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PLEASE SCROLL DOWN FOR ARTICLE This article was downloaded by: [University of Greenwich] On: 14 December 2009 Access details: Access Details: [subscription number 908060688] Publisher Taylor & Francis Informa Ltd Registered in England and Wales Registered Number: 1072954 Registered office: Mortimer House, 37- 41 Mortimer Street, London W1T 3JH, UK Environmental Technology Publication details, including instructions for authors and subscription information: http://www.informaworld.com/smpp/title~content=t791546829 A review of literature and computer models on exposure assessment T. E. Butt a ; M. Clark b ; F. Coulon c ; K. O. K. Oduyemi d a School of Architecture & Construction, University of Greenwich, London, UK b School of Built & Natural Environment, University of Central Lancashire, Preston, UK c Centre for Resource Management and Efficiency, Sustainable Systems Department, School of Applied Sciences, Cranfield University, Cranfield, UK d Department of Built & Natural Environment, School of Contemporary Sciences, University of Abertay Dundee, Scotland, UK Online publication date: 14 December 2009 To cite this Article Butt, T. E., Clark, M., Coulon, F. and Oduyemi, K. O. K.(2009) 'A review of literature and computer models on exposure assessment', Environmental Technology, 30: 14, 1487 — 1501 To link to this Article: DOI: 10.1080/09593330903345952 URL: http://dx.doi.org/10.1080/09593330903345952 Full terms and conditions of use: http://www.informaworld.com/terms-and-conditions-of-access.pdf This article may be used for research, teaching and private study purposes. Any substantial or systematic reproduction, re-distribution, re-selling, loan or sub-licensing, systematic supply or distribution in any form to anyone is expressly forbidden. The publisher does not give any warranty express or implied or make any representation that the contents will be complete or accurate or up to date. The accuracy of any instructions, formulae and drug doses should be independently verified with primary sources. The publisher shall not be liable for any loss, actions, claims, proceedings, demand or costs or damages whatsoever or howsoever caused arising directly or indirectly in connection with or arising out of the use of this material.
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Page 1: A review of literature and computer models on exposure assessment

PLEASE SCROLL DOWN FOR ARTICLE

This article was downloaded by: [University of Greenwich]On: 14 December 2009Access details: Access Details: [subscription number 908060688]Publisher Taylor & FrancisInforma Ltd Registered in England and Wales Registered Number: 1072954 Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK

Environmental TechnologyPublication details, including instructions for authors and subscription information:http://www.informaworld.com/smpp/title~content=t791546829

A review of literature and computer models on exposure assessmentT. E. Butt a; M. Clark b; F. Coulon c; K. O. K. Oduyemi d

a School of Architecture & Construction, University of Greenwich, London, UK b School of Built &Natural Environment, University of Central Lancashire, Preston, UK c Centre for ResourceManagement and Efficiency, Sustainable Systems Department, School of Applied Sciences, CranfieldUniversity, Cranfield, UK d Department of Built & Natural Environment, School of ContemporarySciences, University of Abertay Dundee, Scotland, UK

Online publication date: 14 December 2009

To cite this Article Butt, T. E., Clark, M., Coulon, F. and Oduyemi, K. O. K.(2009) 'A review of literature and computermodels on exposure assessment', Environmental Technology, 30: 14, 1487 — 1501To link to this Article: DOI: 10.1080/09593330903345952URL: http://dx.doi.org/10.1080/09593330903345952

Full terms and conditions of use: http://www.informaworld.com/terms-and-conditions-of-access.pdf

This article may be used for research, teaching and private study purposes. Any substantial orsystematic reproduction, re-distribution, re-selling, loan or sub-licensing, systematic supply ordistribution in any form to anyone is expressly forbidden.

The publisher does not give any warranty express or implied or make any representation that the contentswill be complete or accurate or up to date. The accuracy of any instructions, formulae and drug dosesshould be independently verified with primary sources. The publisher shall not be liable for any loss,actions, claims, proceedings, demand or costs or damages whatsoever or howsoever caused arising directlyor indirectly in connection with or arising out of the use of this material.

Page 2: A review of literature and computer models on exposure assessment

Environmental Technology

Vol. 30, No. 14, 14 December 2009, 1487–1501

ISSN 0959-3330 print/ISSN 1479-487X online© 2009 Taylor & FrancisDOI: 10.1080/09593330903345952http://www.informaworld.com

A review of literature and computer models on exposure assessment

T.E. Butt

a

*, M. Clark

b

, F. Coulon

c

and K.O.K. Oduyemi

d

a

School of Architecture & Construction, University of Greenwich, Avery Hill Campus, Mansion Site, Bexley Road, Eltham, SE9 2PQ, London, UK;

b

School of Built & Natural Environment, University of Central Lancashire, Preston, PR1 2HE, UK;

c

Centre for Resource Management and Efficiency, Sustainable Systems Department, School of Applied Sciences, Cranfield University, Cranfield, MK43 0AL, UK;

d

Department of Built & Natural Environment, School of Contemporary Sciences, University of Abertay Dundee, Bell Street, Dundee, DD1 1HG, Scotland, UK

Taylor and Francis Ltd

(

Received 23 October 2007; Accepted January 2009

)

10.1080/09593330903345952

At the present time, risk analysis is an effective management tool used by environmental managers to protect theenvironment from inevitable anthropogenic activities. There are generic elements in environmental risk assessments,which are independent of the subject to which risk analysis is applied. Examples of these elements are: baseline study,hazard identification, hazards’ concentration assessment and risk quantification. Another important example of suchgeneric elements is exposure assessment, which is required in a risk analysis process for landfill leachate as it wouldin any other environmental risk issue. Furthermore, computer models are also being developed to assist risk analysisin different fields. However, in the review of current computer models and literature, particularly regarding landfills,the authors have found no evidence for the existence of a holistic exposure assessment procedure underpinned witha computational method for landfill leachate. This paper, with reference to the relevant literature and modelsreviewed, discusses the extent to which exposure assessment is absent in landfill risk assessment approaches. Thestudy also indicates a number of factors and features that should be added to the exposure assessment system in orderto render it more strategic, thereby enhancing the quantitative risk analysis.

Keywords:

waste disposal sites; landfill leachate; risk analysis; risk assessment; exposure analysis; exposureassessment; literature review; computer models

1. Introduction

1.1. Background

Because of factors such as the industrial revolution,escalating mass production of commodities, increasedurbanization, propagation of the human population andeconomic growths at national and international levels,wastes are generated at a rate greater than ever before.These wastes include industrial, commercial anddomestic waste streams. Although, in some cases,wastes are reported as being reduced at regional level[1], unfortunately, on the whole, waste production isstill on the increase in the UK [2–9]. Even if wastes arereduced at regional level, in some cases the release ofgreenhouse gases/carbon emissions, related to the trans-port of waste from the point of production to recyclingfacilities and outlets, could outweigh the ‘green’ advan-tage of reuse and/or recycling. For instance, it has beenreported that waste from the North-East of the UK isbeing driven as far as Wales for recycling [10]. More-over, waste is the inescapable outcome of the activitiesthat characterize human society; indeed in one sense it

is an indicator of the health of the modern economy[11]. It can be safely said that no matter now high wemove up the waste hierarchy (which is describedbelow), there will always be some waste left for land-filling.

Sustainable waste management simply means manag-ing waste by prioritizing as per the Waste Hierarchy,which is shown in Figure 1 [5,8,9,12,13]. This implieswaste prevention is the topmost priority if possible. Theother priorities in descending order are reduction; reuse;recovery via recycling, composting and energy utiliza-tion; and disposal, which also includes landfilling. Withreference to Figure 1, it must be noted that the landfillwaste option not only occupies a place in the last groupi.e. ‘Disposal’ but also is in the second to the last categoryup the waste hierarchy, i.e. ‘Recovery’.

