Annexures - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0... · 2014-11-21 · ANNEXURE - 3 : Details of Production Capacity and Raw Material ANNEXURE

Annexures

M/s. Rheomax Gums LLP

LIST OF ANNEXURES

Annexure : Description

ANNEXURE - 1 : Location of the Project Site

ANNEXURE - 2 : Plant Layout

ANNEXURE - 2.1 : Break-Up of Total Land Area

ANNEXURE - 3 : Details of Production Capacity and Raw Material

ANNEXURE - 4 : Details of Manufacturing Process

ANNEXURE - 5 : Details of Storage Facilities For Products, By-Products and Raw Materials

ANNEXURE - 6 : Details of Solid / Hazardous Waste and Mode of Disposal

ANNEXURE - 7 : Details of Water Consumption and Wastewater Generation

ANNEXURE - 7.1 : Details of Effluent (Wastewater) Management System

ANNEXURE - 8 : Details of Electricity and Fuel

ANNEXURE - 8.1 : Details of Stack / Vent, Flue Gas and Air Pollution Control Measures


Annexure-1 of Form-1

ANNEXURE – 1

Location of Project Site

(A). Gujarat Map Showing District- Ahmedabad

Ahmedabad District



(B). Ahmedbad District Map Showing- Project Site at Village- Gangad

Gangad Village



(C). Google Map Showing Project Site



ANNEXURE – 2

Plant Layout

Please see the attached layout plan

(A)

GREEN SPACE

PARKING

FUTURE EXPANSION

(12)

PRODUCTION

BLOCK

(1)

OFFICE

PA

NT

RY

LA

DIE

S

TO

ILE

T

GE

NT

S

TO

ILE

T

PA

SS

AG

E

(2)

RAW MATERIAL

STORAGE

ROOM

(3)

PRODUCT

STORAGE

ROOM

(4)

SOLID

WASTE

STORAGE

ROOM

(5)

HAZARDOUS

CHEMICAL

STORAGE

ROOM

(6)

DRUMS

STORAGE

ROOM

(7)

ELECTRIC

ROOM

(8)

FIRE HYDRANT

ROOM

(9)

BOILER ROOM

(10)

UTILITIES

(11)

ETP AREA

(13) P

AS

SA

G

E

(13) P

AS

SA

G

E

RO

AD

OWNER :-

SCALE :- 1CM : 5MT.

RHEOMAX GUMS L.L.P.SUR NO. - 1905/PART, VILLAGE :- GANGADTALUKA :- BAVLA, DISTRICT :- AHMEDABAD

ENT.

104.9

0

175.12

155.17

51.74

50.58

1) OFFICE = 335.10

3) PRODUCTION STORAGE ROOM = 135.00 4) SOLID WASTE STORAGE ROOM = 135.00 5) HAZARDOUS CHEMICAL STORAGE ROOM = 135.00 6) DRUMS STORAGE ROOM = 135.00 7) ELECTRIC ROOM = 60.00 8) FIRE HYDRANT ROOM = 50.00 9) BOILER ROOM = 60.0010) UTILITIES = 129.4011) ETP + MEE ROOM = 213.0212) PRODUCTION BLOCK = 2405.1013) PASSAGE = 276.24

2) RAW MATERIAL STORAGE ROOM = 180.00

TOTAL FLOOR AREA = 4248.86(B)

88.05

49.79

TOTAL BUILT UP AREA - 4384.00 Sqmts.(A) GREEN SPACE AREA - 6074.26 Sqmts.(B) ROAD AREA - 3260.34 Sqmts.(C) FUTURE EXPANSION WITH PARKING - 3480.40 Sqmts. TOTAL AREA - 17199.00 Sqmts.

(C)

(C)


Annexure- 2.1 of Form-1 1

Annexure – 2.1

LAND AREA DETAILS

Break-up details of land area

Sr.No. Description Area Details (m²)

A Total built-up/ground coverage area (allocated for industrial uses) 4384.0

B Road area 3260.3

C Future expansion with parking 3480.4

D Green belt area (35% of total land area) 6074.3

TOTAL LAND AREA (A+B+C+D) 17199.0

Break-up details of floor area allocated for industrial uses


1. Office 335.1

2. Production block 2405.1

3. Raw materials storage area 180.0

4. Products storage area 135.0

5. Fuel storage area 135.0

6. Hazardous chemical storage 135.0

7. Drums storage area 135.0

8. Electric area 60.0

9. Fire hydrant 50.0

10. Boiler room 60.0

11. Utilities area 129.4

12. ETP + MEE area 213.0

13. Passage 276.2

Total floor area 4248.8


Annexure- 3 of Form-1 1

Annexure - 3

Details of Production Capacity & Raw Material Consumption

(A) DETAILS OF PRODUCTS & PRODUCTION CAPACITY

Sr. No.

Name of Product Quantity

(MT/Month)

