AIR LIQUIDE / Lurgi Your Partner for XtL Technologies 4th International Freiberg XtL Conference 3.-6. May 2010, Dresden, Germany Max-Michael Weiss – Director Gas Production and Gas Cleaning Technologies Dr.-Ing. Waldemar Liebner – Director GTC Technology
26
Embed
AIR LIQUIDE / Lurgi Your Partner for XtL Technologies · DME/MTP Syngas for DRI Raw Material Syngas Final Products Sulfur Recovery CO Cold Box (CO2) Rectisol Stage 2 PSA / Membrane
This document is posted to help you gain knowledge. Please leave a comment to let me know what you think about it! Share it to your friends and learn new things together.
Transcript
AIR LIQUIDE / Lurgi
Your Partner for XtL Technologies
4th International Freiberg XtL Conference3.-6. May 2010, Dresden, Germany
Max-Michael Weiss – Director Gas Production and Gas Cleaning TechnologiesDr.-Ing. Waldemar Liebner – Director GTC Technology
2AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
� Introduction� The Air LIQUIDE Group With Lurgi
� Air LIQUIDE Engineering and Construction
� Lurgi Technologies� References
� Food for thought:
Non-Conventional Feedstocks and Sustainable Develop ment
� Selection of XtL routes from AL / Lurgi’s Portfolio
� Conclusion
Agenda for Today
3AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
� Total Sales 2009 € 12 000 M� Customers > 1,000,000� Employees 42,300 � Companies Owned 125� Operating in Countries 75� Operating Plants > 600� Rating By Standard & Poors A+
� Weathering the Economic Crisis Well
� Ranked In The Forbes 500
� Chemical Week Worldwide 14(Ranked By Chemical Sales)
� Four Main Business Lines – Large Industry, Electronics, Healthcare, Industrial Merchant
Air LIQUIDE Today – Largest Industrial Gas Company
4AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
� Air Separation Units 409� O2 Production 132 kt/d� N2 production 97 kt/d
� Hydrogen, Syngas and Carbon Monoxide Manufacturing Units 60� H2 production > 1.1 Million m3/h� CO production 82,700 m3/h
11AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
Food for thought:
Natural Gas and Non-Conventional Feedstocks (shale gas, CBM)
and Sustainable Development
12AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
-statement: The Challenge Now Is Building Demand for Natural Gas in a Carbon Constrained World
The natural gas resource base, particularly with the worldwide pursuit of gas shales and unconventional gas, is large. It could provide lower CO2emissions options for power generation and possibly for transportation than from continued use of coal and oil.
1.0
0.8
0.6
0.4
0.2
0
Coal Natural Gas
# of CO2/kw
h
0.99(32% E)*
0.75(43% E)*
0.34(54% E)*
Source: EnCana 2009
CO2/SO2 Emissions
by Fuel Type (lbs/BBtu)
CO2 Emissions for
Electricity (lbs/kWh)
*E - - efficiency of the power plant
13AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
(e)3,760
2,100
790
300
320
250
Resource
Endowment
(Tcf)
302Woodford
1301Haynesville
200-Marcellus
45025Total
503Fayetteville
4019Barnett
Undeveloped
Recoverable
Resource
(Tcf)*
Produced/
Proved
Reserves
(Tcf)*
Five of the “Magnificent Seven” gas
shale plays are in the Eastern U.S.
Eastern U.S. Gas Shale BasinsEastern U.S. Gas Shale Basins
Source: Advanced Resources International
14AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
15AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
JAF02052.CDR
Are Gas Shales Economically Affordable?
With a new understanding of supply costs, unconventional gas and particularly the higher quality gas shales make up the low costportion of today’s North American natural gas price/supply curve.
Prior PerceptionPrior Perception New UnderstandingNew Understanding
Gas Resources Gas Resources
Gas
Pric
es
Gas
Pric
es
ConventionalGas
UnconventionalGas (Gas Shale)
UnconventionalGas (Gas Shales)
ConventionalGas
Source: Advanced Resources International
16AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
• CBM: 1,270 Tcf GIP. Over 3,000 drilled wells; horizontal CBM wells show promise in the Qinshui Basin.
• Tight Gas: Producing >400 MMcfd from the Ordos Basin.
• Recently, Shell and PetroChina signed an agreement to appraise the gas shale basins of Sichuan.
BAOTOU
Yinchuan
Hohhot
Datong
XIAN
TAIYUANYulin
Yanan
ZHENGZHOU
I N N E R M O N G O L I A
N I N G X I A
S H A A N X I
H E N A N
S H A N X I
GA
NS
U
JAF02053.CDR
105o
105o
o40
o35
Y e l l o wR i v e r
R i v e r
W e i
1:5,000,000
O r d o s
B a s i nQ i n s h u i
B a s i n
0 100
km
T a i d o n g
B a s i n s
ChinaChina ’’s CBM, Tight Gas and s CBM, Tight Gas and Gas Shale Resources Gas Shale Resources
Are Large and ChallengingAre Large and Challenging
Source: Advanced Resources International
Source: Advanced Resources International
17AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
� Feedstocks Dependency� Availability
� Cost
� Energy Diversity
� Technological Advancements for Their Use
� Carbon Dioxide Emission Mitigation Policies
� Political Willingness and Determination
� Can Be As Complex or As Simple as People Can Make It
� Examples• United States – Liberal Market Policies
• China – Directed Policies
No Such Things as Non-Conventional Feedstocks!
18AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
� Politics/Policy – Beyond the Scope of This Presentat ion!!!
