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UVX-rays IR
Micro
Waves Radio/Televisionwavesg
- rays
Wavelength (m) 10-910-10 10-8 10-7 10-6 10-310-5 10-4 10110-110-2 1
Wave number cm-1108 107 106 105 104 103 102 101 1 10-1 10-2 10-3
700600400
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Electromagnetic Spectrum
(m)
1000 100 10 1 0.1 0.01
ultraviolet
visible
lightinfraredmicrowaves x-rays
High
Energy
Low
Energy
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Sources of EMR
Deuterium Lamp UV
Mercury lamp UV
Xenon lamp UV-VIS
Tungsten Lamp VIS-NIR
Silicon carbide globar
Nernst
IR
Laser UV-VIS-NIR
Hollow-cathode lamp UV-VIS-NIR
Flame ,Furnaces, Plasmas UV- VIS-IR
X-ray tube X-Rays
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A general rule:
The higher an objects temperature, the more intenselythe object emits electromagnetic radiation and theshorter the wavelength at which emits most strongly
Radiation depending on Temperature
The example of heated iron bar.As the temperature increases
The bar glows morebrightly
The color of the bar alsochanges
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The black body is important in thermal radiation theory
and practice.
The ideal black body notion is important in studyingthermal radiation and electromagnetic radiationtransfer in all wavelength bands.
The black body is used as a standard with which the
absorption of real bodies is compared.
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Definition of a black body
A black body is an ideal body whichallows the whole of the incident
radiation to pass into itself (without
reflecting the energy ) and absorbs
within itself this whole incident
radiation. This propety is valid for
radiation corresponding to all
wavelengths and to all angels of
incidence. Therefore, the black body
is an ideal absorber of incidentradaition.
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A blackbody is a hypothetical objectthat is a perfect absorber of
electromagnetic radiation at allwavelengths
The radiation of a blackbody isentirely the result of itstemperature
A blackbody does not reflect anylight at all
Blackbody curve: the intensities ofradiation emitted at variouswavelengths by a blackbody at agiven temperature
The higher the temperature, theshorter the peak wavelength
The higher the temperature, thehigher the intensity
Blackbody Radiation
Blackbody curve
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Basic Laws of Radiation
1) All objects emit radiant energy.
2) Hotter objects emit more energy than colder
objects (per unit area). The amount of energy
radiated is proportional to the temperature of
the object.
3) The hotter the object, the shorter the
wavelength () of emitted energy.
This isWiens Law
max 3000 m
T(K)
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Stefan Boltzmann Law.
F = T4
F = flux of energy (W/m2)
T = temperature (K)
= 5.67 x 10
-8
W/m
2
K
4
(a constant)
Wiens Law
max 3000 m
T(K)
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We can use these equations to calculate properties
of energy radiating from the Sun and the Earth.
6,000 K 300 K
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T(K)
max
(m)
region inspectrum F
(W/m2)
Sun 6000 0.5 Visible 7 x 107
Earth 300 10 infrared 460
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Temperature Source
1,700 K Match flame
1,850 K Candle flame, sunset/sunrise
2,7003,300 K Incandescent lamps
3,000 K Soft White CFL
3,200 K Studio lamps, photo floods lights.
3,350 K Studio "CP" light
4,1004,150 K Moonlight
5,000 K Horizon daylight
5,000 K
tubular fluorescent lamps or cool
white/daylight compact fluorescent
lamps (CFL)
5,5006,000 K electronic flash
6,200 K Xenon arc lamp
6,500 K Daylight
5,50010,500 K LCD or CRT screen
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Light bulbs contain a metal wire filament,
which is heated by electricity. The filament
becomes so hot, it glows white. The change from electrical energy to
visible light energy involves the following
energy transformation:Electrical energy -> thermal energy -> visible
light energy
Incandescent sources
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Spectral Lines
Bright spectrum lines can be seen when a chemicalsubstance is heated and valoprized (Kirchhoff, ~1850)
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Kirchhoffs Laws on Spectrum
Law 1- Continuous spectrum: a hot opaque body, such as
a perfect blackbody, produce a continuous spectrum
acomplete rainbow of colors without any spectral line
Law 2 emission line spectrum: a hot, transparent gasproduces an emission line spectrum a series of bright
spectral lines against a dark background
Law 3 absorption line spectrum: a relatively cool,transparent gas in front of a source of a continuous
spectrum produces an absorption line spectrum aseries of dark spectral lines amongst the colors of thecontinuous spectrum. Further, the dark lines of aparticular gas occur at exactly the same wavelengthas the bright lines of that same gas.
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Each chemical element has its own unique set of spectral lines.
