathered andfresh calcrete (50%),silty weathered caprockclasts up to 20mm.
Clay: Brownish cream silty clay with finecalcareous sand.
Calcrete: Pale white fine- grained chalky sandwith clasts up to 40mm
Saprock: Red brown and cream medium tocoarse angular to sub- angular silty gravel withlarge clasts of weathered caprock.
Saprock: Red brown to Black angular to sub-angular fine- coarse grained gravels with minormagnetite. Large clasts of weathered caprock.
Saprock: Dark green to purple weatheredigneous; clastsup to 10cm, sub- rounded toangular with 50% angular to sub- angulargravels and minor magnetite.
Saprock: GRAVELLY CLAY Grey brown clay50%, angular to sub- angular gravel with largecaprock clasts and magnetite
Mudstone: Red to dark brown medium to coarsegrained angular to sub- angular gravel; largeclasts of mudstone, silty with high magnetite %,minor angular quartz at 55m.
Ultra Mafic: Grey green weathered basalticigneous rock with calcareous band 70- 72m.Friable above with weathering degreedecreasing with depth.
Ore: Dark grey green competent crystalline orebody, mafic basaltic with iron pyrite at base 136-140m.
Ultra Mafic: Pale grey basalt with quartz richfracture zone 142- 151m.
Basalt: Grey green, angular to sub angularbasalt. Becoming fine grained at 78m. High siltcontent at 56-68m. Magntite/ore; sub angular.
2-4m Bentonite Seal
0-6m Blank 50mmPVC Class 12
10-94m 1mm Slotted50mm PVC Class12
1.2-3.6mm GravelPack
94-142m 3mmSlotted 50mm PVCClass 12
Project:Client:
Logged By:
COMPOSITE WELL LOG
Drilled:
Commenced:S
trat Well Completion
Field NotesDepth GraphicLog(mbgl)
Lithological DescriptionNotesDiagram
Easting:
Northing:
Bore No:
Static Water Level:
Elevation:
Remarks:
Area:
Projection:Australia
Completed:
WA 6005
Aq
uif
er
+61 8 93215594
West Perth
85 Havelock St
Method:
Bit Record:
File Ref: Well No:
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
Australian Vanadium Gabanintha
19/06/2019
27/06/2019
Ausdrill North West
LS
10.32 mbtoc
467 mRL
663427
7015416
0.8m Stick up
Orebody
GDA94 zone 50J
19AVWM114
DR 0-106m
DDH 106-148m
241mm(0-106m)/191(106-148m)
F:\183\2.TECH\LogPlot 19AVWM114
FWS
Airlift yield = 2 L/s, EC =4140 uS/cm
Airlift yield = 5 L/s, EC =4000 uS/cm
Airlfit yield = 3-4 L/s, EC= 3940 uS/cm
Airlift yield = 8-10 L/s,EC = 3780 uS/cm
Airlift yield = 8-10 L/s,EC = 3690 uS/cm
Airlift yield = <1 L/s, EC= 4300 uS/cm
Airlift yield = 7-9 L/s, EC= 5210 uS/cm
Airlift yield = 1.5 L/s, EC= 29000 uS/cm
Airlift yield = 4 L/s
Airlift yield = 2 L/s
Airlift yield = 4 L/s, EC =95200 uS/cm
Airlift yield = 4 L/s
Airlift yield = 4-5 L/s
Airlift yield = 6-7 L/s
Airlift yield = 5-6 L/s, EC= 197000 uS/cm
Airlift yield = 5-6 L/s
Airlift yield = 4-5 L/s
Airlift yield = 5 L/s, EC =254000 uS/cm
Duricrust: Red brown gravel and sand; angular -sub angular, clasts upto 12mm.
Gravel: Red brown gravel (1-4mm) and sand,minor clay. Highly magnetic; angular.
Gravel: Red brown large gravel clasts upto30mm; angular - sub rounded. Highly magnetic.Minor clay at 28m.
Gravel and Clay: Red brown gravel (1-4mm);angular. Clay 60%.
Calcrete: Weathered, White red clay, mix of softand stiff. Minor gravel and magnetite. Large hardcalcrete clasts upto 60mm.
Calcrete: Red white soft weathered calcrete(60%) with large calcrete clasts upto 50mm;angular - sub angular. Gravel; medium - coarsegrained 1-5mm gravel ang-sub angular.
Gravel and Clay: Soft clay (40%). Gravel 1-3mm; angular - sub angular. Minor calcreteclasts upto 3mm. Silty.
Gravel: Red brown gravel; angular - sub angular.Trace of calcrete; sub angular. Minor clays.Large gravel clasts upto 40mm @ 54m.
Gravel: Red brown black fine - medium grainedgravel; angular - sub angular. Minor calcrete.Minor magnetite.
Gravel: Khaki grey/red brown gravel with clastsupto 30mm; angular - sub angular. Minor quartzupto 20mm. Minor calcrete and magnetite.
Gravel: Brown red grey gravel with angular rockclasts upto 40mm. Minor calcrete clasts upto20mm. Minor clay.
Saprock: Khaki grey green gravel; angular - subangula. Rock clasts upto 20mm. Clay (50%).
Saprock: Khaki green gravel; angular - subangular. Weathered rock clasts upto 80mm; subangular.
Ultra Mafic: Green blue weathered igneousangular-subangular, clasts upto 40mm. Minorgravels at 92-96m
Ore: Dark blue weathered basalt angular-subangular. Minor gravels. High ore content. Minorquartz; angular - sub angular.
2-4m Bentonite Seal
0-10m Blank 50mmPVC Class 12
1.2-3.6mm GravelPack
10-46m 1mm Slotted50mm PVC Class12
46-52m Blank 50mmPVC Class 12
52-82m 1mm Slotted50mm PVC Class12
3.6-6.4mm GravelPack
82-148m 3mmSlotted 50mm PVCClass 12
Project:Client:
Logged By:
COMPOSITE WELL LOG
Drilled:
Commenced:S
trat Well Completion
Field NotesDepth GraphicLog(mbgl)
Lithological DescriptionNotesDiagram
Easting:
Northing:
Bore No:
Static Water Level:
Elevation:
Remarks:
Area:
Projection:Australia
Completed:
WA 6005
Aq
uif
er
+61 8 93215594
West Perth
85 Havelock St
Method:
Bit Record:
File Ref: Well No:
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
Australian Vanadium Gabanintha
29/06/2019
8/07/2019
Ausdrill North West
LC
15.64 mbtoc
469 mRL
663418
7016082
0.82m Stick up
Orebody
GDA94 zone 50J
19AVWP001
DR 0-94m
DDH 94-184m
346mm(0-94m)/298mm(94-184m)
F:\183\2.TECH\LogPlot 19AVWP001
FWS
Airlft yield = <1 L/s
Airlfit yield = <1 L/s
Airlfit yield = <1 L/s
Airlift yield = <1 L/s
Airlift yield = <1 L/s
Airlift yield = 1 L/s, EC =135000 mS/cm
Airlift yield = 1.5 L/s
Airlift yield = 5.5 L/s, EC= 193000 mS/cm
Airlift yield = 9 L/s, EC =225000 mS/cm
Airlift yield = 9 L/s
Airlift yield = 10 L/s, EC= 322000 mS/cm
Airlift yield = 12 L/s
Airlift yield = 6 L/s, EC =232000 mS/cm
Airlift yield = 9 L/s, EC =280000 mS/cm
Duricrust: Red brown, silty sand and gravel.Sand; fine grained. Gravek; ang to sub angclasts up to 30mm. High magnetite content.Large clasts of ultra mafics.
Gravel: Red - brown, silty. Gravel; ang to subang. 20% clay.
Clay: With minor gravel (20%).
Gravel and Clay: 50% gravel; red brown, ang tosub ang. 50% clay.
Saprolite: Red - brown, silty. Puggy clay withgravel. High magnetite content.
Saprock: Weathered igneous rock with minorgravels. Clasts up to 50mm; ang to sub ang.Clay 30%.
Saprock: Red black medium - coarse grained;sub rounded - sub ang. 50% ore 50% gravel.
Saprock: Weathered ignenous rock with minorgravels. Clasts upto 10mm. High magnetitecontent. 40% clay - becoming hard andgreen/yellow @ 70m.
Saprock: Yellow - green- grey stiff mottled clay(70%). Weathered igneous rock/gravel ang - subang. High magnetite content.
