A Solution for Oil Seed Industry

1

A Solution for Oil Seed Industry

Dr. Supriyo GhoshProduct & Applications Manager, TD-NMR

theminispec Seed Analyzer

1.Who is Bruker2.What is TD-NMR3.How can Bruker’s TD-NMR help me

1.Who is Bruker2.What is TD-NMR3.How can Bruker’s TD-NMR help me

Innovation for customers delivered with integrity

Innovation for customers delivered with integrity

1960First commercial NMR in the world

Innovation for customers delivered with integrity

2008Highest resolution NMR in the world

Innovation for customers delivered with integrity

2008Highest resolution1GHz

9

Bruker Corporation: a Global Company for Analytical Solutions

Other Significant R&D and Production Sites

Direct Sales Offices

Major DE, CH & FR R&D and Production Sites

Many additional distributors around the world

Headquarters

France

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The Netherlands

Wisconsin

Switzerland

Australia

Massachusetts

France

Japan

Germany

Germany

The Netherlands

Wisconsin

Switzerland

Australia

Massachusetts

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HQ: Billerica, MA

December 17, 2012 12

Bruker Corporation TodayLife Science and Analytical (LSA) Systems

Bruker Daltonics Mass Spectrometry• MALDI-TOF(/TOF)• Ion Trap MSn

Bruker AXS Elemental Analysis

• X-ray Diffraction• X-ray Crystallography• X-ray Fluorescence

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• FT-IR • FT-NIR

Technology Platforms

• EDS Microanalysis• Optical Emission Spectroscopy• Combustion Analysis

• ESI-(Qq)-TOF, FTMS• IMS

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Bruker BioSpin Magnetic Resonance

• NMR• MRI

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First Bruker TD-NMR instrument

1972

> 1400 minispecs

Almost every country including Iceland, Bangladesh, Ukraine, Vietnam…

> 400 publications in peer-reviewed journals

First unit sold in 1972

Present all over the world

>1400 running right now

1.Who is Bruker2.What is TD-NMR3.How can Bruker’s TD-NMR help me

Low magnetic fieldBench-top

Low magnetic fieldBench-top

Looking @ molecular level

Low magnetic fieldBench-top

Looking @ molecular level

•Sample prep•Solvents•Time•Manual labor

Low magnetic fieldBench-top

Looking @ molecular level

•Sample prep•Solvents•Time•Manual labor

How does it tell me so much about my sample/process ?

Moisture, Oil, Protein, …

Hydrogen Atom

in Moisture, Oil, Protein, …

Hydrogen Atom

Atomic Nucleus

1H nucleus

+•Charge

1H nucleus

+•Charge•Spin

1H nucleus

+ =tiny magnet

RF Pulse

Molecular InteractionInteraction with immediate environmentRelaxationDiffusion

TD-NMR: Excellent Phase Sensor

Crystalline AmorphousGlassy Liquid

TD-NMR: Excellent Phase Sensor

Crystalline AmorphousGlassy Liquid

time

sign

al

time

sign

al

time

sign

al

TD-NMR: Precise Chemical Detector

Protein

Moisture

Oil

TD-NMR: Precise Chemical Detector

Protein

Moisture

Oil

No SolventsFew SecondsCan be completely automated

TD-NMR: ColorOpacityGrain-sizeLuster

TD-NMR: ColorOpacityGrain-sizeLuster

Independent

TD-NMR: ColorOpacityGrain-sizeLuster

Independent

No Grinding/shreddingNo new calib for new harvestOne universal calibration

TD-NMR: True Bulk Measurement

TD-NMR: True Bulk Measurement

TD-NMR: True Bulk Measurement

TD-NMR: True Bulk Measurement

TD-NMR: True Bulk Measurement

Optical Techniques TD-NMR

Optical Techniques TD-NMR

Optical Techniques TD-NMR

Optical Techniques TD-NMR

up to 1.5mm inside

Optical Techniques TD-NMR

up to 1.5mm inside entire bulk

Seed Crushing Cakes

Seed Crushing Cakes

Enormous Heterogeneity

Seed Crushing Cakes

Enormous Heterogeneity

OpticalTechnique

Seed Crushing Cakes

Enormous Heterogeneity

OpticalTechnique

TD-NMREntire sample

1.Who is Bruker2.What is TD-NMR3.How can Bruker’s TD-NMR help me

Bulk Seed

Single Seed

Sample Sizes: 1 seed – 1kg of seed

Seed Analysis

Seed Analysis

Bulk Seed Analysis

Bulk Seed Analysis

Bulk Seed Analysis

Bulk Seed Analysis

•High-throughput•No extraction (solvent, time, labor)

Bulk Seed Analysis

Calibration•3-5 point calibration•Takes few minutesMeasurement•One press of a button•Few seconds•Simultaneous multi-component

Incoming Material

%Oil on Dry Matter BasisOfficial Method•AOCS Official Method Ak 4-95•ISO 10565•ISO 10632 for residues•USDA, GIPSA Approval, FGIS00-101

Seed Crushing

•Process efficiency monitoring•Animal feed

Oil Processing

Hydrogenation

Oil Processing

Hydrogenation Blending

Oil Processing

Hydrogenation

Blending

Oil Processing

0

20

40

60

80

100

120

10 15 20 25 30 35 40 45

Temperature(C)

%SF

C

Cocoa Butter

Palm Kernel (PK) Oil

PK Stearin

PK Olein

Hydrogenated PK

Hydrogenated/InteresterifiedPKCBR

Fractionated CBRHydrogenation

Blending

Oil Processing

0

20

40

60

80

100

120

10 15 20 25 30 35 40 45

Temperature(C)

%SF

C

Cocoa Butter

Palm Kernel (PK) Oil

PK Stearin

PK Olein

Hydrogenated PK

Hydrogenated/InteresterifiedPKCBR

Fractionated CBR

Oil Processing

0

20

40

60

80

100

120

10 15 20 25 30 35 40 45

Temperature(C)

%SF

C

Cocoa Butter

Palm Kernel (PK) Oil

PK Stearin

PK Olein

Hydrogenated PK

Hydrogenated/InteresterifiedPKCBR

Fractionated CBR

4 seconds for each SFC point

Incoming MaterialSeed: oil/moisture/protein

Incoming MaterialSeed: oil/moisture/protein

Process MonitoringResidual oil in cakes

Amt of oil produced

Incoming MaterialSeed: oil/moisture/protein

Process MonitoringResidual oil in cakes

Outgoing MaterialFeed Industry

Amt of oil produced

Incoming MaterialSeed: oil/moisture/proteinPayment $

Process MonitoringResidual oil in cakesEfficiency $

Outgoing MaterialFeed IndustrySelling Price $

Amt of oil sold $

Incoming MaterialSeed: oil/moisture/proteinPayment $

Process MonitoringResidual oil in cakesEfficiency $

Outgoing MaterialFeed IndustrySelling Price $

Amt of oil sold $

Control your earnings in few seconds using

•Entire sample measured•Color/opacity does not affect•Easy … calib & measurement

Innovation with Integrity

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