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ALBERDINGK® AC 2403
– A super hydrophobic Acrylic resin which provides very dense film
formation for applications with high barrier properties required, like anti
corrosion primers , DTM finishes , Stain blocking coatings, adhesion
primers
Customer Seminar,
Shunde, 23rd, Sept., 2014
Shanghai, 25th, Sept., 2014
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Table of contents
1. Introduction for super-hydrophobic binder ALBERDINGK AC2403
• Product data
• Polymerization of ALBERDINGK® AC2403
• Benefits of two phase acrylic dispersions
• Morphology of ALBERDINGK® AC 2403
2 . Application examples for ALBERDINGK® AC 2403
• Anti-corrosive applicaiton
• Semi-gloss pigmented white top coats for furniture coatings
• Stain locking primers
• Base coats for pigmented outdoor wood coatings
• Adhesion coats on glass, aluminum as oven stoving paints
3. Summary
2 © Alberdingk Resins (Shenzhen) Co., Ltd. | AC 2403 - A super hydrophobic acrylic resin
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ALBERDINGK® AC 2403 product data
self-crosslinking and adhesion promoted two phase acrylic dispersion
Solids-content: 46 - 48 %
pH-value: 7.0 – 8.0
Viscosity: 700 - 3000 mPas
MFFT: approx. 16°C
3 © Alberdingk Resins (Shenzhen) Co., Ltd. | AC 2403 - A super hydrophobic acrylic resin
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Polymerization of hydrophobic ALBERDINGK® AC2403
A type of Hydrophobic Emulsion Polymer
Select:
• Hydrophobic monomers
• Reduce emulsifier content, use as less as possible
• Reduce polymerization initiator content
• super water resistance
• super intercoat layer adhesion
• Very high barrier properties (almost no water absorption and
water vapour transmission)
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Benefits of two phase acrylic dispersions
• Low MFFT combined with high surface hardness
• Less VOC demand in formulations
• Fast drying and high blocking resistance
• High level of elasticity
• Fast sandability
5 © Alberdingk Resins (Shenzhen) Co., Ltd. | AC 2403 - A super hydrophobic acrylic resin
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Morphology of ALBERDINGK® AC 2403
ALBERDINGK® AC 2403 – approx. 5 nm Conventional „CS “ Acrylic – approx. 50 nm
coarse structure fine (dense) structure
6 © Alberdingk Resins (Shenzhen) Co., Ltd. | AC 2403 - A super hydrophobic acrylic resin
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1. ALBERDINGK® AC 2403 anti-corrosive applicaiton —— concept
Advantage of fine film structures
Fine film structure leads to:
• Better film formation
• Dense film
better barrier properties!
• Almost no migration of water/water vapour through.
• No water or oxygen can permeate onto the metal substrate.
• No corrosion on the surface!
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Competitor 62
1. ALBERDINGK® AC 2403 anti-corrosive applicaiton / DTM – 432 h neutral salt spraying test (NSST)
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Competitor 100
Strong corrosion & blisters
AC 2403
Corrosion only at cut
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1. ALBERDINGK® AC 2403 anti-corrosive applicaiton / DTM – 1442h NSST
Ca. 45um DFT, Gardobond OC
panel
Ca. 140um DFT, sand
blasted steel
Ca. 90um DFT,
Gardobond OC panel
FP 2403-25 anti-corrosion coatings, PVC approx. 21.8%, also suitable for sandblasted steel
FP 2403-28 anti-corrosion coatings, PVC approx. 11%, solids approx. 50%
9 © Alberdingk Resins (Shenzhen) Co., Ltd. | AC 2403 - A super hydrophobic acrylic resin
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1. ALBERDINGK® AC 2403 anti-corrosive applicaiton / formulation guidelines
Grinding / dispersing
• don’t grind in the dispersion.
• add dispersion in the let-down phase.
PVC levels
• hard polymer phase of the particle acts like a filler / extender in your formulation
• limit the maximum PVC levels of ALBERDINGKR AC 2403 (≤25% PVC.)
10 © Alberdingk Resins (Shenzhen) Co., Ltd. | AC 2403 - A super hydrophobic acrylic resin
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1. ALBERDINGK® AC 2403 anti-corrosive applicaiton / formulation guidelines
Choice of pigments / extenders / functional anti-corrosive
• use talc or mica based (lamellar fillers) for best water barrier
• Bariumsulfate (e.g. Blanc fixe micro) will not compromise gloss levels.
• no additional benefit by using anticorrosive pigments like zinc phosphates
• anticorrosive pigments are labelled as “hazardous to the environment” (N)
• they may harm the stabilisation system of polymer dispersions
(due to e.g. Ca2+ , Zn2+, Ba2+ or Sr2+ Ions)
• Will decrease the gloss of the corresponding coating films.
• Anticorrosive pigments can be a handicap for cost efficient corrosion protection.
