Annex 4: Limit values table Annex 4: 規制値表 Annex 4 Limit values table / 規制値表 Any value measured in the laboratory (which is measured in mg/kg, μg/m 2 or w-%) must be below the specified limit to obtain the certif- icate. 試験機関で測定された試験結果(測定単位は mg/kg、 μg/ m 2 、 又は w-%) は全て、特定された規制値未満でなけれ ば、認証とはなりません。 Limit values and fastness, part 1 (The testing procedures are described in a separate document) Product Class I Baby II in direct contact with skin III with no direct contact with skin IV Decoration material pH value 1 4.0 - 7.5 4.0 - 7.5 4.0 - 9.0 4.0 - 9.0 Formaldehyde, free and partially releasable [mg/kg] Law 112 n.d. 2 75 150 300 Extractable (heavy) metals [mg/kg] Sb (Antimony) 30.0 30.0 30.0 As (Arsenic) 0.2 1.0 1.0 1.0 Pb (Lead) 0.2 1.0 3 1.0 3 1.0 3 Cd (Cadmium) 0.1 0.1 0.1 0.1 Cr (Chromium) 1.0 2.0 2.0 2.0 Cr(VI) 0.5 Co (Cobalt) 1.0 4.0 4.0 4.0 Cu (Copper) 25.0 4 50.0 4 50.0 4 50.0 4 Ni (Nickel) 5 1.0 6 4.0 7 4.0 7 4.0 7 Hg (Mercury) 0.02 0.02 0.02 0.02 Ba (Barium) 1000 1000 1000 1000 Se (Selenium) 100 100 100 100 Heavy metals total content [mg/kg] As (Arsenic) 100 100 100 100 Cd (Cadmium) 40.0 40.0 3 40.0 3 40.0 3 Hg (Mercury) 0.5 0.5 0.5 0.5 Pb (Lead) 90.0 90.0 3 90.0 3 90.0 3 Pesticides [mg/kg] 8,9 Sum 9 0.5 1.0 1.0 1.0 Glyphosate and salts for conventional cotton 5 5 5 5 Pesticides under observation 9 u.o. 10 1 Exceptions for products which must be treated wet during the further processing: 4.0 - 10.5; for foams: 4.0 - 9.0; for film materials (e.g. polyolefin films) with incorporated Calciumbicarbonate/ carbonate, which do not have directly contact to skin: 4.0 – 10.0 2 n.d. corresponds according to „Japanese Law 112“ test method with an absorbance unit less than 0.05 resp. 16 mg/kg 3 No requirement for accessories made from glass 4 No requirement for accessories and yarns made from inorganic materials, respecting the requirements regarding biological active products 5 Including the requirement by REACH-Regulation Annex XVII, Entry 27 6 For metallic accessories and metallized surfaces: 0.5 mg/kg 7 For metallic accessories and metallized surfaces: 1.0 mg/kg 8 For natural fibres only 9 The individual substances are listed in Annex 5 10 u.o. = under observation; substance is tested randomly and result provided for information purposes; presently not regulated indeed 29.01.2020 Edition 02.2020 1 | 12
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Annex 4: Limit values tableAnnex 4: 規制値表
Annex 4 Limit values table / 規制値表
Any value measured in the laboratory (which is measured in mg/kg, μg/m2 or w-%) must be below the specified limit to obtain the certif-icate.