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Kirchhoffs Laws on Spectrum
Three different spectrum: continuous spectrum, emission-linespectrum, and absorption line spectrum
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Electrons occupy
only certain orbits orenergy levels
When an electronjumps from one orbit
to another, it emits orabsorbs a photon ofappropriate energy.
The energy of the
photon equals thedifference in energybetween the twoorbits.
Bohrs Model of Atom
Bohrs Model of Hydrogen
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Deuterium Arc Lamp
Li ht
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Light sources
Black-body radiation for vis and IR but not UV
- a tungs ten lampis an excellent source of black-body radiation
- operates at 3000 K
- produces from 320 to 2500 nm
For UV:
- a common lamp is a deuterium arc lamp
- electric discharge causes D2 to dissociate and emit UV radiation (160 325
nm)
- other good sources are:Xe (250 1000 nm)
Hg (280 1400 nm)
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D2 Lamps
Type of lamp is used for Ultraviolet Spectroscopy most bulbs mainly show visible light and the intensity
of UV light is very small
D2 lamp, the intensity of the UV light is very high,
Which leads to a better signal to noise ratio for measurements with UV light
Emits wavelengths from 160 nm to 400 nm
Deuterium is stored a controlled pressures
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A deuterium lamp uses
a tungsten filament and anode placed on
opposite sides of a nickel box structure
designed to produce the best output
spectrum.
Unlike an incandescent bulb, the filament
is not the source of light in deuterium
lamps. An arc is created from the filament
to the anode
Since the filament must be very hot
before it can operate, it is heated for
approximately twenty seconds before
use.
Because the discharge process produces
its own heat, the heater is turned down
after discharge begins
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D
2
lamp
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Window Material
UV Glass Synthetic Quartz Synthetic Silica MgF2
Minimum wavelength
115nm, 160 nm, 185 nm
Maximum wavelength
Typically around 400 nm
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a tungsten anode and a cylindrical cathodeneon or argon at a pressure of 1 to 5 torr
The cathode is constructed of the metal whose
spectrum is desired or served to support a layer of
that metal
Hollow Cathode Lamp
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Ne or Ar
at 1-5
Torr
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Ionize the inert gas at a potential of ~ 300 V
Generate a current of ~ 5 to 15 mA as ions andelectrons migrate to the electrodes.
The gaseous cations acquire enough kinetic energy to
dislodge some of the metal atoms from the cathodesurface and produce an atomic cloud.
A portion of sputtered metal atoms is in excited states
and thus emits their characteristic radiation as they
return to the ground sate
Eventually, the metal atoms diffuse back to the cathodesurface or to the glass walls of the tube and are re-
deposited
Hollow Cathode Lamp
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Infrared Sources
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Infrared Sources
Most Common IR Sources
Nernst glower
cylinder of rare-earth oxides
glowbar
silicon carbide rod
50mm long by 5mm diameter
incandescent wire
nichrome wire
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Infrared Sources
Special Application IR Sources
mercury arc
far-infrared tungsten filament
near-infrared
carbon dioxide laser tunable
Th N t l
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The Nernst glower
Typically it is in the form of a cylindrical rod or tube havinga diameter of 1-2 mm and length of 20 mm sealed by a
platinum leads to the ends to permit electrical connection.
It is composed of a mixture of rare earth oxides such aszirconium oxide (ZrO2), yttrium oxide (Y2O3) and erbiumoxide (Er2O3) at a ratio of 90:7:3 by weight.
They are operated by being electrically heated to about1500 to 2000 C. Initially they required external heatingbecause the material is an insulator at room temperature.
Operates best in wavelengths from 2 to 14 micrometers
Produces black body radiation
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The Nernst glower
Nernst glowers are fragile.
They have a large negative temperature coefficient ofelectrical resistance and must be preheated to beconductive.
Resistance decreases with increasing temperature thesource circuit must be designed to limit the current toprevent rapid heating and destroying the source
http://www.google.ps/imgres?imgurl=http://www.nernst.de/museum/glower.jpg&imgrefurl=http://www.nernst.de/museum/museum.htm&usg=__qtJc3Z7sz51nCAjHqsHPzfzsOaw=&h=455&w=1289&sz=142&hl=ar&start=4&zoom=1&um=1&itbs=1&tbnid=Y8cKH9odkXcjsM:&tbnh=53&tbnw=150&prev=/search%3Fq%3Dnernst%2Bglower,%2Bir%2Bsource%26tbnid%3Dv6CsEFAWhRnHvM:%26tbnh%3D0%26tbnw%3D0%26um%3D1%26hl%3Dar%26rlz%3D1W1AMSA_en%26biw%3D1366%26bih%3D492%26tbm%3Disch&ei=9s5WTv-4M4qv8gPSnLTFDA8/11/2019 2 Optics Sources W-3 -4
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Incandescent Wire Source
Lower intensity IR source butlonger life than the Globar orNernst glower.