Ultra Mafic: Weathered igneous rock (basalt?)purple - dark green. Minor clay increasing @96m. High magentite content. Minor Quartz -ang to sub ang, weathered.
Ore: Black metallic magnetite; ang to sub angfine grained with large clasts upto 30mm (80%).Weathered igneous rock (20%).Limitted Quartzand high sulphide content (pyrite).
Basement: Grey green weathered ignenousrock. Quartz; ang to sub ang. Minor gravel.Minor clay - stiff. Minor fine grained magnetite.
2-4m Bentonite Seal
0-94m Blank 200mmPVC Class 12
1.2-3.6mm GravelPack
94-184m 1mmSlotted 200mm PVCClass 12
Project:Client:
Logged By:
COMPOSITE WELL LOG
Drilled:
Commenced:S
trat Well Completion
Field NotesDepth GraphicLog(mbgl)
Lithological DescriptionNotesDiagram
Easting:
Northing:
Bore No:
Static Water Level:
Elevation:
Remarks:
Area:
Projection:Australia
Completed:
WA 6005
Aq
uif
er
+61 8 93215594
West Perth
85 Havelock St
Method:
Bit Record:
File Ref: Well No:
0
10
20
30
Australian Vanadium Gabanintha
10/07/2019
11/07/2019
Ausdrill North West
LC
8.15 mbtoc
464 mRL
663545
7011754
0.41m Stick up
Palaeochannel
GDA94 zone 50J
19AVWP002
DR 0-28m
346mm
F:\183\2.TECH\LogPlot 19AVWP002
Airlift = 15 L/s, EC =13240 mS/cm, pH =7.74
Airlift = 20 L/s, EC =13790 mS/cm, pH =7.71
Completion Airlift = 15L/s
Soil: Surficial soil with rock fragments. Redbrown, angluar caprock and silty soils.
Gravel: Sandy. Tan/khaki clay, silt and rockfragments 10-40mm.
Calcrete: Ivory calcrete with brown coarse sandand gravel 1-8mm. CaCO3 80%.
Gravel and Sand: Brown sandy gravel and clay(30%). Rock fragments 10-25mm.
Accredited for compliance with ISO/IEC 17025 - Testing. NATA accredited laboratory 2562(898/20210).
For determination of soluble metals, filtered sample was not received so samples were laboratory filtered on receipt. This may give soluble metals
results that do not represent the concentrations present at the time of sampling.
Metals: Dissolved Na: Spike recovery failed acceptance criteria due to the presence of significant concentration of analyte (i.e. the concentration
of analyte exceeds the spike level).
Ionic Balance: #4 is outside acceptance criteria due sample heterogeneity.
COMMENTS
Hue Thanh Ly
Metals Team Leader
Mary Ann Ola-A
Inorganics Team Leader
SIGNATORIES
SGS Australia Pty Ltd
ABN 44 000 964 278
Environment, Health and Safety 28 Reid Rd
PO Box 32
Perth Airport WA 6105
Welshpool WA 6983
Australia
Australia
t +61 8 9373 3500
f +61 8 9373 3556
www.sgs.com.au
Member of the SGS Group
Page 1 of 710-August-2018
PE127757 R0ANALYTICAL REPORT
PE127757.001
Water
8/7/18 11:00
GDH904
PE127757.002
Water
2/8/18 11:30
GDH911
PE127757.003
Water
1/8/18 8:00
GDH912
PE127757.004
Water
2/8/18 10:00
GDH914
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
pH in water Method: AN101 Tested: 6/8/2018
pH** No unit 0.1 7.4 7.7 7.7 7.7
Conductivity and TDS by Calculation - Water Method: AN106 Tested: 6/8/2018
Conductivity @ 25 C µS/cm 2 31000 4400 9400 6700
Alkalinity Method: AN135 Tested: 6/8/2018
Total Alkalinity as CaCO3 mg/L 5 97 230 220 180
Carbonate Alkalinity as CO3 mg/L 1 <1 <1 <1 <1
Bicarbonate Alkalinity as HCO3 mg/L 5 120 280 270 220
Chloride by Discrete Analyser in Water Method: AN274 Tested: 6/8/2018
Chloride, Cl mg/L 1 10000 1100 2800 1900
Sulfate in water Method: AN275 Tested: 6/8/2018
Sulfate, SO4 mg/L 1 2200 310 660 580
Metals in Water (Dissolved) by ICPOES Method: AN320 Tested: 7/8/2018
Calcium, Ca mg/L 0.2 440 93 92 94
Magnesium, Mg mg/L 0.1 1100 160 250 170
Potassium, K mg/L 0.1 230 11 55 25
Sodium, Na mg/L 0.5 4700 570 1600 750
Page 2 of 710-August-2018
PE127757 R0ANALYTICAL REPORT
PE127757.005
Water
1/8/18 11:00
GRC161
PE127757.006
Water
2/8/18 7:45
GRC0169
PE127757.007
Water
1/8/18 13:00
GRC0180
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
pH in water Method: AN101 Tested: 6/8/2018
pH** No unit 0.1 7.8 7.8 7.9
Conductivity and TDS by Calculation - Water Method: AN106 Tested: 6/8/2018
Conductivity @ 25 C µS/cm 2 5200 2300 2600
Alkalinity Method: AN135 Tested: 6/8/2018
Total Alkalinity as CaCO3 mg/L 5 180 240 210
Carbonate Alkalinity as CO3 mg/L 1 <1 <1 <1
Bicarbonate Alkalinity as HCO3 mg/L 5 220 290 260
Chloride by Discrete Analyser in Water Method: AN274 Tested: 6/8/2018
Chloride, Cl mg/L 1 1400 470 550
Sulfate in water Method: AN275 Tested: 6/8/2018
Sulfate, SO4 mg/L 1 390 140 180
Metals in Water (Dissolved) by ICPOES Method: AN320 Tested: 7/8/2018
Calcium, Ca mg/L 0.2 110 77 62
Magnesium, Mg mg/L 0.1 180 87 85
Potassium, K mg/L 0.1 25 13 12
Sodium, Na mg/L 0.5 690 260 350
Page 3 of 710-August-2018
PE127757 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Alkalinity Method: ME-(AU)-[ENV]AN135
MB DUP %RPD LCS
%Recovery
Total Alkalinity as CaCO3 LB149123 mg/L 5 <5 1 - 5% 99%
Carbonate Alkalinity as CO3 LB149123 mg/L 1 <1
Bicarbonate Alkalinity as HCO3 LB149123 mg/L 5 <5
LORUnits Parameter QC
Reference
Chloride by Discrete Analyser in Water Method: ME-(AU)-[ENV]AN274
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Sulfate in water Method: ME-(AU)-[ENV]AN275
MB DUP %RPD LCS
%Recovery
MS
%Recovery
Sulfate, SO4 LB149034 mg/L 1 <1 0% 99% 95 - 96%
LORUnits Parameter QC
Reference
Page 5 of 710-August-2018
PE127757 R0
METHOD METHODOLOGY SUMMARY
METHOD SUMMARY
pH in Soil Sludge Sediment and Water: pH is measured electrometrically using a combination electrode (glass plus
reference electrode) and is calibrated against 3 buffers purchased commercially. For soils, an extract with water is
made at a ratio of 1:5 and the pH determined and reported on the extract. Reference APHA 4500-H+.
AN101
Conductivity and TDS by Calculation: Conductivity is measured by meter with temperature compensation and is
calibrated against a standard solution of potassium chloride. Conductivity is generally reported as µmhos/cm or
µS/cm @ 25°C. For soils, an extract with water is made at a ratio of 1:5 and the EC determined and reported on
the extract, or calculated back to the as-received sample. Total Dissolved Salts can be estimated from conductivity
using a conversion factor, which for natural waters, is in the range 0.55 to 0.75. SGS use 0.6. Reference APHA
2510 B.
AN106
Salinity may be calculated in terms of NaCl from the sample conductivity. This assumes all soluble salts present,
measured by the conductivity, are present as NaCl.
AN106
This method is used to calculation the balance of major Anions and Cations in water samples and converts major
ion concentration to milliequivalents and then summed. Anions sum and Cation sum is calculated as a difference
and expressed as a percentage.
AN121
The sum of cations and anions in mg/L may also be reported. This sums Na, K, Ca, Mg, NH3, Fe, Cl, Total
Alkalinity, SO4 and NO3.