1. Chloro Compound (2-chloromethyl-3,4-dimethoxy pyridine hydrochloride)

10

2. Pantaprazole sodium 5

3. Phenylephrine HCl 2

4. Pregabalin 2

5. Telmisartan 2

6. Montekulast sodium 2

7. Ondansetron HCl 2



(B) DETAILS OF RAW MATERIALS & IT’S PRODUCT WISE CONSUMPTION

For Product Name of Raw Material Quantity

Kg/Batch MT/Month

1. Chloro Compound (2-chloromethyl-3,4-dimethoxy pyridine hydrochloride) (10 MT/Month)

Acetic acid 180.00 7.50

Acetic acid glacial 150.00 6.25

Acetic anhydride 1140.00 47.49

Ammonium carbonate 100.00 4.17

Chloroform 2293.50 95.55

Di methyl formamide (DMF) 30.00 1.25

Di methyl sulfate (DMS) 360.00 15.00

H2O2 330.00 13.75 Hexane 425.10 17.71

Ice 450.00 18.75

Iso propyl alcohol (IPA) 157.00 6.54

KOH 156.00 6.50

Methylene dichloride (MDC) 5569.2 232.01

Methanol 1665.30 69.38 Methyl maltol 300.00 12.50

NaOH (caustic lye) 1295.00 53.95

NH3 liquor 543.18 22.63 POCl3 560.00 23.33

SOCl2 195.00 8.12

Sodium methoxide 180.00 7.50

Sodium sulfate 50.00 2.08

Sodium tungstate 15.00 0.62

Toluene 1206.80 50.28

2. Pantaprazole Sodium (5 MT/Month)

10% NaOCl 279.00 1395.00 Acetone 623 3115

Diflouro methoxy-2-MB 73.50 367.50

IPA 1154 5770 NaOH 41.00 205.00

Pantoprazole chloro compound 77.00 385.00

Pantoprazole sulfide 115.00 575.00

3. Phenylephrine HCl (2 MT/Month)

Acidic isopropyl alcohol 275.00 1.83

Ranney nickel (10% charcoal) 12.00 0.08

An.aluminium chloride 17.50 0.12 Ethyl acetate 700.00 4.67




Kg/Batch MT/Month

HCl 88.00 0.59

Hydrogen gas 2.00 0.01

Hyflow powder 4.00 0.03

Isopropyl alcohol 4250.00 28.33

Liq. bromine 204.00 1.36 Methanol 2500.00 16.67

M-hydroxy aceto phenone 350.00 2.33

N-methyl benzyl amine 258.00 1.72 Ranney nickel (10% charcoa 25.00 0.17

Toluene 700.00 4.67

4. Pregabalin (2 MT/Month)

Activated charcoal 10.00 0.08


Diethyl malonate 530.00 4.24

Di-n-propyl amine 25.40 0.20

Ethyl cyano acetate 390.00 3.12

Hydrochloric acid 150.00 1.20


Isoveraldehyde 300.00 2.40

Liq. bromine 245.00 1.96

Methanol 61.20 0.49

Sodium hydroxide 338.00 2.70 n-Hexane 450.00 3.60

R-(+)-(α)-phenyl ethyl amine 205.00 1.64

Urea 215.00 1.72

5. Telmisartan (2 MT/Month)

Acetone 295.10 2.66 Acetic acid 470.60 4.24

Activated carbon 13.10 0.12 Bibenzimidazole 186.70 1.68

Bromo methyl ester 187.30 1.69

Celite 8.80 0.08

Dimethyl formamide 969.60 8.73

Methanol 3304.60 29.74

Potassium hydroxide 76.10 0.68 Sodium hydroxide 33.10 0.30

Recoveries (-)

Acetone 280.30 2.52




Kg/Batch MT/Month

Dimethyl formamide 921.10 8.29

Methanol 3160.20 28.44

6. Montekulast Sodium (2 MT/Month)

Acetic acid 65.00 0.87 Acetone 1600.00 21.33

Carbon 15.00 0.20

Di isopropyl ethylamine 6.00 0.08

HCl for NaOH neutralization 55.50 0.74

MDC 1800.00 24.00

Methane sulfonyl chloride 15.00 0.20 Methanol 2219.80 29.60

N-vinyl pyrrolidone 108.10 1.44

Sodium chloride 120.00 1.60

Sodium hydroxide 86.80 1.16

Tertiary Butyl amine 29.40 0.39

Thiol Acetic acid 74.00 0.99

Thiophene-2-ethylamine 347.40 4.63

Toluene 7200.00 96.00

7. Ondansetron HCl (2 MT/Month)

1,2,3,9-Tetrahydo-4H-carbazole-4-one 325.00 1.86

2-Methyl imidazole 124.00 0.71

Activated charcoal 7.00 0.04

Dimethyl formamide (DMF) 127.00 0.73

Hydrochloric acid 120.00 0.69


Isopropyl alcohol 1700.00 9.71 Methylene dichloride 2200.00 12.57

Morpholine 30.00 0.17

P-formaldehyde 45.00 0.26


Tetra butyl ammonium bromide 2.00 0.01

Toluene 1600.00 9.14



ANNEXURE - 4

Details of Manufacturing Process Manufacturing process details of proposed products are as given under -

(1). Chloro Compound (2-Chloromethyl 3,4-Dimethoxy Pyridine Hydrochloride)

Manufacturing process, reaction chemistry, mass balance diagram and process flow chart of

Chloro Compound (2-Chloromethyl 3,4-Dimethoxy Pyridine Hydrochloride) are presented

here –

a) Manufacturing Process :

Brief Description: Maltol (2 methyl-3 hydroxy-4 pyrone) is reacted with Dimethyl Sulfate to

produce 2methyl 3-Methoxy 4 Pyrone. This methoxy Pyrone is condensed with NH3 liquor to

produce 2 methyl 3 methoxy4 pyridone. This pyridone is then reacted with POCl3 to form 2

methyl 3 methoxy 4 chloro pyridine. This chloro pyridine undergoes oxidation with H2O2 and

Tungstic Acid to give 2 methyl 3 methoxy 4 chloro pyridine anoxide which inturn reacts with

Sodium Methoxide to form dimethoxy in methanol medium. This dimethoxy pyridine

anoxide undergoes acetylation with Acetic Anhydride to give 2 Acetyl 3,4 dimethoxy

pyridine. This then undergoes hydrolysis with NaOH to give 2 hydroxy methyl 3,4 dimethoxy

pyridine. This is then reacted with ThionylChoride (SOCl2) to form 2 chloromethyl 3,4

dimethoxy pyridine Hydrochloride.



b) Chemical Reaction:

Stage- I : Methylation

Stage- II : Ammonialysis

Stage- III : Chlorination

Stage- IV : Oxidation

Methyl Maltol Di Methyl Sulphate (DMS) Potassium Hydroxide 2-methyl 3-methoxy 4-pyrone Potassium sulphate

ammonium carbonate

2-methyl 3-methoxy 4-pyrone

ammonia 2-methyl 3-methoxy 4-pyridone

ammonium hydroxide

carbon dioxide

2-methyl 3-methoxy 4-pyridone 2-methyl 3-methoxy 4- chloro pyridine sodium

chloride phosphoric

acid

2-methyl 3-methoxy 4- chloro pyridine

hydrogen peroxide 2-methyl 3-methoxy 4- chloro pyridine N-oxide



Stage- V : Methoxylation

Stage- VI : Acetylation

Stage- VII : Hydrolysis

Stage- VIII : Chlorination

2-methyl 3-methoxy 4- chloro pyridine N-oxide

sodium methoxide 2-methyl 3,4-dimethoxy pyridine N-oxide

sodium chloride

2-methyl 3,4-dimethoxy pyridine N-oxide

acetic anhydride 2-acetyl 3,4-dimethoxy pyridine

2-acetyl 3,4-dimethoxy pyridine sodium hydroxide 2-hydroxy methyl 3,4-dimethoxy pyridine

2-hydroxy methyl 3,4-dimethoxy pyridine thionyl chloride 2-chloromethyl 3,4- diimethoxy pyridine hydrochloride



a) Mass Balance Diagram :