Figure 1. The waste hierarchy. The arrow points from the least preferred waste management option to the topmost priority [DoE and Welsh Office, 1995a, 1995b, SITA, 2004, Envirowise, 2005, SEPA, 2008].

Having established that waste production is an inev-itable characteristic of an industrial society; most of thewaste produced, particularly in the UK [5], is generallydisposed to landfills. Waste disposal to landfills, ingeneral, is an easy and cheap waste management option.However, landfilling does raise severe environmental

*Corresponding author. Email: [email protected]

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T.E. Butt

et al.

concerns. One reason for this is that during the processof waste degradation, landfills produce waste productsin three phases. These are: solid (i.e. more or lessdegraded waste), liquid (i.e. leachate, which is waterpolluted with wastes) and gas (usually referred to aslandfill gas, comprising, for example, methane, carbondioxide and hydrogen sulphide).

Furthermore, landfills have the potential to pollutethe three principal environmental media – the atmo-sphere, the lithosphere and the hydrosphere. Such pollu-tion will be transmitted through these media and willimpact, either directly or indirectly, upon humans, thenatural environment (including aquatic and terrestrialflora and fauna) and the built environment [18,19].Thus, the risks associated with landfills need to beassessed and managed to guard the environment againstlandfill hazards, not only for humans but also otherreceptors including flora, fauna, water and land or soils.

On the other hand, environmental legislation is notonly becoming stricter and more stringent but also hasincreasingly followed a global trend. Some examples ofsuch legislation are listed below in chronological order.Some legislation is directly related to landfills (e.g. theLandfill Directive, the Waste Management LicensingRegulations, the Environmental Protection Act), whileothers are indirectly related. Directives cover not onlythe UK but also the other member states of the Euro-pean Union.

EC Directive on Groundwater [20],

EC Directive on EIA (Environmental ImpactAssessment) [21],

Environmental Protection Act, 1990 [22],

EC Directive on the Conservation of NaturalHabitats and of Wild Fauna and Flora (TheHabitats Directive) [23],

Waste Management Licensing Regulations[24,25],

Environment Act, 1995 [26],

EU Directive on IPPC (Integrated PollutionControl and Prevention) [27],

Groundwater Regulations [28],

Landfill Directive [29],

Water Framework Directive, [30],

Landfill Regulations [31–33,91],

Strategic Environmental Assessment (SEA)Directive [34].

In parallel with the growing environmental concernsand the globalization process described earlier, havingrealized the significance and effectiveness of riskassessment in environmental management, environ-mental legislators have started to impose risk analysisas a tool for meeting legal requirements associated withwaste hazards [35]. For instance, to protect groundwaterfrom landfill leachate, a risk assessment exercise wasintroduced in the UK as a legal requirement from 1

Figure 1. The waste hierarchy. The arrow points from the least preferred waste management option to the topmost priority[2,3,92,93,127].

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1489

May 1994, through Regulation 15 of the WasteManagement Licensing Regulations [24] and theGroundwater Regulations [28]. The Landfill Directiveis implemented in England and Wales through theLandfill Regulations [31], made under the PollutionPrevention and Control (PPC) Act (England and Wales)1999. The overall aim of the Landfill Directive, whichcame out in 1999, is to prevent or reduce as far as possi-ble negative impacts on the environment – in particularthe pollution of surface water, groundwater, soil and air– and on the global environment, including the green-house effect, as well as any resulting risk to humanhealth, from the landfilling of waste, during the wholelife-cycle of the landfill [36]. Equivalent legislation,which is called the Landfill (Scotland) Regulations, hascome out in Scotland [37–40]. Equivalent legislationhas also been in place in Northern Ireland since 2003[41]. It can be deduced from all these legislative instru-ments that the ‘out of sight, out of mind’ conceptregarding wastes (i.e. simply and blindly buried into theground and forgotten) is no longer applicable. Toachieve the maximum protection of the environmentagainst the hazards associated with landfill sites, allpotential hazards must be identified and risks associatedwith them assessed.

A risk assessment has two main aspects: hazardassessment and risk estimation [42]. The former aspectgenerally focuses on identification of the hazards’source, pathways and receptors/targets, whereas thelatter facet is to establish how likely it is that a givenhazard would reach and hit the receptor/target via thepathway. Specifically, in the former context, risk analy-sis has been applied to a number of subjects for a longtime. However, it is the latter aspect, i.e. the risk estima-

tion part of risk assessment, which is a comparativelynew and rapidly growing science, particularly in rela-tion to probabilistic and statistical approaches. Thus, onthe whole, risk assessment is a relatively new and fastdeveloping field of study [19,43,44]. This is not just inrelation to landfills and other environmental issues butalso in relation to other business fields including thefood industry, ecology, epidemiology, health physics,radiation, earthquakes, finance, construction manage-ment, building contract selection, insurance, economics,fire, landslides, ship navigation and the oil industry[19,44–52]. Regardless of the type of risk assessmentand the environmental area of application, one of theimportant parts of risk analysis is exposure assessment[53]. In the literature review carried out by the authors(examples and further details are contained in Table 1and Section 2), it was concluded that risk analysisapproaches for landfill leachate do not have a holisticexposure assessment procedure aided by a computermodel. A number of important elements of exposureassessment that are absent in risk analysis approachesand computer models are discussed below.

1.2. Definition and terminology implications

Figure 2 represents an overall structure of risk analysiswith a range of building blocks including baselinestudy, hazard identification, exposure assessment,hazards’ concentration assessment, pollutants’ migra-tion assessment, significance assessment, uncertaintyassessment, hazard indices and risk quantification. Inthe UK the term generally used is risk assessment, asopposed to risk analysis, which is more often used in theUSA. Therefore, the authors have noticed that both

Figure 2. The exposure assessment framework in relation to overall risk assessment structure (adapted, derived and concludedfrom the work of various authors including Peacock and Whyte [94], WDA [95], Tweeds [44], WHO [46], EPA [96], TOSC[97], CIRIA [42], Viswanathan et al. [98], CMSA [99]).

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T.E. Butt

et al.

terms are used interchangeably in the literature. Thus,this paper uses both risk assessment and risk analysisinterchangeably. This also helps to cover an interna-tional audience rather than just a national one.

Figure 2. The exposure assessment framework in relation to overall risk assessment structure (adapted, derived and concluded from the work of various authors including Peacock and Whyte [1992], WDA [1994], Tweeds [996], WHO [1997], US EPA [2000], TOSC [2000], CIRIA [2001],Viswanathan

et al.

[2002], CMSA [2004]).

Figure 2 shows the position of exposure assessmentin relation to the overall risk analysis structure. Thefigure also illustrates the other building blocks of therisk assessment process. In the figure, exposure assess-ment further branches out into its parts and sub-parts.The other building blocks are not the focus of thispaper, thus their parts and sub-parts are beyond thescope of this paper.

In the context of landfill risk analysis, the authorsdescribe an exposure assessment process as that funda-mental stage of a risk assessment exercise in which agiven landfill, i.e. the pollutant source, is characterizedand pathways and environmental receptors are identifiedand categorized. For this, the basic information comesfrom the baseline study module of the risk assessment,where the relevant information would already have beengathered by the risk assessor [19]. Similarly, hazards/pollutants would have already been specified in thehazard identification section of the risk assessment [54].In exposure assessment, in addition to identification,characterization and categorization of the hazards’source, pathways and receptors/targets, exposures of theidentified receptors to the identified hazards throughidentified pathways are also quantified to support thequantitative risk analysis. It is worth mentioning thatthe term ‘holistic’ in this paper implies an overall frame-work or system, covering all aspects and factors of theexposure assessment from the point of view of theleachate.

2. Literature on risk analysis and exposure assessment

The literature on risk assessment that is related to envi-ronmental issues, specifically regarding landfills, is themain focus of this review. This literature reviewincludes, for instance, Gregory

et al.