AN121
Alkalinity (and forms of) by Titration: The sample is titrated with standard acid to pH 8.3 (P titre) and pH 4.5 (T titre)
and permanent and/or total alkalinity calculated. The results are expressed as equivalents of calcium carbonate or
recalculated as bicarbonate, carbonate and hydroxide. Reference APHA 2320. Internal Reference AN135
AN135
Chloride by Aquakem DA: Chloride reacts with mercuric thiocyanate forming a mercuric chloride complex. In the
presence of ferric iron, highly coloured ferric thiocyanate is formed which is proportional to the chloride
concentration. Reference APHA 4500Cl-
AN274
sulfate by Aquakem DA: sulfate is precipitated in an acidic medium with barium chloride. The resulting turbidity is
measured photometrically at 405nm and compared with standard calibration solutions to determine the sulfate
concentration in the sample. Reference APHA 4500-SO42-. Internal reference AN275.
AN275
Metals by ICP-OES: Samples are preserved with 10% nitric acid for a wide range of metals and some non-metals.
This solution is measured by Inductively Coupled Plasma. Solutions are aspirated into an argon plasma at
8000-10000K and emit characteristic energy or light as a result of electron transitions through unique energy
levels. The emitted light is focused onto a diffraction grating where it is separated into components .
AN320
Photomultipliers or CCDs are used to measure the light intensity at specific wavelengths. This intensity is directly
proportional to concentration. Corrections are required to compensate for spectral overlap between elements.
Reference APHA 3120 B.
AN320
Free and Total Carbon Dioxide may be calculated using alkalinity forms only when the samples TDS is <500mg/L.
If TDS is >500mg/L free or total carbon dioxide cannot be reported . APHA4500CO2 D.
Calculation
Page 6 of 710-August-2018
PE127757 R0
Samples analysed as received.
Solid samples expressed on a dry weight basis.
Where "Total" analyte groups are reported (for example, Total PAHs, Total OC Pesticides) the total will be calculated as the sum of the individual
analytes, with those analytes that are reported as <LOR being assumed to be zero. The summed (Total) limit of reporting is calcuated by summing
the individual analyte LORs and dividing by two. For example, where 16 individual analytes are being summed and each has an LOR of 0.1 mg/kg,
the "Totals" LOR will be 1.6 / 2 (0.8 mg/kg). Where only 2 analytes are being summed, the " Total" LOR will be the sum of those two LORs.
Some totals may not appear to add up because the total is rounded after adding up the raw values.
If reported, measurement uncertainty follow the ± sign after the analytical result and is expressed as the expanded uncertainty calculated using a
coverage factor of 2, providing a level of confidence of approximately 95%, unless stated otherwise in the comments section of this report.
Results reported for samples tested under test methods with codes starting with ARS -SOP, radionuclide or gross radioactivity concentrations are
expressed in becquerel (Bq) per unit of mass or volume or per wipe as stated on the report. Becquerel is the SI unit for activity and equals one
nuclear transformation per second.
Note that in terms of units of radioactivity:
a. 1 Bq is equivalent to 27 pCi
b. 37 MBq is equivalent to 1 mCi
For results reported for samples tested under test methods with codes starting with ARS -SOP, less than (<) values indicate the detection limit for
each radionuclide or parameter for the measurement system used. The respective detection limits have been calculated in accordance with ISO
11929.
The QC criteria are subject to internal review according to the SGS QAQC plan and may be provided on request or alternatively can be found here :
Accredited for compliance with ISO/IEC 17025 - Testing. NATA accredited laboratory 2562(898/20210).
For determination of soluble metals, filtered sample was not received so samples were laboratory subsampled and filtered on receipt. This may
give soluble metals results that do not represent the concentrations present at the time of sampling.
Metals: LORs raised due to high conductivity.
The upper limit for Conductivity in Water is 100,000 uS/cm. Any result above this is an estimate. This will also cause the TDS on EC ratio to bias
high.
COMMENTS
Hue Thanh Ly
Metals Team Leader
Louise Hope
Laboratory Technician
SIGNATORIES
SGS Australia Pty Ltd
ABN 44 000 964 278
Environment, Health and Safety 28 Reid Rd
PO Box 32
Perth Airport WA 6105
Welshpool WA 6983
Australia
Australia
t +61 8 9373 3500
f +61 8 9373 3556
www.sgs.com.au
Member of the SGS Group
Page 1 of 717-May-2019
PE134594 R0ANALYTICAL REPORT
PE134594.001
Water
27 Apr 2019
19AVWM01
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
pH in water Method: AN101 Tested: 2/5/2019
pH** pH Units - 7.2
Conductivity and TDS by Calculation - Water Method: AN106 Tested: 2/5/2019
Conductivity @ 25 C µS/cm 2 180000
Total Dissolved Solids (TDS) in water Method: AN113 Tested: 7/5/2019
Total Dissolved Solids Dried at 175-185°C mg/L 10 140000
Alkalinity Method: AN135 Tested: 2/5/2019
Total Alkalinity as CaCO3 mg/L 5 47
Carbonate Alkalinity as CO3 mg/L 1 <1
Bicarbonate Alkalinity as HCO3 mg/L 5 58
Chloride by Discrete Analyser in Water Method: AN274 Tested: 14/5/2019
Chloride, Cl mg/L 1 88000
Sulfate in water Method: AN275 Tested: 16/5/2019
Sulfate, SO4 mg/L 1 19000
Page 2 of 717-May-2019
PE134594 R0ANALYTICAL REPORT
PE134594.001
Water
27 Apr 2019
19AVWM01
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
Metals in Water (Dissolved) by ICPOES Method: AN320 Tested: 3/5/2019
Calcium, Ca mg/L 0.2 840
Magnesium, Mg mg/L 0.1 6400
Potassium, K mg/L 0.1 2800
Sodium, Na mg/L 0.5 46000
Page 3 of 717-May-2019
PE134594 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Alkalinity Method: ME-(AU)-[ENV]AN135
MB DUP %RPD LCS
%Recovery
Total Alkalinity as CaCO3 LB159059 mg/L 5 <5 7% 99%
Carbonate Alkalinity as CO3 LB159059 mg/L 1 <1
Bicarbonate Alkalinity as HCO3 LB159059 mg/L 5 <5
LORUnits Parameter QC
Reference
Chloride by Discrete Analyser in Water Method: ME-(AU)-[ENV]AN274
Metals in Water (Dissolved) by ICPOES Method: ME-(AU)-[ENV]AN320
MB DUP %RPD LCS
%Recovery
MS
%Recovery
Calcium, Ca LB159002 mg/L 0.2 <0.2 1% 97% 91%
Magnesium, Mg LB159002 mg/L 0.1 <0.1 0% 97% 90%
Potassium, K LB159002 mg/L 0.1 <0.1 0% 96% 84%
Sodium, Na LB159002 mg/L 0.5 <0.5 1% 100% 85%
LORUnits Parameter QC
Reference
pH in water Method: ME-(AU)-[ENV]AN101
MB LCS
%Recovery
pH** LB159107 pH Units - 5.7 100%
LORUnits Parameter QC
Reference
Page 4 of 717-May-2019
PE134594 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Accredited for compliance with ISO/IEC 17025 - Testing. NATA accredited laboratory 2562(898/20210).
For determination of soluble metals, filtered sample was not received so samples were laboratory filtered on receipt. This may give soluble metals
results that do not represent the concentrations present at the time of sampling.