Stage

INPUT OUTPUT

INPUT Kg/Batch MT/Month OUTPUT Kg/Batch MT/Month

Stage- I Methyl maltol 300.00 12.50 Methanol recovery 924.00 38.49

DMS 360.00 15.00 K2SO4 513.60 21.40

KOH 156.00 6.50 Stage-1 330.00 13.75

Methanol 951.60 39.64 0.00

Sub-total of stage-I 1767.60 73.64 Sub-total of stage-I 1767.60 73.64

Stage- II Stage-1 330.00 13.75 Ammonium hydroxide 228.80 9.53

NH3 liquor 543.18 22.63 Water 300.00 12.50

Ammonium carbonate 100.00 4.17 Toluene recovery 1180.00 49.16

Hexane 130.80 5.45 Hexane recovery 127.00 5.29

Toluene 1206.80 50.28 CO2 204.98 8.54

Stage-2 270.00 11.25

Sub-total of stage-II 2310.78 96.27 Sub-total of stage-II 2310.78 96.27

Stage- III Stage-2 270.00 11.25 Chloroform recovery 58.20 2.42

POCl3 560.00 23.33 Water 600.00 25.00

NaOH (caustic lye) 600.00 25.00 Wastewater (effluent) 531.80 22.15

Chloroform 60.00 2.50 Stage-3 300.00 12.50



Stage

INPUT OUTPUT


Sub-total of stage-III 62.07 1490.00 Sub-total of stage-III 1490.00 62.07

Stage- IV Stage-3 300.00 12.50 Chloroform recovery 2166.50 90.26

Sodium tungstate 15.00 0.62 Wastewater (effluent) 1677.00 69.86

Acetic acid glacial 150.00 6.25 Stage-4 300.00 12.50


H2O2 330.00 13.75

Water 630.00 26.25

Ice 450.00 18.75

NaOH (caustic lye) 35.00 1.46

Sub-total of stage-IV 4143.50 172.62 Sub-total of stage-IV 4143.50 172.62

Stage- V Stage-4 300.00 12.50 Methanol recovery 692.70 28.86

Sodium methoxide 180.00 7.50 Salt 51.00 2.12

Methanol 713.70 29.73 Stage- 5 450.00 18.75

Sub-total of stage-V 1193.70 49.73 Sub-total of stage-V 1193.70 49.73

Stage- VI Stage-5 450.00 18.75 Acetic anhydride distillate 780.00 32.49

Acetic acid 180.00 7.50 Stage- 6 990.00 41.24

Acetic anhydride 1140.00 47.49 0.00



Stage

INPUT OUTPUT


Sub-total of stage-VI 1770.00 73.74 Sub-total of stage-VI 1770.00 73.74

Stage-VII Stage-6 990.00 41.24 0.00

Water 1500.00 62.49 Sodium Acetate 1407.90 58.65

NaOH (caustic lye) 660.00 27.50 MDC recovery 3938.90 164.09

Hexane 294.30 12.26 Hexane recovery 285.50 11.89

Methylene dichloride 3978.00 165.72 Water 1600.00 66.66

Sodium sulfate 50.00 2.08 Stage- 7 240.00 10.00

Sub-total of stage-VII 7472.30 311.30 Sub-total of stage-VII 7472.30 311.30

Stage- VIII Stage- 7 240.00 10.00 MDC recovery 1559.40 64.96

MDC 1591.20 66.29 IPA recovery 153.80 6.41

DMF 30.00 1.25 SO2 260.00 10.83

IPA 157.00 6.54 Chloro Compound- Product 240.00 10.00

SOCl2 195.00 8.12

Sub-total of stage-VIII 2213.20 92.20 Sub-total of stage-VIII 2213.20 92.20

TOTAL INPUT

(Sum of all stages’ sub-total) 22361.08 931.56 TOTAL OUTPUT (Sum of all stages’ sub-total) 22361.08 931.56



b) Process Flow Chart :



(2). Pantaprazole Sodium

Manufacturing process, reaction chemistry, mass balance diagram and process flow chart of Pantaprazole Sodium are presented here –


Brief Description: Pantoprazole chloro compound will react with 5-difluoromethoxy-2-

mercapto benzamidazole in presence of Base in organic solvent to get PT-S compound. PT-S

compound will react with sodium hypochlorite in presence of organic solvent to get PT-1

compound. PT-1 compound will reacts with sodium hydroxide in presence of organic solvent

to get Pantoprazole sodium sesquihydrate.

b) Chemical Reaction:

Stage- 1)

C8H10ClNO2.HCl + C8H6F2N2OS + 2NaOH Pantoprazole chloro compound

5-difluoromethoxy-2- mercapto benzamidazole

Sodium hydoxide

C16H15F2N3O3S + 2NaCl + 2H2O PT-S compound Sodium Chloride Water

Stage- 2)

C16H15F2N3O3S + NaOCl + H2O PT-S compound Sodium hypochlorite Water

C16H15F2N3O4S + NaOH + HCl PT-1 compound Sodium hydroxide Hydrogen chloride

Stage- 3)

C16H15F2N3O4S + NaOH + 1.5H2O PT-1 compound Sodium hydroxide Water

C16H14F2N3NaO4S 1.5H2O + H2O Pantoprazole sodium sesquihydrate Water



c) Mass Balance Diagram :

Stage INPUT OUTPUT

Input Kg / Batch MT/ Month Output Kg/Batch MT/Month

Stage- I Pantoprazole chloro compound 77.00 3.85 Aq. layer 168.50 8.43

Diflouro Methoxy-2-MB 73.50 3.68 IPA MLs 627.00 31.35

NaOH 30.00 1.50 Evaporation loss 15.10 0.76

R.O. water 138.50 6.93 Evaporation loss 8.40 0.42

IPA 385.00 19.25 PT-S compound 115.00 5.75

R.O. water 153.00 7.65

IPA for washing 77.00 3.85


Stage- II Pantoprazole sulfide 115.00 5.75 Aq. layer 472.00 23.60

10% NaOCl 279.00 13.95 Evaporation loss 8.00 0.40

IPA 577.00 28.85 IPA MLs 885.00 44.25

R.O. water 193.00 9.65 Evaporation loss 4.00 0.20

R.O. water 193.50 9.68 PT-1 103.50 5.18

IPA for washing 115.00 5.75


Stage- III Pantoprazole 103.50 5.18 Acetone MLs 638.50 31.93



Stage INPUT OUTPUT

Input Kg / Batch MT/ Month Output Kg/Batch MT/Month

NaOH 11.00 0.55 Evaporation loss 10.00 0.50

Acetone 519.00 25.95 Evaporation loss 7.00 0.35

R.O. water 18.00 0.90 Pantoprazole Sodium- API 100.00 5.00

Acetone washing 104.00 5.20

Sub-total of stage- III 755.50 37.78 Sub-total of stage-III 755.50 37.78

TOTAL INPUT (Sum of all stages’ sub-total) 3162.00 158.10

TOTAL INPUT (Sum of all stages’ sub-total) 3162.00 158.10



d) Process Flow Chart :