Limit values and fastness, part 1 (The testing procedures are described in a separate document)
Product ClassI
BabyII
in direct contact with skinIII
with no direct contact with skin
IVDecoration material
pH value1
4.0 - 7.5 4.0 - 7.5 4.0 - 9.0 4.0 - 9.0
Formaldehyde, free and partially releasable [mg/kg]
Law 112 n.d.2 75 150 300
Extractable (heavy) metals [mg/kg]
Sb (Antimony) 30.0 30.0 30.0
As (Arsenic) 0.2 1.0 1.0 1.0
Pb (Lead) 0.2 1.03 1.03 1.03
Cd (Cadmium) 0.1 0.1 0.1 0.1
Cr (Chromium) 1.0 2.0 2.0 2.0
Cr(VI) 0.5
Co (Cobalt) 1.0 4.0 4.0 4.0
Cu (Copper) 25.04 50.04 50.04 50.04
Ni (Nickel)5 1.06 4.07 4.07 4.07
Hg (Mercury) 0.02 0.02 0.02 0.02
Ba (Barium) 1000 1000 1000 1000
Se (Selenium) 100 100 100 100
Heavy metals total content [mg/kg]
As (Arsenic) 100 100 100 100
Cd (Cadmium) 40.0 40.03 40.03 40.03
Hg (Mercury) 0.5 0.5 0.5 0.5
Pb (Lead) 90.0 90.03 90.03 90.03
Pesticides [mg/kg]8,9
Sum9 0.5 1.0 1.0 1.0
Glyphosate and salts for conventional cotton 5 5 5 5
Pesticides under observation9 u.o.10
1Exceptions for products which must be treated wet during the further processing: 4.0 - 10.5; for foams: 4.0 - 9.0; for film materials (e.g. polyolefin films) with incorporated Calciumbicarbonate/carbonate, which do not have directly contact to skin: 4.0 – 10.0
2n.d. corresponds according to „Japanese Law 112“ test method with an absorbance unit less than 0.05 resp. 16 mg/kg
3No requirement for accessories made from glass
4No requirement for accessories and yarns made from inorganic materials, respecting the requirements regarding biological active products
5Including the requirement by REACH-Regulation Annex XVII, Entry 27
6For metallic accessories and metallized surfaces: 0.5 mg/kg
7For metallic accessories and metallized surfaces: 1.0 mg/kg
8For natural fibres only
9The individual substances are listed in Annex 5
10u.o. = under observation; substance is tested randomly and result provided for information purposes; presently not regulated indeed
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Annex 4: Limit values and fastness, part 2
Annex 4 Limit values and fastness, part 2
(The testing procedures are described in a separate document)
11For coated articles, plastisol prints, flexible foams, and accessories made from plastics
12For all materials containing polyurethane or other materials which may contain free carcinogenic arylamines
13The sum of cleavable cancerogenic arylamine and of possibly also as chemical residue present free cancerogenic (same) arylamine has to be also 20 mg/kg
10u.o. = under observation; substance is tested randomly and result provided for information purposes; presently not regulated indeed
14The sum of cleavable aniline and of possibly also as chemical residue present free aniline has to be also 20 mg/kg (product class I) resp. 50 mg/kg (product classes II till IV)
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Annex 4: Limit values and fastness, part 3
Annex 4 Limit values and fastness, part 3
(The testing procedures are described in a separate document)
Product ClassI
BabyII
in direct contact with skinIII
with no direct contact with skin
IVDecoration material
Chlorinated benzenes and toluenes [mg/kg]9
Sum 1.0 1.0 1.0 1.0
Polycyclic aromatic hydrocarbons (PAHs) [mg/kg]15
Benzo[a]pyrene 0.5 1.0 1.0 1.0
Benzo[e]pyrene 0.5 1.0 1.0 1.0
Benzo[a]anthracene 0.5 1.0 1.0 1.0
Chrysene 0.5 1.0 1.0 1.0
Benzo[b]fluoranthene 0.5 1.0 1.0 1.0
Benzo[j]fluoranthene 0.5 1.0 1.0 1.0
Benzo[k]fluoranthene 0.5 1.0 1.0 1.0
Dibenzo[a,h]anthracene 0.5 1.0 1.0 1.0
Sum 24 PAHs9 5.0 10.0 10.0 10.0
Biological active products
none16
Flame retardant products
General
none
(10 mg/kg; each; for sum SCCP + MCCP50 mg/kg)16,17
15For all synthetic fibres, yarns, or threads and for plastic materials
16With exception of treatments accepted by OEKO‑TEX® (see actual list on http://www.oeko-tex.com)
17Accepted flame retardant products do not contain any of the banned flame retardant substances listed in Annex 5 as active agent
18For fibre, yarns, fabrics and coated articles (e.g. artificial leather) as well as foams (EVA, PVC), where solvents are used during production
19Exception for products which must undergo further industrial production stages (heat process in wet or dry stage preferred, but also other steps are possible): maximal 3.0 %
20For materials made of acrylic (PAN), elastane (EL) / polyurethane, polyimide and aramides as well as coated (PU-, PVC-, PVC-plastisol-, PVDC-, PVC-copolymer) textiles. / For materials made of acrylic (PAN), elastane (EL) / polyurethane, polyimide and aramides as well as coated (PU-, PVC-, PVC-plastisol-, PVDC-, PVC-copolymer) textiles / Für Materialien aus Polyacrylnitril (PAN), Elastan (EL).