[55], Nathanailand Nathanail [56], Bardos

et al.

, [57,58], Eduljee [59],Redfearn

et al.

[60], DoE [61] and CIRIA [42] (seemore references in Table 1). In this study, in addition tothe latest literature, some old material has also beenconsidered, to check if any developments on the subjectwere made in the far past. The review of the literatureclearly shows that exposure assessment is a crucialfactor in an environmental risk analysis becausehazards’ source, pathways and receptors have to bespecified and exposures have to be measured in order tobe able to establish the degree and nature of risks. Thefollowing two sub-sections explain why the develop-ment of a strategic framework of exposure assessmentis necessary for landfill leachate.

2.1. Current and future legislation

Table 1 shows that the current literature (and computermodels discussed in section 3) regarding risk analysisand exposure assessment are just about sufficient tomeet the current legislation requirements, such as thedrinking water standards. The literature mainly consid-ers humans as receptors. Furthermore, in terms of thedevelopment of an overall exposure assessment proce-dure, there is a lack of attention given to some otheraspects. Some examples of such aspects are:

receptors other than humans, such as aquatic andterrestrial flora and fauna (like fish, crops),

natural and yet non-living receptors such as land/soil, air, watercourses/groundwater, etc.,

the built environment such as human-madeponds, buildings and structures,

watercourses other than those used by humans fordrinking, such as rivers of various water grades[62],

statistical descriptions for maximum and meanexposure quantification, in order to assist withmeasuring risks for worst case and most likelyscenarios, respectively, in a risk analysis process.

The above listed areas become more important as futurelegislation becomes more stringent, inclusive and inte-grated (Section 1). For instance, the Water FrameworkDirective [30] will be incorporated into the UK legisla-tion in the near future. This Directive includes newrequirements for protection and restoration not only ofground waters but also of surface waters and dependentecological systems [35]. Similarly, the Landfill Direc-tive and Regulations go beyond surface and groundwater and include air, soil, the global environment,greenhouse gases, and human health [29,32,34,91].Another directive, generally referred to as the HabitatDirective [23], brings a legal obligation to combathazards in order to guard and enhance natural habitatsand wild fauna and flora. On the basis of these examplesof legislation, which are tending to be much more holis-tic than ever before, it can be concluded that an evenmore integrated approach towards exposure assessmentand subsequent risk analysis is required.

2.2. Non-integrated literature on exposure assessment and risk assessment

A review of environmental related literature led to theconclusion that a comprehensive, robust, detailed andsound risk assessment methodology, with a number ofessential features, does not exist in an integratedmanner. Examples of such essential features are listedbelow:

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Environmental Technology

1491Ta

ble

1.L

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atur

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sum

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to a

ddre

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enti

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abo

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in

Row

1)

in a

hol

isti

c fo

rmat

spe

cifi

call

y fo

r la

ndfi

ll l

each

ate.

CIR

IA, [

42]

Thi

s pu

blic

atio

n is

onl

y fo

r cl

osed

lan

dfil

l si

tes.

The

pub

lica

tion

co

ntai

ns a

cha

pter

spe

cifi

call

y on

ris

k as

sess

men

t, w

hich

als

o co

ntai

ns a

bri

ef s

ecti

on o

n ex

posu

re a

sses

smen

t w

here

mai

n fa

ctor

s of

exp

osur

e an

alys

is a

re o

nly

men

tion

ed.

The

re i

s no

pro

cedu

re f

or e

xpos

ure

asse

ssm

ent.

Downloaded By: [University of Greenwich] At: 17:41 14 December 2009

Page 7: A review of literature and computer models on exposure assessment

1492

T.E. Butt

et al.Ta

ble

1.(

Con

tinu

ed

).

Pub

lica

tion

Ele

men

ts p

rese

ntE

lem

ents

abs

ent

Env

iron

men

t A

genc

y, [

35]

Pro

vide

s gu

idel

ines

for

lan

dfil

l ri

sk a

sses

smen

t an

d on

ly f

or

grou

ndw

ater

as

rece

ptor

. Ide

ntif

ies

som

e fu

ndam

enta

l re

quir

emen

ts o

f ris

k as

sess

men

t on,

e.g

. geo

logy

, hyd

roge

olog

y an

d si

te i

nves

tiga

tion

.

Tho

ugh

a gu

idel

ine

on l

andf

ill

risk

ass

essm

ent

exis

ts, i

t do

es n

ot c

onsi

der

rece

ptor

s ot

her

than

gro

undw

ater

. Tho

ugh

this

pub

lica

tion

rel

ates

to

risk

as

sess

men

t for

land

fill

leac

hate

, it i

s no

t hol

isti

c in

the

form

of

a m

etho

dolo

gy

or r

eady

-to-

use

proc

edur

e. T

here

are

no

cons

ider

atio

ns o

f qu

anti

fica

tion

of

expo

sure

and

ris

k. T

he c

ompu

ter

mod

elli

ng a

spec

t of

the

pub

lica

tion

(i.e

. L

andS

im)

is d

iscu

ssed

in

Sec

tion

3.

DE

TR

et a

l.

, [10

2]T

he d

ocum

ent

stat

es t

hat

it p

rovi

des

mat

eria

l, in

gen

eral

, for

the

de

velo

pmen

t of

ris

k an

alys

is g

uida

nce

to a

ssis

t is

sues

lik

e co

ntam

inat

ed l

and,

was

te m

anag

emen

t an

d m

ajor

acc

iden

t ha

zard

s.

The

pub

lica

tion

add

ress

es a

ran

ge o

f is

sues

in

gene

ral

(lis

ted

in t

he l

eft

colu

mn)

bu

t no

t sp

ecif

ical

ly f

or l

andf

ills

or

land

fill

lea

chat

e. T

he o

bjec

tive

of

this

pu

blic

atio

n is

not

to

deve

lop

an i

nteg

rate

d ex

posu

re a

sses

smen

t to

ass

ist

quan

tita

tive

ris

k an

alys

is. I

n su

mm

ary,

in th

e co

ntex

t of

land

fill

leac

hate

all

the

elem

ents

abo

ve (

Row

1)

are

not

in t

he r

emit

of

this

pub

lica

tion

.D

EF

RA

and

E

nvir

onm

ent

Age

ncy,

[77

]

Thi

s pu

blic

atio

n re

late

s to

hum

an e

xpos

ure

asse

ssm

ent

for

cont

amin

ated

lan

d. D

etai

ls o

n va

riou

s as

pect

s of

exp

osur

e as

sess

men

t are

giv

en. E

xam

ples

are

exp

osur

e pa

ram

eter

s (s

uch

as e

xpos

ure

dura

tion

, fre

quen

cy),

soi

l re

leas

e an

d tr

ansf

er

mec

hani

sms,

exp

osur

e eq

uati

ons,

hum

an a

ctiv

itie

s an

d ag

es,

expo

sure

rou

tes

and

vari

ous

land

-use

s.

Dea

ls in

det

ail w

ith

hum

ans

as r

ecep

tors

, but

not

oth

er e

nvir

onm

enta

l spe

cies

and

ec

osys

tem

s. E

lem

ent 5

, abo

ve, i

s al

so n

ot p

rese

nt. I

t doe

s no

t spe

cifi

call

y re

late

to

lan

dfil

l le

acha

te. I

t is

for

con

tam

inat

ed l

and

in g

ener

al.