(3). Phenylephrine HCl


Phenylephrine HCl are presented here –


Brief Description; M-hydroxy aceto phenone reacts with bromine in presence of aluminium

chloride to form M-hydroxyl bromo aceto phenone which will react with N-methyl benzyl

amine in presence of Ranney Nickel to obtain phenylephrine hydrochloride.

b) Chemical Reaction :

M-hydroxy aceto phenone N-methyl benzyl amine

Phenyl Ephrine crude Phenylephrine HCl



c) Mass Balance :

Stages

INPUT OUTPUT

Input Kg/Batch MT/Month Output Kg/Batch MT/Month

Stage- I m-hydroxy aceto phenone 350.00 2.33 Stage- I Mass 500.00 3.33

Ethyl acetate 700.00 4.67 HBr 210.00 1.40

An.Aluminium chloride 17.50 0.12 Solvent 0.00

Liq. Bromine 204.00 1.36 Toluene recovery 665.00 4.43

Toluene 700.00 4.67 Toluene loss 21.00 0.14

n-methyl benzyl amine 258.00 1.72 Ethyl acetate recovery 665.00 4.43

Water 250.00 1.67 Ethyl acetate loss 21.00 0.14

Acidic isopropyl alcohol 75.00 0.50 Liquid waste 0.00

Water 250.00 1.67

Aluminum chloride 17.50 0.12

Toluene 14.00 0.09

Ethyl acetate 14.00 0.09

Acidic Isopropyl alcohol 75.00 0.50

Solid waste 0.00 0.00

Gaseous waste 0.00 0.00

Organic residue 102.00 0.68




Stage- II Stage- I Mass 500.00 3.33 Stage- II mass 400.00 2.67

Methanol 2500.00 16.67 Solvent 0.00

Ranney nickel (10% charcoal) 25.00 0.17 Methyl recovery 2250.00 15.00

Hydrogen gas 2.00 0.01 Methyl loss 125.00 0.83

Hyflow powder 2.00 0.01 Liquid waste 0.00

Water 550.00 3.67 Water 550.00 3.67

Methanol 63.00 0.42

Organic 92.00 0.61





Stage- III Stage- II Mass 400.00 2.67 Stage- III Mass 375.00 2.50

Isopropyl alcohol 2000.00 13.33 Solvent 0.00

HCl 88.00 0.59 Isopropyl alcohol recovery 1800.00 12.00

water 400.00 2.67 Isopropyl alcohol loss 100.00 0.67

Acidic isopropyl alcohol 200.00 1.33 Liquid waste 0.00



Water 400.00 2.67


Acidic isopropyl alcohol 200.00 1.33





Stage- IV Stage- III Mass 375.00 2.50 Phenylephrine HCL - Product 300.00 2.00


Activated charcoal 12.00 0.08 Isopropyl alcohol recovery 1800.00 12.00

Hyflow powder 2.00 0.01 Isopropyl alcohol loss 112.50 0.75

Liquid waste 0.00 0.00





TOTAL INPUT (Sum of all stages’ sub-total) 11860.5 79.07 TOTAL OUTPUT

(Sum of all stages’ sub-total) 11860.5 79.07






(4). Pregabalin


Pregabalin are presented here –


Ethyl cyano acetate was first condensed with isoveraldehyde to give the unsaturated ester

micheak addition of di ethyl malonate followed by acid–induced decarboxylation gave glutaric

acid which was then converted to the amide acid via the anhydride intermediate. Acid can be

resolved with (R) - methl benzyl amine to give the chiral acid in 98%. Hoffmann reaction

rearrangement of amide gave Pregabalin in good yield.


Isoveraldehyde Ethyl Cyano Acetate (Intermediate) Diethyl Malonate M/F: C5H10O M/F: C5H7O 2N M/F: C10H15O2N M/F: C7H12O4

M/W: 86.0 g/m M/W: 113.0 g/m M/W: 181.0 g/m M/W : 160.0 g/m





R-(+)-(α)-phenyl ethyl amine



c) Mass Balance :

Stages INPUT OUTPUT


Stage- I A Isoveraldehyde 300.00 2.40 Stage- IA 506.00 4.05

Ethyl cyano acetate 390.00 3.12 Solvent

Di-n-propyl amine 25.40 0.20 Hexane recovery 427.50 3.42

n-Hexane 450.00 3.60 Hexane loss 13.50 0.11

Liquid waste

Water 60.00 0.48

Hexane 9.00 0.07

Di-n-propyl amine 25.40 0.20

Organic 124.00 0.99




Sub-total of stage-IA 1165.40 9.32 Sub-total of stage-IA 1165.40 9.32

Stage- I B Stage - IA 506.00 4.05 Stage- IB 510.00 4.08

Diethyl malonate 530.00 4.24 Liquid waste

Water 60.00 0.48



Ethanol 150.00 1.20

Diethyl malonate 38.00 0.30

Solid waste

Gaseous waste- CO2 144.00 1.15


Sub-total of stage-IB 1036.00 8.29 Sub-total of stage-IB 1036.00 8.29

Stage- IC Stage- IB 510.00 4.08 Stage- IC 510.00 4.08

Urea 215.00 1.72 Liquid waste

Sodium hydroxide 45.00 0.36 Water 750.00 6.00

Water 750.00 6.00 Sodium hydroxide 45.00 0.36

Activated charcoal 5.00 0.04 Organic 52.00 0.42


Gaseous waste

Gaseous waste- NH3 46.00 0.37

Gaseous waste- CO2 117.00 0.94


Sub-total of stage-IC 1525.00 12.20 Sub-total of stage-IC 1525.00 12.20

Stage- II Stage- IC 510.00 4.08 Stage- II 408.00 3.26



Chloroform 5100.00 40.80 Solvent

Methanol 61.00 0.49 Chloroform recovery 4080.00 32.64

R-(+)-(α)-phenyl ethyl amine 205.00 1.64 Chloroform loss 255.00 2.04

Liquid waste 0.00 0.00





Stage- III Stage- II 408.00 3.26 Stage- III 285.00 2.28

Hydrochloric acid 150.00 1.20 Liquid waste

Water 300.00 2.40 Water 376.00 3.01

Sodium hydroxide 170.00 1.36 Organic 123.00 0.98

NaCl 244.00 1.95





Stage- IV Stage- III 285.00 2.28 Pregabalin - Product 250.00 2.00



Liq. Bromine 245.00 1.96 Liquid waste

Sodium hydroxide 123.00 0.98 Water 326.00 2.61

Activated charcoal 5.00 0.04 Nabr 312.00 2.50

Hyflow powder 3.00 0.02 Solid waste 8.00 0.06

Water 300.00 2.40 Gaseous waste- CO2 65.00 0.52










(5). Telmisartan


Telmisartan are presented here –


Bibenzimidazole & bromomethyl ester is condensed in presence of sodium methoxide in