COMMENTS
Hue Thanh Ly
Metals Team Leader
Louise Hope
Laboratory Technician
Mary Ann Ola-A
Inorganics Team Leader
SIGNATORIES
SGS Australia Pty Ltd
ABN 44 000 964 278
Environment, Health and Safety 28 Reid Rd
PO Box 32
Perth Airport WA 6105
Welshpool WA 6983
Australia
Australia
t +61 8 9373 3500
f +61 8 9373 3556
www.sgs.com.au
Member of the SGS Group
Page 1 of 728-May-2019
PE134996 R0ANALYTICAL REPORT
PE134996.001
Water
14/5/19 12:15
19AVWM02S
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
pH in water Method: AN101 Tested: 17/5/2019
pH** No unit 0.1 8.0
Conductivity and TDS by Calculation - Water Method: AN106 Tested: 17/5/2019
Conductivity @ 25 C µS/cm 2 12000
Total Dissolved Solids (TDS) in water Method: AN113 Tested: 17/5/2019
Total Dissolved Solids Dried at 175-185°C mg/L 10 7200
Alkalinity Method: AN135 Tested: 17/5/2019
Total Alkalinity as CaCO3 mg/L 5 190
Carbonate Alkalinity as CO3 mg/L 1 <1
Bicarbonate Alkalinity as HCO3 mg/L 5 230
Chloride by Discrete Analyser in Water Method: AN274 Tested: 24/5/2019
Chloride, Cl mg/L 1 3500
Sulfate in water Method: AN275 Tested: 24/5/2019
Sulfate, SO4 mg/L 1 800
Page 2 of 728-May-2019
PE134996 R0ANALYTICAL REPORT
PE134996.001
Water
14/5/19 12:15
19AVWM02S
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
Metals in Water (Dissolved) by ICPOES Method: AN320 Tested: 20/5/2019
Calcium, Ca mg/L 0.2 180
Magnesium, Mg mg/L 0.1 390
Potassium, K mg/L 0.1 67
Sodium, Na mg/L 0.5 1600
Page 3 of 728-May-2019
PE134996 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Alkalinity Method: ME-(AU)-[ENV]AN135
MB DUP %RPD LCS
%Recovery
Total Alkalinity as CaCO3 LB159793 mg/L 5 <5 0% 102%
Carbonate Alkalinity as CO3 LB159793 mg/L 1 <1
Bicarbonate Alkalinity as HCO3 LB159793 mg/L 5 <5
LORUnits Parameter QC
Reference
Chloride by Discrete Analyser in Water Method: ME-(AU)-[ENV]AN274
Conductivity and TDS by Calculation - Water Method: ME-(AU)-[ENV]AN106
MB DUP %RPD LCS
%Recovery
Conductivity @ 25 C LB159762 µS/cm 2 <2 0% 104%
LORUnits Parameter QC
Reference
Metals in Water (Dissolved) by ICPOES Method: ME-(AU)-[ENV]AN320
MB DUP %RPD LCS
%Recovery
MS
%Recovery
Calcium, Ca LB159589 mg/L 0.2 <0.2 1% 101% 102%
Magnesium, Mg LB159589 mg/L 0.1 <0.1 0% 101% 101%
Potassium, K LB159589 mg/L 0.1 <0.1 3% 96% 98%
Sodium, Na LB159589 mg/L 0.5 <0.5 2% 98% 98%
LORUnits Parameter QC
Reference
pH in water Method: ME-(AU)-[ENV]AN101
MB DUP %RPD LCS
%Recovery
pH** LB159762 No unit 0.1 5.6 2% 101%
LORUnits Parameter QC
Reference
Page 4 of 728-May-2019
PE134996 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Accredited for compliance with ISO/IEC 17025 - Testing. NATA accredited laboratory 2562(898/20210).
Metals bottles not received for samples 3 4 5. Subsampled from unpreserved
For determination of soluble metals, filtered sample was not received so samples were laboratory filtered on receipt. This may give soluble metals
results that do not represent the concentrations present at the time of sampling.
Metals: LORs raised due to high conductivity.
The upper limit for Conductivity in Water is 100,000 uS/cm. Any result above this is an estimate. This will also cause the TDS on EC ratio to bias
high.
COMMENTS
Louise Hope
Laboratory Technician
Mary Ann Ola-A
Inorganics Team Leader
Sanaa Hussain
Chemist
SIGNATORIES
SGS Australia Pty Ltd
ABN 44 000 964 278
Environment, Health and Safety 28 Reid Rd
PO Box 32
Perth Airport WA 6105
Welshpool WA 6983
Australia
Australia
t +61 8 9373 3500
f +61 8 9373 3556
www.sgs.com.au
Member of the SGS Group
Page 1 of 913-June-2019
PE135457 R0ANALYTICAL REPORT
PE135457.001
Water
15 May 2019
19AVWM03
PE135457.002
Water
18 May 2019
19AVWM04
PE135457.003
Water
29 May 2019
19AVWM104
PE135457.004
Water
23 May 2019
19AVWM108
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
pH in water Method: AN101 Tested: 6/6/2019
pH** pH Units 0.1 8.2 7.9 7.3 8.1
Conductivity and TDS by Calculation - Water Method: AN106 Tested: 6/6/2019
Conductivity @ 25 C µS/cm 2 9200 19000 170000 29000
Total Dissolved Solids (TDS) in water Method: AN113 Tested: 7/6/2019
Total Dissolved Solids Dried at 175-185°C mg/L 10 5000 12000 160000 18000
Alkalinity Method: AN135 Tested: 6/6/2019
Bicarbonate Alkalinity as HCO3 mg/L 5 300 140 100 230
Carbonate Alkalinity as CO3 mg/L 5 <5 <5 <5 <5
Hydroxide Alkalinity as OH mg/L 5 <5 <5 <5 <5
Total Alkalinity as CaCO3 mg/L 5 240 110 83 190
Sulfate in water Method: AN275 Tested: 12/6/2019
Sulfate, SO4 mg/L 1 460 1100 14000 2000
Chloride by Discrete Analyser in Water Method: AN274 Tested: 12/6/2019
Chloride, Cl mg/L 1 2700 7000 84000 9200
Page 2 of 913-June-2019
PE135457 R0ANALYTICAL REPORT
PE135457.001
Water
15 May 2019
19AVWM03
PE135457.002
Water
18 May 2019
19AVWM04
PE135457.003
Water
29 May 2019
19AVWM104
PE135457.004
Water
23 May 2019
19AVWM108
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
Metals in Water (Dissolved) by ICPOES Method: AN320 Tested: 10/6/2019
Calcium, Ca mg/L 0.2 110 330 760 330
Magnesium, Mg mg/L 0.1 220 560 5700 890
Potassium, K mg/L 0.1 66 120 2200 160
Sodium, Na mg/L 0.5 1500 3100 43000 4500
Page 3 of 913-June-2019
PE135457 R0ANALYTICAL REPORT
PE135457.005
Water
03 Jun 2019
19AVWM105
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
pH in water Method: AN101 Tested: 6/6/2019
pH** pH Units 0.1 7.2
Conductivity and TDS by Calculation - Water Method: AN106 Tested: 6/6/2019
Conductivity @ 25 C µS/cm 2 180000
Total Dissolved Solids (TDS) in water Method: AN113 Tested: 7/6/2019
Total Dissolved Solids Dried at 175-185°C mg/L 10 170000
Alkalinity Method: AN135 Tested: 6/6/2019
Bicarbonate Alkalinity as HCO3 mg/L 5 82
Carbonate Alkalinity as CO3 mg/L 5 <5
Hydroxide Alkalinity as OH mg/L 5 <5
Total Alkalinity as CaCO3 mg/L 5 67
Sulfate in water Method: AN275 Tested: 12/6/2019
Sulfate, SO4 mg/L 1 15000
Chloride by Discrete Analyser in Water Method: AN274 Tested: 12/6/2019
Chloride, Cl mg/L 1 86000
Page 4 of 913-June-2019
PE135457 R0ANALYTICAL REPORT
PE135457.005
Water
03 Jun 2019
19AVWM105
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
Metals in Water (Dissolved) by ICPOES Method: AN320 Tested: 10/6/2019
Calcium, Ca mg/L 0.2 760
Magnesium, Mg mg/L 0.1 6000
Potassium, K mg/L 0.1 2600
Sodium, Na mg/L 0.5 47000
Page 5 of 913-June-2019
PE135457 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Alkalinity Method: ME-(AU)-[ENV]AN135
MB DUP %RPD LCS
%Recovery
Bicarbonate Alkalinity as HCO3 LB160459 mg/L 5 <5
LB160460 mg/L 5 <5
Carbonate Alkalinity as CO3 LB160459 mg/L 5 <5
LB160460 mg/L 5 <5
Hydroxide Alkalinity as OH LB160459 mg/L 5 <5
LB160460 mg/L 5 <5
Total Alkalinity as CaCO3 LB160459 mg/L 5 <5 1 - 2% 104%
LB160460 mg/L 5 <5 0 - 1% 102%
LORUnits Parameter QC
Reference
Chloride by Discrete Analyser in Water Method: ME-(AU)-[ENV]AN274
Metals in Water (Dissolved) by ICPOES Method: ME-(AU)-[ENV]AN320
MB DUP %RPD LCS
%Recovery
MS
%Recovery
Calcium, Ca LB160353 mg/L 0.2 <0.2 0% 106% 103%
Magnesium, Mg LB160353 mg/L 0.1 <0.1 1% 106% 104%
Potassium, K LB160353 mg/L 0.1 <0.1 0% 105% 99%
Sodium, Na LB160353 mg/L 0.5 <0.5 0% 104% 92%
LORUnits Parameter QC
Reference
pH in water Method: ME-(AU)-[ENV]AN101
MB DUP %RPD LCS
%Recovery
pH** LB160451 pH Units 0.1 5.5 0% 101%
LB160452 pH Units 0.1 5.6 - 5.7 0% 100%
LORUnits Parameter QC
Reference
Page 6 of 913-June-2019
PE135457 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Accredited for compliance with ISO/IEC 17025 - Testing. NATA accredited laboratory 2562(898/20210).