Env

iron

men

t A

genc

y, [

103]

Thi

s do

cum

ent

brie

fly

addr

esse

s a

broa

d an

d di

vers

e ra

nge

of

face

ts o

f la

ndfi

ll r

isk

anal

ysis

alo

ng s

ocia

l, te

chni

cal,

envi

ronm

enta

l, ec

onom

ic, l

egis

lati

ve a

nd m

anag

eria

l th

emes

. B

oth

land

fill

gas

and

leac

hate

are

add

ress

ed. T

he m

ain

scop

e of

th

e gu

idan

ce i

s li

mit

ed t

o fi

ve a

reas

of

risk

ana

lysi

s, w

hich

are

ac

cide

nts

and

thei

r co

nseq

uenc

es, h

ydro

geol

ogy,

lan

dfil

l ga

s,

part

icul

ate

mat

ter

and

stab

ilit

y. T

he d

ocum

ent

brie

fly

touc

hes

on e

lem

ents

like

sou

rce,

pat

hway

s an

d re

cept

ors

but n

ot a

s pa

rts

of a

n ex

posu

re a

sses

smen

t sy

stem

.

A h

olis

tic

expo

sure

ass

essm

ent

proc

edur

e ac

com

pani

ed w

ith

a co

rres

pond

ing

com

pute

r m

odel

is

not

in t

he r

emit

of

this

pub

lica

tion

. The

re i

s no

all

owan

ce

for

expo

sure

qua

ntif

icat

ion.

Sta

tist

ical

des

crip

tion

s li

ke m

axim

um, m

ean

and

min

imum

exp

osur

es a

re n

ot i

n th

e sc

ope

eith

er. A

s th

e do

cum

ent

stat

es, t

here

ar

e fi

ve m

ain

area

s w

hich

con

stit

ute

the

mai

n re

mit

of

the

guid

ance

(li

sted

in

the

left

col

umn)

. How

ever

, lan

dfil

l le

acha

te i

s no

t on

e of

the

m t

houg

h it

is

addr

esse

d to

an

exte

nt. T

he g

uida

nce

also

men

tion

s th

at it

doe

s no

t pro

vide

all

th

e de

tail

nee

ded

to c

ondu

ct r

isk

anal

ysis

for

a la

ndfi

ll, a

nd th

e sa

me

hold

s fo

r ex

posu

re a

sses

smen

t.G

rego

ry

et a

l.,

[55

]T

his

publ

icat

ion

is f

or r

isk

anal

ysis

of

land

fill

gas

onl

y an

d co

ncer

ns m

ainl

y hu

man

s as

rec

epto

rs. E

ngag

es w

ith

som

e ri

sk

asse

ssm

ent

mod

ules

suc

h as

gas

gen

erat

ion,

hum

an e

xpos

ure

asse

ssm

ent

wit

h qu

anti

fica

tion

asp

ect,

poll

utan

ts’

mig

rati

on.

The

ris

k qu

anti

fica

tion

asp

ect

is a

bsen

t. It

is

not

for

land

fill

lea

chat

e. E

lem

ent

5 ab

ove

is n

ot e

mbe

dded

, eve

n fo

r la

ndfi

ll g

as. F

rom

a l

each

ate

pers

pect

ive,

all

th

e af

ores

aid

elem

ents

are

abs

ent.

Mos

chan

drea

s

et a

l.

, [53

]F

ocus

es o

n on

e ty

pe o

f ha

zard

, i.e

. par

ticu

late

mat

ter

(PM

) an

d on

ly i

n ai

r as

an

expo

sure

med

ium

. The

onl

y ex

posu

re r

oute

ac

coun

ted

for

is i

nhal

atio

n an

d th

is c

onsi

ders

onl

y hu

man

s as

re

cept

ors.

Doe

s no

t pr

esen

t ex

posu

re a

sses

smen

t as

an

over

all

proc

edur

e an

d, s

peci

ally

, el

emen

t 5

abov

e is

not

inc

lude

d. T

his

publ

icat

ion

is n

ot s

peci

fica

lly

for

land

fill

s. A

s m

enti

oned

in th

e co

rres

pond

ing

adja

cent

left

cel

l, co

nsid

erat

ion

of

type

s of

haz

ard,

exp

osur

e m

ediu

m, e

xpos

ure

rout

e an

d re

cept

or is

ver

y li

mit

ed.

Bag

li a

nd S

pado

ni,

[63]

Thi

s pu

blic

atio

n ta

kes

acco

unt

of i

ndus

tria

l fa

cili

ties

as

poll

utan

t so

urce

s an

d hu

man

s as

rec

epto

rs. I

t tou

ches

on

vari

ous

aspe

cts

of e

xpos

ure

asse

ssm

ent

incl

udin

g ex

posu

re r

oute

s, e

quat

ions

an

d qu

anti

fica

tion

. Als

o br

iefl

y w

rite

s ab

out r

isk

asse

ssm

ent i

n th

e li

ght

of G

IS (

geog

raph

ical

inf

orm

atio

n sy

stem

s).

It i

s no

t fo

r la

ndfi

lls

at a

ll. E

xpos

ure

asse

ssm

ent

is n

ot p

rese

nted

as

an o

vera

ll

proc

edur

e. R

ecep

tors

oth

er th

an h

uman

s ha

ve n

ot b

een

incl

uded

. In

the

cont

ext

of l

andf

ill

leac

hate

, all

the

ele

men

ts m

enti

oned

abo

ve a

re a

bsen

t as

wel

l.

Red

fear

n

et a

l.

, [60

]T

his

publ

icat

ion

is r

elat

ed to

ris

k as

sess

men

t and

thus

als

o br

iefl

y m

enti

ons

expo

sure

ass

essm

ent.

How

ever

, thi

s pu

blic

atio

n is

re

late

d to

lan

dfil

l ga

s an

d no

t le

acha

te. T

hus,

it

focu

ses

on t

he

expo

sure

rou

te o

f in

hala

tion

onl

y. A

lso,

it

iden

tifi

es s

ome

sens

itiv

itie

s an

d un

cert

aint

ies

asso

ciat

ed w

ith

expo

sure

as

sess

men

t.

Apa

rt f

rom

a v

ery

lim

ited

sec

tion

on

expo

sure

ass

essm

ent,

ther

e is

no

proc

edur

e fo

r de

scri

bing

how

to

perf

orm

the

exp

osur

e an

alys

is p

roce

ss. A

ll t

he e

lem

ents

m

enti

oned

abo

ve a

re a

bsen

t fro

m th

e pe

rspe

ctiv

e of

leac

hate

. Alt

houg

h th

e fi

rst

four

ele

men

ts a

re p

artl

y ad

dres

sed

to a

n ex

tent

, the

con

side

rati

on i

s fr

om t

he

land

fill

gas

per

spec

tive

.

Downloaded By: [University of Greenwich] At: 17:41 14 December 2009

Page 8: A review of literature and computer models on exposure assessment

Environmental Technology

1493Ta

ble

1.(

Con

tinu

ed

).

Pub

lica

tion

Ele

men

ts p

rese

ntE

lem

ents

abs

ent

DoE

, [61

]T

his

publ

icat

ion

port

rays

, mor

e th

an a

ny o

ther

lite

ratu

re s

tudi

ed to

da

te, e

xpos

ure

asse

ssm

ent

in a

hol

isti

c m

anne

r. H

owev

er, t

he

focu

s is

on

hum

an h

ealt

h on

ly a

nd n

o ot

her

envi

ronm

enta

l re

cept

ors.

Sim

ilar

ly, n

ot a

ll p

oten

tial

pat

hway

s ha

ve b

een

incl

uded

: on

ly s

ix e

xpos

ure

path

way

s, w

hich

cov

er m

ost

risk

s to

hum

an h

ealt

h fr

om l

andf

ills

.

Doe

s no

t pr

esen

t an

exp

osur

e as

sess

men

t pr

oced

ure

in a

hol

isti

c m

anne

r, i

n th

e fo

rm o

f a c

ompu

ter m

odel

, tha

t is

elem

ent n

umbe

r 6 (a

bove

in R

ow 1

) is

abse

nt.

Doe

s no

t ta

ke a

ccou

nt o

f al

l en

viro

nmen

tal

rece

ptor

s su

ch a

s fl

ora

and

faun

a,

but

only

hum

ans.