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1. ALBERDINGK® AC 2403 anti-corrosive applicaiton / formulation guidelines
Dispersants choice
• choice of dispersant not only affects
gloss and corrosion resistance but
also adhesion properties and film
hardness.
• Our standard recommendation is
Orotan 165 or Edaplan 490
(Münzing Chemie)
12 © Alberdingk Resins (Shenzhen) Co., Ltd. | AC 2403 - A super hydrophobic acrylic resin
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1. ALBERDINGK® AC 2403 anti-corrosive applicaiton / formulation guidelines
Pigment pastes
• For colours like black , the choice of dispersants is even more critical
• high amount of (hydrophilic) dispersants
• The following types are recommended for full colour black or tinting :
- Monolite black XBE-HD (Heubach pigments)
- Colanyl N 500 (Clariant)
- Colormatch 50-990-20966 (Plasticolor Inc.)
- UCD 1625 E (Plasticolor Inc.)
Coalescent types / levels
• 2-5% co-solvent on the total formulation
• Butylcellosolve and Texanol Liquid anti-corrosion additives
Liquid anti-corrosion additives
ASCONIUM® additives are able to improve the long term corrosion resistance since they improve
the adhesion property at the scribe.
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1. ALBERDINGK® AC 2403 anti-corrosive applicaiton / FP2403-28 anti-corrosion white pigmented lacquer
14 © Alberdingk Resins (Shenzhen) Co., Ltd. | AC 2403 - A super hydrophobic acrylic resin
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2. Semi-gloss pigmented white top coats for furniture coatings/ stain resistance
Challenge: stain resistance against
• Green tea
• Coffee
• Red wine
• Cola
• vinegar
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2. Semi-gloss pigmented white top coats for furniture coatings
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Test of chemical resistance
Drying: 3 days at 40 degrees C, test after 1h and 16h
AC2714 50%
AC2742
45%
coffee | green tea | cola | vinegar | red wine | ammonia | ethanol
1 h 16h
1 h 16 h
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2. Semi-gloss pigmented white top coats for furniture coatings
AC2714 40% + AC 2403 9.2%
coffee | green tea | cola | vinegar | red wine
1 h 16 h
17 © Alberdingk Resins (Shenzhen) Co., Ltd. | AC 2403 - A super hydrophobic acrylic resin
Test of chemical resistance
Drying: 3 days at 40 degrees C, test after 1h and 16h
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2. Semi-gloss pigmented white top coats for furniture coatings
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Summary of chemical resistances:
semi-gloss white pigmented coatings
25% ammonia
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Remark: SMQ is Shenzhen Academy of Metrology and quality inspection
Pos. Raw Material Amount Product Supplier
1 Alberdingk® AC2714 40 Acrylate dispersion Alberdingk Boley
2 Alberdingk® AC2403 9.2 Acrylate dispersion Alberdingk Boley
3 Tego Foamex 825 0.6 defoamer Tego
4 DPnB 5 Co-solvent Commercial
5 PG 1 Anti-freezer Commercial
6 water 18.3
7 TegoViscoPlus3010 0.4 Thickener Tego
8 Ceraflour929 2 Matting wax BYK
9 R706 dispersion paste* 23 TiO2 paste
10 Tego wet 270 0.1 Wetting agent tego
11 Tego ViscoPlus3030 0.4 Thickener Tego
Total 100.00
2. Semi-gloss pigmented white top coats for furniture coatings/FP2714-sz3 based on AC2714/AC2403
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Remark: SMQ is Shenzhen Academy of Metrology and quality inspection
Pos.
Raw Material Amount Product Supplier
1 water 12.7
2 Tego Dispers735w 7.5 Dispersing agent Tego
3 Tego foamex 825 0.4 Defoamer Tego
4 R706 75 TiO2 Dupont
5 water 4.2
6 BYK420 0.2 anti-settling BYK
Total 100.00
* attached:R706 dispersion paste
2. Semi-gloss pigmented white top coats for furniture coatings/FP2714-sz3 based on AC2714/AC2403
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2. Semi-gloss pigmented white top coats for furniture coatings/FP2714-sz3 based on AC2714/AC2403
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Remark: SMQ is Shenzhen Academy of Metrology and quality inspection
60 °Gloss
hardness
Vinegar
Green tea
qualified
qualified
qualified
normal
normal
Specification Test results conclusion
Inspection results in SMQ according with GB/T23999-2009:
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3. stain locking primers /For tropical wood
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Tropical wood contains rich water soluble tannin, and high content oil
Alberdingk® AC2403 showed:
• better immediate and long term non-discoloration of white top coat by efficientlytannin stain locking
• excellent long term intercoat adhesion, even on high oil contained substrate
with AC 2403 (FP 2403-10) VS. with standard acrylic
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3. stain locking primers /For MDF
Beside of rich hydrophilic tannin stain inside, MDF is also easily get swelled up and grain rising on surface after applying with w/b paints.