DMF to give Telmi-I (Methyl 4’–[[4-Methyl-6(1-methyl-1H benzimidazol-2-yl)-2-propyl-1H

benzimidazole-1yl] methyl] biphenyl-2-carboxylate).

Telmi-I is hydrolyzed using potassium hydroxide in methanol & water mixture to give

Telmisartan.


Stage I- Preparation of Telmi- I



Stage II- Preparation of Telmisartan



c) Mass Balance :

Stage INPUT OUTPUT


Stage- I Bibenzimidazole 186.70 1.68 (Stage- i) - termi-i 261.40 2.35

Bromo methyl ester 187.30 1.69 Fugitive losses 0.00

Sodium hydroxide 33.10 0.30 Dimethyl formamide 38.80 0.35

Dimethyl formamide 969.60 8.73 Acetone 11.80 0.11

Acetone 295.10 2.66 Methanol 0.80 0.01

Water 2240.90 20.17 Wastewater

Water 2240.90 20.17

Recoveries (-) Sodium bromide 63.00 0.57

Dimethyl formamide 921.10 8.29 Organic waste

Acetone 280.30 2.52 Dimethyl formamide 9.70 0.09

Methanol 18.60 0.17 Acetone 3.00 0.03

Methanol 0.20 0.00

Organics 63.10 0.57

Sub-total of stage-I (Total - Recoveries) 2692.70 24.24 Sub-total of stage-I 2692.70 24.24

Stage- II (Stage- I) - Termi-I 261.40 2.35 Telmisartan 222.20 2.00



Potassium hydroxide 76.10 0.68 Fugitive losses

Acetic acid 470.60 4.24 Methanol 132.80 1.20

Methanol 3304.60 29.74 Wastewater

Activated carbon 13.10 0.12 Water 3660.10 32.94

Celite 8.80 0.08 Potassium acetate 133.00 1.20

Water 3817.00 34.36 Spent carbon

Spent carbon 21.90 0.20

Recoveries (-) Methanol 13.10 0.12

Methanol 3141.60 28.28 Organic waste 0.00 0.00

Methanol 33.20 0.30

Water 170.80 1.54

Organics 33.80 0.30


Sub-total of stage-II (Total - Recoveries) 4810.00 43.29 Sub-total of stage-II 4810.00 43.29








(6). Montekulast Sodium


Montekulast Sodium are presented here –


Manufacturing process of Montelukast Sodium completed in following stages:

Stage-I : 1-(Hydoxy methyl) cyclo propane Acetonitrile (MEC-4) is reacted with

methane sulfonyl chloride in presence of Diisoprpylethyl amine, and the product is

further treated with Thiol acetic acid to give MAN.

Stage-II : Condensation of MAN and (2-(2-(3(S)-(3-(2-(7-Chloro-2-quinolinyl) ethenyl)

phenyl-3-(methane sulfonyloxy) propyl)-2-propanol) (QUID-8) in the presence with

n-butyl lithium in the presence of toluene and Dimethyl foramide which on further

hydrolysis with Caustic lye to give MOK-1 –Nitrile

Stage-III & IV : MOK-1 Nitrile underwent sodium hydroxide hydrolysis in the

presence of toluene to give MOK-1. MOK-1 treated with t-butyl amine protection with

acetone acid to give MOK-2 butyl amine.

Stage- V : MOK-2 t-butylamine on further treatment with caustic flakes to give

sodium Montelukast (MOK-3). On further carbon purification with methanol to give

Pure MK-3 salt (Montelukast Sodium).






c) Mass Balance :

