Amet,TM Update EU GHS CLP SDS Authoring Guide

A GUIDE TO FREELY AVAILABLE AND SEARCHABLE INTERNET DATABASES

FOR FREELANCE START-UPS AND SMALL BUSINESS

SAFETY DATA SHEETS WRITERS

Theodore M Amet

Global HazCom Documents Writer

Racine Wisconsin June 2012

Preface The ldquoAhardquo moment for writing this guide came when I started writing Safety Data Sheets (SDSs) at Easterday

Fluid Technologies LLC a manufacturer of industrial ink and ink related products Since chemicalsraw

substances are used in product manufacturing the law requires manufacturers to provide customers Material

Safety Data Sheets

Although I was trained to draft and write Material Safety Data Sheets with MSDS authoring software

(eg EnviroMSDS SAP The WERCS) those platforms were not available to me at Easterday We used

Microsoft Office Suite to prepare GHS compliant Safety Data Sheets (according to EU Directives and Guidance

Documents) to accompany ink and ink related products for clients in Europe and elsewhere

Our efforts in researching guidance documents physical chemical and toxicological properties of

substances and country specific regulatory information on the Internet (in addition to product literature from

chemical manufacturers) yielded adequate information for creating Safety Data Sheets according to European

Union regulations and standards using only Microsoft Word rather than a specialized and expensive authoring

program

We believe this guide will be invaluable to writers of Safety Data Sheets everywhere especially those in

small companies and those wanting to use it as a reference document when their Safety Data SheetsMaterial

Safety Data Sheets authoring system is down

With your help we will be able to keep abreast with European Chemical Regulations and update this

guide as new regulations become available If you know of additional links to free chemical environmental

health and toxicological databases on the Internet please e-mail the link(s) to us at safetywritergmailcom

We will promptly add it in this guide Please acknowledge this guide in Section 15 of your Safety Data Sheet

whenever you use it as one of your sources for information

Thank you for your participation

i

Authorrsquos Biography

Dr Theodore M Amet is Manager Global GHS Compliant SDSs Labels and MSDSs Projects at Easterday

Fluid Technologies LLC in Saint Francis Wisconsin He holds a Bachelorrsquos degree in Agriculture Science

from the University of Liberia and worked as a Seed Technologist Assistant at WARDA (West Africa Rice

Development Association) before joining the faculty in the College of Agriculture and Forestry University of

Liberia Subsequently he earned a Masterrsquos degree in Genetics (major) and Development Studies (minor) from

the University College of Wales-Swansea (Swansea University) and a PhD in Animal Science and

Biotechnology from North Carolina State University Raleigh North Carolina That was followed by a

postdoctoral appointment in Molecular Reproductive Biology in the Department of Biochemistry Molecular

Biology and Cell Biology at Northwestern University Evanston Illinois He also trained in clinical

experimental embryology at the Reproductive Genetics Institute in Chicago Illinois He earned an MBA in

General Management from Loyola University Chicagorsquos School of Business Administration Chicago Illinois

His exposure to chemical regulations came when he worked in the Department of Global Safety

Assessment and Regulatory Affairs (GSARA) at SC Johnson amp Son Inc of Racine Wisconsin He served as

Raw Substance Steward (RSS) MSDS drafter and Regulatory Research Analyst while at SC Johnson

Dr Amet is a member of the American Chemical Society (ACS) and the Society for Chemical Hazard

Communication (SCHC)

ii

DISCLAIMER

This guide was compiled as a service to Safety Data Sheet writers everywhere It neither reflects the

views of others nor does it endorse one link over the other

Internet links cited in this guide and views expressed in the various sections are mine alone Information

in this document is based on data gathered from many sites No warranty is expressed regarding the accuracy of

data obtained from various chemical health toxicological and environmental databases

Responsibility for the accuracy and completeness of information contained herein rests with the users

who must satisfy themselves that the data is appropriate for their needs

It is always a good practice to consult a sectional expert when writing sections of the Safety Data Sheet

to clarify and simplify technical matters

iii

SAMPLE SAFETY DATA SHEET according to Regulation (EC) No 19072006 (REACH) Annex II

Product Name Fendell Cleaning Solvent Blend No 3 Page 1 of 25 Product Code FCSB No3 Prepared Date 06272011 Version 100 Printing Date 08102011

1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING

Information about the company and product (s) (substancemixture) shall be provided to the Safety Data Sheet

(hereinafter ldquoSDSrdquo) writer by a senior authoritymanager (eg regulatory product safety EHS etc) in the

company The writer shall be provided with a numbering system (for generating version(s) of the SDS) as

specified in ECHArsquos Guidance document (Guidance on the compilation of safety data sheets

httpguidanceechaeuropaeudocsdraft_documentsfourth_draft_sds_Guidance_july_2011pdf) Information

on REACH SDS compilation can be found on ECHA Website (httpechaeuropaeuhome_enasp)

Each title page of the hazard communication document (SDS) shall have unique identifiers (product name

date(s) page number version number etc) Use wording that is concise and understandable to end users Avoid

technical and trade jargons whenever possible Blank subsections are not allowed Preferred SDS language shall

be the language of the country where the product is being placed

2 HAZARDS IDENTIFICATION

The following databases which are currently available on the Internet will be used to assessclassify hazardous

substances in an experimental dangerous preparation mixture Fendell Cleaning Solvent Blend (FCSB) No 3

ChemSub Online httpchemsubonlinefr

ESIS European chemical Substances Information System

httpecbjrceceuropaeuesis

Hazardous Substances Information System (HSIS) Online Database httphsisasccgovau

ChemBlink (Chinese Online Database of Chemicals from around the world) httpwwwchemblinkcom

The Good Scents Company httpwwwthegoodscentscompanycom

Product Name Fendell Cleaning Solvent Blend No 3 Page 2 of 25 Product Code FCSB No 3 Prepared Date 06272011 Version 100 Printing Date 08102011

The Chemical Library httpchemlibceficorgindexasp

Letrsquos evaluate the components in our experimental mixture Fendell Cleaning Solvent Blend (FCSB) No 3 The product contains six substances with their weightvolume as indicated below

1 3-Butanone 40 ndash 60

2 n-Butanol 30 ndash 60

3 Ethanol 10 ndash 40

4 Isopropanol 10 ndash 20

5 Toluene 1 ndash 5

6 Xylene 1 ndash 5

Table 1 Components of FCSB No3 identification numbers and corresponding weights Substance Name CAS EC No Index No Weight ()

3- Butanone 78-93-3 201-159-0 606-002-00-3 40 ndash 60

n-Butanol 71-36-3 200-751-6 603-004-00-6 30 ndash 60

Ethanol 64-17-5 200-578-6 603-002-00-5 10 ndash 40

Isopropanol 67-63-0 200-661-7 603-117-00-0 10 ndash 20

Toluene 108-88-3 203-625-9 601-021-00-3 1 ndash 5

Xylene 1330-20-7 215-535-7 601-022-00-9 1 ndash 5

Source of chemical identification numbers The European Inventory of Existing Commercial chemical Substances (EINECS) Information System (httpecbjrceceuropaeuesisindexphpPGM=ein) Table 2 Hazards classification of FCSB No3 components (according to Directive 199945EC)

Substance CAS Risk Phrases (R) Safety Phrases (S) DH Symbol(s)

3- Butanone 78-93-3 R11 R36 R66 R67 S2 S9 S16 F Xi

n-Butanol 71-36-3 R10 R22 R3738-41 R67 S2 S79 S13 S26 S3739 S46 Xn Ethanol 64-17-5 R11 S2 S7 S16 F Isopropanol 67-63-0 R11 R36 R67 S2 S7 S16 S2425 S26 F Xi Toluene 108-88-3 R11 R38 R4820 R63

R65 R67 S2 S3637 S46 S62 F Xn

Xylene 1330-20-7 R10 R2021 R38 S2 S25 Xn

An interesting work on ink is available at httpmonographsiarcfrENGMonographsvol65mono65-5pdf