Alberdingk® AC2403 showed:
• Best non-discolouration of white top coat.
• very good smooth surface after applying topcaot due to minimal grain rising
Substrate: MDF
Clear primers:
100g/m2×2layers by brush,
AC2782 white topcoat:
100g/m2×1layer by spray.
Dry condition: 70°C x 24h
Comp.1 Comp.4 Comp.3 AC2403 Comp.2
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3. stain locking primers /For the scab part of pine wood
Substrate: scab part of pine wood
primer lacquers:
100g/m2×2layers by spraying
AC2782 white topcoat:
100g/m2×1layer by spraying
Dry condition: 70°C×7days
Pine wood scab contains rich hydrophobic pine resin, what is easily to migrate out of the film, especially stocking at high temperature.
Stain locking results after 70°C x 7days:
All have got yellowing, and AC2403 ≈ AC2742 ≥ AC31 ≈ AC25222
1k, AC2403 1k, AC2742
1k, AC31 1k, AC25222
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Compare locking ability of 2K system based on AC2598,AC2742,AC31,AC2403 separately on pine wood scab
Stain locking results for these 2k clear primers after 70°C x 30 days:
AC2598 is the best, still no yellowing. Other three are: AC2403 ≥ AC2742 ≈ AC31
3. stain locking primers /For the scab part of pine wood
2k, AC2742 +
6% Bayhydur305
2K, AC2598 + Bayhydur305
(NCO/OH=1.2)
2k, AC31 + Bayhydur305
(NCO/OH=1.2)
2K, AC2403 + 6%
Bayhydur305
Substrate: scab part of pine wood
primer lacquers:
100g/m2×2layers by spraying
AC2782 white topcoat:
100g/m2×1layer by spraying
Dry condition: 70°C×30 days
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4. Base coats for pigmented outdoor wood coatings /For enhanced exterior durability
Weathering Resistance (EN927): 2016h QUV, on oak
Panels have same primer and same top coat!
Commercial intermediate coat Intermediate coat based on AC 2403 (TF 07)
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4. Base coats for pigmented outdoor wood coatings /For enhanced exterior durability
Weathering Resetance (EN927): 2016h QUV, on oak
Panels have same primer and same top coat!
Commercial intermediate coat Intermediate coat based on AC 2403 (TF 02)
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5. Adhesion coats on glass, aluminum as oven stoving paints /2K baking lacquers with MFR
• 2-components baking system
Cross-linking with water-soluble melamine formaldehyde resin (MFR), such
as MF921 from INEOS
• curing condition
Temperature: depending on MFR,
e.g. 110~160°C
Curing time: 20~30min
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5. Adhesion coats on glass, aluminum as oven stoving paints/Part A of FP 2403-sz1
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FP 2403 –sz1 2k baking clear gloss lacquer, for aluminum, glass
Part A :
Pos. 4~10: pre-mixing.
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5. Adhesion coats on glass, aluminum as oven stoving paints / Part B of FP 2403-sz1
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FP 2403 –sz1 2k baking clear gloss lacquer, for aluminum, glass
Part B :
Pos.3: to adjust PH to 7.5 ~8.0
Applying ratio: Part A / Part B = 100 / 13.6
Pot life: above 24 hours
Curing condition: 120~130°C x 30min
Pencil Hardness on glass: HB~F
MFR INEOS
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FP 2403-sz1 2k baking clear gloss lacquer Adhesion (0 is best, 5 is worst):
5. Adhesion coats on glass, aluminum as oven stoving paints
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0
1
2
3
4
5
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5. Adhesion coats on glass, aluminum as oven stoving paints
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FP 2403–sz1 2k baking clear gloss lacquer + 1% BioWet60G (adhesion promoter, from ADD APT) Adhesion (0 is best, 5 is worst):
0
1
2
3
4
5
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5. Adhesion coats on glass, aluminum as oven stoving paints /Full color or tinting color system
Good compatibility with :
• Colanyl® color pastes,
• Hydrolan® metallic pastes, etc.
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Summary for Alberdingk® AC2403
Waterborne super-hydrophobic acrylic dispersions have super barrier properties which
sets
• The benchmark for corrosion resistance (1K acrylics, for DTM)
...which improve
• Chemical resistance (as top coats)
• Stain resistance (as top coats)
• Weathering resistance ( as base coats)
• Adhesion on oily substrates
• Adhesion on mutil-substrates, such as glass, and aluminum
… which reduce
• Grain raising (as primer)
… and which
• lock stains , e.g. Tannin (as primer), without negative side aspects of Zn2+ ions.
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Thank you for your attention!
For more details, please contact with us
Fred Zhong 钟良福
Senior Engineer
15919879362
[email protected]