Stage INPUT OUTPUT


Stage- I N-vinyl pyrrolidone 108.10 1.44 Stage-I 96.50 1.29

Thiol acetic acid 74.00 0.99 Acetic acid 45.60 0.61

Diisopropyl ethylamine 6.00 0.08 Toluene recovered 1447.50 19.30


Water 1500.00 20.00 Toluene residue 45.00 0.60

Methane sulfonyl Chloride 15.00 0.20 N-vinyl pyrrolidone 23.70 0.32

Thiol acetic acid 16.30 0.22

Diisopropyl ethylamine 6.00 0.08

Methane sulfonyl chloride 15.00 0.20

Water 1500.00 20.00


Stage- II Stage-I 96.50 1.29 Stage-II 350.60 4.67

Thiophene-2-ethylamine 347.40 4.63 Water generated during reaction 11.10 0.15

Toluene 2000.00 26.67 Toluene recovered 1940.00 25.87

Water 1200.00 16.00 Toluene loss 10.00 0.13

Acetic acid 10.00 0.13 Toluene residue 50.00 0.67



Stage INPUT OUTPUT


Sodium chloride 50.00 0.67 Stage-I 17.90 0.24

Carbon 5.00 0.07 Thiophene-2-ethylamine 64.30 0.86


Carbon 5.00 0.07


Water 1200.00 16.00


Stage- III Stage-II 350.60 4.67 Stage-III (Crude Nateglinide Form H) 235.60 3.14

Sodium hydroxide 24.70 0.33 Sodium methoxide 21.70 0.29

Methanol 1219.80 16.26 Ammonia 6.80 0.09

Toluene 1700.00 22.67 Methanol recovered 1152.00 15.36

Water 1500.00 20.00 Methanol loss 6.00 0.08

Acetic acid 30.00 0.40 Methanol wastewater 12.00 0.16

Sodium chloride 70.00 0.93 Methanol residue 30.00 0.40

HCl for NaOH neutralization 7.90 0.11 Toluene recovered 1632.00 21.76

Toluene loss 6.80 0.09



Stage INPUT OUTPUT


Toluene residue 61.20 0.82

Stage-II 122.70 1.64

Methanol 6.90 0.09




Water 1484.00 19.79

NaCl from NaOH neutralization 12.70 0.17

Water from NaOH neutralization 3.90 0.05


Stage-IV Stage-III 235.60 3.14 Stage-IV 198.70 2.65

Tertiary butyl amine 29.40 0.39 Acetone recovered 1536.00 20.48

Acetone 1600.00 21.33 Acetone loss 7.20 0.10

Toluene 2000.00 26.67 Acetone residue 56.80 0.76

Carbon 5.00 0.07 Toluene recovered 1920.00 25.60

Toluene loss 10.00 0.13



Stage INPUT OUTPUT


Toluene residue 70.00 0.93

Stage-III 58.90 0.79

Tertiary butyl amine 7.40 0.10

Carbon 5.00 0.07


Stage- V Stage-IV 198.70 2.65 Montekulast Sodium 150.00 2.00

Sodium hydroxide 62.10 0.83 Tert-butylamine 18.00 0.24

Mdc 1800.00 24.00 Water generated during reaction 4.40 0.06

Acetic acid 25.00 0.33 MDC recovered 1737.00 23.16

Water 1800.00 24.00 MDC loss 9.00 0.12

Methanol 1000.00 13.33 MDC residue 54.00 0.72

Carbon 5.00 0.07 Methanol recovered 970.00 12.93

HCl for NaOH neutralization 47.60 0.63 Methanol loss 4.00 0.05

Methanol residue 26.00 0.35

Stage- IV 36.10 0.48




Stage INPUT OUTPUT


Carbon 5.00 0.07


Water 1747.90 23.30

NaCl from NaOH neutralization 76.30 1.02

Water from NaOH neutralization 23.50 0.31

Sub-total of stage-V 4938.40 65.84 Sub-total of stage-V 4938.40 65.84








(7). Ondansetron HCL


Ondansetron HCL are presented here –


1,2,3,9- tetrahydro-4H-carbazole is react with 2-methyl imidazole in presence of

hydrochloric acid and isopropyl alcohol to obtain Onadansetron hydrochloride.




c) Mass Balance :

Stage INPUT OUTPUT


Stage-I 1,2,3,9-tetrahydo-4H-carbazole-4-one 325.00 1.86 Stage-I 300.00 1.71

Methylene dichloride 2200.00 12.57 Solvent

Sodium hydroxide 65.00 0.37 Methylene dichloride recovery 1540.00 8.80

Process water 165.00 0.94 Methylene dichloride loss 110.00 0.63

Dimethyl formamide 127.00 0.73 Liquid waste

Tetra butyl ammonium bromide 2.00 0.01 Water 165.00 0.94

Methylene dichloride 550.00 3.14

Dimethyl formaide 101.00 0.58

NaOH 65.00 0.37





Stage-II Stage-I 300.00 1.71 Stage-II 350.00 2.00

Morpholine 30.00 0.17 Solvent 0.00



p-formaldehyde 45.00 0.26 Toluene recovery 1280.00 7.31


2-Methyl imidazole 124.00 0.71 Liquid waste

Process Water 300.00 1.71 Process water 328.00 1.87

Toluene 240.00 1.37

Morpholine 30.00 0.17



Organic waste 91.00 0.52


Stage-III Stage-II 350.00 2.00 Ondansetron HCL - Product 350.00 2.00


Process water 1350.00 7.71 Isopropyl alcohol recovery 1026.00 5.86

Hydrochloric acid 120.00 0.69 Isopropyl alcohol loss 85.00 0.49

Activated charcoal 7.00 0.04 Liquid waste 0.00 0.00

Hyflow powder 2.00 0.01 Water 1350.00 7.71


Organic 100.00 0.57







TOTAL INPUT (Sum of all stages’ sub-total) 8812.00 50.35 TOTAL INPUT







ANNEXURE - 5

Details of Storage Facilities for Products and Raw Materials

(A) Storage Facilities for PRODUCTS

Sr. No.

Name of PRODUCT Production Maximum Storage

for 5 days (MT)

Status Storage MOC Capacity No. of containers/

bags

Temp.

(° C)

Pressure

MT/ Month

MT/ Day

1. Chloro compound 10 0.33 1.67 solid HDPE drum 25 kg 67 ambient ambient

2. Pantaprazole sodium 5 0.17 0.83 solid HDPE drum 25 kg 34 ambient ambient

3. Phenylephrine HCl 2 0.07 0.33 solid HDPE drum 25 kg 14 ambient ambient

4. Pregabalin 2 0.07 0.33 solid HDPE drum 25 kg 14 ambient ambient

5. Telmisartan 2 0.07 0.33 solid HDPE drum 25 kg 14 ambient ambient

6. Montekulast sodium 2 0.07 0.33 solid HDPE drum 25 kg 14 ambient ambient

7. OndansetronHCl 2 0.07 0.33 solid HDPE drum 25 kg 14 ambient ambient

(B) Storage Facilities for RAW MATERIALS

Sr. No.

Name of RAW MATERIAL Consumption Maximum Storage

for 5 days (MT)

Status Storage MOC Capacity (kg)

No of containers

/ bags

Temp.

(° C)

Pressure

MT/ Month

MT/ Day

1. 10% NaOCl 13.95 0.47 2.33 solid HDPE drum 50 kg 47 ambient ambient

2. 1,2,3,9-Tetrahydo-4H-carbazole-4-one

1.86 0.06 0.31 solid HDPE drum 25 kg 13 ambient ambient

3. 2-Methyl imidazole 0.71 0.02 0.12 solid HDPE drum 25 kg 5 ambient ambient

4. Acetic Acid 12.61 0.42 2.10 liquid HDPE drum 210 kg 10 ambient ambient



Sr. No.


for 5 days (MT)


No of containers

/ bags

Temp.