COMMENTS
Louise Hope
Laboratory Technician
Mary Ann Ola-A
Inorganics Team Leader
Sanaa Hussain
Chemist
SIGNATORIES
SGS Australia Pty Ltd
ABN 44 000 964 278
Environment, Health and Safety 28 Reid Rd
PO Box 32
Perth Airport WA 6105
Welshpool WA 6983
Australia
Australia
t +61 8 9373 3500
f +61 8 9373 3556
www.sgs.com.au
Member of the SGS Group
Page 1 of 708-July-2019
PE136072 R0ANALYTICAL REPORT
PE136072.001
Water
15 Jun 2019
DEB01R
PE136072.002
Water
15 Jun 2019
DEB10
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
pH in water Method: AN101 Tested: 2/7/2019
pH** pH Units 0.1 7.8 7.9
Conductivity and TDS by Calculation - Water Method: AN106 Tested: 2/7/2019
Conductivity @ 25 C µS/cm 2 16000 2800
Total Dissolved Solids (TDS) in water Method: AN113 Tested: 3/7/2019
Total Dissolved Solids Dried at 175-185°C mg/L 10 9400 1500
Alkalinity Method: AN135 Tested: 2/7/2019
Bicarbonate Alkalinity as HCO3 mg/L 5 260 310
Carbonate Alkalinity as CO3 mg/L 5 <5 <5
Hydroxide Alkalinity as OH mg/L 5 <5 <5
Total Alkalinity as CaCO3 mg/L 5 210 260
Sulfate in water Method: AN275 Tested: 3/7/2019
Sulfate, SO4 mg/L 1 170 1100
Chloride by Discrete Analyser in Water Method: AN274 Tested: 3/7/2019
Chloride, Cl mg/L 1 550 4400
Page 2 of 708-July-2019
PE136072 R0ANALYTICAL REPORT
PE136072.001
Water
15 Jun 2019
DEB01R
PE136072.002
Water
15 Jun 2019
DEB10
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
Metals in Water (Dissolved) by ICPOES Method: AN320 Tested: 3/7/2019
Calcium, Ca mg/L 0.2 160 81
Magnesium, Mg mg/L 0.1 450 110
Potassium, K mg/L 0.1 130 3.7
Sodium, Na mg/L 0.5 2700 310
Page 3 of 708-July-2019
PE136072 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Alkalinity Method: ME-(AU)-[ENV]AN135
MB DUP %RPD LCS
%Recovery
Bicarbonate Alkalinity as HCO3 LB161314 mg/L 5 <5
Carbonate Alkalinity as CO3 LB161314 mg/L 5 <5
Hydroxide Alkalinity as OH LB161314 mg/L 5 <5
Total Alkalinity as CaCO3 LB161314 mg/L 5 <5 1% 104%
LORUnits Parameter QC
Reference
Chloride by Discrete Analyser in Water Method: ME-(AU)-[ENV]AN274
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Accredited for compliance with ISO/IEC 17025 - Testing. NATA accredited laboratory 2562(898/20210).
For determination of soluble metals, filtered sample was not received so samples were laboratory filtered on receipt. This may give soluble metals
results that do not represent the concentrations present at the time of sampling.
Metals: LORs raised due to high conductivity.
The upper limit for Conductivity in Water is 100,000 uS/cm. Any result above this is an estimate. This will also cause the TDS on EC ratio to bias
high.
COMMENTS
Louise Hope
Laboratory Technician
Mary Ann Ola-A
Inorganics Team Leader
Sanaa Hussain
Chemist
SIGNATORIES
SGS Australia Pty Ltd
ABN 44 000 964 278
Environment, Health and Safety 28 Reid Rd
PO Box 32
Perth Airport WA 6105
Welshpool WA 6983
Australia
Australia
t +61 8 9373 3500
f +61 8 9373 3556
www.sgs.com.au
Member of the SGS Group
Page 1 of 729-July-2019
PE136531 R0ANALYTICAL REPORT
PE136531.001
Water
08 Jul 2019
19AVWP001
PE136531.002
Water
13 Jul 2019
19AVWP002
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
pH in water Method: AN101 Tested: 22/7/2019
pH** pH Units 0.1 7.3 7.9
Conductivity and TDS by Calculation - Water Method: AN106 Tested: 22/7/2019
Conductivity @ 25 C µS/cm 2 170000 15000
Total Dissolved Solids (TDS) in water Method: AN113 Tested: 24/7/2019
Total Dissolved Solids Dried at 175-185°C mg/L 10 120000 8300
Alkalinity Method: AN135 Tested: 22/7/2019
Bicarbonate Alkalinity as HCO3 mg/L 5 93 130
Carbonate Alkalinity as CO3 mg/L 5 <5 <5
Hydroxide Alkalinity as OH mg/L 5 <5 <5
Total Alkalinity as CaCO3 mg/L 5 76 110
Sulfate in water Method: AN275 Tested: 25/7/2019
Sulfate, SO4 mg/L 1 18000 850
Chloride by Discrete Analyser in Water Method: AN274 Tested: 25/7/2019
Chloride, Cl mg/L 1 76000 4200
Page 2 of 729-July-2019
PE136531 R0ANALYTICAL REPORT
PE136531.001
Water
08 Jul 2019
19AVWP001
PE136531.002
Water
13 Jul 2019
19AVWP002
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
Metals in Water (Dissolved) by ICPOES Method: AN320 Tested: 23/7/2019
Calcium, Ca mg/L 0.2 680 250
Magnesium, Mg mg/L 0.1 5300 400
Potassium, K mg/L 0.1 2500 94
Sodium, Na mg/L 0.5 43000 2300
Page 3 of 729-July-2019
PE136531 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Alkalinity Method: ME-(AU)-[ENV]AN135
MB DUP %RPD LCS
%Recovery
Bicarbonate Alkalinity as HCO3 LB161953 mg/L 5 <5
Carbonate Alkalinity as CO3 LB161953 mg/L 5 <5
Hydroxide Alkalinity as OH LB161953 mg/L 5 <5
Total Alkalinity as CaCO3 LB161953 mg/L 5 <5 0 - 2% 101%
LORUnits Parameter QC
Reference
Chloride by Discrete Analyser in Water Method: ME-(AU)-[ENV]AN274
Conductivity and TDS by Calculation - Water Method: ME-(AU)-[ENV]AN106
MB DUP %RPD LCS
%Recovery
Conductivity @ 25 C LB162006 µS/cm 2 <2 1% 101%
LORUnits Parameter QC
Reference
Metals in Water (Dissolved) by ICPOES Method: ME-(AU)-[ENV]AN320
MB DUP %RPD LCS
%Recovery
MS
%Recovery
Calcium, Ca LB161925 mg/L 0.2 <0.2 102% 102%
Magnesium, Mg LB161925 mg/L 0.1 <0.1 1% 101% 101%
Potassium, K LB161925 mg/L 0.1 <0.1 99% 102%
Sodium, Na LB161925 mg/L 0.5 <0.5 106% 106%
LORUnits Parameter QC
Reference
pH in water Method: ME-(AU)-[ENV]AN101
MB DUP %RPD LCS
%Recovery
pH** LB162006 pH Units 0.1 5.6 - 5.7 0% 100%
LORUnits Parameter QC
Reference
Page 4 of 729-July-2019
PE136531 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Accredited for compliance with ISO/IEC 17025 - Testing. NATA accredited laboratory 2562(898/20210).
For determination of soluble metals, filtered sample was not received so samples were laboratory filtered on receipt. This may give soluble metals
results that do not represent the concentrations present at the time of sampling.
The upper limit for Conductivity in Water is 100,000 uS/cm. Any result above this is an estimate. This will also cause the TDS on EC ratio to bias
high.
Metals: LORs raised due to high conductivity.