Wit

h re

fere

nce

to p

oint

2 a

bove

. Thi

s pu

blic

atio

n do

es n

ot

seem

to

have

a f

acil

ity

whe

re a

ll i

ndiv

idua

l ex

posu

res

via

vari

ous

corr

espo

ndin

g in

divi

dual

exp

osur

e ro

utes

, cou

ld b

e su

mm

ed u

p to

det

erm

ine

tota

l ex

posu

re f

or a

giv

en r

ecep

tor

expo

sed

to a

giv

en h

azar

d. D

oes

not

take

ac

coun

t of

sta

tist

ical

asp

ects

, as

indi

cate

d in

ele

men

t 5

abov

e.E

dulj

ee, [

59]

A p

roce

dure

on

expo

sure

ass

essm

ent

has

been

out

line

d, w

hich

co

vers

ele

men

ts li

ke 1

and

2 (

list

ed a

bove

) to

var

ious

leve

ls o

f de

tail

. How

ever

, onl

y hu

man

s ha

ve b

een

cons

ider

ed a

s re

cept

ors.

No

com

pute

r m

odel

exi

sts

for

the

expo

sure

ass

essm

ent

proc

edur

e in

a h

olis

tic

man

ner.

Ele

men

ts 3

, 4 a

nd 5

abo

ve a

re a

bsen

t an

d el

emen

t 2

is a

ddre

ssed

to

a li

mit

ed e

xten

t. T

he p

roce

dure

pre

sent

ed e

xclu

des

vari

ous

envi

ronm

enta

l re

cept

ors

such

as

flor

a, f

auna

and

the

bui

lt e

nvir

onm

ent.

Asa

nte-

Dua

h,

[104

]E

ncir

cles

all

im

port

ant

aspe

cts

of r

isk

anal

ysis

and

man

agem

ent

(inc

ludi

ng e

xpos

ure

asse

ssm

ent)

of

cont

amin

ated

land

s, b

ut n

ot

in t

he f

orm

of

a m

etho

dolo

gy. T

he v

ario

us a

spec

ts h

ave

been

co

nsid

ered

ind

epen

dent

ly o

f ea

ch o

ther

.

Not

spe

cifi

call

y fo

r la

ndfi

lls.

Als

o al

l th

e el

emen

ts a

bove

are

abs

ent.

Dau

gher

ty, [

105]

Con

tain

s de

tail

s no

t on

ly o

f ex

posu

re b

ut a

lso

of s

ourc

es (

of

haza

rds)

, pat

hway

s an

d re

cept

ors

in s

epar

ate

chap

ters

.T

his

publ

icat

ion,

lik

e ot

hers

, doe

s no

t de

pict

exp

osur

e as

sess

men

t in

the

for

m o

f a

proc

edur

e th

at a

ris

k as

sess

or c

ould

use

to m

easu

re e

xpos

ure.

The

pub

lica

tion

is

not

spe

cifi

call

y fo

r la

ndfi

lls.

Mor

eove

r, a

ll t

he e

lem

ents

abo

ve a

re a

bsen

t.E

nvir

onm

ent

Age

ncy,

[10

6]T

his

land

fill

risk

ass

essm

ent p

ubli

cati

on is

from

the

pers

pect

ive

of

issu

es i

nclu

ding

noi

se, o

dour

, lit

ter,

bir

ds, v

erm

in, i

nsec

ts a

nd

mud

on

road

.

The

pub

lica

tion

is n

ot a

bout

land

fill

leac

hate

. Thu

s, th

e el

emen

ts in

dica

ted

in R

ow

1 ab

ove

are

not

in t

he s

cope

of

the

publ

icat

ion.

Ber

nard

et a

l.

, [1

07,1

08]

The

se tw

o pa

pers

(P

arts

1 a

nd 2

) ar

e on

haz

ard

anal

ysis

of

land

fill

le

acha

te. T

hey

disc

uss

leac

hate

s fr

om 2

5 la

ndfi

lls

in F

ranc

e as

ca

se s

tudi

es, u

sing

a n

umbe

r of

met

hods

for

det

erm

inin

g le

acha

te t

oxic

ity

and

then

com

pari

ng t

he p

hysi

co-c

hem

ical

ch

arac

teri

stic

s of

the

lea

chat

es.

Alt

houg

h th

e te

chni

ques

ide

ntif

ied

on m

easu

ring

tox

icit

y of

lan

dfil

l le

acha

te c

an

be u

sefu

l in

exp

osur

e as

sess

men

t fo

r a

give

n la

ndfi

ll, t

hese

pap

ers

do n

ot

pres

ent p

roce

dure

s fo

r ex

posu

re a

naly

sis,

and

the

elem

ents

exp

ress

ed a

bove

are

no

t ad

dres

sed

in a

n in

tegr

ated

man

ner.

EP

D, [

109]

Thi

s pu

blic

atio

n is

a g

uide

line

for

haz

ard

anal

ysis

of

land

fill

gas

. It

bri

efly

cov

ers

vari

ous

aspe

cts

of h

azar

d an

d ri

sk a

sses

smen

t su

ch a

s ha

zard

mit

igat

ion

mea

sure

s an

d a

sour

ce–p

athw

ay–

targ

et a

naly

sis.

The

pub

lica

tion

is

not

for

land

fill

lea

chat

e. E

ven

for

land

fill

gas

, the

afo

resa

id

elem

ents

are

eit

her

abse

nt o

r pa

rtly

cov

ered

to a

lim

ited

ext

ent (

as m

enti

oned

in

the

left

col

umn)

.

Kav

azan

jian

et a

l.

, [1

10];

Eis

enbe

is

et a

l.

, [11

1];

Jagg

y, [

112]

; W

DA

, [95

];

LaG

oy, [

43];

D

OE

, [11

3]; a

nd

Pie

per

et a

l.

, [1

14]

In a

ddit

ion

to o

ther

old

lite

ratu

re o

n la

ndfi

ll a

sses

smen

t dis

cuss

ed

earl

ier

in t

he c

urre

nt p

aper

, the

se p

ubli

cati

ons

wer

e al

so

inve

stig

ated

to

mak

e su

re i

f an

y w

ork

had

been

don

e on

ex

posu

re a

naly

sis

rela

tive

ly f

urth

er i

n th

e pa

st. T

hese

pap

ers

wer

e fo

und

to a

ddre

ss v

ario

us r

isk

asse

ssm

ent

issu

es l

ike

seis

mic

haz

ard

anal

ysis

for

lan

dfil

ls, r

isk

asse

ssm

ent

itse

lf,

land

fill

typ

e an

d na

ture

, con

tam

inat

ed l

and

rem

edia

tion

, ha

zard

ous

was

tes,

HW

IR (

haza

rdou

s w

aste

ide

ntif

icat

ion

rule

) an

d sp

ecif

ic h

azar

ds s

uch

as p

olyc

hlor

inat

ed d

iben

zo-p

-dio

xins

an

d fu

rans

(P

CD

D/F

).

The

se p

ubli

cati

ons

cove

r var

ious

asp

ects

and

fact

ors

of ri

sk a

sses

smen

t (in

clud

ing

expo

sure

ana

lysi

s) to

var

ying

deg

rees

. How

ever

, non

e of

them

app

ear t

o pr

esen

t a

holi

stic

sys

tem

of

the

expo

sure

ass

essm

ent

proc

ess

in a

qua

ntit

ativ

e m

anne

r fo

r la

ndfi

ll l

each

ate,

whi

ch c

ould

tak

e ac

coun

t of

all

pos

sibl

e sc

enar

ios

and

elem

ents

ind

icat

ed i

n R

ow 1

abo

ve.

SE

PA

, [11

5]T

his

publ

icat

ion

rega

rds

land

fill

ris

k as

sess

men

t in

the

cont

ext o

f la

ndfi

ll l

each

ate

line

rs a

nd d

rain

age

syst

ems.