(° C)

Pressure

MT/ Month

MT/ Day

5. Acetic acid glacial 6.25 0.21 1.04 liquid HDPE drum 210 kg 5 ambient ambient

6. Acetic anhydride 47.49 1.58 7.92 liquid HDPE drum 210 kg 38 ambient ambient

7. Acetone 55.14 1.84 9.19 liquid MS tank 15 KL 1 ambient ambient

8. Acidic isopropyl alcohol 1.83 0.06 0.31 liquid HDPE drum 210 kg 2 ambient ambient

9. Activated carbon 0.32 0.014 0.05 solid HDPE bags 25 kg 2 ambient ambient

10. Activated charcoal 0.20 0.01 0.03 solid HDPE bags 25 kg 2 ambient ambient

11. Ammonium carbonate 4.17 0.14 0.70 solid HDPE bags 50 kg 14 ambient ambient

12. An.aluminium chloride 0.12 0.004 0.02 solid MS drum 50 kg 1 ambient ambient

13. benzimidazole 1.68 0.06 0.28 solid HDPE bags 50 kg 6 ambient ambient

14. Bromo methyl ester 1.69 0.06 0.28 liquid HDPE drum 50 kg 6 ambient ambient

15. Celite 0.08 0.003 0.01 solid HDPE bags 25 kg 1 ambient ambient

16. Chloroform 136.55 4.55 22.76 liquid HDPE drum 180 litre 85 ambient ambient

17. Di isopropyl ethylamine 0.08 0.003 0.01 solid HDPE bags 25 kg 1 ambient ambient

18. Diethyl malonate 4.24 0.14 0.71 liquid HDPE drum 205 kg 4 ambient ambient

19. Diflouro methoxy-2-MB 3.68 0.12 0.61 solid HDPE drum 50 kg 13 ambient ambient

20. Dimethyl formamide (DMF) 19.00 0.63 3.17 liquid HDPE drum 210 litre 15 ambient ambient

21. Di-n-propyl amine 0.20 0.01 0.03 liquid HDPE drum 190 kg 1 ambient ambient

22. Dimethyl Sulfate 15.00 0.50 2.50 liquid HDPE drum 210 kg 12 ambient ambient

23. Ethyl acetate 4.67 0.16 0.78 liquid HDPE drum 210 litre 5 ambient ambient

24. Ethyl cyano acetate 3.12 0.10 0.52 liquid HDPE drum 210 kg 3 ambient ambient

25. Hydrogen peroxide (H2O2) 13.75 0.46 2.29 liquid HDPE drum 210 kg 11 ambient ambient

26. Hydrochloric acid 3.22 0.11 0.54 liquid HDPE drum 205 litre 3 ambient ambient

27. Hexane 21.31 0.71 3.55 liquid HDPE drum 210 litre 26 ambient ambient

28. Hydrogen gas 0.01 0.0003 0.002 gas MS cylinder 45 kg 1 ambient 200 kg/cm²



Sr. No.


for 5 days (MT)


No of containers

/ bags

Temp.

(° C)

Pressure

MT/ Month

MT/ Day

29. Isopropyl alcohol (IPA) 102.28 3.14 17.05 liquid HDPE drum 210 litre 81 ambient ambient

30. Potassium hydroxide (KOH) 7.18 0.24 1.20 solid HDPE bags 50 kg 24 ambient ambient

31. Isoveraldehyde 2.40 0.08 0.40 liquid MS drum 160 kg 3 ambient ambient

32. Liq. bromine 3.32 0.11 0.55 liquid Glass bottles 18 kg 31 ambient ambient

33. Methane sulfonyl chloride 0.20 0.01 0.03 liquid HDPE drum 25 kg 2 ambient ambient

34. Methanol* 174.32 5.81 29.05 liquid HDPE drum 210 litre 174 ambient ambient

35. Methyl maltol 12.50 0.42 2.08 solid HDPE drum 50 kg 42 ambient ambient

36. Methylene dichloride (MDC) 244.58 8.15 40.76 liquid HDPE drum 205 litre 150 ambient ambient

37. M-hydroxyacetophenone 2.33 0.08 0.39 solid HDPE drum 30 kg 13 ambient ambient

38. Morpholine 0.17 0.01 0.03 liquid HDPE drum 50 litre 1 ambient ambient

39. Sodium hydroxide (NaOH) 263.48 8.78 43.91 solid HDPE bags 50 kg 879 ambient ambient

40. NH3 liquor 22.63 0.75 3.77 liquid HDPE drum 200 litre 23 ambient ambient

41. N-methyl benzyl amine 1.72 0.06 0.29 liquid MS drum 30 kg 10 ambient ambient

42. N-vinyl pyrrolidone 1.44 0.05 0.24 liquid MS drum 210 kg 2 ambient ambient

43. Pantoprazole chloro compound 3.85 0.13 0.64 solid HDPE drum 25 kg 26 ambient ambient

44. P-formaldehyde 0.26 0.01 0.04 solid HDPE bag 25 kg 2 ambient ambient

45. POCl3 23.33 0.78 3.89 liquid HDPE drum 210 kg 19 ambient ambient

46. R-(+)-(α)-phenyl ethyl amine 1.64 0.05 0.27 liquid MS drum 210 kg 2 ambient ambient

47. Ranney nickel (10% charcoal) 0.17 0.01 0.03 solid HDPE drum 25 kg 2 ambient ambient

48. SOCl2 8.12 0.27 1.35 liquid HDPE drum 210 kg 7 ambient ambient

49. Sodium methoxide 7.50 0.25 1.25 solid HDPE drum 50 kg 25 ambient ambient

50. Sodium sulfate 2.08 0.07 0.35 solid HDPE bags 50 kg 7 ambient ambient

51. Sodium tungstate 0.62 0.02 0.10 solid HDPE bags 25 kg 4 ambient ambient



Sr. No.


for 5 days (MT)


No of containers

/ bags

Temp.

(° C)

Pressure

MT/ Month

MT/ Day

52. Sodium chloride 1.60 0.05 0.27 solid HDPE bags 50 kg 6 ambient ambient

53. Tertiary butyl amine 0.39 0.01 0.07 liquid HDPE drum 30 kg 3 ambient ambient

54. Thio acetic acid 0.99 0.03 0.17 liquid HDPE drum 30 kg 6 ambient ambient

55. Thiophene-2-ethylamine 4.63 0.15 0.77 liquid HDPE drum 210 kg 4 ambient ambient

56. Tetra butyl ammonium bromide 0.01 0.0003 0.002 solid HDPE bag 25 kg 1 ambient ambient

57. Toluene* 160.09 5.34 26.68 liquid MS drum 205 litre 151 ambient ambient

58. Urea 1.72 0.06 0.29 solid HDPE bag 50 kg 6 ambient ambient

NOTE : * Fall under the list of Hazardous Chemicals as per Manufacturing, Storage and Import of Hazardous Chemicals (MSIHC) Rules, 2000.



ANNEXURE - 6

Details of Solid/Hazardous Waste and Mode of Disposal

Sr. no.

Type of waste Hazardous waste

category*

Quantity per

month

Mode of storage & disposal

1. ETP sludge 34.3 0.5 MT Will be collected, stored and disposed to an authorized TSDF site.

2. MEE residue --- 30 kg Will be collected, stored and sent to a Common Hazardous Incineration Facility (CHWIF).

3. Sludge from wet scrubber

36.1 20 kg Will be collected, stored and disposed to an authorized TSDF site.