Product Name Fendell Cleaning Solvent Blend No 3 Page 3 of 25 Product Code FCSB No3 Prepared Date 06272011 Version 100 Printing Date 08102011 Hazard ClassificationSymbols

Risk Phrases (R-) 10 11 2021 22 36 3738 38 41 4820 63 65 66 67

Safety Phrases (S-) 2 7 79 9 13 16 2425 25 26 3637 3739 46 62

21 Classification of the substance or mixture

Product definition Mixture

211 Classification according to Regulation (EC) No 12722008 [CLPGHS]

A free German database (BG RCI ndashGisChem information system on hazardous substances Labels and GHS

classification for preparationsmixtures) will be used for classification (see link below) Input Risk

and Safety Phrases and DangerHazards symbols in Table 2 into the German database ( available at httpwwwgischemdeghskonverterindexhtm) Include the following specifications when inputting the data

UN Number 1210 Physical State Liquid Packing Group II Hazard Class 3 (omit ndash Do not input Hazard Class It shall come handy in Section 14)

Please note that the above specifications will vary depending on the hazards of the preparationmixture

Here is the classification according to Regulation (EC) No 12722008 (CLPGHS) for our mixture

Flammable liquids Category 2 H225 Acute toxicity (dermal) Category 4 H312 Acute toxicity (inhalation) Category 4 H332 Acute toxicity (oral) Category 4 H302 Aspiration hazard Category 1 H304 Skin corrosionirritation Category 2 H315 Serious eye damageEye irritation Category 1 H318 Reproductive toxicity D Category 2 H361d Specific Target Organ Toxicity ndash Single exposure Respiratory tract irritation Category 3 H335 Specific Target Organ Toxicity ndash Single exposure Narcotic effects Category 3 H336 Specific Target Organ Toxicity ndash Repeated exposure Category 2 H373

Always have the ldquoGlobally Harmonized Systems (GHS) within the EUrdquo poster by Sigma-Aldrich on hand

It comes in handy when the domain of a hazard code (HXXX) is to be validated Find it at

Product Name Fendell Cleaning Solvent Blend No 3 Page 4 of 25 Product Code FCSB No3 Prepared Date 06272011 Version 100 Printing Date 08102011 httpwwwsigmaaldrichcomsafety-centerglobally-harmonizedhtml [click on GHS Poster EU (PDF)]

212 Classification of the mixture according to European Directives 199945EC or 67548EEC

Highly flammable Irritating to eyes Harmful by inhalation in contact with skin and if swallowed

22 Label elements

Labelling according to Regulation (EC) No 12722008 [CLP]

Hazard Pictograms

Signal word Danger

[Find other hazard pictograms at httpwwwcptecorgsymbols_referenzenhtml]

Hazard statement(s) EUH066 Repeated exposure may cause skin dryness or cracking H225 Highly flammable liquid and vapour H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H312 Harmful in contact with skin H315 Causes skin irritation H318 Cause serious eye damage H332 Harmful if inhaled H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H361d Suspected of damaging the unborn child H373 May cause damage to organ(s) through prolonged or repeated

exposurehellip Precautionary statement(s) P210 Keep away from heatsparksopen flameshot surfaces ndash No

smoking P233 Keep container tightly closed P261 Avoid breathing dustfumegasmistvapoursspray P264 Wash hands with soap and plenty of water after handling P280 Wear protective glovesprotective clothingeye protectionface protection P310 Immediately call a POISON CENTER or doctorphysician P403 + P233 Store in a well-ventilated place Keep container tightly closed P501 Dispose of contentscontainer to be in accordance with localregionalnational regulations


Find the CLP document at httpeur-lexeuropaeuLexUriServLexUriServdouri=OJL200835300011355ENPDF

221 Classification according to Directive 67548EEC or 199945EC

Hazard symbol(s) F Flammable Xi Irritant Xn Harmful Risk (R)-phrase(s) R11 Highly flammable R2021 Harmful by inhalation and in contact with skin R22 Harmful if swallowed R36 Irritating to eyes R3738 Irritating to respiratory system and skin R38 Irritating to skin R41 Risk of serious damage to eyes R4820 Harmful danger of serious damage to health by prolonged exposure through inhalation R63 Possible risk of harm to the unborn child R65 Harmful may cause lung damage if swallowed R66 Repeated exposure may cause skin dryness or cracking R67 Vapours may cause drowsiness and dizziness Safety (S)-phrase(s) S2 Keep out of the reach of children S79 Keep container tightly closed and in a well ventilated place S13 Keep away from food drink and animal feedingstuff S16 Keep away from sources of ignition ndash No smoking S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3637 Wear suitable protective clothing and gloves S3739 Wear suitable gloves and eyeface protection S46 If swallowed seek medical advice immediately and show this container or label S62 If swallowed do not induce vomiting seek medical advice immediately and show this container or label

23 Other hazards Substance meets the criteria No

for PBT according to Regulation (EC) No 12072006 P Not available B Not available T No Annex XIII


Substance meets the criteria Not available for vPvB according to Regulation (EC) No 12072006 Annex XIII

Other hazards which do not Not available result in classification This product is classified as dangerous according to Directive 199945EC and its amendments

3 COMPOSITIONINFORMATION ON INGREDIENTS

We shall use CLPGHS Database Annex VI to Regulation (EC) No 12722008 on Classification Labelling and Packaging of Dangerous Substances Here is the link httpesisjrceceuropaeuindexphpPGM=cla Enter either index number EC number CAS number or substance name in the appropriate field See Table 1 31 Description of the substancemixture Mixture Table 3 Hazard ingredients Chemical Substance

No Name

CAS

EC No

Index No

RRN

Weight ()

Classification 67548EEC Regulation (EC) No 12722008[ CLP]

Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67

Flam Liq 2 H225 Eye irrit H319

3 STOT SE H336 EUH066

[1] [2

n-Butanol 71-36-3 200-751-6 603-004-00-6 - 30 ndash 60 R10 Xn R22

Xi R3738 R41 R67 x 4

3

]

Flam Liq 3 H226 Acute ToH302

3 STOT SE H335 Skin Irrit 2 H315 Eye Dam 1 H318 STOT SE H336

[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225

RRN REACH Registration Number (readily available on the Internet for these chemicals)

od Prepa 72 Version 100 Printing Date 08102011

Product NamProduct C

e Fendell Cleaning Solvent Blee FFSB N

nd No 3

Page 7 of 25 red Date 062o3 011

ca

No

EC No

Chemical CAS RRNSubstance

ame

Index No

Weight ()

Classifi tion

N

67

548EEC Regulation (EC)

No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0

- 10 ndash 20 R11 Flam Liq 2

E 3

] -

FXi R36 R67 H225

Eye Irrit 2 H319 STOT SH336

[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3

8-88-3 03-625- 01-021-00- - 1 ndash 5 F R11 Repr Cat 3 R63

Flam Liq 2 H225 Repr 2 H361d

Asp ToxH304 STOT RE 2 H373

Skin Irrit 2 H315 STOT SE H336

[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]

See Section 2 for the full text of the R- phrases declared

ion 2

nts

[2]

R10 Xi R38 [concentration limit

above

Flam Liq 3 H226 Acute Tox 4

H332 Acute Tox 4H312

Skin Irrit 2315 See Sect for the full textof the H- statemedeclared above

[1]

32 Additional information

[1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No 12072006 Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No 12072006 Annex XIII

Occupational exposure limits if available are listed in Sectio

Product Name Fendell Cleaning Solvent Blend No 3 of 25 Product No FCSB No3 pa 2011 Version 100 nti 2011

substancemixture and appropriate first aid measures before hand here a DS Haz-Map site EHS sites