� Using the Right Processes – for Which Products?
� Feedstock Issues• Availability and Costs
• Applicable Technology
• Life-Cycle Assessments
� Pre Emissions Issues – Designing For Energy Efficien cy and Feedstock Utilization
� Operational Efficiency – Start-ups/Shutdowns and Ste ady State Issues
� Post Emissions Treatment /Issues• Capture Technology – The Right Choice for the Right Process and Right Application
• Agglomeration of Sources
• Sequestration – Not as Easy as It Sounds
� Business Models� Management of Risks – Contractual Obligations Are No t Defined Anywhere in the World
How Can We Deal With Carbon Dioxide Emissions?
19AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
Air LIQUIDE
Lurgi Cleaning
Synthesis Gas
(CO + H2)
Pilot Fast-Pyrolysis Plant In Karlsruhe, Germany
Converts 500 Kg/Hr Biomass.
SyntheticHydrocarbons
MPG Gasificationor
Oxy-Combustion
Bio-OilLurgi Fast Pyrolysis Technology
Lurgi
Fischer-Tropsch
or Chemical
Processes
Decentralized
Fast-PyrolysisBiomass
Processes - Biomass to Liquids (BTL) Concept and Tec hnology
20AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
� There is a World Wide Willingness to Use Biomass as a Feedstock, but Several Issues Prevent It From Being Universally Applicable or More Commercial
� Political Support – Indecision, Fleeting and Unrelia ble, Long Term Support?
� Besides Concerns on Land/Food Limits There are Othe r Issues That Must Be Addressed
• Long Term Availability of Feedstock
• Communication and Education Required to Fend Off Ve sted Interests
� Logistics of Collection, Transport and Use
• Single Largest Problem Needing Resolution
• Impacts Scale and Economics
� Cost Versus Alternatives
• The Price of Crude Is a Constant Constraint/Threat
� Technological Applicability
• Preparation of Biomass for Processes
• Gasification/Syngas Production and Syngas Cleaning
• Downstream Processing
� Life Cycle Assessment
• Can be Controversial and Methodologies Not Coherent
Processes - Biomass Usage Realities
21AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
Natural GasGrid
SyntheticHydrocarbons
Feed
Preparation
Pet-Cokeand/or
Residue
Processes - Pet-Coke / Residue to Liquids (P/RTL), S NG or Power
MethanationLurgi SNG
Air LIQUIDE
Lurgi Cleaning
Synthesis Gas
(CO + H2)MPG Gasification
orOxy-Combustion
Lurgi
Fischer-Tropsch
or Chemical
Processes
Sulfur as a By-Product
22AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
Processes - Pet-Coke / Residue Realities – After Many Studies!
� Pet-coke and Residue Gasification is Easier to do t han Biomass Gasification
� Feedstocks are Available in India, but….
� There is a Need for Government Support for Power Pr oduction
• Government Tariffs or Financing Guarantees
• When Will These Be Available, Although Governments Understand The Need
� Value Added Products Need to be Manufactured
� Which Chemical Markets Addressed – Do Alternative So urces Exist and at What Price?
� Variability of Crude Price Must be Taken into Accou nt
� Alternatives for Pet-coke Exist – Cement Industry/Co nventional Power.
� Pricing Variability Must Be Considered By Producer/ User
� Alternatives still (!) Exist for Residues – Bunker(s) and Power Production
� Carbon Dioxide Mitigation Policies Required
� Where Will Carbon Dioxide Be Collected
• Syngas Cleaning Process
• Chemical Process
• Power Production – H2/N2 Stream or Use SNG Process
� Trends Seem to Support Use of These Feedstocks, But CAPEX Issues Force Many Project Developers to Reconsider…So Far!
23AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
Natural GasGrid
SyntheticHydrocarbons
Feed
Preparation
High Ash Coal
Processes - High Ash Coal to Liquids CTX, SNG or Pow er
MethanationLurgi SNG
Air LIQUIDE
Lurgi Cleaning
Synthesis Gas
(CO + H2)FBDBGasification
Lurgi
Fischer-Tropsch
or Chemical
Processes
Sulfur as a By-Product
24AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
25AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
� The Air LIQUIDE and Lurgi Combination Provides an U nprecedented Offer to Customers
� From Technology to Engineering to Operations and En vironmental Stewardship
� The Customer Has The Freedom and Choice to Use Any or All of the Offerings of Air LIQUIDE and Lurgi ���� Any X to many Ls
� Non-Conventional Feedstocks (like shale gas, CBM, …) Are Only a Matter of Definition
� Availability Must be Coupled to Cost and Technologi es That Can Bring Value
� Biomass – Desired by Many, But Carries With it Costs and The re are Still Considerable Obstacles for Widespread Commercializa tion
� Pet-coke and Residues – Much More Available and Used, Although Value Added Products Must be Manufactured to Offset High Prices, Volatility and On-Stream Factors
� Low Rank Coal – Can Become a Real Feedstock for Petrochemical Use, Although Environmental Footprint Must be Addressed
� Carbon Dioxide Mitigation Must Be Looked at From a Holistic Perspective –Technology, Business Model, Contractual Obligations , Community Involvement
� Air LIQUIDE's and Lurgi’s Experiences Can Help You Navigate the Terrain
Conclusions
26AIR LIQUIDE: The world leader in industrial and med ical gasesDresden – 4 th IFC – 2010/05/3-6
Thank You
Max-Michael WeissDirector Gas Production and Gas Purification TechnologiesLurgi GmbHLurgiallee 560439 Frankfurt am Main, [email protected]