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2 Optics Sources W-3 -4

Jun 02, 2018

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    UVX-rays IR

    Micro

    Waves Radio/Televisionwavesg

    - rays

    Wavelength (m) 10-910-10 10-8 10-7 10-6 10-310-5 10-4 10110-110-2 1

    Wave number cm-1108 107 106 105 104 103 102 101 1 10-1 10-2 10-3

    700600400

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    Electromagnetic Spectrum

    (m)

    1000 100 10 1 0.1 0.01

    ultraviolet

    visible

    lightinfraredmicrowaves x-rays

    High

    Energy

    Low

    Energy

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    Sources of EMR

    Deuterium Lamp UV

    Mercury lamp UV

    Xenon lamp UV-VIS

    Tungsten Lamp VIS-NIR

    Silicon carbide globar

    Nernst

    IR

    Laser UV-VIS-NIR

    Hollow-cathode lamp UV-VIS-NIR

    Flame ,Furnaces, Plasmas UV- VIS-IR

    X-ray tube X-Rays

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    A general rule:

    The higher an objects temperature, the more intenselythe object emits electromagnetic radiation and theshorter the wavelength at which emits most strongly

    Radiation depending on Temperature

    The example of heated iron bar.As the temperature increases

    The bar glows morebrightly

    The color of the bar alsochanges

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    The black body is important in thermal radiation theory

    and practice.

    The ideal black body notion is important in studyingthermal radiation and electromagnetic radiationtransfer in all wavelength bands.

    The black body is used as a standard with which the

    absorption of real bodies is compared.

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    Definition of a black body

    A black body is an ideal body whichallows the whole of the incident

    radiation to pass into itself (without

    reflecting the energy ) and absorbs

    within itself this whole incident

    radiation. This propety is valid for

    radiation corresponding to all

    wavelengths and to all angels of

    incidence. Therefore, the black body

    is an ideal absorber of incidentradaition.

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    A blackbody is a hypothetical objectthat is a perfect absorber of

    electromagnetic radiation at allwavelengths

    The radiation of a blackbody isentirely the result of itstemperature

    A blackbody does not reflect anylight at all

    Blackbody curve: the intensities ofradiation emitted at variouswavelengths by a blackbody at agiven temperature

    The higher the temperature, theshorter the peak wavelength

    The higher the temperature, thehigher the intensity

    Blackbody Radiation

    Blackbody curve

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    Basic Laws of Radiation

    1) All objects emit radiant energy.

    2) Hotter objects emit more energy than colder

    objects (per unit area). The amount of energy

    radiated is proportional to the temperature of

    the object.

    3) The hotter the object, the shorter the

    wavelength () of emitted energy.

    This isWiens Law

    max 3000 m

    T(K)

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    Stefan Boltzmann Law.

    F = T4

    F = flux of energy (W/m2)

    T = temperature (K)

    = 5.67 x 10

    -8

    W/m

    2

    K

    4

    (a constant)

    Wiens Law

    max 3000 m

    T(K)

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    We can use these equations to calculate properties

    of energy radiating from the Sun and the Earth.

    6,000 K 300 K

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    T(K)

    max

    (m)

    region inspectrum F

    (W/m2)

    Sun 6000 0.5 Visible 7 x 107

    Earth 300 10 infrared 460

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    Temperature Source

    1,700 K Match flame

    1,850 K Candle flame, sunset/sunrise

    2,7003,300 K Incandescent lamps

    3,000 K Soft White CFL

    3,200 K Studio lamps, photo floods lights.

    3,350 K Studio "CP" light

    4,1004,150 K Moonlight

    5,000 K Horizon daylight

    5,000 K

    tubular fluorescent lamps or cool

    white/daylight compact fluorescent

    lamps (CFL)

    5,5006,000 K electronic flash

    6,200 K Xenon arc lamp

    6,500 K Daylight

    5,50010,500 K LCD or CRT screen

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    Light bulbs contain a metal wire filament,

    which is heated by electricity. The filament

    becomes so hot, it glows white. The change from electrical energy to

    visible light energy involves the following

    energy transformation:Electrical energy -> thermal energy -> visible

    light energy

    Incandescent sources

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    Spectral Lines

    Bright spectrum lines can be seen when a chemicalsubstance is heated and valoprized (Kirchhoff, ~1850)

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    Kirchhoffs Laws on Spectrum

    Law 1- Continuous spectrum: a hot opaque body, such as

    a perfect blackbody, produce a continuous spectrum

    acomplete rainbow of colors without any spectral line

    Law 2 emission line spectrum: a hot, transparent gasproduces an emission line spectrum a series of bright

    spectral lines against a dark background

    Law 3 absorption line spectrum: a relatively cool,transparent gas in front of a source of a continuous

    spectrum produces an absorption line spectrum aseries of dark spectral lines amongst the colors of thecontinuous spectrum. Further, the dark lines of aparticular gas occur at exactly the same wavelengthas the bright lines of that same gas.