COMMENTS
Louise Hope
Laboratory Technician
Mary Ann Ola-A
Inorganics Team Leader
Sanaa Hussain
Chemist
SIGNATORIES
SGS Australia Pty Ltd
ABN 44 000 964 278
Environment, Health and Safety 28 Reid Rd
PO Box 32
Perth Airport WA 6105
Welshpool WA 6983
Australia
Australia
t +61 8 9373 3500
f +61 8 9373 3556
www.sgs.com.au
Member of the SGS Group
Page 1 of 723-August-2019
PE137221 R0ANALYTICAL REPORT
PE137221.001
Water
12/8/19 8:30
19AVWP001
PE137221.002
Water
5/8/19 13:00
19AVWP002
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
pH in water Method: AN101 Tested: 16/8/2019
pH** pH Units 0.1 7.0 7.0
Conductivity and TDS by Calculation - Water Method: AN106 Tested: 16/8/2019
Conductivity @ 25 C µS/cm 2 150000 150000
Alkalinity Method: AN135 Tested: 16/8/2019
Bicarbonate Alkalinity as HCO3 mg/L 5 100 110
Carbonate Alkalinity as CO3 mg/L 5 <5 <5
Hydroxide Alkalinity as OH mg/L 5 <5 <5
Total Alkalinity as CaCO3 mg/L 5 83 86
Sulfate in water Method: AN275 Tested: 22/8/2019
Sulfate, SO4 mg/L 1 16000 17000
Chloride by Discrete Analyser in Water Method: AN274 Tested: 22/8/2019
Chloride, Cl mg/L 1 75000 77000
Metals in Water (Dissolved) by ICPOES Method: AN320 Tested: 20/8/2019
Calcium, Ca mg/L 0.2 690 730
Magnesium, Mg mg/L 0.1 4900 5200
Potassium, K mg/L 0.1 2100 2300
Sodium, Na mg/L 0.5 41000 41000
Page 2 of 723-August-2019
PE137221 R0ANALYTICAL REPORT
PE137221.001
Water
12/8/19 8:30
19AVWP001
PE137221.002
Water
5/8/19 13:00
19AVWP002
Parameter LORUnits
Sample Number
Sample Matrix
Sample Date
Sample Name
Total Dissolved Solids (TDS) in water Method: AN113 Tested: 20/8/2019
Total Dissolved Solids Dried at 175-185°C mg/L 10 150000 150000
Page 3 of 723-August-2019
PE137221 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Alkalinity Method: ME-(AU)-[ENV]AN135
MB DUP %RPD LCS
%Recovery
Bicarbonate Alkalinity as HCO3 LB162929 mg/L 5 <5
Carbonate Alkalinity as CO3 LB162929 mg/L 5 <5
Hydroxide Alkalinity as OH LB162929 mg/L 5 <5
Total Alkalinity as CaCO3 LB162929 mg/L 5 <5 1 - 2% 99 - 101%
LORUnits Parameter QC
Reference
Chloride by Discrete Analyser in Water Method: ME-(AU)-[ENV]AN274
Conductivity and TDS by Calculation - Water Method: ME-(AU)-[ENV]AN106
MB DUP %RPD LCS
%Recovery
Conductivity @ 25 C LB162934 µS/cm 2 <2 0% 101%
LORUnits Parameter QC
Reference
Metals in Water (Dissolved) by ICPOES Method: ME-(AU)-[ENV]AN320
MB DUP %RPD LCS
%Recovery
MS
%Recovery
Calcium, Ca LB162965 mg/L 0.2 <0.2 0 - 1% 95% 88%
Magnesium, Mg LB162965 mg/L 0.1 <0.1 1% 93% 90%
Potassium, K LB162965 mg/L 0.1 <0.1 1% 94% 87%
Sodium, Na LB162965 mg/L 0.5 <0.5 1% 97% 95%
LORUnits Parameter QC
Reference
pH in water Method: ME-(AU)-[ENV]AN101
MB DUP %RPD LCS
%Recovery
pH** LB162934 pH Units 0.1 5.7 0% 101%
LORUnits Parameter QC
Reference
Page 4 of 723-August-2019
PE137221 R0QC SUMMARY
MB blank results are compared to the Limit of Reporting
LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.
DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided
by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.
Total Dissolved Solids (TDS) in water Method: ME-(AU)-[ENV]AN113
MB DUP %RPD LCS
%Recovery
MS
%Recovery
MSD %RPD
Total Dissolved Solids Dried at 175-185°C LB163002 mg/L 10 <10 1 - 2% 97% 98% 5%
LORUnits Parameter QC
Reference
Page 5 of 723-August-2019
PE137221 R0
METHOD METHODOLOGY SUMMARY
METHOD SUMMARY
pH in Soil Sludge Sediment and Water: pH is measured electrometrically using a combination electrode (glass plus
reference electrode) and is calibrated against 3 buffers purchased commercially. For soils, an extract with water is
made at a ratio of 1:5 and the pH determined and reported on the extract. Reference APHA 4500-H+.
AN101
Conductivity and TDS by Calculation: Conductivity is measured by meter with temperature compensation and is
calibrated against a standard solution of potassium chloride. Conductivity is generally reported as µmhos/cm or
µS/cm @ 25°C. For soils, an extract with water is made at a ratio of 1:5 and the EC determined and reported on
the extract, or calculated back to the as-received sample. Total Dissolved Salts can be estimated from conductivity
using a conversion factor, which for natural waters, is in the range 0.55 to 0.75. SGS use 0.6. Reference APHA
2510 B.
AN106
Salinity may be calculated in terms of NaCl from the sample conductivity. This assumes all soluble salts present,
measured by the conductivity, are present as NaCl.
AN106
Total Dissolved Solids: A well-mixed filtered sample of known volume is evaporated to dryness at 180°C and the
residue weighed. Approximate methods for correlating chemical analysis with dissolved solids are available.
Reference APHA 2540 C.
AN113
The Total Dissolved Solids residue may also be ignited at 550 C and volatile TDS (Organic TDS) and non-volatile
TDS (Inorganic) can be determined.
AN113
Alkalinity (and forms of) by Titration: The sample is titrated with standard acid to pH 8.3 (P titre) and pH 4.5 (T titre)
and permanent and/or total alkalinity calculated. The results are expressed as equivalents of calcium carbonate or
recalculated as bicarbonate, carbonate and hydroxide. Reference APHA 2320. Internal Reference AN135
AN135
Chloride by Aquakem DA: Chloride reacts with mercuric thiocyanate forming a mercuric chloride complex. In the
presence of ferric iron, highly coloured ferric thiocyanate is formed which is proportional to the chloride
concentration. Reference APHA 4500Cl-
AN274
sulfate by Aquakem DA: sulfate is precipitated in an acidic medium with barium chloride. The resulting turbidity is
measured photometrically at 405nm and compared with standard calibration solutions to determine the sulfate
concentration in the sample. Reference APHA 4500-SO42-. Internal reference AN275.
AN275
Metals by ICP-OES: Samples are preserved with 10% nitric acid for a wide range of metals and some non-metals.
This solution is measured by Inductively Coupled Plasma. Solutions are aspirated into an argon plasma at
8000-10000K and emit characteristic energy or light as a result of electron transitions through unique energy
levels. The emitted light is focused onto a diffraction grating where it is separated into components .
AN320
Photomultipliers or CCDs are used to measure the light intensity at specific wavelengths. This intensity is directly
proportional to concentration. Corrections are required to compensate for spectral overlap between elements.
Reference APHA 3120 B.
AN320
Free and Total Carbon Dioxide may be calculated using alkalinity forms only when the samples TDS is <500mg/L.
If TDS is >500mg/L free or total carbon dioxide cannot be reported . APHA4500CO2 D.
Calculation
Page 6 of 723-August-2019
PE137221 R0
Unless it is reported that sampling has been performed by SGS, the samples have been analysed as received.
Solid samples expressed on a dry weight basis.
Where "Total" analyte groups are reported (for example, Total PAHs, Total OC Pesticides) the total will be calculated as the sum of the individual
analytes, with those analytes that are reported as <LOR being assumed to be zero. The summed (Total) limit of reporting is calcuated by summing
the individual analyte LORs and dividing by two. For example, where 16 individual analytes are being summed and each has an LOR of 0.1 mg/kg,
the "Totals" LOR will be 1.6 / 2 (0.8 mg/kg). Where only 2 analytes are being summed, the " Total" LOR will be the sum of those two LORs.
Some totals may not appear to add up because the total is rounded after adding up the raw values.