The Em ertauthority on Occupational Health and Saf

Us

n 8 Page

red Date 0627ng Date 0810

8 Pre Pri

esearch occupational hazards of the

4 FIRST AID MEASURES

RT re various sources to turn to for information (eg product (M) S

ergency Response Guidebook [ERG 2008] etc Consult an expety for assistance when writing this section

eful links

Haz-Map

httphazmapnlmnihgov Database of hazardous chemicals and occupational diseases

International Programme on Chemical Safety (IPCS INCHEM)

httpwwwinchemorg afety information

Database of chemical s

CDC ndash NIOSH Pocket Guide to Chemical Hazards (NPG) httpwwwcdcgovnioshnpg A source of information on general industrial hygiene for hundreds of chemical used in the work environment

International Chemical Safety Cards

httpwwwcdcgovnioshipcsnicstarthtml fety and health information on chemical

Provides sa

Environment Health and Safety Online (EHSO) httpwwwehsocomhmergphp

information

The Emergency Response Guide (ERG 2008) and other hazards

The Merck Manuals httpwwwmerckmanualscom A trusted source for medical information CAMEO Chemicals httpwwwcameochemicalsnoaagov

rvices US DHHS Chemical Information Se httpsisnlmnihgovchemicalhtml The Ships Captainrsquos Medical Guide

ationmcga-dqs_st_shs_seafarer_information- httpwwwdftgovukmcamcga-seafarer_inform apt_medical_guidehtm

First-Aid Information

medicalmcga-dqs_st_shs_ships_c

dsghazcomfirstaidhtml

Prod No 3 Page 9 of 25 Prod Prepared Date 06272011 Version 100 Printing Date 08102011

41

l first aid measures should be followed In case of persistent adverse effects seek immediate medical attention Remove contaminated clothing and shoes promptly and wash

thoroughly before re-use

associated repeated and prolonged occupational overexposure to solvents with permanent brain

and nervous system damage Intentional misuse by deliberately ting and inhaling the contents may be harmful or fatal

httpwwwoshagovuct Name Fendell Cleaning Solvent Blend uct No FCSB No3

Description of first aid measures

411 General information Genera

412 Following inhalation NOTE Reports have

concentra

Emergency responders should use positive air supplied respiratory protection when removing the victim from area Remove person to fresh air If not breathing administer CPR until help arrives or the victim starts to breathe on their own Give artificial respiration if breathing has stopped Seek medical

15 minutes Use soap if available Remove contaminated clothing including shoes after

on

414 Following eye contact minutes ilt the head to prevent chemical from transferring to

after

415 Following ingestion t conscious or having convulsions Seek

medical attention immediately Contact Poison Control Center at

provided based on symptoms

h effects both acute and delayed nervous system depression Frequent or prolonged skin contact

n

Prepared Date 06272011 ersion 100 Printing Date 08102011

re-exposure to this material Small amounts of this liquid may be may

layed health effects such as inflammation of the lungs (pulmonary edema) and infection of the bronchi

43 eatm t needed

attention immediately 413 Following skin contact If exposure occurs immediately flush the affected area thoroughly with water for at least flushing has begun Wash clothing before re-use If irritati persists seek medical attention

Immediately flush affected eye with water for at least 20

the unaffected eye Seek medical attention without delay flushing

DO NOT INDUCE VOMITING if swallowed Rinse mouth ou with water Dilute with milk or water Never give anything to drink if the victim is un

once 416 Self protection of the first aider Appropriate personal protective attire should be worn 417 Note to the doctor Suitable medical intervention should be 42 Most important symptoms and Irritating to eyes skin and respiratory tract upon exposure Hig

vapour concentrations are irritating to eyes nose throat and lungs may cause unconsciousness or other signs of central

may irritate the skin and cause skin rash (dermatitis) May cause skin sensitization an allergic reaction which becomes evident o

Product Name Fendell Cleaning Solvent Blend No 3 Page 10 of 25 Product No FCSB No 3 V

drawn into the lungs by either swallowing or vomiting This cause severe and de (bronchopneumonia) Ingestion may cause irritation of digestive

track and diarrhea

Indication of any immediate Always get immediate medical attentionadvice when symptomsmedical attention and special persist tr en

5 FIRE FIGHTING MEASURES

Useful resources Carriage of Dangerous Goods [International Maritime Dangerous Goods (IMDG) Code] It has information on fire fighting procedures Find it here httpwwwkrscokrkordnRul1025pdf You may want to check CAMEO Chemicals for additi

eoche icalsn aagoonal guide to fire fighting Here is the link to CAMEO Chemicals

httpwwwcam m o v fire chief in your citytown may be able to provide information The

ire Fi ting easur s

SPECIFC GRAVITY 0806 68o F

NITION TEMPERATURE 9610 F

1 Extinguishing media

Suitable extinguishing media Either allow fire to burn out under controlled conditions or

f ut hazard

If a spill has not ignited use water spray to disperse the vapours

ater jet

2 lammable flash point

There is a danger of explosion when container is heated or in fire Toxic gases will form upon combustion Vapour may

may accumulate in low or confined areas or travel to a

roducts r

roduc ame endel Clean g Solv nt Bleroduct No FCSB No3 Prepared Date 06272011

Printing Date 08102011

) be

res U e of S BA may not be required

ecomposition products may cause health hazards Cool containers exposed to fire with water spray

on hazardous chemicals fire fighting procedures and personal protective equipment for fire fighters

F gh M e The following applies to 3-Butanone (from CAMEO Chemicals) FLASHPOINT 26oF EXPLOSIVE LIMITS LEL 18 UEL 110

o AUTOIG 5

extinguish with alcohol type or all purpose type foam or dry chemical powder Try to cover liquid spills with appropriate foam Use water spray to cool fire exposed surfaces Avoid spraying water directly into storage containers due to danger o boilover Shut off fuel to fire if possible to do so witho

Unsuitable extinguishing media Do not use high volume w 5 Special hazards arising from Flammable liquid may release vapours that form f the mixture mixtures when temperatures are at or above the

considerable distance to a source of ignition and flash back Avoid runoff into storm sewers and ditches Hazardous combustion p Smoke fumes oxides of carbon irritating or toxic vapours o gases P t N F l in e nd No 3 Page 11 of 25 PVersion 100 53 Advice for fire-fighters Protective equipment for Respiratory and eye protection gear is required for fire fire fighters fighting personnel Full protective equipment (Bunker Gear and a self-contained breathing apparatus (SCBA) should used for all indoor fires and any significant outdoor fires Use portable fire extinguisher for small outdoor fi s C

54 Additional information Exposure to d

Move un os nt f re if this can be done exp ed co ainers rom fi area

1 Personal precautions protective equipment and emergency procedures

11

rotect e equ ment

sources of ignition Notify the appropriate authorities immediately

e

spill Isolate hazard area and deny entry to unauthorized or unprotected personnel Contain spilled liquid

ith sand or earth DO NOT use combustible materials such as saw dust Absorb spill with an inert material (eg sand or earth)

ner

espiratory and eye protection gear is required for emergency personal protective equipment responders Full protective equipment (Bunker Gear) and a

r

may not

31 On water If spill in water remove from water surface by skimming lv nt Ble 5

011

f allowed by local environmental gulatory agencies you may use a suitable dispersant

or osal

f ontractor

inated absorbent material may pose similar hazard as the spill product

to o her se ions

without risk

6 ACCIDENTAL RELEASE MEASURES

6 6 For non-emergency personnel P iv ip Wear suitable personal protective equipment (eg clothing gloves safety goggles and maskrespirator) Ensure adequate

ventilation remove all

Emergency procedures Eliminate ignition source Shut off leak if safe to do so Tak all additional action necessary to prevent and remedy the adverse effects of the w Then place in a chemical waste contai 612 For emergency responders R self-contained breathing apparatus (SCBA) should be used fo all indoor fires and any significant outdoor fires Use portable

fire extinguisher for small outdoor fires Use of SCBA be required

62 Environmental precautions Avoid dispersal of spilt material and runoff into soil storm sewers and ditches which lead to natural waterways or the immediate environment Inform the relevant authorities if the product has entered into the environment 62 Methods of containment and cleaning up 6Product Name Fendell Cleaning So e nd No 3 Page 12 of 2Product No FCSB No 3 Prepared Date 06272Version 100 Printing Date 08102011 or with suitable absorbent material and place in appropriate disposal container I

re 632 On groundfloor Contain spill and absorb with an inert material (eg dry sand earth) Then place in an appropriate waste container for disp according to local regulations Large spills should be disposed o via a licensed waste disposal establishmentc 633 Other information Contam 64 Reference t ct