10u.o. = under observation; substance is tested randomly and result provided for information purposes; presently not regulated indeed
21For all materials with a water, soil or oil repellent finish or coating
10u.o. = under observation; substance is tested randomly and result provided for information purposes; presently not regulated indeed
22Any other substance having linear or branched perfluorooctyl derivatives with the formula C8F17- as a structural element, including its salts, except those derivatives with the formula C8F17-X, where X= F, Cl, Br or, C8F17-SO2X', C8F17-C(=O)OH or C8F17-CF2-X' (where X'=any group, including salts)
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Annex 4: Limit values and fastness, part 5
Annex 4 Limit values and fastness, part 5
(The testing procedures are described in a separate document)
Other banned dyestuffsC.I. Generic Name C.I. Structure number CAS-Nr.C.I. Basic Green 4 (chloride) 569-64-2C.I. Basic Green 4 (free) 10309-95-2C.I. Basic Green 4 (oxalate) 2437-29-8,
Annex 5: Compilation of the individual substances for Annex 4, part 5
Annex 5 Compilation of the individual substances for Annex 4, part 5
Forbidden flame retardant substancesName CAS-Nr. AcronymPolybromobiphenyls (Polybrominated biphenyls) 59536-65-1 PBBsMonobromobiphenyls various MonoBBDibromobiphenyls various DiBBTribromobiphenyls various TriBBTetrabromobiphenyls various TetraBBPentabromobiphenyls various PentaBBHexabromobiphenyls various HexaBBHeptabromobiphenyls various HeptaBBOctabromobiphenyls various OctaBBNonabromobiphenyls various NonaBBDecabromobiphenyl 13654-09-6 DecaBBPolybrominated diphenyl ethers various PBDEsMonobromodiphenylethers various MonoBDEsDibromodiphenylethers various DiBDEsTribromodiphenylethers various TriBDEsTetrabromodiphenylethers various, 40088-47-9 TetraBDEsPentabromodiphenylethers various, 32534-81-9 PentaBDEsHexabromodiphenylethers various, 36483-60-0 HexaBDEsHeptabromodiphenylethers various, 68928-80-3 HeptaBDEsOctabromodiphenylethers various, 32536-52-0 OctaBDEsNonabromodiphenylethers various, 63936-56-1 NonaBDEsDecabromodiphenylether 1163-19-5 DecaBDETri(2,3-dibromopropyl)phosphate 126-72-7 TRISTris(2-chloroethyl)phosphate 115-96-8 TCEPHexabromocyclododecane and all main diastereomeres identified (alpha-, beta-, gamma-) various, 3194-55-6,
Surfactant, wetting agent residuesName CAS-Nr. AcronymNonylphenol various NPOctylphenol various OPHeptylphenol various HpPPentylphenol various PePNonylphenolethoxylates various NP(EO)Octylphenolethoxylates various OP(EO)
Surfactant, wetting agent residues under observationName CAS-Nr. Acronym4-tert-butylphenol 98-54-4 BP
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Annex 5: Compilation of the individual substances for Annex 4, part 6
Annex 5 Compilation of the individual substances for Annex 4, part 6