A tightly wound spiral of nichromewire heated to about 1100 k by anelectric current.
A similar source is a rhodium wireheater sealed in a ceramiccylinder.
Incandescent wire sources are
longer lasting but of lowerintensity than the glower or globar.
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The Tungsten Filament Lamp
Ordinary tungsten filament lamp (A
quartz halogen lamp contains atungsten wire filament and iodinevapor sealed in a quartz envelope orbulb), used for near IR region of 4000-12,800 cm-1 (2.5-0.78m)
In a standard tungsten filament lamp,
the tungsten evaporates from thefilament and deposits on the lampwall.
This process reduces the light outputas a result of the black deposit on thewall and the thinner filament.
The halogen gas in a tungsten-halogen lamp removes theevaporated tungsten and redepositsit on the filament, increasing the lightoutput and source stability
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Spectrum of Tungsten lamp
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Globar
Globar is a silicon carbide rod of 5 to 10 mm width and
20 to 50 mm length which is electrically heated up to
1,000 to 1,650 C
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Nernst Glower vs. Globar
The two light sources are similar in many ways, such
as the function and temperature range.
However, the Nernst glower is better used at shorter
IR wavelengths (near IR), whereas globar is better
used at longer IR wavelengths.
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Advantages of Nernst
Requires less power than a globar
Lasts a lifetime
Operates in air
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Disadvantages
Very expensive
Extremely fragile
Because it is operated in the air, whichis an advantage, if the temperature
becomes too high, it will burn out, which
is obviously a disadvantage.
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http://www.google.ps/imgres?imgurl=http://www.modulatedlight.org/Modulated_Light_DX/LampMods.jpg&imgrefurl=http://www.modulatedlight.org/Modulated_Light_DX/LongArticle1Jan79.html&usg=__jZlKIFSvuAY-8kmIAgOt_P0NgV4=&h=479&w=391&sz=12&hl=ar&start=1&zoom=1&um=1&itbs=1&tbnid=8BFMZjR2pPAt8M:&tbnh=129&tbnw=105&prev=/search%3Fq%3Dmercury%2Barc%2Blamp,%2BIR%2Bsource%26tbnid%3D8BFMZjR2pPAt8M:%26tbnh%3D0%26tbnw%3D0%26um%3D1%26hl%3Dar%26sa%3DX%26rlz%3D1W1AMSA_en%26biw%3D1366%26bih%3D492%26imgtype%3Di_similar%26tbm%3Disch&ei=UdFWTrHdFJC38QPNkcm6DA8/11/2019 2 Optics Sources W-3 -4
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The Mercury Arc.
Used for Far IR region (>50 m).
It is a high pressure mercury arc
which consist of a quartz - jacketedtube containing Hg vapor at P > 1atm.
When current passes through thelamp, mercury is vaporized, excited,
and ionized, forming a plasmadischarge at high pressure (P>1 atm)
In the UV and visible regions, this
lamp emits atomic Hg emission linesthat are very narrow and discrete, butemits an intense continuum in the far-IR region.
http://www.google.ps/imgres?imgurl=http://www.modulatedlight.org/Modulated_Light_DX/LampMods.jpg&imgrefurl=http://www.modulatedlight.org/Modulated_Light_DX/LongArticle1Jan79.html&usg=__jZlKIFSvuAY-8kmIAgOt_P0NgV4=&h=479&w=391&sz=12&hl=ar&start=1&zoom=1&um=1&itbs=1&tbnid=8BFMZjR2pPAt8M:&tbnh=129&tbnw=105&prev=/search%3Fq%3Dmercury%2Barc%2Blamp,%2BIR%2Bsource%26tbnid%3D8BFMZjR2pPAt8M:%26tbnh%3D0%26tbnw%3D0%26um%3D1%26hl%3Dar%26sa%3DX%26rlz%3D1W1AMSA_en%26biw%3D1366%26bih%3D492%26imgtype%3Di_similar%26tbm%3Disch&ei=UdFWTrHdFJC38QPNkcm6DA8/11/2019 2 Optics Sources W-3 -4
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Hg Lamp Spectrum
Wavelength (nm) Name Color
365.4 I-line ultraviolet (UVA)
404.7 H-line violet
435.8 G-line blue
546.1 green
578.2 yellow-orange
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Summery of different IR sources
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IR Laser Sources
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IR Laser Sources
A laser is a light source that emits very intense
monochromatic radiation.
Some lasers, called tunable lasers, emit more than onewavelength of light, but each wavelength emitted ismonochromatic.
The combination of high intensity and narrow line widthmakes lasers ideal light sources for some applications.
Two types of IR lasers are available: gas phase and solid-state.