See Section 1 for emergency contact information (should be available in an actual document ndash (M)SDS) See Section 8 for information on appropriate personnel protective equipment See Section 13 for additional disposal information

7 HANDLING AND STORAGE

71 Precautions for ha safe ndling

11 rotect e measures ist

Do not eat drink or smoke when using this product Use only

in use Do not reuse container Avoid release to the environ-

12 drinking and smoking in areas where this product hygiene is handled used and stored Wash hands before eating drinking

and smoking and at the end of the working period Contamina- ted work clothing and protective equipment should not be brought into eating smoking and drinking areas Wash soiled

ng before re-using

torage includi

echnical measures and orage conditions

tore and use away from sparks heat open flames and other ignition sources Ground and bond containers and recei-

roduc ame Fendell Cleaning Solvent Ble Page 13 of 25 roduct No FCSB No 3 Prepared Date 06272011

3 pecifi end use(s)

7 P iv Wear appropriate personal protective equipment Do not get in eyes on skin or on clothing Do not breathe vapour or m with adequate ventilation Keep away from sources of ignition Keep only in original container Keep tightly closed when not ment 7 Advice on general occupational Avoid eating clothi 72 Conditions for safe s ng any incompatibilities T Store at ambientroom temperature Protect from extreme cold st and heat Store in a segregated and approved area Store away from strong oxidizing agents Loosen closure cautiously with non-sparking tools before opening Keep only in original container S ving equipment Store locked up Store away from direct sun -light in a dry cool and well-ventilated area Containers that have been opened must be carefully resealed and kept upright to prevent leakage Ground and bond containers when transferring material Ventilation required along storage floor P t N nd No 3 PVersion 100 Printing Date 08102011 Packaging materials Steel drum HDPE (High Density Poly Ethylene) -2 plastic bottles and containers 7 S c Recommendations For industrial use only Industrial sector specific Unavailable solutions There is no workplace exposure data available on the product itself Data for a solvent in the mixture is

8 EXPOSURE CONTROLPERSONAL PROTECTION

provided for EU member countries where available 81 Control parameters 811 Occupational Exposure Limits (OELs) International Exposure Limits can be found at this site httpwwwdguvdeifaengestislimit_valuesindexjsp

os re Li it(s) -Occupational Exposure Limit Values

tanone)

Table 4 Occupational Exp u m OELs

(3-BuEC No 201-159-0

-Butanone g term limit

(8-hour TWA) Short term limit (15-minutes period)

CAS No 78-93-3 Chemical Name Lon3

Limit value type

Country ppm mgm3 ppm mgm3 Austria 100 295 200 590 MAK Belgium 200 600 300 900 VLEP Bulgaria - 590 - 1000 OEL (MH Decree No 132003) Croatia 200 600 300 900 EU OEL (TWASTEL) Czech Republic 2034 600 3051 900 PEL NPK-P Denm 145 100 ark 50 290 OEL Estoni a 200 600 300 90 EU OEL (TWASTEL) 0 Finland - - 100 300 OEL (HTP-arvot) France 200 600 300 900 VLEs Germany 200 600 200 600 MAK Greece 200 600 300 900 L EU OEHungary - 600 - 900 AgraveK CK Ireland 200 600 300 900 OELV (NAOSH 82007) Italy 200 600 300 900 ACGIH Latvia 67 200 300 900 AER Lithuania 200 600 300 900 IPRV TPRV Netherlands - 590 - 900 MAC-TGG Norway 75 220 - - Gjennomsnittsverdier (average values)Poland - 450 - 900 NDS NDSCh Portugal 200 - 300 - VLE-MP VLE-CD Romania 63 200 101 300 VLA (TWA STEL) Slovakia 200 600 - 900 NPEL

Note Highlig num valu ere o d from urces ame Fende an olve nd N Page 14 of 25 o FCSB H Prepared Date 06272011 00 Printing Date 08102011

upat Expo3-Buta

hted bers es w btaine various Internet soProduct N

Nll Cle ing S nt Ble o 3

Product A-1 Version 1

Occ ional sure Limit Values ( none)

EC No 201-

78-

one

Long term lim(8- ur TW

Sho lim(15 tes period)

159-0 CAS No 93-3 Chemical Name 3-Butan

it ho A)

rt term it -minu

Country pp 3 ppm mgm

Limit value type

m mgm 3 Spain 200 600 300 900 VLA-ED VLA-EC Sweden 50 50 100 300 NGV 1 KTV Switzerland 200 590 200 590 VME VLE

Turkey 200 600 300 900 TWA STELUnited 200 600 300 899 WEL (EH402005) Kingdom

Note H

ighlighted numbersvalue urces

me oring pr redients with exposure limits procedure rsonal workplace atmosphere or biological monitoring may

be required to determine the effectiveness of the ventilation or other control measures andor the necessity to use respiratory

protective equipment Reference should be made to European ard EN 689 for methods for the assessment of exposure

inhal nts and national guidance cumen s for the determination of hazardous bstanc

NEL e occu mit value table for guidance

Predicted effect concentrations Not available

81

iedetoolsgebotszeichen) (Directives and Amendments) (9368EEC 9395EEC and 9658EC)

yewear complying with an approved standard should be sk assessment indicates this is necessary to avoid

exposure to liquid splashes mist or dust

ning Solvent Blend No 3 Page 15 of 25 o uct No FCSB No 3 Prepared Date 06272011

approved standard should be worn at all times when handling this in necessary

Body protection Personal protective equipment for the body should be selected

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and

s were obtained from various Internet so

Recom nded monits

If this oduct contains ing pe

Stand by ation of chemical age do ts for method su es Derived effect lev

els [D ] Se pational exposure li

(PNEC Summary)

Exposure controls

811 Appropriate engineering Provide adequate local exhaust ventilation to maintain worker controls below exposure limits The use of mechanical ventilation controls is recommended whenever this product is used in a confined space is heated above ambient temperatures or is agitated Use explosion-proof ventilation equipment 82 Personal protective equipment (httpwwwchem 821 Eye and face protection Safety e used when a ri Product Name Fendell Clea

r dPVersion 100 Printing Date 08102011 822 Skin protection

Hand protection Chemical-resistant impervious gloves complying with an chemical products if a risk assessment indicates

based on the task being performed and the risks involved and should be approved by a specialist before handling this product

the risks l d d pr by a specialist before invo ved an shoul be ap oved

3 Respiratory protection Use approved respiratory protection equipment Respirator on should be based on the form and concentration of

contaminants in the air and in accordance with local regulations

ronmental protection legislation Ensure that emission is at the

91 l and

Colour Characteristic

dour resho

Meltingfreezing point [ F] Not available F]

F] vaporation rate (n-Butyl Acetate 1)

Flammability (solid gas) Not available ailable

Lower flammability Not available

Relative density Not available

Produc lean g Solv nt Ble Page 16 of 25 Product CSB No 3 Prepared Date 06272011 Version Printing Date 08102011

si of Liquid CST 25 C Not available

92 elevant physicochemical properties here 101 Highly flammable Avoid ignition sources Strong oxidizing

handling this product 8 selecti

84 Environmental exposure Emission from ventilation or work process equipment should be controls checked to ensure they comply with the requirements of envi-

acceptable level

9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physica chemical properties [Note Physicochemical analysis was not done on the mixture]

Physical state Liquid

Odour Solvent odour O th ld Not determined pH Not available

o

Initial boiling pointrange [o Not available Flash point [o Not available

E Not available =

Upper flammability Not av

Vapour pressure mm Hg 75 o F Not available Vapour density (Air = 1) Not available