Thi

s pu

blic

atio

n do

es n

ot d

escr

ibe

a st

rate

gic

proc

edur

e to

car

ry o

ut th

e ex

posu

re

asse

ssm

ent

proc

ess

in a

qua

ntit

ativ

e m

anne

r.

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1494

T.E. Butt

et al.Ta

ble

1.(

Con

tinu

ed

).

Pub

lica

tion

Ele

men

ts p

rese

ntE

lem

ents

abs

ent

CP

PD

, [11

6]C

urre

ntly

the

pub

lica

tion

is

in a

dra

ft f

orm

. It

rega

rds

haza

rd a

nd

risk

ass

essm

ent

in t

he c

onte

xt o

f na

tura

l ha

zard

s su

ch a

s fl

oodi

ng, e

arth

quak

e, l

ands

lide

s an

d w

ildf

ires

.

The

pub

lica

tion

doe

s no

t con

side

r an

thro

poge

nic

acti

viti

es a

nd th

eref

ore

does

not

co

nsid

er la

ndfi

lls

at a

ll. I

t dis

cuss

es v

ario

us n

atur

al h

azar

ds, w

ith

stat

isti

cs, b

ut

does

not

pre

sent

a s

truc

ture

d ex

posu

re a

naly

sis

proc

edur

e ev

en f

or t

he n

atur

al

haza

rds

cove

red.

Rud

land

et a

l.

, [1

17]

Des

crib

es a

bas

ic f

ram

ewor

k fo

r th

e ri

sk a

sses

smen

t of

co

ntam

inat

ed l

and.

Not

spe

cifi

call

y fo

r la

ndfi

lls.

All

the

ele

men

ts a

bove

(R

ow 1

) ar

e ab

sent

.

Auc

klan

d R

egio

nal

Cou

ncil

, [11

8]

Thi

s pu

blic

atio

n, w

hich

is

a go

vern

men

t do

cum

ent

for

loca

l au

thor

itie

s, c

over

s ri

sk a

sses

smen

t in

a v

ery

broa

d se

nse

of

haza

rds.

The

se i

nclu

de n

atur

al h

azar

ds s

uch

as t

orna

does

, fl

oodi

ng, e

arth

quak

es; t

echn

olog

ical

haz

ards

like

hig

h pr

essu

re

gas

mai

ns, c

ompu

ter

syst

ems

fail

ure;

bio

logi

cal

haza

rds

incl

udin

g di

seas

e am

ongs

t pe

ople

, ani

mal

s or

pla

nts;

and

civ

il/

poli

tica

l ha

zard

s co

mpr

isin

g te

rror

ism

and

civ

il u

nres

t.

The

pub

lica

tion

is n

ot s

peci

fica

lly

for

land

fill

s. I

t jus

t enc

apsu

late

s al

l nat

ural

and

an

thro

poge

nic

haza

rds

wit

hout

pre

sent

ing

a ho

list

ic p

roce

dure

eit

her

for

expo

sure

ass

essm

ent

or r

isk

anal

ysis

. The

for

mat

is

mor

e li

ke a

che

ckli

st.

DO

E, [

119]

Thi

s en

viro

nmen

tal

guid

ance

men

tion

s ri

sk-b

ased

cor

rect

ive

acti

on (

RB

CA

) st

anda

rds

deve

lope

d fo

r ad

dres

sing

pet

role

um

and

chem

ical

rel

ease

s. T

he p

urpo

se o

f th

is g

uide

is

to e

xpla

in

risk

-bas

ed d

ecis

ion

mak

ing

and

the

RB

CA

pro

cess

for

en

viro

nmen

tal

rest

orat

ion

of c

hem

ical

ly c

onta

min

ated

sit

es.

The

pur

pose

of

this

doc

umen

t is

not

the

dev

elop

men

t of

a h

olis

tic

expo

sure

as

sess

men

t met

hodo

logy

. The

sys

tem

pre

sent

ed is

not

for

land

fill

s as

suc

h. T

he

syst

em p

lace

mor

e em

phas

is o

n de

term

inin

g th

e da

ta r

equi

red

for

tech

nica

l de

cisi

on m

akin

g ra

ther

tha

n on

fol

low

ing

spec

ific

ste

ps o

f an

exp

osur

e as

sess

men

t pr

oces

s, a

s in

dica

ted

in t

he a

fore

said

ele

men

ts i

n R

ow 1

.E

PA

, [12

0];

EP

A,

[121

–123

]T

hese

fou

r do

cum

ents

cov

er r

isk

asse

ssm

ents

rel

atin

g to

ne

urot

oxic

ity,

rep

rodu

ctiv

e to

xici

ty, e

colo

gy a

nd c

arci

noge

ns,

resp

ecti

vely

.

The

se d

ocum

ents

may

be

usef

ul i

n ex

posu

re a

sses

smen

t an

d ri

sk a

naly

sis

of

land

fill

lea

chat

e in

the

con

text

of

esta

blis

hing

neu

roto

xici

ty, r

epro

duct

ive

toxi

city

, eco

logi

cal

and

carc

inog

enic

aff

ects

of

leac

hate

pol

luta

nts.

How

ever

, th

ese

publ

icat

ions

are

not

pro

duce

d sp

ecif

ical

ly f

rom

the

poi

nt o

f vi

ew o

f la

ndfi

ll le

acha

te. T

hus,

ther

e is

no

inte

grat

ed p

roce

dure

to c

arry

out

an

expo

sure

an

alys

is p

roce

ss in

a q

uant

itat

ive

man

ner

for

land

fill

leac

hate

, whi

ch c

ould

take

ac

coun

t of

all

pos

sibl

e sc

enar

ios

and

the

elem

ents

ind

icat

ed a

bove

in

Row

1.

EP

A, [

124,

125]

The

se p

ubli

cati

ons

are

pure

ly f

or e

xpos

ure

asse

ssm

ent.

Thu

s, th

ey

enci

rcle

the

subj

ect f

rom

man

y di

ffer

ent p

ersp

ecti

ves

incl

udin

g no

t onl

y as

pect

s of

haz

ards

, pat

hway

s, r

ecep

tors

and

exp

osur

es;

but a

lso

type

s of

dos

es (

e.g.

pot

enti

al d

ose,

inta

ke d

ose,

app

lied

do

se),

exp

osur

e–do

se r

elat

ions

hips

, unc

erta

inty

ass

essm

ent,

indi

vidu

al a

nd p

opul

atio

n ex

posu

re, e

xpos

ure

anal

ysis

in

epid

emio

logi

cal

stud

ies

and

posi

tion

of

the

expo

sure

as

sess

men

t it

self

wit

h re

spec

t to

ris

k ch

arac

teri

zati

on.

Alt

houg

h th

ese

publ

icat

ions

foc

us p

urel

y on

exp

osur

e as

sess

men

t, th

e do

cum

ents

do

not

por

tray

a h

olis

tic

proc

edur

e fo

r ca

rryi

ng o

ut e

xpos

ure

anal

ysis

, eit

her

spec

ific

ally

for

lan

dfil

ls o

r fo

r an

y ot

her

envi

ronm

enta

l ri

sk a

naly

sis.

All

the

el

emen

ts a

bove

(R

ow 1

) ar

e ab

sent

in

thes

e pu

blic

atio

ns f

rom

the

lan

dfil

l pe

rspe

ctiv

e.

CM

SA

, [99

];

Pun

coch

ar,

[126

]; K

oivi

sto

et a

l.

, [15

];

Fel

dman

and

W

hite

, [16

];

CH

EM

Uni

t, [1

7];

Pau

luhn

, [1

28];

Mut

h

et a

l.