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    Each chemical element has its own unique set of spectral lines.

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    Kirchhoffs Laws on Spectrum

    Three different spectrum: continuous spectrum, emission-linespectrum, and absorption line spectrum

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    Electrons occupy

    only certain orbits orenergy levels

    When an electronjumps from one orbit

    to another, it emits orabsorbs a photon ofappropriate energy.

    The energy of the

    photon equals thedifference in energybetween the twoorbits.

    Bohrs Model of Atom

    Bohrs Model of Hydrogen

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    Deuterium Arc Lamp

    Li ht

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    Light sources

    Black-body radiation for vis and IR but not UV

    - a tungs ten lampis an excellent source of black-body radiation

    - operates at 3000 K

    - produces from 320 to 2500 nm

    For UV:

    - a common lamp is a deuterium arc lamp

    - electric discharge causes D2 to dissociate and emit UV radiation (160 325

    nm)

    - other good sources are:Xe (250 1000 nm)

    Hg (280 1400 nm)

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    D2 Lamps

    Type of lamp is used for Ultraviolet Spectroscopy most bulbs mainly show visible light and the intensity

    of UV light is very small

    D2 lamp, the intensity of the UV light is very high,

    Which leads to a better signal to noise ratio for measurements with UV light

    Emits wavelengths from 160 nm to 400 nm

    Deuterium is stored a controlled pressures

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    A deuterium lamp uses

    a tungsten filament and anode placed on

    opposite sides of a nickel box structure

    designed to produce the best output

    spectrum.

    Unlike an incandescent bulb, the filament

    is not the source of light in deuterium

    lamps. An arc is created from the filament

    to the anode

    Since the filament must be very hot

    before it can operate, it is heated for

    approximately twenty seconds before

    use.

    Because the discharge process produces

    its own heat, the heater is turned down

    after discharge begins

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    D

    2

    lamp

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    Window Material

    UV Glass Synthetic Quartz Synthetic Silica MgF2

    Minimum wavelength

    115nm, 160 nm, 185 nm

    Maximum wavelength

    Typically around 400 nm

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    a tungsten anode and a cylindrical cathodeneon or argon at a pressure of 1 to 5 torr

    The cathode is constructed of the metal whose

    spectrum is desired or served to support a layer of

    that metal

    Hollow Cathode Lamp

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    Ne or Ar

    at 1-5

    Torr

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    Ionize the inert gas at a potential of ~ 300 V

    Generate a current of ~ 5 to 15 mA as ions andelectrons migrate to the electrodes.

    The gaseous cations acquire enough kinetic energy to

    dislodge some of the metal atoms from the cathodesurface and produce an atomic cloud.

    A portion of sputtered metal atoms is in excited states

    and thus emits their characteristic radiation as they

    return to the ground sate

    Eventually, the metal atoms diffuse back to the cathodesurface or to the glass walls of the tube and are re-

    deposited

    Hollow Cathode Lamp

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    Infrared Sources

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    Infrared Sources

    Most Common IR Sources

    Nernst glower

    cylinder of rare-earth oxides

    glowbar

    silicon carbide rod

    50mm long by 5mm diameter

    incandescent wire

    nichrome wire

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    Infrared Sources

    Special Application IR Sources

    mercury arc

    far-infrared tungsten filament

    near-infrared

    carbon dioxide laser tunable

    Th N t l

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    The Nernst glower

    Typically it is in the form of a cylindrical rod or tube havinga diameter of 1-2 mm and length of 20 mm sealed by a

    platinum leads to the ends to permit electrical connection.

    It is composed of a mixture of rare earth oxides such aszirconium oxide (ZrO2), yttrium oxide (Y2O3) and erbiumoxide (Er2O3) at a ratio of 90:7:3 by weight.

    They are operated by being electrically heated to about1500 to 2000 C. Initially they required external heatingbecause the material is an insulator at room temperature.

    Operates best in wavelengths from 2 to 14 micrometers

    Produces black body radiation

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    The Nernst glower

    Nernst glowers are fragile.

    They have a large negative temperature coefficient ofelectrical resistance and must be preheated to beconductive.

    Resistance decreases with increasing temperature thesource circuit must be designed to limit the current toprevent rapid heating and destroying the source

    http://www.google.ps/imgres?imgurl=http://www.nernst.de/museum/glower.jpg&imgrefurl=http://www.nernst.de/museum/museum.htm&usg=__qtJc3Z7sz51nCAjHqsHPzfzsOaw=&h=455&w=1289&sz=142&hl=ar&start=4&zoom=1&um=1&itbs=1&tbnid=Y8cKH9odkXcjsM:&tbnh=53&tbnw=150&prev=/search%3Fq%3Dnernst%2Bglower,%2Bir%2Bsource%26tbnid%3Dv6CsEFAWhRnHvM:%26tbnh%3D0%26tbnw%3D0%26um%3D1%26hl%3Dar%26rlz%3D1W1AMSA_en%26biw%3D1366%26bih%3D492%26tbm%3Disch&ei=9s5WTv-4M4qv8gPSnLTFDA
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    Incandescent Wire Source

    Lower intensity IR source butlonger life than the Globar orNernst glower.