Solubility in water Wt 68 o F Not available Partition coefficient n- Not available octanolwater t Name Fendell C in e nd No 3

No F 100

Auto-ignition temperature Not available Decomposition temperature Not applicable

o Visco tyExplosive properties Not available Oxidizing properties Not available Other information Provide other r

10 STABILITY AND REACTIVITY

Reactivity

agents 102 Chemical stability Stable under normal conditions 103 ct ns ymerization will not occur

104 nd sources of ignition 105 g agents

ition products

httpecbjrceceuropaeuesisindexphpPGM=dat) IARC (httpwwwiarcfr

Possibility of hazardous rea io Hazardous pol

Conditions to avoid Open flames a

Incompatible materials Strong oxidizin 106 Hazardous decompos Burning can produce oxides of carbon

11 TOXICOLOGICAL INFORMATION

Useful links IUCLID DB ( ) tox etnlmand HSDB (http n nihgovcgi-binsishtmlgenHSDB)

111 Information on toxicological effects 1112 Mixture There are no data available on the product itself Data on a

ubstance name Test Species Route of Administration DoseResult Exposure Remark

substance in the mixture is provided

11121 Relevant effects (a) Acute toxicity S

LD50 Rat Oral gt 636 mgkg - - Toluene LDLO Human Oral 50 mgkg - -

LC50 Mouse Inhalation vapour 6405 -7436 ppm 6 hour (s) - TC Human Inhalation vapour 200 ppm - - LO

LD Rabbit Dermal 12124 mgkg - -

Identifiers

50

LD50 Mouse Intra-peritoneum (ip)

66 mgkg - - EC No 203-625-9 CAS No 108-88-3

LD50 Rat Intra venous (iv) 1960 mgkg - - Index No 601-021-00-3 LC50 Rat Inhalation vapour 281 mgl 4 hour (s) -

ConclusionSumm Vapours may cause drowsiness and dizziness Product Name Fendell Cleaning Solvent Blend No 3 Page 17 o

ary f 25

No FCSB No 3 Prepared Date 06272011 Printing Date 08102011

th and hor concentrations ma sciousne or other s of central nervous ression

Skin contact nged co irritate the skin and kin rash (dermati skin se tization

hic evident on r xposure

ll injure eye

Product Version 100 (b) Irritation Inhalation May cause irritation to e nose throat

y cause uncon lungs Hig

vap ss sign system dep

Frequent or prolo ntact may

cause s tis) May cause nsi an allergic reaction w h becomes e-e to this material

Eye contact Severely irritating If not removed promptly wi

tissue w m n age hich ay result in permane t dam

dryness or cracking

(d) Sensitization tion above stated occu-

pational exposure limits

(e) Single dose toxicity (f) Repeated dose toxicity e (g) it

) Mutagenicity No information but adverse effects unlikely

) Toxicity for reproduction No known significant effects or critical hazards

or critical hazards (carcinogenic mutagenic or

r ductio )

drawn into the lungs by either swallowing or vomiting This may cause severe and

such inflammation of the lungs ( pulmonary edema) and infection of the bronchi(broncho-

ion may cause irritation to the digestive tract or diarrhea

13 Potential chronic health effects There is no evidence that exposure to 3-Butanone alone effects

However simultaneous over-exposure to 3-Butanone and eurotoxic

roduct Name Fendell Cleaning Solvent Blend No 3 Page 18 of 25 o 3 te 06272011


effects of n-Hexane There is no reported human evidence

14 ther form ion

httptoxnetnlmnihgovcgi-binsish

Ingestion May cause irritation of the digestive tract and diarrhea (c) Corrosivity Severely irritating to eyes Repeated exposure may cause skin

May cause skin sensitization and or respiratory system irrita due to extended exposure of the preparation

No data available

No data availabl

Carcinogenic y No known significant effects or critical hazards

(h (i 11122 CMR effects No known significant effects toxic for rep o n 112 Potential adverse health effects Small amounts of this liquid may be delayed health effects as pneumonia) Ingest 1 causes progressive or irreversible neurotoxic n-Hexane can potentiate the known irreversible nPProduct No FCSB N Prepared DaVersion 100 that these neurotoxic effects occur when exposure to both chemicals is maintained below established regulatory limits 1 O in at The mixture is not likely to be carcinogen in humans

SECTION12 ECOLOGICAL INFORMATION

Useful links IUCLID DB (httpecbjrceceuropaeuesisindexphpPGM=dat) and HSDB ( tmlgenHSDB) N d on this mixture Ecotoxicological information on componeote Ecological testing has not been conducte nts

in the mixture is presented below 121 Toxicity 3 l data -Butanone [CAS 78-93-3] ecotoxicologicaA re time (h) Species Value (mgl)quatic toxicity Effect dose ExposuA (s) Pimephales promelas 3220 cute fish toxicity LC50 96 hourAcute D (s) Daphnia magna aphnia toxicity EC50 48 hour gt 520 Acute algae toxicity EC3 s Scenedesmus quadricauda ge 4300 7 day n-Butanol [CAS 71-36-3] ecotoxicological data Aquatic toxicity Effect dose Exposure time (h) Species Value (mgl)Acute fish toxicity LC 96 hour (s) Pimephales promelas 50 lt 1630 Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 1983 Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus gt 500

thanol [CAS 64-17-5] ecotoxicE ological data Aquatic toxicity Effect dose Exposure time (h) Species Value (mgl) Acute fish toxicity LC50 96 hour (s) Alburnus alburnus 10000 - 11500 Acute Daphnia toxicity LC50 48 hour (s) Daphnia magna 9268 - 14221 Acute algae toxicity EC50 Not specified Chlorella pyrenoidosa 9310 Isopropanol [CAS 67-63-0 e] cotoxi a cological datAquatic toxicity Effect dose e (h) gl)Exposure tim Species Value (mAcute fish toxicity LC50 (s) 96 hour Pimephales promelas 9640 Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 13299 Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus gt 1000 Toluene [CAS 108-88- toxicol3] e oc ogical data Aquatic toxicity Eff tec dose e (h) mgl)Exposure tim Species Value (Acute fish toxicity LC50 96 hour (s) Pimephales promelas 28 Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 115 Acute algae toxicity EC50 48 hour (s) Scenedesmus subspicatus 125 - 160

ell CProduct Name Fendroduct No FCSB N

lean n i g Solve age 19 of 25

o 3 red Date 06272011 Printing Date 08102011

30-20

nt Blend No 3

PP PrepaVersion 100 Xylene [CAS 13 -7] ecotoxicological data Aquatic toxicity Effect dos time (h lue (mgl)e Exposure ) Species VaAcute fish toxicity LC50 s) 0 96 hour ( Cyprinus carpio gt 78Acute invertebrate toxici 50 s) ty LC 48 hour ( Palaemonetes pugio 085Acute algae toxicity Mortality Unknown Scenedesmus quadricauda gt 200 122 Persistence

and degradability a

eman ues) uantit ation ra (inoculum)

No data av ilable for the product

(Biochemical Oxygen D d ndash BOD valSubstance name Q y Degrad te () Incubation time Evaluation3-Butanone Unknown 83 5 days Sewage

n-Butanol Unknown 66 5 days Sewage sludge Ethanol 10 mgl 74 5 days Filtered sewage seed Isopropanol l 20 days Filtered sewage seed 10 mg 78

Toluene Unknown Completely Short duration Sewage seed Xylene Isomers 72 20 days Activated sewage

Theoretical Oxygen and (Th

tive po a availab

(BCF ndash Bio Concentration Factor) log n-octanolwater partition coefficient (log Kow) estimate

Dem OD) value 123 Bioaccumula tential No dat le

Substance name Estimated BCF log Kow Remarks 3-Butanone 3 029 Low bioaccumulation n-Butanol 3 88 Low bioaccumulation 0Ethanol 3 -031 Low bioaccumulation Isopropanol 05 accum3 0 Low bio ulation Toluene 13 (eel) 90 (Golden ide) 73 Low t ate bi2 o moder oaccumulation Xylene 4 2 accum6 ndash 23 3 Low bio ulation