4. Process waste/ residue

36.4 0.5 MT Will be collected, stored and sent to a Common Hazardous Incineration Facility (CHWIF).

5. Spent carbon/ spent catalyst

28.2 10 kg Will be sent back for regeneration/ reactivation.

6. Used oil 5.1 0.5 kl Will be collected, stored reused as low grade lubrication and left over quantity (if any) sold to an authorized dealer or re-processor.

7. Discarded drum/ containers/carboys Plastic bags/ liners

33.3 600 Nos. Will be collected, stored and sold to an authorized/ registered recyclers.

8. Fly ash # # 10 MT Will be collected stored and given to nearest brick/cement manufacturing unit.

NOTE: * Hazardous waste category as per the Hazardous Waste (Management, Handling &

Transboundary Movement) Rules, 2008.

# Fly ash EXCLUDED from the category of Hazardous Waste (Management, Handling & Transboundary Movement) Rules, 2008.



ANNEXURE - 7

Details of Water Consumption and Wastewater Generation

Source of Water : Water will be met through tankers (local supplier) / bore-well.

WATER CONSUMPTION:

Sr.No. Description Water Consumption (kl/day)

Bore-well / tankers water

ETP treated/ recycled water TOTAL

1. Domestic 3 - 3

2. Industrial

DM / RO feed water # 30 - 30 Process # 11 kl/day

Boiler - makeup # 5 kl/day Cooling – makeup # 10 kl/day

Washing/other use - 7 7 3. Gardening - 18 18

TOTAL (1+2+3) 33 25 58

# Borewell/tanker water (30 kl/day) will be feed in DM/RO plant. DM/ RO treated water (26 kl/day) will be used for industrial purposes and DM/ RO reject will be sent to MEE/ETP.

WASTEWATER GENERATION:

Sr.No. Description Wastewater Generation (kl/day)

1. Domestic 2 * 2. Industrial

DM/RO reject 4

Process 13 Boiler- blow down 1

Cooling- purge 2

Washing/other use 7

Sub-total (2) 25 ** 3. Gardening -

TOTAL (1+2+3) 27

Note: * Domestic wastewater (sewage) will be disposed off through septic tank/soak pit system.

** High TDS effluent will be evaporated in MEE and condensate will be treated in ETP alongwith other trade effluent. A part of treated effluent will be re-used for washing/other purposes & remnant will be used on land for gardening purposes with in premises.



2 20

TOTAL WATER BALANCE DIAGRAM

NOTE:

All figures are given in kl/day. (MEE : Multiple Effect Evaporator, ETP: Effluent Treatment Plant)

Domestic wastewater (sewage) will be disposed off through septic tank/soak pit system.

High TDS effluent will be evaporated in MEE and condensate will be treated in ETP alongwith other trade effluent. A part of treated effluent will be re-used for washing/other purposes & remnant will be used on land for gardening purposes with in premises.

Industrial 30

Total Water Consumption

33

Process 11

Washing/ others

7

ETP 25

From Bore-well /Tanker

Cooling make-up

10

Boiler make-up

5

Gardening *

Domestic 3

15 (condensate)

13 7 2 (purge)

1 (blow-down)

DM/RO plant 30

4 (Reject)

26

MEE 17

Septic tank / soak pit system

2

Residue 1

Loss 1

10

10 5 11

7

20

7

18

2



DETAILS OF WASTE WATER TREATMENT & DISPOSAL

Domestic Wastewater (Sewage)

Domestic wastewater will be treated disposed off through septic tank/soak pit system.

Industrial Wastewater (Trade Effluent) High TDS effluent will be evaporated in MEE and condensate will be treated in ETP

alongwith other trade effluent. (Please refer Annexure- 7.1 for effluent treatment details) A part of treated effluent (7 kl/day) will be re-used for washing/other purposes and remnant (18 kl/day) will used on land for gardening purposes with in premises.

Break up details for our total land area is as given below.


1. Total built-up/ground coverage area (allocated for industrial uses) 4384.0

2. Road area 3260.3

3. Future expansion with parking 3480.4

4. Green belt area ( 35% of total land area ) 6074.3

TOTAL LAND AREA * 17199.0

* for more detail please refer Annexure- 2.1 Details of land area available for gardening/plantation are 6074.3 m².

Total treated effluent quantity 18,000 liters per day will be used for gardening/

plantation.

Thus, hydraulic load on our land area would be 2.96 liters/ m²/ day (18,000 liters per day/ 6074.3 m²).

M/s. Rheomax Gums LLP.


ANNEXURE – 7.1

Details of Effluent (Wastewater) Management System

Details of Effluent Treatment Plant (ETP)

(Schematic flow Diagram of Effluent Treatment Plant is attached under).

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ANNEXURE – 8

Details of Electricity and Fuel

Details of Electricity/Power

Description Estimated Power Requirement Source

Electricity 125 kVA Gujarat Electricity Board

Details of Fuel

Description Type of Fuel Fuel Consumption Rate

Source

Boiler (2 ton/hour ) Coal 160 kg/hr

Indigenous / Imported

D.G. Set * (100 KVA) HSD 5 Lit/hr Local supplier

Note : * D.G. set will be used only in case of emergency/power failure.

M/s. Rheomax Gums LLP.


ANNEXURE – 8.1

Details of Stack/Vent, Flue Gas and Air Pollution Control Measures

Sr. no.

Stack/vent attached to

Type & quantity of fuel

Height of the stack/vent

(m)

Diameter of the stack/vent

(m)

Expected emission

Air pollution control

measures

1. Boiler (2 Ton/hour)

Coal (160 kg/hr)

20 0.45 PM < 150mg/m3

SO2 < 100 ppm

NOx < 50 ppm

Multicyclone / Bag filter

2. Distillation Unit

-- 15 0.15 VOC Water Scrubber

3. D.G. Set * (100 KVA)

HSD * (5 Lit/hr)

15 0.15 PM < 150 mg/m3

SO2 < 100 ppm

NOx < 50 ppm

Not Applicable *

Note : * HSD (High Speed Diesel) for D.G. set will be used as fuel. It would not be out of place to mention that these are comparatively clean fuel and D.G. set will be used only in case of emergency / power failure.

Annexures - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0... · 2014-11-21 · ANNEXURE - 3 : Details of Production Capacity and Raw Material ANNEXURE

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