Other chemical residuesName CAS-Nr. AcronymAniline 62-53-3Benzene 71-43-2Bisphenol A (4,4‘-Isopropylidenediphenol) 80-05-7 BPADiazene-1,2-dicarboxamide 123-77-3 ADCADimethylfumarate 624-49-7 DMFuPhenol 108-95-2o-Phenylphenol 90-43-7 OPPQuinoline (Chinoline / Benzo[b]pyridine) 91-22-5Tris(2-chloroethyl)phosphate 115-96-8 TCEPTris(4-nonylphenyl, branched and linear)phosphite with 0.1% w/w of 4-nonylphenol, branched and linear various TNPP
Chemical residues under observationName CAS-Nr. Name CAS-Nr.1,2-Diethoxyethane 629-14-1 2-Methoxypropanol 1589-47-52-Methoxyethylacetate 110-49-6
Annex 5: Compilation of the individual substances for Annex 4, part 7
Annex 5 Compilation of the individual substances for Annex 4, part 7
PFCs, Per- and polyfluorinated compoundsName CAS-Nr. AcronymPerfluorooctane sulfonic acid and sulfonates 1763-23-1, et. al. PFOSPerfluorooctane sulfonamide 754-91-6 PFOSAPerfluorooctane sulfonfluoride 307-35-7 PFOSF / POSFN-Methyl perfluorooctane sulfonamide 31506-32-8 N-Me-FOSAN-Ethyl perfluorooctane sulfonamide 4151-50-2 N-Et-FOSAN-Methyl perfluorooctane sulfonamide ethanol 24448-09-7 N-Me-FOSEN-Ethyl perfluorooctane sulfonamide ethanol 1691-99-2 N-Et-FOSEPerfluoroheptanoic acid and salts 375-85-9, et. al. PFHpAPerfluorooctanoic acid and salts 335-67-1, et. al. PFOAPerfluorononanoic acid and salts 375-95-1, et. al. PFNAPerfluorodecanoic acid and salts 335-76-2, et. al. PFDAHenicosafluoroundecanoic acid and salts 2058-94-8, et. al. PFUdATricosafluorododecanoic acid and salts 307-55-1, et. al. PFDoAPentacosafluorotridecanoic acid and salts 72629-94-8, et. al. PFTrDAHeptacosafluorotetradecanoic acid and salts 376-06-7, et. al. PFTeDA
Others
Further Perfluorinated carboxylic acidsPerfluorobutanoic acid and salts 375-22-4, et. al. PFBAPerfluoropentanoic acid and salts 2706-90-3, et. al. PFPeAPerfluorohexanoic acid and salts 307-24-4, et. al. PFHxAPerfluoro(3,7-dimethyloctanoic acid) and salts 172155-07-6, et. al. PF-3,7-DMOA
Perfluorinated carboxylic and sulfonic acids under observation2,3,3,3-tetrafluoro-2-(heptafluoro propoxy)propionic acid , its salts and its acyl halides various1H,1H,2H,2H-Perfluorodecanesulphonic acid and its salts 39108-34-4, et. al. 8:2 FTS
Perfluorinated sulfonic acidsPerfluorobutane sulfonic acid and salts 375-73-5, 59933-66-3, et. al. PFBSPerfluorohexane sulfonic acid and salts 355-46-4, et. al. PFHxSPerfluoroheptane sulfonic acid and salts 375-92-8, et. al. PFHpSHenicosafluorodecane sulfonic acid and salts 335-77-3, et. al. PFDS
Partially fluorinated carboxylic / sulfonic acids7H-Perfluoro heptanoic acid and salts 1546-95-8, et. al. 7HPFHpA2H,2H,3H,3H-Perfluoroundecanoic acid and salts 34598-33-9, et. al. 4HPFUnA1H,1H,2H,2H-Perfluorooctane sulfonic acid and salts 27619-97-2, et. al. 1H,1H,2H,2H-