1 bility in soil data a K ndash The soil absorptio ent

e name K value Remarks (soil mobility)

24 Mo No vailable oc n coeffici

Substanc oc

3 Very high mobility -Butanone 29 n-Butanol 72 High mobility Ethanol 1 Very high mobility Isopropanol 25 Very high mobility Toluene variable High to moderate mobility Xylene 39 ndash 365 for individual isomers mobility Very high to moderate

125 BT and vPvB assessment ta a le ta a le

s or critical hazards

Produc Clean Blend No 3 Page 20 of 25 Produc No 3 06272011 Versio 08102011

he information in this section contains generic advice and guidance Waste CodesWaste Designations Support Company ( httpwwwwastesupportcoukewc-

Results of PPBT No da

No da vailab

vPvB vailab 126 Other adverse effects No known significant effect

t Name Fendell ing Solvent t No FCSB Prepared Date n 100 Printing Date

13 DISPOSAL CONSIDERATIONS

Taccording to EWCAVV can be found at Waste codes)

PT WG aste Management (httpwwwgptwastecomeuropean-waste-catalogue-codesasp) 360 Environment n_waste_catalogue_codes(httpwww360environmentalcouklegislationwaste_legislationeuropea ) and in

and H zardouw

the European Waste Catalogue a s Waste List Find the latter information at ttp wwenvironieenPublicationsEnvironmentWasteWEEEFileDownLoad1343enpdfh

Packaging and packaging waste

Directives and Amendments 9463E d 2 C an 2005 0EC 131 Waste treatment methods Product Methods of disposal

The generation of waste should be avoided or minimized whenever possible Empty containers or liners may retain

some product residues This material and its container must not

is- posal of recovered and surplus material Incinerate or recover

be disposed of in a safe way Waste product residue should be disposed of via the foul sewer Consult an expert on the d by distillation Ensure disposal is in compliance with current government requirements and ensure conformity with local authority regulations Packaging waste Methods of disposal The generation of waste should be avoided or minimized

henever possible Waste packaging should be recycled or nd local authority regulations

Consult your StateLocal Land Waste Management Authority

99 waste not otherwise specified

he a code (08 03 99) indicates it is a hazardous waste

ay

and runoff to come in contact with soil waterways drains and

Page 21 of 25 Prepared Date 06272011

ersion 100 Printing Date 08102011

UK Department of Transportation Dangerous Goods Database

w dispose of according to state a Waste codes waste designation 08 03 according to EWCAVV 15 01 01 paper and cardboard packaging 15 01 02 plastic packaging The listed waste numbers according to the European Waste Code (EWC) are intended as recommendation for users The final classification has to be worked out together with the local waste disposal companyauthority

Note An asterisk [] next to t

Special precautions This material and its container must be disposed of according to

local authority regulations Empty containers or packaging m contain some product residue Avoid dispersal of spilt material sewers Product Name Fendell Cleaning Solvent Blend No 3 Product No FCSB No 3 V

14 TRANSPORTATION INFORMATION

Useful links

httpwwwdftgovukdangerous-goods- databasexgovk3w=bl1000ampxgovf0p=|xgovs9k=dft|xgovr3h=dangerousgoods|xgovc8h=1000|xgovk3w=bl1000|ampxgovd2v=enampxgovj6d=138566a41b22fdc972c0f470249d4e76a2b97234

UK Department of Transportation [find ldquoThe Ship Captainrsquos Medical Guiderdquo]

httpwwwdftgovuk

UK Department of Transportation (Carriage of dangerous goods) httpwww2dftgovukpgrfreightdgt1 [Access the Dangerous Goods Database]

Carriage of Dangerous Goods ndash International Maritime Dangerous Goods Code

pdfmsin0664anxpdf httpwwwmardepgovhkenmsnote

wwwgeneralcargoshipcomIMDG-codehtml http The Swedish Transport Agency Freight--CargoBulk-CargoesEmergency-ProcedureshttpwwwtransportstyrelsenseenShipping

IATA Dangerous Goods Regulations

httpwwwiataorgwhatwedocargodangerous_goodsDocumentsDGR52TrainingRequirements15pdf

RoadSafe Europe httpwwwroadsafeeuropecom

Civil Aviation Authority Requirements and Guidance Material for Operators httpwwwcaacoukdocs33CAP20789pdf European Aviation Safety Agency

httpwwweasaeuropaeuapprovals-and-standardisationsafety-assessment-of-foreign-aircraft-SAFAphp

International Civil Aviation Organization (ICAO) ndash Dangerous Goods gerousGoods

ICAO Technical Instructions for the Safe Transport of Dangerous Goods by Air

httpwwwicaointanbFLSDan

sGoodsTechnicalInstructions httpwwwicaointanbFLSDangerou

Technical Instructions for the Safe Transport of Dangerous Goods

ticaonetdcs92849284_2007_2008_addcorr_enpdf httpwwwicaoin

Prod Page 22 of 25 Product No FCSB No 3 Prepared Date 06272011


IATA Dangerous Goods Regulation Manual 2010

uct Name Fendell Cleaning Solvent Blend No 3

Version 100

10-(dgr) httpwwwpdfqueencomiata-dangerous-goods-regulations-manual-20

ADRRID ADNADNR IMDG ICAO-TIIATA-DGR

141 UN No 1210 1210 1210 1210 14

Material Material Material 2 Proper Shipping Name Printing Ink Related Printing Ink Related Printing Ink Related Printing Ink Related

Material

143 Transport hazard class 3 3 3 3

144 Classification code F1

F1

F1

F1

145 Packing group II II II II 146 Hazard label

147 Environmental M lluta hazard No No No

arine po nt No

148 Special provision(s) 163 163 163 Not available 640C 640C

Additional Information Hazard identification number 33 EAC 3Y Ltd Qty LQ6

y UnitTransport Categor

Excepted Quantities

2 240L

E2 Packaging P001 PP1 9 Portable Ta and Bulk

MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-

Ltdand Excpt Qty LQ6 E2

- -

(EmS)

- -

-

Emergency schedules

Fire F-E Spillage S-D Ltd Qty 5l

Excp tyt Q E2

-

Aircraft Quantity limitation

10 L

353 0 L

Cargo Aircra nly Quantity limita

600 L

struction 364

Passenger and Cargo

Packing instructions Y341

5

ft otion

Packaging in

-

-

1 in bulk according to Annex II of MAR 7378 and IB e No Product Name Fendell Cleaning Solvent Blend No 3 Page 23 of 25 Product FCSB No ate 06272011 Version 100 011 151 Safety health an ental re lation for the substance ture EU Regulation (EC) No 19072006 (REACH)

49 Transport POL C Cod t applicable

No 3

Prepared DPrinting Date 08102

d environm gulationslegis specific or mix

15 REGULATORY INFORMATION

REACH Status n compliance Annex XIV ndash List of substances subject to authorization

I

Substances of Very High Concern Candidate List

None of e compon nts in the mixture are listed Annex XVII ndash Re arket and use of certain dangerous

substances mixtures and articles [httpeceuropae orschemicalsfilesmarkrestrannex_xvii_301206_enpdf

th e

striction on the manufacture placing on the m

uenterprisesect ]

Contain oluene (Note product is nots T for sale to the general public and is not intended for use in adhesives and spray paints) Other EU regulations European inventory All components are listed or exempt

Endocrine Disrupters Compon no d chemsecorglistsin-list-20ents t liste (http www ) [EU Directive 200060EC Annex X and Regulation (EEC)

No 79393] Integrated Pollution Prevention Components not listed

and Control List (IPPC) ndash Water

onal regulations

and Control List (IPPC) ndash Air Integrated Pollution Prevention Components not listed Internati