If reported, measurement uncertainty follow the ± sign after the analytical result and is expressed as the expanded uncertainty calculated using a
coverage factor of 2, providing a level of confidence of approximately 95%, unless stated otherwise in the comments section of this report.
Results reported for samples tested under test methods with codes starting with ARS -SOP, radionuclide or gross radioactivity concentrations are
expressed in becquerel (Bq) per unit of mass or volume or per wipe as stated on the report. Becquerel is the SI unit for activity and equals one
nuclear transformation per second.
Note that in terms of units of radioactivity:
a. 1 Bq is equivalent to 27 pCi
b. 37 MBq is equivalent to 1 mCi
For results reported for samples tested under test methods with codes starting with ARS -SOP, less than (<) values indicate the detection limit for
each radionuclide or parameter for the measurement system used. The respective detection limits have been calculated in accordance with ISO
11929.
The QC and MU criteria are subject to internal review according to the SGS QAQC plan and may be provided on request or alternatively can be
found here: www.sgs.com.au.pv.sgsvr/en-gb/environment.
This document is issued by the Company under its General Conditions of Service accessible at www.sgs.com/en/Terms-and-Conditions.aspx.
Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein.
Any holder of this document is advised that information contained hereon reflects the Company 's findings at the time of its intervention only and
within the limits of Client's instructions, if any. The Company's sole responsibility is to its Client only. Any unauthorized alteration, forgery or
falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law .
This report must not be reproduced, except in full.
IS
LNR
*
**
Insufficient sample for analysis.
Sample listed, but not received.
NATA accreditation does not cover the
performance of this service.
Indicative data, theoretical holding time exceeded.
FOOTNOTES
LOR
↑↓
QFH
QFL
-
NVL
Limit of Reporting
Raised or Lowered Limit of Reporting
QC result is above the upper tolerance
QC result is below the lower tolerance
The sample was not analysed for this analyte
Not Validated
Page 7 of 723-August-2019
APPENDIX E
NUMERICAL GROUNDWATER MODELLING
Appendix E Page 1
APPENDIX E - GROUNDWATER MODELLING
E1 Introduction
The objective of the groundwater modelling was to predict:
Groundwater inflows associated with the development of four open pits,
The potential for Managed Aquifer Recharge (MAR) to be used to dispose of water in excess
of the project water demand. Water requirements for the project have been estimated as:
o 0.67 GL per annum for roads (~1,835 kL/d),
o 0.16 GL per annum for mining during the wet season (~440 kL/d),
o 0.31 GL per annum for mining during the dry season (850 kL/d),
o Total water demand is estimated to vary between ~2,300 and 2,700 kL/d.
The regional water level change associated with dewatering,
The long term behaviour of the mined out pit voids.
The model was calibrated to available data and used to predict:
Groundwater inflows to the four proposed open pits over the life of the mine.
The regional drawdown and catchment water balance impact of pit dewatering over the life
of the mine.
The potential for the lower aquifer of the Lake Annean paleochannel, located south of the
open pits, to be used to manage dewatering abstraction, in excess of the project water
demand, via MAR, and any associated water level changes.
The long term behaviour of the final pit voids once mining is complete, including the time
taken for recovery to post mining or equilibrium level and the time taken for recovery.
Key features of the groundwater model are described in detail in the following sections and
summarised below. The model includes:
The upper (shallow mixed aquifer) and lower (deep) paleochannel aquifers of the Lake
Annean paleochannel, separated by a confining clay.
A similar sequence of aquifers and aquitards in tributaries of the Lake Annean paleochannel.
The mine area, including the orebody aquifer and adjacent fault.
Rainfall recharge to the aquifer system.
Groundwater inflow from upstream, from the northwest, southwest and southeast.
Groundwater outflow to the northwest.
E2 Model Set Up and Extent
The model was developed using the Modflow SURFACT groundwater modelling code (Hydrogeologic,
1996) operating under the Groundwater Vistas graphical user interface. The model was calibrated to
steady state conditions, with transient simulations used to predict dewatering of open pits and mine
closure impacts.
The extent of the model domain and the location of model boundaries are shown in Figure E1 and
summarised in Table E1. The model and all associated data are specified using the GDA 94 (Zone 50)
coordinate system. The model grid is rotated 30 degrees to align it with the inferred groundwater
flow direction. The model domain covers an area of 39 km north west to south east and 41 km
northeast to southwest.
Appendix E Page 2
Table E1: Extent of Model Domain
Easting (m)* Northing (m)*
Northwest 660,385 7,042,975
Northeast 694,080 7,023,530
Southwest 638,500 7,005,025
Southeast 672,260 6,985,520
A minimum model cell size of 50 m is assigned in the mine area (refer Figure E1) to accommodate
the geometry of the pits and the paleochannel aquifers. A maximum cell size of 650 m is assigned
elsewhere away from the mine and paleochannel areas. The model includes 408 rows and 413
columns over seven model layers resulting in a total of 1,179,528 model cells and 1,157,233 active
model cells.
E3 Model Geometry
Seven model layers are used to represent the mine area and the lower aquifer, clay aquitard and
upper aquifer of the Lake Annean paleochannel and tributaries. Low hydraulic conductivity basement
is represented by model layer seven, as well as the areas outside the paleochannel aquifer. Model
layers are generally assigned a uniform thickness with model geometry summarised in Table E2.
Aquifer property zones for model layers 1 to 6 are shown in Figures E2, E3 and E4 (model layer 7 is
included as basement only). The orebody is simulated over a length of 14 km and assigned a width
of 0.3 km. In the Lake Annean paleochannels the upper aquifer, aquitard and lower aquifer are
assigned widths of 1 to 2 km, 0.7 to 1.8 km and 0.5 to 1.2 km respectively.
A schematic model section is shown in Figure E5.
Table E2: Summary of Model Geometry
Layer Aquifer Units Layer Geometry
1 Basement, orebody and fault and shallow (upper) mixed aquifer
Top of layer represents ground surface (from SRTM). Base of layer set to simulate a minimum saturated thickness of 10 m in the paleochannel area (15 m total thickness). In areas of higher elevation, layer thickness increases to a maximum of 130 m. In areas of lower elevation, thickness reduces to a minimum of 15 m.
2 Basement, orebody and fault and paleochannel shallow (upper) mixed aquifer
Layer thickness of 10 m across model domain.
3 Basement, orebody and fault and paleochannel clay aquitard Layer thickness of 40 m across model domain.
4 Basement, orebody and fault and paleochannel confining clay aquitard
Layer thickness of 40 m across model domain.
5 Basement, lower orebody and fault and paleochannel deep (lower) aquifer
Layer thickness of 27 m across model domain.
6 Basement, lower orebody and fault
Layer thickness of 80 m to 140 m across model domain, consistent with a base of layer elevation of 230 mRL.
7 Basement Layer thickness of 10 m across model domain.
Appendix E Page 3
E4 Groundwater Inflow and Outflow
E4.1 Groundwater Throughflow
The locations of all model boundaries are shown in Figure E1. The general direction of groundwater
flow in the model domain is as follows:
From areas of higher topographic elevation toward drainage lines and the Lake Annean
paleochannel, including from northeast to southwest, along tributaries to the Lake Annean
paleochannel.
From southeast to northwest along the Lake Annean paleochannel.
Groundwater inflow to the modelled catchment from upstream is simulated by using fixed head inflow
boundaries (shown in Figure E1). The north eastern upstream boundary is set at an elevation of
490 mRL and is aligned with the estimated 490 mRL groundwater elevation. The southwestern
boundary, to the south of the Lake Annean paleochannel is set at an elevation of 465 mRL (also
aligned with the estimated 465 mRL groundwater elevation). This boundary was chosen to allow
simulation of the impacts of dewatering and MAR in the palaoechannel aquifer and the basement
immediately south of paleochannel. The upstream and downstream ends of the Lake Annean
paleochannel are set at elevations of 466 mRL and 440 mRL respectively to simulate groundwater
inflow from upstream and outflow to downstream. In each model layer, the extents of the fixed head
boundaries associated with the Lake Annean paleochannel are limited to the extent of aquifer where
it crosses the boundary (i.e., consistent with the aquifer distributions discussed in Section E3 and
shown in Figures E2 to E4). Fixed head boundaries are assigned in all six model layers.
All other model boundaries are aligned perpendicular to the inferred groundwater flow direction and
are set as no flow boundaries, as shown in Figure E1. These boundaries are set far enough away to
have minimal impact on model predictions.