, [14

];

Tar

azon

a an

d V

ega,

[12

9]

The

se p

ubli

cati

ons

rela

te t

o ha

zard

and

ris

k as

sess

men

t in

the

co

ntex

t of

the

se r

espe

ctiv

e su

bjec

ts:

min

ing,

wor

kpla

ce,

gene

tica

lly

mod

ifie

d or

gani

sms,

neu

rolo

gy, i

ndoo

r en

viro

nmen

t, ec

olog

y, t

oxic

olog

y, f

ood

and

chem

ical

s.

The

se p

ubli

cati

ons

are

not f

or la

ndfi

lls.

All

the

afor

esai

d el

emen

ts a

re a

bsen

t fro

m

the

land

fill

lea

chat

e pe

rspe

ctiv

e.

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Environmental Technology

1495

encompassing various types of landfill systemsand their surroundings,

taking into account all possible characteristics oflandfills in terms of risks and quantification ofrisks,

embedding procedures of relevant modules (suchas baseline study, hazard identification, hazards’concentration assessment, exposure analysis,pollutants’ migration, etc.). Figure 2 illustratesthese modules.

A number of knowledge gaps have been found in theliterature reviewed to date. One of the common gaps isan integrated and computer aided procedure for carry-ing out exposure assessment, specifically for landfillleachate. The literature on exposure assessment islimited, indirect and piecemeal. The current literatureaccounts for different aspects of exposure analysis todifferent levels of detail. The publications are non-inte-grated and independent of each other. Some publica-tions (such as [60]) focus on humans as receptors andonly consider the inhalation exposure route, whereasother environmental species and exposure routes areexcluded. Some publications emphasize certain types ofhazards and not all possible hazards (for example [53]focus only on the particulate matter hazard). In somepublications, only multimedia and multipathway expo-sure and risk assessment of contamination due to anindustrial facility are discussed (e.g. [63]. Some publi-cations (such as [59,61] consider exposure analysis in ageneral context and focus only on humans as receptors.Some literature concentrates on exposure from thecontaminated land perspective but not specifically land-fills. Further details are given in Table 1. In summary,there does not exist an exposure assessment procedurethat allows integrated consideration of all the factorslisted in Table 1 (first row) for all environmental recep-tors, both living and non-living, via all exposure routes.

3. Computer models of risk analysis and exposure assessment

The development of computational methods and theability to model systems more precisely now enablehazards to be quantified, their effects to be simulated,and risk analysis to be pursued with greater accuracy.This leads to a more effective risk management. Thesedevelopments are not only important for all areas ofhuman endeavour, but have particular relevance to envi-ronmental issues where the risks involved are increas-ingly seen as substantial. However, no evidence of acomputer model of total risk assessment, which regardsthe knowledge gaps indicated in Section 2, has beenfound. The case is identical in terms of computermodelling for exposure assessment alone, as discussed

in detail later in this section. In this paper, a computermodel is seen as an electronic representation of a meth-odology or procedure.

The investigation of various relevant computermodels during the literature review led to the identifica-tion of models that are closely related to landfill riskassessment. These models are LandSim [64,65], HELP[66], GasSim [67,68], GasSimLite [69] and RIP [70,71].The first four computer models were specificallydesigned for landfills, although the features of the RIP(Repository Integration Programme) were subsequentlyextended to take landfills into account on a compara-tively large scale. While other software types studied arenot demonstrably related to landfill risks, they couldstill be used to an extent to investigate some aspects oflandfill exposure assessments and, consequently, riskassessments.

Software packages addressing landfill risk assess-ment do not holistically encapsulate all elements ofrisk analysis methodology for landfills, including thatof exposure assessment. However, some of thecomputer models could deal with some aspects ofexposure assessment for landfills. For example, theRIP, which is an integrated probabilistic simulator forenvironmental systems, has been designed generallyfor any potential pollutant source in the ground e.g. achemical storage tank. So with the RIP, which is ageneric software model, risk assessors have to adapt itto their specific problems (such as landfills). Thisadaptation is time-consuming and it is not an easy taskfor everyone [72]). The RIP has features that embracesource, pathway and receptor. This it does in terms oflikely concentrations of hazards leaking from thesource, migrating via a pathway, and reaching andentering receptors. However, the RIP does not readilyprovide such a straightforward exposure assessmentprocedure for landfill leachate where a landfill asses-sor could identify and categorize the hazards’ source(that is a given landfill), pathways (mainly exposuremedia) and receptors. In the same manner, it alsodoes not readily provide for a consideration ofstatistical descriptions for maximum and mean expo-sure values.

On the other hand the LandSim model, which ispurely for landfill risk assessment, does not embed allparts of a landfill risk assessment process, including thatof exposure assessment. LandSim just probabilisticallyestimates the likely concentration of a leachate pollutantthat can reach a given point in the ground (for examplea groundwater abstraction point) in a certain time, interms of years. It does not allow for the quantificationof exposure, such as the degree of exposure for people(or livestock) if they were to consume this groundwater.Therefore, the LandSim’s characteristic of pollutantconcentration estimation in an exposure medium such

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T.E. Butt

et al.

as groundwater can be taken a step further to quantifyexposure to, for instance, livestock or a fish farm, whichwould make quantitative risk assessment more compre-hensive. This way, a holistic exposure assessmentmethodology can be useful to further build on the infor-mation obtained from a software model such asLandSim. Similarly, the HELP (Hydro-geological Eval-uation of Landfill Performance) model contains onlysome aspects of landfill risk assessment. These aremainly the design features of landfill (such as liners andcapping) and some of the baseline study aspects (likeprecipitation and surface run-off). However, it does notconsider a very important aspect of risk assessment, i.e.an exposure assessment system. Although the softwareGasSim deals with some aspects of risk assessment,including gas generation, migration, impact andexposure, it is only for landfill gas and not leachate.Also, the exposure aspect regards mainly humans andthe atmosphere as receptors, and no other environmen-tal species are taken into account. GasSimLite is alsofrom the perspective of landfill gas only and can be usedonly in terms of calculating gas emissions.

The ConSim model is a tool for assessing the risksthat are posed to groundwater quality by pollutantsmigrating from contaminated land [73]. The authorslearnt that this is not specifically for landfills, particu-larly when landfills have a leachate head and/or liners,which is a likely scenario with modern landfills [74].Also, this model does not accommodate receptors otherthan groundwater. The CLEA (Contaminated LandExposure Assessment) model considers risks only tohuman health and not other environmental receptorssuch as plants, animals, buildings and controlled waters[75]. Pathways are seen only from the perspective ofsoil as an exposure medium and not leachate [76]. Also,this model has been developed for contaminated landand not specifically for landfills [77]. Other elementsare absent in the model, such as those at no. 5mentioned in the first row of Table 1.

Spatial Analysis and Decision Assistance (SADA)is software that incorporates tools from environmentalassessment fields into an effective problem solvingenvironment [78]. These tools include integratedmodules for visualization, geospatial analysis, statisti-cal analysis, human health risk assessment, ecologicalrisk assessment, cost–benefit analysis, sampling design,and decision analysis. Out of this wide range of tools ormodules, only two of the most relevant are describedhere as examples. The Human Health Risk moduleprovides a full human health risk assessment and asso-ciated databases from a range of land-use scenarios.These include residential, industrial, agricultural, recre-ational and excavation but not specifically landfills.Ecological Risk is another module or unit of the SADAwhich allows users to perform benchmark screenings,

and has the ability to calculate forward risk to a numberof terrestrial and aquatic receptors that are currentlybeing added. Even after this module has been fullydeveloped, it may only be helpful to an extent toaddress a few aspects of landfill exposure assessments.For instance, it may assist in identifying a whole rangeof environmental receptors (both aquatic and terres-trial), but, for humans as receptors, the user still willhave to consult the former module i.e. Human HealthRisk module. The SADA appears to contain a numberof various software tools to address a range of differentrisk scenarios. Thus, landfill assessors will have to pickthe right combination of these different software toolseach time they are carrying out a landfill exposure anal-ysis, and yet SADA will not provide for each and everyfacet of landfill exposure assessment in a readilyuseable format. Moreover, as the title ‘Spatial Analysisand Decision Assistance’ states, the focus appears to bemore on spatial than temporal factors.