Chemical Weapons Convention List Sch

Chemical Weapons Convention List Chemical Weapons Convention List Schedule III Chemicals

edule I Chemicals Schedule II Chemicals Not listed Not listed Not listed

152 Chemical Safety Assessment out for this

mixture


ool for freelance safety data sheet writers The mixture is fictitious and information in the document is based

idance on the Compilation of Safety Data Sheets (draft October 2010) Please be reminded that the

document does not purport to be a legal advice on compiling dance on the Compilation of Safety

Data Sheets (draft October 2010) for the European Union is normative

roduct The product has been classified and marked in accordance with

161 Indication of changes

Date of previous issue None To comply with Regulation (EC) No 12722008 [CLPGHS]

Date of issue August 10 2011 Prepared by Theodore M Amet Manager

Global GHS Compliant SDSs Labels and MSDSs Projects

No Chemical Safety Assessment has been carried

Product Name Fendell Cleaning Solvent Blend No 3 Page 24 of 25Product No FCSB No 3 Prepared Date 06272011 V

16 OTHER INFORMATION

NOTE This Safety Data Sheet was created as a guide teaching aid and training t

on suggestions in the Gu

Safety Data Sheets Gui

P

EU DirectivesOrdinance on Hazardous Materials

Revisions Nature of version Conforms to Regulation (EC) 19072006 (REACH) Annex II Version 100

162 Abbreviations and acronyms ADN Accord europeacuteen relative au transport international des marchandises dangereuses par voie de navigation inteacuterieure ADNR Accord europeacuteen relative au transport international des marchandises dangereuses par marine sur le Rhin

ur le transport des merchandises dangereuses par route (European Agreement concerning the International Carriage of Dangerous Goods by Road)

BG RCI (Germany) Berufsgenossen CAS Chemical Abstracts Service CDC Centers for Disease Control an CLP Regulation on the Classification

H DangerHazard DGR Dangerous Goods Regulation

DPD Dangerous Preparations Direct DSD Dangerous Substances Directive (Directive 67548EEC)

European Commission nt H lth an Safe

1CLP Document - REGULATION (EC) No 12722008 OF THE EUROPEAN PARLIAMENT AND

16 December 2008 on classification labeling and packaging of substances s 67548EEC and 199945EC and amending

(EC) No 19072006 Produc eaning Solv nt Ble 5 Produc CSB No 3 Prepared Date 06272011 Versio Printing Date 08102011

EINECS European Inventory of ExismS Emergency Schedule

ces Information System

nized System of Classification and Labelling of Chemicals national Agency for Research on Cancer

n and equipment of Ships Carrying Dangerous

Chemical Information Database Dangerous Goods by Air

63 ECHA y) httpeESIS (Existing chemical Substances Information System) httpeGESTIhttpwGuidan

ADR Accord europeacuteen s AVV (Austria) Abfallverzeichnis-Verordnung

schaft Rohstoffe und chemische Industrie

d Prevention Labelling and Packaging of substances and mixtures1

D

ive (Directive 199945EC)

EC EHS Environme ea d ty

OF THE COUNCIL of and mixtures amending and repealing DirectiveRegulationt Name Fendell Cl e nd No 3 Page 25 of 2t No Fn 100

ting Commercial chemicals Substances E ESIS Existing chemical Substan EU European Union GHS Globally HarmoHSDB Hazardous Substances Data Bank IARC Inter

IATA International Air Transport Association ICAO International Civil Aviation Organization

IBC Code International Code for the Constructio Chemicals in Bulk

IUCLID DB International Uniform TI Technical Instructions for the Safe Transport of 1 Key literature references

and sources of data

(European Chemicals Agencchaeuropaeu

cbjrceceuropaeuesis S International Limit values Database wwdguvdeifaengestislimit_valuesindexjsp ce for downstream users

httpguidanceechaeuropaeudocsguidance_documentdu_enpdf Guidance on information requirements and chemical safety assessment Chapter R12 Use descriptor system httpguidanceechaeuropaeudocsguidance_documentinformation_requirements_r12_enpdf Guidance on the compilation of safe data sheets httpg _sheets_20100324pdf TOXNET Toxicology Data Network httptInform erature

terne

AIMER

This gu s of thers ne link over the other Internet links cited in this guide and views expressed in the

various ta gathered from many sites No health toxicological and

nvironmental databases Responsibility for the accuracy and completeness of information contained herein sts with the users who must satisfy themselves that the data is appropriate for their needs It is always a good

g sections of the Safety Data Sheet to clarify and simplify

F SAMPLE SAFETY DATA SHEET

uidanceechaeuropaeudocsdraft_documentsdraft_guidance_on_safety_data

oxnetnlmnihgov ation from technical lit

In t research Suppliersrsquo (Material) Safety Data Sheets

DISCL

ide was compiled as a service to Safety Data Sheet writers everywhere It neither reflects the viewo nor does it endorse o

sections are mine alone Information in this document is based on dawarranty is expressed regarding the accuracy of data obtained from various chemicalerepractice to consult a sectional expert when writintechnical matters

END O

Preface The ldquoAhardquo moment for writing this guide came when I started writing Safety Data Sheets (SDSs) at Easterday

Fluid Technologies LLC a manufacturer of industrial ink and ink related products Since chemicalsraw

substances are used in product manufacturing the law requires manufacturers to provide customers Material

Safety Data Sheets

Although I was trained to draft and write Material Safety Data Sheets with MSDS authoring software

(eg EnviroMSDS SAP The WERCS) those platforms were not available to me at Easterday We used

Microsoft Office Suite to prepare GHS compliant Safety Data Sheets (according to EU Directives and Guidance

Documents) to accompany ink and ink related products for clients in Europe and elsewhere

Our efforts in researching guidance documents physical chemical and toxicological properties of

substances and country specific regulatory information on the Internet (in addition to product literature from

chemical manufacturers) yielded adequate information for creating Safety Data Sheets according to European

Union regulations and standards using only Microsoft Word rather than a specialized and expensive authoring

program

We believe this guide will be invaluable to writers of Safety Data Sheets everywhere especially those in

small companies and those wanting to use it as a reference document when their Safety Data SheetsMaterial

Safety Data Sheets authoring system is down

With your help we will be able to keep abreast with European Chemical Regulations and update this

guide as new regulations become available If you know of additional links to free chemical environmental

health and toxicological databases on the Internet please e-mail the link(s) to us at safetywritergmailcom

We will promptly add it in this guide Please acknowledge this guide in Section 15 of your Safety Data Sheet

whenever you use it as one of your sources for information

Thank you for your participation

i


















ii

DISCLAIMER










iii






























5 Toluene 1 ndash 5

6 Xylene 1 ndash 5


3- Butanone 78-93-3 201-159-0 606-002-00-3 40 ndash 60

n-Butanol 71-36-3 200-751-6 603-004-00-6 30 ndash 60

Ethanol 64-17-5 200-578-6 603-002-00-5 10 ndash 40


Toluene 108-88-3 203-625-9 601-021-00-3 1 ndash 5

Xylene 1330-20-7 215-535-7 601-022-00-9 1 ndash 5





R65 R67 S2 S3637 S46 S62 F Xn

Xylene 1330-20-7 R10 R2021 R38 S2 S25 Xn



Risk Phrases (R-) 10 11 2021 22 36 3738 38 41 4820 63 65 66 67

Safety Phrases (S-) 2 7 79 9 13 16 2425 25 26 3637 3739 46 62
















22 Label elements


Hazard Pictograms

Signal word Danger
















No Name

CAS

EC No

Index No

RRN

Weight ()


Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67



[1] [2


Xi R3738 R41 R67 x 4

3

]