    A tightly wound spiral of nichromewire heated to about 1100 k by anelectric current.

    A similar source is a rhodium wireheater sealed in a ceramiccylinder.

    Incandescent wire sources are

    longer lasting but of lowerintensity than the glower or globar.

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    The Tungsten Filament Lamp

    Ordinary tungsten filament lamp (A

    quartz halogen lamp contains atungsten wire filament and iodinevapor sealed in a quartz envelope orbulb), used for near IR region of 4000-12,800 cm-1 (2.5-0.78m)

    In a standard tungsten filament lamp,

    the tungsten evaporates from thefilament and deposits on the lampwall.

    This process reduces the light outputas a result of the black deposit on thewall and the thinner filament.

    The halogen gas in a tungsten-halogen lamp removes theevaporated tungsten and redepositsit on the filament, increasing the lightoutput and source stability

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    Spectrum of Tungsten lamp

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    Globar

    Globar is a silicon carbide rod of 5 to 10 mm width and

    20 to 50 mm length which is electrically heated up to

    1,000 to 1,650 C

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    Nernst Glower vs. Globar

    The two light sources are similar in many ways, such

    as the function and temperature range.

    However, the Nernst glower is better used at shorter

    IR wavelengths (near IR), whereas globar is better

    used at longer IR wavelengths.

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    Advantages of Nernst

    Requires less power than a globar

    Lasts a lifetime

    Operates in air

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    Disadvantages

    Very expensive

    Extremely fragile

    Because it is operated in the air, whichis an advantage, if the temperature

    becomes too high, it will burn out, which

    is obviously a disadvantage.

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    http://www.google.ps/imgres?imgurl=http://www.modulatedlight.org/Modulated_Light_DX/LampMods.jpg&imgrefurl=http://www.modulatedlight.org/Modulated_Light_DX/LongArticle1Jan79.html&usg=__jZlKIFSvuAY-8kmIAgOt_P0NgV4=&h=479&w=391&sz=12&hl=ar&start=1&zoom=1&um=1&itbs=1&tbnid=8BFMZjR2pPAt8M:&tbnh=129&tbnw=105&prev=/search%3Fq%3Dmercury%2Barc%2Blamp,%2BIR%2Bsource%26tbnid%3D8BFMZjR2pPAt8M:%26tbnh%3D0%26tbnw%3D0%26um%3D1%26hl%3Dar%26sa%3DX%26rlz%3D1W1AMSA_en%26biw%3D1366%26bih%3D492%26imgtype%3Di_similar%26tbm%3Disch&ei=UdFWTrHdFJC38QPNkcm6DA
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    The Mercury Arc.

    Used for Far IR region (>50 m).

    It is a high pressure mercury arc

    which consist of a quartz - jacketedtube containing Hg vapor at P > 1atm.

    When current passes through thelamp, mercury is vaporized, excited,

    and ionized, forming a plasmadischarge at high pressure (P>1 atm)

    In the UV and visible regions, this

    lamp emits atomic Hg emission linesthat are very narrow and discrete, butemits an intense continuum in the far-IR region.

    http://www.google.ps/imgres?imgurl=http://www.modulatedlight.org/Modulated_Light_DX/LampMods.jpg&imgrefurl=http://www.modulatedlight.org/Modulated_Light_DX/LongArticle1Jan79.html&usg=__jZlKIFSvuAY-8kmIAgOt_P0NgV4=&h=479&w=391&sz=12&hl=ar&start=1&zoom=1&um=1&itbs=1&tbnid=8BFMZjR2pPAt8M:&tbnh=129&tbnw=105&prev=/search%3Fq%3Dmercury%2Barc%2Blamp,%2BIR%2Bsource%26tbnid%3D8BFMZjR2pPAt8M:%26tbnh%3D0%26tbnw%3D0%26um%3D1%26hl%3Dar%26sa%3DX%26rlz%3D1W1AMSA_en%26biw%3D1366%26bih%3D492%26imgtype%3Di_similar%26tbm%3Disch&ei=UdFWTrHdFJC38QPNkcm6DA
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    Hg Lamp Spectrum

    Wavelength (nm) Name Color

    365.4 I-line ultraviolet (UVA)

    404.7 H-line violet

    435.8 G-line blue

    546.1 green

    578.2 yellow-orange

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    Summery of different IR sources

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    IR Laser Sources

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    IR Laser Sources

    A laser is a light source that emits very intense

    monochromatic radiation.

    Some lasers, called tunable lasers, emit more than onewavelength of light, but each wavelength emitted ismonochromatic.

    The combination of high intensity and narrow line widthmakes lasers ideal light sources for some applications.

    Two types of IR lasers are available: gas phase and solid-state.