E4.2 Recharge
In addition to groundwater inflows from upstream, the groundwater system is also recharged by
incident rainfall. In this arid environment, where evaporation exceeds long term rainfall by a factor
of almost 10, rainfall recharge to groundwater is expected to be low. Recharge to groundwater is
assumed to be along aquifers and drainage lines with recharge also assigned to the basement.
E4.3 Dewatering
Groundwater inflows into the open pits were simulated using the Drain (DRN) package in Modflow
SURFACT. The DRN package uses a head dependent relationship to predict the groundwater flow
that would result in a reduction in water level to a specified elevation. Drain cell elevations can
change in time and extent over the duration of a model prediction. Dewatering was simulated during
model predictions only.
E5 Model Calibration
Model calibration is the process by which the parameters of a numerical model are adjusted, within
realistic limits to provide the best match to measured data. This process involves testing and refining
the aquifer properties and the boundary conditions of the model to improve the match between
observed data and simulated values. The current model calibration used a manual or trial and error
approach. The amount of available data, in particular water level monitoring across the modelled
catchment and the applicability to a long term or steady state water level calibration means that
Appendix E Page 4
using automated techniques to calibrate the model will not increase the reliability of model
predictions.
An initial steady state model was completed to generate a set of initial or pre-development
groundwater levels that reflect groundwater conditions period to the start of pumping. The
groundwater level data available for model calibration was provided from the following sources:
Groundwater monitoring from the Department of Water and Environmental Regulation
(DWER) data base.
Monitoring from 13 bores installed during the recent hydrogeological investigations, located
on the orebody and in the paleochannel aquifer.
Ideally all water level data used for steady state model calibration would be contemporaneous or
taken over the duration an investigation programme. The investigations to date were focused on
the orebody area and the paleochannel aquifers. The regional DWER monitoring was added to the
water levels from the hydrogeological investigations to allow water levels to be estimated across the
modelled catchment and allow assignment of appropriate boundary conditions. This data has been
used as part of the calibration, however, there are uncertainties associated with this data (bore
construction details, water levels impacted by pumping / discharge etc.).
No historical or long term groundwater monitoring data from across the modelled catchment is
available to calibrate the model to time varying or transient conditions.
E5.1 Steady State Calibration
The locations of bores used for calibration of the steady state model are shown in Figure E6. Measured
groundwater levels and contours of predicted groundwater levels (steady state conditions) are shown
in Figure E7. The contours of predicted water levels show the general direction of groundwater flow
across the model domain.
Measured and modelled water levels are presented in Figure E8 and summarised in Table E3. In
general, measured groundwater levels at investigation bores are well matched with the difference
between measured and modelled water levels between 1 and 2 m. The maximum difference between
measured and modelled water levels in recently installed bores is 4.8 m. This difference is at bore
19AVWP001, which is located in the mine area. This bore is also close to bore 19AVWM105, where
the difference between measured and modelled water levels is 1.4 m.
Appendix E Page 5
Table E3: Measured and Modelled Water Levels
Bore Name Hydrogeological Unit Measured Water Level
Confining Clay Lake Annean Paleochannel and Tributaries 3 & 4 0.001 0.00001 6 0.00005
Basement 3 0.05 0.005 0.1 0.00001
Orebody 3 & 4 0.005 0.0005 1 0.00005
Basement 4 0.005 0.0005 0.1 0.00001
Deep Aquifer Lake Annean Paleochannel and Tributaries
5 10 1.0 15 0.00005
Basement 5 to 7 0.0001 0.0001 0.05 0.00001
Orebody 5 & 6 0.005 0.00005 0.1 0.00005
* Modelled aquifers are assumed to be unconfined in the upper most model layer (layer 1) ** Confined storage coefficient specified in layers 2 to 6 only as the fault is modelled as an unconfined aquifer in model layer 1
E5.3 Other Model Details
Other details of model set up are outlined below:
Transient modelling for dewatering and closure used annual stress periods (periods over
which all stresses are held constant).
o The Modflow SURFACT Automatic Time Stepping (ATO) package was used for all
transient (time varying) simulations with the following parameters:
o An initial time step length of 30 days was used.
o A minimum time step of 1x10-10 days and a maximum time step length of 90 days
o A multiplier factor of 1.2 and a reduction factor of 2.0.
These parameters result in a maximum time step length of up to 90 days.
The model was also run with the Modflow SURFACT Block Centred Flow 4 (BCF4) package
using the Variably Saturated Flow Option (Pseudo Soil Relations).
Appendix E Page 8
The model was run with the Pre-Conjugated 5 (PCG5) solver along with the following
parameters:
o Number of outer iterations - 100
o Number of inner iterations - 20
o Maximum orthoganalisations - 10
o Head change criteria = 0.01 m
o Relative convergence criterion = 0.1
o Newton Raphson Linearisation (Back tracking Factor) = 0.9
o Newton Raphson Linearisation (Residual Reduction Factor) = 1
E6 Model Predictions
The calibrated model was used to:
Predict groundwater inflows to the open pits to allow calculation of water disposal
requirements in excess of the project water demand which has been estimated at between
2,300 kL/d and 2,700 kL/d (for the wet and dry seasons respectively).
Predict the water level (drawdown) impact of open pit dewatering at the end of mine life.
Predict the potential for MAR to the lower paleochannel aquifer to be used to dispose of
dewatering in excess of the project demand.
Predict the recovery of water levels in mine out pits once mine in complete, assuming that
pits are left empty, including final equilibrium levels and the time taken for recovery to final
levels.
These predictions were completed assuming transient conditions.
E6.1 Prediction Set up
For single open pit developments, in low permeability basement rock environments with limited
hydrogeological data, groundwater inflows to open pits and the long term behaviour of final mine
voids can be estimated using analytical methods. This analytical approach can be just as reliable as
numerical approaches in some environments (single pits developed in low permeability
environments). The current plan for the project includes four open pits, with basement rocks to the
north and a paleochannel to the south. To simulate the groundwater interactions between the
adjacent pits / pit voids, and the variable aquifer conditions close to the pits, a numerical approach
is required.
Prediction of groundwater inflow to the open pits was completed for the mine plan provided, in dxf
format. The plan included 40 pit progressions for four pits for a period of 25 years. Mine plans were
provided in quarterly increments for Year 1 to 5 in 0624_avl_v6_1_y1_q1_surf_mga.dxf to
0624_avl_v6_1_y5_q4_surf_mga.dxf and annual increments for Years 6 to 25 in
0624_avl_v6_1_y6_surf_mga.dxf to 0624_avl_v6_1_y25_surf_mga.dxf. Mining will progress to a
depth of between 110 m and 240 m below ground surface and will cover a total mined area of up to
260 ha. The extent of the mining area with Pit Locations is shown in Figure E8.
Other details of model predictions are outlined below:
Operational (mining) model predictions were completed for the period Year 1 to Year 25,
using an annual time increment or stress period, with initial water level conditions for model
predictions taken from the steady state model calibration.
Appendix E Page 9
The dewatering approach, uses the DRN package in Modflow Surfact, Drain elevations and
extents were set consistent with the mining schedule provided. The mining schedule used is
summarised in Table E6.
As the DRN package is used to simulate water level reduction consistent with the mine plan,
no advanced dewatering is predicted ahead of mining.
All other groundwater inflows and outflows in the catchment are assigned consistent with
the steady state calibration.
Aquifer parameters are not changed during model predictions as any enhanced aquifer
potential that develops in the pit area (due to blasting or hydromechanical processes) will
be small in scale and will not impact the regional groundwater flow system.
No other groundwater development (dewatering of open pits, water supply pumping, MAR,
seepage from Tailings Storage Facilities (TSFS) or stock water use) is included in model
predictions.
The results of the dewatering prediction were used to calculate water disposal requirements.
Table E6: Mining Schedule Used for Dewatering Predictions
Dewatering Rate (kL/day) Upper Water Demand (kL/d) Lower Water Demand (kL/d)
Modelled Water Levels for Pits 1 and 2 FIGURE E11F:\183\3.C&R\048 Figs & App\Appendix E_Modelling\[Figure E11 and 12 - Predicted Water Levels.xlsx]Figure E11
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Closure Period of 100 years
Closure Period of 100 years
Modelled Water Levels for Pits 3 and 4 During Closure FIGURE E15\\dc02\Jobs\183\3.C&R\048 Figs & App\Appendix E_Modelling\[Figure E14 and 15 - Predicted Water Levels for Closure.xlsx]Figure E15
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