[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225





nd No 3


ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O


















ii

DISCLAIMER










iii






























5 Toluene 1 ndash 5

6 Xylene 1 ndash 5


3- Butanone 78-93-3 201-159-0 606-002-00-3 40 ndash 60

n-Butanol 71-36-3 200-751-6 603-004-00-6 30 ndash 60

Ethanol 64-17-5 200-578-6 603-002-00-5 10 ndash 40


Toluene 108-88-3 203-625-9 601-021-00-3 1 ndash 5

Xylene 1330-20-7 215-535-7 601-022-00-9 1 ndash 5





R65 R67 S2 S3637 S46 S62 F Xn

Xylene 1330-20-7 R10 R2021 R38 S2 S25 Xn



Risk Phrases (R-) 10 11 2021 22 36 3738 38 41 4820 63 65 66 67

Safety Phrases (S-) 2 7 79 9 13 16 2425 25 26 3637 3739 46 62
















22 Label elements


Hazard Pictograms

Signal word Danger
















No Name

CAS

EC No

Index No

RRN

Weight ()


Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67



[1] [2


Xi R3738 R41 R67 x 4

3

]



[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225





nd No 3


ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O

DISCLAIMER










iii






























5 Toluene 1 ndash 5

6 Xylene 1 ndash 5


3- Butanone 78-93-3 201-159-0 606-002-00-3 40 ndash 60

n-Butanol 71-36-3 200-751-6 603-004-00-6 30 ndash 60

Ethanol 64-17-5 200-578-6 603-002-00-5 10 ndash 40


Toluene 108-88-3 203-625-9 601-021-00-3 1 ndash 5

Xylene 1330-20-7 215-535-7 601-022-00-9 1 ndash 5





R65 R67 S2 S3637 S46 S62 F Xn

Xylene 1330-20-7 R10 R2021 R38 S2 S25 Xn



Risk Phrases (R-) 10 11 2021 22 36 3738 38 41 4820 63 65 66 67

Safety Phrases (S-) 2 7 79 9 13 16 2425 25 26 3637 3739 46 62
















22 Label elements


Hazard Pictograms

Signal word Danger
















No Name

CAS

EC No

Index No

RRN

Weight ()


Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67



[1] [2


Xi R3738 R41 R67 x 4

3

]



[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225





nd No 3


ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O






























5 Toluene 1 ndash 5

6 Xylene 1 ndash 5


3- Butanone 78-93-3 201-159-0 606-002-00-3 40 ndash 60

n-Butanol 71-36-3 200-751-6 603-004-00-6 30 ndash 60

Ethanol 64-17-5 200-578-6 603-002-00-5 10 ndash 40


Toluene 108-88-3 203-625-9 601-021-00-3 1 ndash 5

Xylene 1330-20-7 215-535-7 601-022-00-9 1 ndash 5





R65 R67 S2 S3637 S46 S62 F Xn

Xylene 1330-20-7 R10 R2021 R38 S2 S25 Xn



Risk Phrases (R-) 10 11 2021 22 36 3738 38 41 4820 63 65 66 67

Safety Phrases (S-) 2 7 79 9 13 16 2425 25 26 3637 3739 46 62
















22 Label elements


Hazard Pictograms

Signal word Danger
















No Name

CAS

EC No

Index No

RRN

Weight ()


Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67



[1] [2


Xi R3738 R41 R67 x 4

3

]



[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225





nd No 3


ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O








5 Toluene 1 ndash 5

6 Xylene 1 ndash 5


3- Butanone 78-93-3 201-159-0 606-002-00-3 40 ndash 60

n-Butanol 71-36-3 200-751-6 603-004-00-6 30 ndash 60

Ethanol 64-17-5 200-578-6 603-002-00-5 10 ndash 40


Toluene 108-88-3 203-625-9 601-021-00-3 1 ndash 5

Xylene 1330-20-7 215-535-7 601-022-00-9 1 ndash 5





R65 R67 S2 S3637 S46 S62 F Xn

Xylene 1330-20-7 R10 R2021 R38 S2 S25 Xn



Risk Phrases (R-) 10 11 2021 22 36 3738 38 41 4820 63 65 66 67

Safety Phrases (S-) 2 7 79 9 13 16 2425 25 26 3637 3739 46 62
















22 Label elements


Hazard Pictograms

Signal word Danger
















No Name

CAS

EC No

Index No

RRN

Weight ()


Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67



[1] [2


Xi R3738 R41 R67 x 4

3

]



[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225





nd No 3


ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O


Risk Phrases (R-) 10 11 2021 22 36 3738 38 41 4820 63 65 66 67

Safety Phrases (S-) 2 7 79 9 13 16 2425 25 26 3637 3739 46 62
















22 Label elements


Hazard Pictograms

Signal word Danger
















No Name

CAS

EC No

Index No

RRN

Weight ()


Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67



[1] [2


Xi R3738 R41 R67 x 4

3

]



[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225





nd No 3


ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O




22 Label elements


Hazard Pictograms

Signal word Danger
















No Name

CAS

EC No

Index No

RRN

Weight ()


Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67



[1] [2


Xi R3738 R41 R67 x 4

3

]



[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225





nd No 3


ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O












No Name

CAS

EC No

Index No

RRN

Weight ()


Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67



[1] [2


Xi R3738 R41 R67 x 4

3

]



[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225





nd No 3


ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O






No Name

CAS

EC No

Index No

RRN

Weight ()


Type

3-Butanone 0 3 2 ]

78-93-3 201-159- 606-002-00- - 40 ndash 60 F R11 Xi R36-66-67



[1] [2


Xi R3738 R41 R67 x 4

3

]



[1] [2

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 ndash 40 F R11 [2]

Flam Liq 2 H225





nd No 3


ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O

ca

No

EC No


ame

Index No

Weight ()

Classifi tion

N

67


No 12722008[ CLP]

Type

Isopropanol 67 63-0 200-661-7

603-117-00-0


E 3

] -

FXi R36 R67 H225


[1 [2]

Toluene 10 29

63

Xn R4820 R65 Xi R38 R67

1

3





[1] [2]

Xylene 1330-20-7

215-535-7 601-022-00-9 - 1 ndash 5

]


ion 2

nts

[2]


above




[1]







Us

n 8 Page


8 Pre Pri





eful links

Haz-Map








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



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o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O








Provides sa


information









41









concentra



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O



on


after





n




43 eatm t needed










track and diarrhea






ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O




ire Fi ting easur s





f ut hazard


ater jet




roducts r



) be





o AUTOIG 5







11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O



11

rotect e equ ment


e



ner


r

may not


011


or osal

f ontractor


to o her se ions

without risk
















ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O









ng before re-using

torage includi




3 pecifi end use(s)





tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O



tanone)


(3-BuEC No 201-159-0




Limit value type



upat Expo3-Buta





EC No 201-

78-

one




it ho A)

rt term it -minu


Limit value type



Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O


Note H








81









Recom nded monits




(PNEC Summary)

Exposure controls









91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O





91 l and


dour resho











acceptable level





o


E Not available =




No F 100




Reactivity



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O



ition products














Identifiers

50


66 mgkg - - EC No 203-625-9 CAS No 108-88-3



ary f 25





ll injure eye








dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O


dryness or cracking







r ductio )









14 ther form ion




No data available

No data availabl










30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O






30-20

nt Blend No 3


and degradability a







tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O




tive po a availab







Substanc oc







No da vailab






and H zardouw












ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O










ay










Useful links



httpwwwdftgovuk




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O




















Version 100



141 UN No 1210 1210 1210 1210 14


Material



F1

F1

F1



arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O


arine po nt No




Excepted Quantities

2 240L


MP1

nks Cont T4 TP1 TP8

ode Tunnel c

DE

-


- -

(EmS)

- -

-

Emergency schedules


Excp tyt Q E2

-


10 L

353 0 L


600 L

struction 364

Passenger and Cargo


5

ft otion

Packaging in

-

-



No 3





I




th e


uenterprisesect ]





onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O




onal regulations






mixture

















P





















D








and sources of data




terne

AIMER









DISCL



END O



















D








and sources of data




terne

AIMER









DISCL



END O


terne

AIMER









DISCL



END O

Amet,TM Update EU GHS CLP SDS Authoring Guide

Documents

simplify technical

easterday

personal protective

small outdoor

06272011 printing

ink related

portable fire

significant