The Adaptable Risk Assessment Modelling System(ARAMS) is a computer-based modelling and database-driven analysis system developed for the US Army forestimating the human and ecological health impacts andrisk associated with military-relevant compounds(MRCs) and other constituents [79]. ARAMS takes vari-ous existing databases and models for exposure, intake/update and effects (health impacts) and incorporatesthem into conceptual site-models. The user may need tochoose which particular model and/or database to use foreach scenario. The heart of ARAMS is the object-oriented Conceptual Site Model (CSM), but that relieson another computer program called FRAMES discussedbelow. Thus, it is not an easy task to adapt ARAMS intoa landfill leachate scenario every time a landfill assessordecides to use it. Although, ARAMS appears to concen-trate mostly on the exposure assessment facet of riskanalysis, it does not cover all the elements indicated inTable 1 (first row, last column) in an algorithmic fashion,specifically for landfills. Similarly, the Multimedia Envi-ronmental Pollutant Assessment System (MEPAS) isanother computer-based program that is a suite of envi-ronmental models, developed to assess environmentalcontamination problems for government, industrial, andinternational clients [80]. The software integrates trans-port and exposure pathways for chemical and radioactivereleases to determine their potential impact on thesurrounding environment, individuals, and populations.In the context of landfills, the situation with MEPAS isnot much different than that of ARAMS: neither presentsan overall exposure assessment methodology of landfillleachate.

The Framework for Risk Analysis MultimediaEnvironmental Systems (FRAMES) is a software plat-form for selecting and implementing environmentalsoftware models for risk assessment and management

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1497

problems, which may even include governance issues[81]. In other words, the purpose of FRAMES is toassist users in developing environmental scenarios andto provide options for selecting the most appropriatecomputer codes to conduct human and environmentalrisk management analyses [82]. This program is a flex-ible tool and offers an overall approach to understand-ing how industrial activities affect humans and theenvironment. It incorporates models that integrateacross scientific disciplines, allowing for tailored solu-tions to specific activities, and it provides meaningfulinformation to business and technical managers.FRAMES is the key to identifying, analysing andmanaging potential environmental, safety and healthrisks. Thus, FRAMES is a hugely generic program, andyet it does not contain software for a landfill leachatescenario, which could guide a landfill assessor toperform a landfill exposure analysis holistically includ-ing all the factors (first row, Table 1) in one place.

The RESRAD is a combination of two words,residual and radiation [83], and is used as an acronymfor Residual Radiation environmental analysis [84].The RESRAD is a family of computer codes or modulesto provide a scientifically based assessment of thedegree of cleanliness of residual contamination and toprovide useful tools for evaluating human health risksfrom such contamination [85]. These codes or modulesinclude [85,86]:

RESRAD, for soil contaminated with radionu-clides,

RESRADBUILD, for buildings contaminatedwith radionuclides,

RESRAD-CHEM, for soil contaminated withhazardous chemicals,

RESRADBASELINE, for risk assessmentsagainst measured (baseline) concentrations ofboth radionuclides and chemicals in environmen-tal media,

RESRAD-ECORISK, for ecological riskassessments,

RESRAD-RECYCLE, for recyclng and reuse ofradiologically contaminated metals and equip-ment,

RESRAD-OFFSITE, for off-site receptor dose/risk assessment.

From the above it is obvious that none of thesemodules/codes is specifically for landfill leachate,although they address a range of environmental issuesand aspects. Even if these codes or modules are used incombination, they are not able to address all the featuresof exposure analysis of landfill leachate, expressed inthe first row of Table 1. Furthermore, to combine theseinto a landfill leachate context alone would be a

cumbersome task to execute each time an exposureassessment and risk analysis were to be performed fordifferent landfill scenarios. For instance, RESRAD-CHEM considers nine exposure pathways includinginhalation of dust and volatiles; ingestion of plant foods,meat, milk, soil, aquatic food and water; and dermalabsorption from soil and water contact. This code mayhelp address aspects of exposure assessment but not allthe absent elements in an integrated format. However,this code is no longer being updated [87].

Another three computer models developed for expo-sure assessment and risk analysis are RISC-HUMAN3.1, RUM and Vlier-Humaan [88–90], respectively),but they have been built for contaminated land and notspecifically for landfills. Only humans are considered asreceptors in these software packages. Other potentialenvironmental receptors, such as watercourses and thebuilt environment, have not been taken into consider-ation. The aggregation aspect (i.e. total exposure of thesame receptor via various routes, as mentioned in point2b, first row of Table 1) and statistical considerations(point 5, first row of Table 1) are also absent.

In summary, the authors have come across no inte-grated computer model of a holistic exposure assessmentprocedure, which could assist in the execution of theexposure analysis process, specifically for a given land-fill leachate from start to end and considering a wholerange of eventualities and/or scenarios. Currently avail-able computer models lack the elements indicated in thefirst row of Table 1, either completely or partly. Theseabsent elements or knowledge gaps require furtherinvestigation and resolution. Also, current computermodels do not present such a concise exposure assess-ment model for landfill leachate, which, as a completeunit, could readily be assembled with the format of othermodules and sub-modules of the total risk assessmentframework indicated in Figure 2. In parallel with theliterature (Section 2), computer models are also availablein a non-integrated manner. Thus, not only a holisticprocedure of exposure assessment but also a correspond-ing computer model in an integrated format, specificallyfor landfill leachate, which encapsulates all the absentelements (first row, Table 1) under one umbrella, canhelp to perform a quantitative exposure analysis moreeffectively and efficiently. Subsequently, this will assistthe risk analysis process.

4. Conclusion

Despite having a high potential to pollute the environ-ment, landfills are an inevitable and required wastedisposal option. Risk assessment and management is aneffective tool to guard the environment against landfillhazards. However, there is no integrated methodologyof landfill risk analysis, along with a corresponding

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et al.

knowledge-based computer model, which is helpfulenough to execute the process of risk assessment forlandfill leachate from the start (i.e. baseline study)through exposure assessment to the end (i.e. hazardindices and risk quantification). A number of knowl-edge gaps have been identified in the literaturereviewed to date, and a holistic exposure assessmentprocedure accompanied by a corresponding computermodel is one of them. The exposure assessment is oneof the most important factors of an effective and quan-titative risk analysis, as the success of the latter is basedon the former.

Current literature and models are just about able tomeet the risk assessment requirements of the presentenvironmental legislation in the UK. Future legisla-tion will be more stringent and wider in scope toencapsulate more environmental species such as vari-ous food chain links, ecological systems, terrestrialand aquatic flora and fauna. Therefore a morecomprehensive, concise and robust risk analysissystem, underpinned by a more strategic exposureassessment approach, will be needed. This researchwork assists the authors to recognise the necessity andsignificance of exposure assessment and to identifyknowledge gaps and the limitations of current models,thereby laying the foundation for developing in thefuture a more complete and sequential, or step-by-step, procedure for quantitative exposure assessmentin an integrated fashion specifically for landfillleachate. This study may also be helpful for construct-ing a corresponding holistic computer model ofexposure analysis.

Acknowledgements

The authors acknowledge the financial support of DundeeCity Council in this project. We are additionally grateful forthe discussion and help received from Mr Peter Goldie of theEnvironment & Consumer Protection Department, DundeeCity Council. The support from Stephen T. Washburn(Managing Principal, ENVIRON, New Jersey, USA), Dr I.M.Spence (Consultant Environmental Geologist, Scotland), andcolleagues at the University of Abertay Dundee, including MrOlisanwendu Ogwuda and Mr Phillip Jenkins, is also highlyappreciated.

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